CN1534070A - Drawing ink composition and drawing tool - Google Patents
Drawing ink composition and drawing tool Download PDFInfo
- Publication number
- CN1534070A CN1534070A CNA031492681A CN03149268A CN1534070A CN 1534070 A CN1534070 A CN 1534070A CN A031492681 A CNA031492681 A CN A031492681A CN 03149268 A CN03149268 A CN 03149268A CN 1534070 A CN1534070 A CN 1534070A
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- weight
- ink composite
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- coated
- storage vessel
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/18—Writing inks specially adapted for ball-point writing instruments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K27/00—Multiple-point writing implements, e.g. multicolour; Combinations of writing implements
- B43K27/006—Pen or pencil barrels
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
An ink composition for drawing is provided to have excellent tackiness, interference effect and glittering effect. A drawing instrument using the ink composition is also provided. The ink composition for drawing comprises (a) 10-80 wt% of a solvent; (b) 1-30 wt% of a coloring agent; (c) 0.1-20 wt% of polyethylene oxide represented by the formula 1: HO-(CH2CH2O)n-CH2CH2OH(in which, n is 100,000 to 1,000,000); and (d) 0.5-60 wt% of lower alcohol. Further, the ink composition comprises (e) an interference pigment having a first coating layer mainly composed of SnO2 and a second coating layer mainly composed of metal oxide on a thin layered basic material, or (f) a synthetic pearl coated with TiO2, instead of (d) lower alcohol. The drawing instrument comprises a container(10) for filling the above ink composition(50), a holder(20), a tip(30) with a ball(38) and a resilient member(40).
Description
Technical field
The present invention relates to a kind of drawing ink composite and drawing instrument, relate more specifically to have the drawing drawing instrument and the ink composite of excellent tackiness, interference effect and flicker effect.
Background technology
Recently, the purposes of writing implement is not limited to write, and now has been applied to several purposes, as using the e-Pointer content that gives top priority to what is the most important, and uses photoluminescence writing implement etc. in the place of dark.
Printing ink is applied in these writing implements.The tackiness of printing ink is called as " viscosity (being clamminess) ", and when the writing implement that has viscosity printing ink when use touches paper surface and when lifting when printing ink flows out, printing ink extends as line finely between writing implement and paper.In this manual, the writing implement that is used for drafting figure or drawing geometric figures refers in particular to " drawing instrument ", uses the printing ink in this drawing instrument to refer to " graphic inks ".
Be clamminess if be used for the printing ink of drawing instrument, final literal of drawing and lines meeting are unclean and produce unnecessary lines, therefore need its viscosity low as much as possible for the printing ink that is used for drawing instrument.About this on the one hand, in technology formerly, have low-viscosity writing implement when drawing such as star, rectangle, trilateral figures in use, also need be except drawing instrument as other instruments such as scribe boards.
Application number is that the korean patent application of 2000-0002411 has disclosed and comprises the drawing instrument of giving material with polyethylene oxide as viscosity.Yet, because at application number is that the drawing instrument that discloses in the korean patent application of 2000-0002411 contains the polyethylene oxide of high viscosity and the high surface tension of the ink composite that causes thus, in reality was drawn, ink composite can make the in uneven thickness of lines at some part place thickenings of lines.
In addition, when ink composite is used in the drawing before using, in order to give the color change effect that its color can change according to view direction, the coated interference pigment that use is made by the thin body material thin slice (fine basematerials flakes) that contains just like metal oxide-coated layers such as titanium dioxide, but a little less than its color change effect.
In addition, formerly in the technology,, use glass flake, but glass flake is expensive and flicker effect is unexcellent in order to give graphic inks composition flicker effect.
Summary of the invention
The present invention is used for solving the above-mentioned problem, and one of purpose of the present invention provides the graphic inks composition with excellent viscosity, interference effect and flicker effect.
Another object of the present invention provides the drawing that has excellent viscosity, interference effect and a flicker effect by filling with printing ink and can be with a kind of new mode rendered images or the drawing instrument of figure.
In order to reach above-mentioned purpose, the invention provides a kind of drawing ink composite, this ink composite comprises the solvent of (a) 10～80 weight %; (b) tinting material of 1～30 weight %; (c) polyethylene oxide of the following molecular formula (1) of 0.1～20 weight %:
HO-(CH
2CH
2O)
n-CH
2CH
2OH????????(1)
Wherein n is 100,000～1,000,000; (d) be the lower alcohol of 0.5～60 weight %.
In addition, the invention provides a kind of drawing ink composite, comprise the solvent of (a) 10～80 weight %; (b) tinting material of 1～30 weight %; (c) polyethylene oxide of the top molecular formula (1) of 0.1～20 weight %; (e) coated interference pigment of 1～30 weight %, wherein main ingredient is tindioxide (SnO
2) first coat and main ingredient second coat that is metal oxide be coated in successively on the surface of thin body material thin slice.
In addition, the invention provides a kind of drawing printing ink, comprise the solvent of (a) 10～80 weight %; (b) tinting material of 1～30 weight %; (c) polyethylene oxide of the above-mentioned molecular formula (1) of 0.1～20 weight %; (f) 0.1～30 weight % above be coated with titanium dioxide (TiO
2) synthetic pearl.
In addition, the invention provides a kind of drawing instrument, comprise storage vessel, this storage vessel is constituted and is had the cylinder form of an end opening by the rubber-like resilient material; Support, the open end of this support and storage vessel closely connects, and is connected with storage vessel; The termination, this termination with the relative direction of storage vessel on connect with support, and the end of this termination is equipped with ball and its part can be rotated with exposed state; Be installed in the elastic element between termination and the support, this elastic element applies power to the ball outside that is installed in inside, termination; With the drawing ink composite that is filled in the described storage vessel, this drawing has 100 with what ink composite contained 10～80 weight % solvents, 1～30 weight % tinting material, 0.1～20 weight %, 000～8,000, the lower alcohol of the polyethylene oxide of 000 molecular weight and 0.5～60 weight %.
Description of drawings
Fig. 1 represents how to determine according to the skeleton view of drawing of the present invention with the viscosity of ink composite.
Fig. 2 represents how to use to be filled with according to drawing of the present invention to draw the geometric skeleton view of being made up of Points And lines with the drawing instrument of printing ink.
Fig. 3 is that the geometric orthographic plan that has several shapes with the ink composite drafting according to drawing of the present invention is used in expression.
Fig. 4 is the sectional view of expression according to a kind of embodiment of drawing instrument of the present invention.
Fig. 5 is the partial cross section frontview according to a kind of embodiment of drawing instrument of the present invention that expression is connected with cap.
Description of reference numerals
2 sheet glass, 4 sticking plasters
5 ink composites, 6 printing ink lines
7 paper, 8 geometricdrawing
9 drawing instruments, 10 storage vessels
20 supports, 30 terminations
38 balls, 40 elastic elements
50 draw with ink composite 60 caps
62 caps folder
Embodiment
After this, will describe three kinds of drawing ink composites of the present invention in detail.To draw with the formal classification of ink composite according to the auxiliary agent that is added, they are lower alcohol, coated interference pigment and synthetic pearl.These finish they separately three kinds of auxiliary agents of difference in functionality can use separately or two kinds or more kinds of mixing back is used.Below be these three kinds of auxiliary agents when using separately about these three kinds of drawing with each the detailed description in printing ink.
The drawing ink composite that comprises lower alcohol of first embodiment is the ink composite that comprises aforementioned solvents and tinting material, it is characterized in that further comprising as viscosity giving the lower alcohol of material and the polyethylene oxide (PEO) of following molecular formula (1):
HO-(CH
2CH
2O)
n-CH
2CH
2OH??????(1)
Wherein n is preferably 100,000～1, and 000,000, more preferably 100,000～300,000.
Polyethylene oxide is oxyethane [CH
2CH
2O] polymkeric substance, be also referred to as polyoxyethylene glycol, the viscosity of the solution when polyoxyethylene glycol is dissolved in the solvent by raising is given solvent viscosity.
0.1～20 weight % of the content preferred composition of polyethylene oxide of the present invention, more preferably 0.1～10 weight %.
If viscosity is given the content of material polyethylene oxide less than 0.1 weight %, viscosity is not enough and can not use this characteristic to draw, if surpass 20 weight %, becomes impossible because the excessive increase of viscosity makes to draw.
In addition, ink composite of the present invention is characterised in that and further comprises lower alcohol.Only comprise that when using described solvent, tinting material and viscosity gives the drawing of material when using ink composite, ink composite is at certain a part of thickening of lines, thereby lines are in uneven thickness.Yet the adding of lower alcohol has brought the capillary reduction of ink composite, and therefore the lines thickness of homogeneous is provided, and therefore can be used in ideally and draw with in the ink composite.
Lower alcohol content in the drawing usefulness ink composite of the present invention is preferably at 0.5～60 weight %.If the content of lower alcohol is less than 0.5 weight %, drawing can not be lowered with the surface tension of ink composite, and therefore the thickness of lines becomes inhomogeneous when line, if surpass 60%, it is too low with the surface tension of ink composite to draw, and therefore can not draw.
As the solvent of the main ingredient of ink composite of the present invention, can use ideally be commonly used for ink composition solvent such as water, alcohols, glycols equal solvent.Solvent is preferably 10～80 weight % that draw with ink composite, more preferably 30～50 weight %.
If solvent is less than 10 weight % of composition, the undue height of the viscosity of composition causes that consequently lines break easily when drawing, consequently can not draw, if surpass 80 weight %, the viscosity of composition became low and made that lines may flushing, consequently can not draw.
As the tinting material in the ink composite of the present invention, preferably can be dissolved in the oil-soluble colourant in the solvent, the dyestuff that is used for making alcohol, fluorescence dye or with particle form can stable dispersion at the dyestuff of ink composite or pigment, as mineral dyes such as metal powder, mica sheet, high-visibility pigment, photo-luminescent pigment, titanium dioxide, carbon black and sheet metals; Close mineral dye or their mixtures such as azo pigment, phthalocyanine pigment, perylene, Pei Ruinong (perinone) pigment, anthraquinone pigment as azo Rake (azoreiki), insoluble azo pigment, huge legendary turtle.
The content of this kind tinting material is preferably 1～30 weight % that draws with ink composite, more preferably 3～15 weight %.
Drawing as described above had not only had the viscosity that polyethylene oxide brings with ink composite but also had that lower alcohol brings can use it as printing ink with composition surface tension, also can draw the picture that decorative ceiling is used or wall is used even therefore contain this drawing with the feasible children of the drawing instrument of ink composite, also make and easily to draw greeting card and birthday card for oneself.
The drawing of the present invention that is added with coated interference pigment of second embodiment is with in the ink composite, because the interference effect of coated interference pigment, its color changes with different direction of observations.
The surface-coated of preferred thin body material thin slice has the tindioxide (SnO as first coat
2) and then coated metal oxide as the coated interference pigment of second coat.
As thin body material thin slice, preferred mica, silicate glass or their mixture, the median size of thin body material thin slice is preferably at 5～125 μ m, more preferably at 10～60 μ m, because these particle diameters are the best median size of performance drawing effect.
If the particle diameter of thin body material thin slice is difficult to obtain the unique color of thin body material less than 5 μ m, if surpass 125 μ m, writing effect degenerate and the lines drawn coarse.
Metal oxide as first coat that comprises thin body material thin slice, preferably, most preferably show the tindioxide of performances such as excellent specific refractory power, resistance, weathering resistance, thermotolerance, security because of its column or acicular crystalline structure have high refractive index and the excellent titanium dioxide to interference of light effect, ferric oxide, plumbous oxide, Indium sesquioxide, chromic oxide and zinc oxide etc.
In the coat of thin body material thin slice, interference effect is with changing as the thickness of metal oxides such as titanium dioxide is different, therefore the thickness of second coat becomes key variables of interference effect, the preferred 60～160nm of the thickness of metal oxide layer among the present invention.
As the method that coated interference pigment is coated on the thin body material thin slice, all can use as coating methods such as common pyrolytic decomposition and metallizings, most preferably can control coat thickness and inexpensive high-temperature decomposition easily.
High-temperature decomposition is with the form of hydrate depositing metal oxide on the surface of thin body material thin slice, by high-temperature decomposition the hydrate of metal oxide is converted into oxide compound then.For example, when thin body material thin slice is natural mica and metal oxide when being titanium dioxide, the particle suspension of natural mica thin slice is heated to about 80 ℃ in water and when stirring.The pH value is adjusted to 1.9 titanium tetrachloride and splashes into wherein, use aqueous sodium hydroxide solution then and be about 9 with the pH regulator of suspension, prepared product is deposited on the surface of thin body material as the metatitanic acid of the hydrate of titanium dioxide.Then, solid is told from suspension, after washing and drying, thereby calcined the coated interference pigment that obtains being coated with titanium dioxide at 800～1000 ℃.
As long as it has the interference of light effect, coated interference pigment also is not particularly limited, but especially preferred Iriodin201, Iriodin205, Iriodin211, Iriodin215, Iriodin219, Iriodin221, Iriodin223, Iriodin225, Iriodin231, Iriodin235, Iriodin249, Iriodin259, Iriodin289, Iriodin299 (Japanese MERCK company make) etc.
The invention is characterized in, by before coated metal oxide, further applying tindioxide (SnO
2), interference effect is improved.
The coating rate of tindioxide is preferably 0.1～10% of metal oxide-coated rate, and more preferably the metal oxide-coated rate 0.5～5%.This coating rate refers to the ratio of weight with the weight of thin body material of metal coated oxide compound or titanium dioxide.
As tindioxide, preferred Iriodin7205, Iriodin7215, Iriodin7217, Iriodin7219, Iriodin7225, Iriodin7235 (Japanese MERCK company make) etc.
The content of coated interference pigment of the present invention is preferably 1～30 weight % of composition.If the content of coated interference pigment is difficult to obtain color change effect less than 1 weight %, if surpass 30 weight %, then because the excessive color change effect that is difficult to obtain excellence of coated interference pigment.
The 3rd embodiment of the present invention is the drawing ink composite that demonstrates flicker effect, wherein uses to be coated with titanium dioxide (TiO
2) synthetic pearl replace widely used glass flake.The content of synthetic pearl is preferably 0.1～30 weight % that draws with ink composite, more preferably at 1～20 weight %.
Above three kinds of drawing of the present invention can further comprise the aromatoising substance that good fragrance is provided except viscosity, color change effect and flicker effect with ink composite.Preferred those of aromatoising substance have the material of herbal medicine fragrance, the preferred Flower of Miquel Linden of this aromatoising substance, licorice, Pei Ruilian (pereirian), Mentha arvensis L. syn.M.haplocalyxBrig, lavandula, lemonweed, peppermint, Thymus vulgaris, Rosmarinus officinalis, Paraguay's tealeaves, Flower of Aztec Marigold, tangerine peel, wild strawberry, tangerine, Salvia japonica Thunb., sweet basil, pink rose, cucurbit, black tea, jasmine, valerian, Citrus bergamia, flores anthemidis, cedar wood, Virginia bellflower, cassia bark, Salvia Sclare L., cypress, eucalyptus, fennel, frankincense, Flos Pelargonii, shaddock, ysopol, needle juniper, lemon, bitter orange, marjoram, myrrh, palm, patchouli, rose absolute, santal, tea tree, ylang-ylang, ginger, rose, Elettaria cardamomum (L.) Maton or the like.
Drawing of the present invention may further include as wetting agent, tensio-active agent, sanitas, rust-preventive agent, pH regulator agent etc. with ink composite.
In addition, the invention provides a kind of drawing instrument, comprise storage vessel, this storage vessel is made of the rubber-like resilient material, and has the cylinder form of an end opening; Support, this support closely connects on the open end of storage vessel, and is connected with storage vessel; The termination, this termination connects on support on the direction relative with the end of storage vessel, and its end is equipped with ball and makes the part of ball to rotate with exposed state; Be installed in the elastic element between termination and the support, the ball outside of this elastic element in being installed in the termination applies power; And a kind of drawing ink composite that is filled in the storage vessel, said composition contain 10～80 weight % solvent, 1～30 weight % tinting material, 0.1～20 weight % have 100, the lower alcohol of the polyethylene oxide of 000～8,000,000 molecular weight and 0.5～60 weight %.
Drawing instrument of the present invention comprises storage vessel, and this storage vessel is made of the rubber-like resilient material, and has the cylinder form of an end opening; Support, the open end of this support and storage vessel closely connect and are connected on the storage vessel; The termination, this termination connects on support on the direction relative with the end of storage vessel, and its end is equipped with ball and makes the part of ball to rotate with exposed state; Be installed in the elastic element between termination and the support, the ball outside of this elastic element in being installed in the termination applies power; And a kind of drawing ink composite that is filled in the storage vessel, said composition contain 10～80 weight % solvent, 1～30 weight % tinting material, 0.1～20 weight % have 100, the lower alcohol of the polyethylene oxide of 000～8,000,000 molecular weight and 0.5～60 weight %.
Use ink composite as drawing, the drawing of all the invention described above all can be used with composition.
Below with reference to the preferred implementation of accompanying drawing description according to drawing instrument of the present invention.
According to a kind of embodiment of drawing instrument of the present invention, as shown in Figure 4 and Figure 5, comprise storage vessel 10, this storage vessel 10 is made of the rubber-like resilient material and has an open-ended cylinder form; Fit snugly on the open end of storage vessel 10 and the support 20 that is connected with storage vessel 10; Termination 30, match with support 20 on the direction relative with storage vessel 10 in this termination 30, and its end is equipped with ball 38 so that the part of ball 38 is rotated with exposed state; Be installed between termination 30 and the support 20 and the outside of the ball in being installed in termination 30 applies the elastic element 40 of power; And a kind of drawing ink composite 50 that is filled in the storage vessel 10, said composition contain 10～80 weight % solvent, 1～30 weight % tinting material, 0.1～20 weight % have 100, the lower alcohol of the polyethylene oxide of 000～8,000,000 molecular weight and 0.5～60 weight %.
When the user grasps and push storage vessel 10, exert pressure with ink composite 50 and make ink composite move to the termination direction thereby storage vessel 10 is deformed drawing in it.Therefore, storage vessel 10 uses the rubber-like synthetic resins elastic material that can be out of shape with user's pressure to obtain.
For the structure of support 20, termination 30 and elastic element 40, can use common opaquing fluid with various inner matching structure and/or valve mechanism in coated tool or the beauty liquid usefulness coated tool, so this specification sheets does not provide its detailed description.
According to the embodiment of drawing instrument of the present invention, as shown in Figure 5, further comprise the cap 60 that closely mates with support 20, kill with ink composite 50 with protection termination 30 and the drawing that prevents to fill.
Evenly the cap 60 that forms has a cap folder 62 that is used for being fixed in pocket or the diary.
Drawing ink composite 50 as being filled in the storage vessel 10 can use the drawing of the invention described above all embodiments with ink composite.
In other words, draw and to comprise the solvent of 10～80 weight %, the tinting material of 1～30 weight %, the polyethylene oxide of 0.1～20 weight % with ink composite 50 with above-mentioned molecular formula (1), with the coated interference pigment of 1～30 weight %, wherein with tindioxide (SnO
2) be that second coat of main ingredient is coated on the surface of thin body material thin slice successively for first coat of main ingredient with the metal oxide.
As metal oxide, can use titanium dioxide (TiO
2) etc.
In addition, drawing to comprise the solvent of 10～80 weight % with ink composite 50, the tinting material of 1～30 weight %, and the polyethylene oxide with above-mentioned molecular formula (1) of 0.1～20 weight % and the surface-coated of 0.1～30 weight % have titanium dioxide (TiO
2) synthetic pearl.
The content of synthetic pearl can be selected in scope 1～20 weight %.
Below be preferred embodiment of the present invention and Comparative Examples.Following embodiment that provides and Comparative Examples only are used for more clearly describing the present invention, and should not be interpreted as limitation of the present invention.
Embodiment 1
With the water of 40g as solvent, 20g is as the glycerine of wetting agent, 20g high-visibility pigment Victoria indigo plant (Victoria Blue) G-28 as tinting material, 0.3g benzotriazole as sanitas, 9.7g have 10 as what viscosity was given material, 000, the polyethylene oxide of 000 molecular weight, and the 10g methanol mixture at room temperature uses the high speed agitator mixing to have viscosity, blue color, epipolic drawing ink composite with preparation.
Embodiment 2
Carry out with embodiment 1 in employed same steps as, except using the water of 54g as solvent, 10g is as the pigment MA-100 of tinting material, and 5.7g has 10 as what viscosity was given material, the polyethylene oxide of 000,000 molecular weight prepares black drawing ink composite.
Comparative Examples 1
With the water of 64g as solvent, 20g is as the glycerine of wetting agent, the 10g pigment MA-100 as tinting material, and the mixture of 5.7g gum arabic (Arabic gum) at room temperature uses high speed agitator to mix to draw with preparation black uses ink composite.
Determine tack retention hour and the line length of the drawing of embodiment 1, the embodiment 2 of above-mentioned preparation and Comparative Examples 1 with ink composite, its result is shown in the following table 1.
Table 1
| Kind | Embodiment 1 | Embodiment 2 | Comparative Examples 1 |
| Tack retention hour (Sec.) | 16 | ?15 | ?0 |
| Line length (cm) | 18 | ?17 | ?1.8 |
As shown in Figure 1, be deposited on the glass plate 2 at ink composite 5 1g, and ink composite 5 perpendicular contacts on sticking plaster 4 and the glass plate 2 of 10cm with diameter for 0.5cm length, then with speed 5cm/s sticking plaster 4 is raised up to the height of 5cm after 1 second, the tack retention hour above determining by the required time of breaking of measuring printing ink line 6.That is, tack retention hour is to be connected the maximum time that ink composite 5 on the glass plate 2 and the wire printing ink line 6 between the sticking plaster 4 break.
In addition, when 1g ink composite 5 is collected on the glass plate 2, and be that drawing on sticking plaster 4 and the glass plate 2 of 10cm is with ink composite 5 perpendicular contacts with diameter for 0.5cm length, then with speed 5cm/s sticking plaster 4 is lifted after 1 second, the length when breaking by measuring printing ink line 6 is determined line length.That is, line length is the ink composite 5 on the glass plate 2 and is connected break length between the position of printing ink line 6 on the sticking plaster 4.
As above shown in the table 1, the present invention of embodiment 1 and embodiment 2 draws with in the ink composite, and tack retention hour is greater than 10sec., and line length remains on 18cm and 17cm respectively.Therefore, they demonstrate sufficient viscosity and while lines thickness homogeneous.On the other hand, the ink composite that does not contain polyethylene oxide and methyl alcohol in the Comparative Examples does not maintain viscosity at all as can be seen.
Fig. 2 and Fig. 3 represent by as be filled with the geometricdrawing that drawing of the present invention is drawn with the drawing instrument 9 of the ballpoint pen of printing ink etc.
As shown in Figures 2 and 3, contact with paper 7 with the drawing instrument 9 of ink composite and form a some blink by keeping being filled with drawing of the present invention, lift then and mobile drawing instrument certain distance after, contact with paper 7 once more, repeat above-mentioned order, draw certain geometricdrawing 8 by repeating such program.
Because printing ink is viscosity,, therefore can draws such as interconnective star such as Points And lines or specifically figure such as spend when when the point of being painted lifts and link to each other with next one point, forming printing ink line 6 at the volley.
Below for being used for explaining the drawing that can demonstrate the flicker effect embodiment and the Comparative Examples of ink composite.
Embodiment 3
Is 10 as organic red pigment PANAX Red2RM (Uksung chemical company), the 0.3g of tinting material as benzotriazole, the 9.7g molecular weight of sanitas as the glycerine of wetting agent, 1g as the water of solvent, 20g with 60g, 000,000 polyethylene oxide and 9.0g at room temperature use high speed agitator to stir 1 hour as the mixture of the Reflex Rutile Glitter Pearl R-901E (SKY chemistry company limited) of synthetic pearl, prepare the drawing ink composite that the redness with viscosity has flicker effect.
Comparative Examples 3
Carry out with embodiment 3 in identical program, use ink composite except replacing synthetic pearl to prepare to draw with the metallicity flash of light (metallic shine) (Japanese Oriental Aluminum company limited) that is glass flake pigment.
The flicker effect of prepared printing ink usefulness composition much at one in the foregoing description 3 and the Comparative Examples 3, but, can save manufacturing cost with ink composite if use synthetic pearl to produce the drawing that demonstrates flicker effect because synthetic pearl is more cheap than the metallicity flash of light.So, use synthetic pearl can produce drawing ink composite of the present invention more economically.
Though more than be to have described according to drawing of the present invention ink composite and drawing instrument with preferred implementation, but should be considered to the restriction that the present invention is not subjected to foregoing description, can do various changes within the scope of the claims, detailed description of the present invention and accompanying drawing are also within the scope of the invention.
As mentioned above, drawing of the present invention has excellent viscosity, interference effect and flicker effect with ink composite.
In addition, according to drawing instrument of the present invention, can provide the new deisgn product that can draw a design in a kind of new mode.
Claims (15)
1, a kind of drawing ink composite comprises
(a) solvent of 10～80 weight %;
(b) tinting material of 1～30 weight %;
(c) polyethylene oxide of the following molecular formula (1) of 0.1～20 weight %:
HO-(CH
2CH
2O)n-CH
2CH
2OH?????????????????(1)
Wherein n is 100,000～1,000,000; With
(d) lower alcohol of 0.5～60 weight %.
2, drawing ink composite as claimed in claim 1 is characterized in that, (d) described in lower alcohol content be 5～40 weight %.
3, drawing ink composite as claimed in claim 1 is characterized in that, (d) described in lower alcohol be selected from the group that methyl alcohol, ethanol and propyl alcohol form.
4, a kind of drawing ink composite comprises
(a) solvent of 10～80 weight %;
(b) tinting material of 1～30 weight %;
(c) polyethylene oxide of the following molecular formula (1) of 0.1～20 weight %:
HO-(CH
2CH
2O)n-CH
2CH
2OH????????????????(1)
Wherein n is 100,000～1,000,000; With
(e) coated interference pigment of 1～30 weight %, wherein main ingredient is tindioxide (SnO
2) first coat and main ingredient second coat that is metal oxide be coated in successively on the surface of thin body material thin slice.
5, drawing ink composite as claimed in claim 4 is characterized in that, described metal oxide is titanium dioxide (TiO
2).
6, drawing ink composite as claimed in claim 4 is characterized in that, the thickness of described second coat is 60～160nm.
7, drawing ink composite as claimed in claim 4 is characterized in that, described thin body material thin slice is selected from the group of being made up of mica and silicate glass.
8, drawing ink composite as claimed in claim 4 is characterized in that, the median size of described thin body material thin slice is 5～125 μ m.
9, drawing ink composite as claimed in claim 4 is characterized in that, the coating rate of first coat of described coated interference pigment is 0.1～10% of second coat.
10, drawing ink composite as claimed in claim 4 is characterized in that, the coating rate of first coat of described coated interference pigment is 0.3～5% of second coat.
11, a kind of drawing ink composite comprises
(a) solvent of 10～80 weight %;
(b) tinting material of 1～30 weight %;
(c) the polyethylene oxide of 0.1～20 weight % with following molecular formula (1):
HO-(CH
2CH
2O)n-CH
2CH
2OH???????????????????(1)
Wherein n is 100,000～1,000,000; With
(f) surface-coated of 0.1～30 weight % has titanium dioxide (TiO
2) synthetic pearl.
12, drawing ink composite as claimed in claim 11 is characterized in that, (f) content of the synthetic pearl described in is 1～20 weight %.
13, a kind of drawing instrument comprises
Storage vessel, this storage vessel is made of elastic resilient material, and has the cylinder form of an end opening;
The support that closely connects and link to each other with the open end of storage vessel with storage vessel;
The termination, this termination with the storage vessel relative direction on connect with support, and the end of this termination is equipped with ball and is made its part to rotate with exposed state;
Be installed in the elastic element between termination and the support, this elastic element applies power to the outside of the ball that is installed in inside, termination; With
Be filled in the drawing ink composite in the described storage vessel, this drawing has 100,000～8,000 with what ink composite contained 10～80 weight % solvents, 1～30 weight % tinting material, 0.1～20 weight %, the lower alcohol of the polyethylene oxide of 000 molecular weight and 0.5～60 weight %.
14, drawing instrument as claimed in claim 13, it is characterized in that, described drawing has 100 with what ink composite comprised 10～80 weight % solvents, 1～30 weight % tinting material, 0.1～20 weight %, 000～8,000, the coated interference pigment of the polyethylene oxide of 000 molecular weight and 1～30 weight %, wherein main ingredient is tindioxide (SnO
2) first coat and main ingredient second coat that is metal oxide be coated in successively on the surface of thin body material thin slice.
15, drawing instrument as claimed in claim 13, it is characterized in that, described drawing has 100 with what ink composite comprised 10～80 weight % solvents, 1～30 weight % tinting material, 0.1～20 weight %, 000～8, the surface-coated of the polyethylene oxide of 000,000 molecular weight and 0.1～30 weight % has titanium dioxide (TiO
2) synthetic pearl.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020030019208A KR20040084263A (en) | 2003-03-27 | 2003-03-27 | Ink composition for drawing and drawing instrument |
| KR10-2003-0019208 | 2003-03-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1534070A true CN1534070A (en) | 2004-10-06 |
Family
ID=34309374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA031492681A Pending CN1534070A (en) | 2003-03-27 | 2003-06-18 | Drawing ink composition and drawing tool |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR20040084263A (en) |
| CN (1) | CN1534070A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105143362A (en) * | 2013-04-25 | 2015-12-09 | 株式会社樱花彩色笔 | Oily pigment ink composition and oily pigment ink writing tool |
| CN110091648A (en) * | 2018-01-29 | 2019-08-06 | 清华大学 | A kind of mask pattern drawing apparatus and method for drafting |
-
2003
- 2003-03-27 KR KR1020030019208A patent/KR20040084263A/en not_active Application Discontinuation
- 2003-06-18 CN CNA031492681A patent/CN1534070A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105143362A (en) * | 2013-04-25 | 2015-12-09 | 株式会社樱花彩色笔 | Oily pigment ink composition and oily pigment ink writing tool |
| US9683118B2 (en) | 2013-04-25 | 2017-06-20 | Sakura Color Products Corporation | Oil-based pigment ink composition and oil-based pigment ink writing tool |
| CN110091648A (en) * | 2018-01-29 | 2019-08-06 | 清华大学 | A kind of mask pattern drawing apparatus and method for drafting |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20040084263A (en) | 2004-10-06 |
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