CN1481780A - Cosmetic composition - Google Patents

Cosmetic composition Download PDF

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Publication number
CN1481780A
CN1481780A CNA031545173A CN03154517A CN1481780A CN 1481780 A CN1481780 A CN 1481780A CN A031545173 A CNA031545173 A CN A031545173A CN 03154517 A CN03154517 A CN 03154517A CN 1481780 A CN1481780 A CN 1481780A
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Prior art keywords
surfactant
cosmetic composition
straight
tert
oxyethylene group
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CNA031545173A
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CN1326513C (en
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中西纪元
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Ajinomoto Co Inc
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Ajinomoto Co Inc
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/45—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Abstract

A cosmetic composition which comprises the following ingredients: (A) one or more types of surfactant selected from the group consisting of surfactants which have an oxyethylene group in the molecule (for example, a surfactant represented by [R<1>(OCH2CH2)n-OSO3]<->M<+> (R<1> represents an C7-21 alkyl group and the like, n represents an integer of 1 to 30, and M represents Na, K, NH4, or triethanolamine)); (B) tert-butanol. In the cosmetic composition, the smell change or the odor generation with passage of time caused by addition of a surfactant having an oxyethylene group in the molecule is suppressed, and thus the cosmetic composition with high storage stability is provided.

Description

Cosmetic composition
Technical field
The present invention relates to cosmetic composition.In more detail, the present invention relates to contain at intramolecularly and have the surfactant of oxyethylene group and the cosmetic composition of the tert-butyl alcohol.
Background technology
Intramolecularly has oxyethylene group (CH 2CH 2O-) surfactant is widely used in the cosmetics such as skin abluent, hair detergent, emulsifying agent.For example, use alkyl ether sulfate in skin abluent or the hair detergent,, be extensive use of polyoxyethylene glyceride or polyoxyethylene alkyl ether etc. as emulsifying agent.But, when in cosmetics, cooperating intramolecularly to have the surfactant of oxyethylene group, owing to exist oxyethylene group to distinguish the flavor of into problem through the spoiled or band that causes in time.Up to now, in order to solve problem spoiled or the band flavor, cooperate odor mask, chelating agen or the antioxidant etc. that adopt spice always.
Summary of the invention
Problem of the present invention is, a kind of cosmetic composition is provided, and wherein it is to contain the cosmetics that have the surfactant of oxyethylene group at intramolecularly, can alleviate or eliminate the spoiled or band flavor through causing in time.The inventor has carried out concentrated research in order to solve above-mentioned problem, found that by add the tert-butyl alcohol in containing the cosmetics of surfactant that intramolecularly has oxyethylene group, can significantly suppress the spoiled or band flavor through causing in time.The present invention just is based on that above-mentioned discovery finishes.
That is to say, the invention provides a kind of cosmetic composition, wherein contain following compositions:
(A) has the surfactant of selecting the surfactant of oxyethylene group more than a kind or 2 kinds from intramolecularly; And
(B) tert-butyl alcohol.
Optimal way according to foregoing invention, the surfactant that provides intramolecularly to have oxyethylene group is the above-mentioned cosmetic composition of 1～20 weight % with respect to composition total weight, and the tert-butyl alcohol is the above-mentioned cosmetic composition of 0.01～1000 ppm by weight with respect to composition total weight.
In addition, according to more preferably mode of the present invention, provide above-mentioned cosmetic composition, wherein to have the surfactant of oxyethylene group be the surfactant of selecting from following surfactant more than a kind or 2 kinds to intramolecularly:
The surfactant of following general formula (1) expression,
〔R 1(OCH 2CH 2) n-OSO 3〕 -M +
(in the formula, R 1The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21, n represents 1～30 integer, M represents Na, K, NH 4Or triethanolamine);
The surfactant of following general formula (2) expression,
R 2CO-NH(CH 2CH 2O) mH
(in the formula, R 2The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21, m represents 1～10 integer); And
The surfactant of following general formula (3) expression,
R 3CO-N(CH 2CH 2OH) 2
(in the formula, R 3The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21).
From another viewpoint, the invention provides a kind of inhibition contain intramolecularly have oxyethylene group surfactant cosmetics in time through and the method for spoiled or band flavor, this method is included in the step of adding the tert-butyl alcohol in these cosmetics, according to optimal way of the present invention, provide the said method that adds the tert-butyl alcohol with the ratio that is 0.01～1000 ppm by weight with respect to this cosmetic composition gross weight, and the surfactant that intramolecularly has an oxyethylene group is from above-mentioned general formula (1), the said method of the surfactant of selecting in the surfactant of general formula (2) and general formula (3) expression more than a kind or 2 kinds.Further from another viewpoint, the present invention also provides a kind of inhibitor that has the spoiled or band flavor that the cosmetics of the surfactant of oxyethylene group cause because of effluxion at intramolecularly that contains, and this inhibitor contains the tert-butyl alcohol.
The best mode that carries out an invention
Cosmetic composition of the present invention is characterised in that, contains (A) and has the surfactant of selecting the surfactant of oxyethylene group more than a kind or 2 kinds from intramolecularly; And (B) tert-butyl alcohol, suppress the spoiled or band flavor of process in time by mentioned component (B) tert-butyl alcohol.So-called spoiled or band flavor is meant that the abnormal smells from the patient of compositions changes, and should do the most generalized explanation, comprise increasing stink beastly, and tasteless compositions produces any abnormal smells from the patient etc., and any implication all should not done limited explanation.In addition, so-called suppress spoiled or the band flavor, remove alleviate spoiled or the band flavor, also comprise and avoid spoiled in fact fully or band is distinguished the flavor of.
Has the surfactant of oxyethylene group if having 1 above oxyethylene group (CH at intramolecularly 2CH 2O-), then its kind is not particularly limited.The oxyethylene group that intramolecularly contains is polyoxyethylene groups preferably.More particularly, for example can list polyoxyethylene alkyl ether sulfate salt, polyoxyethylene nonylplenyl ether sulfate, polyxyethylated sulfosuccinate, polyoxyethylene alkyl ether acetate, polyoxyethylene alkyl ether phosphoric acid, polyoxyethylene alkyl phenyl ether phosphoric acid, fatty diglycollic amide, fatty acid one glycollic amide, distearyl acid polyethylene glycol ester, polyoxyethylene alkyl ether, the polyoxyethylene nonylplenyl ether, the aliphatic acid polyethenoxy alkyl ether, aliphatic acid polyethenoxy glyceride, polyoxyethylene hardened castor oil, the aliphatic acid polyethenoxy hardened castor oil, the aliphatic acid polyethenoxy Isosorbide Dinitrate, or polyoxyethylene methyl polysiloxane copolymer etc.Can use surfactant separately, but also can be used in combination more than 2 kinds with oxyethylene group.
As surfactant, particularly preferably be the surfactant of from following surfactant, selecting more than a kind or 2 kinds with oxyethylene group:
The alkyl ether sulfate of following general formula (1) expression,
〔R 1(OCH 2CH 2) n-OSO 3〕 -M +
(in the formula, R 1The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21, n represents 1～30 integer, M represents Na, K, NH 4Or triethanolamine);
The alkanolamide of following general formula (2) expression,
R 2CO-NH(CH 2CH 2O) mH
(in the formula, R 2The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21, m represents 1～10 integer); And
The N-acyl group diglycollic amide of following general formula (3) expression,
R 3CO-N(CH 2CH 2OH) 2
(in the formula, R 3The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21).
In the above-mentioned general formula, R 1, R 2And R 3Any that alkyl that the carbon number of expression is 7～21 or alkenyl can be straight or branched is the occasion of branched alkyl, and ramose number is not particularly limited.The two key numbers that exist in the alkenyl also are not particularly limited, and are about 1～4, and preferred about 1～2, contain the occasion of pair keys more than 2, these pairs key also can be a conjugated double bond.
In the general formula (1), preferred R 1Be the straight or branched thiazolinyl of 11～15 of the straight or branched alkyl of 11～15 of carbon numbers or carbon numbers, M is Na, NH 4Or triethanolamine.More particularly, for example preferred polyoxyethylene (3) alkyl (12～14) ether sodium sulfate or polyoxyethylene (2) alkyl (12,13) ether sodium sulfate etc.
In the general formula (2), preferred R 2Be the straight or branched thiazolinyl of 9～18 of the straight or branched alkyl of 9～18 of carbon numbers or carbon numbers, m is 1, more preferably R 2Be the straight or branched thiazolinyl of 10～14 of the straight or branched alkyl of 10～14 of carbon numbers or carbon numbers, m is 1.More particularly, for example preferred coco-nut oil fatty acid one glycollic amide or lauric acid one glycollic amide etc.
In the general formula (3), preferred R 3Straight or branched thiazolinyl for 9～18 of the straight or branched alkyl of 9～18 of carbon numbers or carbon numbers.More particularly, for example preferred cocoanut fatty acid diethanolamide or lauric acid diethyl amide etc.
Intramolecularly has the use level of surfactant in cosmetic composition of oxyethylene group and can suitably be determined by those skilled in the art according to the kind of cosmetics and required character etc., there is no particular limitation, usually can use the scope of 0.1～50 weight % with respect to the gross weight of cosmetic composition, the scope of preferred 1～20 weight %.In addition, when the use level of above-mentioned surfactant was lower than 1 weight %, process caused that problem spoiled or the band flavor obtains general alleviating in time, thereby because alleviating of this problem no longer needs to add the tert-butyl alcohol sometimes.
There is no particular limitation for the use level of the tert-butyl alcohol in cosmetic composition, and for example preferred gross weight with respect to compositions is 0.01～1000 ppm by weight.If the use level of the tert-butyl alcohol is lower than 0.01 ppm by weight, then sometimes for insufficient through causing inhibition spoiled or the band flavor in time, if surpass 1000 ppm by weight, then the distinctive abnormal smells from the patient of the tert-butyl alcohol can be a problem sometimes.
There is no particular limitation for the kind of cosmetic composition of the present invention, for example can be used as shampoo, the hair rinse agent, two-in-one shampoo, hair detergents such as conditioning shampoo, become visible, hair conditioner, hair physical therapy agent (hair treatment), suppurative mastitis, hair jelly, shampoo, pomade, flood, the hair style agent, permanent wave solution, hair dye, acidic hair coloring preparation, hair is pruned agent various hair cosmetic compositions such as (hair manicure), perhaps astringent, emulsion, the agent of washing one's face, the makeup removing agent, the cleaning lotion, moisturizer, moisturizer, skin lotion, massage cream, facial cleaning cream, body shampoo, the hands soap, Gu shape soap, shave and use cream, sun care preparations, deodorant powder, the deodorization lotion, deodorization spraying, the makeup removing gel, the gel of preserving moisture, the essence of preserving moisture, the anti-ultraviolet essence, shaving foam, face powder, foundation cream, lipstick, cheek is red, eyeliner, eye shadow cream, eyebrow pencil, various skin cosmetics such as baths, perhaps use such as toothpaste.
In the manufacturing of cosmetic composition of the present invention, also can use the general additive more than a kind or 2 kinds that uses in the manufacturing of cosmetic composition.These additives can use with the appropriate amount in the scope that does not hinder effect of the present invention.For example can use anion surfactant; cationic surfactant; amphoteric surfactant; surfactants such as non-ionic surface active agent, the wax class; vegetable oil; animal is an oils and fats; natural series oils and fats derivant; the mineral substance oils and fats; rudimentary or high-grade aliphatic ester; N-acyl glutamic acid esters etc. are synthetic to be oils and fats; polymer substance; alcohols; polyhydric alcohol; extract; aminoacid; nucleic acid; vitamin; aminosal and derivant thereof; glyceryl oleate; enzyme; anti-inflammatory agent; antibacterial; antiseptic; antioxidant; UV absorbent; chelating agen; antiperspirant; oxidation dye; the pH regulator agent; the pearly-lustre agent; additives such as wetting agent.There is no particular limitation for the manufacture method of cosmetic composition of the present invention, adopt suitable means that mentioned component (A) and composition (B) mixing are got final product, add as required in the above-mentioned additive more than a kind or 2 kinds, mix, can easily make according to the method that this area is commonly used.Also there is no particular limitation for the molding means of the interpolation order of each composition and the compositions that obtains etc.
Embodiment
Below, be described more specifically the present invention in conjunction with the embodiments, but scope of the present invention is not subjected to the qualification of following embodiment.Test example 1
Have the shampoo of forming (% represents with weight, and total amount is 100%) shown in the table 1 according to the conventional method preparation, estimate the abnormal smells from the patient after preserving 6 months under 40 ℃.Evaluation is that the evaluation criterion according to the following stated calculates meansigma methods, and meansigma methods is that the situation more than 2.5 is bad (*), and 1.5～2.4 situation has bad (△) slightly, and the situation below 1.4 is good (zero).Evaluation result is as shown in table 1.Comparative example 2 and 3 is prepared to become and is not contained the compositions that has the surfactant of oxyethylene group at intramolecularly.＜evaluation criterion〉abnormal smells from the patient 3 after preserving: with preserve before compare, abnormal smells from the patient alters a great deal or with very big abnormal smells from the patient 2: with preserve before compare, some is spoiled or be with abnormal smells from the patient 1 slightly a little: with preserve before compare, do not have spoiled or band flavor table 1
The composition name Embodiment 1 Embodiment 2 Comparative example 1 Comparative example 2 Comparative example 3
Polyoxyethylene (2) sodium laureth sulfate ????9.0 ????9.0 ????9.0
Sodium lauryl sulfate ????9.0 ????9.0
Folium Cocoe amido propyl betaine (コ カ ミ De プ ロ ピ Le ベ イ Application) ????4.5 ????4.5 ????4.5 ????4.5 ????4.5
Sodium chloride ????1.0 ????1.0 ????1.0 ????1.0 ????1.0
PCA-Na ????1.0 ????1.0 ????1.0 ????1.0 ????1.0
Butanediol ????3.0 ????3.0 ????3.0 ????3.0 ????3.0
ポリクオニウム-10 ????0.2 ????0.2 ????0.2 ????0.2 ????0.2
Methyl parahydroxybenzoate ????0.2 ????0.2 ????0.2 ????0.2 ????0.2
The tert-butyl alcohol (0.1% aqueous solution) ????0.50 ????0.05 ????0.50
Water Surplus Surplus Surplus Surplus Surplus
Amount to ????100.0 ????100.0 ????100.0 ????100.0 ????100.0
Abnormal smells from the patient evaluation after the preservation ????○ ????○ ????× ????○ ????○
Test example 2
Have the body shampoo of forming (% represents with weight, and total amount is 100%) shown in the table 2 according to the conventional method preparation, estimate the abnormal smells from the patient after preserving 6 months under 40 ℃.Evaluation is that the evaluation criterion according to the following stated calculates meansigma methods, and meansigma methods is that the situation more than 2.5 is bad (*), and 1.5～2.4 situation has bad (△) slightly, and the situation below 1.4 is good (zero).Evaluation result is as shown in table 2.＜evaluation criterion〉abnormal smells from the patient 3 after preserving: with preserve before compare, abnormal smells from the patient alters a great deal or with very big abnormal smells from the patient 2: with preserve before compare, some is spoiled or be with abnormal smells from the patient 1 slightly a little: with preserve before compare, do not have spoiled or band flavor table 2
The composition name Embodiment 3 Embodiment 4 Comparative example 4
Lauric acid ????6.0 ????6.0 ????6.0
Myristic acid ????4.0 ????4.0 ????4.0
Palmic acid ????2.0 ????2.0 ????2.0
Potassium hydroxide ????3.4 ????3.4 ????3.4
Propylene glycol ????6.0 ????6.0 ????6.0
Lauramide DEA ????3.0 ????3.0 ????3.0
Folium Cocoe amido propyl betaine (コ カ ミ De Off ロ ピ Le ベ イ Application) ????3.0 ????3.0 ????3.0
Hydroxypropyl emthylcellulose ????0.2 ????0.2 ????0.2
Distearyl acid diol ester ????2.0 ????2.0 ????2.0
The tert-butyl alcohol (0.1% aqueous solution) ????0.05 ????0.005
Water Surplus Surplus Surplus
Amount to ????100.0 ????100.0 ????100.0
Abnormal smells from the patient evaluation after the preservation ????○ ????○ ????×
Test example 3
Preparation has the emulsion of forming (% represents with weight, and total amount is 100%) shown in the table 3, estimates the abnormal smells from the patient after preserving 6 months under 40 ℃.Evaluation is that the evaluation criterion according to the following stated calculates meansigma methods, and meansigma methods is that the situation more than 2.5 is bad (*), and 1.5～2.4 situation has bad (△) slightly, and the situation below 1.4 is good (zero).Evaluation result is as shown in table 3.＜evaluation criterion〉abnormal smells from the patient 3 after preserving: with preserve before compare, abnormal smells from the patient alters a great deal or with very big abnormal smells from the patient 2: with preserve before compare, some is spoiled or be with abnormal smells from the patient 1 slightly a little: with preserve before compare, do not have spoiled or band flavor table 3
The composition name Embodiment 5 Comparative example 5
Liquid paraffin ????5.0 ????5.0
Lauroyl glutamate dioctyl dodecyl ester ????2.0 ????2.0
Stearic acid PG ????0.5 ????0.5
The PEG-5 castor oil hydrogenated ????1.5 ????1.5
Stearic acid PEG-5 glyceride ????2.5 ????2.5
Carbomer (カ Le ボ マ-) ????0.2 ????0.2
Sodium hydroxide ????0.08 ????0.08
Butanediol ????5.0 ????5.0
Methyl parahydroxybenzoate ????0.1 ????0.1
The tert-butyl alcohol (0.1% aqueous solution) ????0.02
Water Surplus Surplus
Amount to ????100.0 ????100.0
Abnormal smells from the patient evaluation after the preservation ????○ ????△
Test example 4
Preparation has the emulsion of forming (% represents with weight, and total amount is 100%) shown in the table 4, estimates the abnormal smells from the patient after preserving 6 months under 40 ℃.Evaluation is that the evaluation criterion according to the following stated calculates meansigma methods, and meansigma methods is that the situation more than 2.5 is bad (*), and 1.5～2.4 situation has bad (△) slightly, and the situation below 1.4 is good (zero).Evaluation result is as shown in table 4.＜evaluation criterion〉abnormal smells from the patient 3 after preserving: with preserve before compare, abnormal smells from the patient alters a great deal or with very big abnormal smells from the patient 2: with preserve before compare, some is spoiled or be with abnormal smells from the patient 1 slightly a little: with preserve before compare, do not have spoiled or band flavor table 4
The composition name Embodiment 6 Embodiment 7 Comparative example 6 Comparative example 7 Comparative example 8
Cyclohexyl methyl polysiloxanes (シ Network ロ メ チ コ Application) ????20.0 ????20.0 ????20.0 ????20.0 ????20.0
Polyoxyethylene methyl polysiloxane copolymer ????3.0 ????3.0 ????3.0
Two glyceryl isostearates ????3.0 ????3.0
Fine particulate titanium dioxide ????10.0 ????10.0 ????10.0 ????10.0 ????10.0
PCA-Na ????1.0 ????1.0 ????1.0 ????1.0 ????1.0
Butanediol ????10.0 ????10.0 ????10.0 ????10.0 ????10.0
Phenyl phenol ????0.2 ????0.2 ????0.2 ????0.2 ????0.2
The tert-butyl alcohol (1% aqueous solution) ????1.0 ????0.1 ????0.1
Water Surplus Surplus Surplus Surplus Surplus
Amount to ????100.0 ????100.0 ????100.0 ????100.0 ????100.0
Abnormal smells from the patient evaluation after the preservation ????○ ????○ ????× ????○ ????○
Embodiment 8: bathe the preparation with gel (shower gel)
Adopt conventional method bath formulation gel according to following prescription.The bath that obtains can be in time through spoiled or band flavor, excellent in stability with gel.Table 5
The composition name Embodiment 9
Polyoxyethylene (3) Zetesol AP ????9.0
Folium Cocoe amido propyl betaine (コ カ ミ De プ ロ ピ Le ベ イ Application) ????4.5
Cocoa acyl glutamic acid 2Na ????0.5
ラウレス-2 ????1.5
PCA-Na ????1.0
ポリクオニウム-10 ????0.4
Methyl parahydroxybenzoate ????0.2
The tert-butyl alcohol (0.1% aqueous solution) ????1.0
Spice In right amount
Water Surplus
Amount to ????100.0
Embodiment 9: the preparation of hair conditioner
Adopt conventional method preparation hair nursing agent according to following prescription.The hair nursing agent that obtains can be in time through spoiled or band flavor, excellent in stability.Table 6
The composition name Embodiment 8
ステアルトリモニウムクロリド ????1.00
Spermol ????4.00
Isostearic acid hexyl decyl ester ????2.00
Dimethicone ????2.00
ステアレス-40 ????2.00
Lactic acid ????0.01
PCA-Na ????1.00
EDTA-2Na ????0.05
Methyl parahydroxybenzoate ????0.20
The tert-butyl alcohol (0.1% aqueous solution) ????1.00
Spice In right amount
Water Surplus
Amount to ????100.0
Embodiment 10: the preparation of foaming mousse cleanser agent
Adopt conventional method preparation foaming mousse cleanser according to following prescription.The foaming mousse cleanser that obtains can be in time through spoiled or band flavor, excellent in stability.Table 7
The composition name Embodiment 9
Lauric acid ????3.00
Myristic acid ????9.00
Palmic acid ????8.00
Stearic acid ????10.00
Glycerol ????25.00
BG ????5.00
Folium Cocoe amide MEA (コ カ ミ De MEA) ????2.00
Tristerin ????1.00
Potassium hydroxide ????5.95
Folium Cocoe amido propyl betaine (コ カ ミ De プ ロ ピ Le ベ イ Application) ????1.00
Cocoa acylglycine potassium ????3.00
Methyl parahydroxybenzoate ????0.20
The tert-butyl alcohol (0.1% aqueous solution) ????1.00
Spice In right amount
Water Surplus
Amount to ????100.0
Industrial applicibility
Cosmetic composition of the present invention has following characteristics: can suppress owing to cooperate the surfactant that has oxyethylene group in the molecule to cause the in time spoiled or band flavor through causing, storage stability is good.

Claims (7)

1, a kind of cosmetic composition, wherein contain following compositions:
(A) surfactant of from the surfactant that has oxyethylene group at intramolecularly, selecting more than a kind or 2 kinds; And
(B) tert-butyl alcohol.
2, cosmetic composition as claimed in claim 1, the surfactant that has oxyethylene group at intramolecularly is 1～20 weight % with respect to composition total weight.
3, cosmetic composition as claimed in claim 1 or 2, wherein to have the surfactant of oxyethylene group be the surfactant of selecting from following surfactant more than a kind or 2 kinds to intramolecularly:
The surfactant of following general formula (1) expression,
〔R 1(OCH 2CH 2) n-OSO 3〕 -M +
In the formula, R 1The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21, n represents 1～30 integer, M represents Na, K, NH 4Or triethanolamine;
The surfactant of following general formula (2) expression,
R 2CO-NH(CH 2CH 2O) mH
In the formula, R 2The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21, m represents 1～10 integer; And
The surfactant of following general formula (3) expression,
R 3CO-N(CH 2CH 2OH) 2
In the formula, R 3The straight or branched thiazolinyl that straight or branched alkyl that the expression carbon number is 7～21 or carbon number are 7～21.
4, as any described cosmetic composition in the claim 1 to 3, the tert-butyl alcohol is 0.01～1000 ppm by weight with respect to composition total weight.
5, a kind of inhibition contain have oxyethylene group at intramolecularly the cosmetics of surfactant because of the method for cause spoiled of effluxion or band flavor, comprise the step of in these cosmetics, adding the tert-butyl alcohol.
6, method as claimed in claim 5 is with respect to the cosmetics gross weight to be the ratio interpolation tert-butyl alcohol of 0.01～1000 ppm by weight.
7, a kind of contain have oxyethylene group at intramolecularly the cosmetics of surfactant because of the inhibitor of cause spoiled of effluxion or band flavor, it contains the tert-butyl alcohol.
CNB031545173A 2002-07-11 2003-07-11 Cosmetic composition Expired - Lifetime CN1326513C (en)

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US9393164B2 (en) 2013-02-28 2016-07-19 Kimberly-Clark Worldwide, Inc. Aldehyde control in personal care products

Family Cites Families (16)

* Cited by examiner, † Cited by third party
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RO81931A (en) * 1979-09-26 1983-06-01 Charbonnages De France,Fr PROCEDURE AND INSTALLATION FOR DRYING GRANULAR OR PULVERULANT FUEL MATERIAL
US4668430A (en) * 1982-06-01 1987-05-26 Basf Corporation Roll-on perfume compositions containing polyoxybutylene-polyoxyethylene copolymers
US4592875A (en) * 1984-06-25 1986-06-03 Atlantic Richfield Company Alkoxylated ether sulfate anionic surfactants from plasticizer alcohol mixtures
US5075025A (en) * 1986-10-24 1991-12-24 Kam Scientific Inc. Disinfectant composition
CA1295550C (en) * 1986-10-24 1992-02-11 Mark A. Wainberg Stabilized hypochlorite disinfectant composition
GB8808157D0 (en) * 1988-04-07 1988-05-11 Dow Corning Ltd Clear shampoo composition
DE59005996D1 (en) * 1989-06-01 1994-07-14 Ciba Geigy Process for the preparation of titanocenes with o, o'-difluoroaryl ligands.
FR2751221B1 (en) * 1996-07-17 1998-09-04 Oreal PRESSURIZED COMPOSITION BASED ON FIXING POLYMER, SOLVENT AND OXYALKYLENATED SILICONE, AND RESULTING FOAM
FR2761598B1 (en) * 1997-04-07 2004-04-02 Oreal DETERGENT COSMETIC COMPOSITIONS AND USE
US6017261A (en) * 1998-08-21 2000-01-25 Telco Creations, Inc. Animated mechanized figure
AU1937899A (en) * 1998-12-22 2000-07-12 Procter & Gamble Company, The Transparent skin care compositions
US6395264B1 (en) * 1999-05-07 2002-05-28 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Low VOC hair spray compositions having enhanced styling benefits
US6107261A (en) * 1999-06-23 2000-08-22 The Dial Corporation Compositions containing a high percent saturation concentration of antibacterial agent
US6190645B1 (en) * 1999-07-15 2001-02-20 Playtex Products, Inc. Sunscreen for the scalp hair and hair
US6376721B1 (en) * 2001-01-19 2002-04-23 Rhodia, Inc. Process for alkoxylation in the presence of rare earth triflimides
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EP1380283A1 (en) 2004-01-14

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