Background technology
Be used to the watercolor writing and paint traditionally, printing ink, ink, wax crayon, Chinese painting colour, window glue, acrylic painting, pigment, oil colour, advertisement poster pigment or the like, various in style, be used to satisfy the needs of people's daily life and creation of art.These be used to write and paint material, derive from natural mineral color or wood dye the earliest, the printing ink that for example is used for Chinese calligraphy and graphics art just contains rosin, carbon black and vegetables oil.Get into after modern age because science and technology development is synthetic or semisynthetic material has replaced natural materials.The raising although improve to some extent, such as color is diversified, convenient manufacturing process, do not have the change of essence.The change of creative property is less, and their essentially consist is sticker, water or solvent, weighting agent, pigment, and other auxiliary materials comprise sanitas, wetting agent etc.Wherein sticker is such as peach gum, gelatin, vinyl resin; The effect of senegal or the like bonds and film forming exactly. the corresponding a kind of sticker of each kind basically, and changing is nothing but the sticker combination, water or solvent change are also little; The adding of aqueous solvent is equal to the adding auxiliary agent, only is the change of some use properties, and pigment is one to one; Adding high-visibility pigment or camouflage paint promptly is the change of color; What wherein change maximum is exactly weighting agent, and it influences viscosity, fineness, color, stability etc., thereby obtains improved pigment.
Like the patent No. 02107391.0 Chinese patent " CaCO
3/ SiO
2NH
2O Nano composite granules and hollow SiO
2NH
2O nano material and preparation method thereof ", a kind of stopping composition is disclosed, it is template with lime carbonate, the SiO of coated with uniform one deck nanometer grade thickness
2NH
2O, thus make CaCO
3/ SiO
2NH
2The O composite particles.This kind composite particles has some character of WHITE CARBON BLACK; Especially when the particle diameter of lime carbonate during less than 100 nanometers; Can partly or entirely substitute the reinforced filling of WHITE CARBON BLACK as rubber; Composite nano-powder treating processes such as dissolves through roasting, acid can prepare the mesoporous nano material that has the hollow structure nano material or have hollow structure; This material is than bigger serface, and even aperture distribution can be used as sorbing material, catalytic material, absorbing material, stupalith, sensitive material, magneticsubstance, nano dye, sensitive media protection reach synthetic accurate one dimension or zero dimension material like enzyme, protein, drug slow releasable material aspects such as template.But these lime carbonate are nano-scale, mainly are as stopping composition, do not make pigment coating obtain stereoeffect.
Comprehensively above-mentioned, because the Writing-painting material restriction has caused can't breaking through of artistic creation to a certain extent, hindered the Writing-painting artistic development.
Summary of the invention
Primary technical problem to be solved by this invention provides a kind of Writing-painting material with stereoeffect; It gives Writing-painting material special performances and visual effect; Widen the Application Areas of Writing-painting material; Give bigger aesthstic space of world of art and imagination space, be adapted at watercolor, printing ink, ink, wax crayon, Chinese painting colour, window glue, acrylic painting, pigment, oil colour or advertisement poster pigment etc. and go up application.
Another technical problem to be solved by this invention can expand after providing a kind of heating, stereoeffect is obvious more, the Writing-painting material with stereoeffect of unique style.
Another technical problem to be solved by this invention provides the simple and practical Writing-painting material preparation method of a kind of production technique.
The present invention solves the technical scheme that above-mentioned primary technical problem adopts: a kind of Writing-painting material with stereoeffect; The original Writing-painting material mixture that it includes as main body is characterized in that: the weighting agent in the Writing-painting material mixture originally partly or entirely replaces with the plastic hollow micropartical; Perhaps on the basis of the mixture of original Writing-painting material, add the plastic hollow micropartical, addition is 1~30 part (quality), is benchmark with the mixture total mass.
The present invention solves the technical scheme that above-mentioned another technical problem adopts: on above-mentioned basis, its micropartical inside of described plastic hollow micropartical is filled with gas.Gas is selected propane, butane, octane or pentane for use.
Described average particle diameter is 1~100 μ m.
Three-dimensional Writing-painting material mixture of the present invention is exactly on the basis of original three-dimensional Writing-painting material mixture, partly or entirely to replace wherein weighting agent with the plastic hollow micropartical, perhaps under the immovable situation of original weighting agent, adds the plastic hollow micropartical of part.A kind of situation is on the basis of original prescription, to add the plastic hollow micropartical; This is just thinner Writing-painting material itself; The Writing-painting material that does not perhaps originally add weighting agent is such as ink, fluorescence pen and ink etc.; Another kind is to add the plastic hollow micropartical again through the weighting agent that reduces original formulation, and the ratio that wherein adds will be introduced in an embodiment.
Key of the present invention is to have found the plastic hollow micropartical is added in the Writing-painting mixture, before the paint drying, through 100~150 ℃ of bakings, can become and has the brand-new Writing-painting material of stereoscopic sensation, has increased the new variety of Writing-painting material.These Writing-painting materials comprise watercolor, printing ink, ink, wax crayon, Chinese painting colour; Window glue, acrylic painting, pigment, oil colour; Advertisement poster pigment or the like, hollow particle can add (under rarer or packless situation) in the original formulation, also can partly or entirely replace the weighting agent (under denseer situation) in original prescription, the plastic hollow micropartical; Plastic material comprises acrylics, polystyrene resin, ABS, or all resins such as SBS.Micropartical inside is filled with propane, butane, all gas such as octane or pentane.These plastic hollow microparticals can expand rapidly when heating, and increase volume, thereby make painting material produce stereoscopic sensation.The plastic hollow micropartical that includes freonll-11 is used for the present invention and can obtains good performance, but because of it has destruction to ozonosphere, is unfavorable for environmental protection, so do not advocate to adopt.In prescription, add the plastic hollow micropartical, perhaps replace weighting agent with the plastic hollow micropartical, and still be sticker basically as the mixture of the painting material of main body; Water or solvent, weighting agent, pigment; Other auxiliary materials comprise sanitas, and wetting agent etc. are so can change original method of manufacture and technology; Also can change to some extent, very practical.
The present invention solves the technical scheme that above-mentioned another technical problem adopts: a kind of Writing-painting material preparation method with stereoeffect is characterized in that the weighting agent in original Writing-painting material mixture partly or entirely replaces with the plastic hollow micropartical; Perhaps on the basis of the mixture of original Writing-painting material, add the plastic hollow micropartical, addition is 1~30 part (quality) preferably, is benchmark with the mixture total mass, in mixing tank, is stirred to then evenly.In fact, addition is more also to be fine, and mainly is limited by the viscosity of cost and painting material.
Further, described mixture is put into grinding machine for grinding to the granularity that requires.
Compare with traditional Writing-painting material, outstanding advantage of the present invention is: drawing is after baking makes gassiness plastic hollow micropartical foaming and intumescing, and it can make works produce spatial visual space effect; Make color more bright-coloured, fine and smooth, lubricated simultaneously; He will never influence Writing-painting material property original or that after improving, give, can on original technology, produce basically, and stereoeffect is good; Unique style is interesting strong.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment 1. is used for watercolor
Peach gum 58
White carbon black 2
White titanium pigment 4
Zinc sulfide white 2
Plastic hollow micropartical 25
More than be mass fraction,
The plastic hollow micropartical is full of octane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Peach gum is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again to the granularity that requires, it is white promptly to get watercolor.
Embodiment 2. is used for watercolor
Peach gum 60
White carbon black 1
China ink ash 7
Plastic hollow micropartical 15
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Peach gum is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again to the granularity that requires, it is black promptly to get watercolor.
Embodiment 3. is used for watercolor
Peach gum 60
Potter's clay 5
White carbon black 5
Pigment vermilion 3,106 3.5
Plastic hollow micropartical 12
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select polystyrene resin for use.
Pigment vermilion 3106: great waves pigment ltd is won in Zhengzhou.
Peach gum is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again to the granularity that requires, it is bright red promptly to get watercolor.
Embodiment 4. is used for watercolor
Peach gum 60
Potter's clay 1
White carbon black 1
Rose color lake 3,293 0.1
Everbright fast violet toner 6,250 1.8
Plastic hollow micropartical 23
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Pigment rose color lake 3293: the blue specialization worker of Shenzhen's method Dye Co., Ltd.
Everbright fast violet toner 6250: great waves pigment ltd is won in Zhengzhou.
Peach gum is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again to the granularity that requires, it is pake purpke promptly to get watercolor.
Embodiment 5. is used for Chinese painting
Gelatin water 39
Permanent white 10
White titanium pigment 13
Plastic hollow micropartical 18
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Polystyrene resin.
Gelatin water is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again, promptly get the Chinese painting titanium white to the granularity that requires.
Embodiment 6. is used for Chinese painting
Gelatin water 40
Permanent white 10
Potter's clay 5
Red 808 14
Plastic hollow micropartical 5
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Red 808: the lucky pigment ltd of sending out in Tianjin.
Gelatin water is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again to the granularity that requires, it is bright red promptly to get Chinese painting.
Embodiment 7 is used for Chinese painting
Gelatin water 40
Permanent white 20
Potter's clay 5
White titanium pigment 3.2
The dark green K8730 1.65 of phthalein
Organic yellow 1,125 0.38
Chromoxide green 4
Phthalocyanine blue 0.24
Plastic hollow micropartical 16
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select ABS resin for use.
The dark green K8730 of phthalein: BASF AG
Organic yellow 1125: Baise, Wenzhou City gets fine pigments chemical industry ltd.
Chromoxide green: the towering clean science, industry and trade in Luoyang ltd
Phthalocyanine blue B: Jiangsu company of De Mao chemical industry ltd.
Gelatin water is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again to the granularity that requires, it is green promptly to get Chinese painting.
Embodiment 8 is used for Chinese painting
Gelatin water 39
Ashes 10
Plastic hollow micropartical 17
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Gelatin water is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again, promptly get Chinese painting black to the granularity that requires.
Embodiment 9. is used for ink
Xanthan gum 1.0
Carbon black 10.0
Isothiazoline sterilant 0.5
Glycol 5.0
Glycerine 5.0
EDTA 0.5
Silicon fluoride tensio-active agent 0.25
Water 76.75
Plastic hollow particle 1
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Add entry by formula ratio, glycerine, glycol, xanthan gum stirs; Then, add EDTA again, silicon fluoride tensio-active agent, ethyl p-hydroxybenzoate, isothiazoline sterilant; After the mixing, add the carbon black of formula ratio again, the plastic hollow particle mixes and promptly gets three-dimensional India ink.
Embodiment 10. is used for Chinese painting
Gelatin water 40
Permanent white 10
Potter's clay 5
Red 14
Plastic hollow micropartical 12
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Red: the lucky pigment ltd of sending out in Tianjin.
Gelatin water is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again to the granularity that requires, it is bright red promptly to get Chinese painting.
Embodiment 11. is used for Chinese painting
Gelatin water 39
Permanent white 10
White titanium pigment 10
Plastic hollow micropartical 14
More than be mass fraction,
The plastic hollow micropartical is full of butane gas.The atomic mean diameter of plastic hollow is 1~100 μ m.Select acrylics for use.
Gelatin water is pressed formula ratio add in the mixing tank, stir, add other compositions respectively by formula ratio again, continue to be stirred to evenly, put into grinding machine for grinding again, promptly get the Chinese painting titanium white to the granularity that requires.