CN101423951A - Cleaning agent capable of oil removing, rust cleaning, antirust and glazing - Google Patents
Cleaning agent capable of oil removing, rust cleaning, antirust and glazing Download PDFInfo
- Publication number
- CN101423951A CN101423951A CNA2008100298068A CN200810029806A CN101423951A CN 101423951 A CN101423951 A CN 101423951A CN A2008100298068 A CNA2008100298068 A CN A2008100298068A CN 200810029806 A CN200810029806 A CN 200810029806A CN 101423951 A CN101423951 A CN 101423951A
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- antirust
- out system
- oil removing
- acid
- rust cleaning
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Abstract
The invention relates to the technical field of cleaning agents, in particular to a cleaning agent capable of removing oil and rust, preventing rust, and glazing. The cleaning agent consists of 15 to 30 percent of modified acrylic resin, 2 to 15 percent of organic silane coupling agent, 5 to 10 percent of emulsifying agent, 2 to 8 percent of antirust agent, 10 to 20 percent of glycol ether solvent and deionized water. The cleaning agent can clean surfaces of metal products and form a protective film on the surfaces of the metal products, thereby preventing damp and rust and making the surfaces of the metal produts bright and beautiful.
Description
Technical field:
The present invention relates to the clean-out system technical field, relate in particular to a kind of oil removing, rust cleaning, antirust, glazing clean-out system.
Background technology:
It is metallic article requisite process procedure in processes such as processing, assembling, storage and maintenance that metal cleans, and its maximum Application Areas is Iron And Steel Industry and automotive industry.The cleaning process of metal cleaner is to utilize tensio-active agent to reduce the surface tension of liquid, produce comprehensive actions such as oriented adsorption, wetting, emulsification, dispersion, solubilising, relend the heating that helps when cleaning, scrub, spray, vibration or hyperacoustic mode make greasy dirt break away from workpiece surface as early as possible, be distributed in the scavenging solution, reach the purpose of eliminating dirt.
Traditional clean-out system is the most original to be based on hydrocarbon mixtures such as gasoline, kerosene; Having developed with strong alkaline substance (as NaOH, Na2CO3, Na2SiO3, Na3PO4) in the sixties in 20th century is the aqueous cleaning agent of main component; Having developed for 70～eighties with the tensio-active agent is the aqueous cleaning agent of main component, has occurred as cleaning performances such as 6501,6503 surfactant monomer preferably; After the eighties in 20th century through composite by between the kinds of surface promoting agent of the continuous effort of researcher, utilize the synergistic effect between each component, make the cleansing power of metal cleaner be greatly improved, its technology has obtained very big development, the petroleum-type solvent will progressively be eliminated as metal cleaner, and halogenated hydrocarbon solvent efficient, environmental protection will become the first-selection of solvent-borne type metal cleaner from now on.Widely used metal cleaner of past is an all kinds of SOLVENTS, alkalescence or tart aqueous cleaning agent, many rules have been issued at present both at home and abroad, limited the use of most solvent, make leaning solvent and water base phosphorous clean-out system progressively to eliminate, pros and cons separately in conjunction with solvent-borne type and aqueous cleaning agent, it is water base metal cleaning agent is difficult to effectively remove the metallic surface under the room temperature situation heavy dirt, to remove greasy dirt rapid and leaning solvent has, the cold washing good effectiveness, novel nontoxic without phosphorus, efficiently, antirust grade has multi-functional environment-friendly type water based cleaning agent will become the direction that cleaning industry is studied energetically.
But proposition along with development of technology and environmental requirement, cleaning products novel, efficient, professional, environmental protection is more worth, and we go deep discussion and research, existing in the market metal cleaner, still there are price height, function singleness, and clean the shortcoming of metallic surface, back rustless property difference.
Summary of the invention:
The objective of the invention is at the deficiencies in the prior art, and disclose a kind of not only with low cost, metallic surface good antirust property, and can form the multifuctional cleaning agent of protective membrane on the metal surface.
The objective of the invention is to be achieved by the following method: a kind of oil removing, rust cleaning, antirust, glazing clean-out system; This clean-out system comprises the material of following weight percent:
Acrylic resin modified 15～30%
Organo silane coupling agent 2～15%
Emulsifying agent 5～10%
Rust-preventive agent 2～8%
Alcohol ether solvents 10～20%
The deionized water surplus.
Wherein, described acrylic resin modified by 20～60% amino monomers that contain two keys, 5～50% unsaturated organic acids or its salt, 10～30% unsaturated ester classes are synthetic, and its synthesis technique is: elder generation adds 50% butyl glycol ether in Polycondensation Reactor and Esterification Reactor, be warming up to 110 ℃, be added drop-wise in the reactor after using 30% acrylic resin modified monomer and 1.0% initiator that Oxybenzene formyl and 19% butyl glycol ether are mixed again, the control dropping time is 3 hours, is incubated 2 hours and gets final product.
Described acrylic resin modified monomer is by the amino monomers that contains two keys, and 20～60%, unsaturated organic acid or its salt, 5～50%, the unsaturated ester class, 10～30% is synthetic.
The described amino monomers that contains two keys is Methacrylamide, n-methylolacrylamide, N, any one or more than one the mixture in the N-dimethyl ethyl aminoethyl methacrylate.
Described unsaturated organic acid or its salt are methacrylic acid, 2-acrylamide-2 methyl propane sulfonic acid, styrene sulfonic acid, vinyl sulfonic acid and sylvite thereof, sodium salt, ammonium salt, any one in the zinc salt etc. or more than one mixture.
Described unsaturated ester class is a methyl methacrylate, butyl methacrylate, any one or more than one the mixture in the methacryloxyethyl acid hydroxy butyl ester.
Described organo silane coupling agent is to have an amino or epoxide group silane coupling agent as functional group.
Described emulsifying agent is the lipid acid ethylene oxide adduct, aliphatic amine polyoxyethylene ether, dehydration sorb fatty acid ester, any one or more than one the mixture in the alkane sodium olefin sulfonate.
Described rust-preventive agent is the boric acid monoethanolamine, boric acid diethanolamine, triethanolamine borate, molybdic acid monoethanolamine, molybdic acid diethanolamine, molybdic acid trolamine, phenylformic acid amine, any one or more than one the mixture in the o-nitrophenol sodium.
Described alcohol ether solvents is methyl alcohol, ethanol, Virahol, propyl carbinol, ethylene glycol, ethylene glycol monomethyl ether, any one in the butyl glycol ether or more than one mixture.
The invention has the beneficial effects as follows; the present invention is by acrylic resin modified; organo silane coupling agent; emulsifying agent; rust-preventive agent alcohol ether solvents and deionized water are formed, and not only raw material is easy to get this clean-out system, technology is simple, excellent property, use range are wide, and also can form a protective membrane on the metal surface when metal surface cleaned; thereby it is antirust to help its protection against the tide, and makes the metal surface-brightening attractive in appearance.
Embodiment:
The invention will be further described below in conjunction with example, and the following examples can be used for making those skilled in the art more fully to understand the present invention, but do not limit the present invention in any way.
Embodiment 1
A kind of oil removing, rust cleaning, antirust, glazing clean-out system; This clean-out system comprises the material of following weight percent:
Acrylic resin modified 15.2%
Organo silane coupling agent 6%
Dehydration sorb fatty acid ester 5.2%
Boric acid monoethanolamine 3.6%
Ethanol 10%
The deionized water surplus,
Wherein, described acrylic resin modified by the amino monomers that contains two keys, unsaturated organic acid or its salt, the unsaturated ester class is synthetic, and its synthesis technique is: elder generation adds 50% butyl glycol ether in Polycondensation Reactor and Esterification Reactor, be warming up to 110 ℃, be added drop-wise in the reactor after using 30% acrylic resin modified monomer and 1.0% initiator that Oxybenzene formyl and 19% butyl glycol ether are mixed again, the control dropping time is 3 hours, is incubated 2 hours and gets final product.
Embodiment 2
A kind of oil removing, rust cleaning, antirust, glazing clean-out system; This clean-out system comprises the material of following weight percent:
Acrylic resin modified 22%
Organo silane coupling agent 8%
Aliphatic amine polyoxyethylene ether 3%
Molybdic acid trolamine 6.8%
Propyl carbinol 16%
The deionized water surplus,
Wherein, acrylic resin modified preparation is with embodiment 1.
Claims (10)
1, a kind of oil removing, rust cleaning, antirust, glazing clean-out system; It is characterized in that this clean-out system comprises the material of following weight percent:
Acrylic resin modified 15～30%
Organo silane coupling agent 2～15%
Emulsifying agent 5～10%
Rust-preventive agent 2～8%
Alcohol ether solvents 10～20%
The deionized water surplus.
2, a kind of oil removing according to claim 1, rust cleaning, antirust, glazing clean-out system; It is characterized in that, described acrylic resin modified by 20～60% amino monomers that contain two keys, 5～50% unsaturated organic acids or its salt, 10～30% unsaturated ester classes are synthetic, its synthesis technique is: elder generation adds 50% butyl glycol ether in Polycondensation Reactor and Esterification Reactor, be warming up to 110 ℃, use 30% acrylic resin modified monomer again, with 1.0% initiator to the Oxybenzene formyl, be added drop-wise in the reactor after mixing with 19% butyl glycol ether, the control dropping time is 3 hours, is incubated 2 hours and gets final product.
3, a kind of oil removing according to claim 2, rust cleaning, antirust, glazing clean-out system; It is characterized in that described acrylic resin modified monomer is by the amino monomers that contains two keys, 20～60%, unsaturated organic acid or its salt, 5～50%, the unsaturated ester class, 10～30% is synthetic.
4, a kind of oil removing according to claim 3, rust cleaning, antirust, glazing clean-out system; It is characterized in that the described amino monomers that contains two keys is Methacrylamide, n-methylolacrylamide, N, any one or more than one the mixture in the N-dimethyl ethyl aminoethyl methacrylate.
5, a kind of oil removing according to claim 3, rust cleaning, antirust, glazing clean-out system, it is characterized in that, described unsaturated organic acid or its salt, be methacrylic acid, 2-acrylamide-2 methyl propane sulfonic acid, styrene sulfonic acid, vinyl sulfonic acid and sylvite thereof, sodium salt, ammonium salt, any one in the zinc salt etc. or more than one mixture.
6, a kind of oil removing according to claim 3, rust cleaning, antirust, glazing clean-out system, it is characterized in that, described unsaturated ester class is a methyl methacrylate, butyl methacrylate, any one or more than one the mixture in the methacryloxyethyl acid hydroxy butyl ester.
According to a kind of oil removing described in any in claim 1 or 2, rust cleaning, antirust, glazing clean-out system, it is characterized in that 7, described organo silane coupling agent is to have amino or the epoxide group silane coupling agent as functional group.
8, according to a kind of oil removing described in any in claim 1 or 2, rust cleaning, antirust, glazing clean-out system, it is characterized in that, described emulsifying agent is the lipid acid ethylene oxide adduct, aliphatic amine polyoxyethylene ether, dehydration sorb fatty acid ester, any one or more than one the mixture in the alkane sodium olefin sulfonate.
9, according to a kind of oil removing described in any in claim 1 or 2, rust cleaning, antirust, glazing clean-out system, it is characterized in that, described rust-preventive agent is the boric acid monoethanolamine, the boric acid diethanolamine, triethanolamine borate, molybdic acid monoethanolamine, the molybdic acid diethanolamine, the molybdic acid trolamine, phenylformic acid amine, any one or more than one the mixture in the o-nitrophenol sodium.
10, according to a kind of oil removing described in any in claim 1 or 2, rust cleaning, antirust, glazing clean-out system, it is characterized in that, described alcohol ether solvents, be methyl alcohol, ethanol, Virahol, propyl carbinol, ethylene glycol, ethylene glycol monomethyl ether, any one in the butyl glycol ether or more than one mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100298068A CN101423951B (en) | 2008-07-29 | 2008-07-29 | Cleaning agent capable of oil removing, rust cleaning, antirust and glazing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100298068A CN101423951B (en) | 2008-07-29 | 2008-07-29 | Cleaning agent capable of oil removing, rust cleaning, antirust and glazing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101423951A true CN101423951A (en) | 2009-05-06 |
| CN101423951B CN101423951B (en) | 2011-12-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100298068A Expired - Fee Related CN101423951B (en) | 2008-07-29 | 2008-07-29 | Cleaning agent capable of oil removing, rust cleaning, antirust and glazing |
Country Status (1)
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| CN (1) | CN101423951B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838420A (en) * | 2010-05-04 | 2010-09-22 | 彭超 | Solid energy saving screw cleaning agent |
| CN102219799A (en) * | 2011-04-06 | 2011-10-19 | 修建东 | Preparation method of organic boric acid ester containing azacycle |
| CN102500823A (en) * | 2011-10-13 | 2012-06-20 | 四川宁江山川机械有限责任公司 | Method for replacing grinding fluid with cleaning/degreasing fluid for use on band sawing machine |
| CN103087567A (en) * | 2012-12-18 | 2013-05-08 | 芜湖恒坤汽车部件有限公司 | Surface silanization protection treatment agent for corrosion inhibiting and resisting metal and preparation method thereof |
| CN103343351A (en) * | 2013-07-15 | 2013-10-09 | 苏州锐耐洁电子科技新材料有限公司 | Water-based cleaning agent |
| CN103757639A (en) * | 2013-12-31 | 2014-04-30 | 湖南金裕化工有限公司 | Efficient and environment-friendly metal antirust agent and production method thereof |
| CN105177616A (en) * | 2015-10-14 | 2015-12-23 | 南京工程学院 | Multifunctional efficient industrial cleaning agent and preparation method thereof |
| CN105220163A (en) * | 2015-10-19 | 2016-01-06 | 南京润屹电子科技有限公司 | A kind of metal cleaner and preparation method thereof |
| CN105312270A (en) * | 2014-06-05 | 2016-02-10 | 通用电气公司 | Off-line wash systems and methods for gas turbine engine |
| CN103757639B (en) * | 2013-12-31 | 2016-11-30 | 湖南金裕化工有限公司 | High-efficiency environment friendly metal antirusting agent and preparation method thereof |
| CN103343354B (en) * | 2013-06-17 | 2017-05-31 | 张家界乾丰高科技术开发有限责任公司 | A kind of polystyrene（PS）Strength rust remover |
| CN107460531A (en) * | 2017-07-03 | 2017-12-12 | 马鞍山蓝科再制造技术有限公司 | A kind of method of automobile panel electrolysis paraffin removal |
| CN112680734A (en) * | 2020-12-09 | 2021-04-20 | 鞍钢集团矿业有限公司 | Corrosion inhibitor suitable for acidic medium and preparation method and application thereof |
| CN112845279A (en) * | 2020-12-24 | 2021-05-28 | 太仓小熊精密模具有限公司 | Environment-friendly energy-saving novel metal cold forming processing method |
Families Citing this family (2)
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| CN103526220A (en) * | 2013-10-30 | 2014-01-22 | 合肥市华美光电科技有限公司 | Copper printed circuit board cleaning agent and preparation method thereof |
| CN103525601A (en) * | 2013-10-30 | 2014-01-22 | 合肥市华美光电科技有限公司 | Water-based strong-lysotype circuit board cleaning agent and preparing method thereof |
-
2008
- 2008-07-29 CN CN2008100298068A patent/CN101423951B/en not_active Expired - Fee Related
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838420A (en) * | 2010-05-04 | 2010-09-22 | 彭超 | Solid energy saving screw cleaning agent |
| CN102219799A (en) * | 2011-04-06 | 2011-10-19 | 修建东 | Preparation method of organic boric acid ester containing azacycle |
| CN102219799B (en) * | 2011-04-06 | 2015-11-25 | 烟台恒迪克能源科技有限公司 | A kind of preparation method of organic boric acid ester containing azacycle |
| CN102500823A (en) * | 2011-10-13 | 2012-06-20 | 四川宁江山川机械有限责任公司 | Method for replacing grinding fluid with cleaning/degreasing fluid for use on band sawing machine |
| CN103087567B (en) * | 2012-12-18 | 2016-03-23 | 芜湖恒坤汽车部件有限公司 | A kind of inhibition Anti-corrosion metal surface silane protective agent for surface treatment and preparation method thereof |
| CN103087567A (en) * | 2012-12-18 | 2013-05-08 | 芜湖恒坤汽车部件有限公司 | Surface silanization protection treatment agent for corrosion inhibiting and resisting metal and preparation method thereof |
| CN103343354B (en) * | 2013-06-17 | 2017-05-31 | 张家界乾丰高科技术开发有限责任公司 | A kind of polystyrene（PS）Strength rust remover |
| CN103343351A (en) * | 2013-07-15 | 2013-10-09 | 苏州锐耐洁电子科技新材料有限公司 | Water-based cleaning agent |
| CN103757639B (en) * | 2013-12-31 | 2016-11-30 | 湖南金裕化工有限公司 | High-efficiency environment friendly metal antirusting agent and preparation method thereof |
| CN103757639A (en) * | 2013-12-31 | 2014-04-30 | 湖南金裕化工有限公司 | Efficient and environment-friendly metal antirust agent and production method thereof |
| CN105312270A (en) * | 2014-06-05 | 2016-02-10 | 通用电气公司 | Off-line wash systems and methods for gas turbine engine |
| CN105312270B (en) * | 2014-06-05 | 2020-03-06 | 通用电气公司 | Offline washing system and method for gas turbine engine |
| CN105177616A (en) * | 2015-10-14 | 2015-12-23 | 南京工程学院 | Multifunctional efficient industrial cleaning agent and preparation method thereof |
| CN105220163A (en) * | 2015-10-19 | 2016-01-06 | 南京润屹电子科技有限公司 | A kind of metal cleaner and preparation method thereof |
| CN107460531A (en) * | 2017-07-03 | 2017-12-12 | 马鞍山蓝科再制造技术有限公司 | A kind of method of automobile panel electrolysis paraffin removal |
| CN112680734A (en) * | 2020-12-09 | 2021-04-20 | 鞍钢集团矿业有限公司 | Corrosion inhibitor suitable for acidic medium and preparation method and application thereof |
| CN112845279A (en) * | 2020-12-24 | 2021-05-28 | 太仓小熊精密模具有限公司 | Environment-friendly energy-saving novel metal cold forming processing method |
Also Published As
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| CN101423951B (en) | 2011-12-21 |
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Granted publication date: 20111221 Termination date: 20170729 |