CN1456610A - Environmental protective latex paint - Google Patents
Environmental protective latex paint Download PDFInfo
- Publication number
- CN1456610A CN1456610A CN 03104618 CN03104618A CN1456610A CN 1456610 A CN1456610 A CN 1456610A CN 03104618 CN03104618 CN 03104618 CN 03104618 A CN03104618 A CN 03104618A CN 1456610 A CN1456610 A CN 1456610A
- Authority
- CN
- China
- Prior art keywords
- polyvinyl alcohol
- proportioning
- emulsion paint
- borax
- alum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 20
- 230000007613 environmental effect Effects 0.000 title 1
- 239000004816 latex Substances 0.000 title 1
- 229920000126 latex Polymers 0.000 title 1
- 230000001681 protective effect Effects 0.000 title 1
- 239000000839 emulsion Substances 0.000 claims abstract description 27
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 229910021538 borax Inorganic materials 0.000 claims abstract description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 9
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 9
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 9
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 9
- 239000010456 wollastonite Substances 0.000 claims abstract description 9
- ZEMWIYASLJTEHQ-UHFFFAOYSA-J aluminum;sodium;disulfate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZEMWIYASLJTEHQ-UHFFFAOYSA-J 0.000 claims abstract description 3
- 239000005083 Zinc sulfide Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 8
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 229940037003 alum Drugs 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- 238000009877 rendering Methods 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- FGVFLAKGWUZGGE-UHFFFAOYSA-N benzene;propane Chemical compound CCC.C1=CC=CC=C1 FGVFLAKGWUZGGE-UHFFFAOYSA-N 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 238000004880 explosion Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
An environment protection type emulsion paint is prepared from polyvinyl alcohol, light calcium carbonate, wollastonite powder, lithopone, titanium white, borax, alum, sodium hexametaphosphate, benzen-propane emulsion and water. Its advantages are high strength, toughness and adhesion, no poison and pollution and low cost.
Description
Technical field
The present invention relates to a kind of chemistry painting industry, particularly relate to a kind of environment-friendly type emulsion paint and preparation technology thereof.
Background technology
Water-borne coatings since with water as solvent, nontoxic pollution-free, no fire hazard, applied range is so be one of extremely rising coating variety.The high and low shelves emulsion paint that appears on the market in the market is of a great variety, and effect is different.Though have suitable intensity as high-grade emulsion paint, cost an arm and a leg, be difficult for promoting the use of; The most of poor quality of low-grade emulsion paint, easily explosion, opacifying power and scrub performance are difficult to be up to state standards.Intensity and the scrub resistance of people in the industry in order to improve emulsion paint all uses class organic compound such as formaldehyde, Pentachlorophenol as binding agent in auxiliary agent, volatilizes harmful material, contaminate environment when causing emulsion paint to use.Therefore,, reduce cost, extend shelf life, improve paint film intensity and technical requirementss such as coating scrub resistance, not explosion and become problem demanding prompt solution in the industry for improving emulsion paint quality and over-all properties.
Summary of the invention
Purpose of the present invention is intended to overcome the deficiencies in the prior art, and provides a kind of have intensity height, flexible, strong adhesion, free of contamination environment-friendly type emulsion paint.
For realizing that the technical scheme that the object of the invention adopted is: a kind of environment-friendly type emulsion paint, it is made up of polyvinyl alcohol, light calcium carbonate, wollastonite powder, zinc sulfide white, titanium dioxide, borax, alum, Sodium hexametaphosphate 99, benzene-acrylic emulsion and water, its moiety and part by weight following (weight percent):
Polyvinyl alcohol 1-2
Light calcium carbonate 13-15
Wollastonite powder 8-11
Zinc sulfide white 8-10
Titanium dioxide 3-5
Borax 0.02-0.1
Alum 0.05-0.5
Sodium hexametaphosphate 99 0.1-0.4
Benzene-acrylic emulsion 22-26
Water 44-33
The present invention has following remarkable advantage than prior art: intensity height, flexible, use sand papering to be difficult for shedding, scrubbing resistance, adsorptive power is strong, be difficult for explosion, pollution resistance is good, and is pollution-free, nontoxic, no fire hazard, low cost of manufacture, production technique is simple, be rated as a kind of good technology, help promoting the use of with novelty, creativeness and practicality.
Embodiment
Below in conjunction with preferred embodiment the present invention is further described:
Weighing polyvinyl alcohol 1.9%, light calcium carbonate 14.77%, wollastonite powder 10.7%, zinc sulfide white 9%, titanium dioxide 5%, borax 0.04%, alum 0.09%, Sodium hexametaphosphate 99 0.1%, benzene-acrylic emulsion 25.8% and water 32.6%, after above-mentioned each component dosage, through making the following technology of emulsion paint:
One, base-material is made: drop into polyvinyl alcohol 1.9% in reactor, add entry 32.6 then, rise
Temperature is to 85 °-90 °, till the polyvinyl alcohol off-bottom, in the rising temperature for dissolving process
The stirring of should often starting shooting, make it thoroughly dissolving after, be cooled to 60 °, add additive again---
The aqueous solution of alum 0.09% and 0.04% borax stirred 10 minutes, continued to stir 20 fens
Base-material is made behind the clock.
Two, coating is made: base-material is rendered in the agitator, dropped into Sodium hexametaphosphate 99 0.1%, start shooting and stir
Mixed 5 minutes, add again light calcium carbonate 14.77%, wollastonite powder 10.7%, zinc sulfide white 9%,
Titanium dioxide 5%, high-speed stirring 30 minutes is taken out 15 microns fineness of sand milling in sand mill,
Taking-up is rendered to and is packed after agitator adding benzene-acrylic emulsion 25.8% stirs.Promptly make
Environment-friendly type emulsion paint.
Claims (3)
1, a kind of environment-friendly type emulsion paint, it is characterized in that: it is made up of polyvinyl alcohol, light calcium carbonate, wollastonite powder, zinc sulfide white, titanium dioxide, borax, alum, Sodium hexametaphosphate 99, benzene-acrylic emulsion and water, its moiety and part by weight following (weight percent):
Polyvinyl alcohol 1-2
Light calcium carbonate 13-15
Wollastonite powder 8-11
Zinc sulfide white 8-10
Titanium dioxide 3-5
Borax 0.02-0.1
Alum 0.05-0.5
Sodium hexametaphosphate 99 0.1-0.4
Benzene emulsion 22-26
Water 44-33
2, environment-friendly type emulsion paint according to claim 1 is characterized in that: above-mentioned moiety and weight preferred proportion are: polyvinyl alcohol 1.9%, light calcium carbonate 14.77%, wollastonite powder 10.7%, zinc sulfide white 9%, titanium dioxide 5%, borax 0.04%, alum 0.09%, Sodium hexametaphosphate 99 0.1%, benzene-acrylic emulsion 25.8% and water 32.6%.
3, the preparation technology of environment-friendly type emulsion paint according to claim 1 is characterized in that: after above-mentioned each component dosage, finish through the following technology of making emulsion paint:
(1) base-material is made: drop into the polyvinyl alcohol of proportioning in reactor, add the water of proportioning then, be warming up to till the polyvinyl alcohol off-bottom, start is cooled to below 60 ° after stirring, and adds the additive of proportioning again---the aqueous solution of alum and borax, stir, base-material is made;
(2) coating is made: base-material is rendered in the agitator, dropped into the Sodium hexametaphosphate 99 of proportioning, start stirs, and adds light calcium carbonate, wollastonite powder, zinc sulfide white, the titanium dioxide of proportioning again, and high-speed stirring is even again; Taking-up is sand milling to 15 micron following fineness in sand mill, takes out and packs after benzene-acrylic emulsion of rendering to agitator adding proportioning stirs, and promptly makes environment-friendly type emulsion paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03104618 CN1252198C (en) | 2003-02-18 | 2003-02-18 | Environmental protective latex paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03104618 CN1252198C (en) | 2003-02-18 | 2003-02-18 | Environmental protective latex paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1456610A true CN1456610A (en) | 2003-11-19 |
| CN1252198C CN1252198C (en) | 2006-04-19 |
Family
ID=29411215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03104618 Expired - Fee Related CN1252198C (en) | 2003-02-18 | 2003-02-18 | Environmental protective latex paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1252198C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331966C (en) * | 2004-04-23 | 2007-08-15 | 谢健文 | Water shedding facade wall paint and its preparing process |
| CN102604499A (en) * | 2012-03-13 | 2012-07-25 | 三棵树涂料股份有限公司 | Crystallized hydrate heat-insulation fireproof coating and preparation method |
| CN107227076A (en) * | 2017-07-25 | 2017-10-03 | 合肥欧仕嘉机电设备有限公司 | A kind of decoration emulsion paint and preparation method |
-
2003
- 2003-02-18 CN CN 03104618 patent/CN1252198C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331966C (en) * | 2004-04-23 | 2007-08-15 | 谢健文 | Water shedding facade wall paint and its preparing process |
| CN102604499A (en) * | 2012-03-13 | 2012-07-25 | 三棵树涂料股份有限公司 | Crystallized hydrate heat-insulation fireproof coating and preparation method |
| CN107227076A (en) * | 2017-07-25 | 2017-10-03 | 合肥欧仕嘉机电设备有限公司 | A kind of decoration emulsion paint and preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1252198C (en) | 2006-04-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: TIANJIN BINXIN COATING CO., LTD. Free format text: FORMER OWNER: YANG GUANGZHONG Effective date: 20090508 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20090508 Address after: No. fifth, seventeen Avenue, Tianjin economic and Technological Development Zone Patentee after: Tianjin Binsense Coating Co., Ltd. Address before: No. 91, No. 501, oil village, Tanggu District, Tianjin Patentee before: Yang Guangzhong |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060419 Termination date: 20130218 |