CN102296003B - Water-saving detergent - Google Patents
Water-saving detergent Download PDFInfo
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- CN102296003B CN102296003B CN2011102088545A CN201110208854A CN102296003B CN 102296003 B CN102296003 B CN 102296003B CN 2011102088545 A CN2011102088545 A CN 2011102088545A CN 201110208854 A CN201110208854 A CN 201110208854A CN 102296003 B CN102296003 B CN 102296003B
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- water
- stir
- add
- nonionogenic tenside
- amphoterics
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Abstract
The invention discloses a water-saving detergent which comprises by weight: 6-15% of anionic surfactant, 1-10% of nonionic surfactant, 1-8% of amphoteric surfactant, 0.2-0.5% of essence, and the balance deionized water. Prepared with surfactants characterized by high efficiency, mild decontamination, high solubility in water and easy rinsing, the detergent of the invention has the advantages of environmental protection, water saving, easy rinsing and no residue, etc.
Description
Technical field
The present invention relates to a kind of washing composition, particularly a kind of water-saving washing composition.
Background technology
When being stained with dirt on the clothing that we wear or use, meeting and clothing produce certain bonding force, can not remove automatically easily.At this moment just need be removed with the method for washing.The medium of washing usefulness is water normally, if dirt is water miscible, uses a large amount of water repetitive scrubbings so, just can decontamination.But a lot of dirts are butyrous, at this moment just need be by washing composition (mainly be through wherein tensio-active agent) with they removals.When will having the soiled clothes of dirt, we are immersed in the washings; Hydrophobic in the tensio-active agent (oleophylic) part be easy to attached to dirt or greasy on; And hydrophilic segment aligns towards water, makes to be not easy originally by getting wet easily of becoming of the dirty fiber surface of water-wet and wetted.Be adsorbed onto the synthetic detergent on fiber and the dirt, also expand because of producing a large amount of bubbles, washings is further infiltrated wherein because of the surface tension that has reduced water makes fiber and dirt.With suitable mechanical force, like hand rubbing, or the agitation wheel for washing machine stirring, those lax dirt particles can be disperseed and come off in water.
The kind of washing composition is a lot; Solid detergent, powder washing composition, liquid washing agent etc. are arranged; But solid detergent and powder washing composition form the inflammable settling of one deck on the surface of clothes easily; Influence permeability, and soap and washing powder itself is alkaline material, can causes damage fabric fibre.Some special clothings; What put out a fire that protective clothing adopts like novel Fr is four-layer structure, and internal layer is made up of chemical films Compound Fabric, Nomex and the multilayers such as Kevlar non-woven material and lining of waterproof and breathable, because of waterproof ventilated membrane geology thin; So intensity and wear resistance are lower than general cloth; During cleaning, need to separate independent cleaning with the coat of fighting uniform, the washing water temperature should not surpass 40oC; As using soap or soap powder washing, soap and soap powder form the inflammable settling of one deck on the surface of clothes easily, influence flame retardant effect and permeability; The decontamination of use chlorinated lime damages the flame retardant properties of material easily and influences the fastness and the weather resistance of fiber.Chinese patent CN1708576A discloses a kind of liquid laundry detergent; The liquid vehicle that this washing composition comprises at least a detergent ingredients, forms cationic polymers, one or more fabric nursing compositions of coacervating phase and be used to provide cleaning and fabric care benefit effect also comprises washing assistant and enzyme.The adding of washing assistant can reach good washing effect for the matching surface promoting agent in this washing composition, but detergent builder are difficult for rinsing, and the rinsing water amount is big, and the discharging of washing assistant can destroy ecology and contaminate environment.So the washing composition of exploitation water-saving and environmental protection is imperative.
Summary of the invention
The technical problem that the present invention will solve provides a kind of water-saving washing composition that has water-saving efficient, is prone to advantages such as rinsing and noresidue.The weight percent of washing composition of the present invention consists of:
AS 6-15%;
Nonionogenic tenside 1-10%;
Amphoterics 1-8%;
Essence 0.2-0.5%;
Deionized water is a surplus;
Wherein, The weight percent of said AS consists of: the carboxylate derivatives AEC-400 3-67% of natural phant oleyl alcohol polyoxypropylene, T 46155 ether block copolymers; Sulfonate type AS 0-97%, sulfuric acid type AS 0-97%;
Said nonionogenic tenside is polyoxyethylene-type nonionogenic tenside and/or alkylol amide type nonionogenic tenside;
Said amphoterics is one or more in amino acid type amphoteric surface active agent, betaine type amphoteric surfac-tant and the octadecyl dihydroxy ethyl amine oxide.
Said washing composition is through following prepared:
In the deionized water of (30～70) ℃, add the AS of being selected for use, stir (2～5) h to evenly; (30～40) ℃ adding nonionogenic tenside stirs (0.5～2) h to even; (30～40) ℃ adding amphoterics stirs (0.5～2) h to even; At (30～40) ℃ adding essence, stir, make product.
Wherein, AS AEC-400 is colourless to weak yellow liquid, is the carboxylate derivatives of natural phant oleyl alcohol polyoxypropylene, T 46155 ether block copolymers, and chemical structural formula is R (CH
2CH
2CH
2O)
n(CH
2CH
2O)
m(CH
2CH
2CH
2O)
nCOOM (R is unsaturated straight-chain paraffin, and M is a metals ion), fully biodegradable is a kind of AS of unique properties, has excellent easy rinsing performance, can significantly eliminate the foam of fabric during rinsing.The present invention adopts AEC-400 and other surfactant compounds, and Study on compatibility and machine washing characteristic analysis through to material filter out scientific formula; Compare with washing powder, it is residual on clothing to have reduced Betengent product, and high alkalinity is to the infringement of fabric fibre; More be prone to rinsing; Reduce residually, meet water saving, environment-friendly type washing composition that national industrial policies require, be particularly useful for turnout gear and clean.
Adopt the beneficial effect that technique scheme produced to be:
1, stronger decontamination, emulsification, degreasing, low bubble performance after utilizing negatively charged ion and nonionogenic tenside composite; And the mildness of amphoterics synergy; Obtain a stable ionic system; Have good water-saving function simultaneously, be applicable to the washing of general family and bunker clothing; Cleaning, water saving are once accomplished, and nontoxic, non-stimulated, have practiced thrift use cost.
2, the adding of AS AEC-400 strengthens the dispersion and the suspending power of dirt, can with the liquid greasy dirt that splits away off on the article surface be emulsified into little oil droplet and dispersion suspension in water; The effect of the collaborative amphoterics of nonionogenic tenside, make oil-water interface charged and stop oil droplet and gather, increase its stability in water and stop soil redeposition in the clothing surface.
3, to getting into the solid dirt of aqueous phase, because of there is like charges in the dirt surface, when its near the time produce electrostatic repulsion and improved the dispersion stabilization of solid dirt in water; The adding of non-ionics produces through long aquation polyoxyethylene chain and sterically hinderedly to make greasy dirt and solid soil dispersion and be stable in the water.
4, AS AEC-400 can change foam property, significantly eliminates the foam during the rinsing, reduces the rinsing number of times, reaches the purpose of water saving.
5, need not add washing assistant such as potassium pyrophosphate, Trisodium Citrate etc., be easy to biological degradation, can not exert an influence simultaneously permeability; Be particularly useful for turnout gear, can the flame retardant effect of fighting uniform do not exerted an influence.
6,,, soil-removing action is efficiently arranged also even when pH be neutrality because the adding of AS AEC-400.
Embodiment
Embodiment 1
(1) AS: AEC-400 40.2g, lauric alcohol sodium sulfate 9g, X 2073 10.8g;
(2) nonionogenic tenside: Tween-40 100g;
(3) amphoterics: AMONYL 380LC 30g, octadecyl dihydroxy ethyl amine oxide 50g;
(4) essence 3g;
(5) deionized water 757g;
In 40 ℃ deionized water, add the AS of being selected for use, stir 2h to even; 35 ℃ add nonionogenic tenside, stir 0.5h to even; 35 ℃ add amphoterics, stir (0.5～2) h to even; At (30～40) ℃ adding essence, stir, make product.
Embodiment 2
(1) AS: AEC-400 4.5g, X 2073 145.5g;
(2) nonionogenic tenside: cocinic acid diethylolamine 30g;
(3) amphoterics: Varion CDG-K 10g;
(4) essence 2g;
(5) deionized water 808g;
In 65 ℃ deionized water, add the AS of being selected for use, stir 3h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 2h to even; 30 ℃ add essence, stir, and make product.
Embodiment 3
(1) AS: AEC-400 4.5g, dodecyl polyethenoxy ether sodium sulfate 145.5g;
(2) nonionogenic tenside: Tween-60 20g, lauric acid diethyl amide 20g;
(3) amphoterics: sodium dodecyl aminopropionitrile 30g, dodecyl dimethyl azochlorosulfonate propyl lycine 10g;
(4) essence 5g;
(5) deionized water 765g;
In 60 ℃ deionized water, add the AS of being selected for use, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Embodiment 4
(1) AS: AEC-400 15g, Aerosol OT 50g, methyl sodiosul foaliphatate 35g;
(2) nonionogenic tenside: Tween-80 10g;
(3) amphoterics: laurylamide ethyl-hydroxyethyl Sodium glycocollate 30g, octadecyl dihydroxy ethyl amine oxide 50g;
(4) essence 5g;
(5) deionized water 805g;
In 70 ℃ deionized water, add the AS of being selected for use, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Embodiment 5
(1) AS: AEC-400 30g, methyl sodiosul foaliphatate 45g, Sodium palmityl sulfate 45g;
(2) nonionogenic tenside: Stearic acid diethanolamine salt 50g;
(3) amphoterics: dodecyl oxyethyl group sultaine 30g;
(4) essence 4g;
(5) deionized water 796g;
In 70 ℃ deionized water, add the AS of being selected for use, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Embodiment 6
(1) AS: AEC-400 40g, X 2073 20g, lauric alcohol sodium sulfate 20g;
(2) nonionogenic tenside: Tween-40 40g; Tween-80 30g;
(3) amphoterics: AMONYL 380LC 50g, Varion CDG-K 10g;
(4) essence 3g;
(5) deionized water 787g;
In 70 ℃ deionized water, add the AS of being selected for use, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Claims (2)
1. water-saving washing composition is characterized in that the weight percent of said washing composition consists of:
AS 6-15%;
Nonionogenic tenside 1-10%;
Amphoterics 1-8%;
Essence 0.2-0.5%;
The deionized water surplus;
The weight percent of said AS consists of: the carboxylate derivatives AEC-400 3-67% of natural phant oleyl alcohol polyoxypropylene, T 46155 ether block copolymers; Sulfonate type AS 0-97%, sulfuric acid type AS 0-97%;
Said nonionogenic tenside is polyoxyethylene-type nonionogenic tenside and/or alkylol amide type nonionogenic tenside;
Said amphoterics is one or more in amino acid type amphoteric surface active agent, betaine type amphoteric surfac-tant and the octadecyl dihydroxy ethyl amine oxide.
2. a kind of water-saving washing composition according to claim 1 is characterized in that said washing composition is through following prepared:
In 30～70 ℃ deionized water, add the AS of being selected for use, stir 2～5h to even; 30～40 ℃ add nonionogenic tenside, stir 0.5～2h to even; 30～40 ℃ add amphoterics, stir 0.5～2h to even; Add essence at 30～40 ℃, stir, make product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102088545A CN102296003B (en) | 2011-05-12 | 2011-07-25 | Water-saving detergent |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110122473 | 2011-05-12 | ||
| CN201110122473.5 | 2011-05-12 | ||
| CN2011102088545A CN102296003B (en) | 2011-05-12 | 2011-07-25 | Water-saving detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102296003A CN102296003A (en) | 2011-12-28 |
| CN102296003B true CN102296003B (en) | 2012-09-19 |
Family
ID=45356681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102088545A Expired - Fee Related CN102296003B (en) | 2011-05-12 | 2011-07-25 | Water-saving detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102296003B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897826A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Novel washing agent |
| CN103897877A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | An efficient detergent |
| CN103897839A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | An environmental-friendly detergent |
| CN103897847A (en) * | 2012-12-27 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Household tableware detergent |
| CN103897830A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Novel safe detergent |
| CN103897851A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Daily nontoxic detergent |
| CN103897859A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Preparation method of novel washing agent |
| CN104629919A (en) * | 2013-11-15 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Pollution-free cleaning agent |
| CN104651068A (en) * | 2013-11-19 | 2015-05-27 | 青岛锦涟鑫商贸有限公司 | A cleaning agent for removing residual pesticides on fruit and vegetable |
| CN103834485A (en) * | 2014-03-18 | 2014-06-04 | 严明东 | Flush toilet cleaner |
| CN104430327A (en) * | 2014-11-26 | 2015-03-25 | 金科 | Ampholytic surfactant composition |
| CN109957479A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | One kind being suitable for fire-entry suit high grease soil detergent and preparation method thereof |
| CN108857856A (en) * | 2018-07-23 | 2018-11-23 | 宁波江丰电子材料股份有限公司 | CMP fixed ring cleaning method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000336392A (en) * | 1999-05-25 | 2000-12-05 | Lion Corp | Liquid detergent composition |
| JP2005255708A (en) * | 2004-03-09 | 2005-09-22 | Teepol Diversey Kk | Condensed neutral detergent composition |
| US20050201965A1 (en) * | 2004-03-11 | 2005-09-15 | The Procter & Gamble Company | Personal cleansing compositions |
| JP4424037B2 (en) * | 2004-03-31 | 2010-03-03 | 日油株式会社 | Cleaning composition |
| CN1272420C (en) * | 2004-09-30 | 2006-08-30 | 霍纪功 | Dirt detergent |
-
2011
- 2011-07-25 CN CN2011102088545A patent/CN102296003B/en not_active Expired - Fee Related
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| CN102296003A (en) | 2011-12-28 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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Effective date of registration: 20160222 Address after: 052160 Gaocheng City, Hebei province Lian Zhou Zhen Dong Jie Cun Wen Yuan Lu Wenxuan Hutong No. 8 Patentee after: Du Jingyu Address before: 052165 No. 8 Yangzi Road West, Shijiazhuang economic and Technological Development Zone, Hebei, China Patentee before: Shijiazhuang Wilubo Daily Chemical Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120919 Termination date: 20160725 |
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| CF01 | Termination of patent right due to non-payment of annual fee |