CN1605275A - Deep processing method of seabuckthorn fruit mud - Google Patents
Deep processing method of seabuckthorn fruit mud Download PDFInfo
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- CN1605275A CN1605275A CNA2004100645582A CN200410064558A CN1605275A CN 1605275 A CN1605275 A CN 1605275A CN A2004100645582 A CNA2004100645582 A CN A2004100645582A CN 200410064558 A CN200410064558 A CN 200410064558A CN 1605275 A CN1605275 A CN 1605275A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The deeply processing of mashed sea-buckthorn fruit includes supercritical CO2 extraction of mashed sea-buckthorn fruit to obtain sea-buckthorn fruit oil and defatted sea-buckthorn fruit paste; water extraction of defatted sea-buckthorn fruit paste; filtering and drying filtrate to obtain sea-buckthorn fruit tea with rich organic acid, vitamin C, sea-buckthorn polysaccharide, pectin, etc.; and alcohol extraction of the filter residue to obtain sea-buckthorn flavone in 40-50 % content and residue. The sea-buckthorn flavone is used as health food and medicine material, and the residue is used as feed additive. The present invention has simple process, and the products sea-buckthorn fruit oil, sea-buckthorn fruit tea, sea-buckthorn flavone and feed additive are marketable.
Description
Technical field
The invention belongs to a kind of seabuckthorn fruit mud deep-processing method.
Background technology
Seabuckthorn fruit mud is to be the product that raw material obtains by sedimentation, fermentation with the sea buckthorn juice, be rich in vitamin C, Hippophate flavone, organic acid, Fructus Hippophae polysaccharide, pectin, fruit wet goods composition, be mainly used in the extraction Hippophate flavone at present, and underuse for wherein hippophae rhamnoides fruit oil, Fructus Hippophae polysaccharide, vitamin C and organic acid etc.
Hippophate flavone has the important physical activity, have resist myocardial ischemia, reducing blood lipid, antitumor, regulate effect such as immune system, can remove the free radical in the body, prevent and treat angiocardiopathy, the effect that also has direct removing free radical, its scavenging action is also stronger than vitamin E, and anti-aging effects is obvious.Isorhamnetin content is the highest in the Hippophate flavone, and Quercetin, Kaempferol take second place.Usually Isorhamnetin content is about 0.6%.At present, the extraction of Hippophate flavone is carried out purifying to the flavones crude extract and is mainly contained solvent degreasing and macroreticular resin absorbing method based on solvent extraction method.Patent of invention " method for preparing flavones (glycosides) with resin adsorption method from the sea-buckthorn leaf " (97108475.0) provides a kind of method with macroreticular resin absorbing method purifying leaf of Fructus Hippophae flavone, resin preliminary treatment, regenerative process are complicated, other active ingredients in the seabuckthorn fruit mud are not fully used simultaneously, and flavones content neither be very high in the product.
Summary of the invention
The deep-processing method that the purpose of this invention is to provide a kind of flavones content height, the active ingredient in the seabuckthorn fruit mud all is fully used.
Researching and analysing the composition that shows Seabuckthorm Seed Oil and fruit oil differs widely, difference such as its aliphatic acid composition, vitamin E and carotene carotene content is bigger, hippophae rhamnoides fruit oil 16 carbon fatty acid content are near 50%, and seed oil is about 10%, and the Seabuckthorm Seed Oil linolenic acid content is 3 times of seed oil.Concrete aliphatic acid composition sees Table 1.
Table 1 Seabuckthorm Seed Oil, fruit fatty acid oil composition analysis
| The C16:0 palmitic acid | The C16:1 palmitoleic acid | The C18:0 stearic acid | C18:1 oleic acid | The C18:2 linoleic acid | The C18:3 alpha-linolenic acid | |
| Seabuckthorm Seed Oil | ??9.6 | ??1.9 | ??2.2 | 20.9 | ??36.9 | ??28.1 |
| Hippophae rhamnoides fruit oil | ??24.7 | ??21.5 | ??1.8 | 24.7 | ??16.0 | ??9.7 |
Fruit Oleovitamin E content be 2～3 times of seed oil (Guo Junwang etc., the difference of sea buckthorn juice oil, Fructus Hippophae dreg oil and hippophae rhamnoides seed oil, sea-buckthorn, 1994,7 (4): 24～27), carotene carotene content also is higher than seed oil.Simultaneously, also contain a large amount of water-soluble components in the seabuckthorn fruit mud, comprise vitamin C, organic acid, Fructus Hippophae polysaccharide, pectin, organic acid comprises malic acid, citric acid, tartaric acid, oxalic acid and butanedioic acid etc. in the sea buckthorn fruit, Fructus Hippophae polysaccharide mainly is made up of arabinose, fucose, wood sugar, galactolipin, mannose, glucose and galacturonic acid, anti-oxidant experiment shows that Fructus Hippophae polysaccharide has antioxidation activity, and antioxidation strengthens with concentration.
The present invention is that raw material removes oil-soluble impurities in the seabuckthorn fruit mud by supercritical extract with the seabuckthorn fruit mud, obtain hippophae rhamnoides fruit oil, hippophae rhamnoides fruit oil, hippophae rhamnoide nectar, Hippophate flavone, feed addictive, its hippophae rhamnoides fruit oil product quality height, no solvent residue, can simplify the purge process of Hippophate flavone, obtain content and reach 40～50% flavones product.
Concrete operations step of the present invention is as follows:
(1) seabuckthorn fruit mud is packed into extractor is used supercritical CO
2Extraction, control extracting pressure 12～40MPa, 31～60 ℃ of extraction temperature, separating pressure 5～12Mpa, 20～80 ℃ of separation temperatures obtain hippophae rhamnoides fruit oil and degreasing puree;
(2) the degreasing puree is mixed with 1: 10～20 part by weight with water, 30～60 ℃ of hot-water soaks 1～4 hour, filter filter residue, filtrate decompression distillation, drying obtain the water-soluble products hippophae rhamnoide nectar;
(3) filter residue that step (2) is obtained mixes with 1: 6～10 weight ratios with 60～80v% ethanol, soak, refluxed 1～5 hour, filter filter residue, the solids that obtains is with water washing, drying obtains the flavones crude product, the flavones crude product is used acetic acid ethyl dissolution again, filter, decompression distillation concentrates filtrate, and crystallization obtains faint yellow Hippophate flavone product;
(4) filter residue and drying that (3) step is obtained is as feed addictive.
The invention provides a kind of method that fully utilizes seabuckthorn fruit mud, can obtain hippophae rhamnoides fruit oil, hippophae rhamnoide nectar, Hippophate flavone and feed product, wherein the content of Hippophate flavone reaches 40～50% in the Hippophate flavone product.
Advantage of the present invention:
This method mainly contains following characteristics: to extract Hippophate flavone, other nutritional labeling is not fully utilized traditional technology mostly.Water-soluble in the Hippophate flavone leaching process, oil-soluble impurities itself is also influential to the quality of its final products Hippophate flavone, should remove, the present invention removes oil-soluble impurities by supercritical fluid extraction, can obtain hippophae rhamnoides fruit oil, carry by water and remove the product that obtains being rich in Fructus Hippophae polysaccharide in the water-solubility impurity process.
Product hippophae rhamnoides fruit oil, hippophae rhamnoide nectar, Hippophate flavone and the feed addictive of gained of the present invention all can directly be put on market, and economic benefit is obvious.
The specific embodiment
Embodiment 1:
(1) getting the 100g seabuckthorn fruit mud puts into extractor and carries out supercritical CO
2Extraction, extracting pressure 16MPa, 32 ℃ of extraction temperature, separating pressure 6MPa, 25 ℃ of separation temperatures obtain 16g hippophae rhamnoides fruit oil and 80g degreasing puree;
(2) with the degreasing puree with hot water (30 ℃) lixiviate of 10 times of weight 1 hour, filter, the filtrate drying obtains the 7g water-soluble products;
(3) the puree bits after the flooding are with the 65v% alcohol reflux of 6 times of weight, filter, reclaim ethanol, the solids that obtains is with water washing, and drying obtains the flavones crude product, and the flavones crude product is used acetic acid ethyl dissolution again, filter, decompression distillation concentrates filtrate, and crystallization obtains faint yellow flavones product, flavones content 42%;
(4) be used as feed after the residue drying that step (3) obtains.
Embodiment 2:
(1) getting the 100g seabuckthorn fruit mud puts into extractor and carries out supercritical CO
2Extraction, extracting pressure 18MPa, 38 ℃ of extraction temperature, separating pressure 7MPa, 68 ℃ of separation temperatures obtain 18g hippophae rhamnoides fruit oil and 75g degreasing puree;
(2) with the degreasing puree with hot water (32 ℃) lixiviate of 12 times of weight 1.5 hours, filter, the filtrate drying obtains the 7.5g water-soluble products;
(3) the puree bits after the flooding are with the 70v% ethanol of 8 times of weight, filter, reclaim ethanol, the solids that obtains is with water washing, and drying obtains the flavones crude product, the flavones crude product is used acetic acid ethyl dissolution again, filter, decompression distillation concentrates filtrate, crystallization obtains faint yellow flavones product, flavones content 41%;
(4) be used as feed after the residue drying that step (3) obtains.
Embodiment 3:
(1) getting the 100g seabuckthorn fruit mud puts into extractor and carries out supercritical CO
2Extraction, extracting pressure 25MPa, 45 ℃ of extraction temperature, separating pressure 9MPa, 60 ℃ of separation temperatures obtain 19g hippophae rhamnoides fruit oil and 73g degreasing puree;
(2) with the degreasing puree with hot water (40 ℃) lixiviate of 14 times of weight 1 hour, filter, the filtrate drying obtains the 7.8g water-soluble products;
(3) the puree bits after the flooding are with 75% ethanol of 10 times of weight, filter, reclaim ethanol, the solids that obtains is with water washing, and drying obtains the flavones crude product, and the flavones crude product is used acetic acid ethyl dissolution again, filter, decompression distillation concentrates filtrate, and crystallization obtains faint yellow flavones product, flavones content 43%;
(4) be used as feed after the residue drying that step (3) obtains.
Embodiment 4
(1) getting the 100g seabuckthorn fruit mud puts into extractor and carries out supercritical CO
2Extraction, extracting pressure 30MPa, 50 ℃ of extraction temperature, separating pressure 10MPa, 45 ℃ of separation temperatures obtain 21g hippophae rhamnoides fruit oil and 70g degreasing puree;
(2) with the degreasing puree with hot water (50 ℃) lixiviate of 16 times of weight 2 hours, filter, the filtrate drying obtains the 9.2g water-soluble products;
(3) the puree bits after the flooding are with the 70v% ethanol of 6 times of weight, filter, reclaim ethanol, the solids that obtains is with water washing, and drying obtains the flavones crude product, and the flavones crude product is used acetic acid ethyl dissolution again, filter, decompression concentrates filtrate, and crystallization obtains faint yellow flavones product, flavones content 48%;
(4) be used as feed after the residue drying that step (3) obtains.
Embodiment 5
(1) getting the 100g seabuckthorn fruit mud puts into extractor and carries out supercritical CO
2Extraction, extracting pressure 36MPa, 55 ℃ of extraction temperature, separating pressure 11MPa, 55 ℃ of separation temperatures obtain 20g hippophae rhamnoides fruit oil and 74g degreasing puree;
(2) with the degreasing puree with hot water (55 ℃) lixiviate of 18 times of weight 3 hours, filter, the filtrate drying obtains the 9g water-soluble products;
(3) the puree bits after the flooding are with the 70v% ethanol of 6 times of weight, filter, reclaim ethanol, the solids that obtains is with water washing, and drying obtains the flavones crude product, and the flavones crude product is used acetic acid ethyl dissolution again, filter, decompression concentrates filtrate, and crystallization obtains faint yellow flavones product, flavones content 41%;
(4) be used as feed after the residue drying that step (3) obtains.
Embodiment 6
(1) getting the 100g seabuckthorn fruit mud puts into extractor and carries out supercritical CO
2Extraction, extracting pressure 38MPa, 58 ℃ of extraction temperature, separating pressure 10MPa, 45 ℃ of separation temperatures obtain 19.5g hippophae rhamnoides fruit oil and 75g degreasing puree;
(2) with the degreasing puree with hot water (45 ℃) lixiviate of 15 times of weight 4 hours, filter, the filtrate drying obtains the 8.5g water-soluble products;
(3) the puree bits after the flooding are with the 70v% alcohol reflux of 8 times of weight, filter, reclaim ethanol, the solids that obtains is with water washing, and drying obtains the flavones crude product, and the flavones crude product is used acetic acid ethyl dissolution again, filter, filtrate is concentrated, and crystallization obtains faint yellow flavones product, flavones content 42%;
(4) be used as feed after the residue drying that step (3) obtains.
Claims (1)
1, a kind of seabuckthorn fruit mud deep-processing method is characterized in that comprising the steps:
(1) seabuckthorn fruit mud is packed into extractor is used supercritical CO
2Extraction, control extracting pressure 12～40MPa, 31～60 ℃ of extraction temperature, separating pressure 5～12Mpa, 20～80 ℃ of separation temperatures obtain hippophae rhamnoides fruit oil and degreasing puree;
(2) the degreasing puree is mixed with 1: 10～20 part by weight with water, 30～60 ℃ of hot-water soaks 1～4 hour, filter filter residue, filtrate decompression distillation, drying obtain the water-soluble products hippophae rhamnoide nectar;
(3) filter residue that step (2) is obtained mixes with 1: 6～10 weight ratios with 60～80v% ethanol, soak, refluxed 1～5 hour, filter filter residue, the solids that obtains is with water washing, drying obtains the flavones crude product, the flavones crude product is used acetic acid ethyl dissolution again, filter, decompression distillation concentrates filtrate, and crystallization obtains faint yellow Hippophate flavone product;
(4) filter residue and drying that (3) step is obtained is as feed addictive.
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| CNB2004100645582A CN1328977C (en) | 2004-11-19 | 2004-11-19 | Deep processing method of seabuckthorn fruit mud |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101103816B (en) * | 2007-08-09 | 2010-04-21 | 宋仟惠 | Sea-buckthorn nutrient food additive and flour composition containing thereof |
| CN1730018B (en) * | 2005-08-04 | 2010-07-28 | 成都中医药大学 | Pharmaceutical composition for treating cardiovascular and cerebrovascular diseases and preparing process and application thereof |
| CN101935585A (en) * | 2010-09-28 | 2011-01-05 | 东北农业大学 | Novel process of extracting seabuckthorn oil by using two-level fractional step method |
| CN101084943B (en) * | 2007-06-13 | 2011-03-23 | 青海清华博众生物技术有限公司 | Method for preparing mixture containing natural vitamin P from sea-buckthorn |
| CN102533431A (en) * | 2011-10-08 | 2012-07-04 | 上海友信生物科技有限公司 | Method for continuously extracting and separating sea buckthorn oil and isorhamnetin from sea buckthorn pulps |
| CN102524562A (en) * | 2011-11-16 | 2012-07-04 | 淮南市施家湖水产养殖中心 | Feed additive for improving immunity of freshwater fish and preparation method thereof |
| CN108342251A (en) * | 2018-05-08 | 2018-07-31 | 深圳市仙迪化妆品有限公司 | One seed pod oil and the preparation method and application thereof |
| CN109200624A (en) * | 2018-09-17 | 2019-01-15 | 南京财经大学 | A method of step by step arithmetic Semen Coicis water extract and Semen Coicis alcohol extract from Semen Coicis |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101125843B (en) * | 2007-08-15 | 2010-06-02 | 中国科学院山西煤炭化学研究所 | Method for extracting refined isorhamnetin in seabuckthorn fruit pulp |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1485324A (en) * | 2002-09-28 | 2004-03-31 | 河北神兴沙棘研究院 | Method of membrane separation technique for producing seabuckthorn flavone |
-
2004
- 2004-11-19 CN CNB2004100645582A patent/CN1328977C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730018B (en) * | 2005-08-04 | 2010-07-28 | 成都中医药大学 | Pharmaceutical composition for treating cardiovascular and cerebrovascular diseases and preparing process and application thereof |
| CN101084943B (en) * | 2007-06-13 | 2011-03-23 | 青海清华博众生物技术有限公司 | Method for preparing mixture containing natural vitamin P from sea-buckthorn |
| CN101103816B (en) * | 2007-08-09 | 2010-04-21 | 宋仟惠 | Sea-buckthorn nutrient food additive and flour composition containing thereof |
| CN101935585A (en) * | 2010-09-28 | 2011-01-05 | 东北农业大学 | Novel process of extracting seabuckthorn oil by using two-level fractional step method |
| CN102533431A (en) * | 2011-10-08 | 2012-07-04 | 上海友信生物科技有限公司 | Method for continuously extracting and separating sea buckthorn oil and isorhamnetin from sea buckthorn pulps |
| CN102524562A (en) * | 2011-11-16 | 2012-07-04 | 淮南市施家湖水产养殖中心 | Feed additive for improving immunity of freshwater fish and preparation method thereof |
| CN108342251A (en) * | 2018-05-08 | 2018-07-31 | 深圳市仙迪化妆品有限公司 | One seed pod oil and the preparation method and application thereof |
| CN109200624A (en) * | 2018-09-17 | 2019-01-15 | 南京财经大学 | A method of step by step arithmetic Semen Coicis water extract and Semen Coicis alcohol extract from Semen Coicis |
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| CN1328977C (en) | 2007-08-01 |
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