CN1536105A - Sanitary processing fiber product and its manufacturing method - Google Patents
Sanitary processing fiber product and its manufacturing method Download PDFInfo
- Publication number
- CN1536105A CN1536105A CNA2004100311026A CN200410031102A CN1536105A CN 1536105 A CN1536105 A CN 1536105A CN A2004100311026 A CNA2004100311026 A CN A2004100311026A CN 200410031102 A CN200410031102 A CN 200410031102A CN 1536105 A CN1536105 A CN 1536105A
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- Prior art keywords
- fiber
- collagen
- oligopeptide
- health processing
- fibre
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/14—Spillage trays or grooves
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Fiber products is characterized by containing a natural moisture retentive ingredient such as oligopeptide and oligochitosan originated from collagen of scales, having excellent moisture retention and antibacterial property, being soft and being effective for eczema, itch and a rough skin. A manufacturing method thereof is provided. Fiber products sanitation-finished is obtained by: preparing a composition reacted oligochitosan and oligopeptide originated from collagen of scales; and then adhering the composition on underclothes, towels, socks, bedclothes or sportswear manufactured out of fabric, knitted fabric or non-woven fabric with a binder.
Description
Technical field
The present invention possesses special quality relevant for the processing mode of using marine collagen albumen, and the health processing fiber goods and the manufacture method thereof of tool antibiotic property and moisture retention.
And the present invention uses the collagen that picks up from the clean fish scale of conduct antagonism rabid ox disease (BSE), and carries out the fibre and the manufacture method thereof of health processing.
Illustrate further, the present invention is meant, use is by the oligopeptide collagen albumen of gained in the fish scale and the reaction constituent of chitin oligosaccharide, has the moisture retention that gives the skin a home from home, the quality of soft fluffy and the feature of antibiotic property, and quite washable excellent health processing fiber goods and manufacture method thereof.
Background technology
In the health of fibre is processed in the past, it is known be as: adopt coating zeolite (zeolite) medical cladding material (spy opens flat 1-15054 communique), use the cloth of sneaking into zeolite, the deodorizing underwear (spy opens flat 1-229801 communique) that reaches the prevent disease effect with flame envelope or retrograde method is general, the method for giving the skin antibacterial effect by fiber base material.
Except that giving antibacterial effect, the method that gives skin a home from home effect is also arranged again.For example; utilize the natural moisture preserving composition of collagen and chitin; with the method that obtains to give skin a home from home and antibacterial effect; with collagen; chitin and reactive silicon (silicon) are inserted fiber; to obtain as the good quality that merges with skin and the fibre (spy opens flat 7-229064 communique) of deodorization antibiotic property; also have and use the collagen that adds the water decomposition thing as animal protein to add the water decomposition thing; by cooperating the chitin lactate; the fibre finish of fourth stage ammonium salt carries out fiber treatment; prevent dry skin; itch, and then obtain the method (spy opens flat 2001-200478 communique) of the physiology protection effect of skin.Again, chitin is an indissolubility to water, order acid makes with its effect becomes chitin salt, use with water miscible fourth stage ammonium salt, by containing the fibre finish (spy opens flat 2002-327168 communique) that constituent that amino acid in chitin oligosaccharide, the sericin (sericin) and sericine add the water decomposition thing forms the moisture retention tunicle.
Collagen instead, though the collagen of being gathered by marine animal is gazed at, under the situation that must be obtained by skin or the bone of fish, the removal of fishlike smell promptly becomes the problem of difficulty, and the problem of bacterial multiplication is also arranged.Moreover although obtain having no the collagen of fishlike smell, the denaturation temperature of its protein is below 20 ℃, and is lower in comparison with terraria, and transparent gastrointestinal disease patient is also many, so its utilization is also had suitable problem.
Therefore, in the past, be about to replace the oligopeptide collagen albumen of gained in the fish scale of collagen and the reaction constituent of chitin oligosaccharide to use, obtained health processing fiber goods whereby with unique quality as fibre finish.
[patent documentation]
[patent documentation 1] spy opens flat 1-15024 communique
[patent documentation 2] spy opens flat 1-229801 communique
[patent documentation 3] spy opens flat 7-229064 communique
[patent documentation 4] spy opens flat 2001-200478 communique
[patent documentation 5] spy opens flat 2002-327168 communique
Summary of the invention
[goal of the invention]
As mentioned above; containing in the processed of the fiber of oligopeptide collagen albumen that ox or pig are obtained and chitin; established by the viewpoint of BSE countermeasure and set out; the fish scale of one of marine collagen albumen of the collagen of ox or pig instead, use by wherein gathering the technology of oligopeptide collagen albumen.Problem of the present invention is, and solves the bacterium and the fishlike smell problem of the problem in the past be considered as marine collagen albumen, and uses fish scale collagen and can guarantee the quality of fiber treatment goods.
Moreover in technique known, in order not undermine increasing of quality and washability, the use of necessary fiber treatment constituent stalemate agent is inevitably, so the stalemate agent that whether can use general fiber to use also becomes problem of the present invention.
Again, provide to have moisture retention and antibiotic property, and the health processing fiber goods person who also has unique soft fluffy quality also is problem of the present invention.
[technical scheme]
The present invention is by the following basis that consists of, to solve above-mentioned every problem.
(1) being characterized as of the fibre of this health processing:, fix it with stalemate agent with fiber with the oligopeptide collagen albumen of gained in the fish scale and the reaction constituent of chitin oligosaccharide.
(2) as (1) described health processing fiber goods, it is characterized in that, use the health processing that has more moisture absorption and antibiotic property.
(3) the health processing fiber goods of being put down in writing as (1) is characterized in that, this oligopeptide collagen albumen comes from the fish that survive in the warm current basin.
As (1) or (2) described fibre, it is characterized in that (4) this fibre is undershirt class, toweling, hosiery, nightwear class, motion dress material class etc.
(5) manufacture method of this fibre is characterized in that, will use fiber to be fixed in the health processing of fibres such as braided fabric or nonwoven fabric with stalemate agent by the oligopeptide collagen albumen of gained in the fish scale and the reaction constituent of chitin oligosaccharide.
The specific embodiment
The present invention is by the following basis that consists of, to solve above-mentioned every problem.
(1) being characterized as of the fibre of this health processing:, fix it with stalemate agent with fiber with the oligopeptide collagen albumen of gained in the fish scale and the reaction constituent of chitin oligosaccharide.
(2) as (1) described health processing fiber goods, it is characterized in that, use the health processing that has more moisture absorption and antibiotic property.
(3) the health processing fiber goods of being put down in writing as (1) is characterized in that, this oligopeptide collagen albumen comes from the fish that survive in the warm current basin.
As (1) or (2) described fibre, it is characterized in that (4) this fibre is undershirt class, toweling, hosiery, nightwear class, motion dress material class etc.
(5) manufacture method of this fibre is characterized in that, will use fiber to be fixed in the health processing of fibres such as braided fabric or nonwoven fabric with stalemate agent by the oligopeptide collagen albumen of gained in the fish scale and the reaction constituent of chitin oligosaccharide.
Oligopeptides among the present invention is, fish scale protein is added gained person after the water decomposition; For fish scale protein source person is the plain boiled pork fish that inhabits the warm current basin, the fish scale that porgy, yellow tin porgy, black porgy, military porgy, ovum head parrot fish (Scarus ovifrons) or the dragon that inhabits states such as Thailand, Malaysia or Indonesia is accounted for (Lethrinus haematopterus) is done the decalcification processing, after adding water decomposition and handle with acid or ferment, make it become oligopeptides and use it.
Again; the fish scale of fish of red flesh such as the husky glass fish (Sardinops melanostictus) in the Far East, Scomber japonicus or yaito tuna, because of its lipid and histidine (histidine) amount are many, taurine (Taurine) content is less; difficult being added in the water decomposition thing by transparent protein, obtained, so not good.
Table 1 those shown is to be used in the oligopeptides molecular weight distribution example of being obtained by fish scale of the present invention.
| Molecular weight | Distributive law % |
| More than 1,000 800～1,000 600～800 400～below 600 400 | ????0 ????12 ????61 ????27 ????0 |
Table 1
Again, table 2 those shown is to constitute the amino acid analysis result of the oligopeptides of obtaining in fish scale among the present invention.
| Kind | The result |
| Arginine Arginine is from the different white amino acid isoleucine MET Methionine a word used in person's names amino acid Valine alanine alanine glycine glycine proline proline paddy amine vinegar amino acid glutamine silk amino acid Serine amino acid Threonine of the Soviet Union acid, aspartic asparagine tryptophane Tryptophan Cystine cystine of the white amino acid Leucine of amino acid Lysine histidine histidine Phenylalanine phenylalanine Tyrosine tyrosine | 0.16g/100g having to detect not have, 0.13g/100g 0.04g/100g 0.06g/100g 0.02g/100g 0.14g/100g 0.07g/100g 0.13g/100g 0.14g/100g 0.71g/100g 1.50g/100g 0.75g/100g 0.49g/100g 0.08g/100g 0.12g/100g 0.03g/100g do not detect |
Table 2
On the other hand, in the present invention, use the reaction product of above-mentioned oligopeptides and chitin oligosaccharide, table 3 is the illustration of its molecular weight distribution of chitin oligosaccharide of using among the present invention.
| Molecular weight | Distributive law % |
| More than 800 700～800 600～700 500～below 600 500 | ?????1.9 ?????22.6 ?????74.4 ?????1.1 ?????0 |
Table 3
By the present invention, the oligopeptides of obtaining as aforementioned use whitefish squama collagen and the reaction constituent of chitin oligosaccharide, above-mentioned reaction constituent is, by being dissolved in water by oligopeptides and the chitin oligosaccharide that fish scale collagen is obtained, be heated to 50～60 ℃, carboxylic acid (Carboxylic) radical reaction of the C end amino acid of the oligopeptides that makes the chitin secondary amine and come by fish scale collagen is caught oligopeptides, the gel that makes it become fourth stage ammonium and have more antibiotic property.Be with the different persons of technology in past,, become fourth stage ammonium and when obtaining antibiotic property, the oligopeptides gelation of solubility with the reaction of oligopeptides and chitin oligosaccharide.Whereby, in the same manner in order to obtain washing resistance, but need not use the stalemate agent of special treatment, can obtain uniqueness, fluffy quality with in the past.With stalemate agent together attached with in fiber, via about 100 ℃ heat treatment, can obtain the fibre of quality excellence.At this moment, as using oligopeptides victory peptide (Peptide) in addition, because of the seizure and the gelation that can't obtain chitin, so can't bring into play above-mentioned treatment effect.Again, the victory peptide that the position beyond the fish scale is obtained also is not suitable for the present invention because of frowziness.
In the present invention, when using stalemate agent, the oligopeptides of obtaining from fish scale collagen and the fixed amount to fiber of chitin oligosaccharide be, and be more than 0.5% below 8%, preferable and can obtain quality, moisture retention and the antibiotic property of fluffy softness below 5%.
This fiber does not need to get final product with the stalemate agent that generally is used in fiber treatment with generally used each distinctive resin system stalemate agent in the past with stalemate agent.For example, can use the resin stalemate agent of urethanes (Urethan) or propylene system.
For the fiber of process object of the present invention is: silk floss, artificial silk (rayon), nylon, polyester fiber, propylene, thin,tough silk or wool etc. all can, its goods kenel has: fabric, compile thing, compile underwear class, bathing gown class, towel class, hosiery, nightwear class or sportswear etc. that thing or nonwoven fabric form.
The suitable finger of above-mentioned finishing agent is dipped in the solution that contains above-mentioned finishing agent by this fibre with process object, gets rid of solution, drying, or use the solution that the contains above-mentioned finishing agent modes such as back drying of spraying, and can easily carry out processed.
Of the present invention being characterized as used oligopeptides and the chitin oligosaccharide obtained from the fish scale that does not have fishy smell, makes its reaction become antibiotic property and moisture retention all behind the gel constituent of excellence, again in fiber process in solution system not.
And because of can obtaining unique fluffy tender texture, so when contacting, can mildly relax its symptom for dry skin or eczema, anaphylaxis skin etc., and elimination is itched with skin.This is the effect of chitin oligosaccharide and the resulting effect of amino acid assortment of fish scale collagen oligopeptides.By moisture retention towards sight, with silk gum and do not hinder, and also can be used the silk gum oligosaccharides with cooperating.
Adopt the present invention can obtain to have the health processing of excellent moisture retention and antibiotic property.
[enforcement group 1～3]
To cooperate with chitin oligosaccharide equivalent by the collagen oligopeptide that the military porgy that catch in the Thailand south is extracted out, be dissolved in water, make it become 100 ones of 20 weight % solution, after one hour, be cooled to room temperature, promptly get fluid,matching in 50 ℃ of heating.
The molecular weight of the collagen oligopeptide that uses and amino acid unit are with table 1 before being shown in and table 2.
Again, chitin oligosaccharide uses the molecular weight shown in the table 3.
For the fiber person that uses the stalemate agent, be with this E-2000 of super Rake (urethanes series fiber stalemate agent; The first industrial Pharmacy stock Co., Ltd goods) adjust in water with 20% weight % after, 100 ones of gained make an addition to above-mentioned fluid,matching, making it become full dose is 200 ones fiber process liquid.
The circle that underwear is used is compiled cotton and is used dipping filling (pad) method, with enforcement group 1～3, comparative group 1,2 with after the fiber fixed amount is handled shown in the table 4, in 100 ℃ of dryings it.
(weight %)
| Constituent experimental group comparative group | |||
| 1???????2???????3 | 1???????????2 | Blank column | |
| The chitin oligosaccharide owf stalemate agent owf of the oligopeptides owf table 3 of table 1 | 1.0％???2.0％???4.0％ 1.0％???2.0％???4.0％ 1.0％???2.0％???2.0％ | 2.0％???????---- ---?????????2.0％ 2.0％???????2.0％ | -?-?-?- -?-?-?- -?-?- |
Table 4
Table 5 those shown tests in example hygiene effects such as the moisture retention of fibre, antibiotic property for each.
| Test portion | Moisture retention | Plant the bacterium number | Number of bacteria after 15 hours | |
| Blank column | Washing washing 10 back scrubbing are not washed 50 times | 14.5 15.0 14.8 | 4×10 54×10 54×10 5 | 3×10 95×10 94×10 9 |
| Comparative group 1 | Washing washing 10 back scrubbing are not washed 50 times | 35.8 15.9 15.2 | 4×10 64×10 64×10 6 | 6×10 128×10 95×10 9 |
| Comparative group 2 | Washing washing 10 back scrubbing are not washed 50 times | 37.5 15.6 15.7 | 4×10 64×10 64×10 6 | 3×10 123×10 92×10 9 |
| Experimental group 1 | Washing washing 10 back scrubbing are not washed 50 times | 42.5 41.3 41.0 | 4×10 64×10 64×10 6 | 10 2Below 10 2Below 10 2Below |
| Experimental group 2 | Washing washing 10 back scrubbing are not washed 50 times | 43.9 42.2 41.8 | 4×10 64×10 64×10 6 | 10 2Below 10 2Below 10 2Below |
| Experimental group 3 | Washing washing 10 back scrubbing are not washed 50 times | 43.0 41.5 41.2 | 4×10 64×10 64×10 6 | 10 2Below 10 2Below 10 2Below |
Table 5
Moisture retention system is evaluation with the Mo Yisixuechuike MY707S of SCALAR company.Antibiotic property is then measured it according to the AATCC method.
[experimental group 4～5]
Use employed oligopeptides and chitin oligosaccharide in the experimental group 1 shown in the table 6, cooperation is the treatment fluid of the Lai Teweibaike S-60NF (chemistry limited company of common prosperity society makes) of stalemate agent for propylene, after propylene felt is 80 weight % with the dipping plugging, with 100 ℃ of dryings it, with its be treated as in preserve moisture and antibiotic property on all quite excellent felt.
Fixed amount to fiber is with shown in the table 6.
(weight %)
| Constituent experimental group comparative group | |||
| 4????????5 | 3?????????4 | Blank column | |
| The chitin oligosaccharide owf propylene stalemate agent owf of the oligopeptides owf table 3 of table 1 | 1.5％????2.5％ 1.5％????2.5％ 1.0％????2.0％ | 2.5％?????---- ---???????2.5％ 2.0％?????2.0％ | -?-?-?- -?-?-?- -?-?- |
Table 6
Table 7 those shown is the hygiene effect of experimental group.
| Test portion | Moisture retention | Plant the bacterium number | Number of bacteria after 15 hours | |
| Blank column | The washing washing is 30 times | 10.5 10.0 | 5×10 65×10 6 | 6×10 95×10 9 |
| Comparative group 3 | The washing washing is 30 times | 30.3 12.8 | 5×10 65×10 6 | 5×10 115×10 9 |
| Comparative group 4 | The washing washing is 30 times | 28.4 11.7 | 5×10 65×10 6 | 5×10 75×10 9 |
| Experimental group 4 | The washing washing is 30 times | 39.6 35.2 | 5×10 65×10 6 | 10 2Below 10 2Below |
| Experimental group 5 | The washing washing is 30 times | 40.1 37.7 | 5×10 65×10 6 | 10 2Below 10 2Below |
Table 7
[evaluation of experimental result]
The unique quality that all has soft fluffy in the fibre of experimental group 4 and 5 gained.And show that by the test result of antibacterial effect the present invention can be through 50 times washing, significantly on moisture retention and antibiotic property all than the comparative group excellence, promptly as can be known with regard to health is processed, the present invention has suitable effect in fact.
[effect of invention]
By the result of above-mentioned inorganic agent health processing of the present invention, because oligopeptides and the chitin oligosaccharide of obtaining from fish scale collagen has natural moisturizing composition, so can give skin comfortable environment by this moisture retention. Particularly, in the present invention, can obtain to have the fibre of unique quality of soft fluffy, moistening effect is also quite excellent, and for eczema, itch, scaly dry skin etc. also has suitable antibacterial effect.
Claims (5)
1. the fibre of a health processing is characterized in that, is fixed with stalemate agent with fiber by the collagen oligopeptide of gained in the fish scale and the reaction constituent of chitin oligosaccharide.
2. health processing fiber goods as claimed in claim 1 is characterized in that, use the health processing that has more moisture absorption and antibiotic property.
3. health processing fiber goods as claimed in claim 1 is characterized in that this oligopeptide collagen albumen comes from the fish that survive in the warm current basin.
4. as claim 1 or the 2nd described fibre, it is characterized in that this fibre is undershirt class, toweling, hosiery, nightwear class, motion dress material class etc.
5. method of making health processing fiber goods as claimed in claim 1, it is characterized in that, to use fiber to be fixed in the health processing of fibres such as braided fabric or nonwoven fabric with stalemate agent by the oligopeptide collagen albumen of gained in the fish scale and the reaction constituent of chitin oligosaccharide.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003104081 | 2003-04-08 | ||
| JP2003104081A JP3787126B2 (en) | 2003-04-08 | 2003-04-08 | Hygienic processed textile product and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1536105A true CN1536105A (en) | 2004-10-13 |
| CN1291078C CN1291078C (en) | 2006-12-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100311026A Expired - Fee Related CN1291078C (en) | 2003-04-08 | 2004-04-06 | Sanitary processing fiber product and its manufacturing method |
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| Country | Link |
|---|---|
| JP (1) | JP3787126B2 (en) |
| KR (1) | KR100763819B1 (en) |
| CN (1) | CN1291078C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102560892A (en) * | 2011-12-14 | 2012-07-11 | 山东俊富非织造材料有限公司 | Production method of collagen composite non-woven fabric |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006188810A (en) * | 2006-02-16 | 2006-07-20 | Taiki:Kk | Hygienically finished fiber product |
| JP5366921B2 (en) * | 2010-12-07 | 2013-12-11 | 株式会社 富田象形 | tabi |
| JP5877674B2 (en) * | 2011-09-19 | 2016-03-08 | アキレス株式会社 | Fiber structure |
| CN102499499A (en) * | 2011-10-08 | 2012-06-20 | 嘉兴学院 | Method for producing antibacterial, TPU (thermoplastic polyurethane) film laminated, waterproof, and moisture-permeable fabric |
| CN107648205B (en) * | 2017-10-19 | 2021-09-24 | 北京九鼎君健医药科技项城有限公司 | Collagen peptide dressing for promoting wound healing and preparation method thereof |
| CN115948913B (en) * | 2022-12-16 | 2024-06-14 | 浙江剑利美针织服饰有限公司 | Antibacterial underwear knitted fabric and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01204998A (en) * | 1988-02-12 | 1989-08-17 | Kobayashi Seiyaku Kk | Detergent composition |
| JPH0711579A (en) * | 1992-11-09 | 1995-01-13 | Nakagawa Momoki | Functional fiber and fiber product |
| JP3106202B2 (en) * | 1993-03-06 | 2000-11-06 | タキロン株式会社 | Synthetic resin molded products and eyeglass parts |
| JPH11266803A (en) * | 1998-03-20 | 1999-10-05 | Yozo Ishizuka | Production of softened product of hard collagen obtained from scale of fish, and its utilization for food |
| JP2001211895A (en) * | 2000-02-04 | 2001-08-07 | Kenji Kida | Method of producing physiologically active peptide |
| JP3439199B2 (en) * | 2001-05-07 | 2003-08-25 | 憲司 中村 | Moisturizing composition |
| JP2003023970A (en) * | 2001-07-13 | 2003-01-28 | Yozo Ishizuka | Method of production for collagen, chitin compound material obtained from fish scale and method of utilizing the same for food |
-
2003
- 2003-04-08 JP JP2003104081A patent/JP3787126B2/en not_active Expired - Fee Related
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2004
- 2004-04-06 CN CNB2004100311026A patent/CN1291078C/en not_active Expired - Fee Related
- 2004-04-07 KR KR1020040023867A patent/KR100763819B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102560892A (en) * | 2011-12-14 | 2012-07-11 | 山东俊富非织造材料有限公司 | Production method of collagen composite non-woven fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20040087926A (en) | 2004-10-15 |
| JP3787126B2 (en) | 2006-06-21 |
| JP2004308063A (en) | 2004-11-04 |
| CN1291078C (en) | 2006-12-20 |
| KR100763819B1 (en) | 2007-10-05 |
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