CN1524416A - N-(4,6-dimethyl pyridine-2-yl) aniline sterilization combination - Google Patents
N-(4,6-dimethyl pyridine-2-yl) aniline sterilization combination Download PDFInfo
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- CN1524416A CN1524416A CNA031558313A CN03155831A CN1524416A CN 1524416 A CN1524416 A CN 1524416A CN A031558313 A CNA031558313 A CN A031558313A CN 03155831 A CN03155831 A CN 03155831A CN 1524416 A CN1524416 A CN 1524416A
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Abstract
The invention discloses a sterilization composition by formula I using N-(4, 6dimethylpyrimidine-2-group) benzeneamine as predominating constituent and containing at least one type of contacting germicidal agent.
Description
The present invention relates to contain the bactericidal composition that N-(4,6-dimethyl pyrimidine-2-yl) aniline compound and some contact bactericide are formed.
N-(4,6-dimethyl pyrimidine-2-yl) aniline is a kind of novel, efficient germicide.It can suppress the secretion of pathogeny mycoprotein matter, comprises reducing some hydrolase levels.
Therefore no cross resistances such as N-(4,6-dimethyl pyrimidine-2-yl) the same triazole type of aniline, dithiocarbamate, benzimidazole and the mould prestige of second all have excellent activity to sensitivity or resistance pathogeny bacterium.If make composition with some contact bactericide, their bactericidal effect can have the increase of surprising degree.
The contact bactericide example that is applicable to composition of the present invention is as follows:
1, anilazine
2, difoltan
3, captan
4, tpn (chlorothalonil)
5, Euparen
6, Delan
7, fentinacetate
8, folpet
9, copper
10, Cupravit
11, mancozeb
12, maneb
13, Carbatene
14, propineb
15, zineb
16, tmtd (thiram)
17, ziram (ziram)
18, ambam (amobam)
19, asomate (asomate)
20, iprodione (iprodione)
21, sulphur
The common name that provides in the above represents to have the compound of following IUPAC title:
(1) 4,6-two chloro-N-(2-chlorphenyl)-1,3,5-triazines-2-amine;
(2) 1,2,3,6-tetrahydrochysene-N-(1,1,2, the 2-tetrachloro is for ethylmercapto group) phthalimide; (3) 1,2,3,6-tetrahydrochysene-N-(trichloro-methylthio) phthalimide;
(4) the different phthalonitrile of tetrachloro;
(5) N-dichloro fluorine methyl mercapto-N ', N '-dimethyl-N-benzene sulfonyl is pressed;
(6) 2,3-dicyan-1,4-dithia-anthraquinone;
(7) acetate fentin;
(8) N-(trichloro-methylthio) phthalimide;
(9) copper;
(10) copper oxychloride;
(11) complex compound of ethylenebis (thiocarbamic acid) manganese and zinc salt;
(12) ethylene bisdithiocarbamic manganese;
(13) ethylenebis [(thiocarbamoyl) disulphide] [zinc ethylene bisdithiocarbamate] polymer;
(14) two (aminodithioformic acid) zinc of polytrimethylene;
(15) ethylenebis (aminodithioformic acid) zinc;
(16) tetramethyl thiuram disulfide;
(17) two (dimethyl dithiocarbamic acid) zinc;
(18) ethylene bisdithiocarbamic ammonium;
(19) three-N-dimethyl dithiocarbamic acid arsenic;
(20) 3-(3, the 5-dichlorophenyl)-N-isopropyl-2,4-dioxo imidazoline-1-carbonyl acid amides;
(21) sulphur.
For composition of the present invention, preferable in the above listed contact bactericide is tpn, Cupravit, mancozeb, tmtd, ziram.
Composition of the present invention can be two combinations, also can be the composition that aforesaid compound forms more than three kinds.
The mechanism of action difference of the various compositions of composition of the present invention, mutually synergy between them, the pesticide resistance of germ reduces, thus the bactericidal effect of composition apparently higher than each component bactericidal effect of single time spent, and fungicidal spectrum is wider.
Composition of the present invention can be used for various crop and prevent and treat multiple diseases, and Ascomycetes, Basidiomycetes, oomycetes subclass and deuteromycetes are all had the good restraining effect.Can be used for grape, fruit tree, vegetables, tomato, cucumber, strawberry, reach ornamental plants etc., double controlling by other germ disease.
The ratio of (4,6-dimethyl pyrimidine-2-yl) aniline compound of the N-of structural formula I in the present composition and contact bactericide is 1: 150～80: 1 based on the parts by weight of active constituent, and the best is 1: 30～30: 1.
Composition of the present invention can also comprise auxiliary agent or filler, and the parts by weight of its shared composition are 0.5%～95%.
Composition of the present invention can wiring solution-forming, emulsion, wetting powder, suspending agent, pulvis, dust agent, paste, soluble powder, granula, microemulsion, missible oil, aerosol, fumicants and sustained release agent.
Composition of the present invention also will add surface reactive materials such as emulsifier, dispersant, wetting agent, to increase stability, wetability, the permeability of composition.
The product that the present invention describes can be the finished product preparation form, and promptly material mixes in the product.Yet the composition of composition also can provide with preparation separately, directly mixes in jar before use.
Composition of the present invention also can contain other active constituent, and for example other has the compound of weeding, desinsection or bactericidal property, also can mix with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Composition of the present invention can use by common method, as pouring into a mould, spray, spray, dust or putting cigarette.
The present composition can illustrate with following embodiment:
The preparation of embodiment 1 wetting powder
N-(4,6-dimethyl pyrimidine-2-yl) aniline 22% (weight)
Carbendazim 30% (weight)
Wetting agent 2% (weight)
Dispersant 8% (weight)
Carrier 38% (weight)
Various components (being solid) are mixed, in airslide disintegrating mill, pulverize and mixing.
The preparation of embodiment 2 aqueous suspensions
N-(4,6-dimethyl pyrimidine-2-yl) aniline 22% (weight)
Triazolone 10% (weight)
Dispersant 2% (weight)
Emulsifier 5% (weight)
Antifreezing agent 5% (weight)
Water 56% (weight)
Various materials are added in the reactor successively, under stirring condition, it is fully mixed, enter sand mill through colloid mill it is repeatedly ground, mix.
The control efficiency of embodiment 3 graw mold of tomato
| Handle | Index before the medicine | Index before the medicine | Average preventive effect | Difference | |
| ??0.05 | ???0.01 | ||||
| 40% (I+ procymidone) WP1000 doubly | ????2.66 | ????1.44 | ????83.40 | ????a | ????A |
| 30% (I) SC1000 doubly | ????3.29 | ????1.69 | ????80.20 | ????a | ????A |
| 50% procymidone WP1000 doubly | ????2.36 | ????1.65 | ????73.00 | ????b | ????B |
| Clear water contrast (CK) | ????2.26 | ????5.85 | ????- | ????c | ????C |
The control efficiency of embodiment 4 pears scab
| Handle | Index before the medicine | Index before the medicine | Average preventive effect | Difference | |
| ??0.05 | ???0.01 | ||||
| 30% (I+ nitrile bacterium azoles) EC2000 doubly | ????2.12 | ????0.74 | ????86.34 | ????a | ????A |
| 40% (I) SC1000 doubly | ????3.09 | ????1.77 | ????77.59 | ????b | ????B |
| 12.5% nitrile bacterium azoles EC3000 doubly | ????2.44 | ????1.45 | ????76.75 | ????b | ????B |
| Clear water contrast (CK) | ????2.68 | ????6.85 | ????- | ????c | ????C |
The control efficiency of embodiment 5 rice sheath blight diseases
| Handle | Index before the medicine | Index before the medicine | Average preventive effect | Difference | |
| ??0.05 | ???0.01 | ||||
| 30% (I+ triazolone) EC1250 doubly | ????3.14 | ????0.66 | ????88.66 | ????a | ????A |
| 20% triazolone EC1500 doubly | ????3.21 | ????1.26 | ????78.82 | ????b | ????B |
| 40% (I) SC1200 doubly | ????4.26 | ????1.91 | ????75.80 | ????b | ????B |
| Clear water contrast (CK) | ????4.08 | ????7.56 | ????- | ????c | ????C |
Claims (7)
1. bactericidal composition, it contains at least a contact bactericide and as shown in the formula the compound of N-(4, the 6-dimethyl pyrimidine-2-yl) aniline of I:
I [N-(4,6-dimethyl pyrimidine-2-yl) aniline/phonetic mould amine]
2. according to the composition of claim 1, wherein the contact bactericide is 4,6-two chloro-N-(2-chlorphenyl)-1,3,5-triazine-2-amine, 1,2,3,6-tetrahydrochysene-N-(1,1,2, the 2-tetrachloro is for ethylmercapto group) phthalimide, 1,2,3,6-tetrahydrochysene-N-(trichloro-methylthio) phthalimide, the different phthalonitrile of tetrachloro, N-dichloro fluorine methyl mercapto-N ', N '-dimethyl-N-benzene sulfonyl is pressed, 2,3-dicyan-1,4-dithia-anthraquinone, the acetate fentin, N-(trichloro-methylthio) phthalimide, copper, copper oxychloride, the complex compound of ethylenebis (aminodithioformic acid) manganese and zinc salt, ethylene bisdithiocarbamic manganese, ethylenebis [(thiocarbamoyl) disulphide] [zinc ethylene bisdithiocarbamate] polymer, two (aminodithioformic acid) zinc of polytrimethylene, ethylenebis (aminodithioformic acid) zinc, tetramethyl thiuram disulfide, two (dimethyl dithiocarbamic acid) zinc, ethylene bisdithiocarbamic ammonium, three-N-dimethyl dithiocarbamic acid arsenic, 3-(3, the 5-dichlorophenyl)-and N-isopropyl-2,4-dioxo imidazoline-1-carbonyl acid amides, sulphur.
3. according to the composition of above-mentioned any one claim, wherein the ratio of compound in structural formula I and contact bactericide is 1: 150 to 80: 1 based on the parts by weight of active component, optimal proportion 1: 40 to 40: 1.
4. composition according to claim 1 also contains other auxiliary agent or filler except that active constituent.
5. composition according to claim 1 also contains surfactant except that active constituent.
6. composition according to claim 1, purposes is a bactericide.
7. composition according to claim 1 can be mixed with solution, wetting powder, suspending agent, pulvis, soluble powder, granula, microemulsion, missible oil, sustained release agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031558313A CN1524416A (en) | 2001-05-15 | 2001-05-15 | N-(4,6-dimethyl pyridine-2-yl) aniline sterilization combination |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031558313A CN1524416A (en) | 2001-05-15 | 2001-05-15 | N-(4,6-dimethyl pyridine-2-yl) aniline sterilization combination |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011180072A Division CN100387128C (en) | 2001-05-15 | 2001-05-15 | Pyrimethanil disinfection composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1524416A true CN1524416A (en) | 2004-09-01 |
Family
ID=34287089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA031558313A Pending CN1524416A (en) | 2001-05-15 | 2001-05-15 | N-(4,6-dimethyl pyridine-2-yl) aniline sterilization combination |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1524416A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101999358A (en) * | 2010-10-13 | 2011-04-06 | 山东农业大学 | Thermal smoke agent containing pyrimethanil and the like for preventing gray mold of greenhouse vegetables |
| CN102907431A (en) * | 2012-11-13 | 2013-02-06 | 利民化工股份有限公司 | Binary compound wettable powder as well as preparation method and application thereof |
| CN106879616A (en) * | 2017-03-13 | 2017-06-23 | 四川群青新材料科技有限公司 | A kind of plastics bactericide for being capable of high-efficiency antimicrobial |
-
2001
- 2001-05-15 CN CNA031558313A patent/CN1524416A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101999358A (en) * | 2010-10-13 | 2011-04-06 | 山东农业大学 | Thermal smoke agent containing pyrimethanil and the like for preventing gray mold of greenhouse vegetables |
| CN102907431A (en) * | 2012-11-13 | 2013-02-06 | 利民化工股份有限公司 | Binary compound wettable powder as well as preparation method and application thereof |
| CN106879616A (en) * | 2017-03-13 | 2017-06-23 | 四川群青新材料科技有限公司 | A kind of plastics bactericide for being capable of high-efficiency antimicrobial |
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