CN1378833A - Solid cosmetic - Google Patents
Solid cosmetic Download PDFInfo
- Publication number
- CN1378833A CN1378833A CN02118315A CN02118315A CN1378833A CN 1378833 A CN1378833 A CN 1378833A CN 02118315 A CN02118315 A CN 02118315A CN 02118315 A CN02118315 A CN 02118315A CN 1378833 A CN1378833 A CN 1378833A
- Authority
- CN
- China
- Prior art keywords
- wax
- composition
- right amount
- solic cosmetic
- fischer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 59
- 239000007787 solid Substances 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 83
- 239000001993 wax Substances 0.000 claims abstract description 66
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 19
- 239000012530 fluid Substances 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000003086 colorant Substances 0.000 claims description 3
- 235000019808 microcrystalline wax Nutrition 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 29
- 235000019198 oils Nutrition 0.000 description 29
- -1 Jojoba oil Chemical compound 0.000 description 24
- 239000011248 coating agent Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical class CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 11
- RJWUMFHQJJBBOD-UHFFFAOYSA-N 2-methylheptadecane Chemical compound CCCCCCCCCCCCCCCC(C)C RJWUMFHQJJBBOD-UHFFFAOYSA-N 0.000 description 10
- 239000003963 antioxidant agent Substances 0.000 description 10
- 230000003078 antioxidant effect Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 235000013599 spices Nutrition 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 9
- 125000005456 glyceride group Chemical group 0.000 description 9
- 239000000470 constituent Substances 0.000 description 8
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 7
- 240000000912 Macadamia tetraphylla Species 0.000 description 7
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 7
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000010466 nut oil Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 6
- 239000004166 Lanolin Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 229940039717 lanolin Drugs 0.000 description 5
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 239000006071 cream Substances 0.000 description 4
- 210000004209 hair Anatomy 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical class CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000004204 candelilla wax Substances 0.000 description 3
- 235000013868 candelilla wax Nutrition 0.000 description 3
- 229940073532 candelilla wax Drugs 0.000 description 3
- 239000004203 carnauba wax Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 235000015110 jellies Nutrition 0.000 description 3
- 239000008274 jelly Substances 0.000 description 3
- 229940119170 jojoba wax Drugs 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 239000001630 malic acid Substances 0.000 description 3
- 235000011090 malic acid Nutrition 0.000 description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 3
- 229920001083 polybutene Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229940032094 squalane Drugs 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- 208000031872 Body Remains Diseases 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000007766 cera flava Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- WQDGUYZIAJKLAB-UHFFFAOYSA-N octan-2-yl nitrite Chemical compound CCCCCCC(C)ON=O WQDGUYZIAJKLAB-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
A solid cosmetic composition, which drastically improves the shape-retaining ability and usability. A solid cosmetic composition has (a) Fischer-Tropsch wax having average molecular weight of 300 to 1200 and (b) Microcrystalline wax in the weight ratio of (a) : (b) = 60:40 to 99.9: 0.1.
Description
Technical field
The present invention relates to Solic cosmetic.
In more detail, the present invention relates to the extremely excellent Solic cosmetic of shape-retaining ability, usability (ductility when particularly being coated with, glossiness).
Background technology
As Solic cosmetic, for example known lipstick, lip pomade, foundation cream, pencil-type cosmetics, hair jelly.
Wherein, for oiliness type Solic cosmetic, powder body is dispersed in the mixture of fluid oil composition (for example, Oleum Ricini, Jojoba oil, squalane, lanoline, various synthetic ester oil, mobile paraffin) and wax (solid agent: for example Brazil wax, candelilla wax, ceresin, microwax, curing animal oil, solidified plant oil, Cera Flava).
Summary of the invention
Above-mentioned oiliness type Solic cosmetic need satisfy necessary shape-retaining ability of goods and usability (ductility when particularly being coated with, glossiness) by the mixed proportion of regulating wax and fluid oil composition.
But it is very difficult satisfying sufficient shape-retaining ability and usability simultaneously.
This is because wax is that the fluid oil composition solidifies necessary composition, in order to keep shape of products (shape-retaining ability), must add enough amounts during use.
But, if the addition of wax is many, the ductility variation when then being coated with, the gloss that also can cause the fluid oil composition to cause becomes dim in addition.
Thereby, because this negative phenomena, provide and satisfy shape-retaining ability and all good Solic cosmetics of usability are extremely difficult.
The Solic cosmetic of shape-retaining ability and usability excellence is that market is expected all the year round, and many researcheres are devoted to its developmental research.
In order to solve above-mentioned problem, the method that can consider to adopt the wax (can present the wax of hardness on a small quantity) that can give sufficient shape-retaining ability on a small quantity to solidify liquid oil component.
But, because such wax fusing point height can bring a lot of problems when making goods.
That is, if use the high wax of fusing point, then Solic cosmetic must at high temperature dissolve and be filled in the container.At this moment, cited significant problem below manufacture view has just produced.1.: the various temperature condition during filling (temperature of the temperature of cosmetics, container, chilling temperature gradient etc. during filling) produces a very large impact shape-retaining ability, bending property, the serviceability of cosmetics.Thereby, each is set prescription is detailed when creating conditions, if the fusing point height of wax, then the setting of this condition is restricted, and makes troubles sometimes.2.: when adopting emulsification composition, the moisture in the Solic cosmetic is easy to evaporation.3.: must make filling containers and manufacturing equipment with material with high temperature durability.Thereby manufacturing cost uprises.
The purpose of this invention is to provide the extremely excellent Solic cosmetic of shape-retaining ability and usability.
Further aim of the present invention provides the Solic cosmetic that does not use dystectic wax promptly can avoid the problem of above-mentioned manufacture view.
Present inventors have carried out concentrated research in order to solve above-mentioned problem, found that, if be that 300～1200 Fischer-Tropsch wax and microwax solidify liquid oil component with the blended wax of special ratios with mean molecule quantity, can significantly increase hardness.
When Wax composition of the present invention adds on a small quantity, can give goods sufficient hardness, also not have above-mentioned fusing point problem, and can make the shape-retaining ability with excellence, the ductility of excellence and the Solic cosmetic of glossiness.
The present invention is as described below.1: contain (a) mean molecule quantity and be 300～1200 Fischer-Tropsch wax and (b) microwax, both mass ratioes are (a): (b)=and 60: 40～99.9: 0.1 Solic cosmetic.2: the above-mentioned Solic cosmetic that further contains the fluid oil composition.3: only contain the above-mentioned Solic cosmetic of above-mentioned wax as solid agent.4: above-mentioned Solic cosmetic is the above-mentioned Solic cosmetic that further contains the lipstick of coloring agent.5: mix (a) mean molecule quantity and be 300～1200 Fischer-Tropsch wax and (b) microwax, both mass ratioes are (a): (b) 60: 40～99.9: 0.1 Solic cosmetic.
The working of an invention mode
Describe the present invention below in detail.
(a) composition Fischer-Tropsch wax is the synthetic wax shape hydrocarbon that adopts Fischer-Tropsch manufactured.
The mean molecule quantity of this wax that the present invention is used is 300～1200.Preferred mean molecule quantity is 400～1100, and preferred especially mean molecule quantity is 500～700.
If mean molecule quantity is less than 300, then the ability to cure of fluid oil composition reduces.
If mean molecule quantity surpasses 1200, then fusing point is too high, makes the difficulty that becomes.
Mean molecule quantity refers to the number-average molecular weight of trying to achieve according to conventional methods.As long as the number-average molecular weight of above-mentioned wax satisfies above-mentioned scope, approach single dispersion in order to make molecular weight distribution, preferably have the wax of sharp-pointed molecular weight distribution curve.
Fischer-Tropsch wax can use commercially available product.
Specifically, can use mean molecule quantity is 300～1200 following commercially available product.
" パ ラ Off リ Application ト C77 ", " パ ラ Off リ Application ト C80 ", " パ ラ Off リ Application ト H1 " (being シ ュ-マ Application サ ゾ-Le corporate system).
" FT100 ", " MDP-7010 " (be Japanese smart pupa Co., Ltd. system).
Addition according to (b) composition, determine that suitably the addition of (a) composition is so that satisfied mass ratio as key element of the present invention with respect to the all-mass of Solic cosmetic, is generally 0.06～29.97 quality %, preferred 0.6～19.98 quality %, more preferably 3.0～14.98 quality %.
(b) the composition microwax is the hydrocarbon that often uses in cosmetics such as lipstick, cream frost.Preferably use fusing point more than 70 ℃, below 100 ℃, more preferably the microwax more than 80 ℃, below 95 ℃.Can use commercially available product among the present invention.
Can suitably determine the addition of (b) composition, but, be generally 0.01～12 quality %, preferred 0.05～8 quality %, more preferably 0.25～6 quality % with respect to the all-mass of Solic cosmetic.
With (a): (b)=60: 40～99.9: 0.1 mass ratio mix (a) composition and (b) Wax composition that obtains of composition be used in the Solic cosmetic of the present invention as solid agent.
The preferred mass ratio is (a): (b)=80: 20～99.8: 0.2.
More preferably mass ratio is (a): (b)=90: 10～95: 5.
Mix (a) composition and (b) during composition, goods hardness has critical meaning with above-mentioned mass ratio, above-mentioned Wax composition can be brought into play extremely excellent effect as solid agent.
During mixing as long as only stir (a) composition and (b) composition with above-mentioned mass ratio.
Also can in Solic cosmetic, add blended Wax composition.
In addition, also can be in the fluid oil composition add (a) composition respectively and (b) stir behind the composition and make Solic cosmetic.
Even also can give Solic cosmetic sufficient hardness on a small quantity,, can provide Solic cosmetic with excellent shape-retaining ability so the ductility and the glossiness that can not cause the fluid oil composition to cause are impaired because this Wax composition adds.
And, in the manufacturing of Solic cosmetic, can not be subjected to the restriction of the fusing point of Wax composition.
Because Wax composition of the present invention has excellent effect as solid agent, even also very big as the succedaneum use value of the solid agent (particularly Chang Yong ceresin) of prior art.
The addition of Wax composition { (a) composition and (b) total addition level of composition } can be determined according to the kind of Solic cosmetic.With respect to the all-mass of Solic cosmetic, preferred 0.1～30 quality %, more preferably 1～20 quality %, preferred especially 5～15 quality %.
If addition can not play the effect of solid agent less than 0.1 quality %, the shape-retaining ability aspect of goods will be affected.
If addition surpasses 30 quality %, goods hardness is excessive, and ductility and glossiness suffer damage.
The used fluid oil composition of the present invention is that (15 ℃) are the oil component of liquid at normal temperatures.Get final product so long as can be used for the fluid oil composition of Solic cosmetic, this is not had special qualification.
Preferred fluid oil composition is listed below.
Three 2 ethyl hexanoic acid glyceride, two glyceryl isostearates, malic acid two isooctadecane base esters, dimethyl polysiloxane, decamethyl five siloxanes, Queensland's macadamia nut oil, three sad trimethylolpropanes, three isostearic acids, two glyceride, the stearic acyloxy stearyl of oxygen base, Jojoba oil, squalane, liquid lanolin, three (Foral isostearic acid) glyceride, methyl phenyl silicone, three glyceryl isostearates, polybutene.
For lipstick, special preferred liquid lanoline, three (Foral isostearic acid) glyceride, methyl phenyl silicone, three glyceryl isostearates, polybutene.
For the dressing effect that makes lipstick better, also preferred volatile fluid oil composition (annular siloxane oil such as octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes).
The addition of fluid oil composition is with respect to the all-mass of Solic cosmetic 30～99.9 quality % normally, preferred 50～99 quality %.If the addition of fluid oil composition is few, then ductility has the tendency of variation, so preferred addition is more than the 50 quality %.
In Solic cosmetic of the present invention, except the fluid oil composition, also can and use solid oil composition, lard composition as required.
Solic cosmetic of the present invention is except above-mentioned necessary composition, in the scope of not damaging effect of the present invention, can suitably add other wax, other oil component, wetting agent, antiseptic, antioxidant, UV absorbent, macromolecule, surfactant, pigment, pigment, powder, medicament, alcohol, solvent, spice as required, and can be according to the kind of goods by the conventional method manufacturing.
The object lesson of Solic cosmetic of the present invention is as follows.
Color make-up cosmetics such as lipstick, lip gloss, lip pomade, foundation cream, eye shadow.
Hair cosmetic composition such as hair jelly, pomade.
So long as Solic cosmetic is unqualified to it.Preferred bar-shaped solid shape shape product.Especially preferably add the lipstick of powder colorant.
Solic cosmetic of the present invention reaches excellent shape-retaining ability and usability by (a) composition of specific mean molecule quantity with the Wax composition that (b) becomes to be grouped into.
Though its reason is not understood, can be carried out following supposition.
That is, for the Solic cosmetic that wax and fluid oil become to be grouped into, the fine crystal of wax is interconnected to latticed and forms skeleton.In its skeleton, comprise the fluid oil composition, make integral body remain solid, shaped.
The structure of Solic cosmetic and character is owing to be subjected to the fine crystal structure of wax and the influence of kind of size, fluid oil composition, is that the mode of the best is being solidified the fluid oil composition with shape-retaining ability and usability perhaps so can infer Wax composition of the present invention.
Embodiment
Be described more specifically the present invention below in conjunction with embodiment, but the present invention is not subjected to the restriction of following embodiment.Addition if not otherwise specified, % represents with quality." solid agent: Wax composition "
The different Wax composition of mixing ratio with (a) composition and (b) composition solidifies liquid oil component.
(a) composition employing mean molecule quantity is Fischer-Tropsch wax (the パ ラ Off リ Application ト C77 of シ ュ-マ Application サ ゾ-Le corporate system) of 530.
The hardness of the solids of measure mixing 10 quality % Wax compositions and 90 quality % fluid oil compositions (three 2 ethyl hexanoic acid glyceride) and obtaining (itself can be used as lip gloss and use).
The durometer that uses is the curdmeter (model M-301AR) of meal tail Electric Co., Ltd system.Under the condition of 3 φ pressure-sensitive axles, 800g weight, the sample of placing 1 hour down at 37 ℃ is measured.
The results are shown in the table 1.
Wax amount in the table is the concentration in the Wax composition.
From this result as can be seen, when mixing ratio is (a): (b)=60: 40～99.9: 0.1, preferred (a): (b)=80: 20～99.8: 0.2, more preferably (a): (b)=90: 10～95: 5 o'clock, the hardness of solids sharply increases.
The mixing ratio of Wax composition demonstrates significant hardness when above-mentioned scope, above-mentioned in the present invention numerical value has critical meaning.Mix (a) composition and (b) during composition, the manufacturer can not predict the maximum that the solids hardness of fluid oil composition can reach, so the Wax composition that preferably has the mixing ratio of the maximum of demonstrating.
In addition, this moment, Wax composition can not make troubles to manufacture view because of fusing point.
" Solic cosmetic "
| Fischer-Tropsch wax | ??100 | ???99.9 | ??99.8 | ????95 | ???90 | ???85 | ??80 | ??70 | ???60 | ???50 | ???40 | ???20 | ??0 |
| Microwax | ??0 | ??0.1 | ??0.2 | ????5 | ???10 | ???15 | ??20 | ??30 | ???40 | ???50 | ???60 | ???80 | ??100 |
| The hardness of solids | ??11 | ??14.3 | ??17.8 | ????21.8 | ???20.5 | ???18.8 | ??16.5 | ??13.8 | ???12 | ???10.3 | ???9.5 | ???8.5 | ??8 |
Make the Solic cosmetic shown in each table, study effect of the present invention.(manufacture method of the Solic cosmetic of table 2～9)
Under 120 ℃, make each composition dissolving, mix with dispersion machine.With this mixture degassing, be poured in metal die or the container, Solic cosmetic is made in cooling.(manufacture method of the lipstick of table 10)
At 90～100 ℃ of each compositions that dissolves (1)～(7), (10)～(16) down, mix with dispersion machine.
In this mixture, add (8) and (9) and dispersion.After its degassing, be poured in the lipstick container, the oil-in-water type lip stick is made in cooling.
Fischer-Tropsch wax used in the prescription of table 2～10 is as described below.
" Fischer-Tropsch wax (1) " → " パ ラ Off リ Application ト C77 (number-average molecular weight 530) "
" Fischer-Tropsch wax (2) " → " パ ラ Off リ Application ト C80 (number-average molecular weight 630) "
" Fischer-Tropsch wax (3) " → " パ ラ Off リ Application ト H1 (number-average molecular weight 1060) "
[shape-retaining ability]
Estimate by visual.
(evaluation criterion)
◎: excellent (excellent solid state)
Zero: good (good solid state)
△: poor (pasty state～softness)
*: extremely poor (aqueous)
[ductility during coating]
Use Solic cosmetic by professional (20), carry out the sense evaluation (mark) of 5 grades.According to fractional meansigma methods, judge with following evaluation criterion.
(mark)
5 minutes: the ductility during coating was good
4 minutes: the ductility during coating was better
3 minutes: the ductility during coating was general
2 minutes: the ductility during coating was relatively poor
1 minute: the poor ductility during coating
(evaluation criterion)
◎: mark (meansigma methods) is more than 4.0 below 5.0
Zero: mark (meansigma methods) is more than 3.0 below 4.0
△: mark (meansigma methods) is more than 2.0 below 3.0
*: mark (meansigma methods) is more than 1.0 below 2.0
[glossiness]
Use Solic cosmetic by professional (20), carry out the sense evaluation (mark) of 5 grades.According to fractional meansigma methods, judge with following evaluation criterion.
(mark)
5 minutes: glossy
4 minutes: glossy slightly
3 minutes: glossiness was general
2 minutes: lackluster slightly
1 minute: lackluster
(evaluation criterion)
◎: mark (meansigma methods) is more than 4.0 below 5.0
Zero: mark (meansigma methods) is more than 3.0 below 4.0
△: mark (meansigma methods) is more than 2.0 below 3.0
*: mark (meansigma methods) is 2.0 following lipstick tables 2 more than 1.0
Table 3
Lip gloss table 4
Lip pomade table 5
Foundation cream table 6
Eyebrow pencil table 7
Hair jelly table 8
Lipstick table 9
| Blending constituent | Embodiment | Comparative example | ||||
| ????1 | ????2 | ????3 | ????4 | ????1 | ????2 | |
| (a) Fischer-Tropsch wax (1) | ????9.5 | ????995 | ????8 | ????- | ????- | ????- |
| (a) Fischer-Tropsch wax (2) | ????- | ????- | ????1.5 | ????9.5 | ????- | ????- |
| (b) microwax | ????0.5 | ????0.05 | ????0.5 | ????0.5 | ????- | ????- |
| Ceresin | ????- | ????- | ????- | ????- | ????10 | ????10 |
| Brazil wax | ????- | ????- | ????- | ????- | ????2 | ????- |
| Candelilla wax | ????- | ????- | ????- | ????- | ????3 | ????- |
| Dimethyl polysiloxane | ????10 | ????10 | ????10 | ????10 | ????10 | ????10 |
| Three (Foral isostearic acid) glyceride | ????20 | ????20 | ????20 | ????20 | ????20 | ????20 |
| Liquid lanolin | ????10 | ????10 | ????10 | ????10 | ????10 | ????10 |
| Three 2 ethyl hexanoic acid glyceride | ????20 | ????20 | ????20 | ????20 | ????15 | ????20 |
| Two glyceryl isostearates | ????15 | ????15 | ????15 | ????15 | ????15 | ????15 |
| Malic acid two isooctadecane base esters | ????10 | ????10 | ????10 | ????10 | ????10 | ????10 |
| Red No. 202 | ????2 | ????2 | ????2 | ????2 | ????2 | ????2 |
| Titanium oxide | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 |
| Iron oxide red | ????2 | ????2 | ????2 | ????2 | ????2 | ????2 |
| Iron oxide black | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 |
| Antioxidant | In right amount | In right amount | In right amount | In right amount | In right amount | In right amount |
| Spice | In right amount | In right amount | In right amount | In right amount | In right amount | In right amount |
| Shape-retaining ability | ????◎ | ????○ | ????◎ | ????◎ | ????○ | ????△ |
| Ductility during coating | ????◎ | ????◎ | ????◎ | ????◎ | ????△ | ????○ |
| Glossiness | ????◎ | ????◎ | ????◎ | ????○ | ????× | ????◎ |
| Blending constituent | Embodiment | |||
| ????5 | ????6 | ????7 | ????8 | |
| Fischer-Tropsch wax (1) | ????10 | ????10 | ????5 | ????9.5 |
| Microwax | ????1 | ????2 | ????0.5 | ????0.5 |
| Candelilla wax | ????0.5 | ????- | ????2 | ????- |
| Brazil wax | ????0.5 | ????- | ????2 | ????- |
| Tissuemat E | ????- | ????- | ????5 | ????5 |
| Dimethyl polysiloxane | ????- | ????10 | ????- | ????10 |
| Methyl phenyl silicone | ????20 | ????- | ????10 | ????5 |
| Polyoxyethylene methyl polysilicon oxygen finishes copolymer | ????- | ????- | ????- | ????5 |
| Organic siliconresin | ????- | ????- | ????- | ????15 |
| Decamethyl five siloxanes | ????- | ????- | ????- | ????30 |
| Malic acid two isooctadecane base esters | ????10 | ????- | ????5 | ????- |
| Three glyceryl isostearates | ????- | ????10 | ????20 | ????- |
| Two glyceryl isostearates | ????23 | ????5 | ????5 | ????- |
| Three 2 ethyl hexanoic acid glyceride | ????- | ????10 | ????19.5 | ????- |
| Three (Foral isostearic acid) glyceride | ????15 | ????5 | ????- | ????15 |
| Polybutene | ????- | ????10 | ????- | ????- |
| Three isostearic acids, two glyceride | ????- | ????13 | ????10 | ????- |
| Oxygen base stearic acid isooctadecane base ester | ????- | ????10 | ????- | ????- |
| Queensland's macadamia nut oil | ????10 | ????- | ????- | ????- |
| Queensland's macadamia nut oil fatty acid cholesterol ester | ????5 | ????- | ????- | ????- |
| Three sad trimethylolpropanes | ????- | ????10 | ????5 | ????- |
| P-methoxycinnamate 2-Octyl Nitrite | ????- | ????- | ????5 | ????- |
| Hydrophobized silica | ????- | ????- | ????1 | ????- |
| Red No. 202 | ????2 | ????2 | ????2 | ????2 |
| Titanium oxide | ????0.5 | ????0.5 | ????0.5 | ????0.5 |
| Iron oxide red | ????2 | ????2 | ????2 | ????2 |
| Iron oxide black | ????0.5 | ????0.5 | ????0.5 | ????0.5 |
| Antioxidant | In right amount | In right amount | In right amount | In right amount |
| Spice | In right amount | In right amount | In right amount | In right amount |
| Shape-retaining ability | ????◎ | ????◎ | ????◎ | ????◎ |
| Ductility during coating | ????◎ | ????◎ | ????○ | ????○ |
| Glossiness | ????◎ | ????◎ | ????○ | ????○ |
| Blending constituent | Embodiment 9 |
| Fischer-Tropsch wax (1) | ????9 |
| Microwax | ????1 |
| Three glyceryl isostearates | ????20 |
| Two glyceryl isostearates | ????4 |
| Three 2 ethyl hexanoic acid glyceride | ????10 |
| Three (Foral isostearic acid) glyceride | ????30 |
| Liquid lanolin | ????5 |
| Queensland's macadamia nut oil fatty acid cholesterol ester | ????10 |
| Three sad trimethylolpropanes | ????10 |
| Pearling agent | ????1 |
| Antioxidant | In right amount |
| Spice | In right amount |
| Shape-retaining ability | ????◎ |
| Ductility during coating | ????◎ |
| Glossiness | ????◎ |
| Blending constituent | Embodiment 10 |
| Fischer-Tropsch wax (1) | ????10 |
| Microwax | ????1 |
| Dimethyl polysiloxane | ????10 |
| Two glyceryl isostearates | ????15 |
| Three 2 ethyl hexanoic acid glyceride | ????13.5 |
| Liquid lanolin | ????20 |
| Queensland's macadamia nut oil | ????15 |
| Jojoba oil | ????15 |
| Menthol | ????0.5 |
| Antioxidant | In right amount |
| Spice | In right amount |
| Shape-retaining ability | ????◎ |
| Ductility during coating | ????◎ |
| Glossiness | ????◎ |
| Blending constituent | Embodiment | |
| ????11 | ????12 | |
| Fischer-Tropsch wax (1) | ????7 | ????9 |
| Microwax | ????1 | ????1 |
| Dimethyl polysiloxane | ????10 | ????25 |
| Methyl phenyl silicone | ????5 | ????10 |
| The ring-type dimethicone | ????34.9 | ????- |
| Squalane | ????10 | ????16.9 |
| Sericite | ????12 | ????18 |
| Titanium oxide | ????15 | ????15 |
| Iron oxide red | ????1 | ????1 |
| Iron oxide yellow | ????4 | ????4 |
| Iron oxide black | ????0.1 | ????0.1 |
| Antioxidant | In right amount | In right amount |
| Spice | In right amount | In right amount |
| Shape-retaining ability | ????◎ | ????◎ |
| Ductility during coating | ????◎ | ????○ |
| Blending constituent | Embodiment 13 |
| Fischer-Tropsch wax (1) | ????14 |
| Microwax | ????2 |
| Dimethyl polysiloxane | ????14 |
| Liquid paraffin | ????10 |
| Queensland's macadamia nut oil | ????10 |
| Three 2 ethyl hexanoic acid glyceride | ????20 |
| Muscovitum | ????10 |
| Iron oxide black | ????15 |
| Iron oxide red | ????5 |
| Antioxidant | In right amount |
| Spice | In right amount |
| Shape-retaining ability | ????◎ |
| Ductility during coating | ????◎ |
| Blending constituent | Embodiment 14 |
| Fischer-Tropsch wax (1) | ????10 |
| Microwax | ????2 |
| Dimethyl polysiloxane | ????20 |
| Methyl phenyl silicone | ????20 |
| Liquid lanolin | ????15 |
| 3 2-thylhexoic acid glyceride | ????23 |
| Liquid paraffin | ????10 |
| Antioxidant | In right amount |
| Spice | In right amount |
| Shape-retaining ability | ????◎ |
| Ductility during coating | ????◎ |
| Glossiness | ????◎ |
| Gradation composition | Embodiment 15 |
| Fischer-Tropsch wax (1) | ????13 |
| Microwax | ????1 |
| Dimethyl polysiloxane (6mm 2/s?25℃) | ????5 |
| Decamethyl five siloxanes | ????3 |
| Methyl phenyl silicone | ????10 |
| Fluorine modified methyl phenyl polysiloxane | ????24 |
| Alkoxy-modified organosilicon | ????2 |
| Polyoxyethylene methyl polysiloxane copolymer | ????5 |
| " the dispersion thing A of nonaqueous polymer " * 1 | ????30 |
| Red No. 202 | ????2 |
| Titanium oxide | ????0.5 |
| Iron oxide red | ????2 |
| Iron oxide black | ????0.5 |
| Glycerol | ????1 |
| Purified water | ????1 |
| Antioxidant | In right amount |
| Spice | In right amount |
| Shape-retaining ability | ????◎ |
| Ductility during coating | ????◎ |
| Glossiness | ????◎ |
*1: " the dispersion thing A of non-water polymer "
Use the dispersion thing of synthetic non-water polymer as follows.
In the disperse medium decamethylcyclopentaandoxane of 54.9 quality %, add 15 quality % methyl methacrylate monomers, 25 quality % ethyl acrylate monomers, 0.1 quality % polymerization initiator, 5 quality % dispersion stabilizer dimethyl polysiloxane graft polymers (molecular weight about 150,000), stirred 10 hours down at 120 ℃, carry out polymerization.
Then, undertaken polymeric solution being cooled to 25 ℃ after demonomerization handles, obtain outward appearance and be milky and be that the volatility organosilicon of 1 μ m is the dispersion thing A of the non-water polymer of disperse medium with the mean diameter of dispersed polymeres particle by decompression.
The oil-in-water type lip stick
Table 10
| Blending constituent | Embodiment 16 |
| (1) Fischer-Tropsch wax (1) | ????8 |
| (2) microwax | ????2 |
| (3) oxygen base stearic acid isooctadecane base ester | ????10 |
| (4) two glyceryl isostearates | ????27 |
| (5) liquid paraffin | ????25 |
| (6) three isostearic acids two glyceride | ????20 |
| (7) dimethyl polysiloxane polyoxyethylene copolymer | ????0.5 |
| (8) purified water | ????1 |
| (9) glycerol | ????0.5 |
| (10) red No. 202 | ????2 |
| (11) titanium oxide | ????0.5 |
| (12) iron oxide red | ????2 |
| (13) iron oxide black | ????0.5 |
| (14) Queensland's macadamia nut oil fatty acid cholesterol ester | ????1 |
| (15) antioxidant | In right amount |
| (16) spice | In right amount |
| Shape-retaining ability | ????◎ |
| Ductility during coating | ????◎ |
| Glossiness | ????◎ |
Effect (1) the Solic cosmetic shape-retaining ability of the present invention of invention and use sense are excellent. Particularly the ductility of lipstick, glossiness and shape-retaining ability are excellent. (2) Wax composition of the present invention is excellent solid agent for the fluid oil composition. (3) according to the present invention, can not produce the problem of the manufacture view that causes when using high melting-point wax.
Claims (5)
1. a Solic cosmetic is characterized in that, contains (a) mean molecule quantity and be 300～1200 Fischer-Tropsch wax and (b) microwax, and both mass ratioes are (a): (b)=60: 40～99.9: 0.1.
2. the described Solic cosmetic of claim 1 wherein, further contains the fluid oil composition.
3. claim 1 or 2 described Solic cosmetics wherein, only contain the described wax of claim 1 as solid agent.
4. claim 1,2 or 3 described Solic cosmetics, wherein, above-mentioned Solic cosmetic is the lipstick that further contains coloring agent.
5. Wax composition, it is with (a): (b)=60: 40～99.9: 0.1 mass ratio, mix (a) mean molecule quantity and be Fischer-Tropsch wax of 300～1200 and (b) microwax form.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP80574/01 | 2001-03-21 | ||
| JP2001080574 | 2001-03-21 | ||
| JP80574/2001 | 2001-03-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1378833A true CN1378833A (en) | 2002-11-13 |
| CN1196460C CN1196460C (en) | 2005-04-13 |
Family
ID=18936832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021183155A Expired - Lifetime CN1196460C (en) | 2001-03-21 | 2002-03-21 | Solid cosmetic |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6740328B2 (en) |
| EP (1) | EP1243248B1 (en) |
| KR (1) | KR100678431B1 (en) |
| CN (1) | CN1196460C (en) |
| DE (1) | DE60207318T2 (en) |
| TW (1) | TWI318574B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115429720A (en) * | 2021-10-11 | 2022-12-06 | 广州花出见生物科技有限公司 | Simple lipstick and preparation method thereof |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0612181A2 (en) * | 2005-04-04 | 2010-10-26 | Du Pont | composition useful as asphalt modifier, asphalt composition, pavement and asphalt composition modification process |
| FR2888112B1 (en) * | 2005-07-11 | 2008-02-22 | Oreal | PHOTOPROTECTIVE COMPOSITION COMPRISING AN AQUEOUS PHASE AND A LOW MELT POOL APOLAR WAX |
| DE102006034026A1 (en) * | 2006-07-17 | 2008-01-24 | Beiersdorf Ag | Cosmetic pen |
| US8431642B2 (en) | 2008-06-09 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US8242198B2 (en) * | 2008-06-09 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US8283400B2 (en) | 2008-06-09 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| KR101664514B1 (en) * | 2009-03-31 | 2016-10-10 | 가부시키가이샤 시세이도 | Lip cosmetic |
| WO2010138253A2 (en) | 2009-05-29 | 2010-12-02 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and method of making thereof |
| US20150320674A1 (en) * | 2014-05-08 | 2015-11-12 | Micro Powders, Inc. | Compositions Comprising Synthetic Waxes |
| CN107849304B (en) | 2015-08-07 | 2020-12-11 | 性能材料北美股份有限公司 | Modified asphalt using phosphorous acid |
| US20200306168A1 (en) * | 2019-03-28 | 2020-10-01 | Elc Management Llc | Color Cosmetic Composition Containing Wax Blend |
| TWI838504B (en) * | 2020-03-27 | 2024-04-11 | 美商Ｅｌｃ管理公司 | Color cosmetic composition containing wax blend |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4699780A (en) * | 1985-05-29 | 1987-10-13 | Estee Lauder Inc. | Cosmetic composition |
| JP3073869B2 (en) | 1993-12-01 | 2000-08-07 | 花王株式会社 | Oily solid cosmetics |
| JP3418881B2 (en) | 1993-12-28 | 2003-06-23 | 株式会社コーセー | Oily solid cosmetics |
| JPH0859428A (en) | 1994-08-26 | 1996-03-05 | Kao Corp | Oily solid cosmetic |
| FR2734717B1 (en) * | 1995-06-02 | 1997-07-04 | Oreal | COSMETIC COMPOSITION IN FLEXIBLE PASTE FORM, PREPARATION METHOD AND USE |
| CA2242569A1 (en) * | 1996-01-16 | 1997-07-24 | The Procter & Gamble Company | Transfer-resistant lip compositions |
| JP3527017B2 (en) | 1996-06-26 | 2004-05-17 | 花王株式会社 | Oily solid cosmetics |
-
2002
- 2002-03-12 TW TW091104578A patent/TWI318574B/zh not_active IP Right Cessation
- 2002-03-15 US US10/097,579 patent/US6740328B2/en not_active Expired - Lifetime
- 2002-03-20 EP EP02006283A patent/EP1243248B1/en not_active Expired - Lifetime
- 2002-03-20 KR KR1020020014945A patent/KR100678431B1/en active IP Right Grant
- 2002-03-20 DE DE60207318T patent/DE60207318T2/en not_active Expired - Lifetime
- 2002-03-21 CN CNB021183155A patent/CN1196460C/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115429720A (en) * | 2021-10-11 | 2022-12-06 | 广州花出见生物科技有限公司 | Simple lipstick and preparation method thereof |
| CN115429720B (en) * | 2021-10-11 | 2023-12-26 | 广州花出见生物科技有限公司 | Extremely simple lipstick and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20020075254A (en) | 2002-10-04 |
| KR100678431B1 (en) | 2007-02-05 |
| US6740328B2 (en) | 2004-05-25 |
| CN1196460C (en) | 2005-04-13 |
| DE60207318D1 (en) | 2005-12-22 |
| EP1243248B1 (en) | 2005-11-16 |
| EP1243248A2 (en) | 2002-09-25 |
| EP1243248A3 (en) | 2003-05-07 |
| TWI318574B (en) | 2009-12-21 |
| DE60207318T2 (en) | 2006-08-03 |
| US20030012754A1 (en) | 2003-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1219550C (en) | Preparation method of cosmetic containg polysiloxane oil and homopolymer or copolymer ethylene wax or medicinal anhydrous composite for curing dermatosis | |
| CN1196460C (en) | Solid cosmetic | |
| CN1139374C (en) | Oil-based solid cosmetic composition | |
| CN1245941C (en) | Mascara compositions comprising water-insoluble polymeric material and water-soluble, film-forming polymers | |
| CN1338919A (en) | Composition for lipstick | |
| CN101151017B (en) | Powder-containing transparent solid cosmetic preparation | |
| CN1689638A (en) | Cosmetic pressed powder | |
| CN1231168A (en) | Topical composition comprising branched C24 to C28 fatty alcohol or acid ester | |
| CN101080253A (en) | Cosmetic composition system with thickening benefits | |
| CN107205905B (en) | Makeup cosmetic | |
| CN1092643A (en) | Moisturizing lipstick compositions | |
| CN1386063A (en) | Cosmetic or pharmaceutical solid composition comprising bis-acyl-amides | |
| JP5432656B2 (en) | Solid powder cosmetic and method for producing the same | |
| CN1226030C (en) | Oily solid cosmetics | |
| CN1173321A (en) | Ester in application of powder-stuck composition and compact powdered anhydrous composition | |
| CN1146386C (en) | Rouge and powder like cosmetic composition containing special esters | |
| CN1119981C (en) | Decorative cosmetic O/W emulsion containing no emulsion | |
| JP5236380B2 (en) | Solid powder cosmetic and method for producing the same | |
| CN1678278A (en) | Lipid preparation, particularly cosmetic preparation | |
| CN1165285C (en) | Cosmetic formulation with voluminous effect | |
| CN1787804A (en) | Oil-based cosmetic preparation | |
| CN1494415A (en) | Cosmetic composition with pasty to powdery texture | |
| JP2006036768A (en) | Cosmetic stick | |
| CN1225259A (en) | Long term stability powder cosmetics composition contg. polymer particles dispersant existing in liquid aliphatic phase | |
| CN100335023C (en) | Cosmetic composition comprising a sebum-absorbing powder and a powder with a low critical surface energy |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20050413 |