CN1605648A - Low expansion superhigh silicon aluminum alloy and method for making same - Google Patents
Low expansion superhigh silicon aluminum alloy and method for making same Download PDFInfo
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- CN1605648A CN1605648A CN 200410043855 CN200410043855A CN1605648A CN 1605648 A CN1605648 A CN 1605648A CN 200410043855 CN200410043855 CN 200410043855 CN 200410043855 A CN200410043855 A CN 200410043855A CN 1605648 A CN1605648 A CN 1605648A
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Abstract
The low expansion Si-Al alloy has very high Si mass ratio of 61.6-70.8 %. The preparation process includes loading Si into mold cavity and pressing with punch head to form pre-fabricated block; preheating the mold to 500-600 deg.c and heating aluminum material to melt; casting aluminum into the mold; pressing with punch head; maintaining the pressure of the punch head while cooling the mold; demolding; and high temperature annealing of the cast ingot. The Si-Al alloy has high Si content, low density, high compactness, low expansion and other performance. The extrusion casting process to add Si element into Al alloy to form Si-Al alloy with very high Si content uses simple preparing apparatus and has low cost.
Description
Technical field:
The present invention relates to a kind of ultra high silicon alloy product and preparation method thereof.
Background technology:
The ultra high silicon aluminium alloy is a kind of novel aluminum alloy that foreign latest grows up, and advantageous property is widely used in motor car engine piston rod, Electronic Packaging, computer hard disk substrate, the demanding part of dimensional stability owing to its lightweight, low bulk, high heat conduction, wear resistance be good etc.According to the aluminum silicon alloy phasor, aluminum silicon alloy can be divided into hypoeutectic al-si alloy, cocrystallized Al-Si alloy and transcocrystallized Al-Si alloy, and along with the increase of Si constituent content in the alloy, the density of aluminium alloy reduces gradually, and linear expansivity reduces gradually.In recent years, external increasing to the research of ultra high silicon aluminium alloy, wherein active with the U.S., Germany, Japan, Taiwan research, the German Mercedes Benz employing transcocrystallized Al-Si alloy manufacturing V-6 of company cylinder sleeve of engine has been obtained good effect to replace existing Cast iron liner.With eutectic Al-Si alloy phase ratio, the hypereutectic Al-Si alloy has hot strength height, hardness height, advantage such as wear-resisting, is particularly suitable for wear-resisting, resistant to elevated temperatures foundry goods.Therefore, silumin and ultra high silicon aluminium alloy are the development trends of following aluminum silicon alloy.The preparation method of ultra high silicon aluminium alloy mainly contains one, powder metallurgic method: this method complex process, density is low and add silicone content low (being lower than 50%), SUMITOMO CHEMICAL electrical equipment company has produced 40Si60Al (massfraction) material C MSHA-40 with traditional powder metallurgy process, but its integrated performance index is still not very good.Two, spray deposition: the U.S. adopts methods such as jet deposition and liquid metal infiltration recently, the Osprey metal company of Britain adopts the method for jet deposition+hot isostatic pressing all to prepare the silumin of high comprehensive performance, it is higher that yet these methods all exist equipment requirements, the shortcoming of manufacturing cost costliness and its application is greatly limited.
Summary of the invention:
The purpose of this invention is to provide the ultra high silicon aluminium alloy that a kind of silicon content is higher than existing aluminum silicon alloy, to obtain the more excellent aluminum silicon alloy of each side use properties, the present invention provides also that processing units is simple, the manufacture method of the ultra high silicon aluminium alloy of low cost of manufacture, to overcome the shortcoming of existing manufacture method and manufacturing cost costliness high to equipment requirements.Technical scheme of the present invention is as follows: a kind of low bulk ultra high silicon aluminium alloy, silicon shared mass percent in whole alloy is 61.6%-70.8%.
A kind of preparation method of low bulk ultra high silicon aluminium alloy: one, silica flour 3 is packed within the die cavity 2 of mold 4, the silica flour radius is 10 μ m～20 μ m, and drift 1 is pressed into prefabricated section to silica flour 3 downwards; Two, mold 4 is preheated to 500 ℃～600 ℃, aluminum is heated to fusing; Three, aluminum is poured in the mold 4; Four, exert pressure downwards by drift 1, metal liquid aluminium is infiltrated up among the gap between silica flour 3 particles; Five, drift 1 holds down pressure and makes mold 4 coolings; Six, the demoulding, the ingot casting of taking-up aluminum silicon alloy; Seven, ingot casting is through The high temperature anneal.Ultra high silicon aluminium alloy of the present invention has silicon content height (61.6%～70.8% mass percent), low density (2.4～2.45g/cm
3), performances such as high fine and close (＞98.5%), low bulk, low cost.The present invention adopts extrusion casting method, and pressure is applied to element silicon and makes the ultra high silicon aluminium alloy in the aluminium alloy.This method has that producing apparatus is simple, cost is lower, material density is high and characteristics such as good uniformity.It has solved, and conventional aluminum alloy silicone content is low, thermal expansivity is big and existing ultra high silicon aluminium alloy preparation method complexity, problems such as production cost height can be widely used in the fields such as motor car engine piston rod, Electronic Packaging, high-dimensional stability instrument part.
Description of drawings:
Fig. 1 is the metallograph of ultra high silicon aluminium alloy of the present invention, and Fig. 2 is the structural representation of preparation method's mould therefor in the embodiment one.
Embodiment:
Embodiment one: specify present embodiment below in conjunction with Fig. 1.The used device (consulting Fig. 2) of this aluminium alloy preparation method is made up of drift 1, mold 4, pressing machine table top 5 and electric furnace 6.A kind of low bulk ultra high silicon aluminium alloy, silicon shared mass percent in whole alloy is 61.6%-70.8%.A kind of preparation method of low bulk ultra high silicon aluminium alloy: one, silica flour 3 is packed within the die cavity 2 of mold 4, drift 1 is pressed into prefabricated section to silica flour 3 downwards; Two, mold 4 is preheated to 500 ℃～600 ℃, aluminum is heated to 700 ℃-800 ℃; Three, aluminum is poured in the mold 4; Four, exert pressure downwards by drift 1, metal liquid aluminium is infiltrated up among the gap between silica flour 3 particles; Applied pressure is 40MPa～60MPa; Five, drift 1 holds down pressure and makes mold 4 internal cooling; Six, the demoulding, the ingot casting of taking-up aluminum silicon alloy; Seven, ingot casting is through 345 ℃ of-410 ℃ of The high temperature anneal.Used silica flour mean radius is 10 μ m～20 μ m.
Embodiment two: the difference of present embodiment and embodiment one is, its preparation process is: one, silica flour filling: with median size is the silica flour of 10 mu m ranges mold 4 die cavities of packing into, 515g packs into, proportion according to silicon, silica flour is pressed into the prefabricated section that is equivalent to silicon proportion 65%, the porose or slit of gathering in the prefabricated section.Precalculated volume rate this moment (the silicon volume accounts for the volume ratio of whole alloy) is 65%; Two, preheating.The mold 4 that silica flour is housed is heated to 600 ℃ in electric furnace 6, alloy adopts the LD11 aluminium alloy, and the LD11 aluminium alloy is heated to 700 ℃ in another electric furnace; Three, the LD11 aluminium alloy is poured within the mold 4; Four, pressurization: exert pressure downwards by drift 1, this moment, pressure was 40MPa; Five, pressurize cooling: aluminium alloy liquid keep-ups pressure after infiltrating fully; Six, the naturally cooling demoulding, the ingot casting material of taking-up aluminum silicon alloy; Seven, ingot casting was through 410 ℃, 3 hours anneal.The performance test results: silicone content is 66.2% (weight percent), and density is 2.42g/cm
3, density is 98.77%, thermal expansivity is 7.9 * 10
-6/ ℃, thermal conductivity is 100W/ (mK), and flexural strength is 340MPa, and Young's modulus is 114GPa, HB=310.
Embodiment three: the difference of present embodiment and embodiment one is, the preparation process of this ultra high silicon aluminium alloy is: one, silica flour filling: with median size be the silica flour of 10 μ m and silica flour that median size is 20 μ m each 50% mix, pack in the mold 4,515g packs into, compacting, this moment, the precalculated volume rate was 65%; Two, preheating.The mold 4 that silica flour is housed is heated to 600 ℃ in electric furnace 6, the LD11 aluminium alloy is heated to 750 ℃ in another electric furnace; Three, the LD11 aluminium alloy is poured in the mold 4; Four, exert pressure downwards by drift 1, this moment, pressure was 60MPa; Five, after metal liquid infiltrates fully, keep-up pressure; Naturally cool to about 300 ℃; Six, the demoulding, the ingot casting material of taking-up aluminum silicon alloy; Seven, the ingot casting of aluminum silicon alloy was through 410 ℃, 3 hours anneal.The performance test results: silicone content is 66.2% (mass percent), and density is 2.41g/cm
3, density is 98.93%, thermal expansivity is 8.1 * 10
-6/ ℃, thermal conductivity is 103W/ (mK), and flexural strength is 270MPa, and Young's modulus is 104GPa, HB=275.
Embodiment four: the difference of present embodiment and embodiment one is, the preparation process of ultra high silicon aluminium alloy is: one, silica flour filling: with median size is that the silica flour of 20 μ m is packed in the mold 4, the 515g that packs into, compacting, this moment, the precalculated volume rate was 65%; Two, the mold 4 that silica flour will be housed is heated to 600 ℃ in electric furnace 6, and LD11 aluminium alloy alloy is heated to 750 ℃ in another electric furnace, fusing; Three, the LD11 aluminium alloy is poured in the mold 4; Four, exert pressure downwards by drift 1, this moment, pressure was 50MPa; Five, the 50MPa that keep-ups pressure is constant, unloading when temperature is reduced to 400 ℃; Six, the demoulding, the ingot casting material of taking-up aluminum silicon alloy; Seven, the ingot casting of aluminum silicon alloy was through 410 ℃, 3 hours anneal.The performance test results: Si content is 66.2% (mass percent), and density is 2.42g/cm
3, density is 98.51%, and thermal expansivity is 8.3 * 10-6/ ℃, and thermal conductivity is 105W/ (mK), and flexural strength is 220MPa, Young's modulus is 100GPa, HB=270.
Embodiment five: the difference of present embodiment and embodiment one is, the preparation process of high purity aluminum alloy is: one, silica flour filling: with median size is that the silica flour of 10 μ m is packed in the mold 4, the 515g that packs into, compacting, this moment, the precalculated volume rate was 65%.Two, preheating.The mold 4 that silica flour is housed is heated to 500 ℃ in electric furnace 6, aluminium alloy adopts the LG5 fine aluminium, is heated to 750 ℃ of fusings in another electric furnace; Three, the LG5 fine aluminium is poured in the mold 4; Four, pressurization: exert pressure downwards by drift 1, this moment, pressure was 40MPa; Five, pressurize cooling: the 40MPa that keep-ups pressure is constant, unloading when temperature is reduced to about 300 ℃; Six, the demoulding, the ingot casting material of taking-up aluminum silicon alloy; Seven, the ingot casting of aluminum silicon alloy was through 410 ℃, 3 hours anneal.The performance test results: silicone content is 61.6% (mass percent), and density is 2.40g/cm
3, density is 98.89%, thermal expansivity is 7.5 * 10
-6/ ℃, thermal conductivity is 110W/ (mK), and flexural strength is 275MPa, and Young's modulus is 112GPa, HB=270.
Embodiment six: the difference of present embodiment and embodiment one is that the preparation process of high purity aluminum alloy is: one, silica flour filling: with median size is the silica flour of the 10 μ m mold 4 of packing into, the 555g that packs into, and compacting, this moment, the precalculated volume rate was 70%.Two, preheating.The mold 4 that silica flour is housed is heated to 600 ℃ in electric furnace 6, aluminium alloy adopts LD11, is heated to 750 ℃ of fusings in another electric furnace; Three, the LD11 aluminium alloy is poured in the mold 4; Four, pressurization: exert pressure downwards by drift 1, this moment, pressure was 40MPa; Five, pressurize cooling: the 40MPa that keep-ups pressure is constant, unloading when temperature is reduced to about 300 ℃; Six, the demoulding, the ingot casting material of taking-up aluminum silicon alloy; Seven, the ingot casting of aluminum silicon alloy was through 410 ℃, 3 hours anneal.The performance test results: silicone content is 70.8% (mass percent), and density is 2.40g/cm
3, density is 99.42%, thermal expansivity is 7.4 * 10
-6/ ℃, thermal conductivity is 110W/ (mK), and flexural strength is 338MPa, and Young's modulus is 110Gpa, HB=282.
Claims (7)
1, a kind of low bulk ultra high silicon aluminium alloy is characterized in that silicon shared mass percent in whole alloy is 61.6%-70.8%.
2, a kind of preparation method of low bulk ultra high silicon aluminium alloy is characterized in that one, silica flour (3) is packed within the die cavity (2) of mold (4), and the silica flour radius is 10 μ m～20 μ m, and drift (1) is pressed into prefabricated section to silica flour (3) downwards; Two, mold (4) is preheated to 500 ℃～600 ℃, aluminum is heated to fusing; Three, aluminum is poured in the mold (4); Four, exert pressure downwards by drift (1), metal liquid aluminium is infiltrated up among the gap between silica flour (3) particle; Five, drift (1) holds down pressure and makes mold (4) cooling; Six, the demoulding, the ingot casting of taking-up aluminum silicon alloy; Seven, ingot casting is through The high temperature anneal.
3, a kind of low bulk ultra high silicon aluminium alloy according to claim 2 and preparation method thereof is characterized in that in step 4, and drift (1) applied pressure downwards is 40MPa～60MPa.
4, a kind of low bulk ultra high silicon aluminium alloy according to claim 2 and preparation method thereof is characterized in that in step 7, and the temperature of high temperature annealing is 345 ℃～410 ℃.
5, a kind of low bulk ultra high silicon aluminium alloy according to claim 2 and preparation method thereof is characterized in that in step 1, silica flour particle diameter 10 μ m.
6, a kind of low bulk ultra high silicon aluminium alloy according to claim 2 and preparation method thereof is characterized in that in step 1, silica flour particle diameter 20 μ m.
7, a kind of low bulk ultra high silicon aluminium alloy according to claim 2 and preparation method thereof is characterized in that in step 2,750 ℃ of the Heating temperatures of aluminum.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101590591B (en) * | 2008-05-30 | 2011-08-03 | 杰出材料科技股份有限公司 | Manufacturing method of aluminium alloy section with easy weld and high strength |
| CN105970013A (en) * | 2016-05-04 | 2016-09-28 | 上海大学 | High-throughput preparation device and method for high-silicon aluminum alloy structural gradient material used for packaging |
| CN106735106A (en) * | 2017-03-24 | 2017-05-31 | 无锡飞而康精铸工程有限公司 | It is a kind of to realize the device that hardware moves minute-pressure type casting moulding |
| CN109487130A (en) * | 2018-12-26 | 2019-03-19 | 东莞理工学院 | A kind of Al-Si composites and preparation method thereof for Electronic Packaging |
| WO2021169073A1 (en) * | 2020-02-28 | 2021-09-02 | 深圳市新星轻合金材料股份有限公司 | Silicon-aluminum alloy and preparation method therefor |
| CN114289702A (en) * | 2021-12-31 | 2022-04-08 | 江苏大学 | Preparation device and preparation method of bimetal composite material |
| CN114505466A (en) * | 2022-01-20 | 2022-05-17 | 清华大学 | Electronic packaging material and preparation method and preparation device thereof |
-
2004
- 2004-09-08 CN CN 200410043855 patent/CN1279197C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101590591B (en) * | 2008-05-30 | 2011-08-03 | 杰出材料科技股份有限公司 | Manufacturing method of aluminium alloy section with easy weld and high strength |
| CN105970013A (en) * | 2016-05-04 | 2016-09-28 | 上海大学 | High-throughput preparation device and method for high-silicon aluminum alloy structural gradient material used for packaging |
| CN106735106A (en) * | 2017-03-24 | 2017-05-31 | 无锡飞而康精铸工程有限公司 | It is a kind of to realize the device that hardware moves minute-pressure type casting moulding |
| CN109487130A (en) * | 2018-12-26 | 2019-03-19 | 东莞理工学院 | A kind of Al-Si composites and preparation method thereof for Electronic Packaging |
| WO2021169073A1 (en) * | 2020-02-28 | 2021-09-02 | 深圳市新星轻合金材料股份有限公司 | Silicon-aluminum alloy and preparation method therefor |
| CN114289702A (en) * | 2021-12-31 | 2022-04-08 | 江苏大学 | Preparation device and preparation method of bimetal composite material |
| CN114505466A (en) * | 2022-01-20 | 2022-05-17 | 清华大学 | Electronic packaging material and preparation method and preparation device thereof |
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| CN1279197C (en) | 2006-10-11 |
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