CN1441116A - Jean whitening slurry and its application in producing printed jean - Google Patents

Jean whitening slurry and its application in producing printed jean Download PDF

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Publication number
CN1441116A
CN1441116A CN 03111802 CN03111802A CN1441116A CN 1441116 A CN1441116 A CN 1441116A CN 03111802 CN03111802 CN 03111802 CN 03111802 A CN03111802 A CN 03111802A CN 1441116 A CN1441116 A CN 1441116A
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China
Prior art keywords
slurry
denim
dawn
grey cloth
cowboy
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CN 03111802
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CN1209523C (en
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曲忠坡
曲广义
曲光耀
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Abstract

The present invention belongs to the field of textile dyeing technology. The stable suspension whitening slurry consists of whitening agent, densifier and water. The slurry is printed on indigo blue jean to form pattern and through further stoving, water washing and re-stoving, printed jean is produced. After water washing, the steps of treatment with water solution of dye fixing agent and subsequent water washing ands toving may be added. In the process, inert densifier is used, and this makes it possible to adopt conventional screen printing or machine printing for the whitening dyeing step.

Description

Denim dawn slurry and the application in the stamp denim is produced thereof
Technical field
The invention belongs to the dyeing category of textiles, be specifically related to a kind of denim dawn slurry and the application in the stamp denim is produced thereof.
Background technology
The denim quality is thick, is not suitable for can not in time penetrating into the fabric deep with traditional mill base printing and dyeing because of mill base floats on the surface, and it is insecure easily to come off; Someone produces " snowflake " denim, is to spray potassium permanganate solution on denim, with the oxalic acid aqueous solution reduction, produces " dawn " effect again; Its shortcoming is that white discharging agent is the aqueous solution, can only show uneven white " point " shape decorative pattern on the indigo background color; Because potassium permanganate is strong oxidizer, with conventional slurry, adhesive mixing chemically reactive, can not prepare slurry routinely for wire mark or machine seal, thereby, can't be imprinted on cowboy's grey cloth of indigo with conventional wire mark or machine and implement printing and dyeing.
Summary of the invention
Purpose of the present invention provides a kind of denim stamp dawn slurry, and develops its application in the stamp denim is produced.
Technical scheme of the present invention is: develop a kind of denim dawn slurry, it is characterized in that adopting the material of weight components proportioning: white discharging agent: thickener: water=1~10: 20~60: 20~75; White discharging agent, thickener and water stir to make stablizes the hybrid state slurry.
Its described white discharging agent can be selected from bleaching powder, clorox, sodium chlorite, bichromate (sodium, potassium or ammonium), permanganate (potassium or sodium) or hydrogen peroxide; Its described thickener can be selected from clay, diatomite, talcum powder or kaolin; Can also add the inorganic adhesive that slurry is stablize the hybrid state aequum in its described slurry.
The application of a kind of denim dawn slurry in the stamp denim is produced, it is characterized in that to stablize the slurry of hybrid state, the discharge of conventional wire mark or machine seal goes out decorative pattern, pattern on indigo cowboy grey cloth, and drying, washing, oven dry make the stamp denim that blue tail band is spent.
Or behind washing step, handle through the color-fixing agent aqueous solution again, be washed to neutrality, oven dry again, make the stamp denim of spending in vain at the blue end.
Its described slurry discharge time on indigo cowboy grey cloth dawn is 0.5~10min;
Its described color-fixing agent aqueous solution is handled, and is meant that the holdup time of cowboy's grey cloth in the color-fixing agent aqueous solution through discharge is 0.5~10min; Its described color-fixing agent aqueous solution is meant 0.1~5% acetic acid, citric acid, oxalic acid or aqueous tartaric acid solution.
Advantage of the present invention is:
1. adopt the inertia thickener, they not with used white discharging agent chemically reactive, can prepare the slurry of the required denseness of discharge smoothly, thereby solve in the discharge operation, can't adopt the difficult problem of conventional wire mark or machine seal.
With this method on cowboy's grey cloth of indigo dawn, make the stamp denim, decorative pattern, pattern are more clear, fair and clear, and fabrics cloth cover is not damaged and even, fabrics feel soft is comfortable, decorative pattern, pattern place do not have stiff sense, are suitable for suitability for industrialized production.
The specific embodiment
The present invention is further elaborated below in conjunction with embodiment.
Embodiment 1 makes the stamp denim of spending in vain at the blue end
The material of dawn slurry employing weight components proportioning: white discharging agent: thickener: water=1: 20: 60 (unit of weight: kilogram); White discharging agent, thickener and water stirred to make stablize the hybrid state slurry.White discharging agent can be selected a kind of from bleaching powder, clorox or sodium chlorite; Thickener can be selected a kind of from clay or diatomite.
To stablize the slurry of hybrid state, the discharge of conventional wire mark or machine seal goes out decorative pattern, pattern on indigo cowboy grey cloth, and the discharge time of slurry on indigo cowboy grey cloth dawn is 0.5~1min; Drying, be washed to neutrality, the aqueous acetic acid with 0.1~0.5% is handled, and the holdup time in the aqueous acetic acid of cowboy's grey cloth 0.1~0.5% of discharge is 9~10min; After routine brightens processing, be washed to neutrality, oven dry again, make the stamp denim of spending in vain at the blue end.
Embodiment 2 makes the stamp denim of blue tail band flower
The material of dawn slurry employing weight components proportioning: white discharging agent: thickener: water=10: 60: 75; White discharging agent, thickener and water stirred to make stablize the hybrid state slurry.White discharging agent can be selected a kind of from bichromate (sodium, potassium or ammonium), permanganate (potassium or sodium); Thickener can be selected a kind of from talcum powder or kaolin; Add the inorganic adhesive (for example, sodium metasilicate) slurry is stablize the hybrid state aequum.To stablize the slurry of hybrid state, the discharge of conventional wire mark or machine seal goes out decorative pattern, pattern on indigo cowboy grey cloth, and the discharge time of slurry on indigo cowboy grey cloth dawn is 8~10min; Drying, be washed to neutrality, oven dry again makes the stamp denim of blue tail band flower; All the other are with example 1.
Embodiment 3 makes the stamp denim of spending in vain at the blue end
Dawn wet end furnish: commercial size hydrogen peroxide 10kg, thickener diatomite 30kg, water 50kg; Make under three's stirring at normal temperature and stablize the hybrid state slurry.The discharge time of slurry on indigo cowboy grey cloth dawn is 2~4min; Holdup time in the aqueous tartaric acid solution of cowboy's grey cloth 5% of discharge is 0.5~1min; All the other are with example 1.
Embodiment 4 makes the stamp denim of blue tail band flower
Dawn wet end furnish: commercial size potassium permanganate 1kg, thickener diatomite 40kg, water 60kg; Three's stirring at normal temperature is made and is stablized the hybrid state slurry.The discharge time of slurry on indigo cowboy grey cloth dawn is 3~5min; All the other are with example 2.
Embodiment 5 makes the stamp denim of spending in vain at the blue end
Dawn wet end furnish: commercial size sodium dichromate 1kg, thickener talcum powder 50kg, water 75kg; Add inorganic adhesive slurry is stablize the hybrid state aequum, make under the stirring at normal temperature and stablize the hybrid state slurry.The discharge time of slurry on indigo cowboy grey cloth dawn is 6~7min; Is 8~9min through cowboy's grey cloth of discharge in 1% oxalic acid or the holdup time in the aqueous tartaric acid solution; All the other are with example 1.
Embodiment 6 makes the stamp denim of spending in vain at the blue end
Dawn wet end furnish: commercial size ammonium dichromate 1kg, thickener talcum powder 40kg, water 55kg; Make under the stirring at normal temperature and stablize the hybrid state slurry.The discharge time of slurry on indigo cowboy grey cloth dawn is 8~9min; Holdup time in the aqueous citric acid solution of cowboy's grey cloth 5% of discharge is 1~2min; All the other are with example 1.
Embodiment 7
Dawn wet end furnish: commercial size bleaching powder 5kg, thickener kaolin 40kg, water 65kg adds inorganic adhesive slurry is stablize the hybrid state aequum; Make under the stirring at normal temperature and stablize the hybrid state slurry.The discharge time of slurry on indigo cowboy grey cloth dawn is 1~3min; Is 6~7min through cowboy's grey cloth of discharge in 2% oxalic acid or the holdup time in the aqueous tartaric acid solution; All the other are with example 1.
Embodiment 8
Dawn wet end furnish: commercial size clorox or sodium chlorite 5kg, thickener talcum powder 30kg, water 75kg adds inorganic adhesive slurry is stablize the hybrid state aequum; Make under the stirring at normal temperature and stablize the hybrid state slurry.The discharge time of slurry on indigo cowboy grey cloth dawn is 4~6min; Holdup time in the aqueous acetic acid of cowboy's grey cloth 2% of discharge is 5~6min; All the other are with example 1.
Embodiment 9
Dawn wet end furnish: commercial size sodium permanganate 10kg, thickener talcum powder 40kg, water 75kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 0.5~2min; Holdup time in the aqueous citric acid solution of cowboy's grey cloth 2% of discharge is 5~6min; All the other are with example 1.
Embodiment 10
Dawn wet end furnish: commercial size hydrogen peroxide 10kg, thickener clay 40kg, water 20kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 1~2min; Holdup time in the aqueous citric acid solution of cowboy's grey cloth 0.1% of discharge is 9~10min; All the other are with example 1.
Embodiment 11
Dawn wet end furnish: industrial clorox 10kg, thickener clay 40kg, water 40kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 8~10min; Is 7~8min through cowboy's grey cloth of discharge in 2% oxalic acid or the holdup time in the aqueous tartaric acid solution; All the other are with example 1.
Embodiment 12
Dawn wet end furnish: industrial sodium dichromate 1kg, thickener diatomite 20kg, water 50kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 0.5~2min; Holdup time in the oxalic acid aqueous solution of cowboy's grey cloth 0.1% of discharge is 9~10min; All the other are with example 1.
Embodiment 13
Dawn wet end furnish: industrial bleaching powder 10kg, thickener talcum powder 60kg, water 75kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 3~4min; Holdup time in the oxalic acid aqueous solution of cowboy's grey cloth 5% of discharge is 0.5~1min; All the other are with example 1.
Embodiment 14
Dawn wet end furnish: industrial potassium permanganate 2kg, thickener clay 40kg, water 75kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 1~3min; Holdup time in the aqueous acetic acid of cowboy's grey cloth 3% of discharge is 2~3min; All the other are with example 1.
Embodiment 15
Dawn wet end furnish: industrial hydrogen peroxide 10kg, thickener kaolin 50kg, water 35kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 5~6min; Holdup time in the oxalic acid aqueous solution of cowboy's grey cloth 3% of discharge is 3~4min; All the other are with example 1.
Embodiment 16
Dawn wet end furnish: industrial sodium chlorite 3kg, thickener diatomite 30kg, water 65kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 6~8min; Holdup time in the aqueous tartaric acid solution of cowboy's grey cloth 2% of discharge is 4~5min; All the other are with example 1.
Embodiment 17
Dawn wet end furnish: industrial sodium permanganate 5kg, thickener talcum powder 40kg, water 75kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 4~6min; Holdup time in the aqueous acetic acid of cowboy's grey cloth 5% of discharge is 0.5~1min; All the other are with example 1.
Embodiment 18
Dawn wet end furnish: industrial potassium permanganate 2kg, thickener diatomite 40kg, water 50kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 2~4min; Holdup time in the oxalic acid aqueous solution of cowboy's grey cloth 1% of discharge is 6~7min; All the other are with example 1.
Embodiment 19
Dawn wet end furnish: industrial hydrogen peroxide 10kg, thickener talcum powder 40kg, water 55kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 8~10min; Holdup time in the aqueous acetic acid of cowboy's grey cloth 3% of discharge is 1~2min; All the other are with example 1.
Embodiment 20
Dawn wet end furnish: industrial sodium dichromate 5kg, thickener clay 40kg, water 75kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 5~7min; Holdup time in the oxalic acid aqueous solution of cowboy's grey cloth 3% of discharge is 3~4min; All the other are with example 1.
Embodiment 21
Dawn wet end furnish: industrial bleaching powder 10kg, thickener clay 40kg, water 75kg.The discharge time of slurry on indigo cowboy grey cloth dawn is 4~6min; Holdup time in the aqueous tartaric acid solution of cowboy's grey cloth 5% of discharge is 0.5~1min; All the other are with example 1.

Claims (9)

1. denim dawn slurry is characterized in that adopting the material of weight components proportioning: white discharging agent: thickener: water=1~10: 20~60: 20~75; White discharging agent, thickener and water stir to make stablizes the hybrid state slurry.
2. according to the described denim of claim 1 dawn slurry, it is characterized in that described white discharging agent can select from bleaching powder, clorox, sodium chlorite, bichromate (sodium, potassium or ammonium), permanganate (potassium or sodium) or hydrogen peroxide.
3. according to the described denim of claim 1 dawn slurry, it is characterized in that described thickener can select from clay, diatomite, talcum powder or kaolin.
4. according to the described denim of claim 1 dawn slurry, it is characterized in that to add in the described slurry inorganic adhesive that slurry is stablize the hybrid state aequum.
5. according to the application of the described denim of claim 1 dawn slurry in the stamp denim is produced, it is characterized in that to stablize the slurry of hybrid state, the discharge of conventional wire mark or machine seal goes out decorative pattern, pattern on indigo cowboy grey cloth, drying, washing, baking operation make the stamp denim that blue tail band is spent.
6. according to the application of the described denim of claim 5 dawn slurry in the stamp denim is produced, it is characterized in that behind washing step, handling through the color-fixing agent aqueous solution again, be washed to neutrality, oven dry again, make the stamp denim of spending in vain at the blue end.
7. the application in the stamp denim is produced according to claim 5 or 6 described denim dawn slurries is characterized in that the described discharge time of slurry on indigo cowboy grey cloth dawn is 0.5~10min.
8. according to the application of the described denim of claim 6 dawn slurry in the stamp denim is produced, it is characterized in that described color-fixing agent aqueous solution processing, be meant that the holdup time of cowboy's grey cloth in the color-fixing agent aqueous solution through discharge is 0.5~10min.
9. the application in producing according to the described denim of claim 6 dawn slurry stamp denim is characterized in that the described color-fixing agent aqueous solution is meant 0.1~5% acetic acid, citric acid, oxalic acid or aqueous tartaric acid solution.
CN 03111802 2003-01-03 2003-01-03 Jean whitening slurry and its application in producing printed jean Expired - Fee Related CN1209523C (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN 03111802 CN1209523C (en) 2003-01-03 2003-01-03 Jean whitening slurry and its application in producing printed jean

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CN1209523C CN1209523C (en) 2005-07-06

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1298920C (en) * 2004-03-24 2007-02-07 王喜武 Long effective single component whitening pulp applied under normal temperature
CN101275366B (en) * 2007-03-28 2010-05-26 浙江丝绸科技有限公司 Pulpy discharging agent for textile printing and preparation thereof
CN101845759A (en) * 2009-03-26 2010-09-29 许阳涛 Discharge printing process of national cloth product
CN102409539A (en) * 2011-09-26 2012-04-11 张志军 Special denim size and preparation method and application thereof
CN102433776A (en) * 2011-09-09 2012-05-02 浙江理工大学 Method for preparing environment-friendly natural fiber printing paste
CN103046405A (en) * 2013-01-08 2013-04-17 华韩(泉州)新型面料开发有限公司 Wash fade slurry and method for fabricating imitated yarn-dyed wash fade fabric
CN103046406A (en) * 2012-12-14 2013-04-17 常熟市张桥雪松印花厂 Cloth discharge printing process
CN106968116A (en) * 2017-04-21 2017-07-21 昆明市宜良阳昇工艺品厂 A kind of method of discharge printing
CN109518483A (en) * 2018-11-08 2019-03-26 辽东学院 A kind of resistance to potassium permanganate thickener and its preparation, application method
CN110923900A (en) * 2019-12-05 2020-03-27 蒋暾 Production method of denim
CN113026398A (en) * 2021-02-04 2021-06-25 广州美术学院 Discharging agent, preparation method thereof and application thereof in sequin discharge printing process

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1298920C (en) * 2004-03-24 2007-02-07 王喜武 Long effective single component whitening pulp applied under normal temperature
CN101275366B (en) * 2007-03-28 2010-05-26 浙江丝绸科技有限公司 Pulpy discharging agent for textile printing and preparation thereof
CN101845759A (en) * 2009-03-26 2010-09-29 许阳涛 Discharge printing process of national cloth product
CN102433776A (en) * 2011-09-09 2012-05-02 浙江理工大学 Method for preparing environment-friendly natural fiber printing paste
CN102409539A (en) * 2011-09-26 2012-04-11 张志军 Special denim size and preparation method and application thereof
CN103046406A (en) * 2012-12-14 2013-04-17 常熟市张桥雪松印花厂 Cloth discharge printing process
CN103046405A (en) * 2013-01-08 2013-04-17 华韩(泉州)新型面料开发有限公司 Wash fade slurry and method for fabricating imitated yarn-dyed wash fade fabric
CN106968116A (en) * 2017-04-21 2017-07-21 昆明市宜良阳昇工艺品厂 A kind of method of discharge printing
CN109518483A (en) * 2018-11-08 2019-03-26 辽东学院 A kind of resistance to potassium permanganate thickener and its preparation, application method
CN110923900A (en) * 2019-12-05 2020-03-27 蒋暾 Production method of denim
CN113026398A (en) * 2021-02-04 2021-06-25 广州美术学院 Discharging agent, preparation method thereof and application thereof in sequin discharge printing process

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