CN1486219A - Resin electrode and electrostatic dust collector using the same - Google Patents

Resin electrode and electrostatic dust collector using the same Download PDF

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Publication number
CN1486219A
CN1486219A CNA028031660A CN02803166A CN1486219A CN 1486219 A CN1486219 A CN 1486219A CN A028031660 A CNA028031660 A CN A028031660A CN 02803166 A CN02803166 A CN 02803166A CN 1486219 A CN1486219 A CN 1486219A
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China
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electrode
resin
collecting
electrostatic dust
collect plant
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CN1261227C (en
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三船裕造
深田草平
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Midori Anzen Co Ltd
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Midori Anzen Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • B03C3/60Use of special materials other than liquids
    • B03C3/64Use of special materials other than liquids synthetic resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • B03C3/60Use of special materials other than liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/02Plant or installations having external electricity supply
    • B03C3/04Plant or installations having external electricity supply dry type
    • B03C3/08Plant or installations having external electricity supply dry type characterised by presence of stationary flat electrodes arranged with their flat surfaces parallel to the gas stream
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/02Plant or installations having external electricity supply
    • B03C3/04Plant or installations having external electricity supply dry type
    • B03C3/12Plant or installations having external electricity supply dry type characterised by separation of ionising and collecting stations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/36Controlling flow of gases or vapour
    • B03C3/368Controlling flow of gases or vapour by other than static mechanical means, e.g. internal ventilator or recycler
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • B03C3/41Ionising-electrodes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • B03C3/45Collecting-electrodes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • B03C3/45Collecting-electrodes
    • B03C3/47Collecting-electrodes flat, e.g. plates, discs, gratings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C2201/00Details of magnetic or electrostatic separation
    • B03C2201/04Ionising electrode being a wire

Abstract

Provided is a resin electrode and an electrostatic dust collector using the same which has satisfactory electrical conductivity as an electrode and is excellent in discharge property and dust collecting property. This resin electrode is used for a counter electrode of a discharge electrode and comprises a conductive resin prepared by mixing polyolefin or polyester resin with conductive carbon black.

Description

Resin electrode and use the electrostatic dust collect plant of this resin electrode
Technical field
The present invention relates to the employed resin electrode of counter electrode of corona discharge electrode of the ionization source portion, duplicator, Destaticizing device, ozone generating-device etc. of electrostatic dust collect plant, the collecting electrode of the curren-collecting part of electrostatic dust collect plant, and the electrostatic dust collect plant that uses ionization source portion's counter electrode and curren-collecting part collecting electrode.
Background technology
For example, electrostatic dust collect plant makes electric charge on the dust lane in the air-flow by corona discharge etc., when this charged particle passes through in electric field, and caught and be removed, so the various types from industrial large-scale plant to home-use midget plant obtains using by electrostatic force.
On so electrostatic dust collect plant, usually aluminium, stainless steel and other metal materials are used to make electric charge on the dust particle band ionization source portion counter electrode and catch the collecting electrode of charged particle.
Such electrode constitutes, generally ionization source portion will be relative with corona discharge electrode to counter electrode be that intermediary arranges with the dividing plate, curren-collecting part also be the high voltage side electrode that similarly will apply positive potential or negative potential with relative with it to earth electrode alternately be the structure that intermediary is arranged in parallel with the dividing plate.
But when metallic plate was used for electrode, conductance was good, but had the weight of electrode itself to become heavy problem.
In addition, when metallic plate is used for electrode, need be that intermediary forms stackedly with the multi-disc metallic plate, so the numerous and diverse problem of assembling procedure is arranged with the dividing plate.
So, in order to simplify the assembling procedure of electrode, can consider, and, still the depth of pole plate can not be lengthened to more than the spacing between pole plate, so can not make large-area electrode with by integrally formed electrodes such as panel beating press process without the stacked structure of electrode.In addition, the zone that is made the particle neutral by the bending part of bending etc. and pass through is for example arranged, and the problem that causes dust collecting performance to descend.
In addition, the electrode of being made by metallic plate also exists the high problem of electrode, manufacturing cost that is difficult to make complicated shape.
In order to solve such problem, developed technology with resin manufacture electrode with electric conductivity.
As resin with electric conductivity, can be in resin as base material, for example suitably allocating into, the conductive material of carbon black, carbon fiber, conductive metal palpus crystalline substance and stainless steel fibre etc. obtains.
But, usually to get on very well at present, when allocating the carbon black as conductive material into, the words of not allocating in large quantities just can not obtain as the required low impedance value of counter electrode, and the words of allocating in a large number then make the intensity of resin descend significantly.And, generally be to adopt in ABS resin, to mix the resin electrode of making as the carbon fiber of conductive material.
Because carbon fiber is fibrous,,, but there is the problem that can not obtain enough dust collecting performances even have the advantage that also can obtain required resistance value on a small quantity so compare with granular carbon black.
Therefore, in order to address this problem, the motion of mixing water absorbent polymer in the resin electrode of being made up of the ABS resin of allocating carbon fiber into has again been carried (the special flat 08-227789 communique of opening).
This electroconductive resin that mixes water absorbent polymer has on the surface of resin the uniform conductive performance is arranged, and easily conducting can reduce the advantage of the amount of carbon fiber of mixing resin.
But, mixed the resin electrode of water absorbent polymer, under the condition of high humiture (than 15 ℃, 30% height), can obtain the characteristic and the good resin electrode of performance of dust catching efficiency and flash-over characteristic etc., but under the condition of low humiture (15 ℃, 30% below), the problem of characteristic and performance decline is arranged then.
Summary of the invention
The object of the present invention is to provide a kind of as electrode, the have resin electrode of sufficient electric conductivity and flash-over characteristic and control of dust characteristic good and the electrostatic dust collect plant that uses this resin electrode.
The result who studies in order to achieve the above object and repeatedly, when finding to use carbon fiber as conductive material, because the discontiguous each other words of conductive material just can't conducting, so fiber is disposed in resin randomly, and make the contact that electricity is arranged between the conductive material, still such result is, because resin surface is uneven from microcosmic, so can not discharge equably, and dust collecting effect reduces.In addition, carbon black is with respect to the ABS resin that generally uses as resin electrode at present, the tendency that dispersiveness is undesirable and intensity is low is arranged, can not obtain electric conductivity, intensity and mouldability on the realistic scale, but found given electrical conductivity Carbon black, even dispersion and surface state also are not concentrate on some point and easily become even distribution from microcosmic equably with respect to specific resin such as polypropylene, can obtain good flash-over characteristic and control of dust characteristic, thereby finish the present invention.
A first aspect of the present invention is the resin electrode that is used for the counter electrode of sparking electrode, it is characterized in that: be made of the electroconductive resin of allocating electrical conductivity Carbon black in polyolefin or mylar into.
In first aspect,, electrical conductivity Carbon black is distributed equably by polyolefin or mylar being used for resin as base material.In addition, resin surface also is uniformly from microcosmic, so can obtain uniform flash-over characteristic, has also improved the control of dust characteristic.
A second aspect of the present invention is that the resin electrode in the first aspect is characterised in that: the nitrogen specific area of above-mentioned electrical conductivity Carbon black is 500m 2More than/the g, the DBP oil absorption is 200cm 3More than/the 100g.
In second aspect, in polyolefin or mylar, can disperse well, thereby can evenly discharge.
A third aspect of the present invention is, first or second aspect in resin electrode be characterised in that: specific insulation is 10 7Below the Ω cm order of magnitude.
In the third aspect, by the even dispersion of electrical conductivity Carbon black, the specific insulation that can obtain stipulating.
A fourth aspect of the present invention is, the resin electrode in first~the 3rd in the either side is characterised in that: the counter electrode as the sparking electrode that is connected in positive potential uses.
In fourth aspect,, can obtain good control of dust characteristic by the counter electrode of resin electrode as the sparking electrode that is connected in positive potential used.
A fifth aspect of the present invention is, the resin electrode in first~the 4th in the either side is characterised in that: be used for having the ionization source portion counter electrode of the curren-collecting part collecting electrode of the counter electrode of corona discharge electrode, electrostatic dust collect plant and the one-piece type electrostatic dust collect plant of ionization source-dust arrester and curren-collecting part collecting electrode function electrode any.
In aspect the 5th,, can obtain good control of dust characteristic by resin electrode of the present invention is used as these electrodes.
A sixth aspect of the present invention is electrostatic dust collect plant, it is characterized in that: the counter electrode of the resin electrode in the either side in first~the 5th as ionization source portion used.
In aspect the 6th,, can improve the control of dust characteristic by the uniform resin electrode of flash-over characteristic is used as counter electrode.
A seventh aspect of the present invention is electrostatic dust collect plant, it is characterized in that: utilize the resin electrode of either side in first~the 5th, the counter electrode of ionization source portion and the collecting electrode of curren-collecting part are formed as one.
In aspect the 7th, by counter electrode and collecting electrode are formed as one, thereby reduce manufacturing cost significantly and increase dust-collecting area improve dust catching efficiency in, can improve the intensity of electrode and prevent distortion etc.
In the present invention, by the electrical conductivity Carbon black of regulation is allocated in polyolefin or the mylar, electrical conductivity Carbon black can not concentrated on some point and dispersion equably, even consequently resin surface also is obviously uniformly from microcosmic, can obtain good flash-over characteristic and control of dust characteristic.
As vistanex, can enumerate for example polypropylene (PP), polyethylene (PE) etc. here.
In addition, as mylar, can enumerate for example polybutylene terephthalate (PBT) (PBT), PETG (PET).
Such resin, different with ABS resin, electrical conductivity Carbon black is disperseed equably, and the intensity of resin self also seldom reduces.
In addition, though as long as electrical conductivity Carbon black is disperseed equably and has excellent conducting performance, do not do special qualification in these resins, the preferred nitrogen specific area is 500m 2More than/the g, the DBP oil absorption is 200cm 3More than/the 100g.Thus, infer and to obtain good dispersiveness and electric conductivity.
As such electrical conductivity Carbon black, can enumerate for example ケ ッ チ ェ Application Block ラ ッ Network (trade name).
In addition, though the granularity of such electrical conductivity Carbon black is not done special qualification, below the μ m order of magnitude, be preferably nm order of magnitude degree.Owing to have such particle diameter, can in resin, disperse equably, can bring into play even discharge and good control of dust characteristic.
The specific insulation of the resin electrode that is made of the resin that has added electrical conductivity Carbon black is 10 like this 7Be desirable below the cm order of magnitude.Because can obtain good flash-over characteristic and control of dust characteristic like this.
In order to make resin electrode moulding of the present invention, need to use the resin of having allocated electrical conductivity Carbon black into, and for electrical conductivity Carbon black being allocated in the resin as base material, by for example utilizing two roller mixing rolls, Banbury, continuous mixer etc. and pressing the usual way melting mixing, can modulate.In this case, preferably allocate into respect to electrical conductivity Carbon black as the 18 weight %~30 weight % of the resin of base material.Lack than this amount of allocating into, can not obtain desirable electric conductivity, thereby can not obtain good flash-over characteristic and control of dust characteristic.Than the then mechanical strength decline of electroconductive resin of these words of Duoing.When particularly using, generally to allocate fire retardant into, but allocate the tendency that fire retardant is compared with the situation of only allocating electrical conductivity Carbon black in resin into has mechanical strength to descend into as safety measure as the electrode of electrostatic dust collect plant.If mechanical strength is also lower than intensity at this moment, when the electrode filth that causes owing to control of dust being cleaned with assembling operation, do not carry out special operation and will damage electrode etc., the advantage of the electrostatic dust collect plant that electrode uses repeatedly will be lost by cleaning.
Resin electrode of the present invention can be made by the resin forming that above-mentioned such usefulness has been allocated electrical conductivity Carbon black into, and needn't limit forming method.For example get final product with moulding such as injection mo(u)lding, punch formings.In addition, the resin electrode of making the so of the present invention collecting electrode that can be used for the counter electrode of the ionization source portion of electrostatic dust collect plant, the counter electrode of giving ionization source portion and curren-collecting part is with the one-piece type electrode of the ionization source/dust arrester of common electric potential etc.
Description of drawings
Fig. 1 is the schematic diagram of an example of the electrostatic dust collect plant of expression embodiment of the present invention 1.
Fig. 2 is the exploded perspective view of an example of the electrostatic dust collect plant of expression embodiment of the present invention 2.
Fig. 3 is the schematic diagram of Fig. 2.
Fig. 4 is the plane that expression the present invention tests the test method of example 1.
Fig. 5 is the plane that expression the present invention tests the test method of example 2.
The specific embodiment
Below, describe formation of the present invention in detail.
(embodiment 1)
Fig. 1 is the schematic diagram of an example of the electrostatic dust collect plant of the expression resin electrode that uses embodiment of the present invention 1.
As shown in Figure 1, electrostatic dust collect plant 1 has: the conduct that is made of sparking electrode 11 and counter electrode 12 thereof powers up the ionization source portion 10 of portion; By when sparking electrode 11 is connected with positive potential, the curren-collecting part 20 that constitutes of the non-collecting electrode 21 that relatively is connected and the collecting electrode 22 that relatively is connected as dust collecting part with negative potential with positive potential.In addition, when sparking electrode 11 was connected with negative potential, non-collecting electrode 21 relatively was connected with negative potential, and collecting electrode 22 relatively is connected with positive potential.
Ionization source portion 10 is set up in parallel a plurality of flat counter electrodes 12 and conducting mutually, between each counter electrode 12, to dispose sparking electrode 11 with counter electrode 12 discontiguous modes.
In addition, curren-collecting part 20 is set up in parallel a plurality of flat collecting electrodes 22 in the downstream of ionization source portion 10, and flat non-collecting electrode 21 is set respectively between each collecting electrode 22.That is, curren-collecting part 20 alternatively is set up in parallel collecting electrode 22 and non-collecting electrode 21.
In addition, collecting electrode 22 can not directly contact with non-collecting electrode 21.In addition, non-collecting electrode 21 is except that power supply, and it is desirable not contacting with casing etc. with framework.This is because insulant surfaces such as framework by electrostatic dust collect plant 1 and casing ground connection indirectly can cause that current potential descends.
In such embodiment, ionization source portion 10 and curren-collecting part 20 are formed by the combination of sparking electrode 11, counter electrode 12, non-collecting electrode 21 and collecting electrode 22, and counter electrode 12 and collecting electrode 22 are 10 by specific insulation 7The following electroconductive resin material of the Ω cm order of magnitude forms, and non-collecting electrode 21 is 10 by specific insulation 10~10 13The semiconduction resin material of Ω cm forms, and this is preferred.
In the ionization source portion 10 and curren-collecting part 20 that constitute like this, even being mixed in, the electric conductivity dust is ionized in the dust particle that source portion 10 added electric charge, because the electric charge of non-collecting electrode 21 moves by the resistance of semiconduction resin material and limits, so can prevent flashing between non-collecting electrode 21 and the collecting electrode 22.
By constitute the counter electrode 12 of so electrostatic dust collect plant 1 with the polyolefin of having allocated electrical conductivity Carbon black into or mylar, can obtain the electrostatic dust collect plant 1 that discharge performance is good, dust collecting performance is good.
Certainly, collecting electrode 22 can constitute with the polyolefin of having allocated electrical conductivity Carbon black into or mylar too.
In addition, sparking electrode 11, with regard to electrostatic dust collect plant, can use well-known line formula or pin type, as the semiconduction resin material that forms non-collecting electrode 21, do not need special restriction, for example can enumerate resin system electrode of in ABS resin, allocating conductive material into or also allocating water-absorbing resins into etc.
In addition, in the present embodiment, only represented dust collecting part and powered up portion as electrostatic dust collect plant 1, and this electrostatic dust collect plant 1 also makes the suction apparatus and the air-supply arrangement of air draught simultaneously, assembling is also used aircleaning facility, cold and warm air-conditioner, air attemperation apparatus etc.
(embodiment 2)
Fig. 2 is the exploded perspective view of an example of the electrostatic dust collect plant of the expression resin electrode that uses embodiment of the present invention 2.Fig. 3 is its schematic diagram.
As shown in Figures 2 and 3, electrostatic dust collect plant 1A has: the conduct that is made of sparking electrode 11A and counter electrode 12A thereof powers up the 10A of ionization source portion of portion; The curren-collecting part 20A that constitutes by non-collecting electrode 21A that when sparking electrode is connected in positive potential, relatively is connected and the collecting electrode 22A that relatively is connected with negative potential with positive potential.In addition, when sparking electrode 11A was connected with negative potential, the current potential of setting each electrode in the same manner with above-mentioned embodiment 1 got final product.
The counter electrode 12A of the 10A of ionization source portion and the collecting electrode 22A of curren-collecting part 20A have writing board shape, on the face of counter electrode 12A with the framework 35 that is arranged on the air that makes the dust particle that contains collection to the outstanding mode of airflow direction side by side and passes through, on the face of the opposite side of framework 35, collecting electrode 22A is being provided with side by side with counter electrode 12A's and on the perpendicular direction of column direction and is forming as one.
By counter electrode 12A and collecting electrode 22A are formed as one, can increase dust-collecting area like this, improve the arresting efficiency of charged particle.In addition, by being set up in parallel, counter electrode 12A and collecting electrode 22A can improve intensity on orthogonal direction, both can prevent from the warpage of each electrode and scratch to become distortion, also, can make electrostatic dust collect plant 1A do compactlyer owing to the space that does not need between counter electrode 12A and the collecting electrode 22A.
The non-collecting electrode 21A of curren-collecting part 20A has and can insert logical collecting electrode 22A and make collecting electrode 22A and non-collecting electrode 21A does not contact with each other such peristome that forms 25 with the interval of equalization.By collecting electrode 22A being inserted equably the peristome 25 of this non-collecting electrode 21A, can form the curren-collecting part 20A that can between non-collecting electrode 21A and collecting electrode 22A, apply uniform electric field.
In addition, the sparking electrode 11A that constitutes the ionization source 10A of portion be arranged on counter electrode 12A with the chimeric fitting portion 13 of framework 35 relative to the position on, between it, can insert logical counter electrode 12A.That is, go into framework 35 with fitting portion 13 is chimeric, counter electrode 12A is inserted between the sparking electrode 11A that is arranged on the fitting portion 13 with the interval of equalization and is fixed.
By with having allocated counter electrode 12A that becomes one and the collecting electrode 22A that the polyolefin of electrical conductivity Carbon black or mylar constitute so electrostatic dust collect plant 1A into, can obtain that flash-over characteristic is good, the electrostatic dust collect plant 1A of control of dust characteristic good.
(embodiment 1)
The electroconductive resin that 30 weight % make as the ケ ッ チ ェ Application Block ラ ッ Network (CB) of electrical conductivity Carbon black has been allocated in use in acrylic resin into and moulding makes the resin electrode of 100mm * 26mm * 0.8mm (thickness).Specific insulation is 10 0~10 1Ω cm.
(embodiment 2)
The electroconductive resin that 20 weight % make as the ケ ッ チ ェ Application Block ラ ッ Network (CB) of electrical conductivity Carbon black has been allocated in use in polybutylene terephthalate (PBT) (PBT) into and moulding makes the resin electrode of 100mm * 26mm * 0.8mm (thickness).Specific insulation is 10 3Ω cm.
(embodiment 3)
The electroconductive resin that 18 weight % make as the ケ ッ チ ェ Application Block ラ ッ Network (CB) of electrical conductivity Carbon black has been allocated in use in acrylic resin into and moulding makes the resin electrode of 100mm * 26mm * 0.8mm (thickness).Specific insulation is 10 5Ω cm.
(comparative example 1)
The electroconductive resin that 20 weight % carbon fibers (CF) make has been allocated in use in polybutylene terephthalate (PBT) (PBT) into and moulding makes the resin electrode of 100mm * 26mm * 3.0mm (thickness).Specific insulation is 10 3Ω cm.
(comparative example 2)
The electroconductive resin that 20 weight % carbon fibers (CF) make has been allocated in use in ABS resin into and moulding makes the resin electrode of 100mm * 26mm * 0.8mm (thickness).Specific insulation is 10 1~10 2Ω cm.
(comparative example 3)
The electroconductive resin that 15 weight % make as the ケ ッ チ ェ Application Block ラ ッ Network (CB) of electrical conductivity Carbon black has been allocated in use in acrylic resin into and moulding makes the resin electrode of 100mm * 26mm * 0.8mm (thickness).Specific insulation is 10 8Ω cm.
(test example 1)
Carry out the mensuration of flash-over characteristic as counter electrode with the resin electrode of embodiment 1~3 and comparative example 1~3.
As shown in Figure 4, the mensuration of flash-over characteristic is carried out as follows, promptly, with resin electrode as counter electrode 12B, spaced and parallel setting with 14mm, at the center the superfine sparking electrode 11B that is made of metal (tungsten) line is set, it is just discharged, repeatedly bioassay standard operating point (20 μ m) is located applies voltage.
The voltage that applies with this moment is estimated flash-over characteristic with respect to the ratio that applies the voltage determination value at metal counter electrode place.Its result is shown in the following table 1 as the value that comprises the deviation part.
As metewand, preferably satisfy following formula (1), with this as qualified benchmark.In addition, represent that the situation of this benchmark flash-over characteristic in addition is,, the so-called anti-ionization phenomena of the electrically charged hardly grade of dust particle takes place, can not play a role with regard to electrostatic dust collect plant as the sparking electrode 11A vibration of metal wire.
(formula 1)
Figure A0280316600111
Table 1
Base resin Conductive material The amount of allocating into of conductive material (weight %) Flash-over characteristic (15 ℃, 27%RH) Flash-over characteristic (20 ℃, 65%RH)
Embodiment 1 ??PP ??CB ????30 ????1.(0)±0.01 ????1.00±0.01
Embodiment 2 ??PBT ??CB ????20 ????1.00±0.01 ????1.00±0.01
Embodiment 3 ??PP ??CB ????18 ????1.00+0.03 ???????~ ????1.00-0.01 ????1.00±0.01
Comparative example 1 ??PBT ??CF ????20 Anti-ionization (0.84) takes place Anti-ionization (0.90) takes place
Comparative example 2 The ABS resin The CF+ water-absorbing resins ????20 Anti-ionization (0.90) takes place ????1.00±0.01
Comparative example 3 ??PP ??CB ????15 Anti-ionization (1.12) takes place Anti-ionization (1.09) takes place
As shown in Table 1, embodiment 1,2 and 3 the counter electrode 12B that in vistanex or mylar, has allocated electrical conductivity Carbon black into, any one can obtain the stability in discharge in the benchmark.In addition, comparative example 1 in acrylic resin on allocated the counter electrode of carbon fiber into, anti-ionization phenomena has taken place.
In addition, the result who on the electrode of embodiment 1, uses the condition identical to carry out continuous discharge with the flash-over characteristic determination test, even carried out continuously 3000 hours, flash-over characteristic is no change also, even and continue also do not have generation problem (continuing now) for more time.In addition, the rare ozone that causes because of corona discharge as electrostatic dust collect plant, is comparatively ideal when just discharging.
(test example 2)
Observe the surface of the resin electrode of embodiment 1,3 and comparative example 1 with SEM.Consequently, the surface of the resin electrode of embodiment 1 is smooth, can confirm the conducting state on surface, do not observe the particle of carbon black, and on the resin electrode of comparative example 1, can observe carbon fiber, can observe position and non-existent position that carbon fiber exists significantly, can differentiate the part of conducting and the part of not conducting.
With regard to embodiment 3, smooth degree, the conducting state on surface are identical with embodiment 1, can not observe the particle of carbon black equally, and also not have the difference on discovery and the surface observation of embodiment 1.
(test example 3)
The counter electrode 12B that resin electrode with embodiment 1, embodiment 3, comparative example 2 and comparative example 3 is constituted has carried out performance evaluation.
Performance evaluation is, to the SEM observation of the dust catching efficiency under 15 ℃, the condition of humidity 27%RH, surface state, the discharging efficiency of the moulding product of each counter electrode 12B when packing electrostatic dust collect plant into is measured.It the results are shown in the following table 2.
In addition, the mensuration of dust catching efficiency as shown in Figure 5, is provided with the represented identical electrostatic dust collect plant 1B of structure among the Fig. 2 with the counter electrode 12B that is provided with embodiment 1 on being arranged at flue 40 necking part 41 in the middle of approximately.Send into particulate material from the one side with air-supply arrangement 50, measure amount preceding by electrostatic dust collect plant 1B and by the particulate material behind the electrostatic dust collect plant 1B.
Be exactly in detail,, produce the control of dust particle that forms by DOP (dioctyl phthalate) with particle generator 42 in air-supply arrangement 50 1 sides of flue 40, by air-supply arrangement 50 with 1.3m 3The air quantity of/min makes it pass through electrostatic dust collect plant 1B.
With particle weight analyzer 45 before the control of dust of flue 40 behind particle acquisition port 43 and the control of dust particle acquisition port 44 measure this moment pass through preceding and pass through after particle weight (population).
And the particle diameter of the particulate material that particle generator 42 produces is 0.3~0.5 μ m.Particle weight is 1500~3000/L (liter) before the control of dust, calculates dust catching efficiency by such measurement result by following formula (2).It the results are shown in the following table 2.
(formula 2)
Table 2
Conductive material Flash-over characteristic (15 ℃, 27%RH) Flash-over characteristic (20 ℃, 65%RH)
Embodiment 1 ??CB 85 is stable 85 is stable
Embodiment 3 ??CB 85 is stable 85 is stable
Comparative example 2 The CF+ water-absorbing resins 72 instabilities 85 is stable
Comparative example 3 ??CB ????28 ??????28
As known from Table 2, embodiment 1 and 3 resin electrode be not subjected to ambient condition about but stable, and shown high dust collecting performance, but the resin electrode of comparative example 2 is in low humiture next part dirt decrease in efficiency, and measure numerical value all to be deviation be the above such labile state of evaluated error scope at every turn.
In addition, the obvious step-down of the dust collecting performance of the resin electrode of comparative example 3.This is considered to cause that owing to the quantity not sufficient of allocating into of conductive material dust collecting performance does not reach required value (for example, 80%).
Industrial utilizability
As described above, in the present invention, consist of resin electrode by being used in as the electroconductive resin of having allocated electrical conductivity Carbon black in the polyolefin of substrate resin or the mylar into, electrical conductivity Carbon black does not concentrate on some point and Uniform Dispersion, shown electric conductivity, thus be not subjected to ambient condition about but stable, can realize uniform discharge, and with the electrostatic dust collect plant of this resin electrode as counter electrode, can improve dust catching efficiency.

Claims (7)

1. resin electrode that is used for the counter electrode of sparking electrode is characterized in that: the electroconductive resin by the electrical conductivity Carbon black of having allocated in polyolefin or mylar constitutes.
2. resin electrode as claimed in claim 1 is characterized in that: the nitrogen specific area of described electrical conductivity Carbon black is 500m 2/ g is above, the DBP oil absorption is 200cm 3More than/the 100g.
3. resin electrode as claimed in claim 1 or 2 is characterized in that: specific insulation is 10 7Below the Ω cm order of magnitude,
4. as each described resin electrode in the claim 1~3, it is characterized in that: the counter electrode as the sparking electrode that is connected in positive potential uses.
5. as each described resin electrode in the claim 1~4, it is characterized in that: any of electrode that can be used for having the function of the ionization source portion counter electrode of the curren-collecting part collecting electrode of the counter electrode of corona discharge electrode, electrostatic dust collect plant and the one-piece type electrostatic dust collect plant of ionization source-dust arrester and curren-collecting part collecting electrode.
6. one kind is used in the claim 1~5 each described resin electrode as the electrostatic dust collect plant of the counter electrode of ionization source portion.
7. electrostatic dust collect plant that utilizes each described resin electrode in the claim 1~5, the collecting electrode of the counter electrode of ionization source portion and curren-collecting part is formed as one.
CNB028031660A 2001-05-02 2002-05-02 Resin electrode and electrostatic dust collector using the same Expired - Fee Related CN1261227C (en)

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JP3729403B2 (en) 2005-12-21
CN1261227C (en) 2006-06-28

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