CN105419197A - Green and flame-retardant cable filler - Google Patents

Green and flame-retardant cable filler Download PDF

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Publication number
CN105419197A
CN105419197A CN201511006567.0A CN201511006567A CN105419197A CN 105419197 A CN105419197 A CN 105419197A CN 201511006567 A CN201511006567 A CN 201511006567A CN 105419197 A CN105419197 A CN 105419197A
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China
Prior art keywords
parts
green
flame
cable filler
environmental protection
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Pending
Application number
CN201511006567.0A
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Chinese (zh)
Inventor
王丽萍
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Individual
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Individual
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Priority to CN201511006567.0A priority Critical patent/CN105419197A/en
Publication of CN105419197A publication Critical patent/CN105419197A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
    • C08J2423/30—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by oxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Provided is a green and flame-retardant cable filler. The green and flame-retardant cable filler is prepared from the following raw materials, by weight, 16-32 parts of acrylic acid ester rubber microballoons, 8-14 parts of hydroquinone, 4-7 parts of zinc oxide, 5-8 parts of environmental protection thermal stabilizing agent, 6-17 parts of filling agent, 10-20 parts of magnesium hydroxide, 0.8-1.6 parts of AC foaming agent, 3-6 parts of magnesium stearate, 12-22 parts of nano graphene, 8-15 parts of graphite, 3-4 parts of oxidized polyethlene wax, 0.8-2.4 parts of curing accelerator, 6-13 parts of potassium nitrate, 4-7 parts of calcium stearate, 6-10 parts of sodium nitrite, 7-12 parts of sodium salicylate, and 5-8 parts of potassium sulfate. The beneficial effects are that the green and flame-retardant cable filler is advantaged by good flame retardant effects, high temperature resistance, low smoke, no generation of toxic substances, green and environmental protection.

Description

A kind of Green Flammability type cable filler
Technical field
The present invention relates to a kind of Green Flammability type cable filler.
Background technology
Along with the fast development of China's economy, electric wire serves very important link effect in the middle of the capital construction of China.In cable production process, for ensureing the rounding property of cable, avoid the mutual friction between heart yearn simultaneously, need to add packing material between heart yearn, PVC flame retardant filler strip mainly has halogen fire-retardant, when presence of fire, a large amount of smog can be produced, produce poisonous, with irritating and corrosive hydrogen halide; Smog can hinder fire fighting and evacuating personnel, and hydrogen halide meeting etching apparatus, also can be detrimental to health.Along with the enhancing of mankind's environmental consciousness, the requirement of each field to the quality and performance of electric wire is more and more higher, should accident occur burning or because of overload and other situation generation spontaneous combustions time, the flue dust smog of a large amount of contaminate environment can be produced, larger pollution is caused to environment.Therefore, the stopping composition for cable needs to reduce the harm for environment as far as possible, and the stopping composition of environmental protection more and more receives an acclaim.
Summary of the invention
For the deficiencies in the prior art, the problem to be solved in the present invention is, provide a kind of Green Flammability type cable filler, good flame retardation effect, high temperature resistant, low cigarette, can not produce toxic substance, environmental protection.
For solving prior art problem, technical scheme provided by the invention is, a kind of Green Flammability type cable filler, and it is made up of the raw material of following parts by weight:
Acrylic elastomer microballoon 16-32 part, Resorcinol 8-14 part, zinc oxide 4-7 part, environmental protection thermal stabilizer 5-8 part, weighting agent 6-17 part, magnesium hydroxide 10-20 part, AC whipping agent 0.8-1.6 part, Magnesium Stearate 3-6 part, nano-graphene 12-22 part, graphite 8-15 part, oxidized polyethlene wax 3-4 part, curing catalyst 0.8-2.4 part, saltpetre 6-13 part, calcium stearate 4-7 part, Sodium Nitrite 6-10 part, sodium salicylate 7-12 part, potassium sulfate 5-8 part.
Further, a kind of Green Flammability type cable filler, it is made up of the raw material of following parts by weight:
Acrylic elastomer microballoon 24 parts, Resorcinol 11 parts, 5.5 parts, zinc oxide, environmental protection thermal stabilizer 6.5 parts, weighting agent 11 parts, magnesium hydroxide 15 parts, AC whipping agent 1.2 parts, Magnesium Stearate 4.5 parts, nano-graphene 18 parts, 11 parts, graphite, oxidized polyethlene wax 3.5 parts, curing catalyst 1.7 parts, 10 parts, saltpetre, calcium stearate 5.5 parts, Sodium Nitrite 8 parts, sodium salicylate 9 parts, potassium sulfate 6.5 parts.
The invention has the beneficial effects as follows: Green Flammability type cable filler of the present invention, good flame retardation effect, high temperature resistant, low cigarette, can not produce toxic substance, environmental protection.
Embodiment
embodiment 1
A kind of Green Flammability type cable filler, it is made up of the raw material of following parts by weight:
Acrylic elastomer microballoon 16 parts, Resorcinol 8 parts, 4 parts, zinc oxide, environmental protection thermal stabilizer 5 parts, weighting agent 6 parts, magnesium hydroxide 10 parts, AC whipping agent 0.8 part, Magnesium Stearate 3 parts, nano-graphene 12 parts, 8 parts, graphite, oxidized polyethlene wax 3 parts, curing catalyst 0.8 part, 6 parts, saltpetre, calcium stearate 4 parts, Sodium Nitrite 6 parts, sodium salicylate 7 parts, potassium sulfate 5 parts.
embodiment 2
A kind of Green Flammability type cable filler, it is made up of the raw material of following parts by weight:
Acrylic elastomer microballoon 32 parts, Resorcinol 14 parts, 7 parts, zinc oxide, environmental protection thermal stabilizer 8 parts, weighting agent 17 parts, magnesium hydroxide 20 parts, AC whipping agent 1.6 parts, Magnesium Stearate 6 parts, nano-graphene 22 parts, 15 parts, graphite, oxidized polyethlene wax 4 parts, curing catalyst 2.4 parts, 13 parts, saltpetre, calcium stearate 7 parts, Sodium Nitrite 10 parts, sodium salicylate 12 parts, potassium sulfate 8 parts.
embodiment 3
A kind of Green Flammability type cable filler, it is made up of the raw material of following parts by weight:
Acrylic elastomer microballoon 24 parts, Resorcinol 11 parts, 5.5 parts, zinc oxide, environmental protection thermal stabilizer 6.5 parts, weighting agent 11 parts, magnesium hydroxide 15 parts, AC whipping agent 1.2 parts, Magnesium Stearate 4.5 parts, nano-graphene 18 parts, 11 parts, graphite, oxidized polyethlene wax 3.5 parts, curing catalyst 1.7 parts, 10 parts, saltpetre, calcium stearate 5.5 parts, Sodium Nitrite 8 parts, sodium salicylate 9 parts, potassium sulfate 6.5 parts.

Claims (2)

1. a Green Flammability type cable filler, is characterized in that: it is made up of the raw material of following parts by weight:
Acrylic elastomer microballoon 16-32 part, Resorcinol 8-14 part, zinc oxide 4-7 part, environmental protection thermal stabilizer 5-8 part, weighting agent 6-17 part, magnesium hydroxide 10-20 part, AC whipping agent 0.8-1.6 part, Magnesium Stearate 3-6 part, nano-graphene 12-22 part, graphite 8-15 part, oxidized polyethlene wax 3-4 part, curing catalyst 0.8-2.4 part, saltpetre 6-13 part, calcium stearate 4-7 part, Sodium Nitrite 6-10 part, sodium salicylate 7-12 part, potassium sulfate 5-8 part.
2. Green Flammability type cable filler according to claim 1, is characterized in that: it is made up of the raw material of following parts by weight:
Acrylic elastomer microballoon 24 parts, Resorcinol 11 parts, 5.5 parts, zinc oxide, environmental protection thermal stabilizer 6.5 parts, weighting agent 11 parts, magnesium hydroxide 15 parts, AC whipping agent 1.2 parts, Magnesium Stearate 4.5 parts, nano-graphene 18 parts, 11 parts, graphite, oxidized polyethlene wax 3.5 parts, curing catalyst 1.7 parts, 10 parts, saltpetre, calcium stearate 5.5 parts, Sodium Nitrite 8 parts, sodium salicylate 9 parts, potassium sulfate 6.5 parts.
CN201511006567.0A 2015-12-29 2015-12-29 Green and flame-retardant cable filler Pending CN105419197A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511006567.0A CN105419197A (en) 2015-12-29 2015-12-29 Green and flame-retardant cable filler

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201511006567.0A CN105419197A (en) 2015-12-29 2015-12-29 Green and flame-retardant cable filler

Publications (1)

Publication Number Publication Date
CN105419197A true CN105419197A (en) 2016-03-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201511006567.0A Pending CN105419197A (en) 2015-12-29 2015-12-29 Green and flame-retardant cable filler

Country Status (1)

Country Link
CN (1) CN105419197A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108017804A (en) * 2017-11-15 2018-05-11 郴州国盛新材科技有限公司 A kind of fiber reinforcement high density polyethylene (HDPE)/graphite composite material and preparation method thereof
CN108250642A (en) * 2017-12-23 2018-07-06 董晓 A kind of preparation method of cable filler

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102354561A (en) * 2011-07-12 2012-02-15 安徽润佳电缆集团股份有限公司 Vertical water-blocked filler material used in cable
CN102604296A (en) * 2012-01-06 2012-07-25 安徽塞帕斯电缆材料有限公司 Novel cable filler and preparation method thereof
CN103194028A (en) * 2013-03-02 2013-07-10 安徽金田通信科技实业有限公司 Cable filler and preparation method thereof
CN103756225A (en) * 2014-01-23 2014-04-30 宜昌华润红旗电缆有限公司 High-flame-resistance filler and preparation method thereof as well as mining high-flame resistance flexible cable made from high-flame-resistance filler

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102354561A (en) * 2011-07-12 2012-02-15 安徽润佳电缆集团股份有限公司 Vertical water-blocked filler material used in cable
CN102604296A (en) * 2012-01-06 2012-07-25 安徽塞帕斯电缆材料有限公司 Novel cable filler and preparation method thereof
CN103194028A (en) * 2013-03-02 2013-07-10 安徽金田通信科技实业有限公司 Cable filler and preparation method thereof
CN103756225A (en) * 2014-01-23 2014-04-30 宜昌华润红旗电缆有限公司 High-flame-resistance filler and preparation method thereof as well as mining high-flame resistance flexible cable made from high-flame-resistance filler

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108017804A (en) * 2017-11-15 2018-05-11 郴州国盛新材科技有限公司 A kind of fiber reinforcement high density polyethylene (HDPE)/graphite composite material and preparation method thereof
CN108250642A (en) * 2017-12-23 2018-07-06 董晓 A kind of preparation method of cable filler

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Application publication date: 20160323