CN1398957A - Cleaning agent - Google Patents

Cleaning agent Download PDF

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Publication number
CN1398957A
CN1398957A CN 01128510 CN01128510A CN1398957A CN 1398957 A CN1398957 A CN 1398957A CN 01128510 CN01128510 CN 01128510 CN 01128510 A CN01128510 A CN 01128510A CN 1398957 A CN1398957 A CN 1398957A
Authority
CN
China
Prior art keywords
clean
out system
alkane
alcohol
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 01128510
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Chinese (zh)
Other versions
CN1232626C (en
Inventor
邓和升
于耀强
张建辉
邓和军
邓妍
邓曦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHENZHOU GOLD ARROW SOLDER Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN 01128510 priority Critical patent/CN1232626C/en
Publication of CN1398957A publication Critical patent/CN1398957A/en
Application granted granted Critical
Publication of CN1232626C publication Critical patent/CN1232626C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

A scavenger for electronic industry consists of C3-C9 alkane 10-85 wt%, C3-C8 ketone 1-30 wt5, C3-C10 ether 1-30 wt%, C1-C5 alcohol 1-30 wt% and additive 0.01-10 wt%. It contains no fluorochloric alkane and similar matter, and thus has no environmental pollution, and has excellent scavengine capability to rosin, resin, oil dirt and pollutant. It may be used in direct soaking and washing of electronic equipment and PCB, and is supersonic cleaning.

Description

Clean-out system
Technical field:
The present invention relates to the clean-out system of electronics, mechanical industry, particularly relate to rosiny leaning solvent on greasy dirt on the objects such as being applicable to clean metal, pottery and the wiring board.
Background technology:
At present; electronics; advancing by leaps and bounds of electrician trade; the soldering that matches is with it also proposed higher requirement with material; simultaneously; the importance of HUMAN HEALTH is also more and more paid attention to by people; advocate and taked a series of measures by developed country; be used to improve the global environment that the mankind depend on for existence; United Nations's Environmental Protection Administration has also proposed the requirement of the material of the harmful atmospheric environment of time limit change; and the electron and electrician industry is because very high to the reliability requirement of portioned product; must after producing welding, clean product; and the clean-out system major part of using now is fluorine-containing; the hydrocarbon compound of chlorine substituent; this type of material has serious destruction to atmospheric ozone layer; belong to necessary time limit that United Nations proposes and forbid the scope of producing and using, this type of material of while hazardness very big to operative employee's healthy same existence is at above factor; the electron and electrician industry presses for to be transformed existing clean-out system, to reach the purpose of protection human health and atmospheric environment.Wherein a measure is exactly the clean-out system that clean-out system is made not contain into the fluorochlorohydrocarbon class.The domestic research institute that how tame clean-out system once occurred, some unit has developed aqueous cleaning agent, " a kind of acidic water-based cleaning agent for metals " of the southern power machine of the notification number announced as Chinese patent 1067275 company, this clean-out system contains carboxylic acid, esters surface active agent and inorganic salts, described carboxylic acid contains 2-7 C, the alkyd of at least one carboxyl and a carboxyl, described esters surface active agent is an alkyl phosphate, described inorganic salt are vitriol, but most of electronic products is avoided and is washed with water, makes that aqueous cleaning agent is promoted aspect PCB and utilization is very restricted.
The organic solvent type clean-out system has appearred again subsequently, the notification number of announcing as Chinese patent is 1045134 Chengdu organic chemistry institutes " a kind of remove the multi-component high-efficient detergent that solder flux is used ", this clean-out system is by Nitromethane 99Min., acetonitrile, ethyl acetate, 1,1,1-trichloroethane, and Virahol or propyl alcohol or ethanol composition, also " 1 of notification number 1078257 U.S. United info stock Co., Ltd that announce just like Chinese patent, 1,2,3, the azeotropic shape composition of 3-pentafluoropropane ", this clean-out system is to contain 1,1,2,3,3-pentafluoropropane and methyl alcohol or ethanol and the composition that contains Nitromethane 99Min..Though the clean-out system of these organic types has stability preferably, and the workpiece that is cleaned is not had corrosion, seepage force is stronger, can remove solder flux and degreasing effectively, toxicity is low, but hydrocarbons still fluorine-containing in clean-out system, chlorine.
Summary of the invention:
The object of the present invention is to provide a kind of syntheticly, the ability of good cleaning rosin, resin, greasy dirt, pollutent is arranged, and it is fast to clean after drying by no fluorochlorohydrocarbon class material; Both can be used to embathe electronic component, can be used for the clean-out system of ultrasonic cleaning again.
Clean-out system of the present invention, composed of the following components by weight percentage
C 3-C 9Alkane 10-90%
C 3-C 8Ketone 1-30%
C 3-C 10Ether 1-30%
C 1-C 3Alcohol 1-30%
Additive 0.01-10%
Alkane is naphthenic hydrocarbon or straight-chain paraffin, and ketone is naphthenone or straight alkane ketone, and ether is straight chain alkane ether, and alcohol is monohydroxy-alcohol; Additive is the mixture of synergy with nonionogenic tenside, inhibiter, complexing agent.
The preparation method that it is concrete:
1, with 1-2 kind C 3-C 9Alkane 10-90%, 1-2 kind C 3-C 8Ketone 1-30%, C 3-C 10Ether 1-30%, C 1-C 3Alcohol 1-30% joins in the reactor, stirs 30-40 minute, forms mixture.
2, in mixture, slowly splash into additive by weight proportion; After dropwising, restir 10-15 minute, obtain clean-out system of the present invention.
Clean-out system among the present invention does not contain the halohydrocarbon such as freonll-11 that atmospheric ozone layer had destruction, and its hydrocarbons is naphthenic hydrocarbon or straight-chain paraffin, its polarity and C 1-C 5The polarities match of alcohol; be complementary with key in the ethers and the bond polarity in the ketone; has tensio-active agent in the additive; inhibiter, complexing agent; be cleaned that metal object smooth finish is good, not oxidation; being cleaned PCB does not return white; the greasy dirt that is cleaned surfaces such as metal such as copper, aluminium is cleaned; the components and parts of PCB generally all are zinc-plated, and the position of leaking copper is arranged once in a while, also do not corrode owing to generate the copper complex of protectiveness; not patination; rosin that it is surperficial and additive reaction are dissolved in wherein and form the material that is soluble in clean-out system, do not contain to remain in PCB surface whitening look.
Clean-out system of the present invention detects the synopsis of data and normal data
Test item Normal data Detected result
????I ????II
Outward appearance Clear Clear Clear
Smell Free from extraneous odour Free from extraneous odour Free from extraneous odour
Acidity (% is in HCI) ????≤0.001 ????<0.001 ????<0.001
Moisture content (%) ????≤0.05 ????0.01 ????0.01
Evaporation residue (%) ????≤0.01 ????0.005 ????0.001
Clean-out system of the present invention and like product detect the data synopsis
Test item Detect data Contrasting data *
Outward appearance Clear Clear
Smell Free from extraneous odour Free from extraneous odour
Acidity (% is in HCI) ????0.001 ????0.02
Moisture content (%) ????0.04 ????0.05
Evaporation residue (%) ????0.005 ????0.01
Washing power (%) Clean greasy dirt ????92 ????93
Clean rosin ????91 ????90
PH value ????6.5 ????6.5
*Contrasting data is the import clean-out system.
Clean-out system of the present invention is slightly better than external product aspect the cleaning resin, and slightly poor what compare aspect the cleaning greasy dirt.
Description of drawings:
Accompanying drawing is preparation technology's schema of the present invention.
The C that A is weight percentage 3-C 9Alkane;
The C that B is weight percentage 3-C 8Ketone;
The C that C is weight percentage 3-C 10Ether;
The C that D is weight percentage 1-C 3Alcohol;
E is an intermediate blend;
F is an additive;
G is a clean-out system of the present invention.
1 normal temperature and pressure stirred 30-40 minute down
2 stirred 10-20 minute
Embodiment:
Below in conjunction with the drawings and specific embodiments explanation the present invention.
Embodiment 1:A is the hexanaphthene of 70% (weight); B is the pimelinketone of 10% (weight); C is the ethylene glycol ethyl ether of 8% (weight); D is the Virahol of 10% (weight); F is the additive of 2% (weight), and additive is the mixture of trolamine and ethyl acetate.
Embodiment 2:A is the heptane of 65% (weight); B is the pimelinketone of 8% (weight); C is the butyl glycol ether of 7% (weight); D is 18.5% (weight) Virahol; F is the additive of 1.5% (weight), and additive is the mixture of trolamine and ethyl acetate.

Claims (3)

1, a kind of clean-out system that is applicable to electron trade, it comprises that composition by weight contains:
C 3-C 9Alkane 10-85%
C 3-C 8Ketone 1-30%
C 3-C 10Ether 1-30%
C 1-C 3Alcohol 1-30%
Additive 0.01-10%
2, it is characterized in that according to the described clean-out system of claim 1: alkane is naphthenic hydrocarbon or straight-chain paraffin, and ketone is naphthenone or straight alkane ketone, and ether is straight chain alkane ether, and alcohol is monohydroxy-alcohol.
3, it is characterized in that according to claim 1 or 2 described clean-out systems: additive is for containing complexing agent, inhibiter, surfactant mixtures.
CN 01128510 2001-07-25 2001-07-25 Cleaning agent Expired - Fee Related CN1232626C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 01128510 CN1232626C (en) 2001-07-25 2001-07-25 Cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 01128510 CN1232626C (en) 2001-07-25 2001-07-25 Cleaning agent

Publications (2)

Publication Number Publication Date
CN1398957A true CN1398957A (en) 2003-02-26
CN1232626C CN1232626C (en) 2005-12-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 01128510 Expired - Fee Related CN1232626C (en) 2001-07-25 2001-07-25 Cleaning agent

Country Status (1)

Country Link
CN (1) CN1232626C (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100346889C (en) * 2002-04-23 2007-11-07 索尼科环境方案公司 Sonication treatment of polychlorinated biphenyl contaminated media
CN101319171B (en) * 2008-07-23 2011-01-26 重庆四胜电气有限公司 Electrotechnical ceramic cleaning fluid
CN102660408A (en) * 2012-04-20 2012-09-12 东莞市新球清洗科技有限公司 Circuit board cleaning agent replacing trichloroethylene
CN103194331A (en) * 2013-03-29 2013-07-10 深圳市同方新源科技有限公司 Cleaning agent for electronics and preparation method thereof
CN103555447A (en) * 2013-10-30 2014-02-05 合肥市华美光电科技有限公司 Water-based computer printed circuit board cleaning agent and preparation method thereof
CN104099194A (en) * 2013-04-03 2014-10-15 东莞市剑鑫电子材料有限公司 Circuit board cleaning agent and preparation method thereof
CN105039025A (en) * 2015-06-04 2015-11-11 宁夏共享化工有限公司 Cleaning agent for cleaning 3D-type sand printing head and preparation method of cleaning agent
CN105296208A (en) * 2015-11-25 2016-02-03 深圳市裕满实业有限公司 Environment-friendly type circuit board cleaning agent and preparation method thereof
CN108531303A (en) * 2017-08-23 2018-09-14 长沙普济生物科技股份有限公司 A kind of agent for carbon hydrogen detergent and preparation method containing acyl amino acids surfactant
CN105802758B (en) * 2016-05-17 2019-04-05 江苏筑磊电子科技有限公司 Cleaning Agent for PCB agent after fire
CN109576089A (en) * 2018-12-31 2019-04-05 广东新球清洗科技股份有限公司 Pcb board ultrasound agent for carbon hydrogen detergent and its application method
CN111073776A (en) * 2019-12-25 2020-04-28 广东好顺欧迪斯科技股份有限公司 Clearing agent composition and application thereof
CN111117816A (en) * 2019-12-31 2020-05-08 苏州市晶协高新电子材料有限公司 Novel welding slag cleaning agent and preparation method thereof
CN112877143A (en) * 2021-01-22 2021-06-01 盐城市贝加尔电子材料有限公司 Preparation method of acidic degreasing agent for PCB (printed circuit board)
CN113150883A (en) * 2021-04-26 2021-07-23 山东京博石油化工有限公司 Environment-friendly aerosol for vehicles and preparation method thereof
CN113604292A (en) * 2021-09-13 2021-11-05 常州智高化学科技有限公司 Modified alcohol detergent and preparation method thereof

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100346889C (en) * 2002-04-23 2007-11-07 索尼科环境方案公司 Sonication treatment of polychlorinated biphenyl contaminated media
CN101319171B (en) * 2008-07-23 2011-01-26 重庆四胜电气有限公司 Electrotechnical ceramic cleaning fluid
CN102660408A (en) * 2012-04-20 2012-09-12 东莞市新球清洗科技有限公司 Circuit board cleaning agent replacing trichloroethylene
CN103194331A (en) * 2013-03-29 2013-07-10 深圳市同方新源科技有限公司 Cleaning agent for electronics and preparation method thereof
CN104099194A (en) * 2013-04-03 2014-10-15 东莞市剑鑫电子材料有限公司 Circuit board cleaning agent and preparation method thereof
CN103555447A (en) * 2013-10-30 2014-02-05 合肥市华美光电科技有限公司 Water-based computer printed circuit board cleaning agent and preparation method thereof
CN105039025A (en) * 2015-06-04 2015-11-11 宁夏共享化工有限公司 Cleaning agent for cleaning 3D-type sand printing head and preparation method of cleaning agent
CN105296208A (en) * 2015-11-25 2016-02-03 深圳市裕满实业有限公司 Environment-friendly type circuit board cleaning agent and preparation method thereof
CN105802758B (en) * 2016-05-17 2019-04-05 江苏筑磊电子科技有限公司 Cleaning Agent for PCB agent after fire
CN108531303A (en) * 2017-08-23 2018-09-14 长沙普济生物科技股份有限公司 A kind of agent for carbon hydrogen detergent and preparation method containing acyl amino acids surfactant
CN109576089A (en) * 2018-12-31 2019-04-05 广东新球清洗科技股份有限公司 Pcb board ultrasound agent for carbon hydrogen detergent and its application method
CN111073776A (en) * 2019-12-25 2020-04-28 广东好顺欧迪斯科技股份有限公司 Clearing agent composition and application thereof
CN111117816A (en) * 2019-12-31 2020-05-08 苏州市晶协高新电子材料有限公司 Novel welding slag cleaning agent and preparation method thereof
CN112877143A (en) * 2021-01-22 2021-06-01 盐城市贝加尔电子材料有限公司 Preparation method of acidic degreasing agent for PCB (printed circuit board)
CN113150883A (en) * 2021-04-26 2021-07-23 山东京博石油化工有限公司 Environment-friendly aerosol for vehicles and preparation method thereof
CN113604292A (en) * 2021-09-13 2021-11-05 常州智高化学科技有限公司 Modified alcohol detergent and preparation method thereof

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PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
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GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: CHENZHOU JINJIAN SOLDER LTD.

Free format text: FORMER OWNER: DENG HESHENG

Effective date: 20090626

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20090626

Address after: Science and Technology Industrial Zone, Chenzhou Development Zone, Hunan

Patentee after: Chenzhou Gold Arrow Solder Co., Ltd.

Address before: Hunan city in Chenzhou Province Economic and Technological Development Zone Wan Hua Lu Chenzhou Jinjian solder Co Ltd

Patentee before: Deng Hesheng

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20051221

Termination date: 20150725

EXPY Termination of patent right or utility model