CN1479783A - Improvements relating to fabric care - Google Patents
Improvements relating to fabric care Download PDFInfo
- Publication number
- CN1479783A CN1479783A CNA01820368XA CN01820368A CN1479783A CN 1479783 A CN1479783 A CN 1479783A CN A01820368X A CNA01820368X A CN A01820368XA CN 01820368 A CN01820368 A CN 01820368A CN 1479783 A CN1479783 A CN 1479783A
- Authority
- CN
- China
- Prior art keywords
- lubricant
- purposes
- weight
- fabric
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2205/00—General characteristics of the apparatus
- A61M2205/60—General characteristics of the apparatus with identification means
- A61M2205/6063—Optical identification systems
- A61M2205/6072—Bar codes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
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- Outer Garments And Coats (AREA)
Abstract
The invention is concerned with improvements relating to fabric care and in particular to means by which the apparent ageing of clothes can be reduced or retarded. Colour loss during laundering, as opposed to during wear, is a significant source of colour loss. We have determined that this problem may be overcome by use of a lubricant during the laundering process, to prevent the visible appearance of local colour loss through mechanical damage by the laundering process.
Description
Technical field
The present invention relates to the innovative approach relevant, particularly weaken or delay the measure of the apparent catabiosis of clothing with fabric nursing.
Background technology
The clothing that known clothing, particularly cost and quality are lower can lose dyestuff when washing.Once washed the people of a lot of clothings, almost each all had washing simultaneously newly to dye the unhappy experience of article and white articles.Simply, migration has taken place from tinted article to white articles in dyestuff, thereby causes serious color to change.For this problem, common terms of settlement is to wash new clothing separately.
The past heritage product are released dye also, and just speed is slower.Therefore, all be proposed in the various dyestuffs of introducing " laking agent ", " dye scavenging agent " or " guarantor's look " SYNTHETIC OPTICAL WHITNER in the laundry composition all the time.The research work of this respect is all deeply being carried out all the time widely, and has found and manyly make dyestuff fixing, prevent that its generation from depositing or suffering the method for chemical bleaching again, is intended to solve the dye migration problem in the mixing, washing thing.
As you know, when most of dyestuff release phenomenon occurs in new clothing and washs for the first time, and the duds thing only discharges the dyestuff of relatively small amount.To specifying that this does, this initial dyestuff loss phenomenon is seldom noted by the human consumer, except sporadic dye migration phenomenon according to following.
WO 01/53600 (P﹠amp; G:2000) relate to the dye for fabrics guard method, this method is only at jean.Described and from other approach as can be known according to this patent, jean is fairly individual cloth.At first, it is that yarn by two kinds of forms forms through weaving, a kind of through the dyeing another kind then without crossing dyeing.Secondly, the yarn that dyed look is generally through indigo dyeing, and most of dyestuff is arranged in the outer layer fiber of this yarn.This dyeing form is called as " ring type staining ", this method obtains be a kind of in wearing process dyestuff be easy to the fabric that lacks because of friction: so-called in the prior art that Here it is " friction is faded " process.Therefore, dyestuff separates with fabric in wearing process gradually, particularly at buttocks, knee and thigh place, is easy to subsequently just be leached in washing process.
The eclipsed behavior of characteristic that some people looks jean is needed characteristic.Some people even to deliberately increasing the weight of the destructiveness of jean article so that this class article seem the stage of " older ".It is problem that other people (according to the applicant of WO 01/53600) look the eclipsed phenomenon of this class.
WO 01/53600 points out; this quite special problem can solve by being used in combination cationic polymers, lower molecular weight polyamine, crystal growth inhibitor and laking agent; thereby for the jean fabric provides eclipsed protection effect, this eclipsed phenomenon mainly is that mechanical loss causes.This mechanical loss is to produce owing to the normal friction in the fabric wearing process destroys.Can combine and make color to fix significantly with clothing for addressing this problem the preparation that proposes, prevent or reduce the appearance of catabiosis thus.
The eclipsed behavior of this characteristic of jean is because its special structure causes, and is a bit unique.This seldom have other clothing to recommend to adopt the ring type staining, because can aggravate eclipsed phenomenon.
Even through ring type dyeing, the clothing catabiosis still can not brought many problems.
As mentioned above, even if be not the overwhelming majority, also there is greatly eclipsed phenomenon when washing for the first time, to take place.However, after through washing for the first time, generally also discover less than clothing change " old ".In fact, the general viewers general sensation causes any change less than the washing meeting first time to article apparent.Though noticeable change may take place for the tone or the color depth, do not have suitable contrast to see not too easily yet and draw.Therefore, prevent that actual eclipsed (adopting dye transfer inhibitor, laking agent etc.) still is not enough to prevent the apparent aging of clothing in itself.
The invention summary
The inventor thinks, the most significant signal was local eclipsed and non-integral is eclipsed when clothing and other article were aging.Though can lose color greatly from article generally speaking, this loss is not discovered by the viewer of carelessness, unless the phenomenon of turning pale is extremely serious.But any partial eclipsed phenomenon such as seam, will become an intensive signal, allows the people think that these article " have faded ".
In addition, the inventor thinks that the actual disappearance of dyestuff is not the prerequisite that apparent eclipsed phenomenon is behaved and discovered.Locate in seam etc., surface abrasion just is enough to scattering of light is changed, and looks that resembling dyestuff has lost the same.And practical situation are, dyestuff may still also exist.
And the inventor thinks, washing process but not eclipsed in the wearing process is the main root of turning pale.
The inventor thinks that this problem can be resolved by making with lubricator in laundry processes, thereby prevents the local eclipsed phenomenon of the visible that occurs because of physical disturbance in the laundry processes.
By making in this way with lubricator, it is believed that and to weaken or delay to be subjected to the local friction of washing product to act on.
Bypass that any theory of operation is explained no matter, it is believed that DYED FABRICS when fading, almost increasing with the luminance component of color without any exception is feature.The ability of known person perceived brightness fine difference is with space (spatial) relevant [M.D.Fairchild, " Colour Appearancemodels ", Addison Wesley Longman Publishing Co., New York (1998)].High sensitive is corresponding to the spatial frequency in 2-15 circulation/degree scope.If when happening to be in typical viewing distance place observation clothing (such as jeans), just might fall within this spatial frequency range by the caused feature of fading of laundry.Therefore, the subtle change of color can both influence the impression of clothing consumingly, as long as they are local existence.
Though totally eclipsed phenomenon is still very serious and be easy to measurement, if eclipsed very even, will have a greatly reduced quality to the sensory effect of this eclipsed phenomenon.Prevent that local eclipsed effect from being to reduce the washed aged degree that looks that is subjected to greatly.
Detailed Description Of The Invention
The physical disturbance degree that is subjected to the washing product and Machine Type, condition and the washing stage of being paid close attention to are relevant.The water yield is low and stir violent expection and can increase the weight of destruction, and the high water yield and not too violent stirring then can reduce destruction.Unfortunately, mechanize washing machine and the consideration of environment all required to improve stirring extent and reduce the water yield.
Stirring extent is different with water consumption in the wash cycle process, and lubricant preferably is present in the cyclic part that relates to low wash water and/or high-speed stirring.
Particularly preferred lubricant is a polymer substance.
Preferred feature of the present invention is, by adopting not provide protection when being subjected to washed adsorbed material to realize washing.It is believed that this can avoid to fabric through the washing after drying useful performance cause disadvantageous effect.Such as, preferably do not make the fabric sclerosis, do not increase the tendency that fabric absorbs and keep dirt or stain, breathing performance or the water absorption character that does not reduce fabric.
Therefore, preferred lubricant is that class material of not being with cationic charge.Preferred nonionic and anionic species.The performance that it is believed that anionic species can be better, extends (extended) structure because they form easily.
In order further to understand the present invention better, below be described with reference to each preferred feature.
Lubricant:
Can define suitable lubricant by many modes.
Preferred lubricant reduces frictional force on wet cotton.Preferred lubricant is among the present invention in full, is containing 1g/dm by following friction techniques and employing
3When the solution of this material is tested, its I
Wc1(wet cotton lubricating coefficient) material greater than 15.This coefficient is preferably greater than 50, more preferably greater than 75.
Preferred lubricant has specific viscosity performance.Preferred lubricant is with 1g/dm under 25 ℃ among the present invention in full
3After concentration was dissolved in the water, the solution that is obtained was at shearing rate 100s
-1Viscosity is greater than the material of 0.05Pa.s when measuring down.
Suitable lubricant comprises :-polyacrylate, its molecular weight are greater than 100, and 000Dalton (dalton) is preferably greater than 500,000Dalton;-polyacrylic acid, its molecular weight are greater than 100, and 000Dalton is preferably greater than 500,000Dalton;-polyacrylamide, its molecular weight are greater than 100, and 000Dalton is preferably greater than 500,000Dalton; Perhaps-multipolymer of various acrylic acid or the like materials.
Dextran also suits, and preferably its molecular weight is greater than 50, and 000Dalton is preferably greater than 200,000Dalton.
Other suitable material be molecular weight greater than 100, the polyvinylpyrrolidone of 000Dalton; Emulsive polydimethylsiloxane in the nonionic surface active agent; And the dispersion of mild oxidation polyethylene wax, such as (the Imacol C of Clariant
TM)
The lubricant material preferably exists with fabric consistency carrier.Generally speaking, carrier preferably constitutes the main part of the used product of the present invention.
In compositions for use of the present invention, the content of polymeric lubricant is 0.05 weight %～20 weight %, preferred 0.5～5 weight %.Unless otherwise noted, all percent value that provide in this specification sheets all are weight percentage, and all ratios are weight ratio.
Because the consumption of lubricant is very low,, as required lubricant is included in the prescription then so can make the cleaning product of pulvis, granule, tablet, liquid agent and other form in the usual way.
Tensio-active agent:
If the present composition is the form (such as main cleaning composition) of common cleaning composition, then fabric consistency carrier can be selected from soap class and soap anionic, positively charged ion, nonionic, both sexes and zwitierionic detergent active compound, and composition thereof.
Have many suitable detergent-active compounds available, and document did explanation fully to it, such as referring to " Surface-Active Agents and Detergents ", I and II volume, Schwartz, Perry and Berch compile.
Preferred used fabric consistency carrier is soap class and synthetic soap anionic and non-ionic surface active compound.
Anion surfactant is that the one skilled in the art is known.Material commonly used comprises alkylbenzene sulfonate, and particularly alkyl chain length is C
8-C
15Linear alkyl benzene sulfonate; Primary and secondary alkyl-sulphate, particularly C
8-C
15Primary alkyl sulphates; Sulfated alkyl ether; Alkene sulfonate; Alkylxylene sulfonate; Dialkyl sulfosuccinates; And fatty sulfonate.General particular certain cancers.
The available ionic surfactant pack is drawn together the primary and secondary alcohol ethoxylate, and particularly every mol alcohol is with the C of average 1～20mol oxyethane ethoxylation
8-C
20Fatty Alcohol(C12-C14 and C12-C18), more particularly every mol alcohol is with the C of average 1～10mol oxyethane ethoxylation
10-C
15The primary and secondary Fatty Alcohol(C12-C14 and C12-C18).The non-ethoxylated ionic surfactant pack is drawn together alkylpolyglycosides, glycerol monoethers and polyhydroxy amides (glucamide).
The available cats product comprises that general formula is R
1R
2R
3R
4N
+X
-Quaternary ammonium salt, wherein the R group is that length is C independently
1-C
22Hydrocarbon chain, generally be alkyl, hydroxyalkyl or ethoxylated alkyl, and X be add dissolved cation (such as this compounds, R wherein
1Be C
8-C
22Alkyl, preferred C
8-C
10Or C
12-C
14Alkyl, R
2Be methyl, and R
3And R
4Can be identical or different, be methyl or hydroxyethyl); And cationic ester (such as cholinesterase) and pyridinium salt.
The total amount of detergent surfactant is 0.1～60 weight % aptly in the composition, preferred 0.5～55 weight %, more preferably 5～50 weight %.
The amount of anion surfactant (if present) preferably accounts for 1～50 weight % of total composition.The amount of anion surfactant is 3～55 weight % more preferably, such as 5～30 weight %.
If present, preferred 2～25 weight % of the amount of nonionogenic tenside, more preferably 5～20 weight %.
Also can adopt amphoterics, such as amine oxide or trimethyl-glycine.Washing assistant:
These compositions contain the detergent builder compound of 10～70 weight %, preferred 15～70 weight % aptly.Preferred 15～50 weight % of the amount of washing assistant.
Cleaning composition can contain the crystal aluminosilicate washing assistant, preferred as alkali silico-aluminate, more preferably sodium silicoaluminate.
The addition of silico-aluminate is generally 10～70 weight % (butt), preferred 25～50 weight %.Silico-aluminate is the material of following general formula:
0.8-1.5 M
2O Al
2O
3.0.8-6 SiO
2Wherein M is a monovalent cation, preferred sodium.These materials contain some combination water, and require its calcium ion exchange capacity to be at least 50mg CaO/g.Preferred sodium silicoaluminate contains 1.5-3.5 SiO in aforementioned structural formula
2The unit.They are easy to be prepared by the reaction between water glass and the sodium aluminate, and particular content is referring to document.Rinsing and care composition:
Composition of the present invention can be the form of rinse composition, such as fabric-conditioning compositions.
If Fabrid care composition of the present invention or clothing rinse composition are the forms of fabric-conditioning compositions, then fabric consistency carrier can be fabric sofetening and/or conditioning compound (hereinafter referred to as " fabric soft compound "), and it can be positively charged ion or non-ionic compound.
Softness and/or conditioning compound can be water-insoluble on-macromolecular type quaternary ammonium compounds.The content of these compounds is up to 8 weight % (based on the total amount of composition), and this moment, composition was regarded as dilution type, perhaps content is 8 weight %～about 50 weight %, and this moment, composition was regarded as concentrated type.
The composition that is suitable for carrying in the rinse cycle process also can flow to fabric in roller dryer, but type of service is wanted suitably.Therefore, another kind of suitable product form is to be suitable for being coated on the composition (such as paste) of realizing conveying on the base material then from here in the roller dryer working cycle, and base material is such as being flexible sheet material or sponge or suitable divider (such as container with holes).
Suitable cationic fabric softening compound thing is water-fast basically quaternary ammonium material, and they comprise a mean chain length more than or equal to C
20Alkyl or alkenyl long-chain, perhaps more preferably, these compounds comprise polarity headgroup and two mean chain lengths more than or equal to C
14Alkyl or alkenyl chain.Fabric soft compound preferably has two chain alkyls or alkenyl chain, and the mean chain length of every kind of chain is all more than or equal to C
16Most preferably its chain length of at least 50% chain alkyl or alkenyl is at least C
18The chain alkyl of fabric soft compound or alkenyl preferably mainly are linear.
The quaternary ammonium compound that has two long-chain fat family groups such as VARISOFT TA100 and two (hardened tallow alkyl) alkyl dimethyl ammonium chloride, has been widely used in the commercially available rinsing care composition.Other example of these cation compounds is referring to " Surface-Active Agentsand Detergents ", and I and II roll up, and Schwartz, Perry and Berch compile.This compounds of any general type all can be used in the composition of the present invention.
Fabric soft compound preferably can provide the compound of the soft effect of excellence, and these compounds are characterised in that its chain fusion L β～L α transition temperature greater than 25 ℃, is preferably greater than 35 ℃, most preferably greater than 45 ℃.L β～L α changes can pass through " Handbook of LipidBilayers ", D Marsh, and CRC Press, Boca Raton, Florida, the defined DSC method of 1990 (the 137th and 337 pages) is measured.Basically water-fast fabric soft compound is defined as in deionized water the solubleness under 20 ℃ less than 1 * 10
-3The fabric soft compound of weight %.The solubleness of fabric soft compound is preferably less than 1 * 10
-4Weight % is more preferably less than 1 * 10
-8～1 * 10
-6Weight %.
Particularly preferably be cationic fabric softening compound thing, they are water-fast quaternary ammonium materials, have two C that link to each other with molecule by at least one ester bond
12-22Alkyl or alkenyl, preferred two ester bonds.
If the quaternary ammonium material is biodegradable on the physiology, be exactly suitable especially so.Preferred this class material is such as being 1, two (hardened tallow the acyloxy)-3-trimethyl ammonium propane chloride of 2-, and this class material and preparation method thereof is such as referring to United States Patent (USP) 4 137 180 (LeverBrothers Co.).These materials preferably comprise a small amount of corresponding monoester compound, referring to United States Patent (USP) 4 137 180, such as 1-hardened tallow acyloxy-2-hydroxyl-3-trimethyl ammonium propyl muriate.
The tetrahydroglyoxaline material that other useful cationic softener is Fixanol and replacement.The primary, the second month in a season and tertiary amine also are useful.
Composition or contain the water-soluble cationic fabric softener or contain the water-soluble cationic fabric softener in addition is referring to GB 2 039 556B (Unilever).
Composition can comprise cationic fabric softening compound thing and oils, such as referring to EP-A-0829531.
Composition or contain the nonionic fabric softener or contain the nonionic fabric softener in addition is such as lanolin and derivative thereof.
Yelkin TTS also is the softening compound thing that suits.
NON IONIC SOFTNER comprises into L β phase sugar ester (referring to people such as M Hato, Langmuir 12,1659,1966 (1996)) and related substances, such as Zerol or sorbitan ester.These materials usually and cationic substance be used in combination, with the assistant depositing process (referring to such as, GB 2 202 244).Siloxanes can according to cationic softener in handling with rinsing help the similar mode of softening agent use (such as referring to, GB 1 549 180).
Composition also can contain nonionic stabiliser aptly.Suitable nonionic stabiliser is through the oxyalkylated linear C of 10～20mol alkylene oxide
8～C
22Alcohol, C
10～C
20Alcohol or its mixture.Nonionic stabiliser is through the oxyalkylated linear C of 10～20mol alkylene oxide aptly
8～C
22Alcohol.The preferable amount of nonionic stabiliser is 0.1～10 weight %, more preferably 0.5～5 weight %, 1～4 weight % most preferably.The suitable mol ratio of quaternary ammonium compound and/or other cationic softener and nonionic stabiliser is 40: 1～about 1: 1, preferred 18: 1～about 3: 1.
Composition also can contain lipid acid, such as C
8～C
24Alkyl or alkenyl monocarboxylic acid or its polymkeric substance.The preferred saturated fatty acid, particularly hardened tallow C of adopting
16～C
18Lipid acid.The preferred non-saponification type of lipid acid, more preferably free type lipid acid is such as oleic acid, lauric acid or tallow fatty acid.The content of fatty acid material is preferably greater than 0.1 weight %, more preferably greater than 0.2 weight %.The concentrated type composition can comprise 0.5～20 weight % lipid acid, more preferably 1～10 weight %.Preferred 10: 1～1: 10 of the weight ratio of quaternary ammonium material or other cationic softener and fatty acid material.
This fabric-conditioning compositions can comprise siloxanes, such as the polydialkysiloxane based on linearity, such as polydimethylsiloxane or contain the aminosiloxane of amino-functionalization side chain; Amphoterics; The smectite type inorganic clay; The zwitter-ion quaternary ammonium compound; And nonionogenic tenside.Silicone components preferably has the dimethyl polysiloxane of aminoalkyl group.
Fabric-conditioning compositions also can comprise the apparent preparation of generation pearly-lustre, and such as organic compound such as Unister E 275, perhaps inorganic pearly pigment is such as ultra-fine mica or titanium dioxide (TiO
2) coating mica.
Fabric-conditioning compositions can be the form of emulsion or emulsion precursor.Accessory constituent and other component:
Other is chosen wantonly and accessory composition comprises emulsifying agent, ionogen (such as sodium-chlor or calcium chloride), preferred 0.01～5 weight % of its content, pH value buffer reagent and spices (preferred 0.1～5 weight %).
Other optional member comprises one or more non-aqueous solvents, fragrance carrier, white dyes, tinting material, hydrotropic agent, defoamer, enzyme, white dyes, opacifying agent, sanforzing agent, anti wrinkling agent, ecchymose removing agent, sterilant, mycocide, antioxidant, UV absorption agent (sun-screening agent), heavy metal chelant, chlorine scavenger, laking agent, anticorrosive agent, drape imparting agent, static inhibitor and flatiron auxiliary agent.This is enumerated not is to be exhaustive.Product form and manifestation:
Composition of the present invention can be the form of liquid agent, solid formulation (such as pulvis or tablet), gelifying agent or paste, sprays, stylus or foaming agent or mousse.The example comprises washes preceding infusion product, rinsing treating product (such as amendment or finishing composition) or the main product of washing.Also composition can be applied on the dirt-carrying body (such as flexible sheet material) or be placed in the divider and use, this divider can use in cycles of washing or rinse cycle.
Embodiment of the present invention show as, and introduce in the product and make with lubricator main washing.In these embodiments, product form generally is the form of pulvis or other granule, its size range from granule until tablet, perhaps liquid agent.Liquid agent of the present invention can be structurizing or isotropic.
The fabric of handling according to the inventive method generally is the form of clothing, preferred package cellulose fibrid, the cellulosic fibre of preferred 1～100 weight % (more preferably 5～100 weight % cellulosic fibres, 40～100 weight % most preferably are such as 75～100 weight %).If the content of cellulosic fibre is less than 100 weight % in the fabric, surplus then comprises other fiber or the fibre blend that is suitable for the clothing use, such as polyester or polymeric amide.Preferred cotton of cellulosic fibre or regenerated cellulose type such as viscose yarn.
As previously mentioned, said composition is preferably used as a main part of washing prescription especially.In automatic washing machine, this product is general washes the used packing of orders (packaged) together with the master.
In order further to understand the present invention, the present invention will be described referring now to following indefiniteness embodiment.
Embodiment
Embodiment 1---eye tracking research:
At Miele
TMAdopt the cotton circulation pattern of 40 ' C to make the cotton jeans of a black stand 10 repeated washings and dry recycle in the muzzle-loading automatic washing machine, then at Miele
TMCarry out 1 hour dry recycle in the roller dryer.These jeans are gone through repeatedly washing and are not are not also worn and torn.
These conditions have produced the typical pattern that brings out the inhomogeneous phenomenon of fading when washing: particularly along shank double joint place periodic depth pattern is arranged, and the phenomenon of fading increases the weight of to some extent at pocket, fly garment and waist-belt seam crossing.Generate the digital image of match colors for the front and back of jeans.These images as the stimulator in the following test, are come thus to determine how the viewer discovers clothing and fade.
Before study subject is sitting in computer display screen.Place a skinny device under display screen, this equipment has used infra-red tracing system, and after overcorrection, this system can detect study subject and to which direction see.Then it is carried out conversion, thereby calculate which part that study subject is being watched image on the screen attentively.In entire test, continue this information of record,, particularly determine order, position and time length when they watch screen attentively and go up visual different piece so that might reproduce the eyes situation of movement of study subject.
Through after the initial calibration, tell study subject their task.Their task be exactly on the viewing screen image and judge that the number of times of which washing in two shown clothings is more.See blank screen to them during beginning, but a coloured circle is arranged, Here it is informs the blinkpunkt that they will see.Change the front and back image of same jeans then into.This moment opening entry study subject eyes situation of movement, say oneself judgement up to them.The purpose of using two images of same clothing is that its difference is not too large when guaranteeing that the observer only promptly draws a conclusion with peripheral visual acuity.Adopt 6 different study subjects to repeat this test.
Eye tracking record result shows that most blinkpunkts is all relevant with the clothing feature that demonstrates the inhomogeneous and non-homogeneous phenomenon of fading with fixation time, that is: seam, button covering, pocket and waistband are exhausted without exception.
Embodiment 2---and the people is to the susceptibility of color change:
For quantitatively with washed on friction bring out inhomogeneous color changed when evenly color change compares, the enhancing situation of people's color change sensation has been carried out following test.
By proofreading and correct setting of printing Adobe Photoshop
TMProduce two groups and proofread and correct color chips.One group of color chips is made of many color chips to even color, and this moment, difference in color only was its brightness value.These differences have contained a series of value.6 serial color chips that tone is different have been adopted.Second group of color chips is made of same serial color chips, and just that more shallow color that it is shallow overlaps on the original color in two color chips this moment, and it is the striped that is under the color chips central authorities.When selecting width of fringe, the spatial frequency that make the viewing distance place is 2 circulation/degree.Require 24 members of evaluation group that the order that each series in two groups of color chips all increases the weight of by fading is arranged.Adopt Probit
TMStatistical analysis method is analyzed their review result, providing " only can know difference " (JND) value of the sensation of fading then.
The result is listed in the table below with the form of CIELAB δ-E value in (table 1).(δ-E represents the size of heterochromia).Clearly, though absolute size is different along with the difference of tone, with seeing that the sample that evenly fades compares, the member of evaluation group is when seeing the inhomogeneous sample that fades, and the ability that they discover the phenomenon of slightly fading is consistent.
Table 1:
All even inhomogeneous " only can know difference " value of fading
| Tone | The JND that evenly fades/CIELAB Δ E | The inhomogeneous JND that fades/CIELAB Δ E |
| Yellow | ????1.50 | ????1.00 |
| Pinkish red | ????1.10 | ????0.50 |
| Blue | ????0.45 | ????0.25 |
| Black | ????0.75 | ????0.35 |
Embodiment 3---correlation research:
Adopting a plurality of different washing schemes (different washing composition, drying means, through or without flatiron) will many black cottons " military " type trousers to carry out repeatedly (1～10) washs and dry recycle.The result of these different methods is, the clothing of whole cupboard all shows fading in various degree.
Find the zone of a 10cm * 10cm at the shank of clothing, it contains and fades double slit splice grafting seam serious and zone that " background " look evenly disappears and takes off.Adopt DatacolorSpectraflashTM 500 photometric determinations to go out the reflection spectrum of background and seam region.
Calculate the CIELAB value of its seam of every clothing and background area from these spectrometers.Then these clothings are given once that everyone shows one among 20 different members of evaluation group.When showing clothing, only allow it see the zone of 10 * 10cm size.The requirement member of evaluation group is fading extent marking by 0～100 scale.Calculate the mean scores of every clothing.Draw out two width of cloth graphic representations by these data: a width of cloth figure is the L of clothing background area
*Value is to the member's of evaluation group scoring mapping; And another width of cloth is the L of seam
*Value is to the member's of evaluation group scoring mapping.Calculate the relation conefficient of every curve.
The results are shown in the following table 2.Can be clear that from these values the visual score value that fades of the brightness of the inhomogeneous seam of fading and the member of evaluation group more is closely related, the brightness value of the background of evenly fading fabric is then than for poor.
Table 2: the dependency between test brightness and the visual score value
| Relation conefficient | |
| L *The member of (background)-evaluation group scoring | ????0.79 |
| L *The member of (seam)-evaluation group scoring | ????0.90 |
Embodiment 4---friction testing:
Adopt E1dredge
TMTribometer is measured the frictional coefficient between two white cotton fabrics that are immersed in the lubricant substance solution, and this tribometer can be used for studying subsurface material through improvement.
Simply, this device is made of round shape watertightness elongated slot, fixed in its bottom a 30 * 8cm common, weave, white and 100% cotton bedspread of non-mercerization.On it, put the similar fabric of a slice, settling a diameter all around along it is that 1cm and length are the round shape clamper of 6cm, be connected on the revoliving arm, this revoliving arm can make the fabric cylinder contact with the immobilized cloth under the normal load of regulation when driving, and makes it drive into 6.5cm along the cloth length direction then under controlled velocity.Stain measuring apparatus on the arm can be measured the frictional force opposite with this direction of motion.Can calculate frictional coefficient (μ) from frictional force and normal load.This test can be carried out under a series of speed; But for this paper purpose, suitable is that the selection sliding velocity is 6cm/s.
In order to estimate the efficient of potential oiling system, cotton lubricating coefficient (I will wet
Wcl) be defined as:
μ wherein
0Be frictional coefficient, it is to adopt the solution that does not contain oiling system to measure according to preceding method.
Embodiment 5～8:---prescription
Following examples are representative formulas of the present invention.Material branch used among the embodiment is listed in the table 3.
Table 3: specifications of raw materials
| Component | Specification |
| LAS | LINER ALKYL BENZENE SULPHONIC ACID SOFT 96, Marlon AS3 TM, from Huls |
| Na-PAS | The primary alkyl Phenylsulfonic acid neutralizes through sodium hydroxide |
| Dobanol TM?25-7 | C 12-15Ethoxylated alcohol, 7EO is from Shell |
| Zeolite | Wassalith TMP is from Degussa |
| STPP | Tripoly phosphate sodium STPP, Thermphos TMNW is from Hoechst |
| Dequest TM?2066 | Metal chelator is from Monsanto |
| Lipolase | The 100L type is from Novo |
| Savinase TM?16L | Proteolytic enzyme is from Novo |
| Sokalan TM?CP5 | Vinylformic acid/Malaysia acids helps washes polymkeric substance, from BASF |
| The deflocculate polymkeric substance | EP-A-346 995 disclosed polymer A-11 |
| SCMC | Xylo-Mucine |
| Accessory constituent | Antiredeposition polymkeric substance, transition metal scavenging agent/bleaching stibilizer, white dyes, defoamer, dye transfer inhibiting polymers, enzyme, spices |
Embodiment 5---the spraying drying pulvis:
Embodiment 5 provides spraying drying pulvis of the present invention.The composition of pulvis sees Table 4.
Table 4
| Component | W/w % |
| PAS sodium | ????11.5 |
| Dobanol?25-7 | ????6.3 |
| Soap | ????2 |
| Zeolite | ????24.1 |
| SCMC | ????0.6 |
| Trisodium Citrate | ????10.6 |
| Yellow soda ash | ????23 |
| Sodium polyacrylate (molecular weight 1 300 000) | ????0.7 |
| Dequest?2066 | ????0.4 |
| Sokalan?CP5 | ????0.9 |
| Savinase?16L | ????0.7 |
| Lipolase | ????0.1 |
| Spices | ????0.4 |
| Water/salt | Complement to 100% |
Embodiment 6---by the washing granule agent of non-spray drying method for preparation
Embodiment 6 provides and has passed through non-tower approach granule prescription made in accordance with the present invention.
Table 5
| Component | W/w % |
| PAS sodium | ????13.5 |
| Dobanol?25-7 | ????2.5 |
| STPP | ????45.3 |
| Yellow soda ash | ????4 |
| Polyacrylamide (molecular weight 5-6 000 000) | ????2.8 |
| Water glass | ????10.1 |
| Accessory constituent | ????1.5 |
| Water | Complement to 100% |
Embodiment 7---the isotropy washing liquid
Embodiment 7 provides the example of isotropy washing liquid of the present invention.Prescription sees Table 6:
Table 6
| Component | W/w % |
| Trisodium Citrate | ????10.7 |
| Propylene glycol | ????7.5 |
| Ethylene glycol | ????4.5 |
| Borax | ????3 |
| Savinase?16L | ????0.3 |
| Lipolase | ????0.1 |
| Dextran (molecular weight 800 000) | ????1.0 |
| Monoethanolamine | ????0.5 |
| Fatty acid distribution of coconut oil | ????1.7 |
| Sodium hydroxide (50%) | ????2.2 |
| LAS | ????10.3 |
| Dobanol?25-7 | ????6.3 |
| LES | ????7.6 |
| Accessory constituent (the pH value being adjusted to 7) with sodium hydroxide | ????1.3 |
| Water | Complement to 100% |
Embodiment 8---the structurizing washing liquid
Embodiment 8 provides the example of structurizing washing liquid of the present invention.The prescription of product sees Table 7.
Table 7
| Component | W/w % |
| LAS | ????16.5 |
| Dobanol?25-7 | ????9 |
| Oleic acid (Priolene (6907)) | ????4.5 |
| Zeolite | ????15 |
| Potassium hydroxide, neutralizing acid and adjusting pH value are used | ????8.5 |
| Citric acid | ????8.2 |
| The deflocculate polymkeric substance | ????1 |
| Proteolytic enzyme | ????0.38 |
| Lipolase | ????0.2 |
| Imacol C (from Clariant) | ????2.0 |
| Accessory constituent | ????0.4 |
| Water | Complement to 100% |
Embodiment 9---wp formula:
Embodiment 9 provides the example of other wp formula.Its composition sees Table 8.
Table 8
| Component | W/w % |
| LAS sodium | ????6.3 |
| Nonionic 3EO branching | ????3.15 |
| Nonionic 7EO branching | ????4.05 |
| Soap | ????0.28 |
| Tripoly phosphate sodium STPP | ????23.9 |
| Sodium peroxoborate | ????20.00 |
| Water glass | ????6.31 |
| Tetra acetyl ethylene diamine | ????2.22 |
| SCMC | ????0.23 |
| Sodium sulfate | ????9.87 |
| Yellow soda ash | ????8.49 |
| Sodium polyacrylate (molecular weight 1 300 000) | ????5.0 |
| Dequest?2047 | ????0.55 |
| Sokalan?CP5 | ????1.13 |
| Savinase?12?TXT | ????0.40 |
| Lipolase | ????0.1 |
| Spices | ????0.24 |
| Water/salt | Complement to 100% |
Claims (10)
1. the purposes of lubricant in laundry processes is with the local eclipsed phenomenon of the visible that prevents to occur because of mechanical damage in the laundry processes.
2. the purposes of claim 1, wherein lubricant is nonionic or anionic high molecular substance.
3. the purposes of claim 2 wherein contains 1g/dm in employing
3When the solution of lubricant was tested, this lubricant was pressed wet cotton lubricating coefficient defined herein greater than 15.
4. the purposes of claim 2, wherein lubricant is with 1g/dm under 25 ℃
3Concentration be dissolved in the water after, the solution that is obtained is at shearing rate 100s
-1Viscosity is greater than the material of 0.05Pas when measuring down.
5. the purposes of claim 2, wherein the molecular weight of lubricant is greater than 100,000Dalton.
6. the purposes of claim 5, wherein lubricant is polyacrylate, polyacrylic acid, polyacrylamide, polyvinylpyrrolidone or its multipolymer.
7. the purposes of claim 2, wherein lubricant is a polydimethylsiloxane.
8. the purposes of claim 2, wherein lubricant is an oxidized polyethlene wax.
9. the purposes of claim 2, wherein the consumption of lubricant is 0.5～5 weight %.
10. the purposes of claim 2, wherein being subjected to the washing product is clothings.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0030177.0 | 2000-12-11 | ||
| GBGB0030177.0A GB0030177D0 (en) | 2000-12-11 | 2000-12-11 | Textile care composition |
| GB0109142A GB0109142D0 (en) | 2001-04-11 | 2001-04-11 | Textile care composition |
| GB0109142.0 | 2001-04-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1479783A true CN1479783A (en) | 2004-03-03 |
Family
ID=26245415
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018203671A Expired - Fee Related CN100439483C (en) | 2000-12-11 | 2001-12-03 | Textile care composition |
| CNA01820368XA Pending CN1479783A (en) | 2000-12-11 | 2001-12-03 | Improvements relating to fabric care |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018203671A Expired - Fee Related CN100439483C (en) | 2000-12-11 | 2001-12-03 | Textile care composition |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7091172B2 (en) |
| EP (2) | EP1341889B1 (en) |
| CN (2) | CN100439483C (en) |
| AT (2) | ATE319797T1 (en) |
| AU (2) | AU2002237227A1 (en) |
| BR (1) | BR0116073A (en) |
| CA (2) | CA2429646C (en) |
| DE (2) | DE60124949T2 (en) |
| ES (2) | ES2260312T3 (en) |
| WO (2) | WO2002048305A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114318904A (en) * | 2022-01-11 | 2022-04-12 | 绍兴思奈纺织有限公司 | Dyeing process of super-soft warp knitted fabric |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2388610A (en) * | 2002-05-17 | 2003-11-19 | Procter & Gamble | Detergent composition containing silicone and fatty acid |
| US20040033924A1 (en) * | 2002-08-14 | 2004-02-19 | Murphy Dennis Stephen | Methods for conferring fabric care benefits during laundering |
| GB0623004D0 (en) * | 2006-11-17 | 2006-12-27 | Unilever Plc | Fabric treatment method and composition to impart differential hydrophobocity |
| US7868071B2 (en) * | 2007-07-30 | 2011-01-11 | Georgia-Pacific Chemicals Llc | Method of stabilizing aqueous cationic polymers |
| TW201113409A (en) * | 2009-10-06 | 2011-04-16 | Ruentex Ind Ltd | A yarn manufacturing method and a mixing yarn |
| US9265458B2 (en) | 2012-12-04 | 2016-02-23 | Sync-Think, Inc. | Application of smooth pursuit cognitive testing paradigms to clinical drug development |
| US9380976B2 (en) | 2013-03-11 | 2016-07-05 | Sync-Think, Inc. | Optical neuroinformatics |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3594355A (en) * | 1969-10-29 | 1971-07-20 | Hercules Inc | Water-soluble isothiuronium salts of epihalohydrin polymers |
| US3694258A (en) * | 1970-12-28 | 1972-09-26 | Hercules Inc | Dimensional stabilization of wool |
| FR2436213A1 (en) * | 1978-09-13 | 1980-04-11 | Oreal | COMPOSITION FOR TREATING FIBROUS MATERIALS BASED ON CATIONIC AND ANIONIC POLYMERS |
| US5160733A (en) | 1991-05-06 | 1992-11-03 | Clairol Inc. | Conditioning compositions with perfluoropolymethylisopropylethers |
| US5354335A (en) | 1993-02-04 | 1994-10-11 | Isaac Lipshitz | Intraocular insert for implantation in the human eye |
| GB9510396D0 (en) * | 1995-05-23 | 1995-07-19 | Allied Colloids Ltd | Polymers for drilling and reservoir fluids and their use |
| US5830843A (en) * | 1996-01-31 | 1998-11-03 | The Procter & Gamble Company | Fabric care compositions including dispersible polyolefin and method for using same |
| AU7162796A (en) | 1996-09-19 | 1998-04-14 | Procter & Gamble Company, The | Color care compositions |
| US5827813A (en) * | 1997-02-28 | 1998-10-27 | Procter & Gamble Company | Detergent compositions having color care agents |
| JP4183904B2 (en) * | 1997-07-29 | 2008-11-19 | ザ プロクター アンド ギャンブル カンパニー | Aqueous gel laundry detergent composition |
| WO1999041347A1 (en) * | 1998-02-11 | 1999-08-19 | Rhodia Chimie | Detergent compositions containing an amine silicone and a polymer inhibiting colour transfer |
| ATE278758T1 (en) | 1998-08-03 | 2004-10-15 | Procter & Gamble | CREASEPROOF COMPOSITION |
| CN1318096A (en) | 1998-09-15 | 2001-10-17 | 宝洁公司 | Fabric care and laundry compsns. comprising low molecular weight linear on cyclic polyamines |
| US6376456B1 (en) * | 1998-10-27 | 2002-04-23 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Wrinkle reduction laundry product compositions |
| CA2359438A1 (en) | 1999-02-19 | 2000-08-24 | The Procter & Gamble Company | Fabric enhancement compositions |
| GB9923279D0 (en) * | 1999-10-01 | 1999-12-08 | Unilever Plc | Fabric care composition |
| EP1240382A1 (en) * | 2000-01-18 | 2002-09-18 | The Procter & Gamble Company | Compositions which prevent abrasive color loss from denim fabric |
| GB0002964D0 (en) * | 2000-02-09 | 2000-03-29 | Unilever Plc | Fabric caare composition |
-
2001
- 2001-12-03 BR BR0116073-7A patent/BR0116073A/en not_active IP Right Cessation
- 2001-12-03 WO PCT/EP2001/014382 patent/WO2002048305A1/en active IP Right Grant
- 2001-12-03 WO PCT/EP2001/014378 patent/WO2002048303A1/en active IP Right Grant
- 2001-12-03 US US10/450,076 patent/US7091172B2/en not_active Expired - Fee Related
- 2001-12-03 AU AU2002237227A patent/AU2002237227A1/en not_active Abandoned
- 2001-12-03 CN CNB018203671A patent/CN100439483C/en not_active Expired - Fee Related
- 2001-12-03 CA CA2429646A patent/CA2429646C/en not_active Expired - Fee Related
- 2001-12-03 US US10/450,077 patent/US20050192202A1/en not_active Abandoned
- 2001-12-03 ES ES01986401T patent/ES2260312T3/en not_active Expired - Lifetime
- 2001-12-03 DE DE60124949T patent/DE60124949T2/en not_active Expired - Lifetime
- 2001-12-03 EP EP01986401A patent/EP1341889B1/en not_active Expired - Lifetime
- 2001-12-03 AT AT01986401T patent/ATE319797T1/en not_active IP Right Cessation
- 2001-12-03 CA CA2429644A patent/CA2429644C/en not_active Expired - Fee Related
- 2001-12-03 CN CNA01820368XA patent/CN1479783A/en active Pending
- 2001-12-03 AT AT01989585T patent/ATE346904T1/en not_active IP Right Cessation
- 2001-12-03 DE DE60117845T patent/DE60117845T2/en not_active Expired - Lifetime
- 2001-12-03 EP EP01989585A patent/EP1341890B1/en not_active Expired - Lifetime
- 2001-12-03 ES ES01989585T patent/ES2276851T3/en not_active Expired - Lifetime
- 2001-12-03 AU AU2002227997A patent/AU2002227997A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114318904A (en) * | 2022-01-11 | 2022-04-12 | 绍兴思奈纺织有限公司 | Dyeing process of super-soft warp knitted fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100439483C (en) | 2008-12-03 |
| CA2429646C (en) | 2011-10-18 |
| CN1599790A (en) | 2005-03-23 |
| DE60124949D1 (en) | 2007-01-11 |
| EP1341889A1 (en) | 2003-09-10 |
| DE60117845D1 (en) | 2006-05-04 |
| AU2002237227A1 (en) | 2002-06-24 |
| DE60124949T2 (en) | 2007-03-15 |
| ATE319797T1 (en) | 2006-03-15 |
| DE60117845T2 (en) | 2006-08-24 |
| ATE346904T1 (en) | 2006-12-15 |
| CA2429644A1 (en) | 2002-06-20 |
| CA2429646A1 (en) | 2002-06-20 |
| ES2276851T3 (en) | 2007-07-01 |
| CA2429644C (en) | 2010-10-12 |
| AU2002227997A1 (en) | 2002-06-24 |
| US20040045093A1 (en) | 2004-03-11 |
| US20050192202A1 (en) | 2005-09-01 |
| EP1341890A1 (en) | 2003-09-10 |
| EP1341889B1 (en) | 2006-03-08 |
| EP1341890B1 (en) | 2006-11-29 |
| BR0116073A (en) | 2004-02-17 |
| ES2260312T3 (en) | 2006-11-01 |
| US7091172B2 (en) | 2006-08-15 |
| WO2002048305A1 (en) | 2002-06-20 |
| WO2002048303A1 (en) | 2002-06-20 |
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