CN103289152A - High-temperature resistant rubber conveyor belt and production method thereof - Google Patents
High-temperature resistant rubber conveyor belt and production method thereof Download PDFInfo
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- CN103289152A CN103289152A CN2013102374940A CN201310237494A CN103289152A CN 103289152 A CN103289152 A CN 103289152A CN 2013102374940 A CN2013102374940 A CN 2013102374940A CN 201310237494 A CN201310237494 A CN 201310237494A CN 103289152 A CN103289152 A CN 103289152A
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Abstract
The invention provides a production method of a high-temperature resistant rubber conveyor belt which comprises a main body material and rubber cover plastic, wherein the plastic cover plastic comprises the following components in parts by weight of: 80-120 parts of butadiene styrene rubber, 2-10 parts of a vulcanizing agent, 10-20 parts of stearic acid, 20-50 parts of carbon black, 2-3 parts of an accelerant, 0.1-1 part of sulphur, 5-10 parts of a softening agent, 2-5 parts of an anti-aging agent and 20-50 parts of a multi-crystal water compound. The high-temperature resistant rubber conveyor belt produced by adopting the production method has the advantages of good heat resistance and long service life.
Description
Technical field
The present invention relates to the goods transportation art of metallurgy, chemical industry and building materials, be specifically related to a kind of high-temperature resistant rubber conveying belt and production method thereof.
Background technology
At metallurgy, industries such as building materials need be carried high-temp solid material, as sintered ore, cement clinker, lime and coke etc., standard GB/T20021-2005 is divided into heatproof zone four grades such as T1, T2, T3, T4, its experimental temperature is respectively 100 ℃, 125 ℃, 150 ℃, 175 ℃, allow use temperature below 175 ℃, and the working temperature of these industries can reach 300-500 ℃.Catabiosis such as in use be easy to chap, come unstuck has just been scrapped later on.Existing production method is in order to improve the work-ing life of product, general all be select can be relatively with the rubber of high temperature, as styrene-butadiene rubber(SBR), terpolymer EP rubber etc. and by the research to its prescription, comprise prescription of material of main part and rubber cover etc., but still can't satisfy high request to resistance to elevated temperatures, still need its work-ing life further to improve, to reduce replacement cost.
Summary of the invention
A kind of high-temperature resistant rubber conveying belt and the production method thereof of providing of the present invention.When the heat in the material of conveying belt is transmitted to conveyer belt coating rubber surperficial, heat can be absorbed, thereby stops the rubber temperature in the rubber cover to rise rapidly, also stops heat to the conveying belt conducted inside, postpone the aging of conveying belt, guarantee to prolong the work-ing life of conveying belt.
Dehydration reaction can take place in the multi-crystallization water compound under the condition of high temperature, absorb the heat in the rubber, reduces the temperature of rubber, postpones the aging of rubber, the work-ing life of improving high temperature-resistance conveyor belt.
Be not that all multi-crystallization water compounds all can satisfy the use needs, they must possess following performance:
1 has well actively mutually with rubber, rubber is had strengthening action preferably.
2 are difficult for dehydration in the course of processing of rubber.
Temperature lowers and can absorb water after 3 high temperature dehydrations, and namely process is reversible.
4 thermal conduction capability are low
The crystal water of 5 combinations is many.
6 do not promote the effect of ageing of rubber.
For achieving the above object, the present invention adopts following technical scheme
A kind of high-temperature resistant rubber conveying belt and preparation method thereof comprises material of main part and rubber rubber cover, and the prescription of its rubber rubber cover is in weight part: styrene-butadiene rubber(SBR) 80-120 part; Vulcanizing agent 2-10 part; Stearic acid 10-20 part; Carbon black 20-50 part; Promotor 2-3 part; Sulphur 0.1-1 part; Tenderizer 5-10 part; Anti-aging agent 2-5 part; Multi-crystallization water compound 20-50 part.
The described high temperature resistant temperature that refers to is at 300-500 ℃, and instantaneous temperature is higher than 800 ℃.
Described material of main part is one or more in cis-1,4-polybutadiene rubber, natural rubber, styrene-butadiene rubber(SBR), isoprene-isobutylene rubber or the chloroprene rubber.
Described material of main part is cis-1,4-polybutadiene rubber and natural rubber, and its amount ratio is 1:1.
Styrene-butadiene rubber(SBR) in the described rubber rubber cover is 90-100 part, is preferably 100 parts.
Described vulcanizing agent is 5 parts, is preferably zinc oxide.
Described stearic acid is preferably 15 parts.
Described carbon black is preferably 40 parts.
Described promotor is preferably 2.5 parts of dimethyl-p-toluidines.
Described sulphur is preferably 0.5 part.
Described tenderizer is petroleum line softener, is preferably 6 parts; Wherein petroleum line softener comprises that carbon 9 resins and resol are tenderizer.
Described anti-aging agent is anti-aging agent RD or antioxidant BLE, is preferably 4 parts.
Described multi-crystallization water compound is preferably the aluminium hydroxide (Al of seven hydrate zinc borates and colloidal
2O
33H
2O), wherein the mass ratio of the aluminium hydroxide of zinc borate and colloidal is 2:1.
The high-temperature resistant rubber conveying belt that the present invention produces is through specific formulating of recipe, and resistance toheat is good, and long service life has the incomparable advantage of other conveying belt.
Embodiment
Embodiment 1
The preparation high-temperature resistant rubber, its main rubber is cis-1,4-polybutadiene rubber and natural rubber, the prescription of rubber rubber cover: 100 parts in styrene-butadiene rubber(SBR); 5 parts in zinc oxide; 15 parts of stearic acid; 40 parts of N330 carbon blacks; Promotor dimethyl-p-toluidine DMDT2.5 part; 0.5 part in sulphur; 6 parts of petroleum line softeners; 4 parts in anti-aging agent; 20 parts of seven hydrate zinc borates; 10 parts in the aluminium hydroxide of colloidal.
Comparative Examples 1: its main rubber is cis-1,4-polybutadiene rubber and natural rubber, the prescription of rubber rubber cover: 100 parts in styrene-butadiene rubber(SBR); 5 parts in zinc oxide; 15 parts of stearic acid; 40 parts of N330 carbon blacks; Promotor dimethyl-p-toluidine DMDT2.5 part; 0.5 part in sulphur; 6 parts of petroleum line softeners; 4 parts in anti-aging agent; 30 parts of seven hydrate zinc borates.
Comparative Examples 2: its main rubber is cis-1,4-polybutadiene rubber and natural rubber, the prescription of rubber rubber cover: 100 parts in styrene-butadiene rubber(SBR); 5 parts in zinc oxide; 15 parts of stearic acid; 40 parts of N330 carbon blacks; Promotor dimethyl-p-toluidine DMDT2.5 part; 0.5 part in sulphur; 6 parts of petroleum line softeners; 4 parts in anti-aging agent; 30 parts in the aluminium hydroxide of colloidal.
Comparative Examples 3: its main rubber is cis-1,4-polybutadiene rubber and natural rubber, the prescription of rubber rubber cover: 100 parts in styrene-butadiene rubber(SBR); 5 parts in zinc oxide; 15 parts of stearic acid; 40 parts of N330 carbon blacks; Promotor dimethyl-p-toluidine DMDT2.5 part; 0.5 part in sulphur; 6 parts of petroleum line softeners; 4 parts in anti-aging agent.
Test 1: make conveying belt according to said ratio and test later on, be installed to temperature of charge and be 250 ℃ cement mill, test its work-ing life.
Test 2: make conveying belt according to said ratio and test later on, temperature of charge is 300 ℃, test goods variation of temperature situation after conveying belt moves 20 minutes.
The contrast of table 1 experimental data
? | The work-ing life (moon) of test 1 | Test the value that 2 temperature drop to (℃) |
Embodiment 1 | 20 | 145 |
Comparative Examples 1 | 15 | 208 |
Comparative Examples 2 | 14 | 200 |
Comparative Examples 3 | 12 | 252 |
This shows that with the aluminium hydroxide that does not add zinc borate and colloidal and add wherein a kind of situation and compare, the conveying belt of formulating of recipe of the present invention has excellent.
It will be recognized by those skilled in the art, under the prerequisite that does not depart from protection scope of the present invention, can carry out various modifications, variation and combination to above-mentioned embodiment, and think that this modification, variation and combination are within the scope of originality thought.
Claims (9)
1. the production method of a high-temperature resistant rubber conveying belt comprises material of main part and rubber rubber cover, and the prescription of its rubber rubber cover is in weight part: styrene-butadiene rubber(SBR) 80-120 part; Vulcanizing agent 2-10 part; Stearic acid 10-20 part; Carbon black 20-50 part; Promotor 2-3 part; Sulphur 0.1-1 part; Tenderizer 5-10 part; Anti-aging agent 2-5 part; Multi-crystallization water compound 20-50 part.
2. the method for claim 1, wherein said material of main part is one or more in cis-1,4-polybutadiene rubber, natural rubber, styrene-butadiene rubber(SBR), isoprene-isobutylene rubber or the chloroprene rubber.
3. the method for claim 1, wherein said material of main part is cis-1,4-polybutadiene rubber and natural rubber, its amount ratio is 1:1.
4. the method for claim 1, the styrene-butadiene rubber(SBR) in the wherein said rubber rubber cover is 90-100 part, is preferably 100 parts.
5. the method for claim 1, wherein said vulcanizing agent is 5 parts in zinc oxide; Described stearic acid is preferably 15 parts; Described carbon black is preferably 40 parts; Described promotor is preferably 2.5 parts of dimethyl-p-toluidines; Described sulphur is preferably 0.5 part.
6. the method for claim 1, wherein said tenderizer is 6 parts of petroleum line softeners, wherein petroleum line softener comprises that carbon 9 resins and resol are tenderizer.
7. the method for claim 1, wherein said anti-aging agent is anti-aging agent RD or antioxidant BLE, is preferably 4 parts.
8. the method for claim 1, wherein said multi-crystallization water compound is preferably the aluminium hydroxide (Al of seven hydrate zinc borates and colloidal
2O
33H
2O), wherein the mass ratio of the aluminium hydroxide of zinc borate and colloidal is 2:1.
9. the high-temperature resistant rubber conveying belt for preparing as the method for claim 1-7.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103709453A (en) * | 2013-11-29 | 2014-04-09 | 山东永泰化工有限公司 | Coating rubber of conveying belt for refrigeration industry |
CN105906882A (en) * | 2016-07-06 | 2016-08-31 | 南通鸿图橡塑有限公司 | Rubber plastic material for elevator and preparation method thereof |
CN106279844A (en) * | 2016-08-31 | 2017-01-04 | 天台鑫凯橡塑有限公司 | A kind of new type rubber and processing method thereof |
CN106865112A (en) * | 2017-01-05 | 2017-06-20 | 开封铁塔橡胶(集团)有限公司 | Compound anti-tear, anti-impact steel wire rope core conveyer belt and preparation method thereof |
CN106928513A (en) * | 2017-03-17 | 2017-07-07 | 广州飞旋橡胶有限公司 | A kind of burning-resistant conveyor belt |
CN108440852A (en) * | 2018-05-04 | 2018-08-24 | 安徽悦尔伟塑料机械有限公司 | High-temperature resistant rubber composite material and preparation method |
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CN1439671A (en) * | 2002-08-01 | 2003-09-03 | 阜新橡胶有限责任公司 | Smokeless flame resistant conveying belt without halide |
CN101580681A (en) * | 2009-03-24 | 2009-11-18 | 无锡宝通带业股份有限公司 | Surface covering rubber of flame-retardant canvas laminated core conveying belt and preparation method thereof |
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CN1439671A (en) * | 2002-08-01 | 2003-09-03 | 阜新橡胶有限责任公司 | Smokeless flame resistant conveying belt without halide |
CN101580681A (en) * | 2009-03-24 | 2009-11-18 | 无锡宝通带业股份有限公司 | Surface covering rubber of flame-retardant canvas laminated core conveying belt and preparation method thereof |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103709453A (en) * | 2013-11-29 | 2014-04-09 | 山东永泰化工有限公司 | Coating rubber of conveying belt for refrigeration industry |
CN105906882A (en) * | 2016-07-06 | 2016-08-31 | 南通鸿图橡塑有限公司 | Rubber plastic material for elevator and preparation method thereof |
CN105906882B (en) * | 2016-07-06 | 2018-03-23 | 南通鸿图橡塑有限公司 | A kind of elevator rubber-plastics material and preparation method |
CN106279844A (en) * | 2016-08-31 | 2017-01-04 | 天台鑫凯橡塑有限公司 | A kind of new type rubber and processing method thereof |
CN106865112A (en) * | 2017-01-05 | 2017-06-20 | 开封铁塔橡胶(集团)有限公司 | Compound anti-tear, anti-impact steel wire rope core conveyer belt and preparation method thereof |
CN106928513A (en) * | 2017-03-17 | 2017-07-07 | 广州飞旋橡胶有限公司 | A kind of burning-resistant conveyor belt |
CN108440852A (en) * | 2018-05-04 | 2018-08-24 | 安徽悦尔伟塑料机械有限公司 | High-temperature resistant rubber composite material and preparation method |
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Address after: 317200 South Industrial Park, Tiantai Economic Development Zone, Taizhou City, Zhejiang Province Patentee after: Zhejiang baoerli Rubber & Plastic Co.,Ltd. Address before: 317200 South Industrial Park, Tiantai Economic Development Zone, Taizhou City, Zhejiang Province Patentee before: ZHEJIANG POWERBELT Co.,Ltd. |
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