CN1397425A - Strengthened artificial granite - Google Patents
Strengthened artificial granite Download PDFInfo
- Publication number
- CN1397425A CN1397425A CN 02133612 CN02133612A CN1397425A CN 1397425 A CN1397425 A CN 1397425A CN 02133612 CN02133612 CN 02133612 CN 02133612 A CN02133612 A CN 02133612A CN 1397425 A CN1397425 A CN 1397425A
- Authority
- CN
- China
- Prior art keywords
- layer
- aggregate
- room temperature
- raw materials
- gloss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010438 granite Substances 0.000 title claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004579 marble Substances 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 6
- 239000003086 colorant Substances 0.000 claims abstract description 4
- 239000003063 flame retardant Substances 0.000 claims abstract description 4
- 238000012423 maintenance Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002969 artificial stone Substances 0.000 claims description 6
- 230000002787 reinforcement Effects 0.000 claims description 6
- 238000005266 casting Methods 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000003469 silicate cement Substances 0.000 claims description 4
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical group CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 3
- 238000007688 edging Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000005357 flat glass Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical group CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- -1 promoter Substances 0.000 abstract description 2
- 230000002285 radioactive effect Effects 0.000 abstract description 2
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 abstract 2
- 239000004568 cement Substances 0.000 abstract 1
- 239000002932 luster Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 241000109329 Rosa xanthina Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006063 cullet Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
A strengthened artificial granite is composed of lustre layer, aggregate layer and stuck layer. Its raw materials include solution of resin "196" in acetone, solidifying agent, promoter, fire retardant, broken marble with different colors, broken glass and high-grade cement. Its advantages are high surface lustre, smooth surface, not decoloring, and no radioactive elements.
Description
One, technical field
The invention belongs to building and ornament materials, be specifically related to a kind of artificial stone and manufacture method thereof.
Two, background technology
At present, multiple artificial stone is arranged on the market, they are not all roses on serviceability, are exactly that cost is too high.The Chinese invention patent application that have a publication number October 4 nineteen ninety-five is CN1109545A is open, it is a kind of artificial granite decorative plate, be No. 307 resins and/or No. 191 resins to be dissolved in the solution that styrene makes with polystyrene carry out modification, add filler aggregates such as curing agent, promoter and calcite, marble particle, silicon ash again and mix cast molding.This artificial granite flag has higher intensity and hardness, be fit to make the decoration on outdoor metope and ground, but it exists following defective: what it adopted is one-time formed technology, the surperficial poor transparency that causes the artificial stone, decorative pattern lacks third dimension, and the color and luster instability, also easy rake angle aliquation; Not having the lattice of stickup because of the bottom surface in addition makes stickup inconvenient.
Three, summary of the invention
The objective of the invention is at above-mentioned the deficiencies in the prior art, adopt different formula for raw stock and preparation technology, produce a kind of strengthened artificial granite material, make it more perfect on various serviceabilities such as brightness, color and luster figure line and weatherability, cost low and paste convenient, can be widely used in indoor and outdoor building element and furniture platform and industrial art and decorate, increase noble elegant style to people's life.
Realize purpose of the present invention by the following technical solutions.
A kind of strengthened artificial granite is made up of gloss layer, aggregate layer and adhered layer three-decker, it is characterized in that:
1) the raw materials used weight portion proportioning of gloss layer is: 196 resin solution 70.00-80.00 parts, curing agent 1.5-2.5 part, promoter 1.5-2.5 part, fire retardant 0.5-1.0 part; The raw materials used weight portion proportioning of aggregate layer is: 196 resin solution 230-250 parts, curing agent 4.0-5.0 part, promoter 4.0-5.0 part, marble particle 900-1000 part of all kinds, glass crushed aggregate 200-300 part; Adhered layer is 1300 parts of the conventional concrete of high grade silicate cement; Weight ratio between three layers of mixed ingredients is a gloss layer: aggregate layer: adhered layer=1: 18: 18;
2) manufacture method is that three-decker is divided three casting, earlier be mixed with uniform compound by weight ratio with gloss layer is raw materials used, sending into the base plate of getting ready in advance is in the mould of smooth thick plate glass, and mix shaken up on glass plate, at room temperature kept flat maintenance 10-30 minute, and made it to solidify to form gloss layer; Make uniform compound by weight ratio with aggregate layer is raw materials used again, insert on the gloss layer in the mould, and evenly vibrate 3-5 minute, at room temperature kept flat maintenance 15-40 minute, form and solidify and the aggregate layer of viscosity slightly; Place the bar-mat reinforcement of the φ 3.0-6.5mm of a respective area again on the aggregate layer surface, the conventional concrete mixture of high grade silicate cement is poured on rolls out the stickup lattice after evenly being vibrated to the concrete primary solidification on the bar-mat reinforcement, at room temperature kept flat maintenance 48-72 hour; The demoulding then, corner cut edging are placed on by glassy surface the artificial stone of moulding and inflate pressurization in the mutual press to glassy surface, pressed mutually 5-7 days, put into the maintenance of room temperature pond at last 7 days, to eliminate internal stress.
Strengthened artificial granite of the present invention, its feature also is: 196 resin solutions do with acetone preferably that the solvent of 196 resins makes; Used curing agent is methyl ethyl ketone peroxide preferably, and used promoter is cobalt naphthenate preferably.
Strengthened artificial flower steel stone of the present invention when not adding colorant in addition, sees through transparent gloss layer, presents relief natural marble color and luster figure line; Also can in the aggregate filler, add micro-colorant toning, perhaps on the gloss layer of first one-step forming, cover pre-designed scenery with hills and waters calligraphy and painting pattern, the aggregate layer of casting again according to the demand in user or market.
Stonite of the present invention, surface gloss is more than 90, color and luster figure line is uniform and stable, place in the open never fade, matting; Its flatness height, anhydrous seam crackle, and also anti-skidding; After testing, it does not contain any harmful radioactive element; Test block was soaked respectively 24 hours in 3% acid solution and 3% aqueous slkali, and its upper surface does not have corrosion; Strengthened artificial granite of the present invention, cost is low, and its price has only famous brand natural granite or import artificial granitic 1/3rd; Dress pastes convenient, can directly adorn to be attached to metope and must not beat hook.Strengthened artificial granite of the present invention, can substitute natural granite popular on the current market, marble, mosaic tile, ceramic granite and other artificial stone fully, can be widely used as the decoration of indoor and outdoor building element, furniture table-board and workmanship, give people with noble elegant sense organ.
Four, the specific embodiment
Below, further specify the specific embodiment of the present invention with a kind of preparation process of strengthened artificial granite trial-production piece.
Will be with 196 resin solution 700g of acetone solvent modulation, methyl ethyl ketone peroxide 15g, cobalt naphthenate 15g and fire retardant 5g, mixing and stirring, sending into the base plate of getting ready in advance is in the mould of smooth thick plate glass, and mix shaken up on glass, mould was kept flat at room temperature maintenance 10-30 minute, make it to solidify to form gloss layer; Get 196 same resin solution 2300g again, above-mentioned curing agent 40g, above-mentioned promoter 40g, natural marble particle 9000g of all kinds, cullet 2000g mixing and stirring, insert on the gloss layer in the mould, and evenly vibrate 5 minutes, keep flat maintenance at room temperature to the aggregate layer " receipts sweat " that forms and be not clamminess; Place the φ 3.0mm bar-mat reinforcement of a respective area on the aggregate layer surface again, conventional concrete mixture 13000g with No. 525 portland cements is poured on the bar-mat reinforcement then, evenly be vibrated to and roll out the stickup lattice after concrete is received sweat, at room temperature kept flat maintenance 60 hours, the demoulding then, corner cut edging, concora crush is put into room temperature pond maintenance 7 days after 5 days, promptly get qualified strengthened artificial granite plate product.
Claims (3)
1, a kind of strengthened artificial granite is made up of gloss layer, aggregate layer and adhered layer three-decker, it is characterized in that:
1) the raw materials used weight portion proportioning of gloss layer is: 196 resin solution 70.00-80.00 parts, curing agent 1.5-2.5 part, promoter 1.5-2.5 part, fire retardant 0.5-1.0 part; The raw materials used weight portion proportioning of aggregate layer is: 196 resin solution 230-250 parts, curing agent 4.0-5.0 part, promoter 4.0-5.0 part, marble particle 900-1000 part of all kinds, glass crushed aggregate 200-300 part; Adhered layer is 1300 parts of the conventional concrete of high grade silicate cement; Weight ratio between three layers of mixed ingredients is a gloss layer: aggregate layer: adhered layer=1: 18: 18;
2) manufacture method is that three-decker is divided three casting, earlier be mixed with uniform compound by weight ratio with gloss layer is raw materials used, sending into the base plate of getting ready in advance is in the mould of smooth thick plate glass, and mix shaken up on glass plate, at room temperature kept flat maintenance 10-30 minute, and made it to solidify to form gloss layer; Make uniform compound by weight ratio with aggregate layer is raw materials used again, insert on the gloss layer in the mould, and evenly vibrate 3-5 minute, at room temperature kept flat maintenance 15-40 minute, form and solidify and the aggregate layer of viscosity slightly; Place the bar-mat reinforcement of the φ 3.0-6.5mm of a respective area again on the aggregate layer surface, the conventional concrete mixture of high grade silicate cement is poured on rolls out the stickup lattice after evenly being vibrated to the concrete primary solidification on the bar-mat reinforcement, at room temperature kept flat maintenance 48-72 hour; The demoulding then, corner cut edging are placed on by glassy surface the artificial stone of moulding and inflate pressurization in the mutual press to glassy surface, pressed mutually 5-7 days, put into the maintenance of room temperature pond at last 7 days.
2, according to the described strengthened artificial granite of claim 1, its feature also is: said 196 resin solutions are to make with the solvent that acetone is made 196 resins; Said curing agent is a methyl ethyl ketone peroxide; Said promoter is cobalt naphthenate.
3, according to the described strengthened artificial granite of claim 1, its feature also is: add micro-colorant toning as required in the aggregate filler; Perhaps on the gloss layer of first one-step forming, cover pre-designed scenery with hills and waters calligraphy and painting pattern, the aggregate layer of casting again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02133612 CN1238183C (en) | 2002-08-13 | 2002-08-13 | Strengthened artificial granite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02133612 CN1238183C (en) | 2002-08-13 | 2002-08-13 | Strengthened artificial granite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1397425A true CN1397425A (en) | 2003-02-19 |
| CN1238183C CN1238183C (en) | 2006-01-25 |
Family
ID=4747297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02133612 Expired - Fee Related CN1238183C (en) | 2002-08-13 | 2002-08-13 | Strengthened artificial granite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1238183C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102529556A (en) * | 2011-12-29 | 2012-07-04 | 江孟东 | Artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and preparing method thereof |
| CN105271945A (en) * | 2015-09-29 | 2016-01-27 | 广西钟山县中源石业有限公司 | Artificial granite and making method thereof |
-
2002
- 2002-08-13 CN CN 02133612 patent/CN1238183C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102529556A (en) * | 2011-12-29 | 2012-07-04 | 江孟东 | Artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and preparing method thereof |
| CN102529556B (en) * | 2011-12-29 | 2013-09-04 | 江孟东 | Artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and preparing method thereof |
| CN105271945A (en) * | 2015-09-29 | 2016-01-27 | 广西钟山县中源石业有限公司 | Artificial granite and making method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1238183C (en) | 2006-01-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: CHONGQING CITY JIUSHAN BUILDING MATERIALS CO.,LTD. Free format text: FORMER OWNER: LIU BENHE Effective date: 20090327 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20090327 Address after: C1, building -C13, glorious market, Wanzhou District, Chongqing Patentee after: Chongqing Jiushan building materials limited liability company Address before: Chongqing Wanzhou District Li River town large slope Three Gorges Project School compound Patentee before: Liu Benhe |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060125 Termination date: 20100813 |