CN100374505C - Natural texture irradiant artificial stone material and its production process - Google Patents
Natural texture irradiant artificial stone material and its production process Download PDFInfo
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- CN100374505C CN100374505C CNB200510060854XA CN200510060854A CN100374505C CN 100374505 C CN100374505 C CN 100374505C CN B200510060854X A CNB200510060854X A CN B200510060854XA CN 200510060854 A CN200510060854 A CN 200510060854A CN 100374505 C CN100374505 C CN 100374505C
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Abstract
The present invention relates to a production technology for artificial stones with natural textures and luminescence, which comprises: firstly, unsaturated resin and agate level of aluminium hydroxide with the proportion by weight of 1: (1.3 to 2.2) are mixed, natural pigments and a curing agent are added into the unsaturated resin and the agate level of aluminium hydroxide so as to make mother liquor; unsaturated resin and toothpaste level of aluminium hydroxide with the proportion by weight of 1: (1.0 to 2.0) are mixed, and natural pigments, noctilucent powder and a curing agent are added into the unsaturated resin and the toothpaste level of aluminium hydroxide so as to make son liquor; 5 to 20 wt% of son liquor is taken and poured into a stone material mold after accelerant is added into the son liquor; then 95 to 80 wt% of mother liquor is taken and poured onto a mixture of the son liquor and accelerant in the stone material mold and is then put into a vacuum box for pumping air after the accelerant is added into the mother liquor; the stone material mold is then taken out and is solidified after pumping the air, and finally, the artificial stones with natural textures and luminescence are made by mold stripping and grinding. The production technology is simple, and the made artificial stones have the same inside natural textures and outside natural textures, beautiful and difficultly damaged textures and capacity of energy storage and light emission and is widely applied to the fields of decoration, gardens, bridge railings, etc.
Description
One, technical field
The present invention relates to a kind of building and ornament materials, specifically relate to luminous artificial stone-like material of a kind of energy and production technique thereof.
Two, background technology
Chinese invention patent ublic specification of application CN 1453301A (open day: on November 5th, 2003, application number 02111433.1) a kind of luminous artificial slabstone and production method thereof are disclosed, this production method comprises light-accumulated luminous grain granulation operation, making sheet operation, the stone slab that makes can send brighter light voluntarily, and can last for hours, twilight sunset is held light and is reached more than 20 hours.But this production method must first granulation after making sheet, technology more complicated, the lines of the stone slab that makes are the parian lines, its lines only is embodied in the surface of stone slab, is manually to be brushed according to required lines by hairbrush, lines is and scatters shape and seem not attractive in appearance.And, if the surface of stone slab is damaged, then coup injury lines itself, thereby influenced the quality of product.
Three, summary of the invention
The objective of the invention is to overcome above-mentioned deficiency, a kind of technology is simple, lines is attractive in appearance, have the irradiant artificial stone material and the production technique thereof of native texture and provide.
Purpose of the present invention realizes by following technical solution: a kind of production technique of natural texture irradiant artificial stone material comprises the following steps: that successively (1) is 1 with weight ratio at first: unsaturated polyester (1.3-2.2) and Agate-Grade Alumina-Hydroxide mixing and adding natural pigment, solidifying agent are made for mother liquor through stirring; With weight ratio is 1: unsaturated polyester (1.0-2.0) and toothpaste level aluminium hydroxide mix and add natural pigment, luminescent powder and solidifying agent and is made for sub-liquid through stirring; (2) the sub-liquid of getting above-mentioned weight 5-20% adds promotor, pours into after stirring in the stone material mould; The mother liquor of getting above-mentioned weight 95-80% again adds promotor, pours into after stirring on the miscellany of sub-liquid in this stone material mould and promotor, is placed in the vacuum chamber then and bleeds; (3) after vacuum chamber is bled, take out the stone material mould again and solidify, after demoulding, polishing and make natural texture irradiant artificial stone material by it.
After adopting production technique of the present invention, difference according to the diameter of the different specific weight (concentration) of above-mentioned mother liquor, two kinds of pasty state liquid of sub-liquid and weighting material aluminium hydrate powder thereof, the principle that under vacuum environment, interpenetrates along with the discharge of air, the native texture that makes the artificial stone-like material who makes form from the inside to the outside, think and act in one and the same way, and the lines that forms is concentrated, attractive in appearance, not yielding, survivable.And can be energy-accumulating luminous, have energy-conserving action.Can be widely used in fields such as decoration, furniture, artwork, gardens, sculpture, bridge railing, flower bed railing.
Four, embodiment
The present invention is described in further detail below in conjunction with embodiment.
The production technique of natural texture irradiant artificial stone material of the present invention, comprise the following steps: that successively (1) is 1 with weight ratio at first: unsaturated polyester (1.3-2.2) and Agate-Grade Alumina-Hydroxide (powdery, thicker) (divide import, homemade two kinds, the import natural pigment is with respect to the 0.005-0.008% of unsaturated polyester weight to mix and add natural pigment; Homemade natural pigment is with respect to the 0.05-0.08% of unsaturated polyester weight), solidifying agent is made for mother liquor through stirring: under same case, with weight ratio is 1: unsaturated polyester (1.0-2.0) and toothpaste level aluminium hydroxide (powdery, thinner) (divide import, homemade two kinds, the import natural pigment is with respect to the 0.25-0.5% of unsaturated polyester weight to mix and add natural pigment; Homemade natural pigment is with respect to the 2.5-5.0% of unsaturated polyester weight), luminescent powder (with respect to the 5-100% of unsaturated polyester weight) and solidifying agent be made for sub-liquid through stirring; (2) coat demoulding wax at the stone material die surface, the sub-liquid of getting above-mentioned weight 5-20% adds promotor, pours into after stirring in the stone material mould; The mother liquor (gross weight that is sub-liquid and mother liquor is 100%) of getting above-mentioned weight 95-80% again adds promotor, pours into after stirring on the miscellany (before the curing) of sub-liquid in this stone material mould and promotor, is placed in the vacuum chamber then and bleeds; (3) after vacuum chamber is bled, take out the stone material mould again and solidify, after demoulding, polishing (surface finish and polishing) and make natural texture irradiant artificial stone material by it.
Wherein the concentration of mother liquor is higher, is 0.7-1.5% in the weight (for unsaturated polyester) of the solidifying agent that adds in the mother liquor, promotor, and can be according to the difference of temperature and difference: be 1.3-1.5% below 20 ℃; 20-25 ℃ is 1.3-1.1%; 25-30 ℃ is 1.1-0.9%; More than 30 ℃ 0.9-0.7%.The concentration of sub-liquid is lower, and the solidifying agent that adds in sub-liquid, the weight of promotor (for unsaturated polyester) are 0.4-1.3%, and can be according to the difference of temperature and difference: be 1.0-1.3% below 20 ℃; 20-25 ℃ is 1.1-1.0%; 25-30 ℃ is 1.0-0.7%; More than 30 ℃ 0.7-0.4%.Unsaturated polyester can be crystal resin, MMA type resin (being the methymethacrylate resin), 885 types, 818 types or 138 type resins (being liquid); Solidifying agent can be cyclohexanone peroxide, I type methylethyl ketone peroxide or II type methylethyl ketone peroxide; Promotor can be T-8A cobalt iso-octoate or T-8E cobalt naphthenate.The weight of the promotor of natural pigment, luminescent powder, solidifying agent and adding in mother liquor, sub-liquid also can be made appropriate change according to user's requirement.Difference according to the gimmick of the miscellany of pouring sub-liquid in the stone material mould and promotor into can make the artificial stone-like material's who makes lines have nothing in common with each other.This production technique is simple, has saved former granulating working procedure, and the artificial stone-like material who makes is owing to contain luminescent powder, and can absorb luminous energy and accumulation of energy its daytime, and when treating that illumination is lower than certain standard, the artificial stone-like material is can be automatic continuous luminous to reach more than 10 hour.
In order to accelerate set time, the above-mentioned stone material mould that takes out after vacuum chamber is bled (having filled sub-liquid and mother liquor and promotor) can be placed on and to solidify (being the point of the 3rd in the production technique) in the homothermic baking box.In order to form better native texture, make the artificial stone-like material's who makes lines more attractive in appearance, the sub-liquid that filling of above-mentioned (being the 2nd point in the production technique) can be stirred and the stone material mould of promotor are placed on earlier bleeds in the vacuum chamber, wait to bleed and take out after finishing, again the above-mentioned mother liquor that stirs and promotor are poured on the miscellany (before the curing) of sub-liquid in this stone material mould and promotor, be placed in the vacuum chamber then and bleed.The above-mentioned time length of bleeding in the vacuum chamber that is placed on, the directly shape and the thickness of the artificial stone-like material's that makes of influence lines.In order to form better native texture, make the artificial stone-like material's who makes lines more attractive in appearance, above-mentioned unsaturated polyester and Agate-Grade Alumina-Hydroxide blended weight ratio can be 1: (1.6-2.0), above-mentioned unsaturated polyester and toothpaste level aluminium hydroxide blended weight ratio can be 1: (1.0-1.5) (being the point of the 1st in the production technique).
Claims (6)
1. the production technique of a natural texture irradiant artificial stone material is characterized in that: comprise the following steps: that successively (1) is 1 with weight ratio at first: unsaturated polyester (1.3-2.2) and Agate-Grade Alumina-Hydroxide mix and add natural pigment, solidifying agent is made for mother liquor through stirring; With weight ratio is 1: unsaturated polyester (1.0-2.0) and toothpaste level aluminium hydroxide mix and add natural pigment, luminescent powder and solidifying agent and is made for sub-liquid through stirring; (2) the sub-liquid of getting above-mentioned weight 5-20% adds promotor, pours into after stirring in the stone material mould; The mother liquor of getting above-mentioned weight 95-80% again adds promotor, pours into after stirring on the miscellany of sub-liquid in this stone material mould and promotor, is placed in the vacuum chamber then and bleeds; (3) after vacuum chamber is bled, take out the stone material mould again and solidify, after demoulding, polishing and make natural texture irradiant artificial stone material by it.
2. the production technique of natural texture irradiant artificial stone material as claimed in claim 1, it is characterized in that: unsaturated polyester is crystal resin or MMA type resin.
3. the production technique of natural texture irradiant artificial stone material as claimed in claim 1, it is characterized in that: solidifying agent is a cyclohexanone peroxide.
4. the production technique of natural texture irradiant artificial stone material as claimed in claim 1, it is characterized in that: above-mentioned unsaturated polyester and Agate-Grade Alumina-Hydroxide blended weight ratio are 1: (1.6-2.0), above-mentioned unsaturated polyester and toothpaste level aluminium hydroxide blended weight ratio are 1: (1.0-1.5).
5. as the production technique of claim 1,2,3 or 4 described natural texture irradiant artificial stone materials, it is characterized in that: the above-mentioned stone material mould that fills the sub-liquid that stirs and promotor is placed in the vacuum chamber earlier bleeds, wait to bleed and take out after finishing, again the above-mentioned mother liquor that stirs and promotor are poured on the miscellany of sub-liquid in this stone material mould and promotor, be placed in the vacuum chamber then and bleed.
6. natural texture irradiant artificial stone material, it is characterized in that: the production technique by claim 1 is made.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB200510060854XA CN100374505C (en) | 2005-09-23 | 2005-09-23 | Natural texture irradiant artificial stone material and its production process |
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| Application Number | Priority Date | Filing Date | Title |
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| CNB200510060854XA CN100374505C (en) | 2005-09-23 | 2005-09-23 | Natural texture irradiant artificial stone material and its production process |
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| CN1769352A CN1769352A (en) | 2006-05-10 |
| CN100374505C true CN100374505C (en) | 2008-03-12 |
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| CNB200510060854XA Expired - Fee Related CN100374505C (en) | 2005-09-23 | 2005-09-23 | Natural texture irradiant artificial stone material and its production process |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106272890A (en) * | 2015-05-20 | 2017-01-04 | 宁志峰 | There is imitation wood and the production method of imitative stone matter series furniture of native texture |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HK1150492A2 (en) * | 2011-08-18 | 2011-12-30 | Greatmat Technology China Ltd | A kind of luminescent stone material and a method of preparing the same |
| ES2820515T3 (en) * | 2013-01-11 | 2021-04-21 | Cosentino Res And Development S L | Procedure to obtain a tile and / or a stratified agglomerated artificial stone slab |
| CN104628361A (en) * | 2013-11-07 | 2015-05-20 | 陈少跃 | Noctilucent marble-imitated handicraft, and preparation method thereof |
| CN105350738A (en) * | 2015-09-30 | 2016-02-24 | 吴火福 | Marble-imitated decoration board and manufacturing method thereof |
| CN106477968A (en) * | 2016-10-31 | 2017-03-08 | 佛山市震东石材有限公司 | A kind of environment protection multiple-colour jade stone entity plane materiel and its production method |
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| JPS6144747A (en) * | 1984-07-27 | 1986-03-04 | 株式会社イナックス | Manufacture of artificial marble |
| CN1256256A (en) * | 1998-12-07 | 2000-06-14 | 厦门华玉石实业有限公司 | Scagliola and its making process |
| CN1287980A (en) * | 2000-07-23 | 2001-03-21 | 骆荣泰 | Process for mfg. synthetic stone |
| CN1307959A (en) * | 2001-01-18 | 2001-08-15 | 梅县龙盘新型建材有限公司 | Artificial slate making process |
| JP2001335678A (en) * | 2000-05-25 | 2001-12-04 | Toto Ltd | Molded resin article |
| CN1528695A (en) * | 2003-10-18 | 2004-09-15 | 孙有新 | Noctilucent and luminous artificial stone and production process thereof |
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2005
- 2005-09-23 CN CNB200510060854XA patent/CN100374505C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6144747A (en) * | 1984-07-27 | 1986-03-04 | 株式会社イナックス | Manufacture of artificial marble |
| CN1256256A (en) * | 1998-12-07 | 2000-06-14 | 厦门华玉石实业有限公司 | Scagliola and its making process |
| JP2001335678A (en) * | 2000-05-25 | 2001-12-04 | Toto Ltd | Molded resin article |
| CN1287980A (en) * | 2000-07-23 | 2001-03-21 | 骆荣泰 | Process for mfg. synthetic stone |
| CN1307959A (en) * | 2001-01-18 | 2001-08-15 | 梅县龙盘新型建材有限公司 | Artificial slate making process |
| CN1528695A (en) * | 2003-10-18 | 2004-09-15 | 孙有新 | Noctilucent and luminous artificial stone and production process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106272890A (en) * | 2015-05-20 | 2017-01-04 | 宁志峰 | There is imitation wood and the production method of imitative stone matter series furniture of native texture |
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| CN1769352A (en) | 2006-05-10 |
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