Summary of the invention
The technical problem to be solved in the present invention provides the light-accumulated luminous PVC plate of a kind of fluorescence, and this plate has luminescent properties in fluorescence and the dark simultaneously.
Another technical problem that the present invention will solve provides the preparation method of the light-accumulated luminous PVC plate of a kind of fluorescence, this method is simple and practical, make fluorescent material and the abundant strong bonded of light-accumulated luminous powder in the coating of PVC plate, also possess the color and luster degree function of the light-accumulated luminous powder of further raising fluorescence by day the time.
The technical scheme that the present invention is adopted for the technical solution problem is: the light-accumulated luminous PVC plate of a kind of color fluorescence, based on the PVC plate, it is characterized in that: increase the light-accumulated luminous layer of one deck color fluorescence on described PVC plate, the light-accumulated luminous layer of this fluorescence contains 10 ~ 35% fluorescent material and 10 ~ 35% light-accumulated luminous powder.
As improvement, on the light-accumulated luminous layer of described color fluorescence, increase the preservative oil enamelled coating that one deck contains fluorescent material again.
The preparation method of the light-accumulated luminous PVC plate of aforesaid color fluorescence, on the surface of PVC plate, carry out steps of processing:
(1) preparation contains the fluorescence solvent of light-accumulated luminous powder: in filling the closed container of Tianna solution, adding weight is the color phosphor of Tianna solution weight 10 ~ 35%, fully stirs more than 24 hours, then standing demix, remove sediment, obtain the fluorescence solvent of supernatant liquid shape; After in the fluorescence solvent, adding weight and be Tianna solution weight 10 ~ 35% granularities and be light-accumulated luminous powder more than 200 orders, clear varnish that weight is Tianna solution weight 25 ~ 40% and weight and be 1 ~ 10% curing agent of Tianna solution weight, stir, obtain containing the fluorescence solvent of light-accumulated luminous powder; Curing agent can adopt epoxy resin.
(2) spraying contains the fluorescence solvent of light-accumulated luminous powder; The direct fluorescence solvent that contains light-accumulated luminous powder that prepared of spraying on plate surface divides 2 ~ 3 sprayings, treats once to spray after a preceding spray coating liquor is dried at 50 ~ 60% o'clock and just carries out;
(3) air-dry: the soleplate of the light-accumulated luminous liquid of fluorescence that back is sprayed carries out natural air drying or is heated to 30 ~ 70 ℃ of hot blasts doing, and obtains the light-accumulated luminous PVC plate of color fluorescence.
Aforementioned preparation method is further improved, the PVC plate surface after the process aforementioned processing, carry out following processing again:
(4) preparation protection fluorescence paint: in filling the closed container of Tianna solution, adding weight is the color phosphor of Tianna solution weight 10 ~ 20%, fully stirs more than 24 hours, and standing demix is removed sediment then, obtains the fluorescence solvent of supernatant liquid shape; Adding weight in the fluorescence solvent is after Tianna solution weight 30 ~ 40% clear varnishes and weight are the curing agent of Tianna solution weight 1 ~ 10%, to stir, and obtains fluorescence paint; This curing agent can adopt epoxy resin;
(5) this fluorescence paint is coated in through the plate surface after the spray treatment;
(6) natural air drying or be heated to 30 ~ 70 ℃ of hot blasts and do and to get final product.
Aforementioned (one) step main realization purification fluorescent material also carries out painted to light-accumulating powder.
The concrete color of the light-accumulated luminous PVC plate of the resulting colour of the present invention is mainly determined by the color of fluorescent material, as adopt single red fluorescence powder to obtain the light-accumulated luminous PVC plate of high brightness red fluorescence at last, as adopt two kinds of basic colors or three kinds of red, yellow, green basic colors high brightness autochromatic plate by different deals modulation different colours.
For further improving the color and luster degree of product, the preparation method of the light-accumulated luminous PVC plate of aforesaid color fluorescence in prepared fluorescence paint of described (four) step, also can add the transparent mill base close with the fluorescent material color, and the mill base addition is a weight ratio 0.1 ~ 2%.The color of mill base is selected as required, as selecting for use red fluorescence powder to add the FS-01 mill base, can obtain the light-accumulated luminous PVC plate of high brightness red fluorescence; As when selecting yellow fluorescent powder and red fluorescence powder for use, adding the FS-03 mill base, can obtain the light-accumulated luminous PVC plate of high brightness fluorescent orange; As when selecting faint yellow fluorescent material for use, adding No. 28 yellow slurries of 0.1%FS-03 mill base and 1.9%, can obtain the light-accumulated luminous PVC plate of high brightness yellow fluorescence.
The preparation method of the light-accumulated luminous PVC plate of aforesaid color fluorescence, the coating layer thickness that sprays the light-accumulated luminous liquid of fluorescence in described (two) step is preferably 0.5 ~ 1 millimeter.
Light-accumulated luminous powder used in the present invention is the light-accumulated luminous powder of certain color of " meteor shower " board, as redness, and green, yellow light-accumulated luminous powder.
Owing to adopted Tianna solution that fluorescent material and light-accumulated luminous powder have been carried out the dissolving combination, both improved and be not easy the shortcoming that combines with paint or organic granular in fluorescent material and the light-accumulated luminous powder, remove sediments such as impurity again, improved the purity of fluorescent material and light-accumulated luminous powder.
The invention has the beneficial effects as follows: on PVC plate surface, increase the light-accumulated luminous layer of one deck fluorescence, fluorescent material and light-accumulated luminous powder fully be combined in the coating, make the PVC plate have fluorescence and night lighting function, improve the night vision effect, save the energy.In coating, add mill base, further improved the fluorescence light-accumulated luminous powder color and luster degree by day the time.Owing to adopt Tianna solution and varnish as solvent combined with fluorescent powder and light-accumulated luminous powder, further improved the conjugation of this powder and PVC plate.Preparation method disclosed in this invention, simple and reliable, cost is low to be promoted easily.
The specific embodiment
The invention will be further described by the following examples, but embodiment is not used for limiting the scope of the invention.
Embodiment 1: the light-accumulated luminous PVC plate of a kind of red fluorescence, based on the PVC plate, on the PVC plate, increase the light-accumulated luminous layer of the thick red fluorescence of one deck 0.5mm, and the light-accumulated luminous layer of this fluorescence contains 31% fluorescent material and 32% light-accumulated luminous powder; On the light-accumulated luminous layer of described color fluorescence, increase the preservative oil enamelled coating that one deck 0.3mm contains red fluorescence powder again.
The light-accumulated luminous PVC plate of this red fluorescence is suitable as the advertisement background base plate of outdoor advertising.
The preparation method of the light-accumulated luminous PVC plate of aforesaid red fluorescence, on 2 square metres PVC plate surface, carry out steps of processing:
(1) preparation contains the fluorescence solvent of light-accumulated luminous powder: in the closed container that fills the 1000ml Tianna solution, adding weight is the red fluorescence powder of 200g, fully stirs 36 hours, and standing demix is removed sediment then, obtains the fluorescence solvent of supernatant liquid shape; In the fluorescence solvent, add after weight is the epoxy resin of the light-accumulated luminous powder more than 200 orders, clear varnish that weight is 350g and the weight 20g that is Tianna solution weight for the 200g granularity, stir, obtain containing the fluorescence solvent of light-accumulated luminous powder;
(2) spraying contains the fluorescence solvent of light-accumulated luminous powder; The direct fluorescence solvent that contains light-accumulated luminous powder that prepared of spraying on plate surface divides 2 sprayings, treats once to spray after a preceding spray coating liquor is dried at 60% o'clock and just carries out;
(3) air-dry: the soleplate of the light-accumulated luminous liquid of fluorescence that back is sprayed is heated to 50 ℃ of hot blasts and does, and obtains the light-accumulated luminous PVC plate of color fluorescence.
PVC plate surface after the aforementioned spray treatment of process, carry out following processing again:
(4) preparation protection fluorescence paint: in the closed container that fills the 1000ml Tianna solution, adding weight is the red fluorescence powder of 150g, fully stirs 30 hours, and standing demix is removed sediment then, obtains the fluorescence solvent of supernatant liquid shape; Adding weight in the fluorescence solvent is after 400g clear varnish and weight are the epoxy resin of 20g, to stir, and obtains fluorescence paint;
(5) this fluorescence is painted the plate surface that is coated in after treatment, spray 300ml on 1 square metre the PVC plate;
(6) natural air drying gets final product.
Embodiment 2: the light-accumulated luminous PVC plate of a kind of red fluorescence, based on the PVC plate, on the PVC plate, increase the light-accumulated luminous layer of the thick red fluorescence of one deck 0.5mm, and the light-accumulated luminous layer of this fluorescence contains 31% fluorescent material and 32% light-accumulated luminous powder; On the light-accumulated luminous layer of described color fluorescence, increase the preservative oil enamelled coating that one deck 0.3mm contains red fluorescence powder and red pigments again.Preparation method is identical with embodiment 1 basically, and different is in prepared fluorescence paint of described (four) step, also can add the transparent mill base close with the fluorescent material color, and the mill base addition is a weight ratio 0.2%.The color of mill base is selected red fluorescence powder as required, adds the red transparent mill base of FS-01, can obtain the light-accumulated luminous PVC plate of high brightness red fluorescence.
The redness that the sheet material that this plate obtains than embodiment 1 is showed by day is more bright-coloured, and fluorescence is consistent with illumination effect.