CN1563520A - Technical method for fabricating refined waste silk of silk spinning through softening solid glue on blaze silk - Google Patents
Technical method for fabricating refined waste silk of silk spinning through softening solid glue on blaze silk Download PDFInfo
- Publication number
- CN1563520A CN1563520A CN 200410022061 CN200410022061A CN1563520A CN 1563520 A CN1563520 A CN 1563520A CN 200410022061 CN200410022061 CN 200410022061 CN 200410022061 A CN200410022061 A CN 200410022061A CN 1563520 A CN1563520 A CN 1563520A
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- Prior art keywords
- silk
- husks
- solution
- soaked
- blaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000009987 spinning Methods 0.000 title claims abstract description 17
- 239000003292 glue Substances 0.000 title claims description 5
- 239000007787 solid Substances 0.000 title abstract description 4
- 239000002699 waste material Substances 0.000 title description 2
- 230000008961 swelling Effects 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 3
- 238000001035 drying Methods 0.000 claims abstract description 3
- 239000010903 husk Substances 0.000 claims description 43
- 239000000243 solution Substances 0.000 claims description 27
- 239000012670 alkaline solution Substances 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 11
- 238000007654 immersion Methods 0.000 claims description 11
- 239000012535 impurity Substances 0.000 claims description 5
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 description 6
- 238000006297 dehydration reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 5
- 235000011613 Pinus brutia Nutrition 0.000 description 5
- 241000018646 Pinus brutia Species 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- 238000003809 water extraction Methods 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Abstract
A technology method for softening solid sots baves to manufacture schappe spinning fine products includes the following steps: Selecting cocoons - swelling - protected by sols-solid sols softened - protection sols softened - cleaning and washing - drying, finally silk spun fine products are got.
Description
Technical field
The invention belongs to silk spinning industry, relating in particular to a kind of is raw material with the husks, makes the process of silk spinning refined silk through fixed gum softening.
Background technology
Blaze silk is the outer sleave part of silk cocoon, accounts for about 5%～7% of silk cocoon, is characterized in that fiber is short, random, the content of silk gum height, chance water is instant, does the back and becomes the lump shape, and peculiar smell is arranged, thereby in actual production, seldom utilize, and have only a spot of blaze silk can be spun into cotton or make wool blend.In order to turn waste into wealth, rationally use blaze silk, Chinese patent 91111324.X discloses a kind of processing technology of blaze silk staple fibre, and the process of high-elastic silk is made in Chinese patent 95111290.2 disclosed a kind of blaze silk sex change.The described processing method of Chinese patent 91111324.X though trace has used husks, makes husks admittedly in the blending thing, does not utilize husks fully, does not also change the performance of blaze silk; Though and the processing method of Chinese patent 91111324.X has been utilized the performance of husks fully, and the silk gum in the silk made high-elastic silk by the easy sex change of aldehyde radical, do not solve silk gum and in weak acid, weak caustic solution, boil still the problem of coming unstuck, hardening.In addition, this method has been owing to adopted the sex change of dialdehyde-based solution, thereby solution contains a large amount of formaldehyde, and it does not meet the standard-required of national PARA FORMALDEHYDE PRILLS(91,95) content, therefore the silk produced of this method can only be used as filler not next to the shin, and its scope of application is subjected to great restriction.
Summary of the invention
The purpose of this invention is to provide a kind of blaze silk fixed gum softening and make the process of silk spinning refined silk, can not come unstuck after the blaze silk that adopts this method to make to produce boils, dries in weak acid and weak base solution and harden, and soft, the postorder arranging process of adaptation silk spinning, blending.
Process of the present invention is carried out in the following order:
A, the preceding process of selecting: remove impurity and select husks, take by weighing husks;
B, swelling process: in husks: the ratio of acid solution=1: 10 is put into husks in the acid solution of PH=1～5 and was soaked 1～3 hour, stirs once, and dewaters after the immersion in per 0.5～2 hour;
C, protect the glue process: the husks after will dewatering is put into to contain in the multi-functional aldehyde radical solution and was soaked 6～10 hours, dewaters after the immersion in the PH=2 of this solution～5;
D, fixed gum softening process: soaked in the alkaline solution that the husks after will dewatering is put into again 14～18 hours, the PH=9 of this alkaline solution～13 are heated to 40 ℃～100 ℃ to alkaline solution, stir once, and dewater after the immersion in per 1 hour;
E, protect the gum softening process: soaked 18～24 hours the PH=9 of this solution～13 in the alkaline solution that contains waterglass that the husks after will dewatering is put at last;
F, cleaning, drying process: the husks that will soak at last cleans, dewaters, and obtains the silk spinning refined silk being lower than to dry under 100 ℃ the temperature.
In above-mentioned steps, preceding to select the purpose of process be that the husks that will buy back screens, and removes impurity (as flax silk, wire, careless slag etc.); The purpose of swelling process is that husks is swollen, and makes it be in a kind of solvent swelling state, for the solid glue of next step husks lays the first stone; The purpose of protecting the glue process is the albumen that solidifies in the husks, and silk gum is fixed on the husks; The purpose of fixed gum softening process is further silk gum to be fixed, and makes silk gum have certain flexibility rather than elasticity; The effect of protecting the gum softening process is that husks is bleached, and finally makes whole solution reach neutral.
Husks can obtain pure white, soft, nontoxic, tasteless silk spinning refined silk after processing through above-mentioned steps, and this silk spinning refined silk can boil the back in weak acid, weak caustic solution soft, can not come unstuck and harden.
The process that high-elastic silk is made in the present invention and Chinese patent 95111290.2 disclosed blaze silk sex change is compared as follows table:
| Performance indications | Before the processing | Make the process processing of high-elastic silk with the blaze silk sex change after | After the present invention's processing |
| Color and luster | Yellowish, brown Huang | Pure white | Pure white |
| Smell | Silkworm urine stink is arranged | There is not any smell | There is not any smell |
| Deposit situation | Time is long slightly, and the silk quality pigment is deepened, is clamminess, smell increases the weight of | Prolonged nondiscolouring is as good as stink | Prolonged nondiscolouring is as good as stink |
| The former performance that possesses of silk | Possess | Possess | Possess |
| Use the cold water soak situation | Meet the water swelling, do the back and become piece | Not swelling, non-caked, keep the pine bubble soft | Not swelling, non-caked, keep the pine bubble soft |
| Boiling water | Meet the water swelling, do the back and become piece | Silk gum dissolves bonding | The pine bubble is soft |
| 100 ℃ of weak acid and weak base solution | Meet the water swelling, do the back and become piece | Harden fully | The pine bubble is soft |
This shows: the product that the present invention makes has good and cheap, pure white tasteless advantage, still can keep the pine bubble soft after in weak acid, weak caustic solution, boiling, the husks cotton balls of making like this can fully adapt to the back whole operation of silk spinning, blending, greatly reduce the silk spinning raw material cost, and be with a wide range of applications, have great economic benefit, social benefit and ecological, environmental protective simultaneously and be worth.
The specific embodiment
Describe in conjunction with the embodiments:
Embodiment 1:
Husks is screened, remove impurity, take by weighing 500 gram husks, husks is put in the refining pond soaked 1 hour, the PH=2 of solution in the pond heavily is 5 kilograms a acid solution.Stirred once in per 0.5 hour, and soaked the back and carry out processed with Water Extraction Machinery; Husks after the dehydration put in the glutaraldehyde solution soaked 6 hours, the PH=2 of this solution puts into Water Extraction Machinery and carries out processed after the immersion; Husks after the dehydration put in the alkaline solution of PH=10 again soaked 14 hours, alkaline solution is heated to 60 ℃, stirred once, and dewatered again after the immersion in per 1 hour; Husks after the dehydration put in the alkaline solution that contains waterglass of PH=10 at last soaked 18 hours, the husks that soaks is at last cleaned, dewaters, obtain silk spinning refined silk 450 grams being lower than to dry under 100 ℃ the temperature.
Embodiment 2:
Husks is screened, remove impurity, take by weighing 1000 gram husks, husks is put in the refining pond of acid solution of PH=3 and soaked 3 hours, stirred once, and dewatered after the immersion in per 1 hour; Husks after the dehydration put into to contain in the glutaraldehyde solution soaked 10 hours, the PH=4 of this solution carries out processed after the immersion; Husks after the dehydration put in the alkaline solution of PH=12 again soaked 18 hours, alkaline solution is heated to 80 ℃, stirred once, and dewatered after the immersion in per 1 hour; Husks after the dehydration put in the alkaline solution that contains waterglass of PH=12 at last soaked 24 hours.The husks that soaks is at last cleaned, dewaters, obtain silk spinning refined silk 950 grams being lower than to dry under 100 ℃ the temperature.
Claims (2)
1, a kind of blaze silk fixed gum softening is made the process of silk spinning refined silk, it is characterized in that carrying out as follows:
A, the preceding process of selecting: remove impurity and select husks, take by weighing husks;
B, swelling process: in husks: the ratio of acid solution=1: 10 is put into husks in the acid solution of PH=1～5 and was soaked 1～3 hour, stirs once, and dewaters after the immersion in per 0.5～2 hour;
C, protect the glue process: the husks after will dewatering is put into to contain in the multi-functional aldehyde radical solution and was soaked 6～10 hours, dewaters after the immersion in the PH=2 of this solution～5;
D, fixed gum softening process: soaked in the alkaline solution that the husks after will dewatering is put into again 14～18 hours, the PH=9 of this alkaline solution～13 are heated to 40 ℃～100 ℃ to alkaline solution, stir once, and dewater after the immersion in per 1 hour;
E, protect the gum softening process: soaked 18～24 hours the PH=9 of this solution～13 in the alkaline solution that contains waterglass that the husks after will dewatering is put at last;
F, cleaning, drying process: the husks that will soak at last cleans, dewaters, and obtains the silk spinning refined silk being lower than to dry under 100 ℃ the temperature.
2, blaze silk fixed gum softening according to claim 1 is made the process of silk spinning refined silk, it is characterized in that: multi-functional aldehyde radical solution is glutaraldehyde solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410022061 CN1242102C (en) | 2004-03-17 | 2004-03-17 | Technical method for fabricating refined waste silk of silk spinning through softening solid glue on blaze silk |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410022061 CN1242102C (en) | 2004-03-17 | 2004-03-17 | Technical method for fabricating refined waste silk of silk spinning through softening solid glue on blaze silk |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1563520A true CN1563520A (en) | 2005-01-12 |
| CN1242102C CN1242102C (en) | 2006-02-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410022061 Expired - Lifetime CN1242102C (en) | 2004-03-17 | 2004-03-17 | Technical method for fabricating refined waste silk of silk spinning through softening solid glue on blaze silk |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1242102C (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100352975C (en) * | 2005-12-14 | 2007-12-05 | 杨朝友 | Method of processing sericin conteining natural silk fiber |
| CN100368616C (en) * | 2006-01-13 | 2008-02-13 | 席星航 | Silk denaturated nonwoven cotton containing sericin, and its uses |
| CN100379915C (en) * | 2006-01-13 | 2008-04-09 | 席星航 | Silk denaturated nonwoven fabric containing sericin, and its uses |
| CN100540796C (en) * | 2007-07-25 | 2009-09-16 | 席星航 | The production method of greige fixed gum slaking |
| CN100540758C (en) * | 2007-07-25 | 2009-09-16 | 席星航 | The production method of raw silk fixed gum softening |
| CN102031569A (en) * | 2010-11-16 | 2011-04-27 | 席星航 | Method for producing silk glue-enriched silk spinning refined waste silk |
| CN102560696A (en) * | 2011-11-29 | 2012-07-11 | 湖州市农业科学研究院 | Production method of natural colorful mulberry silk floss |
| CN102605438A (en) * | 2012-04-05 | 2012-07-25 | 常德诺雅蚕丝制品有限公司 | Manufacture method of washable mulberry silkworm long silk floss with high sericin content |
| CN103726306A (en) * | 2013-12-28 | 2014-04-16 | 杭州泛林科技有限公司 | Functional silk fiber preparation method using husks |
| CN106758191A (en) * | 2016-12-12 | 2017-05-31 | 广西江缘茧丝绸有限公司 | Mulberry silk fiber deoils and protects the process of glue |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100540759C (en) * | 2007-07-25 | 2009-09-16 | 席星航 | The production method of cocoon glue |
-
2004
- 2004-03-17 CN CN 200410022061 patent/CN1242102C/en not_active Expired - Lifetime
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100352975C (en) * | 2005-12-14 | 2007-12-05 | 杨朝友 | Method of processing sericin conteining natural silk fiber |
| CN100368616C (en) * | 2006-01-13 | 2008-02-13 | 席星航 | Silk denaturated nonwoven cotton containing sericin, and its uses |
| CN100379915C (en) * | 2006-01-13 | 2008-04-09 | 席星航 | Silk denaturated nonwoven fabric containing sericin, and its uses |
| CN100540796C (en) * | 2007-07-25 | 2009-09-16 | 席星航 | The production method of greige fixed gum slaking |
| CN100540758C (en) * | 2007-07-25 | 2009-09-16 | 席星航 | The production method of raw silk fixed gum softening |
| CN102031569A (en) * | 2010-11-16 | 2011-04-27 | 席星航 | Method for producing silk glue-enriched silk spinning refined waste silk |
| CN102031569B (en) * | 2010-11-16 | 2012-02-29 | 席星航 | Method for producing silk glue-enriched silk spinning refined silk |
| CN102560696A (en) * | 2011-11-29 | 2012-07-11 | 湖州市农业科学研究院 | Production method of natural colorful mulberry silk floss |
| CN102605438A (en) * | 2012-04-05 | 2012-07-25 | 常德诺雅蚕丝制品有限公司 | Manufacture method of washable mulberry silkworm long silk floss with high sericin content |
| CN102605438B (en) * | 2012-04-05 | 2014-03-19 | 常德诺雅蚕丝制品有限公司 | Manufacture method of washable mulberry silkworm long silk floss with high sericin content |
| CN103726306A (en) * | 2013-12-28 | 2014-04-16 | 杭州泛林科技有限公司 | Functional silk fiber preparation method using husks |
| CN103726306B (en) * | 2013-12-28 | 2015-10-28 | 杭州泛林科技有限公司 | A kind of function silk fiber preparation method utilizing husks |
| CN106758191A (en) * | 2016-12-12 | 2017-05-31 | 广西江缘茧丝绸有限公司 | Mulberry silk fiber deoils and protects the process of glue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1242102C (en) | 2006-02-15 |
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Owner name: CHONGQING XIANG FEI INDUSTRIAL (GROUP) CO., LTD. Free format text: FORMER OWNER: XI XINGHANG Effective date: 20080215 |
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Effective date of registration: 20080215 Address after: Chongqing Jiangbei District red Huang Road No. 10 building 27 floor cre Patentee after: Chongqing Xiang Fei Industry (Group) Co.,Ltd. Address before: Chongqing city Shapingba District Yubei Road No. 62 of No. 2 4-1 Patentee before: Xi Xinghang |
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Owner name: XI XINGHANG Free format text: FORMER OWNER: CHONGQING XIANG FEI INDUSTRIAL (GROUP) CO., LTD. Effective date: 20090403 |
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Effective date of registration: 20090403 Address after: No. 17-5, building C, 112 Fung Fung Road, Shapingba, Chongqing Patentee after: Xi Xinghang Address before: Chongqing Jiangbei District red Huang Road No. 10 building 27 floor cre Patentee before: Chongqing Xiang Fei Industry (Group) Co.,Ltd. |
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| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: CHONGQING WELAND MATTRESS FURNITURE Co.,Ltd. Assignor: Xi Xinghang Contract record no.: 2011500000045 Denomination of invention: Technical method for fabricating refined waste silk of silk spinning through softening solid glue on blaze silk Granted publication date: 20060215 License type: Exclusive License Open date: 20050112 Record date: 20110720 |
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Effective date of registration: 20170609 Address after: 400713 Chongqing city Beibei district on 128 Lilu Technology Innovation Center building B 505 Patentee after: CHONGQING SIMABO TECHNOLOGY CO.,LTD. Address before: 400038, No. 17-5, building C, 112 Fung Fung Road, Shapingba District, Chongqing Patentee before: Xi Xinghang |
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Address after: No. 003-2, Gangbin Road, Shipan Industrial Park, Pingshan Town, Pingshan County, Yibin City, Sichuan Province, 645350 Patentee after: Sichuan Sima Silk Technology Co.,Ltd. Address before: 400713 505, building B, science and technology entrepreneurship center, 128 Anli Road, Beibei District, Chongqing Patentee before: CHONGQING SIMABO TECHNOLOGY Co.,Ltd. |
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