CN1584141A - Composite electric conductive fibers coloreld at original liquid - Google Patents
Composite electric conductive fibers coloreld at original liquid Download PDFInfo
- Publication number
- CN1584141A CN1584141A CN 200410044897 CN200410044897A CN1584141A CN 1584141 A CN1584141 A CN 1584141A CN 200410044897 CN200410044897 CN 200410044897 CN 200410044897 A CN200410044897 A CN 200410044897A CN 1584141 A CN1584141 A CN 1584141A
- Authority
- CN
- China
- Prior art keywords
- original liquid
- cortex
- composite conducting
- feature
- liquid coloring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 55
- 239000007788 liquid Substances 0.000 title claims abstract description 16
- 239000002131 composite material Substances 0.000 title claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 229920000728 polyester Polymers 0.000 claims abstract description 25
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 7
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 5
- 239000010439 graphite Substances 0.000 claims abstract description 5
- 238000004040 coloring Methods 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 18
- 239000011148 porous material Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- -1 polyethylene terephthalate Polymers 0.000 claims description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 9
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 6
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical compound OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 4
- 238000004043 dyeing Methods 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 238000007639 printing Methods 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 2
- 238000012805 post-processing Methods 0.000 claims description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 2
- 150000003504 terephthalic acids Chemical class 0.000 claims description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000009941 weaving Methods 0.000 abstract description 2
- 239000012792 core layer Substances 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 2
- 239000003610 charcoal Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 229910021392 nanocarbon Inorganic materials 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 17
- 238000010304 firing Methods 0.000 description 9
- LLYXJBROWQDVMI-UHFFFAOYSA-N 2-chloro-4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1Cl LLYXJBROWQDVMI-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229910001361 White metal Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical group 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- 239000010969 white metal Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Multicomponent Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
The invention relates to weaving industry, that is, a kind of effective electric fiber colored by original liquid. It contains core layer and cortex, and the core layer is polyester containing 2-60%(w) electric components, and the cortex is made of non-electric components involving non-electric fiber polyester. The cortex contains 1-10% colorant, 2-10% light-shielded agent, and 1-8% hole-forming agent. The electric component of core layer is electric charcoal or nano-carbon or nano-graphite or electric metal oxide. The polyester in core layer is benzene twin-formyl glycol ester. The invention adopts refining mixedly to obtain the production that detract 2-60% electric atom inbenzene twin-formyl glycol ester. It can remain the color of the electric fiber as the same of its production by using this invention.
Description
Technical field
The present invention relates to textile industry, specifically a kind of conductive fiber that utilizes original liquid coloring.
Background technology
Polyester fiber, pet fiber particularly, has excellent performance at aspects such as DIMENSIONAL STABILITY, heat resistance and resistances to chemical reagents, and be widely used in dress material and industrial circle, but because its hygroscopicity is poor, the friction back easily produces static (bringing electrostatic hazard, as spark discharge and dust suction) and is subjected to certain restriction.Other textile fabrics such as polyamide fibre, wool etc. also easily produce static in addition.
The effective measures that solve electrostatic hazard in the past are to add the electrically conductive composite fibre that a spot of polymer that is dispersed with conductive carbon black constitutes in textile fabrics, thereby reach permanently antistatic.This method is mainly used in carpet, the dust-free sterile clothes of electronics pharmaceuticals industry, the antistatic protective clothing of petroleum chemical industry and the occasion that some are relatively more responsive to static.But because conductive carbon black is a black, also present certain secret note, influenced the use field and cause conductive fiber to be black, textile fabrics; The white conductive fiber that adopts light color or white metal oxide conducting powder is also arranged in addition, but because its host material is terylene, nylon etc., be not quite similar, thereby still have color distortion during dyeing with the base material of weaving face fabric.
Summary of the invention
The objective of the invention is to seek a kind of original liquid coloring composite conducting fiber, so that make the color of conductive fiber consistent with the color and luster of made goods.
At the problems referred to above, the present invention will be how consistent with the color and luster of made goods research topic the color of conductive fiber, find through studying intensively the back, adopt core-skin composite spinning silk method, after adding colouring agent, photomask agent and pore former in the cortex component at conductive fiber, just can be made into well behaved coloured conductive fiber, and can be according to the color of colouring agent, the color that content changes conductive fiber, make the scope of application of conductive fiber wider, and COLOR FASTNESS further improve.
According to design provided by the present invention, this composite conducting fiber is made up of the sandwich layer cortex outer with being coated on sandwich layer, sandwich layer wherein is the polyester that contains 2～60% electric conductivity composition, cortex is that non-conductive one-tenth is grouped into, and non-conductive composition is made of dielectric fiber-grade polyester polymer.
In the cortex component, contain 1～10% colouring agent, 2～10% photomask agent and 1～8% pore former; The electric conductivity composition that contains in the sandwich layer component is conductive carbon black or CNT or nano-graphite or conductive metal oxide, the polyester that contains in the sandwich layer component is the polyester polymers based on the repeating segment of ethylene glycol terephthalate, and utilize mixing mode, electrically conductive microparticle to be scattered in the polyester polymers based on the repeating segment of ethylene glycol terephthalate to form with 2～60%.
The invention relates to the original liquid coloring composite conducting fiber that conductive component and non-conductive component form through the conjugation composite spinning.Wherein the electric conductivity composition is the polyester of main repeating segment by ethylene glycol terephthalate, disperses the particles such as conductive carbon black, graphite, CNT, metal oxide of 2～60%wt to form by compounding process; But not conductive compositions then is made up of the polyester that has added colouring agent, pore former, photomask agent in the dielectric fiber-grade polyester, prepared conductive fiber after the printing and dyeing post processing, its than resistance less than 10
6Ω cm, fibrocortex produces micropore, has reduced the firing potential of conductive fiber.
The polymer of the electric conductivity component that the present invention is used is made up of dicarboxylic acids (based on the derivative of terephthalic acid (TPA) or terephthalate) and the formed thermoplasticity polymer of dihydroxylic alcohols (based on ethylene glycol, butanediol), it is arbitrarily that such polyester polymers is selected, but from the spinnability angle, preferably select into fine molded lines polymer for use, M-phthalic acid etc. is arranged as the dicarboxylic acids composition of copolymerization.
Glycol component as copolymerization has: 1, and 4-butanediol, polyethylene glycol etc.
Used electroconductive particle has conductive carbon black, graphite, CNT and metal oxide etc. among the present invention, and, if above-mentioned substance is lower than 10 than resistance when pulverulence
4Ω cm all can use.The electric conductivity of electroconductive particle, it is desirable to powder than resistance 10
4Below the Ω cm, particularly 10
2Ω cm is preferably 10
1Below the Ω cm.In fact than resistance 10
2～10
-2The electroconductive particle of Ω cm all is suitable for the present invention.Certainly electric conductivity is high more good more.
The particle diameter of electroconductive particle must be quite little, and the average grain diameter of used particle is below 1 μ m usually, and especially below 0.5 μ m, optimal is below the 0.3 μ m.
The mode that electroconductive particle is added into polymer can adopt method mixing under molten condition to realize, but this method can only reach the purpose of dispersion, also can add a spot of incremental dose in order to improve its flowability, (as plasticizer, coupling agents etc.), the addition of electroconductive particle is according to its kind, electric conductivity, the character of chain lock construction and polymer such as crystallinity etc. are different and different, but all in 2～60% scope.
Constitute the non-conductive polyester of the cortex component of fiber of the present invention, all linear all can using, as polyethylene terephthalate, polybutylene terephthalate (PBT) and copolymer thereof or blend or the like
In the cortex component, can add versicolor colouring agent according to back road user's request, photomask agent, and the auxiliary pore former that increases electric conductivity that adds, the addition of colouring agent is decided on kind, is generally 1～10%, is preferably 2～4%.The addition of photomask agent is 2～10%, is preferably 3～4%, and the addition of pore former is generally 1～8%, is preferably 3～5%.Meeting under the prerequisite of electric conductivity, can improve its spinnability like this.
Also be added with pore former in the cortex component, it act as when finishing process in printing and dye-ing, and the effect by alkaline aqueous solution is dissolved out pore former from cortex, generates micropore at cortex, the conductive component of sandwich layer is linked up with extraneous, thereby improved antistatic performance.Pore former can be inorganic compound such as SiO
2, TiO
2, ZnO.Also can be organic compound such as PVA, COPET, PEG or the like.
Also can add photomask agent in the cortex component in addition, stop the color of sandwich layer to expose.Be generally TiO
2, SiO
2, CaCO
3Or the like.
Fiber of the present invention is made up of cortex component that is added with colouring agent, pore former and photomask agent and the sandwich layer component that contains conducting particles, and core-skin compound (volume) ratio is 10～40%: 90～60%, preferably be controlled at 15～20%: 85～80%.
The specific embodiment
Following examples are done to specify the present invention.Percentage wherein (%) all is weight percentage (wt%) unless otherwise noted, and is basis with the weight of polyester, and the A component is the sandwich layer component, and the B component is the cortex component.
Embodiment 1
With particle diameter is the high conductive carbon black 35% of 20～30 μ m, carries out mixingly with 75% polyethylene terephthalate, makes electroconductive resin, as sandwich layer component A.By after 1 pair of sandwich layer component of screw extruder A melt extruded, be metered into composite spinneret pack after drying with 10g/min;
At screw extruder 2 inlet good 5% the green master batch (solid content 35%) of drying by the Masterbatch syringe, be injected into and contain 5% photomask agent TiO
2, 3% pore former PEG dry polyester slice (being the B component) in, after melt extruded, be metered into composite spinneret pack with 25g/min;
In composite spinneret pack, component A and B component spue from spinneret orifice with cortex and sandwich layer type combined state by distributing, compound ratio is 29%: 71%, under 25 ℃, the condition of 70%RH, cool off, and then the coiling that oils, coiling speed is 3200m/min.Pass through the two-region heat stretching machine again at 85 ℃/185 ℃, draw ratio 1.5 stretches under the draw speed 600m/min, and made conductive fiber fiber number is 35dtex/5f, and fracture strength is 3cN/dtex, and elongation at break is 30%, and resistance is 5.6 * 10
6Ω/cm.Color is green.Firing potential is 1000V.
Conductive powder body is a CNT in the embodiment 2 A component materials, and content is 10%, contains yellow look mother 8% in the B component, photomask agent SiO
22%, pore former COPET5%, all the other are with example 1, and gained conductive fiber fiber number is 35dtex/5f, and fracture strength is 4.0cNdtex, and elongation at break is 35%, resistance is 2 * 10
6Ω/cm.Firing potential is 820V.
The pump of embodiment 3 A components is 20g/min for amount, and the pump of B component is 55g/min for amount, and (being that the compound ratio of core-skin is 69%: 31%) all the other are with example 1.Prepared conductive fiber fiber number is 44dtex/5f, and fracture strength is 2.9cN/dtex, and elongation at break is 40%, and resistance is 1.2 * 10
5Ω/cm.Firing potential is 860V.
Embodiment 4 remove the A component be contain 60%, metal oxide that particle diameter is 0.3 μ m replaces 35% carbon black, and winding speed is 2000m/min, draw ratio is outside 2.8, all the other are with example 1.Gained conductive fiber fiber number is 50dtex/5f as a result, and fracture strength is 2.2cN/dtex, and elongation at break is 60%, and resistance is 3 * 10
8Ω/cm, firing potential are 1000V.
It is that 60% particle diameter is that the metal oxide of 0.5 μ m replaces 35% carbon black, photomask agent CaCO that embodiment 5 removes the A component
3Addition is 2%, pore former ZnO addition be 1% and winding speed be 2000m/min, draw ratio 2.8, outside the draw speed 600m/min, all the other are with example 1, and the fiber number of gained fiber is 50dtex/5f as a result, fracture strength is 2.5cN/dtex, and elongation at break is 65%, and resistance is 1.9 * 10
8Ω/cm, firing potential are 1500V.
Embodiment 6 removes the A component is 30%, particle diameter is 100nm graphite powder, and to replace 35% carbon black and winding speed be 2500m/mi, and outside the drawing-off multiplying power 2.5, other is with example 1.Gained conductive fiber fiber number is 40dtex/5f as a result, and fracture strength is 3.0cN/dtex, and elongation at break is 38%, and resistance is 4.5 * 10
7Ω/cm, firing potential are 800V.
Embodiment 7 is except that the polybutylene terephthalate (PBT) of the A component is 30%, particle diameter is 35nm high conductive carbon black and 70% mixes, and all the other are with embodiment 1.The made conductive fiber fiber number of result is 35dtex/5f, and fracture strength is 3.1cN/dtex, and elongation at break is 35%, and resistance is 3.0 * 10
6Ω/cm.Color is green.Firing potential is 1000V.
Embodiment 8 A components be contain 8%, particle diameter is poly-terephthaldehyde's ester glycol ester of 20nm CNT, the B component is for adding 3% navy master batch, 5% pore former SiO
2, 2% photomask agent CaCO
3Polyethylene terephthalate.The compound ratio of core-skin is 80～20%, and spinning speed is 1000m/min, and the after-drawing multiple is 5.2, and draft temperature is 95/200 ℃, and draw speed is 240m/min.It is 83dtex/24f that the gained conductive fiber gets fiber number, and fracture strength is 6.5cN/dtex, and elongation at break is 25%, and resistance is 6 * 10
6Ω/cm.Color is a navy.
Embodiment 9 A components be contain 30%, particle diameter is the polyethylene terephthalate and the polyethylene glycol isophthalate blend (mixing ratio is 75%: 25%) of the conductive carbon black of 40nm, the B component is a polybutylene terephthalate (PBT), include 3% blue Masterbatch, 2% photomask agent TiO
2With 1.5% pore former PVA.All the other are with embodiment 1, and gained conductive fiber fiber number is 33dtex/5f, and fracture strength is 3.0CN/dtex, and elongation at break is 40%, and resistance is 3.8 * 10
6Ω/cm.Firing potential is 1000V, and color is sky blue.
Claims (10)
1, a kind of original liquid coloring composite conducting fiber is characterized in that, this composite conducting fiber is made up of the sandwich layer cortex outer with being coated on sandwich layer, and sandwich layer wherein is the electric conductivity component, and cortex is non-conductive component; And sandwich layer is the polyester that contains 2～60% electric conductivity composition, and the non-conductive composition in the cortex is made of dielectric fiber-grade polyester polymer.
2, original liquid coloring composite conducting fiber according to claim 1, its feature also be, contains 1～10% colouring agent, 2～10% photomask agent and 1～8% pore former in the cortex component, and all the other are the fiber-grade polyester polymer; Electric conductivity composition in the sandwich layer is conductive carbon black or CNT or nano-graphite or conductive metal oxide, polyester is the polyester polymers based on the repeating segment of ethylene glycol terephthalate, and utilize mixing mode, the electric conductivity composition microparticulate with 2～60% forms in the polyester polymers based on the repeating segment of ethylene glycol terephthalate.
3, original liquid coloring composite conducting fiber according to claim 1, its feature also be, this conductive fiber after the printing and dyeing post processing, its than resistance less than 10
6Ω cm, fibrocortex produces micropore.
4, original liquid coloring composite conducting fiber according to claim 2, its feature also is, in the electric conductivity composition is that the polyester polymers of main repeating segment is made up of dicarboxylic acids and the formed thermoplasticity polymer of dihydroxylic alcohols based on the derivative of terephthalic acid (TPA) or terephthalate with ethylene glycol terephthalate, and the average grain diameter of electric conductivity composition particulate is below 1 μ m.
5, original liquid coloring composite conducting fiber according to claim 4, its feature are that also dicarboxylic acids is a M-phthalic acid; Dihydroxylic alcohols is 1,4-butanediol or polyethylene glycol.
6, original liquid coloring composite conducting fiber according to claim 1, its feature are that also the fiber-grade polyester polymer in the cortex component is polyethylene terephthalate or polybutylene terephthalate (PBT) and copolymer or blend.
7, original liquid coloring composite conducting fiber according to claim 2, its feature are that also pore former is SiO
2Or TiO
2Or ZnO, or PVA or COPET or PEO; Photomask agent is TiO
2Be SiO
2Or CaCO
3
8, original liquid coloring composite conducting fiber according to claim 1, its feature is that also the compositely proportional of cortex and sandwich layer is 10～40%: 60～90%.
9, original liquid coloring composite conducting fiber according to claim 8, its feature is that also the compositely proportional of cortex and sandwich layer is 15～20%: 85～80%.
10, original liquid coloring composite conducting fiber according to claim 2, its feature are that also the addition of colouring agent is 2～4%; The addition of photomask agent is 3～4%; The addition of pore former is 3～5%, and all the other are the fiber-grade polyester polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410044897 CN1245539C (en) | 2004-05-28 | 2004-05-28 | Composite electric conductive fibers coloreld at original liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410044897 CN1245539C (en) | 2004-05-28 | 2004-05-28 | Composite electric conductive fibers coloreld at original liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1584141A true CN1584141A (en) | 2005-02-23 |
| CN1245539C CN1245539C (en) | 2006-03-15 |
Family
ID=34601812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410044897 Expired - Lifetime CN1245539C (en) | 2004-05-28 | 2004-05-28 | Composite electric conductive fibers coloreld at original liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1245539C (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314845C (en) * | 2005-05-26 | 2007-05-09 | 天津工业大学 | Microwave shielding fiber and fabricating method |
| CN101338067B (en) * | 2007-07-04 | 2011-02-16 | 中国纺织科学研究院 | Black polyester chip and method for preparing black polyester chip |
| CN102002848A (en) * | 2010-09-21 | 2011-04-06 | 中国人民解放军总后勤部军需装备研究所 | Metalized fabric base cloth capable of improving attachment fastness of metal coating and preparation method thereof |
| CN102154736A (en) * | 2011-03-28 | 2011-08-17 | 际华三五零六纺织服装有限公司 | Conductive fiber for clothing |
| CN102517683A (en) * | 2011-08-24 | 2012-06-27 | 杭州泛林科技有限公司 | Method for preparing conductive polyester fibers |
| US8216492B2 (en) | 2008-12-08 | 2012-07-10 | Taiwan Textile Research Institute | Conductive masterbatches and conductive monofilaments |
| CN103046155A (en) * | 2012-12-18 | 2013-04-17 | 烟台泰和新材料股份有限公司 | Method for preparing conduction meta-position aramid fibers |
| CN105155024A (en) * | 2015-10-26 | 2015-12-16 | 太仓市双宇化纤有限公司 | Conductive composite fiber material and preparation method thereof |
| CN106757507A (en) * | 2015-11-20 | 2017-05-31 | 北京中纺优丝特种纤维科技有限公司 | A kind of high-performance polyamide fibre base can contaminate conductive fiber and preparation method thereof |
| CN107043961A (en) * | 2016-02-05 | 2017-08-15 | 财团法人纺织产业综合研究所 | Antistatic polyester grain, can dyeing polyester grain and dyeable antistatic sheath-core type conjugate fiber |
| CN107385555A (en) * | 2017-09-19 | 2017-11-24 | 安徽省银锂子生物科技发展有限公司 | A kind of underpants that can thoroughly kill harmful bacteria |
| CN108570228A (en) * | 2018-01-16 | 2018-09-25 | 江苏海阳锦纶新材料有限公司 | A kind of 6 black of polyamide fibre slice and manufacturing method |
| CN110117838A (en) * | 2019-05-27 | 2019-08-13 | 宁波石墨烯创新中心有限公司 | A kind of functional fibre, preparation method and fibre |
| CN110409017A (en) * | 2019-08-12 | 2019-11-05 | 杭州高烯科技有限公司 | A kind of highly conductive brocade washs composite fibre and preparation method thereof |
| CN111155187A (en) * | 2020-01-19 | 2020-05-15 | 浙江纳美新材料股份有限公司 | Conductive black water-based color paste for coloring viscose stock solution and preparation method thereof |
| CN111710872A (en) * | 2008-11-18 | 2020-09-25 | Cps科技控股有限公司 | Electrical energy storage device |
-
2004
- 2004-05-28 CN CN 200410044897 patent/CN1245539C/en not_active Expired - Lifetime
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314845C (en) * | 2005-05-26 | 2007-05-09 | 天津工业大学 | Microwave shielding fiber and fabricating method |
| CN101338067B (en) * | 2007-07-04 | 2011-02-16 | 中国纺织科学研究院 | Black polyester chip and method for preparing black polyester chip |
| CN111710872A (en) * | 2008-11-18 | 2020-09-25 | Cps科技控股有限公司 | Electrical energy storage device |
| US8216492B2 (en) | 2008-12-08 | 2012-07-10 | Taiwan Textile Research Institute | Conductive masterbatches and conductive monofilaments |
| CN102002848A (en) * | 2010-09-21 | 2011-04-06 | 中国人民解放军总后勤部军需装备研究所 | Metalized fabric base cloth capable of improving attachment fastness of metal coating and preparation method thereof |
| CN102154736A (en) * | 2011-03-28 | 2011-08-17 | 际华三五零六纺织服装有限公司 | Conductive fiber for clothing |
| CN102517683A (en) * | 2011-08-24 | 2012-06-27 | 杭州泛林科技有限公司 | Method for preparing conductive polyester fibers |
| CN103046155B (en) * | 2012-12-18 | 2016-03-23 | 烟台泰和新材料股份有限公司 | The preparation method of conduction meta-aramid fibers |
| CN103046155A (en) * | 2012-12-18 | 2013-04-17 | 烟台泰和新材料股份有限公司 | Method for preparing conduction meta-position aramid fibers |
| CN105155024A (en) * | 2015-10-26 | 2015-12-16 | 太仓市双宇化纤有限公司 | Conductive composite fiber material and preparation method thereof |
| CN106757507A (en) * | 2015-11-20 | 2017-05-31 | 北京中纺优丝特种纤维科技有限公司 | A kind of high-performance polyamide fibre base can contaminate conductive fiber and preparation method thereof |
| CN106757507B (en) * | 2015-11-20 | 2019-02-22 | 北京中纺优丝特种纤维科技有限公司 | A kind of high-performance polyamide fibre base can contaminate conductive fiber and preparation method thereof |
| CN107043961A (en) * | 2016-02-05 | 2017-08-15 | 财团法人纺织产业综合研究所 | Antistatic polyester grain, can dyeing polyester grain and dyeable antistatic sheath-core type conjugate fiber |
| CN107385555A (en) * | 2017-09-19 | 2017-11-24 | 安徽省银锂子生物科技发展有限公司 | A kind of underpants that can thoroughly kill harmful bacteria |
| CN108570228A (en) * | 2018-01-16 | 2018-09-25 | 江苏海阳锦纶新材料有限公司 | A kind of 6 black of polyamide fibre slice and manufacturing method |
| CN110117838A (en) * | 2019-05-27 | 2019-08-13 | 宁波石墨烯创新中心有限公司 | A kind of functional fibre, preparation method and fibre |
| CN110409017A (en) * | 2019-08-12 | 2019-11-05 | 杭州高烯科技有限公司 | A kind of highly conductive brocade washs composite fibre and preparation method thereof |
| CN110409017B (en) * | 2019-08-12 | 2022-01-14 | 杭州高烯科技有限公司 | High-conductivity polyamide-polyester composite fiber and preparation method thereof |
| CN111155187A (en) * | 2020-01-19 | 2020-05-15 | 浙江纳美新材料股份有限公司 | Conductive black water-based color paste for coloring viscose stock solution and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1245539C (en) | 2006-03-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1245539C (en) | Composite electric conductive fibers coloreld at original liquid | |
| EP3626758B1 (en) | Graphene composite material and preparation method therefor | |
| US5776608A (en) | Process for making electrically conductive fibers | |
| CN102108566B (en) | Antistatic type composite flame retardant fiber and preparation method thereof | |
| US8216492B2 (en) | Conductive masterbatches and conductive monofilaments | |
| EP3819410A2 (en) | Plant-based functional polyester filament and preparation method thereof | |
| KR19990064112A (en) | Conductive polymer composition | |
| CN105002595A (en) | Polymer composite function fibers containing partial graphene, and preparation method thereof | |
| CN101358387A (en) | White composite electric conductive fiber | |
| CN105780190A (en) | Macromolecular composite antistatic fiber | |
| CN112127005A (en) | Polyester filament yarn and preparation process thereof | |
| JP4367038B2 (en) | Fiber and fabric | |
| CN108728924B (en) | Halogen-free flame-retardant reinforced nylon 66 nano fiber and preparation method thereof | |
| CN102031588B (en) | Durable carbon black conductive fiber and preparation method thereof | |
| CN106894225A (en) | Graphene coated composite construction conductive fiber and preparation method thereof | |
| US20050124744A1 (en) | Modified polyolefin fibres | |
| DE69318789T2 (en) | Process for the production of polyamides with reduced flammability | |
| JP3791919B2 (en) | Polypropylene conductive composite fiber and method for producing the same | |
| KR101058203B1 (en) | White antistatic and antibacterial fiber containing acicular zinc oxide single crystal | |
| Aslan et al. | Influence of spinning velocity on mechanical and structural behavior of PET/nylon 6 fibers | |
| DE2700436A1 (en) | CONDUCTIVE CORE-COAT FEDES AND THEIR USE | |
| CN117552127A (en) | Parallel multidimensional curled PET/PA6 double-component antistatic antibacterial fiber and preparation method thereof | |
| JPS6240444B2 (en) | ||
| JP3210787B2 (en) | Conductive mixed yarn | |
| JPS63270811A (en) | Electrically conductive composite fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: JIANGSU TEXTILE INSTITUTE CO., LTD. Free format text: FORMER NAME: JIANGSU PROV. TEXTILE INST. CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 214104 No. 706 Jincheng Road, Nanchang District, Jiangsu, Wuxi Patentee after: JIANGSU TEXTILE RESEARCH INSTITUTE Co.,Ltd. Address before: 214024 Jiangsu city of Wuxi Province Jincheng West Ramp Bridge Patentee before: JIANGSU PROVINCE TEXTILE RESEARCH INSTITUTE Co.,Ltd. |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20060315 |