CN1597900A - Cleaning-rust-proof dual functional cleaning agent - Google Patents
Cleaning-rust-proof dual functional cleaning agent Download PDFInfo
- Publication number
- CN1597900A CN1597900A CN 03133991 CN03133991A CN1597900A CN 1597900 A CN1597900 A CN 1597900A CN 03133991 CN03133991 CN 03133991 CN 03133991 A CN03133991 A CN 03133991A CN 1597900 A CN1597900 A CN 1597900A
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- Prior art keywords
- out system
- acid
- polyolefine
- emulsifying agent
- clean
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- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention discloses a washing-anticorrosive difunctional detergent, especially a colloidal detergent that has good washing effect on heavy dirty and oil stain and process-in antirusting function. It is combined of petroleum hydrocarbon, emulsifier, emulsion adjuvant, antirusting agent, defoaming agent, corrosion preventive and water. The emulsifier is made of C4 and C5 polyalkenes, low-price. The antirusting agent has process-in antirusting effect.
Description
Technical field
The present invention relates to a kind of clean-out system, particularly a kind of counterweight dirt greasy dirt has good cleaning performance and the bifunctional colloid clean-out system of rust prevention during manufacture.
Technical field
Mechanical component, the equipment greasy dirt, especially heavy dirt needs to clean strong washing composition, and the petroleum hydrocarbon of light constituent is comparatively ideal component.Cleaning the rust prevention during manufacture of back machinery part surface, also is one of key property of washing composition.Although petroleum hydrocarbon is the good washing composition of heavy dirty greasy dirt, energy shortage, cost is higher, and it is poor to clean metallic surface, back rust-preventing characteristic.Mention negatively charged ion, the composite water soluble detergent of nonionogenic tenside among CN 1038313A and the CN 92102734A, general greasy dirt is had effect, but counterweight dirt greasy dirt cleaning is relatively poor, and this washing composition does not have rust inhibition yet.
Summary of the invention
At the deficiencies in the prior art, the invention provides the cleansing composition that low, the heavy dirty greasy dirt cleaning performance of a kind of cost is good, have the rust prevention during manufacture function.
The colloidal compositions of the heavy dirty greasy dirt cleaning-antirust dual-purpose clean-out system of the present invention contains petroleum hydrocarbon, emulsifying agent, the assistant for emulsifying agent of light constituent, rust-preventive agent, defoamer, sanitas and water.It is composed as follows by weight:
Petroleum hydrocarbon 30～70%
Emulsifying agent 5～15%
Assistant for emulsifying agent 0.01～5%
Rust-preventive agent 1～10%
Defoamer 0.0001～0.1%
Sanitas 0.01～1%
Water surplus.
Petroleum hydrocarbon of the present invention is a gasoline, kerosene, solvent oil, petroleum naphtha, toluene, dimethylbenzene, one or more mixtures of BTX aromatics.The amount ranges of petroleum hydrocarbon preferably 40～50%.
The emulsion that helps of the present invention is R
1COOH, R
1(OH), R
3R
4(R
2OH)
nR
1Be C
4～C
20Straight chain or the alkane of isomery, R
2Be C
mH
2m, m is 1～3, R
3Be C or N, R
4Be H
vV is 0～2.N is 1～3.Help the emulsion amount ranges 0.01～5%, preferably 1～2%.
Rust-preventive agent of the present invention is the multiple mixture of boric acid monoethanolamine, boric acid diethanolamine, triethanolamine borate, molybdic acid monoethanolamine, molybdic acid diethanolamine, molybdic acid trolamine, phenylformic acid monoethanolamine, phenylformic acid diethanolamine, phenylformic acid trolamine, phenylformic acid amine, o-nitrophenol sodium, o-nitrophenol dicyclohexyl amine, o-nitrophenol stearylamine, benzotriazole, nitro benzotriazole, 2-mercaptobenzothiazole, hexahydroaniline, monoethanolamine, diethanolamine, trolamine.
Defoamer of the present invention is one or more in polyethers, methyl-silicone oil, hydroxy silicon oil, amido silicon oil, the silicon-dioxide.
Sanitas of the present invention is Pentachlorophenol, tetra-chloro-phenol, O-SyL, 2,4 dinitrophenols, 2-methylol-2 nitro-1, one or more mixtures of ammediol.
Emulsifying agent is the emulsifying agent (polyolefine carboxylicesters) that polyolefine carboxylic acid or polyolefine acid anhydrides and oxy-compound make through esterification, also can be the emulsifying agent (polyolefine carboxylate salt) that polyolefinic acid or polyolefine acid anhydrides and alkali make through saponification reaction, or the mixture of two kinds of emulsifying agents.The polyolefinic number-average molecular weight of emulsifying agent is 600～3000, is preferably 800～1200, and viscosity is 500～3000 (100 ℃ of mm
2/ s).The preparation method of emulsifying agent can adopt ordinary method in the prior art, as adopting the preparation method of relevant emulsifying agent among the CN1335355A.
Cleansing composition of the present invention is water in oil microemulsion or colloidal solution, contain the petroleum hydrocarbon, emulsifying agent and the assistant for emulsifying agent that clean strong light constituent, the boron that contains environmentally safe simultaneously is antirust compound, both had the dirty cleaning of good weight, had good rust prevention during manufacture again.The present invention is heavy, and dirty greasy dirt cleaning-antirust dual-purpose clean-out system is cheap, can save the bulk petroleum hydrocarbon, and the emulsifying agent cost is low.
Embodiment
Below by specific examples the dual-purpose oil formula of cleaning rust-proof of the present invention is described, various components promptly get final rinse product through simple the mixing.Following examples and comparative example all adopt weight percent.
Wherein emulsifying agent A～J is the prepared emulsifying agent of CN1335355A embodiment 1～10.
Embodiment 1
Gasoline 60
Emulsifying agent A 5
Emulsifying agent D 7
Emulsifying agent G 2
Lauryl alcohol 2
Benzotriazole 0.2
Diethanolamine 0.1
Sodium Benzoate 0.1
Triethanolamine borate 8
Amido silicon oil 0.1
Water surplus
Embodiment 2
Kerosene 50
Emulsifying agent B 3
Emulsifying agent F 6
Emulsifying agent H 1
Boric acid diethanolamine 3
Trolamine 1
O-nitrophenol stearylamine 0.2
2-mercaptobenzothiazole 0.9
Nitro benzotriazole 0.4
Tetra-chloro-phenol 0.8
Hydroxy silicon oil 0.005
Water surplus
Embodiment 3
Dimethylbenzene 70
Emulsifying agent C 3
Emulsifying agent I 2
Emulsifying agent E 1
Hexadecanol 1
Triethanolamine borate 7
O-nitrophenol sodium 2
Trolamine 2
Benzotriazole 1
Methyl-silicone oil 0.05
Pentachlorophenol 0.2
Water surplus
Comparative example 1
Alkyl benzene sulphonate (ABS) 13
Sodium hydroxide 2.2
OP-4 emulsifying agent 3.63
OP-10 emulsifying agent 15.63
JFC permeate agent 5.63
Acetone 11.88
Water surplus
Comparative example 2
Water (70%)+base solvent I (15%)+secondary solvent II (10%)+auxiliary agent III (3%)+tensio-active agent IV (2%), wherein: I is a kerosene; II is that 1 part of ethanol, 2 parts of ethyl acetate, 2 parts of mixed preparing of acetone form; III is a sodium alkyl benzene sulfonate; IV is nonionic surface active agent OP.
Table 1 clean-out system performance
| Performance | Outward appearance | Rust-preventing characteristic, 15 days one-level cast iron sheets, copper sheet | Cleaning |
| Embodiment 1 | Transparent | Qualified | Qualified |
| Embodiment 2 | Transparent | Qualified | Qualified |
| Embodiment 3 | Transparent | Qualified | Qualified |
| Comparative example 1 | Transparent | Defective | Qualified |
| Comparative example 2 | Transparent | Defective | Qualified |
Claims (10)
1, a kind of cleaning-antirust difunctional clean-out system, it is composed as follows by weight:
Petroleum hydrocarbon 30～70%
Emulsifying agent 5～15%
Assistant for emulsifying agent 0.01～5%
Rust-preventive agent 1～10%
Defoamer 0.0001～0.1%
Sanitas 0.01～1%
Water surplus.
2, according to the described clean-out system of claim 1, it is characterized in that described petroleum hydrocarbon be gasoline, kerosene, solvent oil, petroleum naphtha, toluene, dimethylbenzene, BTX aromatics one or more, the consumption of petroleum hydrocarbon is 40～50%.
3,, it is characterized in that the described emulsion that helps is R according to the described clean-out system of claim 1
1COOH, R
1(OH), R
3R
4(R
2OH)
n, R wherein
1Be C
4～C
20Straight chain or the alkane of isomery, R
2Be C
mH
2m, m is 1～3, R
3Be C or N, R
4Be H
v, v is 0～2, n is 1～3, helps the emulsion amount ranges 0.01～5%, and preferably 1～2%.
4,, it is characterized in that described rust-preventive agent is one or more mixtures of boric acid monoethanolamine, boric acid diethanolamine, triethanolamine borate, molybdic acid monoethanolamine, molybdic acid diethanolamine, molybdic acid trolamine, phenylformic acid monoethanolamine, phenylformic acid diethanolamine, phenylformic acid trolamine, phenylformic acid amine, o-nitrophenol sodium, o-nitrophenol dicyclohexyl amine, o-nitrophenol stearylamine, benzotriazole, nitro benzotriazole, 2-mercaptobenzothiazole, hexahydroaniline, monoethanolamine, diethanolamine and trolamine according to the described clean-out system of claim 1.
5,, it is characterized in that described defoamer is one or more in polyethers, methyl-silicone oil, hydroxy silicon oil, amido silicon oil and the silicon-dioxide according to the described clean-out system of claim 1.
6,, it is characterized in that described sanitas is one or more mixtures of Pentachlorophenol, tetra-chloro-phenol, O-SyL, 2,4 dinitrophenols, 2-methylol-2 nitro-1 and ammediol according to the described clean-out system of claim 1.
7,, it is characterized in that described emulsifying agent polyolefine carboxylicesters and/or polyolefine carboxylate salt according to the described clean-out system of claim 1.
8, according to the described clean-out system of claim 7, it is characterized in that described polyolefine carboxylicesters is that polyolefine carboxylic acid or polyolefine acid anhydrides and oxy-compound make through esterification, the polyolefine carboxylate salt is that polyolefinic acid or polyolefine acid anhydrides and alkali make through saponification reaction.
9,, it is characterized in that the polyolefinic number-average molecular weight of emulsifying agent is 600～3000 according to claim 7 or 8 described clean-out systems.
10,, it is characterized in that described polyolefinic number-average molecular weight 800～1200 according to the described clean-out system of claim 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03133991 CN1268730C (en) | 2003-09-15 | 2003-09-15 | Cleaning-rust-proof dual functional cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03133991 CN1268730C (en) | 2003-09-15 | 2003-09-15 | Cleaning-rust-proof dual functional cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1597900A true CN1597900A (en) | 2005-03-23 |
| CN1268730C CN1268730C (en) | 2006-08-09 |
Family
ID=34658936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03133991 Expired - Fee Related CN1268730C (en) | 2003-09-15 | 2003-09-15 | Cleaning-rust-proof dual functional cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1268730C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899669A (en) * | 2012-10-23 | 2013-01-30 | 鞍钢股份有限公司 | Antirust agent for cold-rolled steel sheet in cold-rolling process |
| CN104629921A (en) * | 2013-11-08 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Detergent for vegetables and fruits |
| CN104651871A (en) * | 2015-03-05 | 2015-05-27 | 苏州市凯业金属制品有限公司 | Antirust detergent for metal products |
| CN104862124A (en) * | 2015-04-23 | 2015-08-26 | 深圳宣顶实业有限公司 | Part cleaning agent |
| CN106929197A (en) * | 2017-03-31 | 2017-07-07 | 赵学法 | A kind of oil base cleaning agent for petrochemical equipment cleaning |
| CN107338072A (en) * | 2017-07-26 | 2017-11-10 | 徐文忠 | Reformer corrosion inhibiter and preparation method thereof |
| CN109942944A (en) * | 2019-03-28 | 2019-06-28 | 林雷祥 | A kind of general purpose type gasification anti-rust master batch and its production technology |
-
2003
- 2003-09-15 CN CN 03133991 patent/CN1268730C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899669A (en) * | 2012-10-23 | 2013-01-30 | 鞍钢股份有限公司 | Antirust agent for cold-rolled steel sheet in cold-rolling process |
| CN104629921A (en) * | 2013-11-08 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Detergent for vegetables and fruits |
| CN104651871A (en) * | 2015-03-05 | 2015-05-27 | 苏州市凯业金属制品有限公司 | Antirust detergent for metal products |
| CN104862124A (en) * | 2015-04-23 | 2015-08-26 | 深圳宣顶实业有限公司 | Part cleaning agent |
| CN106929197A (en) * | 2017-03-31 | 2017-07-07 | 赵学法 | A kind of oil base cleaning agent for petrochemical equipment cleaning |
| CN106929197B (en) * | 2017-03-31 | 2020-05-22 | 赵学法 | Oil-based cleaning agent for cleaning petrochemical equipment |
| CN107338072A (en) * | 2017-07-26 | 2017-11-10 | 徐文忠 | Reformer corrosion inhibiter and preparation method thereof |
| CN107338072B (en) * | 2017-07-26 | 2019-09-13 | 徐文忠 | Reformer corrosion inhibiter and preparation method thereof |
| CN109942944A (en) * | 2019-03-28 | 2019-06-28 | 林雷祥 | A kind of general purpose type gasification anti-rust master batch and its production technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1268730C (en) | 2006-08-09 |
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