CN102296003A - Water-saving detergent - Google Patents
Water-saving detergent Download PDFInfo
- Publication number
- CN102296003A CN102296003A CN 201110208854 CN201110208854A CN102296003A CN 102296003 A CN102296003 A CN 102296003A CN 201110208854 CN201110208854 CN 201110208854 CN 201110208854 A CN201110208854 A CN 201110208854A CN 102296003 A CN102296003 A CN 102296003A
- Authority
- CN
- China
- Prior art keywords
- water
- anion surfactant
- nonionogenic tenside
- amphoterics
- stir
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 27
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 17
- -1 polyoxypropylene Polymers 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N monoethyl amine Natural products CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 229940055577 oleyl alcohol Drugs 0.000 claims description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 238000005202 decontamination Methods 0.000 abstract description 4
- 230000003588 decontaminative effect Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 29
- 239000004744 fabric Substances 0.000 description 7
- 239000000835 fiber Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000013042 solid detergent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RZEWIYUUNKCGKA-UHFFFAOYSA-N 2-(2-hydroxyethylamino)ethanol;octadecanoic acid Chemical compound OCCNCCO.CCCCCCCCCCCCCCCCCC(O)=O RZEWIYUUNKCGKA-UHFFFAOYSA-N 0.000 description 1
- LQPUCRPHHIWEMI-UHFFFAOYSA-N C(CCCCCCCCCCC)C(C#N)(C)N.[Na] Chemical compound C(CCCCCCCCCCC)C(C#N)(C)N.[Na] LQPUCRPHHIWEMI-UHFFFAOYSA-N 0.000 description 1
- GRFKSWLHWQPHNN-UHFFFAOYSA-N CCCCCCCCCCCCN.CCC(C[Na])O Chemical compound CCCCCCCCCCCCN.CCC(C[Na])O GRFKSWLHWQPHNN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 description 1
- 229920000784 Nomex Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000004763 nomex Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a water-saving detergent which comprises by weight: 6-15% of anionic surfactant, 1-10% of nonionic surfactant, 1-8% of amphoteric surfactant, 0.2-0.5% of essence, and the balance deionized water. Prepared with surfactants characterized by high efficiency, mild decontamination, high solubility in water and easy rinsing, the detergent of the invention has the advantages of environmental protection, water saving, easy rinsing and no residue, etc.
Description
Technical field
The present invention relates to a kind of washing composition, particularly a kind of water-saving washing composition.
Background technology
When being stained with dirt on the clothing that we wear or use, meeting and clothing produce certain bonding force, can not remove automatically easily.At this moment just need be removed with the method for washing.The medium of washing usefulness is water normally, if dirt is water miscible, uses a large amount of water repetitive scrubbings so, just can decontamination.But a lot of dirts are butyrous, at this moment just need be by washing composition (mainly be by wherein tensio-active agent) with they removals.When will having the soiled clothes of dirt, we are immersed in the washings, hydrophobic in the tensio-active agent (oleophylic) part be easy to attached to dirt or greasy on, and hydrophilic segment aligns towards water, makes to be not easy originally by getting wet easily of becoming of the dirty fiber surface of water-wet and wetted.Be adsorbed onto the synthetic detergent on fiber and the dirt, also expand because of producing a large amount of bubbles, washings is further infiltrated wherein because of the surface tension that has reduced water makes fiber and dirt.With suitable mechanical force, as hand rubbing, or the agitation wheel for washing machine stirring, those lax dirt particles can be disperseed and be come off in water.
The kind of washing composition is a lot, solid detergent, powder washing composition, liquid washing agent etc. are arranged, but solid detergent and powder washing composition form the inflammable settling of one deck on the surface of clothes easily, influence permeability, and soap and washing powder itself is alkaline material, can cause damage to fabric fibre.Some special clothings, what put out a fire that protective clothing adopts as novel fire fighter is four-layer structure, internal layer is made of chemical films Compound Fabric, Nomex and the multilayers such as Kevlar non-woven material and lining of waterproof and breathable, because of waterproof ventilated membrane geology approaches, so intensity and wear resistance are lower than general cloth, during cleaning, need to separate cleaning separately with the coat of fighting uniform, the washing water temperature should not surpass 40oC; As using soap or soap powder washing, soap and soap powder form the inflammable settling of one deck on the surface of clothes easily, influence flame retardant effect and permeability; The decontamination of use chlorinated lime damages the flame retardant properties of material easily and influences the fastness and the weather resistance of fiber.Chinese patent CN1708576A discloses a kind of liquid laundry detergent, the liquid vehicle that this washing composition comprises at least a detergent ingredients, forms cationic polymers, one or more fabric nursing compositions of coacervate phase and be used to provide cleaning and fabric care benefit effect also comprises washing assistant and enzyme.The adding of washing assistant can reach good washing effect for the matching surface promoting agent in this washing composition, but detergent builder are difficult for rinsing, and the rinsing water amount is big, and the discharging of washing assistant can destroy ecology and contaminate environment.So the washing composition of exploitation water-saving and environmental protection is imperative.
Summary of the invention
The technical problem to be solved in the present invention provide have water-saving efficient, the easy a kind of water-saving washing composition of advantage such as rinsing and noresidue.The weight percent of washing composition of the present invention consists of:
Anion surfactant 6-15%;
Nonionogenic tenside 1-10%;
Amphoterics 1-8%;
Essence 0.2-0.5%;
Deionized water is a surplus;
Wherein, the weight percent of described anion surfactant consists of: the carboxylate derivatives AEC-400 3-67% of natural phant oleyl alcohol polyoxypropylene, polyoxyethylene ether block copolymers, sulfonate type anion surfactant 0-97%, sulfuric acid type anion surfactant 0-97%;
Described nonionogenic tenside is polyoxyethylene-type nonionogenic tenside and/or alkylol amide type nonionogenic tenside;
Described amphoterics is one or more in amino acid type amphoteric surface active agent, betaine type amphoteric surfac-tant and the octadecyl dihydroxy ethyl amine oxide.
Described washing composition is by following prepared:
In the deionized water of (30～70) ℃, add selected anion surfactant, stir (2～5) h to evenly; (30～40) ℃ adding nonionogenic tenside stirs (0.5～2) h to even; (30～40) ℃ adding amphoterics stirs (0.5～2) h to even; At (30～40) ℃ adding essence, stir, make product.
Wherein, anion surfactant AEC-400 is colourless to weak yellow liquid, is the carboxylate derivatives of natural phant oleyl alcohol polyoxypropylene, polyoxyethylene ether block copolymers, and chemical structural formula is R (CH
2CH
2CH
2O)
n(CH
2CH
2O)
m(CH
2CH
2CH
2O)
nCOOM (R is unsaturated straight-chain paraffin, and M is a metal ion), fully biodegradable is a kind of anion surfactant of unique properties, has excellent easy rinsing performance, can significantly eliminate the foam of fabric during rinsing.The present invention adopts AEC-400 and other surfactant compounds, by Study on compatibility and machine washing characteristic analysis to material, filter out scientific formula, compare with washing powder, it is residual on clothing to have reduced Betengent product, and high alkalinity is to the infringement of fabric fibre, easier rinsing, reduce residually, meet water saving, environment-friendly type washing composition that national industrial policies require, be particularly useful for turnout gear and clean.
Adopt the beneficial effect that technique scheme produced to be:
1, stronger decontamination, emulsification, degreasing, low bubble performance after utilizing negatively charged ion and nonionogenic tenside composite, and the mildness of amphoterics synergy, obtain a stable ionic system, have good water-saving function simultaneously, be applicable to the washing of general family and bunker clothing; Cleaning, water saving are once finished, and nontoxic, non-stimulated, have saved use cost.
2, the adding of anion surfactant AEC-400 strengthens the dispersion and the suspending power of dirt, the liquid greasy dirt that splits away off on the article surface can be emulsified into little oil droplet and dispersion suspension in water; The effect of the collaborative amphoterics of nonionogenic tenside, make oil-water interface charged and stop oil droplet and poly-, increase its stability in water and stop soil redeposition in the clothing surface.
3, to entering the solid dirt of aqueous phase, because of there is like charges in the dirt surface, when its near the time produce electrostatic repulsion and improved the dispersion stabilization of solid dirt in water; The adding of nonionic surface active agent produces by long aquation polyoxyethylene chain and sterically hinderedly to make greasy dirt and solid soil dispersion and be stable in the water.
4, anion surfactant AEC-400 can change foam property, significantly eliminates the foam during the rinsing, reduces the rinsing number of times, reaches the purpose of water saving.
5, need not add washing assistant such as potassium pyrophosphate, Trisodium Citrate etc., be easy to biological degradation, can not exert an influence simultaneously permeability; Be particularly useful for turnout gear, can the flame retardant effect of fighting uniform do not exerted an influence.
6,,, soil-removing action is efficiently arranged also even when pH be neutrality because the adding of anion surfactant AEC-400.
Embodiment
Embodiment 1
(1) anion surfactant: AEC-400 40.2g, lauric alcohol sodium sulfate 9g, Sodium dodecylbenzene sulfonate 10.8g;
(2) nonionogenic tenside: Tween-40 100g;
(3) amphoterics: AMONYL 380LC 30g, octadecyl dihydroxy ethyl amine oxide 50g;
(4) essence 3g;
(5) deionized water 757g;
In 40 ℃ deionized water, add selected anion surfactant, stir 2h to even; 35 ℃ add nonionogenic tenside, stir 0.5h to even; 35 ℃ add amphoterics, stir (0.5～2) h to even; At (30～40) ℃ adding essence, stir, make product.
Embodiment 2
(1) anion surfactant: AEC-400 4.5g, Sodium dodecylbenzene sulfonate 145.5g;
(2) nonionogenic tenside: cocinic acid diethanolamine 30g;
(3) amphoterics: Varion CDG-K 10g;
(4) essence 2g;
(5) deionized water 808g;
In 65 ℃ deionized water, add selected anion surfactant, stir 3h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 2h to even; 30 ℃ add essence, stir, and make product.
Embodiment 3
(1) anion surfactant: AEC-400 4.5g, dodecyl polyethenoxy ether sodium sulfate 145.5g;
(2) nonionogenic tenside: Tween-60 20g, lauric acid diethyl amide 20g;
(3) amphoterics: sodium dodecyl aminopropionitrile 30g, dodecyl dimethyl azochlorosulfonate propyl lycine 10g;
(4) essence 5g;
(5) deionized water 765g;
In 60 ℃ deionized water, add selected anion surfactant, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Embodiment 4
(1) anion surfactant: AEC-400 15g, Aerosol OT 50g, methyl sodiosul foaliphatate 35g;
(2) nonionogenic tenside: Tween-80 10g;
(3) amphoterics: laurylamide ethyl-hydroxyethyl Sodium glycocollate 30g, octadecyl dihydroxy ethyl amine oxide 50g;
(4) essence 5g;
(5) deionized water 805g;
In 70 ℃ deionized water, add selected anion surfactant, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Embodiment 5
(1) anion surfactant: AEC-400 30g, methyl sodiosul foaliphatate 45g, Sodium palmityl sulfate 45g;
(2) nonionogenic tenside: Stearic acid diethanolamine salt 50g;
(3) amphoterics: dodecyl oxyethyl group sultaine 30g;
(4) essence 4g;
(5) deionized water 796g;
In 70 ℃ deionized water, add selected anion surfactant, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Embodiment 6
(1) anion surfactant: AEC-400 40g, Sodium dodecylbenzene sulfonate 20g, lauric alcohol sodium sulfate 20g;
(2) nonionogenic tenside: Tween-40 40g; Tween-80 30g;
(3) amphoterics: AMONYL 380LC 50g, Varion CDG-K 10g;
(4) essence 3g;
(5) deionized water 787g;
In 70 ℃ deionized water, add selected anion surfactant, stir 2.5h to even; 35 ℃ add nonionogenic tenside, stir 2h to even; 35 ℃ add amphoterics, stir 1h to even; Add essence at 30 ℃, stir, make product.
Claims (1)
1. water-saving washing composition is characterized in that the weight percent of described washing composition consists of:
Anion surfactant 6-15%;
Nonionogenic tenside 1-10%;
Amphoterics 1-8%;
Essence 0.2-0.5%;
The deionized water surplus;
The weight percent of described anion surfactant consists of: the carboxylate derivatives AEC-400 3-67% of natural phant oleyl alcohol polyoxypropylene, polyoxyethylene ether block copolymers, sulfonate type anion surfactant 0-97%, sulfuric acid type anion surfactant 0-97%;
Described nonionogenic tenside is polyoxyethylene-type nonionogenic tenside and/or alkylol amide type nonionogenic tenside;
Described amphoterics is one or more in amino acid type amphoteric surface active agent, betaine type amphoteric surfac-tant and the octadecyl dihydroxy ethyl amine oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102088545A CN102296003B (en) | 2011-05-12 | 2011-07-25 | Water-saving detergent |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110122473 | 2011-05-12 | ||
| CN201110122473.5 | 2011-05-12 | ||
| CN2011102088545A CN102296003B (en) | 2011-05-12 | 2011-07-25 | Water-saving detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102296003A true CN102296003A (en) | 2011-12-28 |
| CN102296003B CN102296003B (en) | 2012-09-19 |
Family
ID=45356681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102088545A Expired - Fee Related CN102296003B (en) | 2011-05-12 | 2011-07-25 | Water-saving detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102296003B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834485A (en) * | 2014-03-18 | 2014-06-04 | 严明东 | Flush toilet cleaner |
| CN103897847A (en) * | 2012-12-27 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Household tableware detergent |
| CN103897859A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Preparation method of novel washing agent |
| CN103897877A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | An efficient detergent |
| CN103897830A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Novel safe detergent |
| CN103897826A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Novel washing agent |
| CN103897851A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Daily nontoxic detergent |
| CN103897839A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | An environmental-friendly detergent |
| CN104430327A (en) * | 2014-11-26 | 2015-03-25 | 金科 | Ampholytic surfactant composition |
| CN104629919A (en) * | 2013-11-15 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Pollution-free cleaning agent |
| CN104651068A (en) * | 2013-11-19 | 2015-05-27 | 青岛锦涟鑫商贸有限公司 | A cleaning agent for removing residual pesticides on fruit and vegetable |
| CN108857856A (en) * | 2018-07-23 | 2018-11-23 | 宁波江丰电子材料股份有限公司 | CMP fixed ring cleaning method |
| CN109957479A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | One kind being suitable for fire-entry suit high grease soil detergent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000336392A (en) * | 1999-05-25 | 2000-12-05 | Lion Corp | Liquid detergent composition |
| CN1616627A (en) * | 2004-09-30 | 2005-05-18 | 霍纪功 | Dirt detergent |
| WO2005093028A1 (en) * | 2004-03-09 | 2005-10-06 | Johnsondiversey, Inc. | Concentrated neutral detergent composition |
| JP2005281640A (en) * | 2004-03-31 | 2005-10-13 | Nof Corp | Detergent composition |
| CN1929812A (en) * | 2004-03-11 | 2007-03-14 | 宝洁公司 | Personal cleansing compositions |
-
2011
- 2011-07-25 CN CN2011102088545A patent/CN102296003B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000336392A (en) * | 1999-05-25 | 2000-12-05 | Lion Corp | Liquid detergent composition |
| WO2005093028A1 (en) * | 2004-03-09 | 2005-10-06 | Johnsondiversey, Inc. | Concentrated neutral detergent composition |
| CN1929812A (en) * | 2004-03-11 | 2007-03-14 | 宝洁公司 | Personal cleansing compositions |
| JP2005281640A (en) * | 2004-03-31 | 2005-10-13 | Nof Corp | Detergent composition |
| CN1616627A (en) * | 2004-09-30 | 2005-05-18 | 霍纪功 | Dirt detergent |
Non-Patent Citations (2)
| Title |
|---|
| 《日用化学工业》 19821231 姜柏青 等 "烷基磺酸钠金和烷基苯磺酸钠在酸性介质中的消泡和缓蚀效率的研究" 第14-17页 1 , 第4期 * |
| 《河北化工》 19991231 杜宝石 "高级羊绒洗涤剂的研制" 第14-15页 1 , 第1期 * |
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| CN109957479A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | One kind being suitable for fire-entry suit high grease soil detergent and preparation method thereof |
| CN108857856A (en) * | 2018-07-23 | 2018-11-23 | 宁波江丰电子材料股份有限公司 | CMP fixed ring cleaning method |
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