CN102529556B - Artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and preparing method thereof - Google Patents

Artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and preparing method thereof Download PDF

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CN102529556B
CN102529556B CN 201110449771 CN201110449771A CN102529556B CN 102529556 B CN102529556 B CN 102529556B CN 201110449771 CN201110449771 CN 201110449771 CN 201110449771 A CN201110449771 A CN 201110449771A CN 102529556 B CN102529556 B CN 102529556B
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add
calligraphy
outer mold
type unsaturated
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CN102529556A (en
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江孟东
江伟
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Abstract

The invention discloses an artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and a preparing method thereof. The artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque is prepared through a certain process with methyl ethyl ketone serving as a curing agent, naphthenic acid cobalt liquid serving as an accelerating agent, a 3388type, a 6688 type and 191 type or 196 type unsaturated polyester resin and talcum powder serving as adhesion agents and river sand serving as main raw materials. Different pigments are added according to different plaques so that patterns of the plaques are beautiful and bright in color. Therefore, the artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque has the advantages of avoiding problems of aging, fading, breaking or delaminating, deformation and the like, and being clear and real in pattern, beautiful, bright in color, vivid and smooth in line, accurate and lifelike in modeling, high in breaking strength, durable, environment-friendly, high in quality and inexpensive. The preparing method of the artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque can design out various patterns according to actual needs and is used for manufacturing various exquisite crystal environmental-protection stone material craft calligraphy and painting plaques (such as large longevity plaques, marriage commemoration plaques, large colorful gravestones, plaques with landscape, painting of flowers and birds, calligraphy and painting, various figures and animals).

Description

The quartzy environment friendly stone technology of artificial fineness calligraphy and painting plaque board and preparation method thereof
Technical field
The present invention relates to the plaque board, especially relate to the quartzy environment friendly stone technology of a kind of artificial fineness calligraphy and painting plaque board and preparation method thereof.
Background technology
Along with development of times and progress, the raising gradually of people's living standard, living conditions also constantly improve and improve, except the outlying mountain area that minority very falls behind, each large, medium and small city, the whole nation and even small towns again are difficult to civil structure tile-roofed house or the thatched cottage that discovery was seen everywhere before 30 years now, almost most buildings of all having lived in common brick and cement structures.Yet at present parlor and the ornaments on the surroundings wall of bedroom of building still stick calligraphy and painting traditionally or hang up glass plaque board, of long duration not only seem vulgar, but also have easily aging, fugitive color, easy shortcoming such as fragmentation.
Summary of the invention
First purpose of the present invention is to provide a kind of and can occur wearing out, fades, fragmentation or problems such as delamination and distortion, clear patterns is true to nature, beauty is beautiful, bright in luster, rupture strength is high, the quartzy environment friendly stone technology of the artificial fineness calligraphy and painting plaque board of durable in use, environmental protection.
Second purpose of the present invention is to provide the preparation method of the quartzy environment friendly stone technology of a kind of artificial fineness calligraphy and painting plaque board, and this method raw material is easily purchased, method is simple.
First purpose of the present invention is achieved in that
The quartzy environment friendly stone technology of a kind of artificial fineness calligraphy and painting plaque board, feature is: prescription is made up of following raw material:
MEK: 280-350 ml talcum powder: 1-3 kg
Cobalt naphthenate solution: 180-200 ml river sands: 17-23 kg
High efficient demoulding agent: 0.1-0.2 kg pigment: 50-80 g
3388 type unsaturated polyester resins: 400--500 ml
6688 type unsaturated polyester resins: 400--500 ml
191 types or 196 type unsaturated polyester resins: 4000--5500 ml.
Described pigment is a kind of in iron oxide red, iron oxide black, iron oxide yellow, iron orchid or the titanium dioxide, or their mixture.
The purpose that the present invention is second is achieved in that
The preparation method of the quartzy environment friendly stone technology of a kind of artificial fineness calligraphy and painting plaque board, feature is:
(1), in computer, design the plaque board pattern that the user needs, print all satisfactory coloured pictures of dimensions size with blueprint machine again, standby;
(2), glass template and stainless steel mould bases are cleaned up, with the screw rod iron clamp stainless steel mould bases is fixed on the glass template, the two constitutes outer mold, and the spray high efficient demoulding agent is on outer mold, and the dress mould is finished;
(3), make quartzy surface layer: earlier 3388 type unsaturated-resins and 6688 type unsaturated-resins are mixed, stir, add MEK and cobalt naphthenate solution again, pour into after stirring in the outer mold that has sprayed high efficient demoulding agent, push open with rubber flap and to strike off, and held two of outer mold on operating desk, to vibrate the eliminating bubble a little, did the back to tack-free, and obtained quartzy surface layer in 30 minutes;
(4), art pattern CAD layer processed: in 191 types or 196 type unsaturated polyester resins, add MEK and cobalt naphthenate solution, the crystal face layer of falling back stirs, with rubber flap push open strike off after, spread rapidly and shifted to an earlier date printed coloured picture, coloured picture just facing to quartzy surface layer, strike off with the back side of rubber flap with coloured picture again, and thoroughly deaeration steeps; For every the look moulding, should put the scale copper of 5 mm wides at this moment at the periphery of coloured picture, allow scale copper and coloured picture solidify simultaneously, did the back to tack-free, and obtained the art pattern CAD layer in 30 minutes;
(5), the colored bag layer of system: in 191 types or 196 type unsaturated polyester resins, add talcum powder, stir, with Baume hydrometer test concentrations to 60-70 degree, add selected pigment then, continue to stir, add MEK and cobalt naphthenate solution again, after continuing to stir, be poured on the art pattern CAD layer, scrape off with rubber flap, bubble is got rid of in vibration a little, strikes off again, do the back in 30 minutes to tack-free, obtain colored bag layer;
(6), stone boundary layer processed: before the construction batch turning, earlier along interior 1.8cm distance interior mould bases with the outer mold equal height is installed in the surrounding of outer mold, form the limit groove between interior mould bases and the outer mold, spray high efficient demoulding agent at interior mould bases towards the outer wall surface of colored bag layer, in 191 types or 196 type unsaturated-resins, add again talcum powder and with step 5 in identical pigment, spend with Baume hydrometer test concentrations to 60-70, add MEK and cobalt naphthenate solution again, pour into after stirring in the groove of limit, bubble is got rid of in vibration a little, after striking off, does the back to tack-free in 50 minutes again, obtain the stone boundary layer, mould bases in removing simultaneously;
(7), stone body layer processed: cut out the interior thick steel wire of 0.5mm identical with the long-pending size of colored bag aspect with the stone boundary layer earlier, again steel wire is placed on the colored bag layer, in 191 types or 196 type unsaturated-resins, add again river sand and with step 5 in identical pigment, add MEK and cobalt naphthenate solution again, pour on the steel wire of having put after thoroughly stirring, spread out with mud mould and wiping board at last, bubble is got rid of in vibration a little, strike off again, solidify after 3-4 hours to tack-free, obtain height a little less than the stone body layer of stone boundary layer;
(8), paste fiber mesh layer: fiber mesh cloth big or small on an equal basis with stone body layer of first cutting, be placed in the back side of stone body layer, flatten, in 191 types or 196 type unsaturated-resins, add talcum powder again, with the Baume hydrometer test concentrations to the 35--45 degree, add MEK and cobalt naphthenate solution again, pour on the fiber mesh cloth after stirring, push striking off with scraper plate open, concordant with stone boundary layer height to fiber mesh layer, did the back in 30 minutes to tack-free, remove outer mold, get product.
The present invention be adopt MEK as curing agent, cobalt naphthenate solution as promoter, 3388 types, 6688 types and 191 types or 196 type unsaturated polyester resins and talcum powder be binding agent, river sand as main raw material(s), be prepared from by certain technology.The present invention can add different pigment according to different plaque board needs, makes the pattern beauty of plaque board beautiful, bright in luster, durable in use.The size of plaque board, thickness, all size can design, make according to user's needs.Therefore, the present invention have can not occur wearing out, fade, fragmentation or problems such as delamination and distortion, clear patterns is true to nature, beauty is beautiful, bright in luster, lines are eloquent, moulding is accurate, life-like, rupture strength is high, durable in use, environmental protection, good and cheap, raw material is easily purchased, the simple advantage of method, and can design various patterns as required, be used for making the quartzy environment friendly stone Artist horizontal inscribed board of various finenesses board (as: large-scale longevity plaque, marriage memorial tablet, large colour gravestone, mountain, water, flower, bird, word, picture and various personage and animal plaque etc.).
The specific embodiment
Be described in further detail below in conjunction with the present invention of embodiment.
Embodiment 1: the longevity plaque
(1), in computer, design the longevity plaque pattern that the user needs, print all satisfactory coloured pictures of dimensions size with blueprint machine again, standby;
(2), glass template and stainless steel mould bases are cleaned up, with the screw rod iron clamp stainless steel mould bases is fixed on the glass template, the two constitutes outer mold, and spray 0.06Kg high efficient demoulding agent is on outer mold, and the dress mould is finished;
(3), make quartzy surface layer: get each 400 ml of 3388 type unsaturated-resins and 6688 type unsaturated-resins earlier, both mix, stir, add 40 ml MEKs and 20 ml cobalt naphthenate solutions again, pour into after stirring in the outer mold that has sprayed high efficient demoulding agent, push striking off with rubber flap open, and held two of outer mold on operating desk, to vibrate the eliminating bubble a little, do the back in 30 minutes to tack-free, obtain quartzy surface layer;
(4), art pattern CAD layer processed: get 191 type unsaturated-resin 300ml earlier, the temperature of pressing at that time adds 30ml MEK and 20 ml cobalt naphthenate solutions in 191 type unsaturated polyester resins, the crystal face layer of falling back stirs, with rubber flap push open strike off after, spread rapidly and shifted to an earlier date printed coloured picture, coloured picture just facing to quartzy surface layer, strike off with the back side of rubber flap with coloured picture again, and thorough deaeration bubble; For every the look moulding, should put the scale copper of 5 mm wides at this moment at the periphery of coloured picture, allow scale copper and coloured picture solidify simultaneously, did the back to tack-free, and obtained the art pattern CAD layer in 30 minutes;
(5), the colored bag layer of system: get 191 type unsaturated-resin 1300ml earlier, in 191 type unsaturated polyester resins, add the 0.5Kg talcum powder, stir, spend with Baume hydrometer test concentrations to 60, add the selected pigment of 25g then: iron oxide red, continue to stir, add 70ml MEK and 50ml cobalt naphthenate solution again, after continuing to stir, be poured on the art pattern CAD layer, scrape off with rubber flap, bubble is got rid of in vibration a little, strike off again, did the back to tack-free, and obtained colored bag layer in 30 minutes;
(6), stone boundary layer processed: before the construction batch turning, earlier along interior 1.8cm distance interior mould bases with the outer mold equal height is installed in the surrounding of outer mold, form the limit groove between interior mould bases and the outer mold, spray the 0.04Kg high efficient demoulding agent at interior mould bases towards the outer wall surface of colored bag layer, get 191 type unsaturated-resin 1000ml, in 191 type unsaturated-resins, add 0.3Kg talcum powder and 10g iron oxide red, spend with Baume hydrometer test concentrations to 70, add 50ml MEK and 30 ml cobalt naphthenate solutions again, pour into after stirring in the groove of limit, bubble is got rid of in vibration a little, after striking off again, did the back in 50 minutes to tack-free, obtain the stone boundary layer, mould bases in removing simultaneously;
(7), stone body layer processed: cut out an interior 0.5mm thick steel wire identical with the long-pending size of colored bag aspect with the stone boundary layer earlier, again steel wire is placed on the colored bag layer, 191 types of getting are got 1200 milliliters of unsaturated-resins, in 191 type unsaturated-resins, add 17Kg river sand and 15g iron oxide red, add 60ml MEK and 40ml cobalt naphthenate solution again, pour on the steel wire of having put after thoroughly stirring, spread out with mud mould and wiping board at last, bubble is got rid of in vibration a little, strike off again, solidify after 3 hours to tack-free, obtain height a little less than the stone body layer of stone boundary layer;
(8), paste fiber mesh layer: fiber mesh cloth big or small on an equal basis with stone body layer of first cutting, be placed in the back side of stone body layer, flatten, get 191 type unsaturated-resins, 200 ml, in 191 type unsaturated-resins, add the 0.2Kg talcum powder, spend with Baume hydrometer test concentrations to 35, add 30ml MEK and 20ml cobalt naphthenate solution again, pour on the fiber mesh cloth after stirring, push to strike off open with scraper plate, concordant with stone boundary layer height to fiber mesh layer, did the back to tack-free in 30 minutes, remove outer mold, get product.
Embodiment 2: the animal plaque
(1), in computer, design the animal plaque pattern that the user needs, print all satisfactory coloured pictures of dimensions size with blueprint machine again, standby;
(2), glass template and stainless steel mould bases are cleaned up, with the screw rod iron clamp stainless steel mould bases is fixed on the glass template, the two constitutes outer mold, and spray 0.12Kg high efficient demoulding agent is on outer mold, and the dress mould is finished;
(3), make quartzy surface layer: get each 500 ml of 3388 type unsaturated-resins and 6688 type unsaturated-resins earlier, both mix, stir, add 45 ml MEKs and 24 ml cobalt naphthenate solutions again, pour into after stirring in the outer mold that has sprayed high efficient demoulding agent, push striking off with rubber flap open, and held two of outer mold on operating desk, to vibrate the eliminating bubble a little, do the back in 30 minutes to tack-free, obtain quartzy surface layer;
(4), art pattern CAD layer processed: get 196 type unsaturated-resin 500ml earlier, the temperature of pressing at that time adds 45ml MEK and 24ml cobalt naphthenate solution in 196 type unsaturated polyester resins, the crystal face layer of falling back stirs, with rubber flap push open strike off after, spread rapidly and shifted to an earlier date printed coloured picture, coloured picture just facing to quartzy surface layer, strike off with the back side of rubber flap with coloured picture again, and thorough deaeration bubble; For every the look moulding, should put the scale copper of 5 mm wides at this moment at the periphery of coloured picture, allow scale copper and coloured picture solidify simultaneously, did the back to tack-free, and obtained the art pattern CAD layer in 30 minutes;
(5), the colored bag layer of system: get 196 type unsaturated-resin 1700ml earlier, in 196 type unsaturated polyester resins, add the 2Kg talcum powder, stir, spend with Baume hydrometer test concentrations to 70, add the selected pigment of 40g then: the iron oxide black, continue to stir, add 90ml MEK and 55ml cobalt naphthenate solution again, after continuing to stir, be poured on the art pattern CAD layer, scrape off with rubber flap, bubble is got rid of in vibration a little, strike off again, did the back to tack-free, and obtained colored bag layer in 30 minutes;
(6), stone boundary layer processed: before the construction batch turning, earlier along interior 1.8cm distance interior mould bases with the outer mold equal height is installed in the surrounding of outer mold, form the limit groove between interior mould bases and the outer mold, spray the 0.08Kg high efficient demoulding agent at interior mould bases towards the outer wall surface of colored bag layer, get 196 type unsaturated-resin 1200ml, in 196 type unsaturated-resins, add 1.4Kg talcum powder and 20g iron oxide black, spend with Baume hydrometer test concentrations to 60, add 60ml MEK and 32 ml cobalt naphthenate solutions again, pour into after stirring in the groove of limit, bubble is got rid of in vibration a little, after striking off again, did the back in 50 minutes to tack-free, obtain the stone boundary layer, mould bases in removing simultaneously;
(7), stone body layer processed: cut out an interior 0.5mm thick steel wire identical with the long-pending size of colored bag aspect with the stone boundary layer earlier, again steel wire is placed on the colored bag layer, 196 types of getting are got 1300 milliliters of unsaturated-resins, in 196 type unsaturated-resins, add 23Kg river sand and 20g iron oxide black, add 70ml MEK and 43ml cobalt naphthenate solution again, pour on the steel wire of having put after thoroughly stirring, spread out with mud mould and wiping board at last, bubble is got rid of in vibration a little, strike off again, solidify after 3 hours to tack-free, obtain height a little less than the stone body layer of stone boundary layer;
(8), paste fiber mesh layer: fiber mesh cloth big or small on an equal basis with stone body layer of first cutting, be placed in the back side of stone body layer, flatten, get 196 type unsaturated-resins, 300 ml, in 196 type unsaturated-resins, add the 0.6Kg talcum powder, spend with Baume hydrometer test concentrations to 45, add 40ml MEK and 22ml cobalt naphthenate solution again, pour on the fiber mesh cloth after stirring, push to strike off open with scraper plate, concordant with stone boundary layer height to fiber mesh layer, did the back to tack-free in 30 minutes, remove outer mold, get product.
Embodiment 3: the birds and flowers plaque
(1), in computer, design the birds and flowers plaque pattern that the user needs, print all satisfactory coloured pictures of dimensions size with blueprint machine again, standby;
(2), glass template and stainless steel mould bases are cleaned up, with the screw rod iron clamp stainless steel mould bases is fixed on the glass template, the two constitutes outer mold, and spray 0.1Kg high efficient demoulding agent is on outer mold, and the dress mould is finished;
(3), make quartzy surface layer: get each 450 ml of 3388 type unsaturated-resins and 6688 type unsaturated-resins earlier, both mix, stir, add 45ml MEK and 23 ml cobalt naphthenate solutions again, pour into after stirring in the outer mold that has sprayed high efficient demoulding agent, push striking off with rubber flap open, and held two of outer mold on operating desk, to vibrate the eliminating bubble a little, do the back in 30 minutes to tack-free, obtain quartzy surface layer;
(4), art pattern CAD layer processed: get 191 type unsaturated-resin 400ml earlier, the temperature of pressing at that time adds 35ml MEK and 22 ml cobalt naphthenate solutions in 191 type unsaturated polyester resins, the crystal face layer of falling back stirs, with rubber flap push open strike off after, spread rapidly and shifted to an earlier date printed coloured picture, coloured picture just facing to quartzy surface layer, strike off with the back side of rubber flap with coloured picture again, and thorough deaeration bubble; For every the look moulding, should put the scale copper of 5 mm wides at this moment at the periphery of coloured picture, allow scale copper and coloured picture solidify simultaneously, did the back to tack-free, and obtained the art pattern CAD layer in 30 minutes;
(5), the colored bag layer of system: get 191 type unsaturated-resin 1500ml earlier, in 191 type unsaturated polyester resins, add the 1.5Kg talcum powder, stir, spend with Baume hydrometer test concentrations to 65, add the selected pigment of 35g then: iron oxide yellow, continue to stir, add 80ml MEK and 53ml cobalt naphthenate solution again, after continuing to stir, be poured on the art pattern CAD layer, scrape off with rubber flap, bubble is got rid of in vibration a little, strike off again, did the back to tack-free, and obtained colored bag layer in 30 minutes;
(6), stone boundary layer processed: before the construction batch turning, earlier along interior 1.8cm distance interior mould bases with the outer mold equal height is installed in the surrounding of outer mold, form the limit groove between interior mould bases and the outer mold, spray the 0.05Kg high efficient demoulding agent at interior mould bases towards the outer wall surface of colored bag layer, get 191 type unsaturated-resin 1100ml, in 191 type unsaturated-resins, add 0.6Kg talcum powder and 15g iron oxide yellow, spend with Baume hydrometer test concentrations to 65, add 55ml MEK and 33ml cobalt naphthenate solution again, pour into after stirring in the groove of limit, bubble is got rid of in vibration a little, after striking off again, did the back in 50 minutes to tack-free, obtain the stone boundary layer, mould bases in removing simultaneously;
(7), stone body layer processed: cut out an interior 0.5mm thick steel wire identical with the long-pending size of colored bag aspect with the stone boundary layer earlier, again steel wire is placed on the colored bag layer, 191 types of getting are got 1200 milliliters of unsaturated-resins, in 191 type unsaturated-resins, add 20Kg river sand and 25g iron oxide yellow, add 65ml MEK and 41ml cobalt naphthenate solution again, pour on the steel wire of having put after thoroughly stirring, spread out with mud mould and wiping board at last, bubble is got rid of in vibration a little, strike off again, solidify after 4 hours to tack-free, obtain height a little less than the stone body layer of stone boundary layer;
(8), paste fiber mesh layer: fiber mesh cloth big or small on an equal basis with stone body layer of first cutting, be placed in the back side of stone body layer, flatten, get 191 type unsaturated-resins, 300 ml, in 191 type unsaturated-resins, add the 0.4Kg talcum powder, spend with Baume hydrometer test concentrations to 40, add 40ml MEK and 25ml cobalt naphthenate solution again, pour on the fiber mesh cloth after stirring, push to strike off open with scraper plate, concordant with stone boundary layer height to fiber mesh layer, did the back to tack-free in 30 minutes, remove outer mold, get product.

Claims (1)

1. the preparation method of the quartzy environment friendly stone technology of an artificial fineness calligraphy and painting plaque board is characterized in that:
(1), in computer, design the plaque board pattern that the user needs, print all satisfactory coloured pictures of dimensions size with blueprint machine again, standby;
(2), glass template and stainless steel mould bases are cleaned up, with the screw rod iron clamp stainless steel mould bases is fixed on the glass template, the two constitutes outer mold, and the spray high efficient demoulding agent is on outer mold, and the dress mould is finished;
(3), make quartzy surface layer: earlier 3388 type unsaturated-resins and 6688 type unsaturated-resins are mixed, stir, add MEK and cobalt naphthenate solution again, pour into after stirring in the outer mold that has sprayed high efficient demoulding agent, push open with rubber flap and to strike off, and held two of outer mold on operating desk, to vibrate the eliminating bubble a little, did the back to tack-free, and obtained quartzy surface layer in 30 minutes;
(4), art pattern CAD layer processed: in 191 types or 196 type unsaturated polyester resins, add MEK and cobalt naphthenate solution, the crystal face layer of falling back stirs, with rubber flap push open strike off after, spread rapidly and shifted to an earlier date printed coloured picture, coloured picture just facing to quartzy surface layer, strike off with the back side of rubber flap with coloured picture again, and thoroughly deaeration steeps; For every the look moulding, should put the scale copper of 5 mm wides at this moment at the periphery of coloured picture, allow scale copper and coloured picture solidify simultaneously, did the back to tack-free, and obtained the art pattern CAD layer in 30 minutes;
(5), the colored bag layer of system: in 191 types or 196 type unsaturated polyester resins, add talcum powder, stir, with Baume hydrometer test concentrations to 60-70 degree, add selected pigment then, continue to stir, add MEK and cobalt naphthenate solution again, after continuing to stir, be poured on the art pattern CAD layer, scrape off with rubber flap, bubble is got rid of in vibration a little, strikes off again, do the back in 30 minutes to tack-free, obtain colored bag layer;
(6), stone boundary layer processed: before the construction batch turning, earlier along interior 1.8cm distance interior mould bases with the outer mold equal height is installed in the surrounding of outer mold, form the limit groove between interior mould bases and the outer mold, spray high efficient demoulding agent at interior mould bases towards the outer wall surface of colored bag layer, in 191 types or 196 type unsaturated-resins, add again talcum powder and with step 5 in identical pigment, spend with Baume hydrometer test concentrations to 60-70, add MEK and cobalt naphthenate solution again, pour into after stirring in the groove of limit, bubble is got rid of in vibration a little, after striking off, does the back to tack-free in 50 minutes again, obtain the stone boundary layer, mould bases in removing simultaneously;
(7), stone body layer processed: cut out the interior thick steel wire of 0.5mm identical with the long-pending size of colored bag aspect with the stone boundary layer earlier, again steel wire is placed on the colored bag layer, in 191 types or 196 type unsaturated-resins, add again river sand and with step 5 in identical pigment, add MEK and cobalt naphthenate solution again, pour on the steel wire of having put after thoroughly stirring, spread out with mud mould and wiping board at last, bubble is got rid of in vibration a little, strike off again, solidify after 3-4 hours to tack-free, obtain height a little less than the stone body layer of stone boundary layer;
(8), paste fiber mesh layer: fiber mesh cloth big or small on an equal basis with stone body layer of first cutting, be placed in the back side of stone body layer, flatten, in 191 types or 196 type unsaturated-resins, add talcum powder again, with the Baume hydrometer test concentrations to the 35--45 degree, add MEK and cobalt naphthenate solution again, pour on the fiber mesh cloth after stirring, push striking off with scraper plate open, did the back in 30 minutes to tack-free, concordant with stone boundary layer height to fiber mesh layer, remove outer mold, get product.
CN 201110449771 2011-12-29 2011-12-29 Artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and preparing method thereof Expired - Fee Related CN102529556B (en)

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CN106398488A (en) * 2015-07-27 2017-02-15 刘飞 Handicraft picture reinforcing agent and handicraft picture reinforcing method
CN106517990A (en) * 2016-10-31 2017-03-22 周兴和 A plaque manufacturing method
CN107739495A (en) * 2017-11-02 2018-02-27 成都金川田农机制造有限公司 A kind of preparation method of anti-stone desktop

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1397425A (en) * 2002-08-13 2003-02-19 刘本和 Strengthened artificial granite
CN1827363A (en) * 2006-01-23 2006-09-06 邓伟 Artificial stone composite platform and method for manufacturing same
CN101508554A (en) * 2009-03-12 2009-08-19 江伟 Artificial stone wood combined colorful environment friendly stone furniture table-board and method of producing the same

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Publication number Priority date Publication date Assignee Title
US20020041937A1 (en) * 2000-10-10 2002-04-11 Clemmer Clay E. Stone veneer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1397425A (en) * 2002-08-13 2003-02-19 刘本和 Strengthened artificial granite
CN1827363A (en) * 2006-01-23 2006-09-06 邓伟 Artificial stone composite platform and method for manufacturing same
CN101508554A (en) * 2009-03-12 2009-08-19 江伟 Artificial stone wood combined colorful environment friendly stone furniture table-board and method of producing the same

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