CN108570228A - A kind of 6 black of polyamide fibre slice and manufacturing method - Google Patents

A kind of 6 black of polyamide fibre slice and manufacturing method Download PDF

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Publication number
CN108570228A
CN108570228A CN201810041306.XA CN201810041306A CN108570228A CN 108570228 A CN108570228 A CN 108570228A CN 201810041306 A CN201810041306 A CN 201810041306A CN 108570228 A CN108570228 A CN 108570228A
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CN
China
Prior art keywords
carbon black
black
polyamide fibre
internal layer
section
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810041306.XA
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Chinese (zh)
Inventor
陈亮
丁峰
朱德骅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Haiyang Technology Co., Ltd
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Jiangsu Haiyang Polyamide New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Haiyang Polyamide New Material Co Ltd filed Critical Jiangsu Haiyang Polyamide New Material Co Ltd
Priority to CN201810041306.XA priority Critical patent/CN108570228A/en
Publication of CN108570228A publication Critical patent/CN108570228A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Artificial Filaments (AREA)

Abstract

The present invention provides a kind of 6 black of polyamide fibre slice, additionally provides a kind of 6 black of polyamide fibre slice manufacturing method, and 6 black of the polyamide fibre is sliced, including:Outer layer, internal layer, carbon black particle, the outer layer are connected with inner compact layer, and the carbon black particle is in internal layer;The internal layer is carbon black chinlon 6 section;The outer layer is chinlon 6 section;The proportional region of the outer layer and the cross-sectional diameter of the internal layer is 1:8 to 8:1;The slice cross section is rectangle, ellipse, circle or triangle;The carbon black quality accounts for the percentage of the internal layer quality ranging from:0.02%‑30%.The present invention has the beneficial effect that:1)Carbon black is unaffected when subsequent technique needs white colouring or light color in internal layer;2)Carbon black good light stability, under illumination condition, black slice is than common slice longer life expectancy.

Description

A kind of 6 black of polyamide fibre slice and manufacturing method
Technical field
The present invention relates to polyamide fibre field, more particularly to a kind of 6 black of polyamide fibre slice and manufacturing method.
Background technology
The chemico-physical properties and polyamide fibre 66 of polyamide fibre 6 are much like, however, its fusing point is relatively low, and Process temperature ranges It is very wide.Its impact resistance and antilysis is got well than 66 plastics of polyamide fibre, but hygroscopicity is also stronger.
Current chinlon 6 section is commonly milky and Transparent color, and 6 black of polyamide fibre slice will not be received substantially under illumination condition To influence, the service life is longer, there are no the report of research and development or the production of black slice at home.
Invention content
It is an object of the invention to propose a kind of 6 black of polyamide fibre slice, have many advantages, such as simple in structure, applied widely.
To achieve the goals above, the present invention provides a kind of 6 black of polyamide fibre slice, including:Outer layer, internal layer, carbon black particle, The outer layer is connected with inner compact layer, and the carbon black particle is in internal layer.
Further, the internal layer is carbon black chinlon 6 section.
Further, the outer layer is chinlon 6 section.
Further, the proportional region of the outer layer and the cross-sectional diameter of the internal layer is 1:8 to 8:1.
Further, the slice cross section is rectangle, ellipse, circle or triangle.
Further, the carbon black quality accounts for the percentage of the internal layer quality ranging from:0.02%-30%.
The present invention also provides a kind of 6 black of polyamide fibre to be sliced manufacturing method, and steps are as follows:
Carbon black particle is provided;
The carbon black particle is mixed with chinlon 6 section, carbon black chinlon 6 section is made;
Using the carbon black chinlon 6 section as internal layer, composite junction is obtained by spinning and processing using chinlon 6 section as outer layer 6 black of polyamide fibre of structure is sliced.
Further, providing carbon black particle step includes:
Dispersant, carbon black particle and particle dressing agent are sequentially added in a solvent;
To the solution obtained by the substance that is added every time, disperseed by dispersing technology, obtains modification carbon black dispersion;
By modification carbon black dispersion filtering, drying and grinding, modification carbon black particle is made.
The present invention has the beneficial effect that:1)Carbon black is in internal layer, when subsequent technique needs white colouring or light color, not by shadow It rings;2)Carbon black good light stability, under illumination condition, black slice is than common slice longer life expectancy.
Description of the drawings
Fig. 1 is that 6 black of polyamide fibre of the present invention is sliced schematic diagram;
Wherein:1 it is outer layer, 2 be internal layer, 3 is carbon black particle.
Specific implementation mode
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, it is intended to for explaining the present invention, and is not considered as limiting the invention.
Embodiment 1:
As shown in Figure 1, the present invention provides a kind of 6 black of polyamide fibre slice, including:Outer layer 1, internal layer 2, carbon black particle 3, the outer layer 1 and the fine and close connection of internal layer 2, the carbon black particle 3 is in internal layer 2.
Wherein, the internal layer 2 is carbon black chinlon 6 section.
Wherein, the outer layer 1 is chinlon 6 section.
Wherein, the proportional region of the outer layer 1 and the cross-sectional diameter of the internal layer 2 is 1:2.
Wherein, the slice cross section is rectangle.
Wherein, 3 mass of the carbon black particle accounts for ranging from the 0.02% of the percentage of 2 mass of the internal layer.
The present invention also provides a kind of 6 black of polyamide fibre to be sliced manufacturing method, and steps are as follows:
Carbon black particle 3 is provided;
The carbon black particle 3 is mixed with chinlon 6 section, carbon black chinlon 6 section is made;
Using the carbon black chinlon 6 section as internal layer 2, obtained compound by spinning and processing using chinlon 6 section as outer layer 1 6 black of polyamide fibre of structure is sliced.
Further, providing 3 step of carbon black particle includes:
Dispersant, carbon black particle and particle dressing agent are sequentially added in a solvent;
To the solution obtained by the substance that is added every time, disperseed by dispersing technology, obtains modification carbon black dispersion;
By modification carbon black dispersion filtering, drying and grinding, modification carbon black particle 3 is made.
Embodiment 2:
As shown in Figure 1, the present invention provides a kind of 6 black of polyamide fibre slice, including:Outer layer 1, internal layer 2, carbon black particle 3, the outer layer 1 and the fine and close connection of internal layer 2, the carbon black particle 3 is in internal layer 2.
Wherein, the internal layer 2 is carbon black chinlon 6 section.
Wherein, the outer layer 1 is chinlon 6 section.
Wherein, the ratio of the outer layer 1 and the cross-sectional diameter of the internal layer 2 is 8:1.
Wherein, the slice cross section is circle.
Wherein, 3 mass of the carbon black particle accounts for ranging from the 30% of the percentage of the internal layer quality.
The present invention also provides a kind of 6 black of polyamide fibre to be sliced manufacturing method, and steps are as follows:
Carbon black particle 3 is provided;
The carbon black particle 3 is mixed with chinlon 6 section, carbon black chinlon 6 section is made;
Using the carbon black chinlon 6 section as internal layer 2, obtained compound by spinning and processing using chinlon 6 section as outer layer 1 6 black of polyamide fibre of structure is sliced.
Further, providing 3 step of carbon black particle includes:
Dispersant, carbon black particle and particle dressing agent are sequentially added in a solvent;
To the solution obtained by the substance that is added every time, disperseed by dispersing technology, obtains modification carbon black dispersion;
By modification carbon black dispersion filtering, drying and grinding, modification carbon black particle 3 is made.
The present invention has the beneficial effect that:1)Carbon black is in internal layer, when subsequent technique needs white colouring or light color, not by shadow It rings;2)Carbon black good light stability, under illumination condition, black slice is than common slice longer life expectancy.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (8)

1. a kind of 6 black of polyamide fibre slice, including:Outer layer, internal layer, carbon black particle, the outer layer are connected with inner compact layer, the carbon Black particle is in internal layer.
2. a kind of 6 black of polyamide fibre slice according to claim 1, which is characterized in that the internal layer is carbon black chinlon 6 section.
3. a kind of 6 black of polyamide fibre slice according to claim 1, which is characterized in that the outer layer is chinlon 6 section.
4. a kind of 6 black of polyamide fibre slice according to claim 1, which is characterized in that the outer layer is transversal with the internal layer The proportional region of face diameter is 1:8 to 8:1.
5. a kind of 6 black of polyamide fibre slice according to claim 1, which is characterized in that the slice cross section is rectangle, ellipse Round, round or triangle.
6. a kind of 6 black of polyamide fibre slice according to claim 1, which is characterized in that the carbon black quality accounts for the internal layer matter The percentage of amount is ranging from:0.02%-30%.
7. a kind of 6 black of polyamide fibre is sliced manufacturing method, which is characterized in that steps are as follows:
Carbon black particle is provided;
The carbon black particle is mixed with chinlon 6 section, carbon black chinlon 6 section is made;
Using the carbon black chinlon 6 section as internal layer, composite junction is obtained by spinning and processing using chinlon 6 section as outer layer 6 black of polyamide fibre of structure is sliced.
8. a kind of 6 black of polyamide fibre is sliced manufacturing method according to claim 7, which is characterized in that provide carbon black particle step Including:
Dispersant, carbon black particle and particle dressing agent are sequentially added in a solvent;
To the solution obtained by the substance that is added every time, disperseed by dispersing technology, obtains modification carbon black dispersion;
By modification carbon black dispersion filtering, drying and grinding, modification carbon black particle is made.
CN201810041306.XA 2018-01-16 2018-01-16 A kind of 6 black of polyamide fibre slice and manufacturing method Pending CN108570228A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810041306.XA CN108570228A (en) 2018-01-16 2018-01-16 A kind of 6 black of polyamide fibre slice and manufacturing method

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Application Number Priority Date Filing Date Title
CN201810041306.XA CN108570228A (en) 2018-01-16 2018-01-16 A kind of 6 black of polyamide fibre slice and manufacturing method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111440312A (en) * 2019-12-24 2020-07-24 海阳科技股份有限公司 Polycondensation process of chinlon 6 colored chips

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5916945A (en) * 1995-12-19 1999-06-29 Elf Atochem S.A. Antistatic and adherent compositions based on polyamide
CN1584141A (en) * 2004-05-28 2005-02-23 江苏省纺织研究所有限公司 Composite electric conductive fibers coloreld at original liquid
CN201406488Y (en) * 2009-04-30 2010-02-17 江苏江南高纤股份有限公司 Skin core type color fiber
CN103388191A (en) * 2013-07-05 2013-11-13 江苏中杰澳新材料有限公司 Skin-core type polyamide antibacterial fiber and preparation method thereof
CN106592013A (en) * 2016-12-05 2017-04-26 嘉兴博锐新材料有限公司 Electroconductive carbon fiber production technology

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5916945A (en) * 1995-12-19 1999-06-29 Elf Atochem S.A. Antistatic and adherent compositions based on polyamide
CN1584141A (en) * 2004-05-28 2005-02-23 江苏省纺织研究所有限公司 Composite electric conductive fibers coloreld at original liquid
CN201406488Y (en) * 2009-04-30 2010-02-17 江苏江南高纤股份有限公司 Skin core type color fiber
CN103388191A (en) * 2013-07-05 2013-11-13 江苏中杰澳新材料有限公司 Skin-core type polyamide antibacterial fiber and preparation method thereof
CN106592013A (en) * 2016-12-05 2017-04-26 嘉兴博锐新材料有限公司 Electroconductive carbon fiber production technology

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111440312A (en) * 2019-12-24 2020-07-24 海阳科技股份有限公司 Polycondensation process of chinlon 6 colored chips

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Effective date of registration: 20210112

Address after: 225300 No. 2 Chuanghui Road, Taizhou Medical High-tech Zone, Jiangsu Province

Applicant after: Haiyang Technology (Jiangsu) Research Institute Co., Ltd

Address before: 225300 No. 2 Chuanghui Road, Taizhou Medical High-tech Zone, Jiangsu Province

Applicant before: JIANGSU HAIYANG POLYAMIDE NEW MATERIAL Co.,Ltd.

TA01 Transfer of patent application right
CB03 Change of inventor or designer information

Inventor after: Chen Liang

Inventor after: Feng Qidu

Inventor after: Ding Feng

Inventor after: Zhu Dehua

Inventor before: Chen Liang

Inventor before: Ding Feng

Inventor before: Zhu Dehua

CB03 Change of inventor or designer information
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Effective date of registration: 20210429

Address after: 225300 No. 122 Haiyang West Road, Taizhou City, Jiangsu Province

Applicant after: Haiyang Technology Co., Ltd

Address before: 225300 Taizhou Province medical hi tech Zone, foreign exchange Road No. 2, No.

Applicant before: Haiyang Technology (Jiangsu) Research Institute Co., Ltd

TA01 Transfer of patent application right