CN1470682A - Method for preparing fiber with negative ion far infrared antibacterial health-care function and product thereof - Google Patents
Method for preparing fiber with negative ion far infrared antibacterial health-care function and product thereof Download PDFInfo
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- CN1470682A CN1470682A CNA021456038A CN02145603A CN1470682A CN 1470682 A CN1470682 A CN 1470682A CN A021456038 A CNA021456038 A CN A021456038A CN 02145603 A CN02145603 A CN 02145603A CN 1470682 A CN1470682 A CN 1470682A
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- tourmaline
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Abstract
The present invention relates to a production method of fibre capable of releasing negative ions, sending far infrared ray and having anti-bacterial health-care function. THe composition of said fibre includes component A, nano silver and component B, tomalin. The addition of two components not only can improve surface gliding property of mineral fibre, do not damage equipment component in the course of production to raise production efficiency, but also can use a certain quantity of metal particles as release channel of negativbe ions, so that the negative ion releasing quantity of said fibre can be raised.
Description
The present invention relates to a kind of fiber that contains functional mineral powder, has plurality of health care functions, particularly relate to and a kind ofly can discharge anion, launch far infrared and have the fiber method for making and the goods thereof of antibiotic health-care function.
Anion extensively is present in the Nature, areas such as place that content is high such as forest, seashore, waterfall, and it can make the people feel in a good mood.This is after entering blood of human body by skin and absorption system because of anion, cytoactive to be increased, thereby improves the vis medicatrix naturae and the immunity of human body, also can activate parasympathetic nerve simultaneously, and people's mind peacefulness, blood pressure drops, mood are loosened.
Infrared ray is a kind of electromagnetic wave between visible light and microwave, and wavelength is between 0.76～1000 micron.Its medium wavelength can be absorbed by the body at the 4-15 micron waveband, produces thermogenetic effect, thus the expansion capillary, and microcirculation improvement enhances metabolism.In the prior art, existing many foreign literatures have carried out deep argumentation and discussion to the anion far IR fibre.The fiber and the fabric that possess this function also come into the market, and wherein " 10LINA " fiber of " HOLIC " fiber of island weaving, big and weaving applies in Japan, " IONAGE " fiber that day is spun clearly is more representative.These fibers all adopt the technology of co-blended spinning, are used for synthetic fiber such as terylene, polypropylene fibre.Also there are many Chinese patent application that this is disclosed, as CN1266119 " rayon fiber and the manufacture method thereof that contain tourmaline particle "; CN1308149 described " a kind of synthetic fiber and manufacture method thereof " for another example; CN1293278 described " anion far infrared health care fabric and method for making thereof " and for example.Wherein main component is the natural silicate mineral--Tourmaline (tourmaline), English name tourmaline.It is the natural minerals that self forever has electromagnetic field, exists extremely faint electric current between its crystal, though electric current is very weak, voltage can reach 1,000,000 electron-volts, and the electronics of emitting makes airborne H
2O ionization, H+ combines with electronics and generates hydrogen, OH-and the generation of water molecules on every side H
3O
2-, produce anion.Therefore, its generation of anion in fabric is nonvolatil.But because the crystal shape of Tourmaline is a column crystallization, the cross section is hexagon, this many shuttles body material has destroyed the surface characteristic of fiber itself in fiber, produce hard thorn, in the process of spinning cotton and weaving cloth, can damage card clothing in the Weaving device, yarn introduction member, and brown sheet etc., thereby influence the quality of final textiles.
In addition, although Tourmaline has preferable performance at aspects such as anion and far infrared generations, the performance of its antibacterial and mouldproof is not fully up to expectations.Or perhaps a kind of shortcoming of Tourmaline.In the routine fashion of fiber, having of the functional mineral powder that can add is a variety of.Normally used functional powder is two classes, and it first is the mineral matter composite powder, and crystalline form is a pinacoid; The secondth, crystalline form be prism, rhombohedron, hexahedron, mineral dust.Crystalline form is that the mineral of prism have: discrasite, corundum, rutile, zircon, pyroxene, modenite, jade, tourmaline etc.These class mineral easily cause the fiber broken end because its crystalline structure can influence the slickness of fiber surface, and the Weaving device accessory that can wear and tear.Crystalline form is that the mineral of pinacoid have: vitreous copper, marcasite, chrysoberyl, ilmenite, shepardite, talcum powder, paragonite, montmorillonite, serpentine, palygorskite etc.The crystalline form of these class mineral can be orientated with fiber orientation, not only can not influence the surface property of fiber, but also can improve the spinnability of simple prism mineral fibres.
One of purpose of the present invention is: propose a kind ofly not only have the far function of generating negative ions, but also have the fiber of excellent antibacterial and mouldproof health-care function.
Two of purpose of the present invention is: propose a kind of manufacture method that contains the fiber of two kinds of functional mineral powders.Improving the surface smoothness of simple faceted pebble body mineral fibres, not damage equipment accessory such as card clothing, yarn introduction member, brown sheet etc. in manufacture process, and then boost productivity.
Three of purpose of the present invention is: propose a kind of function that promotes that anion discharges, add the release channel that a certain amount of metal particle can be used as anion in fiber, thereby improve the anion burst size of fiber.
Technical scheme of the present invention is: a kind of synthetic fiber are provided, and wherein containing particle diameter in the fiber at least is following Nano Silver and Tourmaline (tourmaline) particulates of 100 nanometers.
In order to realize purpose of the present invention, at first make component A: Nano Silver and B component: Tourmaline.A: make: at first count by following weight portion by following proportioning and manufacture method:
Palygorskite 100
Water soluble silver salt 4-20
NaOH 0.5-3.0
Dense NH
3H
2O 7.0-45.0
Reductant 10-50
Water 400-1000 manufacturing step is: a. with water-soluble silver salt solution and NaOH reaction, adds NH earlier again
3H
2O forms silver ammonia complex in the aqueous solution; B. palygorskite clay is added in the above-mentioned solution, stirred through 3-8 hour, to colloid shape solution; C. further add reductant and heat to 50-95 ℃, make the surface of palygorskite and the silver ammino ion in the micropore be reduced into Nano Silver, its particle diameter is about 35 nanometers.D. through dehydration, heating bakes, and is crushed to average grain diameter 300 nanometers, obtains component A.The preparation of B component: select Tourmaline (tourmaline) crystal, be crushed to the bulk of 8-25 millimeter size, be crushed between the 20-40 micron covering pulverizer by thunder by gyratory crusher; Being ground to solid particle mean size in the aqueous solution by the sand mill wet method at last is 0.3 micron slurry.
Again with A component and B component with 1: the ratio of 1-4.8 mixes, will be spun into CSK-AB Nano Silver/Tourmaline fiber after fiber magma or high polymer fully mix.Wherein the content of Nano Silver is the 1-2% percentage by weight, and the content of Tourmaline is the 0.5-5% percentage by weight.
Wherein the crystalline form of CSK-A is a monoclinic crystal, and is loaded with nano level metal silver, can be used as pinacoid; The crystalline form of CSK-B is a hexahedron.After being spun into fiber, the laminated crystalline body of CSK-A is orientated with the orientation of fiber, makes this fiber surface become smooth, has improved the intensity and the spinnability of simple Tourmaline (tourmaline) fiber.And can not produce damage, thereby boost productivity equipment.
Under the characteristic functions effect of CSK-AB Nano Silver/Tourmaline, biological ripple (far infrared) function of the emission 4-14 micron that causes this fiber not only to keep other tourmaline fibers to be had, its emissivity is more than 85%; Permanent negative ion-releasing function, its burst size is at 4.0 * 103/cm
3And produce 0.06 milliampere of bioelectricity function, and has significant antibacterial and deodouring function.It collects multiple health care function is one, clings to the body stimulated by the movable friction of body temperature and each position, excites and carries thermoelectric, the piezo-electric effect of silver-colored tourmaline generation.Long-term dress can be received multiple function acting in conjunction and the comprehensive health-care effect that produces.In addition, because Nano Silver has great specific area, there are a large amount of strong chemical bonds that close again in surface texture, causes chemical activity to heighten, and realizes that it is long-acting, wide spectrum, antibiotic, anti-mildew characteristic.Thereby the antibacterial action and deodorization of fiber is superposeed, is strengthened; Especially the excellent effect that commute is perspired, body odour is dense, the people of pruitus and the people that suffers from gynaecology's andrological diseases can play antibacterial deodorizing.Moreover the argent in the Nano Silver can play electric action, forms ion channel in fiber, has promoted the anion of fiber to discharge.
Fig. 1 is a process chart of the present invention.
For the present invention being done detailed elaboration, below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1: get AgNO
34.0 kilogram under agitation is dissolved in 600 kg water, adds 0.5 kilogram of NaOH and 26%NH
3H
27.0 kilograms of O add the palygorskite double centner of powdery then, at room temperature stir 3 hours, and it is fully reacted, and are the colloid shape until product.Get 10.0 kilograms of addings of hydrogen peroxide wherein, be warming up to 70 ℃, make the silver ammino ion that is loaded in the palygorskite micropore be reduced into Nano Silver.Products therefrom is filtered, drying is crushed to 0.3 micron again, and silver-colored particle wherein is the 30-50 nanometer, and is standby as the A component.
10KG black Tourmaline (tourmaline) is passed through the bulk that gyratory crusher is crushed to 15 millimeters sizes, be crushed to 30 microns by battalion's illiteracy pulverizer; Be to add in sand mill at 1: 4 with the ratio of Tourmaline (tourmaline) and water (quality) at last,, obtain solid particle mean size in the aqueous solution and be 0.5 micron slurry with wet grinding mill 10 hours, standby as the B component.
A, B component are mixed, and mixing ratio is 1: 3.Control its solid content that mixes back preparation liquid 25%, with after viscose glue stoste is fully mixed, be spun into Nano Silver/Tourmaline viscose with the method for injection.Its flow process as shown in Figure 1.
Embodiment 2: the method for making of component A and B component is undertaken by embodiment 1 identical method.The wet pulp of B component is made 0.5 micron particulate through after the spray drying, and after A, B component were mixed by 1: 3 mixing ratio, the weight % with 5% added polyester fondant, makes polyester master particle.Can spin Nano Silver/Tourmaline polyster fibre with conventional spinning process.
Embodiment 3: except replacing the polyester with polypropylene, present embodiment is undertaken by embodiment 2 identical methods, can make CSK-AB Nano Silver/Tourmaline polypropylene fiber.
Embodiment 4: the Nano Silver/Tourmaline viscose of gained among the embodiment 1 is passed through the water acupuncture manipulation, and through shredding, lapping, the water thorn, the back arrangement obtains spunlace non-woven cloth.Grammes per square metre 50-60 gram/square metre.
Claims (5)
1, a kind of fiber with negative ion far-infrared antimicrobial health care, it is characterized in that containing at least in the fiber particle diameter is following Nano Silver and Tourmaline particulates of 100 nanometers.
2, fiber as claimed in claim 1 is characterized in that the percentage by weight of Nano Silver/Tourmaline of being contained is: Nano Silver 1-2%, the 0.5-5% of Tourmaline.
3, a kind of manufacture method of fiber as claimed in claim 1 is characterized in that it comprises manufacturing component A: Nano Silver and B component: Tourmaline; A: make: at first count by following weight portion by following proportioning and manufacture method:
Palygorskite 100
Water soluble silver salt 4-20
NaOH 0.5-3.0
Dense NH
3H
2O 7.0-45.0
Reductant 10-50
Water 400-1000 manufacturing step is: a. with water-soluble silver salt solution and NaOH reaction, adds NH earlier again
3H
2O forms silver ammonia complex in the aqueous solution; B. palygorskite clay is added in the above-mentioned solution, stirred through 3-8 hour, to colloid shape solution; C. further add reductant and heat to 50-95 ℃, make the surface of palygorskite and the silver ammino ion in the micropore be reduced into Nano Silver, its particle diameter is about 35 nanometers; D. through dehydration, heating bakes, and is crushed to average grain diameter 300 nanometers, obtains component A; The preparation of B component: select Tourmaline (tourmaline) crystal, be crushed to the bulk of 8-25 millimeter size, be crushed between the 20-40 micron covering pulverizer by thunder by gyratory crusher; Being ground to solid particle mean size in the aqueous solution by the sand mill wet method at last is 0.3 micron slurry;
Again with A component and B component with 1: the ratio of 0.1-4.8 mixes, will be spun into Nano Silver/Tourmaline fiber after fiber magma or high polymer fully mix.
4, a kind of nonwoven fabric that adopts the described fiber of claim 1 is characterized in that containing Nano Silver/Tourmaline in this nonwoven fabric, and wherein the content of Nano Silver is the 1-2% percentage by weight, and the content of Tourmaline is the 0.5-5% percentage by weight.
5, the described nonwoven fabric of claim 4 is characterized in that described nonwoven fabric is a spunlace non-woven cloth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021456038A CN1470682A (en) | 2002-07-26 | 2002-10-12 | Method for preparing fiber with negative ion far infrared antibacterial health-care function and product thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN02136228.9 | 2002-07-26 | ||
| CN02136228 | 2002-07-26 | ||
| CNA021456038A CN1470682A (en) | 2002-07-26 | 2002-10-12 | Method for preparing fiber with negative ion far infrared antibacterial health-care function and product thereof |
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| CN1470682A true CN1470682A (en) | 2004-01-28 |
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| CNA021456038A Pending CN1470682A (en) | 2002-07-26 | 2002-10-12 | Method for preparing fiber with negative ion far infrared antibacterial health-care function and product thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101856726A (en) * | 2010-06-17 | 2010-10-13 | 哈尔滨得意药业有限责任公司 | Method for preparing multifunctional nano silver solution |
| CN101647608B (en) * | 2008-08-14 | 2012-05-30 | 通德兴业股份有限公司 | Nano far infrared belt |
| CN102517802A (en) * | 2011-12-09 | 2012-06-27 | 水经(上海)生物科技有限公司 | Filter nonwoven fabric capable of releasing negative ions |
| CN102828298A (en) * | 2012-08-20 | 2012-12-19 | 肖晖 | Hetian jade yarn and preparation method thereof |
| CN103122491A (en) * | 2013-02-04 | 2013-05-29 | 温州卓晟特鞋服有限公司 | Process for manufacturing tourmaline fibers |
| CN103122490A (en) * | 2011-11-19 | 2013-05-29 | 大连得达科技发展有限公司 | Far-infrared spontaneous heating and warmth-keeping fabric |
| CN104562263A (en) * | 2015-02-03 | 2015-04-29 | 湖州吉昌丝绸有限公司 | Novel negative ion regenerated silk fiber and preparation method thereof |
| CN107740201A (en) * | 2017-11-03 | 2018-02-27 | 中科纺织研究院（青岛）有限公司 | A kind of negative-oxygen ion health function polyester fiber and preparation method thereof |
| CN108797132A (en) * | 2018-05-23 | 2018-11-13 | 乔德（南通）纺织品有限公司 | A kind of manufacture craft of nano-silver anion functional home textile fabric |
| CN109009682A (en) * | 2018-07-17 | 2018-12-18 | 浙江优全护理用品科技有限公司 | A kind of core and preparation method thereof of uniform water conservancy diversion |
-
2002
- 2002-10-12 CN CNA021456038A patent/CN1470682A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101647608B (en) * | 2008-08-14 | 2012-05-30 | 通德兴业股份有限公司 | Nano far infrared belt |
| CN101856726B (en) * | 2010-06-17 | 2012-05-30 | 哈尔滨得意药业有限责任公司 | Method for preparing multifunctional nano silver solution |
| CN101856726A (en) * | 2010-06-17 | 2010-10-13 | 哈尔滨得意药业有限责任公司 | Method for preparing multifunctional nano silver solution |
| CN103122490A (en) * | 2011-11-19 | 2013-05-29 | 大连得达科技发展有限公司 | Far-infrared spontaneous heating and warmth-keeping fabric |
| CN102517802A (en) * | 2011-12-09 | 2012-06-27 | 水经(上海)生物科技有限公司 | Filter nonwoven fabric capable of releasing negative ions |
| CN102828298A (en) * | 2012-08-20 | 2012-12-19 | 肖晖 | Hetian jade yarn and preparation method thereof |
| CN103122491A (en) * | 2013-02-04 | 2013-05-29 | 温州卓晟特鞋服有限公司 | Process for manufacturing tourmaline fibers |
| CN104562263A (en) * | 2015-02-03 | 2015-04-29 | 湖州吉昌丝绸有限公司 | Novel negative ion regenerated silk fiber and preparation method thereof |
| CN104562263B (en) * | 2015-02-03 | 2017-04-12 | 广东绮瑞制衣实业有限公司 | Novel negative ion regenerated silk fiber and preparation method thereof |
| CN107740201A (en) * | 2017-11-03 | 2018-02-27 | 中科纺织研究院（青岛）有限公司 | A kind of negative-oxygen ion health function polyester fiber and preparation method thereof |
| CN107740201B (en) * | 2017-11-03 | 2019-12-24 | 中科纺织研究院（青岛）有限公司 | Negative oxygen ion polyester fiber with health care function and preparation method thereof |
| CN108797132A (en) * | 2018-05-23 | 2018-11-13 | 乔德（南通）纺织品有限公司 | A kind of manufacture craft of nano-silver anion functional home textile fabric |
| CN109009682A (en) * | 2018-07-17 | 2018-12-18 | 浙江优全护理用品科技有限公司 | A kind of core and preparation method thereof of uniform water conservancy diversion |
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