CN1514045A - Plasma body electrolytic deposition method of aluminium alloy cglinder body inner wall ceramic coating and its device - Google Patents
Plasma body electrolytic deposition method of aluminium alloy cglinder body inner wall ceramic coating and its device Download PDFInfo
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- CN1514045A CN1514045A CNA021602093A CN02160209A CN1514045A CN 1514045 A CN1514045 A CN 1514045A CN A021602093 A CNA021602093 A CN A021602093A CN 02160209 A CN02160209 A CN 02160209A CN 1514045 A CN1514045 A CN 1514045A
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Abstract
A process for preparing a coated ceramic layer on the inner surface of Al-alloy cylinder by plasma electrolyzing deposition includes washing said Al-alloy cylinder while removing oil fron it, pumping the electrolyte liquid in the cylinder, which is the solution of sodium phosphate or the mixture of sodium phosphate solution and sodium borate solution, and plasma electrolyzing for 20-150 min by using the cylinder as anode and the stainless steel rod in the cylinder as cathode. Its apparatus is composed of asymmetrical AC power supply, electrolyte liquid pool in cooling pool, and insulating cylinder supporter, circulating pump and U-shaped pipe.
Description
Invention field
The invention belongs to the preparation method and the preparation facilities thereof of aluminium alloy cylinder internal wall ceramic coating, particularly a kind of plasma electrolysis deposition method and device of aluminium alloy cylinder internal wall ceramic coating.
Background technology
The lightweight of automobile, motorcycle is a very important development trend.In order to alleviate the weight of vehicle body, scientific and technical personnel have done a large amount of work.Change the little aluminum alloy materials of density into by the big ferrous materials of density the whole of body material or certain are a part of, can alleviate tare greatly.The weight of engine accounts for very big proportion in tare, the weight that therefore how to alleviate engine has just become the focus of scientific research personnel's thinking.
Because aluminium alloy wears no resistance, change engine into aluminium alloy by original cast iron materials after, if aluminium alloy is not handled,, significantly reduce the work-ing life of engine with the part generation heavy wear that the engine air inside wall of cylinder is contacted with piston.The at present general solution that adopts is to add a Cast iron liner in aluminium alloy engine inside, and piston ring and Cast iron liner rather than rub with aluminum alloy materials can be avoided the wearing and tearing of aluminium alloy like this.The defective that this method exists is: complex process, the while has increased the weight of aluminium alloy cylinder again.
The present invention must not inlay Cast iron liner in aluminium alloy cylinder, directly prepare ceramic layer at the aluminium alloy cylinder inwall, has improved the wear resistance of cylinder body.
Summary of the invention
The object of the invention is to overcome the above-mentioned defective that installs the Cast iron liner existence in the oil engine aluminium alloy cylinder additional, and a kind of plasma electrolysis deposition method for preparing the inboard wall of cylinder block ceramic coating of layer of ceramic film in aluminium alloy cylinder inwall using plasma electrolytic deposition technology is provided.
Another object of the present invention provides a kind of plasma electrolysis deposition apparatus for preparing the aluminium alloy cylinder internal wall ceramic coating of layer of ceramic film in aluminium alloy cylinder inwall using plasma electrolytic deposition technology.
Technical scheme of the present invention is as follows:
The plasma electrolysis deposition method of aluminium alloy cylinder internal wall ceramic coating provided by the invention is characterized in that step is as follows:
1) right aluminium alloy cylinder cleans and the oil removing pre-treatment;
2) electrolytic solution that will be placed in the interior electrolytic solution liquid storage tank of cooling pool pumps in the aluminium alloy cylinder, described electrolytic solution be sodium radio-phosphate,P-32 solution or with the mixing solutions of dobell's solution, the weight percent concentration of described electrolytic solution is 1-10%, wherein, the ratio of sodium phosphate content and Sodium Tetraborate content is 95-100: 5-0; To be placed on a stainless steel bar in the aluminium alloy cylinder as negative electrode, make anode with aluminium alloy cylinder, connect the asymmetry AC power that is attached thereto, plasma electrolysis 20-150 minute; Just the ceramic coating that in aluminium alloy cylinder, prepares one deck 5 μ m--50 μ m.
The forward current density 2.5-10A/dm of the asymmetry AC power that is fed
2, negative current density 0.5-2.5A/dm
2
The plasma electrolysis deposition apparatus of aluminium alloy cylinder internal wall ceramic coating provided by the invention is characterized in that, this plasma electric is separated deposition apparatus and comprised:
One asymmetry AC power, this asymmetry AC power 1 is forward current density 2.5-10A/dm
2, negative current density 0.5-2A/dm
2The asymmetry AC power, this asymmetry AC power has a positive contact and to be connected to the negative electrode of stainless steel bar;
One is placed on the electrolytic solution liquid storage tank in the cooling pool, is provided with one directly over it in order to the fixing insulating support of aluminium alloy cylinder; The upper end installation one of this insulating support is the conduit of ∩ type;
One recycle pump, the liquid-inlet pipe of this recycle pump is arranged in the electrolytic solution liquid storage tank.
The plasma electrolysis deposition method of aluminium alloy cylinder internal wall ceramic coating provided by the invention, technology is simple, easy and simple to handle, its apparatus structure is simple, and preparation one deck ceramic coating on the aluminium alloy cylinder inwall has been avoided inlaying Cast iron liner at the aluminium alloy cylinder inwall easily, solved the wear resistance difficult problem of aluminium alloy cylinder inwall, and prepared ceramic layer has excellent abrasion resistance, can alleviate the wearing and tearing of cylinder body greatly, prolongs the work-ing life of engine.
Description of drawings
The structural representation of the plasma electrolysis deposition apparatus of this aluminium alloy cylinder internal wall ceramic coating that provides clearly is provided accompanying drawing 1;
Accompanying drawing 2 prepares ceramic coating principle of work synoptic diagram for aluminium alloy cylinder 6 is placed on the insulating support 4 with plasma electrolysis deposition method in aluminium alloy cylinder 6;
Wherein: asymmetry AC power 1 cooling pool 2 electrolytic solution liquid storage tanks 3
Insulating support 4 metallic cathodes rod 5 aluminium alloy cylinders 6
Recycle pump 7 conduits 8
Embodiment:
As shown in Figure 1, the plasma electrolysis deposition apparatus of aluminium alloy cylinder internal wall ceramic coating of the present invention comprises:
One asymmetry AC power 1, this asymmetry AC power 1 provides forward current density 2.5-10A/dm
2, negative current density 0.5-2A/dm
2, this asymmetry AC power 1 has a positive contact and to be connected to the negative electrode of stainless steel cathode rod 5;
One is placed on the electrolytic solution liquid storage tank 3 in the cooling pool 2, is provided with one directly over it in order to the fixing insulating support 4 of aluminium alloy cylinder 6; The conduit 8 that also can be the ∩ type in the upper end of this insulating support 4 installation one;
One recycle pump 7, the liquid-inlet pipe of this recycle pump is arranged in electrolytic solution liquid storage tank 3.
During use, at first the aluminium alloy cylinder to engine cleans and the oil removing pre-treatment; Engine aluminum alloy cylinder 6 is fixed in place (electrolytic solution liquid storage tank 3 directly over) with insulating support 4 again, and the positive terminal of asymmetry AC power 1 linked to each other with aluminium alloy cylinder 6, and as anode, stainless steel cathode rod 5 is placed in the aluminium alloy cylinder 6 as negative electrode; The liquid-inlet pipe of recycle pump 7 is placed in the electrolytic solution liquid storage tank 3, and the drain pipe of recycle pump 7 is placed in the aluminium alloy cylinder 6;
During work, ON cycle pump 7, recycle pump 7 is delivered to the electrolytic solution (described electrolytic solution is phosphate solution) of electrolytic solution liquid storage tank 3 in the aluminium alloy cylinder 6, behind the electrolysis hydroful in the aluminium alloy cylinder 6, adopts the mode of outwards overflowing to be back in the electrolytic solution liquid storage tank 3; Also can adopt an end that is ∩ type conduit 8 that will be installed in insulating support 4 upper ends to be placed in the aluminium alloy cylinder 6, the port that is positioned at the inside and outside the other end of aluminium alloy cylinder 6 flushes with the liquid level of the electrolytic solution of aluminium alloy cylinder 6; Cooling pool 2 makes the temperature of the electrolytic solution of electrolytic solution liquid storage tank 3 be no more than the scope of permission, to guarantee the quality of prepared ceramic coating; Connect asymmetry AC power 1, make anode, to be placed on a stainless steel metal rod 5 in the aluminium alloy cylinder as negative electrode, plasma electrolysis 20-150 minute with aluminium alloy cylinder; Just the ceramic coating that in aluminium alloy cylinder, prepares one deck 5 μ m--50 μ m.
The present invention is actually aluminium alloy cylinder as an electrolyzer, and it is again an anode simultaneously.Stainless steel electrode 5 is a negative electrode.Electric current during work between negative electrode, the anode, voltage are controlled by the asymmetry AC power; Increase electrode, can simultaneously treated a plurality of cylinder bodies.
Embodiment 1, prepares ceramic coating with apparatus and method of the present invention in engine aluminum alloy cylinder, and its step is as follows:
1) right aluminium alloy cylinder cleans and the oil removing pre-treatment;
2) electrolytic solution that will be placed in the interior electrolytic solution liquid storage tank of cooling pool pumps in the aluminium alloy cylinder, and described electrolytic solution is sodium radio-phosphate,P-32 solution, and the weight percent concentration of sodium radio-phosphate,P-32 solution is 10%; To be placed on a stainless steel bar in the aluminium alloy cylinder as negative electrode, make anode with aluminium alloy cylinder, connect the asymmetry AC power that is attached thereto,
The forward current density 10A/dm of the asymmetry AC power that present embodiment fed
2, negative current density 2.5A/dm
2
Embodiment 2, prepare ceramic coating with apparatus and method of the present invention in engine aluminum alloy cylinder, and its step is as follows:
1) right aluminium alloy cylinder cleans and the oil removing pre-treatment;
2) electrolytic solution that will be placed in the interior electrolytic solution liquid storage tank of cooling pool pumps in the aluminium alloy cylinder, described electrolytic solution is the mixing solutions of sodium radio-phosphate,P-32 solution and dobell's solution, its concentration is 10%, and the ratio of sodium phosphate content and Sodium Tetraborate content is 98: 2 in electrolytic solution; To be placed on a stainless steel metal rod in the aluminium alloy cylinder as negative electrode, make anode with aluminium alloy cylinder, connect the asymmetry AC power that is attached thereto, plasma electrolysis 60 minutes; Just the ceramic coating that in aluminium alloy cylinder, prepares one deck 15 μ m.
The forward current density 10A/dm of the asymmetry AC power that present embodiment fed
2, negative current density 2.5A/dm
2
Embodiment 3, prepare ceramic coating with apparatus and method of the present invention in engine aluminum alloy cylinder, and its step is as follows:
1) right aluminium alloy cylinder cleans and the oil removing pre-treatment;
2) electrolytic solution that will be placed in the interior electrolytic solution liquid storage tank of cooling pool pumps in the aluminium alloy cylinder, described electrolytic solution is the mixing solutions of sodium radio-phosphate,P-32 solution and dobell's solution, its concentration is 10%, and the ratio of sodium phosphate content and Sodium Tetraborate content is 95: 5 in electrolytic solution; To be placed on a stainless steel bar in the aluminium alloy cylinder as negative electrode, make anode with aluminium alloy cylinder, connect the asymmetry AC power that is attached thereto, plasma electrolysis 150 minutes; Just the ceramic coating that in aluminium alloy cylinder, prepares one deck 50 μ m.
The forward current density 10A/dm of the asymmetry AC power that present embodiment fed
2, negative current density 2.5A/dm
2
Claims (4)
1, a kind of plasma electrolysis deposition method of aluminium alloy cylinder internal wall ceramic coating, its step is as follows:
1) right aluminium alloy cylinder cleans and the oil removing pre-treatment;
3) electrolytic solution that will be placed in the interior electrolytic solution liquid storage tank of cooling pool pumps in the aluminium alloy cylinder, described electrolytic solution be sodium radio-phosphate,P-32 solution or with the mixing solutions of dobell's solution, the weight percent concentration of described electrolytic solution is 1-10%, wherein, the ratio of sodium phosphate content and Sodium Tetraborate content is 95-100: 5-0; To be placed on a stainless steel bar in the aluminium alloy cylinder as negative electrode, make anode with aluminium alloy cylinder, connect the asymmetry AC power that is attached thereto, plasma electrolysis 20-150 minute; Just the ceramic coating that in aluminium alloy cylinder, prepares one deck 5 μ m--50 μ m.
2, the plasma electrolysis by the described aluminium alloy cylinder internal wall ceramic of claim 1 coating deposits. and method is characterized in that the forward current density 2.5--10A/dm of the asymmetry AC power that is fed
2, negative current density 0.5--2A/dm
2
3, the plasma electrolysis deposition apparatus of the described aluminium alloy cylinder internal wall ceramic of a kind of claim 1 coating is characterized in that, this plasma electric is separated deposition apparatus and comprised:
One asymmetry AC power (1), this asymmetry AC power (1) is forward current density 2.5-10A/dm
2, negative current density 0.5-2.5A/dm
2The asymmetry AC power, this asymmetry AC power has a positive contact and to be connected to the negative electrode of stainless steel bar (5);
One is placed on electrolytic solution liquid storage tank (3) in the cooling pool (2) is provided with one directly over it in order to the fixing insulating support of aluminium alloy cylinder (4);
One recycle pump (7), the liquid-inlet pipe of this recycle pump (7) is arranged in electrolytic solution liquid storage tank (3).
By the plasma electrolysis deposition apparatus of the described aluminium alloy cylinder internal wall ceramic of claim 3 coating, it is characterized in that 4, the upper end installation one of described insulating support (4) is the conduit (8) of ∩ type;
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02160209 CN1221686C (en) | 2002-12-31 | 2002-12-31 | Plasma body electrolytic deposition method of aluminium alloy cglinder body inner wall ceramic coating and its device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02160209 CN1221686C (en) | 2002-12-31 | 2002-12-31 | Plasma body electrolytic deposition method of aluminium alloy cglinder body inner wall ceramic coating and its device |
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| CN1514045A true CN1514045A (en) | 2004-07-21 |
| CN1221686C CN1221686C (en) | 2005-10-05 |
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| CN 02160209 Expired - Fee Related CN1221686C (en) | 2002-12-31 | 2002-12-31 | Plasma body electrolytic deposition method of aluminium alloy cglinder body inner wall ceramic coating and its device |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234828A (en) * | 2010-04-28 | 2011-11-09 | 中国科学院力学研究所 | In situ preparation method of self-lubricating ceramic coating on aluminium alloy surface |
| CN102719870A (en) * | 2012-07-04 | 2012-10-10 | 石家庄金刚凯源动力科技有限公司 | Flow rotating combined device for micro-arc oxidation |
| CN103255467A (en) * | 2012-10-25 | 2013-08-21 | 北京太禹天工科技有限公司 | Novel material surface modification method and apparatus |
| CN109371441A (en) * | 2018-11-28 | 2019-02-22 | 中国特种飞行器研究所 | A kind of inner-cavity structure differential arc oxidation method |
| CN110331425A (en) * | 2019-07-08 | 2019-10-15 | 西安理工大学 | A kind of flatwise cylinder holes surface micro-arc oxidation technology equipment |
| CN114214689A (en) * | 2022-01-11 | 2022-03-22 | 山东省科学院新材料研究所 | Method for electrodepositing ceramic coating by bipolar pulse cathode plasma with low current density |
-
2002
- 2002-12-31 CN CN 02160209 patent/CN1221686C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234828A (en) * | 2010-04-28 | 2011-11-09 | 中国科学院力学研究所 | In situ preparation method of self-lubricating ceramic coating on aluminium alloy surface |
| CN102719870A (en) * | 2012-07-04 | 2012-10-10 | 石家庄金刚凯源动力科技有限公司 | Flow rotating combined device for micro-arc oxidation |
| CN102719870B (en) * | 2012-07-04 | 2014-11-12 | 石家庄金刚凯源动力科技有限公司 | Flow rotating combined device for micro-arc oxidation |
| CN103255467A (en) * | 2012-10-25 | 2013-08-21 | 北京太禹天工科技有限公司 | Novel material surface modification method and apparatus |
| CN109371441A (en) * | 2018-11-28 | 2019-02-22 | 中国特种飞行器研究所 | A kind of inner-cavity structure differential arc oxidation method |
| CN110331425A (en) * | 2019-07-08 | 2019-10-15 | 西安理工大学 | A kind of flatwise cylinder holes surface micro-arc oxidation technology equipment |
| CN114214689A (en) * | 2022-01-11 | 2022-03-22 | 山东省科学院新材料研究所 | Method for electrodepositing ceramic coating by bipolar pulse cathode plasma with low current density |
| CN114214689B (en) * | 2022-01-11 | 2023-09-01 | 山东省科学院新材料研究所 | Low current density bipolar pulse cathode plasma electro-deposition ceramic coating method |
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| CN1221686C (en) | 2005-10-05 |
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