CN1439671A - Smokeless flame resistant conveying belt without halide - Google Patents

Smokeless flame resistant conveying belt without halide Download PDF

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Publication number
CN1439671A
CN1439671A CN 02132725 CN02132725A CN1439671A CN 1439671 A CN1439671 A CN 1439671A CN 02132725 CN02132725 CN 02132725 CN 02132725 A CN02132725 A CN 02132725A CN 1439671 A CN1439671 A CN 1439671A
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China
Prior art keywords
conveyor belt
flame retardant
low cigarette
halide
parts
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CN 02132725
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Chinese (zh)
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CN1260280C (en
Inventor
王奇
曲成东
唐大志
孟凡有
李平
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FUXIN HUANYU RUBBER (GROUP) CO LTD
FUXIN RUBBER (Group) Co.,Ltd.
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FUXIN RUBBER Co Ltd
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Publication of CN1260280C publication Critical patent/CN1260280C/en
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Expired - Fee Related legal-status Critical Current

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Abstract

A low-smoke non-halogen conveying belt difficult to burn features that its covering and transition rubber materials are prepared from natural rubber (10-30 wt portions), synthetic rubber (70-90), promoter (0.5-2.5), zinc oxide (4-7), stearic acid (1-3), carbon black (5-25), anti-ageing agent (0.5-6.0), sulfur (1.0-3.0), non-halogen fire-retarding agent (70-150) and smoke inhibitor (2-25). Its advantages are better fire-retarding performance, less generation of smoke and not containing toxic hydrogen halides.

Description

Low cigarette, without halide flame retardant conveyor belt
Technical field the present invention relates to a kind of transfer roller adhesive tape, particularly a kind of low cigarette, without halide flame retardant conveyor belt.
Background technology is present, in order to satisfy the difficulty combustion requirement that the coal industry standard proposes with conveying belt the colliery, the fire retardant that homemade flame retardant conveyor belt uses contains haloid element mostly, (production technology of conveying belt and development trend, " adhesive tape industry " the 4th phase in 1998) yet, all macromolecular materials all are combustible under the direct effect of fire, in case presence of fire generates a large amount of smog and hydrogen halide toxic gas after the decomposes.Smog hinders fire fighting personnel's sight line, influence is in time rescued and hedging, the more direct life security that is threatening personnel of hydrogen halide that generates, from combustion products toxicity test research (" ISO/TC " 92.654) and fire statistics numeral being found that the number that poisoning is choked to death in the coal-mine fire accident is far more than directly being burnt dead number abroad.
Summary of the invention the present invention has overcome deficiency of the prior art, and a kind of good flame retardant property that not only has is provided, and the exhaust gas volumn that generates of burning back is few and flue gas in do not contain low cigarette, the without halide flame retardant conveyor belt of toxicity gas hydrogen halide.
For solving the problems of the technologies described above, the present invention adopts following technical proposals, and low cigarette, the used rubber cover of without halide flame retardant conveyor belt and transition glue sizing material are made up of following each components in part by weight: natural rubber 10-30 part, synthetic rubber 70-90 part, promotor 0.5-2.5 part, zinc oxide 4-7 part, stearic acid 1.0-3.0 part, carbon black 5-25 part, anti-aging agent 0.5-6.0 part, sulphur 1.0-3.0 part, halogen-free flame retardants 70-150 part is pressed down fumicants 2-25 part.
Halogen-free flame retardants of the present invention is active aluminium hydroxide, magnesium hydroxide, zinc borate, flame-resistant lubricant MB-202, halogen-free flame retardants MRP, ammonium octamolybdate, polyphosphoric acid amine, fire retardant SP-1, FR-S101, TBC.This based flame retardant belongs to inorganic combustion inhibitor, does not contain the halogen family element, and the amount of being fuming is low when fire-retardant, does not produce the toxic gas hydrogen halide.Pressing down fumicants is to press down fumicants XY-1, XY-2, FZY-14, FZY-21, molybdenum sesquioxide.The fire retardant that adds and press down fumicants makes the present invention and general flame retardant conveyor belt compare, and has significant difficult characteristic and low cigarette, the Halogen characteristic of firing.Fire-retardant oxygen index (ASTM-2863) produces smoke density value (SDR value)≤75 between 34%-42%, reach the difficulty combustion level in " GB/T 8624-1997 " standard; The corrosive gases hydrogen halide content is 0mg/g, meets European cable, the non-halogen standard of electric wire " IEC 754-1 " to (requirement of hydrogen halide content≤0.5mg/g) of hydrogen halide content.Described synthetic rubber is isoprene-isobutylene rubber, polyisoprene rubber.Promotor is thiuram type accelerator, comprises promotor PTD, TBTS, TBTD, TMTM and TMTT; Dithiocarbamatetype accelerator comprises accelerant B Z, CED, CPD, DBZ, E, PX, TP and ZPD.This two classes promotor is contained two active groups and two promotion bases, vulcanization rate is fast, especially dithiocarbamatetype accelerator, more active than thiuram type accelerator, vulcanization rate is faster, and promote the rubber after the sulfuration to have good ageing-resistant performance through it.Described anti-aging agent is antioxidant A P, APN, CEA, CMA, DOPC, TPPD, KY-405, SP.The promotor of conveying belt of the present invention and anti-aging agent form by one or more cooperations in above-mentioned promotor and the anti-aging agent, the be up to state standards requirement of " GB 10822-89 " of related physical mechanical property.
Compared with prior art, the invention has the beneficial effects as follows: have following characteristic during the conveying belt integral combustion: difficult combustion characteristic, fire-retardant oxygen index is between 34%-42%; Low cigarette characteristic is produced smoke density (SDR value)≤75; The Halogen characteristic, poisonous gas hydrogen halide content=0mg/g.Because the present invention adopts low cigarette, halogen-free flameproof sizing material to do rubber cover and transition glue sizing material, solved when existing general flame retardant conveyor belt burns and to have produced a large amount of poisonous gas hydrogen halide, cause serious secondary disaster, the problem of harm personnel life security and pollutant atmosphere is a kind of low cigarette, the nuisanceless goods of halogen-free flameproof.And raw material is easy to get all commercially available, and the preparation method is simple and easy, is suitable for suitability for industrialized production.
Embodiment will help to understand the present invention by following embodiment, but can not limit content of the present invention.
Embodiment 1:
20 parts of natural rubbers, 80 parts of isoprene-isobutylene rubbers, accelerant B Z1.0 part, 5 parts in zinc oxide, 1.2 parts of stearic acid, 10 parts of carbon blacks, 50 parts of active aluminium hydroxides, 40 parts of magnesium hydroxides, 15 parts of zinc borates, 0.5 part of antioxidant A P, 0.5 part of antioxidant A PN presses down fumicants XY-22 part, 2.0 parts in sulphur.
Embodiment 2:
20 parts of natural rubbers, 80 parts of isoprene-isobutylene rubbers, 1.5 parts of TM monex TM, 5 parts in zinc oxide, 1.5 parts of stearic acid, 20 parts of carbon blacks, 20 parts of active aluminium hydroxides, 30 parts of magnesium hydroxides, 15 parts of zinc borates, 15 parts of flame-resistant lubricant MB-202,10 parts of halogen-free flame retardants MRP, 0.5 part of anti-aging agent CEA, 0.5 part of anti-aging agent CMA, 0.5 part of antioxidant D OPC, 1.5 parts of molybdenum sesquioxides, press down fumicants FZY-215 part, 1.5 parts in sulphur.
Embodiment 3:
30 parts of natural rubbers, 70 parts of polyisoprene rubbers, 1.5 parts of accelerant C PD, 7 parts in zinc oxide, 2.5 parts of stearic acid, 15 parts of carbon blacks, 50 parts of active aluminium hydroxides, 40 parts of magnesium hydroxides, 25 parts of zinc borates, 10 parts of flame-resistant lubricant MB-202,10 parts of halogen-free flame retardants MRP, 2.5 parts of antioxidant A P, 1.5 parts of antioxidant SPs, press down 10 parts of fumicants FZY-14,2.0 parts in sulphur.Embodiment 4:
30 parts of natural rubbers, 70 parts of polyisoprene rubbers, 1.0 parts of promotor PTD, 0.5 part of promotor TBTD, 0.5 part of TM monex TM, 2 parts in zinc oxide, 3.0 parts of stearic acid, 20 parts of carbon blacks, 50 parts of active aluminium hydroxides, 50 parts of magnesium hydroxides, 25 parts of zinc borates, 15 parts of flame-resistant lubricant MB-202, anti-aging agent KY-4050.5 part, 0.5 part of antioxidant SP, 1.5 parts of anti-aging agent TPPD, press down 25 parts of fumicants FZY-21,3.0 parts in sulphur.
Earlier natural rubber is plasticated, mix with synthetic rubber and various Synergist S-421 95 again and carry out the mixing rubber master batch of making.Rubber master batch rolls after descending sheet, cooling off, park, made-up belt is made in moulding, promptly gets low cigarette of the present invention, without halide flame retardant conveyor belt after the made-up belt sulfuration.
The detected result of low cigarette, without halide flame retardant conveyor belt
Figure A0213272500051

Claims (8)

1, a kind of low cigarette, without halide flame retardant conveyor belt, it is characterized in that used rubber cover and transition glue sizing material be made up of following each components in part by weight: natural rubber 10-30 part, synthetic rubber 70-90 part, promotor 0.5-2.5 part, zinc oxide 4-7 part, stearic acid 1.0-3.0 part, carbon black 5-25 part, anti-aging agent 0.5-6.0 part, sulphur 1.0-3.0 part, halogen-free flame retardants 70-150 part is pressed down fumicants 2-25 part.
2, low cigarette according to claim 1, without halide flame retardant conveyor belt is characterized in that described halogen-free flame retardants is active aluminium hydroxide, magnesium hydroxide, zinc borate, flame-resistant lubricant MB-202, halogen-free flame retardants MRP, ammonium octamolybdate, polyphosphoric acid amine, fire retardant SP-1, FR-S101, TBC.
3, low cigarette according to claim 1, without halide flame retardant conveyor belt is characterized in that the described fumicants that presses down is to press down fumicants XY-1, XY-2, FZY-14, FZY-21, molybdenum sesquioxide.
4, low cigarette according to claim 1, without halide flame retardant conveyor belt is characterized in that described synthetic rubber is isoprene-isobutylene rubber, polyisoprene rubber.
5, low cigarette according to claim 1, without halide flame retardant conveyor belt is characterized in that described anti-aging agent is antioxidant A P, APN, CEA, CMA, DOPC, TPPD, KY-405, SP.
6, low cigarette according to claim 1, without halide flame retardant conveyor belt is characterized in that described promotor is dithiocarbamatetype accelerator, thiuram type accelerator.
7, low cigarette according to claim 6, without halide flame retardant conveyor belt is characterized in that described dithiocarbamatetype accelerator is accelerant B Z, CED, CPD, DBZ, E, PX, TP, ZPD.
8, low cigarette according to claim 6, without halide flame retardant conveyor belt is characterized in that described thiuram type accelerator is promotor PTD, TBTS, TBTD, TMTM, TMTT.
CN 02132725 2002-08-01 2002-08-01 Smokeless flame resistant conveying belt without halide Expired - Fee Related CN1260280C (en)

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CN1260280C CN1260280C (en) 2006-06-21

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100372746C (en) * 2005-06-24 2008-03-05 阳江市北山胶化有限公司 Impact resistance high wearing-proof conveyer belt
CN100412133C (en) * 2004-04-15 2008-08-20 上海普利特复合材料有限公司 Flame retardant fiberglass enhanced PCT composite materal in low smoke
CN101973446A (en) * 2010-07-29 2011-02-16 安徽中意胶带有限责任公司 Environmentally-friendly flame-retardant conveyor belt with steel cable core used for coal mines
CN102127253A (en) * 2010-11-16 2011-07-20 安徽天地人科技集团输送带有限公司 Steel wire rope core flame-resistant conveyor belt for coal mine
CN102558582A (en) * 2011-12-30 2012-07-11 大连亚泰科技新材料有限公司 Method for preparing whole core conveyor belt covered with magnesium hydroxide flame retardants
CN102730366A (en) * 2012-07-12 2012-10-17 重庆中南橡胶有限公司 Anti-burning conveyor belt
CN103012977A (en) * 2012-12-25 2013-04-03 阜新环宇橡胶(集团)有限公司 Fabric laminated flame retardant conveyer belt used for coal mine
CN103289152A (en) * 2013-06-14 2013-09-11 浙江保尔力胶带有限公司 High-temperature resistant rubber conveyor belt and production method thereof
CN104558718A (en) * 2013-10-09 2015-04-29 阜新环宇橡胶(集团)有限公司 Flame-retardant heat-resistant conveyer belt
CN106084314A (en) * 2016-06-01 2016-11-09 安徽强力重工起重机械有限公司 A kind of wear resistant belt for Coal Transport machine
CN106433083A (en) * 2016-10-19 2017-02-22 黄宇 Graphene modified rubber material with high bending strength
CN106633790A (en) * 2016-10-19 2017-05-10 黄宇 Graphene modified rubber material with high shock resistance
CN106633422A (en) * 2016-10-19 2017-05-10 黄宇 Graphene modified rubber material
CN106633436A (en) * 2016-10-19 2017-05-10 黄宇 Flame-retardant graphene modified rubber material
EP3940026A4 (en) * 2019-07-31 2022-06-29 Sumitomo Riko Company Limited Flame-retardant vibration-damping rubber composition and flame-retardant vibration-damping rubber member

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101214880B (en) * 2008-01-11 2010-07-28 浙江东南橡胶机带有限公司 Tearing-proof high temperature resisting conveyer belt

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100412133C (en) * 2004-04-15 2008-08-20 上海普利特复合材料有限公司 Flame retardant fiberglass enhanced PCT composite materal in low smoke
CN100372746C (en) * 2005-06-24 2008-03-05 阳江市北山胶化有限公司 Impact resistance high wearing-proof conveyer belt
CN101973446A (en) * 2010-07-29 2011-02-16 安徽中意胶带有限责任公司 Environmentally-friendly flame-retardant conveyor belt with steel cable core used for coal mines
CN101973446B (en) * 2010-07-29 2012-05-30 安徽中意胶带有限责任公司 Environmentally-friendly flame-retardant conveyor belt with steel cable core used for coal mines
CN102127253B (en) * 2010-11-16 2012-11-14 安徽天地人塑胶有限公司 Steel wire rope core flame-resistant conveyor belt for coal mine
CN102127253A (en) * 2010-11-16 2011-07-20 安徽天地人科技集团输送带有限公司 Steel wire rope core flame-resistant conveyor belt for coal mine
CN102558582A (en) * 2011-12-30 2012-07-11 大连亚泰科技新材料有限公司 Method for preparing whole core conveyor belt covered with magnesium hydroxide flame retardants
CN102730366B (en) * 2012-07-12 2015-04-22 重庆中南橡胶有限公司 Anti-burning conveyor belt
CN102730366A (en) * 2012-07-12 2012-10-17 重庆中南橡胶有限公司 Anti-burning conveyor belt
CN103012977A (en) * 2012-12-25 2013-04-03 阜新环宇橡胶(集团)有限公司 Fabric laminated flame retardant conveyer belt used for coal mine
CN103012977B (en) * 2012-12-25 2015-06-10 阜新环宇橡胶(集团)有限公司 Fabric laminated flame retardant conveyer belt used for coal mine
CN103289152A (en) * 2013-06-14 2013-09-11 浙江保尔力胶带有限公司 High-temperature resistant rubber conveyor belt and production method thereof
CN103289152B (en) * 2013-06-14 2015-05-27 浙江保尔力胶带有限公司 High-temperature resistant rubber conveyor belt and production method thereof
CN104558718A (en) * 2013-10-09 2015-04-29 阜新环宇橡胶(集团)有限公司 Flame-retardant heat-resistant conveyer belt
CN106084314A (en) * 2016-06-01 2016-11-09 安徽强力重工起重机械有限公司 A kind of wear resistant belt for Coal Transport machine
CN106433083A (en) * 2016-10-19 2017-02-22 黄宇 Graphene modified rubber material with high bending strength
CN106633790A (en) * 2016-10-19 2017-05-10 黄宇 Graphene modified rubber material with high shock resistance
CN106633422A (en) * 2016-10-19 2017-05-10 黄宇 Graphene modified rubber material
CN106633436A (en) * 2016-10-19 2017-05-10 黄宇 Flame-retardant graphene modified rubber material
EP3940026A4 (en) * 2019-07-31 2022-06-29 Sumitomo Riko Company Limited Flame-retardant vibration-damping rubber composition and flame-retardant vibration-damping rubber member

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