CN113604292A - Modified alcohol detergent and preparation method thereof - Google Patents
Modified alcohol detergent and preparation method thereof Download PDFInfo
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- CN113604292A CN113604292A CN202111067467.4A CN202111067467A CN113604292A CN 113604292 A CN113604292 A CN 113604292A CN 202111067467 A CN202111067467 A CN 202111067467A CN 113604292 A CN113604292 A CN 113604292A
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- 150000001298 alcohols Chemical class 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003599 detergent Substances 0.000 title claims description 17
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000012459 cleaning agent Substances 0.000 claims abstract description 40
- 239000002519 antifouling agent Substances 0.000 claims abstract description 31
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 28
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 25
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims abstract description 23
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 23
- 229950011008 tetrachloroethylene Drugs 0.000 claims abstract description 23
- 239000003381 stabilizer Substances 0.000 claims abstract description 18
- 229920001529 polyepoxysuccinic acid Polymers 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229940043237 diethanolamine Drugs 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims description 182
- 238000006243 chemical reaction Methods 0.000 claims description 56
- 239000000203 mixture Substances 0.000 claims description 31
- 239000003921 oil Substances 0.000 claims description 20
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 16
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- 239000011737 fluorine Substances 0.000 claims description 14
- -1 polysiloxane Polymers 0.000 claims description 14
- 230000007797 corrosion Effects 0.000 claims description 12
- 238000005260 corrosion Methods 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 9
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 7
- 244000060011 Cocos nucifera Species 0.000 claims description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 150000001408 amides Chemical class 0.000 claims description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 239000002199 base oil Substances 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 229960001545 hydrotalcite Drugs 0.000 claims description 5
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 5
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 claims description 5
- 239000003208 petroleum Substances 0.000 claims description 5
- 150000008301 phosphite esters Chemical class 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 230000003373 anti-fouling effect Effects 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 230000002035 prolonged effect Effects 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000003111 delayed effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/181—Hydrocarbons linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/185—Hydrocarbons cyclic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/187—Hydrocarbons aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
- C11D3/245—Organic compounds containing halogen containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a modified alcohol cleaning agent and a preparation method thereof, relating to the technical field of cleaning agents, and the technical scheme is as follows: the compound feed comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 8 g-10 g of water, 2 g-8 g of modified methanol, 2 g-4 g of alkane, 1 g-2 g of cyclane, 2 g-3 g of aromatic hydrocarbon, 1 g-3 g of tetrachloroethylene, 2 g-4 g of n-hexane, 1 g-3 g of freon and 1 g-2 g of butanone, wherein the auxiliary materials (by weight) comprise: 4-6 g of cocoyl diethanol amine, 6-8 g of polyepoxysuccinic acid, 4-8 g of an anti-fouling agent, 8-10 g of antirust oil, 2-6 g of a stabilizer and 2-4 g of a nonionic surfactant, and the modified alcohol cleaning agent and the preparation method thereof have the beneficial effects that: through the cocoyl diethanol amine, the polyepoxysuccinic acid and the anti-fouling agent, the anti-fouling performance of the part can be improved, and the rusting time of the part can be delayed, so that the use performance of the part can be improved, and the service life of the part can be prolonged.
Description
Technical Field
The invention relates to the technical field of cleaning agents, and particularly relates to a modified alcohol cleaning agent and a preparation method thereof.
Background
The cleaning agent is a large category and various types, including inorganic cleaning and organic cleaning, and the difference between the organic cleaning agent and the inorganic cleaning agent is that the organic cleaning agent is a cleaning agent made of a carbon-containing compound, and the inorganic cleaning agent is a cleaning agent made of a carbon-free compound, so that the organic cleaning agent and the inorganic cleaning agent belong to inorganic matters, the classification methods of the cleaning agents are various and different from each country, and the cleaning agents are generally classified into three types, namely water-based cleaning agent, semi-water-based cleaning agent and non-water-based cleaning agent, and the industrial cleaning agents are chemical or biological agents used in industry for removing dirt and are collectively called industrial cleaning agents.
The prior art has the following defects: after most of the existing cleaning agents are used, the cleaned parts are easy to be stained with oil stains and rusted, so that inconvenience is brought to users, and the use performance of the parts is affected.
Therefore, it is necessary to develop a modified alcohol detergent and a process for producing the same.
Disclosure of Invention
The invention provides a modified alcohol cleaning agent and a preparation method thereof, wherein water, modified methanol, alkane, cycloparaffin, aromatic hydrocarbon, tetrachloroethylene, normal hexane, freon and butanone are selected as raw materials, cocoyl diethanol amine, polyepoxysuccinic acid, an anti-fouling agent, anti-rust oil, a stabilizer and a nonionic surfactant are selected as auxiliary materials, and then the auxiliary materials are proportioned according to a certain proportion, so that the problems that the cleaned parts are easy to be stained with oil stains and rusty stains after most of the existing cleaning agents are used are solved.
In order to achieve the above purpose, the invention provides the following technical scheme: a modified alcohol cleaning agent comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 8 g-10 g of water, 2 g-8 g of modified methanol, 2 g-4 g of alkane, 1 g-2 g of cyclane, 2 g-3 g of aromatic hydrocarbon, 1 g-3 g of tetrachloroethylene, 2 g-4 g of n-hexane, 1 g-3 g of freon and 1 g-2 g of butanone, wherein the auxiliary materials (by weight) comprise: 4-6 g of coconut diethanol amide, 6-8 g of polyepoxysuccinic acid, 4-8 g of an anti-fouling agent, 8-10 g of antirust oil, 2-6 g of a stabilizer and 2-4 g of a nonionic surfactant.
Preferably, the anti-fouling agent is one or a mixture of fluorine modified siloxane and fluorine alkyl polyether modified polysiloxane.
Preferably, the anti-rust oil consists of a corrosion inhibitor and base oil, wherein the corrosion inhibitor is one or a mixture of lead naphthenate, zinc naphthenate and petroleum sodium sulfonate.
Preferably, the stabilizer is one or a mixture of phosphite ester, antioxidant and hydrotalcite.
Preferably, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil and fatty alcohol-polyoxyethylene ether.
The preparation method of the modified alcohol detergent comprises the following specific steps:
s1, adding water and modified methanol into a reaction kettle for stirring, and adding alkane into the reaction kettle for stirring after stirring;
s2, adding the naphthenic hydrocarbon and the aromatic hydrocarbon into a reaction kettle for stirring, and after stirring, adding the tetrachloroethylene into the reaction kettle for stirring;
s3, adding n-hexane and freon into a reaction kettle for stirring, and after stirring, adding butanone into the reaction kettle for stirring;
s4, adding the cocoyl diethanol amine and the polyepoxysuccinic acid into a reaction kettle for stirring, and after stirring, adding the anti-fouling agent into the reaction kettle for stirring;
s5, placing the anti-rust oil and the stabilizer into a reaction kettle for stirring, and then placing the nonionic surfactant into the reaction kettle for stirring after stirring;
s6, the mixture of S1, S2, S3, S4 and S5 is put into a reaction kettle in sequence and stirred to obtain the detergent.
Preferably, in the step S1, the stirring temperature without adding alkane is 60-70 ℃, the stirring time is 20-30 min, the stirring temperature after adding alkane is 50-60 ℃, and the stirring time is 30-35 min.
Preferably, in the step S2, the stirring temperature without adding tetrachloroethylene is 60-65 ℃, the stirring time is 15-20 min, the stirring temperature after adding tetrachloroethylene is 52-56 ℃, and the stirring time is 25-30 min;
in the step S3, the stirring temperature without butanone is 70-75 ℃, the stirring time is 30-40 min, the stirring temperature after butanone is added is 70-75 ℃, and the stirring time is 30-40 min.
Preferably, in the step S4, the stirring temperature without the anti-fouling agent is 320-400 ℃, the stirring time is 60-70 min, the stirring temperature after the anti-fouling agent is added is 300-320 ℃, and the stirring time is 20-25 min.
Preferably, in the step S5, the stirring temperature without the nonionic surfactant is 340-360 ℃, the stirring time is 35-40 min, the stirring temperature after the nonionic surfactant is added is 340-360 ℃, and the stirring time is 35-40 min;
in the step S6, the stirring temperature is 380-400 ℃, and the stirring time is 55-60 min.
The invention has the beneficial effects that:
1. the coconut diethanol amide has the function of improving the detergency and the rust resistance of the cleaning agent;
2. the polyepoxysuccinic acid has the function of inhibiting corrosion of parts, so that the service life of the parts is prolonged;
3. the anti-fouling agent has the function of improving the high-temperature resistance and the anti-fouling performance of the cleaning agent;
4. through the cocoyl diethanol amine, the polyepoxysuccinic acid and the anti-fouling agent, the anti-fouling performance of the part can be improved, and the rusting time of the part can be delayed, so that the use performance of the part can be improved, and the service life of the part can be prolonged.
Detailed Description
The following description of the preferred embodiments of the present invention is provided for the purpose of illustration and description, and is in no way intended to limit the invention.
Example 1:
the invention provides a modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 8g of water, 2g of modified methanol, 2g of alkane, 1g of cyclane, 2g of aromatic hydrocarbon, 1g of tetrachloroethylene, 2g of n-hexane, 1g of freon and 1g of butanone, wherein the auxiliary materials (by weight) comprise: 4g of coconut diethanol amide, 6g of polyepoxysuccinic acid, 4g of an anti-fouling agent, 8g of antirust oil, 2g of a stabilizer and 2g of a nonionic surfactant;
furthermore, the coco-diethanol amide is prepared by the reaction of coconut oleic acid and diethanol amine, is an amber viscous liquid, and has strong foaming power, penetration power, detergency, antirust power, good dispersibility and the like;
the polyepoxysuccinic acid is a nitrogen-free and non-phosphorus organic compound and has double effects of scale inhibition and corrosion inhibition.
Further, the anti-fouling agent is one or a mixture of more of fluorine modified siloxane and fluorine alkyl polyether modified polysiloxane, specifically, the fluorine modified siloxane is named organic fluorine modified polysiloxane, is a special modified silicon and fluorine composition, and has the effects of high temperature resistance and oil resistance;
the fluorine-based alkyl polyether modified polysiloxane is a chemical substance, consists of alkyl polyether modified fluorine-containing polydimethylsiloxane and has an antifouling effect.
Further, the anti-rust oil consists of a corrosion inhibitor and base oil, wherein the corrosion inhibitor is one or a mixture of lead naphthenate, zinc naphthenate and petroleum sodium sulfonate.
Further, the stabilizer is one or a mixture of phosphite ester, antioxidant and hydrotalcite.
Further, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil and fatty alcohol-polyoxyethylene ether.
The preparation method of the modified alcohol detergent comprises the following specific steps:
s1, adding water and modified methanol into a reaction kettle, stirring, and then adding alkane into the reaction kettle, stirring, wherein the stirring temperature of the mixture without the alkane is 60 ℃, the stirring time is 20min, the stirring temperature of the mixture after the alkane is added is 50 ℃, and the stirring time is 30 min;
s2, adding the naphthenic hydrocarbon and the aromatic hydrocarbon into a reaction kettle, stirring, adding tetrachloroethylene into the reaction kettle, and stirring, wherein the stirring temperature of the tetrachloroethylene which is not added is 60 ℃, the stirring time is 15min, the stirring temperature of the tetrachloroethylene which is added is 52 ℃, and the stirring time is 25 min;
s3, placing n-hexane and freon into a reaction kettle for stirring, and after stirring, placing butanone into the reaction kettle for stirring, wherein the stirring temperature when butanone is not placed is 70 ℃, the stirring time is 30min, and the stirring temperature when butanone is placed is 70 ℃, and the stirring time is 30 min;
s4, adding cocoyl diethanol amine and polyepoxysuccinic acid into a reaction kettle for stirring, and after stirring, adding the anti-fouling agent into the reaction kettle for stirring, wherein the stirring temperature when the anti-fouling agent is not added is 320 ℃, the stirring time is 60min, the stirring temperature when the anti-fouling agent is added is 300 ℃, and the stirring time is 20 min;
s5, placing the anti-rust oil and the stabilizer into a reaction kettle for stirring, and after stirring, placing the nonionic surfactant into the reaction kettle for stirring, wherein the stirring temperature when the nonionic surfactant is not placed is 340 ℃, the stirring time is 35min, the stirring temperature after the nonionic surfactant is placed is 340 ℃, and the stirring time is 35 min;
s6, sequentially putting the mixture of S1, S2, S3, S4 and S5 into a reaction kettle, and stirring to obtain the detergent, wherein the stirring temperature is 380 ℃ and the stirring time is 55 min.
Example 2:
the invention provides a modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 9g of water, 5g of modified methanol, 3g of alkane, 1.5g of cyclane, 2.5g of aromatic hydrocarbon, 2g of tetrachloroethylene, 3g of n-hexane, 2g of freon and 1.5g of butanone, wherein the auxiliary materials (by weight) comprise: 5g of coconut diethanol amide, 7g of polyepoxysuccinic acid, 6g of an anti-fouling agent, 9g of antirust oil, 4g of a stabilizer and 3g of a nonionic surfactant.
Further, the anti-fouling agent is one or a mixture of more of fluorine modified siloxane and fluorine alkyl polyether modified polysiloxane.
Further, the anti-rust oil consists of a corrosion inhibitor and base oil, wherein the corrosion inhibitor is one or a mixture of lead naphthenate, zinc naphthenate and petroleum sodium sulfonate.
Further, the stabilizer is one or a mixture of phosphite ester, antioxidant and hydrotalcite.
Further, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil and fatty alcohol-polyoxyethylene ether.
The preparation method of the modified alcohol detergent comprises the following specific steps:
s1, adding water and modified methanol into a reaction kettle, stirring, adding alkane into the reaction kettle, and stirring, wherein the stirring temperature of the alkane not added is 65 ℃, the stirring time is 25min, the stirring temperature of the alkane added is 55 ℃, and the stirring time is 32.5 min;
s2, adding the naphthenic hydrocarbon and the aromatic hydrocarbon into a reaction kettle, stirring, adding tetrachloroethylene into the reaction kettle, and stirring, wherein the stirring temperature of the tetrachloroethylene which is not added is 62.5 ℃, the stirring time is 17.5min, the stirring temperature of the tetrachloroethylene which is added is 54 ℃, and the stirring time is 27.5 min;
s3, placing n-hexane and freon into a reaction kettle for stirring, and after stirring, placing butanone into the reaction kettle for stirring, wherein the stirring temperature when butanone is not placed is 72.5 ℃, the stirring time is 35min, the stirring temperature when butanone is placed is 72.5 ℃, and the stirring time is 35 min;
s4, adding cocoyl diethanol amine and polyepoxysuccinic acid into a reaction kettle for stirring, and after stirring, adding the anti-fouling agent into the reaction kettle for stirring, wherein the stirring temperature when the anti-fouling agent is not added is 360 ℃, the stirring time is 65min, the stirring temperature when the anti-fouling agent is added is 310 ℃, and the stirring time is 22.5 min;
s5, placing the anti-rust oil and the stabilizer into a reaction kettle for stirring, and after stirring, placing the nonionic surfactant into the reaction kettle for stirring, wherein the stirring temperature when the nonionic surfactant is not placed is 350 ℃, the stirring time is 37.5min, the stirring temperature when the nonionic surfactant is placed is 350 ℃, and the stirring time is 37.5 min;
s6, sequentially putting the mixture of S1, S2, S3, S4 and S5 into a reaction kettle, and stirring to obtain the detergent, wherein the stirring temperature is 390 ℃, and the stirring time is 57.5 min.
Example 3:
the invention provides a modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 10g of water, 8g of modified methanol, 4g of alkane, 2g of cyclane, 3g of aromatic hydrocarbon, 3g of tetrachloroethylene, 4g of n-hexane, 3g of freon and 2g of butanone, wherein the auxiliary materials (by weight) comprise: 6g of coconut diethanol amide, 8g of polyepoxysuccinic acid, 8g of an anti-fouling agent, 10g of antirust oil, 6g of a stabilizer and 4g of a nonionic surfactant.
Further, the anti-fouling agent is one or a mixture of more of fluorine modified siloxane and fluorine alkyl polyether modified polysiloxane.
Further, the anti-rust oil consists of a corrosion inhibitor and base oil, wherein the corrosion inhibitor is one or a mixture of lead naphthenate, zinc naphthenate and petroleum sodium sulfonate.
Further, the stabilizer is one or a mixture of phosphite ester, antioxidant and hydrotalcite.
Further, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil and fatty alcohol-polyoxyethylene ether.
The preparation method of the modified alcohol detergent comprises the following specific steps:
s1, adding water and modified methanol into a reaction kettle, stirring, and then adding alkane into the reaction kettle, stirring, wherein the stirring temperature of the mixture without the alkane is 70 ℃, the stirring time is 30min, the stirring temperature of the mixture after the alkane is added is 60 ℃, and the stirring time is 35 min;
s2, adding the naphthenic hydrocarbon and the aromatic hydrocarbon into a reaction kettle, stirring, adding tetrachloroethylene into the reaction kettle, and stirring, wherein the stirring temperature of the tetrachloroethylene without being added is 65 ℃, the stirring time is 20min, the stirring temperature of the tetrachloroethylene after being added is 56 ℃, and the stirring time is 30 min;
s3, placing n-hexane and freon into a reaction kettle for stirring, and after stirring, placing butanone into the reaction kettle for stirring, wherein the stirring temperature when butanone is not placed is 75 ℃, the stirring time is 40min, and the stirring temperature when butanone is placed is 75 ℃, and the stirring time is 40 min;
s4, adding cocoyl diethanol amine and polyepoxysuccinic acid into a reaction kettle for stirring, and after stirring, adding the anti-fouling agent into the reaction kettle for stirring, wherein the stirring temperature when the anti-fouling agent is not added is 400 ℃, the stirring time is 70min, the stirring temperature when the anti-fouling agent is added is 320 ℃, and the stirring time is 25 min;
s5, placing the anti-rust oil and the stabilizer into a reaction kettle for stirring, and after stirring, placing the nonionic surfactant into the reaction kettle for stirring, wherein the stirring temperature when the nonionic surfactant is not placed is 360 ℃, the stirring time is 40min, the stirring temperature after the nonionic surfactant is placed is 360 ℃, and the stirring time is 40 min;
s6, sequentially putting the mixture of S1, S2, S3, S4 and S5 into a reaction kettle, and stirring to obtain the detergent, wherein the stirring temperature is 400 ℃, and the stirring time is 60 min.
The following data were obtained by comparing the detergents prepared in examples 1 to 3 above:
as can be seen from the above table, the cleaning agent prepared in examples 1-3 has better performances in terms of cleaning effect, rust resistance and anti-fouling performance, but the cleaning agent has different effects in terms of cleaning effect, rust resistance and anti-fouling performance due to different proportions of water, modified methanol, alkane, cycloalkane, aromatic hydrocarbon, tetrachloroethylene, n-hexane, freon, butanone, cocoyl diethanolamine, polyepoxysuccinic acid, anti-fouling agent, anti-rust oil, stabilizer and nonionic surfactant, and after the cleaning agent is used, the cleaning agent in example 2 has the best effect, and also has efficient rust resistance and anti-fouling performance in terms of efficient cleaning effect.
The above description is only a preferred embodiment of the present invention, and any person skilled in the art may modify the present invention or modify it into an equivalent technical solution by using the technical solution described above. Therefore, any simple modifications or equivalent substitutions made in accordance with the technical solution of the present invention are within the scope of the claims of the present invention.
Claims (10)
1. The modified alcohol cleaning agent comprises raw materials and auxiliary materials, and is characterized in that: the raw materials (by weight) comprise: 8 g-10 g of water, 2 g-8 g of modified methanol, 2 g-4 g of alkane, 1 g-2 g of cyclane, 2 g-3 g of aromatic hydrocarbon, 1 g-3 g of tetrachloroethylene, 2 g-4 g of n-hexane, 1 g-3 g of freon and 1 g-2 g of butanone, wherein the auxiliary materials (by weight) comprise: 4-6 g of coconut diethanol amide, 6-8 g of polyepoxysuccinic acid, 4-8 g of an anti-fouling agent, 8-10 g of antirust oil, 2-6 g of a stabilizer and 2-4 g of a nonionic surfactant.
2. A modified alcohol cleaning agent according to claim 1, wherein: the anti-fouling agent is one or a mixture of more of fluorine modified siloxane and fluorine alkyl polyether modified polysiloxane.
3. A modified alcohol cleaning agent according to claim 1, wherein: the anti-rust oil consists of a corrosion inhibitor and base oil, wherein the corrosion inhibitor is one or a mixture of lead naphthenate, zinc naphthenate and petroleum sodium sulfonate.
4. A modified alcohol cleaning agent according to claim 1, wherein: the stabilizer is one or a mixture of phosphite ester, antioxidant and hydrotalcite.
5. A modified alcohol cleaning agent according to claim 1, wherein: the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil and fatty alcohol-polyoxyethylene ether.
6. A preparation method of a modified alcohol cleaning agent is characterized by comprising the following steps: the method comprises the following specific steps:
s1, adding water and modified methanol into a reaction kettle for stirring, and adding alkane into the reaction kettle for stirring after stirring;
s2, adding the naphthenic hydrocarbon and the aromatic hydrocarbon into a reaction kettle for stirring, and after stirring, adding the tetrachloroethylene into the reaction kettle for stirring;
s3, adding n-hexane and freon into a reaction kettle for stirring, and after stirring, adding butanone into the reaction kettle for stirring;
s4, adding the cocoyl diethanol amine and the polyepoxysuccinic acid into a reaction kettle for stirring, and after stirring, adding the anti-fouling agent into the reaction kettle for stirring;
s5, placing the anti-rust oil and the stabilizer into a reaction kettle for stirring, and then placing the nonionic surfactant into the reaction kettle for stirring after stirring;
s6, the mixture of S1, S2, S3, S4 and S5 is put into a reaction kettle in sequence and stirred to obtain the detergent.
7. The process according to claim 6, wherein said alcohol-modified detergent comprises: in the step S1, the stirring temperature of the mixture without the alkane is 60-70 ℃, the stirring time is 20-30 min, the stirring temperature after the alkane is added is 50-60 ℃, and the stirring time is 30-35 min.
8. The process according to claim 6, wherein said alcohol-modified detergent comprises: in the step S2, the stirring temperature without adding tetrachloroethylene is 60-65 ℃, the stirring time is 15-20 min, the stirring temperature after adding tetrachloroethylene is 52-56 ℃, and the stirring time is 25-30 min;
in the step S3, the stirring temperature without butanone is 70-75 ℃, the stirring time is 30-40 min, the stirring temperature after butanone is added is 70-75 ℃, and the stirring time is 30-40 min.
9. The process according to claim 6, wherein said alcohol-modified detergent comprises: in the step S4, the stirring temperature without the anti-fouling agent is 320-400 ℃, the stirring time is 60-70 min, the stirring temperature after the anti-fouling agent is added is 300-320 ℃, and the stirring time is 20-25 min.
10. The process according to claim 6, wherein said alcohol-modified detergent comprises: in the step S5, the stirring temperature without the nonionic surfactant is 340-360 ℃, the stirring time is 35-40 min, the stirring temperature after the nonionic surfactant is added is 340-360 ℃, and the stirring time is 35-40 min;
in the step S6, the stirring temperature is 380-400 ℃, and the stirring time is 55-60 min.
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