CN1526003A - Composition for soil containing industrial waste as primary component - Google Patents
Composition for soil containing industrial waste as primary component Download PDFInfo
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- CN1526003A CN1526003A CNA028138953A CN02813895A CN1526003A CN 1526003 A CN1526003 A CN 1526003A CN A028138953 A CNA028138953 A CN A028138953A CN 02813895 A CN02813895 A CN 02813895A CN 1526003 A CN1526003 A CN 1526003A
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- zeolite
- diatomite
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F7/00—Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
- C05F7/02—Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses from sulfite liquor or other waste lyes from the manufacture of cellulose
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Soil Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Fertilizers (AREA)
- Treatment Of Sludge (AREA)
- Processing Of Solid Wastes (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
A composition for soil containing industrial wastes as a primary component, which is prepared by charging a composition comprising the sludge from a paper making process, fly ash, zeolite and/or diatomaceous earth, and an aqueous adhesive into a rotary mixer, mixing the composition at 50 to 100 rpm, forming the composition into granules by means of an extruder, and heating and drying the granules at 130 to 150 1/2 C for 20 to 30 minutes by means of a heating dryer. The above composition for soil has exhibited growth promoting effect for a plant, resulting in great yield increase in the cultivation of some field crops. Further, a composition for soil containing the sludge from a paper making process and fly ash is useful as an agent for treating a garbage, an excrement and a putrefactive material, a dehumidifying agent, and a deodorant.
Description
Technical field
The present invention relates to novel composition for soil and manufacture method thereof.More particularly, the present invention relates to the industry refuse is the composition for soil and the manufacture method thereof of the novelty of main raw.But also relate to soil improvement agent, soil moisture conditioning agent, food waste treatment agent, fecaluria treatment agent, putrefaction treatment agent, fertilizer starting material, dehumidizier or reodorant.
Background technology
Grow vigorously with the manufacture method of artificial association of soil thing about various crops, know many in the past.Particularly in the 98-63340 Korean Patent is open, a kind of flying dust (Fly ash) using method invention that the strongly-acid amino acid fermentation waste liquid fertilizerization that produces in the food flavouring factory is used is disclosed, but thisly with the rough sledding of advantage another side be with strongly-acid by-product of amino acid fermentation thing fertilizerization, owing in final product (final product), contain organism (organicmaterials), so can only be used for the later stage of crop growth, be subjected to the kind of soil, for example use in the plot in the large-scale polyethylene greenhouse of assembling soil as salt etc. is subjected to great restriction.
Summary of the invention
Although the main patent of aforesaid Korea S has good general soil improvement and moisture regulating effect, the object of the invention is to improve aforesaid rough sledding.That is to say, the object of the invention is to provide a kind of any stage that no matter is in crop growth can both make fertilizer and uses, general paddy field soil much less, even in the plot, large-scale polyethylene greenhouse and general cultivation of fruit tree usefulness upland field soil of salt gathering soil, no matter how the growth and development stage of soil type and raise crop can both use, make effect maximization as composition for soil, can significantly promote growing of crop, with the soil improvement composition of industry refuse as the novelty of main raw formation.Further purpose of the present invention is to provide a kind of soil improvement agent, soil moisture conditioning agent, food waste treatment agent, fecaluria treatment agent, putrefaction treatment agent, fertilizer starting material, dehumidizier or reodorant.Other purposes of the present invention are to provide the manufacture method of a kind of soil improvement agent, soil moisture conditioning agent, food waste treatment agent, fecaluria treatment agent, putrefaction treatment agent, fertilizer starting material, dehumidizier or reodorant.Other purpose of the present invention in addition will be illustrated by the detailed description of remembering specification sheets down.
This purpose of the present invention, by after in the industry refuse, selecting inorganic materials, determining its proportion of composing, make required composition for soil, composition for soil of the present invention is used for the various crop cultivation, estimate its experimental result of growing, perhaps be used for food waste, fecaluria, putrefaction etc., estimate its moisture regulatory function, deodorization functions and dehumidification function, reached by these means.
That is to say that content of the present invention comprises:
1. a composition for soil is characterized in that, contains at least two kinds of materials in paper mill sludge, flying dust (Fly ash), zeolite (Zeolite), the diatomite, perhaps contains three kinds of materials that these two kinds of materials and water-based tackiness agent are formed.
2. according to above-mentioned composition for soil, wherein combination selection is following or combined by them and water-based tackiness agent:
9) paper mill sludge, flying dust (Fly ash)
10) flying dust (Fly ash), zeolite (Zeolite), diatomite
11) paper mill sludge, zeolite (Zeolite), diatomite
12) paper mill sludge, diatomite
13) flying dust (Fly ash), diatomite
14) flying dust (Fly ash), zeolite (Zeolite)
15) paper mill sludge, zeolite (Zeolite)
16) paper mill sludge, flying dust (Fly ash), zeolite (Zeolite), diatomite.
3. according to above-mentioned composition for soil, wherein contain pitchstone and replace zeolite (Zeolite) and/or diatomite.
4. the composition for soil of the above is as the purposes of soil improvement agent, soil moisture conditioning agent, food waste treatment agent, fecaluria treatment agent, putrefaction treatment agent, fertilizer starting material, dehumidizier or reodorant.
5. the manufacture method of above-mentioned composition for soil.
Embodiment
Formation of the present invention and effect below are described.
The invention is characterized in, by soil improvement and deodorizing effect in the industry of the selection refuse, the moisture regulating effect, the good inorganic materials of fertilizer starting material is determined the stage of its ratio of components, the manufacturing stage of composition for soil, for confirming that composition for soil of the present invention is used for that growth facilitation effect and turnout increase effect with implementing actual experiment in cultivation after the various crop, in its evaluation of result stage, perhaps composition for soil of the present invention is used for food waste and handles, fecaluria is handled, putrefaction is handled, the stage of its moisture adjustment of postevaluations such as dehumidification treatments and deodorizing effect and effect on moisture extraction constitutes.
Among the present invention, selected industry refuse is the flying dust (Fly ash) of paper pulp and paper mill depleted system paper mud (Sludge) and fuel-burning power plant generation.As the material composition that is suitable for soil water-retaining power maximization usefulness, be zeolite (Zeolite) and/or diatomite.Also preferably use pitchstone (trade(brand)name: グ ラ ス ト Application) replace this zeolite (Zeolite) and/or diatomite.
The flying dust of selecting among the present invention, purpose are to supply with silicic acid, aluminium, lime, iron and boron.Therefore, in the formation raw material of the present composition, flying dust plays a part to promote that soil granular (aggregate) forms, and the result can make the porosity of soil maximization.Flying dust is the ashes that reclaim from the smog that fires into micro mist, can be described as very thin material.The effective constituent of using as fertilizer is boron, contains 52～63% silicon.Its effect is the effect height of boron fertilizer, and improves the tractive force of rice root system.
The major portion of the paper mill sludge of selecting among the present invention is that Mierocrystalline cellulose and xylogen are placed in the middle.This material for example in compost treatment the Mierocrystalline cellulose major part be decomposed, can significantly improve the shared ratio of xylogen and coarse ash.System paper mud is applicable to whole crops.Wherein under the influence of aluminum nitrate, phosphatic manure usually worsens, and is used for the winter can use 2～3 one-tenth during crop more.
The diatomite that the present composition constitutes in the raw material is fines, the purpose of selecting it be by with crosslinked combination of water-based tackiness agent CMC, make goods of the present invention can form granular product effectively.
The preferred composition of the present composition is by system paper mud 10～90, preferred 20～80, more preferably 30～70 weight %, flying dust (Fly ash) 10～80, preferred 20～75, more preferably 30～70 weight %, zeolite (Zeolite) 5～50, preferred 10～40 weight %, diatomite 20～50, preferred 25～40 weight %, and water-based tackiness agent in case of necessity, CMC (carboxymethyl cellulose) 0.5～10 for example, preferred 1～3 weight % constitutes.The ratio of using separately when these ratios are to use each composition need not to comprise whole compositions.
Composition example of the present invention can be listed following applicable combination, and wherein " % " is meant weight %.
1. flying dust 10～50%, system paper mud 10～90%, CMC 0～3%
2. flying dust 50～70%, zeolite 10～20%, diatomite 20～30%, CMC 0～3%
3. make paper mud 50～70%, zeolite 10～20%, diatomite 20～30%, CMC 0～3%
4. make paper mud 60～80%, diatomite 20～40%, CMC 0～3%
5. flying dust 60～80%, diatomite 20～40%, CMC 0～3%
6. flying dust 50～70%, zeolite 30～50%, CMC 0～3%
7. make paper mud 50～70%, zeolite 30～50%, CMC 0～3%
8. flying dust 10～20%, system paper mud 45～65%, diatomite 20～40%, CMC 0～3%
9. flying dust 10～50%, system paper mud 10～65%, zeolite 10～20%, diatomite 20～30%,
CMC?0～3％
Wherein, can be with the quid pro quo of pitchstone under same ratio as diatomite and/or zeolite.These compositions can be used as soil moisture conditioning agent, soil improvement agent, the use of fertilizer starting material.Though shown in the ratio of last note is to be suitable for ratio, by carrying out the quantity adjustment according to edaphic condition, can obtain better result.As the composition of particularly suitable, can use and 1. 3. 4. 7. 8. do the use of soil moisture conditioning agent, 2. 5. 6. make the fertilizer starting material and use, will bring into play effect.And preparation 1.～8. or from these preparations, remove the preparation of CMC, can in the moisture adjustment of fecaluria and putrefaction, deodorizing, dehumidifying, play a role.Wherein, will bring into play equal effect if use pitchstone (グ ラ ス ト Application) to replace diatomite and/or zeolite with same ratio.
The final fertilizer that uses for composition of the present invention is made as the fertilizer starting material can suitably mix various Natural fertilizers raw materials with the present composition.As the Natural fertilizers starting material, distributions such as the marc after can using food waste, various fruit (for example apple, oranges and tangerines etc.) to squeeze the juice to produce, cow dung, horsehit, fallen leaves extensively are called as the material of Natural fertilizers.Its ratio of mixture is counted by volume, the present composition be 1 o'clock be 0.001～100, for example can enumerate under the marc blended occasion of squeezing the juice and be 1: 1～9 (count 1: 0.1 by weight～7), and under the cow dung blended occasion be 1: 0.1～3 (weight ratio is 1: 0.01～2) with the tangerine mandarin orange.There is no particular restriction to blending means, but in order to ensure the homogeneous admixture, for example rotary mixing machine of preferred employing.Mixing can at room temperature be carried out.Mix the back for making its Natural fertilizersization must add fermentation procedure.Fermentation is under proper temperature (for example 15～28 ℃) condition, and suitably humidity is handled through about 20～90 days preservations, can reach the fertilizer purpose.
When composition of the present invention is used for the adjustment of food waste, fecaluria, putrefaction moisture and deodorizing, can employing directly contacts the blended mode and carry out with food waste, fecaluria, putrefaction.When handling food waste, be filled in combination treatment in the food waste treatment agent with composition of the present invention.During animal fecalurias such as processing ox, horse, chicken, pig, mix the back with composition of the present invention when gathering fecaluria to preserve 1～a few days of placement, can reach moisture adjustment and deodorizing purpose.When handling various fruits (for example apple, oranges and tangerines etc.) and squeezing the juice putrefactions such as marc after producing, practically identical with the treatment process of fecaluria.Though the multiple-effect fruit is good more certainly more for deodorizing for its proportioning, should preferably with 0.05～0.5, more preferably add with weight ratio 0.01～1 with 0.1～0.3.Adjust moisture and use under the occasion of composition of the present invention, should determine according to following calculating formula according to the purpose moisture content.
(with respect to the calculating formula of 1 ton of fecaluria)
The necessary water ratio of (moisture is adjusted quantity of material X moisture and adjusted material water ratio X fecaluria amount) ÷ (moisture is adjusted quantity of material+fecaluria amount)=fecaluria
Wherein work as
Moisture is adjusted quantity of material: A kg
Moisture is adjusted material water ratio: 7.8%=0.078
Fecaluria amount: 1 ton
Fecaluria water ratio: 95%
Fecaluria amount: 1000kg
The necessary water ratio of (A kgX1 ton X0.95) ÷ (A kg+1000kg)=fecaluria
For example, the fecaluria water ratio was reduced to from 95% at 85% o'clock, with this formula moisture is adjusted quantity of material and be decided to be A, judging by following calculating needs 129.53kg.
(A kgX1 ton X0.95) ÷ (A kg+1000kg)=0.85
A＝129.53kg
In addition, the moisture during from 95% every reduction by 10% is adjusted material (diminishing material) and is measured as follows with the water ratio of fecaluria.
85% (water ratio that fecaluria is required)=129.53kg
80% (water ratio that fecaluria is required)=207.7kg
Therefore composition of the present invention can be used for determining the required suitable proportioning of moisture adjustment.
Use under the occasion of composition of the present invention as dehumidizier or reodorant, a certain amount of composition of the present invention is dispersed in the purpose space handles.Though dispersion volume is generally 0.05～1, preferred 0.5～1kg/m
2, but can suitably increase and decrease according to the spatial air-tight state.Be dispersed in them under eaves when using, in the foot of a wall, space segment of the space segment between the step or between the walls, sordes storage place etc.And composition of the present invention by with material of construction and usefulness, can bring into play the effect of the dehumidizier and the reodorant of house, buildings.Under this occasion, material of construction is mixed directly as uses such as wall soil with composition of the present invention.Therefore composition of the present invention utilizes it is dispersed in method eaves under, can bring into play effectively and dehumidify and deodorizing effect.
Embodiment
Below specify the present invention with embodiment, but the present invention is not subjected to a bit restriction of these embodiment.
Embodiment 1
System paper mud (Sludge) 49 weight %
Flying dust (Fly ash) 49 weight %
Water-based tackiness agent (Binder) 2 weight %
This composition can be used as soil moisture conditioning agent and fertilizer starting material.Its analytical results is as follows.
Table 1
| Analysis project | Unit | In the raw material | In the dry |
| Moisture | ????％ | ????34.62 | |
| Total nitrogen | ????％ | ????0.308 | ????0.472 |
| Phosphorus (P 2O 5) | ????％ | ????0.130 | ????0.199 |
| Calcium (CaO) | ????％ | ????3.001 | ????4.591 |
| Magnesium (MgO) | ????％ | ????0.315 | ????0.482 |
| Potassium (K 2O) | ????％ | ????0.105 | ????0.160 |
| Ash content | ????％ | ????42.75 | ????65.40 |
| ????CEC | ????me/100g | ????6.86 | ????10.50 |
| Total nitrogen | ????％ | ????22.10 | ????33.81 |
| The C/N ratio | ????％ | ????71.69 | |
| ????PH | ????7.70 | ||
| ????EC | ????ms/cm | ????4.48 |
Table 2
| Analysis project | Unit | In the raw material | In the dry |
| Sodium (Na) | ????％ | ||
| Suddenly (Mn) | ????ppm | ????86.7 | ????132.7 |
| Boron (B) | ????ppm | ||
| Zinc Zn) | ????ppm | ????45.3 | ????69.4 |
| Copper (Cu) | ????ppm | ????53.8 | ????82.3 |
| Iron (Fe) | ????％ | ????0.589 | ????0.900 |
| Nickel (Ni) | ????ppm | ||
| Selenium (Se) | ????ppm | ||
| Cobalt (Co) | ????ppm |
Table 3
| Analysis project | Unit | In the raw material | In the dry |
| Nitric nitrogen | ????ppm | ????1.168 | ????1.786 |
| Ammonia-state nitrogen | ????ppm | ????33.966 | ????51.955 |
| Inorganic nitrogen | ????ppm | ????35.133 | ????53.741 |
Embodiment 2
Flying dust (Fly ash) 59 weight %
Zeolite 14 weight %
Diatomite 24 weight %
Water-based tackiness agent (Binder) 3 weight %
This composition can be used as soil improvement agent.
Embodiment 3
System paper mud (Sludge) 59 weight %
Zeolite 14 weight %
Diatomite 24 weight %
Water-based tackiness agent (Binder) 3 weight %
This composition can be used as soil moisture conditioning agent and fertilizer starting material.Its analytical results is as follows.
Table 4
| Analysis project | Unit | In the raw material | In the dry |
| Moisture | ????％ | ????39.17 | |
| Total nitrogen | ????％ | ????0.292 | ????0.479 |
| Phosphorus (P 2O 5) | ????％ | ????0.108 | ????0.177 |
| Calcium (CaO) | ????％ | ????3.345 | ????5.499 |
| Magnesium (MgO) | ????％ | ????0.375 | ????0.617 |
| Potassium (K 2O) | ????％ | ????0.371 | ????0.610 |
| Ash content | ????％ | ????40.78 | ????67.05 |
| ????CEC | ????me/100g | ????20.62 | ????33.90 |
| Total nitrogen | ????％ | ????18.53 | ????30.47 |
| The C/N ratio | ????％ | ????63.56 | |
| ????PH | ????7.70 | ||
| ????EC | ????ms/cm | ????1.59 |
Table 5
| Analysis project | Unit | In the raw material | In the dry |
| Sodium (Na) | ????％ | ||
| Suddenly (Mn) | ????ppm | ????85.3 | ????140.2 |
| Boron (B) | ????ppm |
| Zinc Zn) | ????ppm | ????81.6 | ????134.1 |
| Copper (Cu) | ????ppm | ????65.0 | ????106.9 |
| Iron (Fe) | ????％ | ????0.444 | ????0.729 |
| Nickel (Ni) | ????ppm | ||
| Selenium (Se) | ????ppm | ||
| Cobalt (Co) | ????ppm |
Table 6
| Analysis project | Unit | In the raw material | In the dry |
| Nitric nitrogen | ????ppm | ????1.197 | ????2.789 |
| Ammonia-state nitrogen | ????ppm | ????123.952 | ????203.771 |
| Inorganic nitrogen | ????ppm | ????125.649 | ????206.560 |
Embodiment 4
System paper mud (Sludge) 69 weight %
Diatomite 29 weight %
Water-based tackiness agent (Binder) 2 weight %
This composition can be used as soil moisture conditioning agent and fertilizer starting material.Its analytical results is as follows.
Table 7
| Analysis project | Unit | In the raw material | In the dry |
| Moisture | ????％ | ????42.66 | |
| Total nitrogen | ????％ | ????0.316 | ????0.551 |
| Phosphorus (P 2O 5) | ????％ | ????0.115 | ????0.201 |
| Calcium (CaO) | ????％ | ????3.576 | ????6.236 |
| Magnesium (MgO) | ????％ | ????0.379 | ????0.660 |
| Potassium (K 2O) | ????％ | ????0.136 | ????0.237 |
| Ash content | ????％ | ????34.76 | ????62.62 |
| ????CEC | ????me/100g | ????12.04 | ????21.00 |
| Total nitrogen | ????％ | ????18.74 | ????32.68 |
| The C/N ratio | ????％ | ????59.29 | |
| ????PH | ????7.50 |
| ????EC | ????ms/cm | ????1.62 |
Table 8
| Analysis project | Unit | In the raw material | In the dry |
| Sodium (Na) | ????％ | ||
| Suddenly (Mn) | ????ppm | ????73.5 | ????128.1 |
| Boron (B) | ????ppm | ||
| Zinc Zn) | ????ppm | ????64.6 | ????112.6 |
| Copper (Cu) | ????ppm | ????77.1 | ????134.6 |
| Iron (Fe) | ????％ | ????0.407 | ????0.711 |
| Nickel (Ni) | ????ppm | ||
| Selenium (Se) | ????ppm | ||
| Cobalt (Co) | ????ppm |
Table 9
| Analysis project | Unit | In the raw material | In the dry |
| Nitric nitrogen | ????ppm | ????1.394 | ????2.430 |
| Ammonia-state nitrogen | ????ppm | ????67.394 | ????117.541 |
| Inorganic nitrogen | ????ppm | ????68.788 | ????119.971 |
Embodiment 5
Flying dust (Fly ash) 69 weight %
Diatomite 29 weight %
Water-based tackiness agent (Binder) 2 weight %
This composition can be used as soil improvement agent.
Embodiment 6
Flying dust (Fly ash) 59 weight %
Zeolite 39 weight %
Water-based tackiness agent (Binder) 2 weight %
This composition can be used as soil improvement agent.
Embodiment 7
System paper mud (Sludge) 59 weight %
Zeolite 39 weight %
Water-based tackiness agent (Binder) 2 weight %
This composition can be used as soil moisture conditioning agent and fertilizer starting material.Its analytical results is as follows.
Table 10
| Analysis project | Unit | In the raw material | In the dry |
| Moisture | ????％ | ????38.56 | |
| Total nitrogen | ????％ | ????0.291 | ????0.474 |
| Phosphorus (P 2O 5) | ????％ | ????0.102 | ????0.165 |
| Calcium (CaO) | ????％ | ????3.318 | ????5.400 |
| Magnesium (MgO) | ????％ | ????0.341 | ????0.555 |
| Potassium (K 2O) | ????％ | ????0.687 | ????1.118 |
| Ash content | ????％ | ????40.84 | ????66.47 |
| ????CEC | ????me/100g | ????36.68 | ????59.70 |
| Total nitrogen | ????％ | ????15.73 | ????25.60 |
| The C/N ratio | ????％ | ????54.00 | |
| ????PH | ????％ | ????7.90 | |
| ????EC | ????ms/cm | ????1.82 |
Table 11
| Analysis project | Unit | In the raw material | In the dry |
| Sodium (Na) | ????％ | ||
| Suddenly (Mn) | ????ppm | ????99.6 | ????162.1 |
| Boron (B) | ????ppm | ||
| Zinc Zn) | ????ppm | ????61.7 | ????100.4 |
| Copper (Cu) | ????ppm | ????64.3 | ????104.6 |
| Iron (Fe) | ????％ | ????0.381 | ????0.619 |
| Nickel (Ni) | ????ppm | ||
| Selenium (Se) | ????ppm | ||
| Cobalt (Co) | ????ppm |
Table 12
| Analysis project | Unit | In the raw material | In the dry |
| Nitric nitrogen | ????ppm | ???2.375 | ??3.865 |
| Ammonia-state nitrogen | ????ppm | ???153.924 | ??250.515 |
| Inorganic nitrogen | ????ppm | ???156.298 | ??254.381 |
Embodiment 8
System paper mud (Sludge) 69 weight %
Pitchstone 29 weight %
Water-based tackiness agent (Binder) 2 weight %
This composition can be used as soil redeposition and fertilizer starting material.
Embodiment 9
System paper mud (Sludge) 70 weight %
Flying dust (Fly ash) 30 weight %
This composition can be used as soil improvement agent, fertilizer starting material, reodorant, dehumidizier.
Embodiment 10
(manufacturing of the present composition)
The composition selective collection of note embodiment 1～9 record in the selection, with behind its input hopper (Hopper), more than the disclosed weight proportion of note drops into it in impeller (Rotarymixer) automatically respectively.At this moment, the determining of the kind of hopper and input amount becomes to utilize program to move by microcomputer via storer by means of calculation Design in advance.The design of this program and utilization can be implemented easily by those of ordinary skills.Though it is unimportant to constitute the mixing velocity of material composition in the impeller, preferred 50～100rpm.Mixed material composition, utilization is located at the lateral delivery system of mixing tank it is stated from the conveying belt, with its input make granular product with end have be engraved as dice (Dice) extrusion machine in, make granulated product, with its in 130～150 ℃ heat drier dry 20～30 minutes, make the finished product.Can in last note mixing tank, promote this moment to bond between material composition and the granulating of product is used water-based tackiness agent, though can use multiple, CMC preferably.
Embodiment 11
Utilize rotary blender that arbitrary composition that embodiment 1,3,4,7～9 obtains is mixed according to weight ratio with oranges and tangerines marc raw material at 1: 3,, obtained Natural fertilizers in order under room temperature (15～25 ℃), its fertilizerization to be made it to ferment about 30 days.In fact become loose condition (of surface), do not find to come from the stench of oranges and tangerines putrefaction through 10 people's sensory test.
Embodiment 12
Utilize rotary blender that arbitrary composition that embodiment 1,3,4,7～9 obtains is mixed according to volume ratio with the cow dung raw material at 1: 1,, obtained Natural fertilizers in order under room temperature (15～25 ℃), its fertilizerization to be made it to ferment about 30 days.Fertilizer has good effect aspect water-absorbent and the deodorization.In fact become loose condition (of surface), do not find to come from the stench of cow dung through 10 people's sensory test.
Embodiment 13
Use arbitrary composition of the present invention among the embodiment 1～9, any 1 part of chicken manure, horsehit urine, oranges and tangerines putrefaction, household garbage are mixed with weight ratio with 0.3 part of present composition test sample, carried out the sense qualification test with regard to stink.By eight triers the composition of embodiment 1～9 is carried out stink test evaluation result and show that stink reduced by half in 48 hours, can't find stink fully after preserving a week.
Embodiment 14
(garlic and onion plant are used test by the soil moisture conditioning agent of the present invention's product preparation)
With the ratio of 500kg/10 hectare, to garlic and onion plant, use soil moisture conditioning agent by arbitrary example preparation among the embodiment 1,3,4,7～9 as test plant, measured its light compositing rate respectively.The measurement result of results artifact body weight shows that when using the Natural fertilizers of the present invention's preparation, the effect of increasing income of bringing because of growth-promoting effect amounts up to more than 5%.
Embodiment 15
(muskmelon and capsicum plant are used test by the soil moisture conditioning agent of the present invention's product preparation)
Near the salt accumulation on the gold three Li Shi farms flowers field, Yi Shan city damages in the big polyethylene greenhouse, the trial plot of the soil improvement agent that arbitrary example is made in using by embodiment 2,5,6 with 500kg/10 hectare ratio and do not use its check plot to cultivate capsicum plant.In the treatment zone with the fertilizer of the present invention's product preparation, light compositing amount, chlorophyll content and pore conductivity improve, and fruiting rate improves more than 10%.
Embodiment 16
(flowers and plants are cultivated experiment)
The fertilizer that obtains with embodiment 11 utilizes and has used the soil of 10% (V/V) that the cultivation of flowers and plants is tested as base manure.After planting germinate, bloom after tens of days through a few days.And, use the Natural fertilizers of composition as fertilizer sources raw material preparing of the present invention through confirming, extremely useful for the growth of flowers and plants.Carry out the present composition of various flowers and plants experiments, had soil moisture and adjust effect and reclamation result, confirmed its developmental state.And compare with utilizing commercially available in the past flowers and plants soil, it is identical substantially to find to cultivate effect.
Embodiment 17
In the co-worker farm that Wakayama Ken lives, use embodiment 11 and 12 compositions of making to urinate treatment agent as cow dung.By making the proportioning between cow dung urine and the fecaluria treatment agent do various variations since 1: 1, studied usage quantity.Its result proves, in case use the composition of crossing through composition compost treatment of the present invention to replace sawdust, can be used as the fecaluria treatment agent and uses.Approximately fast twice is compared in the rising of fermentation degree, leavening temperature with the first time.On the water-absorbent of fecaluria and deodorization, has excellent results.For 1 ton of fecaluria of moisture content 95%, to regulate material (diminishing material) quantity (weight) as follows for the required moisture of diminishing in 24 hours.Wherein, promptly use the same processing of oranges and tangerines putrefaction also to obtain same result as process object.
10% diminishing (reducing to 85%) time=90kg (diminishing quantity of material)
20% diminishing (reducing to 75%) time=180kg (diminishing quantity of material)
30% diminishing (reducing to 65%) time=260kg (diminishing quantity of material)
Embodiment 18
In the co-worker farm that Wakayama Ken lives, use is removed the arbitrary composition water-based tackiness agent, that embodiment 1～8 makes and is urinated treatment agent as cow dung.Blending ratio is 1 a weight part cow dung urine: each composition of 0.3 weight part.The result proves that two kinds of composition groups have all obtained fecaluria is produced good water-absorbent effect and deodorization effect.In the foul smell test of being undertaken by eight co-workers, all do not find foul smell after handling in next week of the occasion of using arbitrary composition.
Embodiment 19
In the co-worker farm that Wakayama Ken lives, use and remove the arbitrary composition water-based tackiness agent, that embodiment 1～8 makes as dehumidizier or reodorant.Usage quantity is respectively every square metre of 1～0.5kg under the eaves.Found that arbitrary composition group all has the good moist and deodorization of removing under eaves.
The possibility of utilizing on the industry
More than experiment and embodiment explanation, composition for soil of the present invention have the remarkable result that promotes growth for the trial crops in the garden crop. And confirm, press the result of use of the composition for soil of the present invention's preparation, for the hardness of stem, leaf, intensity, the bright-coloured degree of color, and the Optimality of flower number is significant. And confirm that the present composition uses as garbage inorganic agent, fecaluria inorganic agent, rot inorganic agent, dehumidizer, deodorant, has in the past unexistent moisture regulatory function and deodorization functions. The present invention is a kind of invention extremely useful on refuse industry and fertilizer industry in addition.
Claims (5)
1. a composition for soil is characterized in that, contains at least two kinds of materials in paper mill sludge, flying dust, zeolite, the diatomite, perhaps contains three kinds of materials that these two kinds of materials and water-based tackiness agent are formed.
2. according to the described composition for soil of claim 1, wherein combination selection is following or combined by them and water-based tackiness agent:
1) paper mill sludge, flying dust
2) flying dust, zeolite, diatomite
3) paper mill sludge, zeolite, diatomite
4) paper mill sludge, diatomite
5) flying dust, diatomite
6) flying dust, zeolite
7) paper mill sludge, zeolite
8) paper mill sludge, flying dust, zeolite, diatomite.
3. according to claim 1 or 2 described composition for soil, wherein contain pitchstone and replace zeolite and/or diatomite.
4. any one described composition for soil in the claim 1～3 is as the purposes of soil improvement agent, soil moisture conditioning agent, food waste treatment agent, fecaluria treatment agent, putrefaction treatment agent, fertilizer starting material, dehumidizier or reodorant.
5. the manufacture method of any one described composition for soil in the claim 1～4.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP220341/2001 | 2001-07-19 | ||
| JP2001220341 | 2001-07-19 | ||
| JP2001268087A JP2003096452A (en) | 2001-07-19 | 2001-09-04 | Composition for soil consisting of industrial waste |
| JP268087/2001 | 2001-09-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1526003A true CN1526003A (en) | 2004-09-01 |
| CN1280382C CN1280382C (en) | 2006-10-18 |
Family
ID=26619047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028138953A Expired - Fee Related CN1280382C (en) | 2001-07-19 | 2002-07-18 | Composition for soil containing industrial waste as primary component |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2003096452A (en) |
| CN (1) | CN1280382C (en) |
| WO (1) | WO2003008517A1 (en) |
Cited By (5)
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| CN102187777A (en) * | 2010-03-19 | 2011-09-21 | 许水茂 | Planting soil and preparation method thereof |
| CN102040356B (en) * | 2009-10-21 | 2013-01-16 | 财团法人工业技术研究院 | Light heat-insulating composite particles and preparation method thereof |
| CN106613476A (en) * | 2016-11-10 | 2017-05-10 | 陈建峰 | Method for cultivating matrix nutrient soil by means of household waste incineration fly ash |
| CN107502362A (en) * | 2017-08-29 | 2017-12-22 | 湖南泰谷生物科技股份有限公司 | The method and its application of acidic soil conditioner are prepared with black liquid |
| CN108329010A (en) * | 2018-02-01 | 2018-07-27 | 东北师范大学 | A kind of hollow porous gap ball-type conditioner suitable for meadow |
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| CN101781568B (en) * | 2010-02-03 | 2011-08-31 | 北京海亚地大生化科技有限公司 | Soil conditioner, preparation method and application thereof |
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| CN101863706B (en) * | 2010-07-08 | 2012-09-19 | 李桓宇 | Organic composite fertilizer produced by using paper making sludge and manufacturing method thereof |
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| JPH1036836A (en) * | 1996-07-26 | 1998-02-10 | Yamashita Kenji | Spraying soil stabilizer for planting |
| JP2001104998A (en) * | 1999-10-05 | 2001-04-17 | Kankyo Biken:Kk | Fluid mud immediate effect solidifying agent |
| JP3077061U (en) * | 2000-10-18 | 2001-05-11 | 正志 小池 | Continuous drying equipment |
| JP2002121555A (en) * | 2000-10-18 | 2002-04-26 | Mc Kohsan Co Ltd | Soil stabilizer |
| JP2002256266A (en) * | 2001-02-15 | 2002-09-11 | Soruteko Kk | Soil-conditioning and water-controlling agent for composition using industrial waste as main component and process for preparing the same |
| JP2002338382A (en) * | 2001-05-23 | 2002-11-27 | Soruteko Kk | Fertilizer raw material resource consisting of industrial waste as chief material |
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- 2001-09-04 JP JP2001268087A patent/JP2003096452A/en active Pending
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- 2002-07-18 WO PCT/JP2002/007294 patent/WO2003008517A1/en active Application Filing
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040356B (en) * | 2009-10-21 | 2013-01-16 | 财团法人工业技术研究院 | Light heat-insulating composite particles and preparation method thereof |
| CN102187777A (en) * | 2010-03-19 | 2011-09-21 | 许水茂 | Planting soil and preparation method thereof |
| CN106613476A (en) * | 2016-11-10 | 2017-05-10 | 陈建峰 | Method for cultivating matrix nutrient soil by means of household waste incineration fly ash |
| CN107502362A (en) * | 2017-08-29 | 2017-12-22 | 湖南泰谷生物科技股份有限公司 | The method and its application of acidic soil conditioner are prepared with black liquid |
| CN108329010A (en) * | 2018-02-01 | 2018-07-27 | 东北师范大学 | A kind of hollow porous gap ball-type conditioner suitable for meadow |
| CN108329010B (en) * | 2018-02-01 | 2021-02-26 | 东北师范大学 | Hollow porous spherical moisture regulator suitable for grassland |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003008517A1 (en) | 2003-01-30 |
| JP2003096452A (en) | 2003-04-03 |
| CN1280382C (en) | 2006-10-18 |
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