CN1637037A - 硬化剂 - Google Patents
硬化剂 Download PDFInfo
- Publication number
- CN1637037A CN1637037A CNA200410100379XA CN200410100379A CN1637037A CN 1637037 A CN1637037 A CN 1637037A CN A200410100379X A CNA200410100379X A CN A200410100379XA CN 200410100379 A CN200410100379 A CN 200410100379A CN 1637037 A CN1637037 A CN 1637037A
- Authority
- CN
- China
- Prior art keywords
- randomly
- reaction
- under
- polymerization
- polyisocyanates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
- C08G18/673—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing two or more acrylate or alkylacrylate ester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8048—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/34
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
- C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31547—Of polyisocyanurate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31931—Polyene monomer-containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
Abstract
Description
实施例 | 催化剂 | 酸值24h后(mgKOH/g) | 酸值48h后(mgKOH/g) | 羟值(mgKOH/g) | GPC主信号(%面积) | 外观 |
1 | 氢氧化四丁基铵 | 9.2 | 1.2 | 222 | 70 | |
2 | 三乙胺 | 5.3 | 0.8 | 220 | 68 | 黄色 |
3 | Fascat4100*) | 7.0 | 3.8 | 208 | 58 | |
4 | 氯化铯 | 5.9 | 0.7 | 224 | 70 | 黄色 |
5 | 溴化四丁基磷鎓 | 6.2 | 0.8 | 219 | 71 | 黄色 |
6 | dizabicyclooctane | 9.0 | 1.9 | 232 | 80 | 黄色 |
7 | 磷酸二丁酯 | 12.4 | 6.0 | - | - | - |
8 | 辛酸锡(II) | 9.3 | 7.4 | - | - | 粘性的 |
9 | 二月桂酸二丁基锡 | 12.3 | 6.4 | - | - | - |
10 | 硫二甘醇 | 8.5 | 4.4 | - | - | - |
11 | 氯化三乙基苄基铵 | 2.7 | - | 245 | 84 | - |
12 | 三苯膦 | 1.3 | - | 224 | 68 | - |
13 | 二甲基氨基吡啶 | 1.4 | - | 249 | 85 | 黄色 |
实施例 | 催化剂 | 酸值24h后(mgKOH/g) | 酸值48h后(mgKOH/g) | 羟值(mgKOH/g) | GPC主信号(%面积) | 外观 |
14 | 氯化三乙基苄基铵 | 9.2 | 2.1 | 243 | 79 | - |
15 | 三苯膦 | 6.3 | 1.0 | 220 | 75 | - |
16 | 二甲基氨基吡啶 | 5.7 | 1.6 | 244 | 82 | 黄色 |
粘度 | 羟值 | 酸值 | 环氧化物值 | 颜色指数(APHA) | |
对比实施例VI | 233mPas | 233 | 0.9 | 0.60% | 18 |
实施例17 | 245mPas | 228 | 0.6 | 0.10% | 25 |
粘度 | 羟值 | 酸值 | 环氧化物值 | 颜色指数(APHA) | |
实施例18 | 65mPas | 228 | 3.5 | 0.10% | 29 |
粘度 | 羟值 | 酸值 | 环氧化物值 | 颜色指数(APHA) | |
实施例19 | 76mPas | 232 | 3.0 | <0.10% | 85 |
粘度 | 羟值 | 酸值 | 环氧化物值 | 颜色指数(APHA) | |
对比实施例V2 | 80mPas | 228 | 0.3 | 0.8% | 80 |
实施例 | 初始批次中的链终止剂 | 结束时的链终止剂 | 室温下保存 | 在60℃下保存 |
V4 | 无 | 无 | 11天后凝胶化 | 4天后凝胶化 |
V5 | 苯甲酰氯0.02wt% | 无 | 20天后凝胶化 | 4天后凝胶化 |
V6 | 无 | 苯甲酰氯0.02wt% | 16天后凝胶化 | 5天后凝胶化 |
V7 | 4-甲苯磺酸0.02wt% | 无 | 15天后凝胶化 | 5天后凝胶化 |
V8 | 无 | 4-甲苯磺酸0.02wt% | 15天后凝胶化 | 5天后凝胶化 |
V9 | 磷酸二丁酯0.02% | 无 | 21天后凝胶化 | 8天后凝胶化 |
V10 | 无 | 磷酸二丁酯0.02wt% | 21天后凝胶化 | 8天后凝胶化 |
V11 | 无 | 无 | 16天后凝胶化 | 6天后凝胶化 |
20 | 无 | 无 | 21天后终止,没有结果 | 21天后终止,没有结果 |
粘度 | 固含量 | NCO含量 | 颜色指数(APHA) | |
对比实施例V13 | 2050mPas | 89.6% | 9.0% | 25 |
粘度 | 固体含量 | NCO含量 | 颜色指数(APHA) | |
实施例21 | 280mPas | 79.1% | 9.1% | 50 |
粘度 | 固体含量 | NCO含量 | 颜色指数(APHA) | |
实施例22 | 650mPas | 70.3% | 5.5% | 31 |
粘度 | 固体含量 | NCO含量 | 颜色指数(APHA) | |
实施例23 | 1300mPas | 79.5% | 0.1%(4.0%未封闭的) | 121 |
粘度 | 固体含量 | 酸值 | NCO含量 | 颜色指数(APHA) | |
实施例24 | 18600mPas | 79.6% | 10.4 | 0.1%(6.0%封闭的) | 75 |
粘度 | 固体含量 | NCO含量 | |
实施例25 | 5700mPas | 80.1% | 7.1% |
变量 | V26 | 实施例27 |
部分溶解度X/MPA/EA/AC 1分钟/5分钟 | 0011/1122 | 0000/0012 |
部分溶解度(没有UV固化) | 3344/- | 3344/- |
摆锤冲击硬度(没有UV固化) | 100 | 132 |
抗划伤性(使用56小时刷划操作) | ||
刮伤前光泽度20° | 90.1 | 89.9 |
刮伤后光泽度20° | 42.2 | 46.2 |
残余光泽度,% | 46.8% | 51.4% |
60℃回流2h后的光泽度20° | 65.2 | 61.9 |
残余光泽度,% | 72.4% | 68.9% |
Daimler-Chrysler温度梯度炉热试验*) | ||
树树脂 | 62 | >68 |
制动液 | 36 | 36 |
胰酶 | 36 | 36 |
NaOH,1% | 36 | 40 |
H2SO4,1% | 45 | 48 |
Claims (20)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2003157712 DE10357712A1 (de) | 2003-12-09 | 2003-12-09 | Härter |
DE10357712.2 | 2003-12-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1637037A true CN1637037A (zh) | 2005-07-13 |
CN1637037B CN1637037B (zh) | 2010-06-16 |
Family
ID=34485293
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200410100379XA Active CN1637037B (zh) | 2003-12-09 | 2004-12-09 | 硬化剂 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7641975B2 (zh) |
EP (1) | EP1541609B1 (zh) |
JP (1) | JP5162077B2 (zh) |
KR (1) | KR101106421B1 (zh) |
CN (1) | CN1637037B (zh) |
AT (1) | ATE459672T1 (zh) |
CA (1) | CA2489261C (zh) |
DE (2) | DE10357712A1 (zh) |
ES (1) | ES2340034T3 (zh) |
HK (1) | HK1080499A1 (zh) |
PL (1) | PL1541609T3 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102471225A (zh) * | 2009-07-18 | 2012-05-23 | 拜尔技术服务有限责任公司 | 制备(甲基)丙烯酸羟烷基酯的方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004057916A1 (de) * | 2004-11-30 | 2006-06-01 | Bayer Materialscience Ag | Neue Dual Cure-Systeme |
DE102004060966A1 (de) * | 2004-12-17 | 2006-06-29 | Basf Coatings Ag | Strukturviskose härtbare Gemische, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE102005011231A1 (de) | 2005-03-11 | 2006-09-14 | Bayer Materialscience Ag | Spezielle Allophanate enthaltende, modifizierte Polyurethane |
US20070066698A1 (en) * | 2005-09-20 | 2007-03-22 | Yang Wenliang P | Dual cure compositions, methods of curing thereof and articles therefrom |
DE102005057925A1 (de) * | 2005-12-05 | 2007-06-06 | Basf Coatings Ag | Radikalisch polymerisierbare Gemische, Verfahren zu ihrer Herstellung und ihre Verwendung |
SI2218740T1 (sl) * | 2009-02-13 | 2014-03-31 | Bayer Materialscience Llc | ÄŚistilni poliuretanski premazi na vodni osnovi |
US20120138223A1 (en) | 2011-09-29 | 2012-06-07 | General Electric Company | Uv-ir combination curing system and method of use for wind blade manufacture and repair |
WO2013125288A1 (ja) * | 2012-02-25 | 2013-08-29 | 三菱樹脂株式会社 | 塗布フィルム |
DE102012015729A1 (de) * | 2012-08-09 | 2014-05-15 | Delo Industrie Klebstoffe Gmbh & Co. Kgaa | Dualhärtende lösungsmittelfreie Einkomponenten-Massen und ihre Verwendung |
RU2655364C2 (ru) | 2014-01-14 | 2018-05-25 | Кроноплюс Техникаль АГ | Многослойная строительная панель для внутренних и наружных работ |
EP4001332A1 (en) * | 2020-11-18 | 2022-05-25 | Covestro Deutschland AG | A modified polyisocyanate |
WO2022069561A1 (en) * | 2020-09-30 | 2022-04-07 | Covestro Deutschland Ag | A modified polyisocyanate |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4841706B1 (zh) * | 1970-05-29 | 1973-12-07 | ||
US3660145A (en) * | 1970-12-21 | 1972-05-02 | Ford Motor Co | Epoxy resin and acrylic rubber-urethane-acrylate paint and painting process |
US3719521A (en) * | 1970-12-21 | 1973-03-06 | Ford Motor Co | Polyester and graded acrylic rubber-urethane-acrylate paint and painting process |
DE3130545C2 (de) * | 1981-08-01 | 1986-05-07 | Basf Farben + Fasern Ag, 2000 Hamburg | Selbstvernetzendes Kunstharz |
JPS5989331A (ja) * | 1982-11-12 | 1984-05-23 | Mitsui Petrochem Ind Ltd | 被覆用硬化型樹脂組成物 |
DE3316592A1 (de) | 1983-05-06 | 1984-11-08 | Basf Ag, 6700 Ludwigshafen | Verwendung zur herstellung von (meth) acrylsaeureestern und deren verwendung |
JPS62184010A (ja) * | 1986-02-10 | 1987-08-12 | Showa Highpolymer Co Ltd | 硬化可能な樹脂の製造方法 |
DE3703130A1 (de) * | 1986-07-25 | 1988-01-28 | Bayer Ag | Urethangruppen enthaltende (meth)-acrylsaeurederivate |
DE3917320A1 (de) * | 1989-05-27 | 1990-12-20 | Bayer Ag | Harnstoffgruppen enthaltende (meth)-acrylsaeure-derivate von triisocyanaten und ihre verwendung |
DE4040290C2 (de) | 1990-12-17 | 1996-05-15 | Synthopol Chemie Dr Koch | Verfahren zur Herstellung von strahlungshärtbaren Polyesteracrylat-Bindemitteln |
US5234970A (en) * | 1991-07-16 | 1993-08-10 | W. R. Grace & Co.-Conn. | Dual curing composition based on isocyanate trimer and use thereof |
EP0755420B1 (en) * | 1994-04-13 | 1999-10-20 | PPG Industries Ohio, Inc. | Thermosetting powder coating compositions |
US5739251A (en) * | 1997-03-27 | 1998-04-14 | Bayer Corporation | Low viscosity, ethylenically unsaturated polyurethanes containing allophanate groups |
DE19737017A1 (de) * | 1997-08-26 | 1999-03-04 | Bayer Ag | Verfahren zur Herstellung von Estern ethylenisch ungesättigter Carbonsäuren und deren Verwendung |
DE19800528A1 (de) | 1998-01-09 | 1999-07-15 | Bayer Ag | Beschichtungssystem aus UV-härtenden Isocyanatgruppen aufweisenden Urethan(meth)acrylatisocyanaten |
DE19860041A1 (de) * | 1998-12-23 | 2000-06-29 | Basf Ag | Durch Addition an Isocyanatgruppen als auch durch strahlungsinduzierte Addition an aktivierte C-C-Doppelbindungen härtbare Beschichtungsmittel |
DE19919826A1 (de) * | 1999-04-30 | 2000-11-02 | Basf Ag | Verfahren zur Herstellung von Polyurethanschaumstoffen |
DE19944156A1 (de) * | 1999-09-15 | 2001-03-22 | Bayer Ag | Elastisches Beschichtungssystem enthaltend UV-härtbare, Isocyanatgruppen aufweisende Urethan(meth)acrylate und seine Verwendung |
JP2001089200A (ja) * | 1999-09-22 | 2001-04-03 | Shin Etsu Chem Co Ltd | 放射線硬化型光ファイバ用被覆材及びその硬化方法 |
DE19956231A1 (de) * | 1999-11-23 | 2001-05-31 | Bayer Ag | Strahlungshärtbare Isocyanatgruppen enthaltende Urethanacrylate und ihre Verwendung |
DE10016194A1 (de) * | 2000-03-31 | 2001-10-04 | Bayer Ag | Beschichtungssystem enthaltend UV-härtbare, Isocyanatgruppen aufweisende Urethan(meth)acrylate und Hydroxylgruppen aufweisende Urethan(meth)acrylate |
US6632880B2 (en) * | 2001-07-09 | 2003-10-14 | E. I. Du Pont De Nemours And Company | Coating compositions containing isocyanate-functional non-aqueous dispersed polymers |
US7144955B2 (en) * | 2003-10-27 | 2006-12-05 | Bayer Materialscience Llc | Acrylate-functional blocked polyisocyanate resin for UV/thermally curable coatings |
-
2003
- 2003-12-09 DE DE2003157712 patent/DE10357712A1/de not_active Withdrawn
-
2004
- 2004-11-26 AT AT04028096T patent/ATE459672T1/de active
- 2004-11-26 ES ES04028096T patent/ES2340034T3/es active Active
- 2004-11-26 EP EP20040028096 patent/EP1541609B1/de active Active
- 2004-11-26 PL PL04028096T patent/PL1541609T3/pl unknown
- 2004-11-26 DE DE200450010843 patent/DE502004010843D1/de active Active
- 2004-12-03 US US11/003,651 patent/US7641975B2/en active Active
- 2004-12-06 CA CA2489261A patent/CA2489261C/en not_active Expired - Fee Related
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102471225A (zh) * | 2009-07-18 | 2012-05-23 | 拜尔技术服务有限责任公司 | 制备(甲基)丙烯酸羟烷基酯的方法 |
Also Published As
Publication number | Publication date |
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CA2489261C (en) | 2012-07-24 |
EP1541609A3 (de) | 2006-03-08 |
KR20050056150A (ko) | 2005-06-14 |
CN1637037B (zh) | 2010-06-16 |
JP2005213495A (ja) | 2005-08-11 |
PL1541609T3 (pl) | 2010-08-31 |
EP1541609A2 (de) | 2005-06-15 |
DE502004010843D1 (de) | 2010-04-15 |
HK1080499A1 (en) | 2006-04-28 |
ES2340034T3 (es) | 2010-05-28 |
JP5162077B2 (ja) | 2013-03-13 |
EP1541609B1 (de) | 2010-03-03 |
KR101106421B1 (ko) | 2012-01-18 |
CA2489261A1 (en) | 2005-06-09 |
US7641975B2 (en) | 2010-01-05 |
DE10357712A1 (de) | 2005-07-14 |
ATE459672T1 (de) | 2010-03-15 |
US20050123768A1 (en) | 2005-06-09 |
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