JP2015093859A - Cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an excellent cosmetic which provides an excellent refreshing feeling in the early stages of use, as well as is excellent in lasting of the refreshing feeling, further increases the refreshing feeling when sweating, and furthermore in which an unpleasant stimulus at the time of use is reduced.SOLUTION: The cosmetic of the invention comprises a component (A): l-menthol, a component (B): l-menthyl glyceryl ether, a component (C): eucalyptol and/or borneol, a component (D): lactic acid menthyl and/or oxalic acid menthyl ethylamide, and a component (E): PCA menthyl and/or succinic acid mono-menthyl.

Description

  The present invention relates to a cosmetic. In more detail, it is related with the cosmetics which give a refreshing feeling.

  Conventionally, cosmetics containing a refreshing agent and a cooling sensation agent that give the user a refreshing feeling and cooling sensation are known. Furthermore, among the above cosmetics, for the purpose of improving the refreshing sensation and its sustainability, cosmetics using an immediate-acting refreshing agent and a slow-acting refreshing agent are known (Patent Document 1). However, in the cosmetics described above, when the content of the refreshing agent is increased in order to improve the refreshing feeling and sustainability, there is a problem that unpleasant irritation occurs.

  For this, for example, a refreshing composition is known in which the expression of irritation is reduced by combining different refreshing agents (Patent Document 2).

  However, in recent years, the demand level of consumers for the characteristics of cosmetics that give a refreshing feeling has been further increased. For example, a stronger refreshing feeling and a further improvement in the sustainability of the refreshing feeling have been demanded. Furthermore, it has been demanded to develop a high refreshing feeling when sweating after application. For such demands, the above cosmetics cannot be said to have sufficient characteristics. Moreover, even if the knowledge of the said patent document 2 is used if it is going to satisfy | fill these requests | requirements by the increase in content of a refreshing agent, it was the present condition that irritation | stimulation cannot fully be reduced.

JP-A-10-231238 JP 11-92327 A

  Therefore, an object of the present invention is a cosmetic that not only gives a high refreshing feeling in the initial stage of use, but also has an excellent refreshing feeling and further improves the refreshing feeling when sweated, and An object of the present invention is to provide an excellent cosmetic with reduced unpleasant irritation during use.

  As a result of intensive studies, the inventor formulated 1-menthol; l-menthyl glyceryl ether; eucalyptol and / or borneol; menthyl lactate and / or menthyl oxalate ethylamide; Therefore, the refreshing feeling in the initial stage of use, the persistence of the refreshing feeling, and the refreshing feeling when sweating after use are both at a high level, and the unpleasant irritation during use is reduced. The inventors found that a cosmetic can be obtained and completed the present invention.

That is, this invention provides the cosmetics characterized by including the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E).
Component (A): l-menthol Component (B): l-menthyl glyceryl ether Component (C): eucalyptol and / or borneol Component (D): menthyl lactate and / or menthylethylamide oxalate component (E): PCA menthyl and / or monomenthyl succinate

  The content of the component (A) in the cosmetic is 0.10 to 10.0% by mass, the content of the component (B) is 0.010 to 3.0% by mass, and the component The content of (C) is 0.005 to 1.0 mass%, the content of the component (D) is 0.010 to 3.0 mass%, and the content of the component (E) is 0. It is preferable that it is 0.005-1.0 mass%.

The cosmetic preferably further contains the following component (F).
Component (F): a compound selected from the group consisting of camphor, linalool, geraniol, menthone, eugenol, and hydroxycitronellal

  It is preferable that content of the said component (F) in the said cosmetics is 0.001-1.0 mass%.

  The cosmetic is preferably a skin cosmetic.

  The cosmetic of the present invention gives a high refreshing feeling to the user at the initial stage of use. In addition, the refreshing feeling is excellent. Furthermore, when the user sweats after use, the refreshing feeling is improved and a more comfortable refreshing feeling can be given to the user. In addition, the cosmetic of the present invention has sufficiently reduced unpleasant irritation such as irritation during use.

  The cosmetic of the present invention contains at least 1-menthol; 1-menthyl glyceryl ether; eucalyptol and / or borneol; menthyl lactate and / or menthyl oxalate ethylamide; PCA menthyl and / or monomenthyl succinate. The cosmetic of the present invention preferably further contains a compound (at least one compound) selected from the group consisting of camphor, linalool, geraniol, menthone, eugenol, and hydroxycitronellal.

  In the present specification, the “l-menthol” is referred to as “component (A)”; the “l-menthyl glyceryl ether” as “component (B)”; and the “eucalyptol and / or borneol” as “ “Component (C)”; “Mentyl lactate and / or menthyl oxalate ethylamide” as “Component (D)”; “PCA menthyl and / or monomenthyl succinate” as “Component (E)”; The “compound selected from the group consisting of linalool, geraniol, menthone, eugenol, and hydroxycitronellal” may be referred to as “component (F)”.

  The cosmetic of the present invention contains at least a component (A), a component (B), a component (C), a component (D), and a component (E). The cosmetic of the present invention preferably further contains a component (F). The cosmetic of the present invention may contain components (other components) other than the components (A) to (F). Moreover, only 1 type may be used for the component (For example, component (C) -component (F) and other components) contained in the cosmetics of this invention, respectively, and 2 or more types may be used. .

[Ingredient (A): l-menthol]
The component (A) is l-menthol. The said component (A) has a role which improves the refreshing feeling in the initial stage of use of the cosmetics of this invention. The “initial stage of use” is not particularly limited. For example, it means about 1 minute from the time when the cosmetic of the present invention is used (for example, at the time of application) and immediately after use (for example, application).

  Although content of the component (A) in the cosmetics of this invention is not specifically limited, 0.10-10.0 mass% is preferable with respect to 100 mass% of cosmetics of this invention, More preferably, 1. It is 0-7.0 mass%. It is preferable that the content of the component (A) is 0.10% by mass or more, since the cool feeling at the initial stage of use of the cosmetic of the present invention is further improved. Moreover, since content of a component (A) is 10.0 mass% or less, the unpleasant irritation | stimulation of the cosmetics of this invention reduces further, it is preferable.

[Component (B): l-menthyl glyceryl ether]
The component (B) is l-menthyl glyceryl ether. The said component (B) has a role which improves the refreshing feeling improvement effect at the time of perspiration of the cosmetics of this invention. By blending the component (B), the refreshing feeling is improved when the user sweats after using (for example, applying) the cosmetic of the present invention.

  Although content of the component (B) in the cosmetics of this invention is not specifically limited, 0.010-3.0 mass% is preferable with respect to 100 mass% of cosmetics of this invention, More preferably, it is 0.00. It is 050-0.50 mass%. It is preferable that the content of the component (B) is 0.010% by mass or more because the effect of improving the refreshing feeling during sweating of the cosmetic of the present invention is further enhanced. Moreover, since content of a component (B) is 3.0 mass% or less, the unpleasant irritation | stimulation of the cosmetics of this invention reduces further, it is preferable.

[Component (C): Eucalyptol and / or Borneol]
The component (C) is eucalyptol and / or borneol (that is, one or both of eucalyptol and borneol). Examples of the borneol include d-borneol and dl-borneol. In other words, the component (C) is a compound (at least one compound) selected from the group consisting of eucalyptol and borneol. The said component (C) has a role which reduces the unpleasant irritation | stimulation of the cosmetics of this invention. In the present specification, the above-mentioned “unpleasant irritation” means a tingling sensation, a tingling sensation, a burning sensation, an itchiness, or an uncomfortable sensation caused by use (for example, application) of the cosmetic of the present invention.

  Although content of the component (C) in the cosmetics of this invention is not specifically limited, 0.005-1.0 mass% is preferable with respect to 100 mass% of cosmetics of this invention, More preferably, it is 0.00. It is 010 to 0.50 mass%. It is preferable that the content of the component (C) is 0.005% by mass or more because unpleasant irritation of the cosmetic of the present invention is further reduced. Moreover, since content of a component (C) is 1.0 mass% or less, the fragrance of a component (C) does not become strong too much, it is preferable. Content of the said component (C) is a total amount of content of all the components (C) in the cosmetics of this invention.

  From the viewpoint of further improving the effect of reducing unpleasant stimuli, it is preferable to use eucalyptol and borneol in combination. That is, component (C) is preferably eucalyptol and borneol. When eucalyptol and borneol are used in combination as component (C), the mass ratio of the eucalyptol content to the borneol content [eucalyptol content / borneol content] is not particularly limited. From the viewpoint of the scent of (C), 0.10 to 100.0 is preferable, and 0.5 to 20.0 is more preferable.

[Component (D): Menthyl lactate and / or Menthyl oxalate ethylamide]
The component (D) is lactyl menthyl and / or oxalic acid menthyl ethylamide (that is, one or both of menthyl lactate and menthyl ethyl oxalate). In other words, the component (D) is a compound (at least one compound) selected from the group consisting of menthyl lactate and menthyl oxalate ethylamide. The said component (D) has the role which raises all the effects of the refreshing feeling of the initial stage and the time of perspiration, the persistence of a refreshing feeling, and unpleasant irritation | stimulation of the cosmetics of this invention.

  As said component (D), oxalic acid menthyl ethylamide is especially preferable. In addition, oxalic acid menthylethylamide (INCI name: MENTYL ETHYLAMIDO OXALATE) is also called menthylethylaminooxalic acid.

  Although content of the component (D) in the cosmetics of this invention is not specifically limited, 0.010-3.0 mass% is preferable with respect to 100 mass% of cosmetics of this invention, More preferably, it is 0.00. It is 050-0.50 mass%. When the content of the component (D) is 0.010% by mass or more, the cosmetic composition of the present invention has an initial and perspiration refreshing effect, a refreshing sustainability improving effect, and an unpleasant stimulus reduction. All of the effects are further enhanced, which is preferable. Moreover, since content of a component (D) is 3.0 mass% or less, unpleasant irritation | stimulation further reduces, it is preferable. Content of the said component (D) is a total amount of content of all the components (D) in the cosmetics of this invention. In particular, the content of oxalic acid menthylethylamide is preferably in the above range.

[Component (E): PCA menthyl and / or monomenthyl succinate]
The component (E) is PCA menthyl and / or monomenthyl succinate (that is, one or both of PCA menthyl and succinate monomenthyl). In other words, the component (E) is a compound (at least one compound) selected from the group consisting of PCA menthyl and monomenthyl succinate. The said component (E) has a role which improves the sustainability of the refreshing feeling of the cosmetics of this invention.

  As the component (E), PCA menthyl is particularly preferable.

  Although content of the component (E) in the cosmetics of this invention is not specifically limited, 0.005-1.0 mass% is preferable with respect to 100 mass% of cosmetics of this invention, More preferably, it is 0.00. It is 010 to 0.50 mass%. It is preferable that the content of the component (E) is 0.005% by mass or more because the refreshing feeling of the cosmetic of the present invention is further enhanced. Moreover, since content of a component (E) is 1.0 mass% or less, the unpleasant irritation | stimulation of the cosmetics of this invention reduces further, it is preferable. Content of the said component (E) is a total amount of content of all the components (E) in the cosmetics of this invention. In particular, the content of PCA menthyl is preferably in the above range.

[Component (F): a compound selected from the group consisting of camphor, linalool, geraniol, menthone, eugenol, and hydroxycitronellal]
The component (F) is a compound (at least one compound) selected from the group consisting of camphor, linalool, geraniol, menthone, eugenol, and hydroxycitronellal. The said component (F) has a role which provides the relaxation effect by an odor to the cosmetics of this invention. As for the said component (F), only 1 type may be used and 2 or more types may be used.

  Of these, camphor, linalool, geraniol, eugenol, and hydroxycitronellal are preferable as the component (F), and camphor, linalool, geraniol, and hydroxycitronellal are more preferable.

  Although content of the component (F) in the cosmetics of this invention is not specifically limited, 0.001-1.0 mass% is preferable with respect to 100 mass% of cosmetics of this invention, More preferably, it is 0.00. It is 010 to 0.50 mass%. When the content of the component (F) is within the above range, the odor becomes more appropriate strength, which is preferable because the relaxation effect by the odor is further improved. Content of the said component (F) is a total amount of content of all the components (F) in the cosmetics of this invention.

  Among the above, the cosmetic of the present invention preferably contains 1-menthol, 1-menthyl glyceryl ether, eucalyptol, borneol, menthol ethyl oxalate, and PCA menthyl.

[Other ingredients]
The cosmetic of the present invention may contain components (other components) other than the components (A) to (F). Other components include, for example, polyoxyethylene alkyl ethers having a branched alkyl group, water, surfactants, fats and oils, hydrocarbon oils, waxes, higher fatty acids, fatty acid ester oils, higher alcohols, lower alcohols (for example, ethanol) Etc.), polyhydric alcohols, sterols, moisturizers, viscosity modifiers, pH adjusters, powders, inorganic pigments, dyes, antioxidants, UV absorbers, vitamins, astringents, whitening agents, animal and plant extracts, Examples include sequestering agents, antiperspirant components, bactericidal components, deodorant components, fragrances, dyes, inorganic powders, and organic powders. Only 1 type may be used for the said other component, and 2 or more types may be used for it.

  It is preferable that the cosmetics of this invention contain the polyoxyethylene alkyl ether which has a branched alkyl group from a viewpoint of further improving the sustainability of the refreshing feeling of the cosmetics of this invention. Although carbon number of the said branched alkyl group is not specifically limited, From a viewpoint of raising the sustainability of a refreshing feeling, 16-20 are preferable. Although it does not specifically limit as said polyoxyethylene alkyl ether which has the said branched alkyl group, For example, polyoxyethylene isostearyl ether, polyoxyethylene isocetyl ether, polyoxyethylene octyldodecyl ether etc. are mentioned. Among these, polyoxyethylene isostearyl ether is preferable. Only 1 type may be used for the polyoxyethylene alkyl ether which has the said branched alkyl group, and 2 or more types may be used for it.

  The average added mole number of the oxyethylene group (ethylene oxide group) of the polyoxyethylene alkyl ether having a branched alkyl group is not particularly limited, but is preferably 10 to 30, more preferably from the viewpoint of enhancing the refreshing feeling. Is 10-25.

  The content of the polyoxyethylene alkyl ether having a branched alkyl group in the cosmetic of the present invention is not particularly limited, but from the viewpoint of enhancing the persistence of the refreshing feeling and suppressing stickiness, the cosmetic of the present invention. The amount is preferably 0.010 to 5.0% by mass, more preferably 0.050 to 3.0% by mass, and still more preferably 0.10 to 2.0% by mass with respect to 100% by mass. The content of the polyoxyethylene alkyl ether having a branched alkyl group is the total content of the polyoxyethylene alkyl ether having all the branched alkyl groups in the cosmetic of the present invention. In particular, the content of polyoxyethylene isostearyl ether is preferably in the above range.

  The cosmetic of the present invention preferably contains water. The water is not particularly limited, but purified water is preferable. Although content of water in the cosmetics of this invention is not specifically limited, From a refreshing use feeling, 10.0-95.0 mass% is with respect to 100 mass% of cosmetics of this invention. More preferably, 10.0-75.0 mass% is preferable, More preferably, it is 20.0-65.0 mass%.

  The cosmetic of the present invention preferably contains ethanol. The content of ethanol in the cosmetic of the present invention is not particularly limited, but from the viewpoint of a refreshing feeling of use and further improving the solubility of the refreshing component, the content of ethanol is 100% by mass. 10.0-95.0 mass% is preferable, More preferably, 20.0-80.0 mass% is preferable, More preferably, it is 30.0-70.0 mass%.

  The polyhydric alcohol is not particularly limited. For example, ethylene glycol, propylene glycol, isoprene glycol, dipropylene glycol, polyethylene glycol, diethylene glycol, dipropylene glycol, triethylene glycol, 1,3-butylene glycol (1,3 -Butanediol), 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, glycerin (1,2,3-propanetriol) ), Diglycerin, polyglycerin, sorbitol, maltitol, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside and the like.

  In particular, when the content of the component (A) in the cosmetic of the present invention is 5.0% by mass or more, for example, 5.0 to 15.0% by mass, particularly 5.0 to 10.0% by mass. From the viewpoint of further reducing the primary skin irritation of the cosmetic of the present invention, the cosmetic of the present invention comprises polyethylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, polyoxypropylene methyl glucoside, and polyoxy It is preferable to include a compound (at least one compound) selected from the group consisting of ethylene methyl glucoside. Among these, polyethylene glycol is preferable. The content of the above compound (a compound selected from the group consisting of polyethylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, polyoxypropylene methyl glucoside, and polyoxyethylene methyl glucoside) in the cosmetic of the present invention is Although not particularly limited, from the viewpoint of further reducing the primary skin irritation, 0.050 to 10.0% by mass is preferable with respect to 100% by mass of the cosmetic of the present invention, and more preferably 0.10 to 5.0. % By mass. The content of the compound is the total content of polyethylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, polyoxypropylene methyl glucoside, and polyoxyethylene methyl glucoside.

  Although the number average molecular weight of the said polyethylene glycol is not specifically limited, From a viewpoint of reducing the skin primary irritation | stimulation of the cosmetics of this invention more, 200-20000 are preferable, More preferably, it is 200-2000.

  The antiperspirant component is not particularly limited, and examples thereof include aluminum chloride, aluminum potassium sulfate, aluminum sulfate, aluminum acetate, chlorohydroxyaluminum, allantochlorohydroxyaluminum, and zinc paraphenolsulfonate.

  The sterilizing component is not particularly limited. Can be mentioned.

  Although it does not specifically limit as said deodorizing component, For example, metal oxides, such as a zinc oxide, a silica, alkyl diethanolamide, a hydroxyapatite, a tea extract, etc. are mentioned.

[Production method, use, properties, etc. of cosmetics of the present invention]
The manufacturing method of the cosmetics of this invention is not specifically limited, A well-known manufacturing method can be used. For example, there is a method in which the above components are mixed and stirred with a paddle mixer to homogenize the components.

  Although the cosmetics of this invention are not specifically limited, For example, it can be used with dosage forms, such as a lotion, an aerosol spray, a natural spray, a stick, powder, roll-on, cream, a gel, an emulsion, a sheet | seat (paper). Of these, lotion, roll-on, gel, and sheet (paper) are preferable.

  The cosmetic of the present invention is not particularly limited, but is preferably a skin cosmetic used for the skin. The skin cosmetics are applied to the skin (including spray application). The part to which the skin cosmetic is applied is not particularly limited, and examples include the body and the head (scalp). Of these, the body is preferable, and examples include the chest, back, arms, legs, neck, and arms.

  The cosmetic composition of the present invention is not particularly limited. For example, lotion, soft cosmetic, astringent lotion, wipe lotion, after shave lotion, skin lotion, skin cream, massage cream, massage cream, cleansing cream, milky lotion Lip balm, hair nick, hair gel, hair restorer, face wash, shaving foam, shaving cream, body soap, shampoo, hair rinse, hair treatment, hair conditioner, milk, antiperspirant, deodorant and the like.

  The cosmetics of the present invention are not limited to “cosmetics” in the Pharmaceutical Affairs Law, and include, for example, cosmetics, quasi drugs, pharmaceuticals, and miscellaneous goods.

The cosmetic of the present invention comprises a component (A) that exhibits an effect of giving a refreshing feeling immediately after use, and a component (E) that has an effect of giving a refreshing feeling that is delayed (persistent). Thereby, a comparatively high refreshing feeling is obtained immediately after using the cosmetic, and the refreshing feeling lasts for a long time. Furthermore, by blending the component (B) that amplifies the refreshing feeling during sweating, the effect of increasing the refreshing feeling during sweating can be obtained.
However, it is known that component (A) or a derivative thereof gives a strong refreshing feeling to the user when it comes into contact with human skin. However, some users may feel pain when menthol or its derivatives come into contact with the skin. Therefore, when trying to obtain a very high refreshing feeling only with the component (A), the component (B), and the component (E), the blending amount of these components becomes too high and an unpleasant irritation may occur. Was a problem.
Therefore, in the present invention, the component (C) that can reduce irritation caused by the component (A) is blended while maintaining a refreshing feeling. Furthermore, the component (D) which can raise the effect of another component by improving the solubility of each refreshing component and enhancing skin permeability was blended.
As a result, the use of the cosmetic composition of the present invention allows the user to obtain a sufficient refreshing feeling for a long time without feeling uncomfortable irritation. A high refreshing feeling is obtained. For this reason, since a user can obtain high comfort, it is preferable.

  Hereinafter, the present invention will be described in more detail based on examples and the like, but the present invention is not limited only to such examples.

  Details of each component described in the table and the following formulation examples are as follows.

l-Menthol: Takasago International Corporation, trade name “Menthol JP COS”
l-Mentylglyceryl ether: trade name “Cooling Agent 10 (N)” manufactured by Takasago International Corporation
Eucalyptor: Takasago International Corporation, trade name “EUCALYPTOL 100 BP USP”
d-borneol: manufactured by Ogi Pharmaceutical Co., Ltd., trade name “d-borneol”
dl-borneol: manufactured by Koshiro Pharmaceutical Co., Ltd., trade name “dl-borneol”
Lactic acid menthyl: manufactured by Simrise Co., Ltd., trade name “Frescolat ML / 620105”
Oxalic acid menthyl ethylamide: trade name “Fresolat X-Cool” manufactured by Simrise Co., Ltd.
PCA Menthil: Givaudan, trade name “QUESTICE LIQUID CQ / UA”
Monomenthyl succinate: product name “PHYSOOL N.2188” manufactured by Ve Man Fis Fragrance Co., Ltd.
Polyethylene glycol 1500: Lion Corporation, trade name “PEG # 1500K”
Ethanol: Takara Shuzo Co., Ltd., trade name “95 ° general fermented alcohol”

  According to the composition described in Table 1 and Table 2, cosmetics (lotions) of Examples 1 to 14 and Comparative Examples 1 to 5 were prepared by a conventional method and subjected to the following evaluation.

(1) Test 1 (initial refreshment, unpleasant irritation, persistence of refreshment)
Ten subjects (specialized panels) were evaluated. The lower part of the ear of the neck of the subject was wiped with a wet towel to remove sebum stains and the like, and after resting for 10 minutes, the evaluation was performed. Evaluation was performed in an environment of 21 to 23 ° C. and 45 to 60% RH.
Using a dispenser (product number “Y-150” manufactured by Yoshino Kogyo Co., Ltd.) under the ear of the neck of the subject, about 0.3 mL of cosmetic was sprayed from a location 10 cm away from the skin.
Thereafter, the following (1-1) to (1-3) were evaluated.

(1-1) Initial refreshing feeling Each subject judged the strength of the refreshing feeling 1 minute after the spraying based on the following “score of refreshing feeling”. The average score of 10 subjects was determined, and the initial cool feeling was evaluated based on the following criteria.
<Score of coolness>
5 points: A refreshing feeling is felt very strongly.
4 points: Between “clear” and “very strong”.
3 points: A refreshing feeling is clearly felt.
2 points: halfway between "Kasuka" and "Clear".
1 point: A slight refreshing feeling is felt.
0 points: No refreshing feeling.
<Initial coolness criteria>
A (Excellent): The average score is 4.0 points or more.
○ (Good): The average score is 3.0 or more and less than 4.0.
Δ (insufficient): The average score is 2.0 or more and less than 3.0.
X (defect): The average score is less than 2.0 points.

(1-2) Unpleasant stimulation Each subject determined the intensity of unpleasant stimulation 1 minute, 3 minutes, 5 minutes, 7 minutes, and 10 minutes after the spraying based on the following scores. . The average score of each subject was determined, the average score of 10 subjects was determined, and unpleasant stimuli were evaluated based on the following criteria. The “unpleasant stimulus strength” was determined for the strongest stimulus among a tingling sensation, a tingling sensation, a burning sensation, an itch, and a sense of discomfort.
<Scoring of unpleasant stimulus strength>
5 points: I feel the stimulus so strong that I can't stand it 4 points: The middle between “clear” and “I can't stand” 3 points: I feel the stimulus clearly 2 points: The middle between “slightly” and “clear” 1 point: Stimulus Feels faint 0 point: No stimulation at all <Judgment criteria for unpleasant stimulation>
A (Excellent): The average score is less than 2.0 points.
○ (Good): The average score is 2.0 or more and less than 3.0.
Δ (insufficient): The average score is 3.0 or more and less than 4.0.
X (defect): The average score is 4.0 points or more.

(1-3) Sustainability of refreshing feeling Each subject judged the strength of refreshing feeling 30 minutes after the spraying based on the above-mentioned “score of refreshing feeling strength”. The average score of 10 subjects was determined, and the initial cool feeling was evaluated based on the following criteria.
<Criteria for sustainability of coolness>
A (Excellent): The average score is 1.5 or more.
○ (Good): The average score is 1.0 or more and less than 1.5.
Δ (insufficient): The average score is more than 0.5 and less than 1.0.
X (defect): The average score is less than 0.5 points.

(2) Test 2 (cool feeling when sweating)
Ten subjects (specialized panels) were evaluated. The lower part of the ear of the neck of the subject was wiped with a wet towel to remove sebum stains and the like, and after resting for 10 minutes, the evaluation was performed.
Makeup from 10 cm away from the skin using a dispenser (product number “Y-150”, manufactured by Yoshino Kogyo Co., Ltd.) under the ear of the neck of the subject in an environment of 21-23 ° C. and 45-60% RH. About 0.3 mL of the material was sprayed.
Each subject judged the strength of the refreshing feeling 15 minutes after the spraying based on the above “score of the refreshing strength”, and made it “the score of the refreshing strength before exercise”. Then, it moved to the room of 29-31 degreeC and 45-60% RH, and exercise | moved the exercise bike for 5 minutes. Thereafter, the refreshing strength 5 minutes after the end of the exercise was judged based on the above-mentioned “refreshing strength score”, and was defined as “the refreshing strength score after exercise”. The difference between the above “score of refreshing strength after exercise” and the above “score of refreshing strength before exercise” [(score of refreshing strength after exercise) − ( Strength score)].
The average score of the above differences of 10 subjects was determined, and the refreshing feeling during sweating was evaluated based on the following criteria.
<Judgment criteria for coolness when sweating>
A (Excellent): The difference is 1.0 point or more.
○ (Good): Difference is 0 point or more and less than 1.0 point.
Δ (insufficient): The difference is -0.5 point or more and less than 0 point.
X (defect): Difference is less than -0.5 point.

  Furthermore, the formulation example of the cosmetics of this invention is shown below.

(Formulation example 1) Deodorant gel l-menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.050 mass%
Oxalic acid menthylethylamide 0.10% by mass
Menthyl lactate 0.10% by mass
PCA Mentil 0.10% by mass
Monomenthyl succinate 0.10% by mass
0.10% by mass
Linalool 0.10% by mass
Polyethylene glycol 1500 0.50 mass%
Acrylic acid / alkyl methacrylate copolymer 0.20% by mass
Polyoxyethylene isostearyl ether (20E.O.) 1.0% by mass
Potassium hydroxide 0.020 mass%
Isononyl isononanoate 1.50% by mass
Triclosan 0.20% by mass
Ethanol 30.0% by mass
Fragrance Appropriate amount of purified water

(Formulation example 2) Lotion 1-menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.010 mass%
Oxalic acid menthylethylamide 0.10% by mass
Menthyl lactate 0.10% by mass
PCA Mentil 0.10% by mass
Monomenthyl succinate 0.10% by mass
Hydroxycitronellal 0.10% by mass
Eugenol 0.10 mass%
Polyethylene glycol 1500 0.50 mass%
1,3-butylene glycol 6.0% by mass
Glycerin 4.0% by mass
Hydrolyzed hyaluronic acid 0.10% by mass
Polyoxyethylene polyoxypropylene-2-decyltetradecyl ether 0.20% by mass
Polyoxyethylene isostearyl ether (20E.O.) 1.0% by mass
Phenoxyethanol 0.30% by mass
Ethanol 3.0% by mass
Perfume Appropriate amount of purified water Total remaining amount 100.0% by mass

(Formulation example 3) Deodorant roll-on l-menthol 5.0 mass%
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
0.10% by mass
Geraniol 0.10 mass%
Polyethylene glycol 1500 0.50 mass%
Triclosan 0.20% by mass
Chlorhydroxyaluminum 10.0% by mass
Isononyl isononanoate 1.0% by mass
Hydroxypropyl cellulose 1.0% by mass
Ethanol 60.0% by mass
Perfume Appropriate amount of purified water Total remaining amount 100.0% by mass

(Formulation example 4) Wiping sheet (skin cleaning sheet cosmetic)
1 g of nonwoven fabric was impregnated with 5 g of the following skin lotion.
(Lotion)
l-Menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
Polyethylene glycol 1500 0.50 mass%
Talc 3.0% by mass
Polyoxyethylene polyoxypropylene-2-decyltetradecyl ether 0.20% by mass
Ethanol 40.0% by mass
Perfume Appropriate amount of purified water Total remaining amount 100.0% by mass

(Formulation Example 5) Skin care gel l-menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
dl-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
1,3-butylene glycol 10.0% by mass
Glycerin 3.0% by mass
Dipropylene glycol 5.0% by mass
Polyethylene glycol 1500 0.50 mass%
Acrylic acid / alkyl methacrylate copolymer 0.40% by mass
Xanthan gum 0.010 mass%
Potassium hydroxide 0.150% by mass
Decamethylpolysiloxane 5.0% by mass
Trimethylglycine 10.0% by mass
1,2-pentanediol 0.10% by mass
Glycerin mono 2-ethylhexyl ether 0.050% by mass
Dipotassium glycyrrhizinate 0.10% by mass
Ethanol 3.0% by mass
Edetic acid disodium appropriate amount perfume appropriate amount purified water remaining total 100.0% by mass

(Formulation Example 6) Body lotion 1-menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
Polyoxyethylene isostearyl ether (20E.O.) 1.0% by mass
1,3-butylene glycol 5.0% by mass
Polyethylene glycol 1500 0.50 mass%
Nylon powder 5.0% by mass
Ethanol 50.0% by mass
Perfume Appropriate amount of purified water Total remaining amount 100.0% by mass

(Prescription Example 7) Tonic l-menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
dl-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
D-pantothenyl alcohol 0.20% by mass
Nicotinamide 0.10% by mass
Dl-α-tocopherol acetate 0.10% by mass
Canful 0.001% by mass
Polyoxyethylene hydrogenated castor oil (50 EO) 0.30% by mass
Sodium lactate 0.50 mass%
Citric acid 0.050% by mass
Polyethylene glycol 1500 0.50 mass%
Ethanol 50.0% by mass
Perfume Appropriate amount of purified water Total remaining amount 100.0% by mass

(Prescription Example 8) Deodorant spray 5 parts by mass of the following stock solution and 95 parts by mass of the following propellant.
(Stock solution)
Talc 20.0% by mass
Silic anhydride 20.0% by mass
Chlorhydroxyaluminum 10.0% by mass
l-Menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
Triclosan 0.20% by mass
Dimethylpolysiloxane 15.0% by mass
Fragrance Appropriate amount Isopropyl myristate Total remaining amount 100.0% by mass
(Propellant)
LPG 100.0% by mass

(Formulation example 9) Deodorant stick isopropyl methyl phenol 0.20% by mass
Potassium aluminum sulfate 20.0% by mass
Chlorhydroxyaluminum 10.0% by mass
Stearyl alcohol 5.0 mass%
Glycerol monostearate 3.0% by mass
Silica anhydride 35.0% by mass
Candelilla wax 0.50% by mass
Castor oil 0.10% by mass
l-Menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
Citral 0.040% by mass
Eugenol 0.050% by mass
Decamethylcyclopentasiloxane Total remaining 100.0% by mass

(Prescription Example 10) Isocetyl lip stearate 25.0% by mass
Paraffin 20.0% by mass
Trioctanoin 10.0% by mass
Ceresin 5.0% by mass
Microcrystalline wax 5.0% by mass
Vaseline 1.0% by mass
l-Menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
Polyethylene glycol 1500 0.50 mass%
Citral 0.040% by mass
Eugenol 0.050% by mass
Liquid paraffin total remaining 100.0% by mass

(Formulation example 11) Body shampoo lauric acid 5.0 mass%
Myristic acid 7.0% by mass
Propylene glycol 4.0% by mass
Lauryldimethylaminoacetic acid betaine 3.50% by mass
Potassium hydroxide 3.60% by mass
Sodium sulfite 0.030% by mass
Methyl paraoxybenzoate 0.30% by mass
Phenoxyethanol 0.80% by mass
l-Menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
Polyethylene glycol 1500 0.50 mass%
Edetic acid salt Appropriate perfume Appropriate amount of purified water Total remaining amount 100.0% by mass

(Prescription Example 12) Sodium shampoo polyoxyethylene lauryl ether sulfate 6.0% by mass
Lauryldimethylaminoacetic acid betaine 2.0% by mass
Polyoxyethylene lauryl ether sodium acetate 3.0% by mass
Disodium lauryl sulfosuccinate 1.0% by mass
Coconut oil fatty acid diethanolamide 5.0% by mass
O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride 0.20% by mass
Dipotassium glycyrrhizinate 0.20% by mass
l-Menthol 5.0% by mass
l-Mentylglyceryl ether 0.10% by mass
Eucalyptol 0.10% by mass
d-borneol 0.10% by mass
Oxalic acid menthylethylamide 0.10% by mass
PCA Mentil 0.10% by mass
Polyethylene glycol 1500 0.50 mass%
Ethanol 3.0% by mass
Sodium chloride Appropriate amount edetate salt Appropriate amount Sodium benzoate Appropriate perfume Appropriate amount Purified water Total remaining amount 100.0% by mass

Claims (5)

A cosmetic comprising the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E).
Component (A): l-menthol Component (B): l-menthyl glyceryl ether Component (C): eucalyptol and / or borneol Component (D): menthyl lactate and / or menthylethylamide oxalate Component (E): PCA menthyl and / or monomenthyl succinate The content of the component (A) is 0.10 to 10.0% by mass,
The content of the component (B) is 0.010 to 3.0% by mass,
Content of the said component (C) is 0.005-1.0 mass%,
The content of the component (D) is 0.010 to 3.0% by mass,
Content of the said component (E) is 0.005-1.0 mass%
The cosmetic according to claim 1, wherein Furthermore, the cosmetics of Claim 1 or 2 containing the following component (F).
Component (F): a compound selected from the group consisting of camphor, linalool, geraniol, menthone, eugenol, and hydroxycitronellal   The cosmetic according to claim 3, wherein the content of the component (F) is 0.001 to 1.0 mass%.   The cosmetic according to any one of claims 1 to 4, which is a skin cosmetic.