JP6967219B2 - Manufacturing method of far-infrared radiation fiber, non-woven fabric, filament, and far-infrared radiation fiber - Google Patents

Description

The present invention relates to a method for producing a far-infrared radiating fiber, a non-woven fabric, a filament, and a far-infrared radiating fiber in which particles made of a far-infrared radiating material are dispersed inside a polymer wire. The present invention relates to a method for producing an excellent far-infrared radiation fiber, a non-woven fabric, a filament, and a far-infrared radiation fiber.

In the natural world, when "mud" consisting of silt or clay is deposited and then dehydrated and consolidated, porous clay minerals are produced. Such porous clay minerals are called "mudstones", and although there are differences in the mineral components and the like contained depending on the type of mud deposited, most of them generally generate far infrared rays and negative ions.

Here, Non-Patent Document 1 shows data on far-infrared radiation characteristics of various natural minerals including mudstone obtained from red mud and the like. These are measured by applying a slurry containing crushed natural minerals to the surface of a steel sheet. It is said that the radioactive characteristics are almost determined by the constituent elements and the crystallinity does not have much influence, and the radiation intensity tends to increase from the same wavelength of about 3 to 20 μm.

By the way, heat-generating fibers in which such natural minerals that generate far infrared rays and negative ions are combined with fibers have been proposed, and woven fabrics processed from these have been used in many clothing, agricultural materials, heat insulating products, and the like. Can be used in applied products.

For example, Patent Document 1 discloses a far-infrared heating sheet for floor heating in which a far-infrared radiant substance is applied to both sides or one side of a non-woven fabric and dried. Here, as far-infrared radiation material, graphite silica stone powder (trade name "silica black") mainly composed of silicon oxide produced in the fault crushed part in the third black hard mudstone and mullite-based far-infrared radiation material are used. There is. It is said that these are kneaded with water and applied. It is said that far-infrared rays with a wavelength of 600 to 2000 μm can be efficiently emitted, and heat energy and active energy can be generated in the molecules constituting the human body or a substance to efficiently heat the molecules.

Further, Patent Document 2 discloses an artificial fiber in which clay radiating far infrared rays is dispersed in a chemical fiber, a woven fabric, a heat insulating article, and a material for a heat sheet. Here, fine particles of smectite-based clay such as montmorillonite and nontronite are dispersed in a chemical fiber carrier such as nylon and polyethylene terephthalate (PET) to be composited. Clay fine particles such as montmorillonite are mixed with a polymer raw material such as caprolactam, polymerized and dispersed in the polymer material.

Japanese Unexamined Patent Publication No. 2002-317949 Japanese Unexamined Patent Publication No. 2005-97506

Ken Otani, "Far Infrared Radiation Characteristics of Natural Products", Hokkaido Prefectural Industrial Research Institute Report No.293 (1994), pp. 115-121

Natural minerals that emit far-infrared rays activate the molecular activity of intracellular water when the emitted far-infrared rays are absorbed by the human body, for example, thereby causing heat to be generated. Therefore, the clay contained in the artificial fiber by directly wearing the artificial fiber in which the clay that radiates far infrared rays as disclosed in Patent Document 2 is dispersed in the chemical fiber or the clothes processed by the woven fabric, etc. It is said that the far-infrared rays emitted from the wearer's cells, which contain water, generate heat and feel warmth.

On the other hand, since the above-mentioned artificial fibers and the like do not generate heat by themselves, they do not generate heat unless a water-containing object such as a living cell is close to a distance affected by far infrared rays. Therefore, for example, in a dry state where the temperature is low, such as in winter, it takes time to generate heat even if the clothes made of these are worn.

The present invention has been made in view of the above circumstances, and an object thereof is a far-infrared radiation fiber in which particles made of a far-infrared radiation material having more heat generation are dispersed inside a polymer wire. The present invention is to provide a non-woven fabric and a filamentous body using such a far-infrared radiation fiber.

The far-infrared radiating fiber according to the present invention is a far-infrared radiating fiber in which particles of porous clay mineral are dispersed inside a polymer wire, and is a cellulose-derived polymer material in which the polymer wire has hygroscopicity. It is characterized by having a self-heating property.

According to such an invention, the far infrared rays emitted from the far infrared rays radiating particles easily react with the moisture captured by the hygroscopic material to generate heat of the fiber itself, and the heat generation is more excellent.

In the above invention, the porous clay mineral may be characterized by being mudstone. Further, the polymer material may be rayon and may be characterized by having a cross-sectional shape obtained by shrinking a part of a circular cross section. According to such an invention, although it is more excellent in heat generation, it is made of only a natural material and is also excellent in environmental compatibility.

The far-infrared radiation fiber according to the above invention can be applied to a non-woven fabric or a filamentous body. According to such an invention, when a garment manufactured by using far-infrared ray radiating fibers absorbs sweat emitted from a human body, the garment itself generates heat and the far-infrared rays radiated from the fiber are contained in the human body itself. Because it reacts with and generates heat, you can feel the warmth of clothes more strongly. In addition, when it is used as an agricultural material, it can react with water, which is indispensable for the growth of plants, and give a heat-generating effect efficiently and continuously.

Further, the production method according to the present invention is a method for producing a self-heating far-infrared radiation fiber in which particles of a porous clay mineral are dispersed inside a polymer wire, and the porous clay mineral is crushed. A crushing step of forming a pulverized body, a kneading step of dispersing the pulverized body in an alkaline aqueous solution, mixing with an alkaline viscous solution and stirring to generate a precursor, and a kneading step of injecting the precursor into an acidic solution from a nozzle to form a fiber. It is characterized by including a molding step of forming into a shape.

According to such an invention, far-infrared radiation particles made of porous clay minerals are efficiently dispersed inside a polymer wire, and the fibers themselves absorb water to generate heat by themselves, resulting in far-infrared radiation fibers having higher heat generation properties. Can be manufactured by a simple process.

In the above invention, the porous clay mineral may be mudstone. According to such an invention, it becomes possible to produce a far-infrared radiation fiber which is made of only a natural material and has excellent environmental compatibility by a simple process.

It is a partial perspective view which shows the far-infrared radiation fiber by this invention. It is a table which shows the content of the main component of the far-infrared radiation material applied to the far-infrared radiation fiber by this invention. It is a figure which shows the system for manufacturing the far-infrared radiation fiber by this invention. It is a chart figure of the FTIR analysis of the far-infrared radiation fiber by this invention. It is sectional drawing of the far-infrared radiation fiber by this invention. It is an electron micrograph of the side surface of the far-infrared radiation fiber by this invention. It is an electron micrograph which includes the cross section of the far-infrared radiation fiber by this invention.

Hereinafter, examples of the far-infrared radiation fiber according to the present invention and the method for producing the same will be specifically described.

FIG. 1 is a partial perspective view showing an outline of a far-infrared radiation fiber according to a typical example of the present invention. The far-infrared radiation fiber 10 is formed by dispersing far-infrared radiation particles 12 made of a far-infrared radiation material on a polymer wire 14 made of a base hygroscopic material.

The polymer wire 14 is made of a material having a property of adsorbing moisture contained in the surrounding atmosphere and retaining it inside. As these materials, for example, polymer materials such as cellulose-derived resins, acrylic resins, and polylactic acid-based resins are applied. Among these, examples of the cellulose-derived polymer material include rayon, cellophane, polynosic, and cupra. All of these are natural materials and provide fibers with excellent environmental compatibility, and are particularly suitable for agricultural material applications.

Examples of the far-infrared radiation material constituting the far-infrared radiation particles 12 include unfired clay minerals, for example, porous mudstone such as montmorillonite and vermiculite. _{The porous mudstone is mainly composed of SiO 2 of about 60% and Al 2} O _{3 of} about 10 to 18% in terms of the mass percentage of the oxide amount ratio, as shown in FIG. 2 described later, and is underground. Although the properties are slightly different depending on the pressurized state and the mineral contained in a small amount, the viscosity mineral here is preferably one having a slight water absorption. The far-infrared radiation particles 12 are formed as fine particles having a particle size of, for example, sub-μm order to several tens of μm by pulverizing such a far-infrared radiation material with a pulverizer.

FIG. 2 is a table showing an example of the main oxide amount ratio of the porous mudstone applied to the far-infrared radiation particles 12. It contains a large amount of _{SiO 2} and Al ₂ O ₃ , and also contains other oxides such as _{Na 2} O, MgO, SO ₃ , K ₂ O, CaO, TiO _{2, and FeO.} Mudstone is water-soluble because it is made by solidifying fine clay particles. Due to these characteristics, it can be easily dispersed in the above-mentioned polymer material having excellent water absorption and water affinity. Moreover, since it is a natural material together with the above-mentioned polymer material and both are water-soluble, it provides a fiber complex having excellent environmental compatibility.

FIG. 3 is a schematic view showing a manufacturing system for manufacturing the far-infrared radiation fiber 10. The manufacturing system 100 includes a mudstone crushing device 110, a kneading device 120 for kneading crushed mudstone particles into a raw material of a polymer wire, and a spinning device 130.

The crushing device 110 includes a mechanism (for example, a ball mill) for crushing the rock of the far-infrared radiation material which is the raw material of the far-infrared radiation particles 12 shown in FIG. 1, and the rock as the raw material is dried and crushed. The far-infrared radiation particles 12 have a particle size of about several μm to several tens of μm.

The far-infrared radiation particles 12 produced by the crusher 110 are dispersed in a sodium hydroxide aqueous solution having a predetermined concentration, mixed with an alkaline viscose solution which is a raw material of the polymer wire 14, and stirred (for example, a screw or the like). It is kneaded by the kneading device 120 provided with the above. As a result, the far-infrared radiation particles 12 are evenly dispersed in the raw material of the polymer wire 14. The kneading device 120 may include a heating mechanism (not shown).

The spinning device 130 is a device for extruding a mixture (precursor) produced by the kneading device 120 from a nozzle (base) having a plurality of minute through holes to form a fiber, and the extruded fiber is formed after the nozzle. It is wound by a winding mechanism located on the flow side to form a thread. Further, when the mixture is heated by the kneading device 120, the wake of the nozzle is additionally provided with a cooling mechanism for cooling the fibers extruded by gas or liquid.

Using the manufacturing system having such a configuration, the material of the far infrared radiation particles 12 is pulverized by the pulverizer 110 and then kneaded with the raw material of the polymer wire 14 made of the hygroscopic material by the kneader 120, and then kneaded. It is formed as a thread-like fiber by the spinning device 130.

FIG. 4 shows the results of infrared spectrophotometric measurement of aggregates of filamentous fibers by FTIR. As can be seen from this chart, the spectral emissivity is relatively flat at wavelengths of 7 μm or higher, but the spectral emissivity drops A1 and A2 at wavelengths of 10 to 12 μm in the far infrared region, and small peaks occur during this period. B1 is clearly observed.

The following shows a specific aspect of the far-infrared radiation fiber according to the present invention manufactured by using the manufacturing system shown in FIG.

First, the rock of the far-infrared radiation material containing the components of Examples 1 to 3 shown in FIG. 2 is crushed by the crushing device 110 shown in FIG. 3 to prepare a powder.

Subsequently, the powder and viscose, which is the raw material of the polymer wire 14, are put into the kneading device 120, and the mixture is stirred while being heated to perform kneading.

Then, the mixture (precursor) is taken out from the kneading device 120 and formed into filamentous fibers by the spinning device 130. Specifically, the mixture is extruded into an acidic solution tank from a base having a large number of through holes, and a chemical reaction is caused by cooling. Rayon fibers dispersed in the are formed.

The far-infrared ray radiating fiber according to a typical example of the present invention manufactured by such a manufacturing process disperses particles made of porous mud that emits far-infrared rays into a hygroscopic material made of a polymer material such as rayon. Has a structure. As a result, when the far-infrared radiating fiber absorbs moisture, the far-infrared ray emitted from the particles reacts with the moisture captured by the hygroscopic material, and the fiber itself generates heat, which is excellent in heat generation. In addition, it has a certain degree of water retention and the retained water is activated. Therefore, when manufacturing clothing that comes into contact with the skin with such fibers, for example, when making gloves, activated water will continue to be in contact with the skin.

Therefore, the agricultural material using the far-infrared radiant fiber described above can react with water, which is indispensable for the growth of plants, to efficiently and continuously give a heat-generating effect. Furthermore, the roots of the plant recognize the fibers containing the mudstone-like far-infrared radiation particles 12 as soil, and the roots are firmly formed toward the inside of the fibers, which can contribute to the growth of the plant.

Further, by manufacturing cloth products such as non-woven fabrics and clothes, it becomes possible to form cloth products and clothes containing fibers having a function of generating heat when absorbing moisture. In addition, by wearing such clothes, for example, when the fibers constituting the clothes absorb the sweat emitted from the human body, the clothes themselves generate heat and the far infrared rays emitted from the fibers are contained in the human body itself. Since it reacts with the moisture to generate heat, it has the effect of feeling the warmth of clothes more strongly.

5 to 7 are cross-sectional views and micrographs of rayon fibers (far-infrared radiation fibers) 20 in which muddy rocky far-infrared radiation particles 22 are dispersed in a polymer wire 24 made of rayon.

As shown in FIGS. 5 and 6, the rayon fiber 20 is formed by dispersing mudstone-like far-infrared radiation particles 22 in a polymer wire 24 made of rayon, which is a hygroscopic material. In the polymer wire 24, a plurality of side surfaces 24a corresponding to the outer periphery of a substantially circular cross section (dashed-dotted line in FIG. 5) and a plurality of concave surfaces 24b located between the plurality of side surfaces 24a are alternately arranged. , Has a cross-sectional shape with a part of the circular cross section contracted.

Such a cross-sectional shape of the rayon fiber 20 is formed by shrinking the polymer material by being rapidly cooled by the acidic solution when the heated viscose material is extruded from the mouthpiece into the acidic solution tank. Can be done.

By having such a cross-sectional shape, the rayon fiber 20 increases the surface area of the side surface of the fiber that absorbs moisture, so that the heat generation function of the fiber itself by absorbing moisture can be enhanced. Further, since the area of the far-infrared radiation surface of the rayon fiber 20 is also increased, the heat generating action of agricultural materials and clothes using this fiber can be improved. In particular, since the roots of the plant recognize the rayon fiber 20 containing the muddy rocky far-infrared radiation particles 22 like soil, the roots are firmly formed toward the inside of the rayon fiber 20 and can contribute to the growth of the plant. be.

In the example shown in FIG. 5, a far-infrared radiation fiber 20 having a cross-sectional shape including three side surfaces 24a and three concave surfaces 24b is illustrated, but as shown in FIG. 7, the number of the plurality of side surfaces and concave surfaces is three. It is not limited to one and can be formed in any number. In addition, the shape of the through hole formed in the mouthpiece is polygonal or star-shaped in addition to circular, and the cross-sectional shape is a desired cross-sectional shape other than circular, such as polygonal cross-section or star-shaped cross-section. obtain.

Further, it may be a bead-shaped dispersed grain instead of a fiber-shaped one. It is preferable to use such dispersed grains as a soil substitute for agricultural materials.

Although the examples according to the present invention and the modifications based on the same have been described above, the present invention is not necessarily limited to these examples. Also, one of ordinary skill in the art will be able to find various alternative and modified examples without departing from the gist of the present invention or the appended claims.

10, 20 Far-infrared radiation fiber 12, 22 Particle 14, 24 Polymer wire 24a Side surface 24b Concave surface 100 Manufacturing system 110 Grinding device 120 Kneading device 130 Spinning device

Claims (7)

It is a far-infrared radiating fiber in which particles of porous clay mineral are dispersed inside a polymer wire, and the polymer wire is made of a cellulose-derived polymer material having hygroscopicity, and the particles are the porous. a clay particles obtained by pulverizing mudstone containing clay minerals, far infrared rays far infrared rays radiated from the clay particles, wherein Rukoto give self exothermic via the trapped water to the polymer containing lines Radiant fiber. The far-infrared radiation fiber according to claim 1, wherein the mudstone contains at least montmorillonite and vermiculite. The far-infrared radiation fiber according to claim 2, wherein the polymer material is rayon and has a cross-sectional shape obtained by shrinking a part of a circular cross section. A nonwoven fabric comprising the far-infrared radiating fiber according to any one of claims 1 to 3. A filamentous body comprising the far-infrared radiating fiber according to any one of claims 1 to 3. A method for producing self-heating far-infrared radiant fibers in which particles of porous clay minerals are dispersed inside a polymer wire.
A crushing step of obtaining clay particles obtained by crushing mudstone containing the porous clay mineral, and
A kneading step in which the clay particles are dispersed in an alkaline aqueous solution, mixed with an alkaline viscose solution, and stirred to form a precursor.
A method for producing a far-infrared radiated fiber, which comprises a molding step of injecting the precursor into an acidic bath from a nozzle to form a fiber. The method for producing a far-infrared radiation fiber according to claim 6, wherein the mudstone contains at least montmorillonite and vermiculite.

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