CN1369675A - Magnetically refrigerating unit of magnetic refrigerator - Google Patents
Magnetically refrigerating unit of magnetic refrigerator Download PDFInfo
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- CN1369675A CN1369675A CN02113407A CN02113407A CN1369675A CN 1369675 A CN1369675 A CN 1369675A CN 02113407 A CN02113407 A CN 02113407A CN 02113407 A CN02113407 A CN 02113407A CN 1369675 A CN1369675 A CN 1369675A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
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Abstract
A magnetic refrigerating device of magnetic refrigerator includes operation case body, magnetic refrigerating composite material block in slice shape, gap for passing heat exchanging fluid, slice type of magnetic refrigerating composite material block which is formed by two thin metal sheets of high heat conducting ability and magnetic refrigerating material powder layer in between and the slice type of magnetic refrigerating composite material block to be fixed by the slot of operation case. The pressure invention has provided a high heat exchanging ability and high efficiency magnetic refrigerating device that the heat exchanging fluid will not cantact and impact with chemical compounding type of magnetic refrigerating material in between brittle metal to avoid smashing step by step of magnetic refrigerating material when heat exchanging fluid is passing through it.
Description
The present invention relates to refrigerating field, particularly based on the magnetic refrigeration apparatus on the magnetic refrigerator of magnetothermal effect.
The magnetothermal effect of material is the physical basis of magnetic refrigerator.Material heats up or cooling after entering magnetic field, and withdraws from magnetic field cooling or intensification, utilizes heat transfer medium and magnetic refrigerating material to carry out heat exchange and promptly can reach the purpose that heats or freeze.The magnetic refrigerating material that is used for magnetic refrigerator is called magnetic refrigeration working substance.It not only should have high magnetic entropy change, and will have good heat exchange efficiency.The magnetic refrigeration working substance that traditional low temperature magnetic refrigerator or utensil adopted is that the spheric granules by 0.1～0.5mm combines, this magnetic refrigeration working substance and helium or nitrogen can carry out effective heat exchange, and formed gap can not hinder gas flow again between the spheric granules simultaneously.U.S. Pat 5593517 and US5332029 have disclosed the preparation method of the refrigeration working medium of the sphere that is used for refrigeration machine, and they are used for the low temperature magnetic refrigerator is effective.The general now rare earth metal gadolinium that adopts of the magnetic refrigeration working substance that is used near the magnetic refrigerator of room temperature, U.S.'s Ames Lab and U.S. spaceflight laboratory have disclosed at US5934078 uses metal gadolinium spheric granules as magnetic refrigeration working substance in the active shuttle type magnetic refrigerator, water carries out the technical process of heat exchange with it.Ames Lab has been set forth the characteristics of the Gd-Si-Ge series alloy that is used for the active magnetic refrigeration machine in US5743095 simultaneously, and it not only can be used for the low temperature magnetic refrigerator, also can be used for room-temperature magnetic refrigerator.Publication number is that the Chinese patent application of CN1323913A has disclosed a kind of rare earth-iron base compound with great magnetic entropy variation that is used for room temperature district magnetic refrigeration working substance, and these compounds are to be the intermetallic compound of matrix with the rare earth element.They are generally brittle substance, are pulverized under the effect of external force easily.These intermetallic compounds are made the granular magnetic refrigeration apparatus that is used for magnetic refrigerator as magnetic refrigeration working substance to carry out heat exchange with water and can reach the purpose that heats or freeze.In room-temperature magnetic refrigerator, magnetic refrigerating material is placed in the work box body of magnetic refrigeration apparatus, and the import and export of current stop with woven wire.The granularity of magnetic refrigeration working substance must keep the aperture greater than silk screen, could guarantee that this graininess working material can not washed away by current in the work box.The magnetic refrigeration working substance that existing invention is adopted is the intermetallic compound of fragility, and in the magnetic refrigerator course of work, the speed of current is bigger, generally greater than 0.5M/S.Along with the increasing of the operating frequency of magnetic refrigerator, water velocity is big more.Because collision mutually, the easy so further pulverizing that causes granular materials between the magnetic refrigerating material particle, can take place between magnetic refrigerating material and the box body in the impact of current.If size drops to the aperture that is less than or equal to silk screen, material will be gone out the work box by water, makes the quality of magnetic refrigerating material fewer and feweri like this, finally can cause the magnetic refrigerator operating efficiency to descend, even magnetic refrigerator is quit work.
The object of the present invention is to provide a kind of when heat exchanging fluid passes through, can directly not contact and collide with the intermetallic compound kind magnetic refrigerating material of fragility, avoid making it progressively to pulverize, the handling capacity of heat exchanging fluid is strong, and the exchange capability of heat of heat exchanging fluid and magnetic refrigerating material is strong, the magnetic refrigeration apparatus of high efficiency.
The objective of the invention is to realize by following technical solution: a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator, comprise the work box body of both ends open, it is characterized in that: the sheet magnetic refrigeration composite block that in this work box body, is provided with at least more than one; This sheet magnetic refrigeration composite block be parallel to each other and be formed with at least more than one along the heat exchanging fluid flow direction and the gap that can allow heat exchanging fluid flow through; This sheet magnetic refrigeration composite block is by strong two sheet metals of the capacity of heat transmission and is positioned at its intermediate magnetic refrigeration powder bed and is constituted, this sheet metal surrounding is along projection, middle recessed, two sheet metal surroundings are along being tightly connected, form cavity in the middle of making, this magnetic refrigerating material powder bed is clipped in this cavity; In this work box body, offer along the heat exchanging fluid flow direction, at least more than one be used to separate and the fixing groove of sheet magnetic refrigeration composite block.
Magnetic refrigeration principle of the present invention is to adopt sheet magnetic refrigeration composite block as heat exchange element, when needing the refrigeration heat exchange, heat exchanging fluid is clipped on the magnetic refrigeration composite block of being made up of two strong sheet metals of the capacity of heat transmission by the magnetic refrigerating material powder and realizes the refrigeration heat exchange function.In the refrigeration heat transfer process, thereby avoid heat exchanging fluid directly contact and collision magnetic refrigerating material powder, solved the impact that is subjected to heat exchanging fluid in magnetic refrigerator when fragility and granular magnetic refrigerating material use and the problem of progressively pulverizing.Because between the sheet magnetic refrigeration composite block enough gaps are arranged, the handling capacity of heat exchanging fluid is strong; The strong sheet metal of two capacity of heat transmission is arranged and wherein clamp enough magnetic cooling dusty materials because sheet magnetic refrigeration composite block adopts, so the high efficiency of magnetic refrigerator, exchange capability of heat is strong.
Sheet magnetic refrigeration composite block of the present invention (1) is to be the left sheet (2) and the right sheet (3) of the strong sheet metal of 0.02mm～0.1mm capacity of heat transmission such as copper sheet or aluminium flake by thickness, and the magnetic refrigerating material alloy powder layer (4) in the middle cavity (5) that is formed by left sheet (2) and right sheet (3) forms, and the freeze thickness of composite block (1) of magnetic is 0.1～2mm.The appearance and size of magnetic refrigerator job box body (7) is determined according to the magnetic refrigerator actual design.Adopt mould molding left side sheet (2) and right sheet (3), the degree of depth of mold cavity is 0.1～0.9mm, the mold cavity depth-adjustment.The surrounding of moulding left side sheet (2) and right sheet (3) is 5mm along width, with magnetic refrigerating material alloy powder layer (4) pack into cavity (5) after vibration and pressing, is tightly connected with special tooling.The aperture (6) of reserving φ a 0.1～1mm on an end edge of magnetic refrigeration composite block (1) is used to bleed, and its internal pressure is reached be not more than 3Pa, forms vacuum, at last aperture (6) is sealed.Then the edge is trimmed to and size that the groove (8) of the box body of working adapts, has just made sheet magnetic refrigeration composite block (1).Magnetic refrigerating material alloy powder layer (4) can adopt Gd-Si-Ge series alloy powder, also can adopt the magnetic refrigeration dusty material of other type.These powder systems adopt breaking method to become 60～200 orders.The purpose that vacuumizes, be to remove air, and magnetic refrigeration powder bed (4) and left sheet (2) and right sheet (3) are compressed, thereby guarantee the thermal conductivity of material, by the volume ratio of the volume of left sheet (2) and right sheet (3) and magnetic refrigeration powder bed (4) less than 10%, the influence that the adiabatic temperature of magnetic refrigeration powder bed (4) in magnetic field become is not more than 10%, but the not loss of the total amount of heat of magnetic refrigerating material heating.The wall thickness of work box body (7) is 1～2mm, process a series of grooves that are parallel to each other (8) on one side at work box body (7), spacing between the groove (8) is 0.11～2.5mm, be used for separating and fixing sheet magnetic refrigeration composite block (1), wide 0.1～the 1mm of groove (8), dark 0.5～1mm inserts sheet magnetic refrigeration composite block (1) in the groove (8), and the width in the gap (9) that sheet magnetic refrigeration composite block (1) forms each other is 0.01～0.5mm.The volume occupation rate of magnetic refrigerating material powder bed (4) is about (60～80) % of work box body (7) like this.At the open-ended place of work box body (7), be fixed with a catch (10), be subjected to displacement along the direction that heat exchanging fluid flows to prevent sheet magnetic refrigeration composite block (1).
Below in conjunction with accompanying drawing embodiments of the invention are described further.
Fig. 1 is sheet magnetic refrigeration composite block structural diagram.
Fig. 2 is the magnetic refrigeration apparatus structure chart.
Fig. 3 is sheet magnetic refrigeration composite block and work box body assembling relationship figure.
According to Fig. 1, sheet magnetic refrigeration composite block (1) by thickness be the 0.02mm copper sheet or left sheet (2) and right sheet (3) and be positioned in the middle of it Gd-Si-Ge alloy powder layer (4) of cavity (5) and form, the freeze thickness of composite block (1) of its magnetic is 0.64mm.At a work box body (7) of magnetic refrigerator, it is of a size of length * wide * height=80mm * 20mm * 30mm, adopts the right sheet (3) of diel moulding red copper left side sheet (2) and red copper, and the depth of cavity of this diel is 0.3mm, the mold cavity depth-adjustment.The mould concave die cavity is of a size of 28mm * 80mm, the red copper left side sheet (2) after the shaping and the surrounding of right sheet (3) are 5mm along width, with pack into cavity (5) after vibration and flatten of Gd-Si-Ge alloy powder layer (4), lump together by the soldering after melting with the edge of pressure sintering two copper sheet left side sheets (2) and right sheet (3), the aperture (6) of reserving a φ 0.5mm on an end edge of magnetic refrigeration composite block (1) is used to bleed, then it being inserted vacuum is not more than and keeps in the vacuum tank of 3Pa being no less than 4 minutes, with the point-like thermal head with aperture (6) welding jail after, the edge is trimmed to 1mm has just made sheet magnetic refrigeration composite block (1).This Gd-Si-Ge alloy powder layer (4) can adopt Gd
5Si
2Ge
2Alloy powder or Gd
5Si
4Alloy powder also can adopt the magnetic refrigeration dusty material of other type.The broken earlier back of these powder systems becomes 60～200 orders with the ball mill grinding.
According to Fig. 2 and Fig. 3, the wall thickness of work box body (7) is 1mm, process a series of grooves that are parallel to each other (8), spacing between the groove (8) is 0.8mm, be used for separating and fixing sheet magnetic refrigeration composite block (1) the dark 0.5mm of groove (8), wide 0.15mm, sheet magnetic refrigeration composite block (1) is inserted in the groove (8), and the gap (9) that sheet magnetic refrigeration composite block (1) forms each other is 0.16mm.The volume occupation rate of magnetic refrigerating material powder bed (4) is about about 70% of work box body (7) like this.At the open-ended place of work box body (7), be fixed with a catch (10), be subjected to displacement along the direction that heat exchanging fluid flows to prevent sheet magnetic refrigeration composite block (1).
Advantage of the present invention is that the handling capacity of heat exchanging fluid is strong, high efficiency, and exchange capability of heat is strong, and is whole Magnetic refrigeration apparatus is installed in the mechanism of moving in circles of magnetic refrigerator, and its installation, dismounting and replacing are very convenient, Be conducive to batch production.
Claims (10)
1, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator comprises it is characterized in that the work box body of both ends open: the sheet magnetic refrigeration composite block that is provided with at least more than one in this work box body; This sheet magnetic refrigeration composite block be parallel to each other and be formed with at least more than one along the heat exchanging fluid flow direction and the gap that can allow heat exchanging fluid flow through; This sheet magnetic refrigeration composite block is made up of strong two sheet metals of the capacity of heat transmission and magnetic refrigerating material powder bed of being clipped in the middle of it, this sheet metal surrounding is along projection, middle recessed, the edge of projection is tightly connected around these two sheet metals, form cavity in the middle of it, this magnetic refrigerating material powder bed is positioned at this cavity; In this work box body, offer along the heat exchanging fluid flow direction, at least more than one be used to separate and the fixing groove of sheet magnetic refrigeration composite block.
2, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1 is characterized in that the thickness of this sheet magnetic refrigeration composite block is 0.1～2mm.
3, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1 is characterized in that described sheet metal is the thick copper sheet of 0.02～0.1mm.
4, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1 is characterized in that described sheet metal is the thick aluminium flake of 0.02～0.1mm.
5, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1 is characterized in that the cavity in this sheet magnetic refrigeration composite block is a vacuum.
6, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1 is characterized in that the spacing between this groove is 0.11～2.5mm.
7, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1 is characterized in that described magnetic refrigeration powder is the Gd-Si-Ge alloy powder.
8, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 7 is characterized in that this Gd-Si-Ge alloy powder is 60～200 purpose Gd
5Si
2Ge
2Alloy powder.
9, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1, the width that it is characterized in that this gap is 0.01～0.5mm.
10, a kind of magnetic refrigeration apparatus that is used on the magnetic refrigerator according to claim 1 is characterized in that the two ends of described work box body are fixedly connected with the catch that can prevent that sheet magnetic refrigeration composite block is subjected to displacement along the heat exchanging fluid flow direction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021134073A CN1242228C (en) | 2002-03-01 | 2002-03-01 | Magnetically refrigerating unit of magnetic refrigerator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021134073A CN1242228C (en) | 2002-03-01 | 2002-03-01 | Magnetically refrigerating unit of magnetic refrigerator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1369675A true CN1369675A (en) | 2002-09-18 |
| CN1242228C CN1242228C (en) | 2006-02-15 |
Family
ID=4742598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021134073A Expired - Fee Related CN1242228C (en) | 2002-03-01 | 2002-03-01 | Magnetically refrigerating unit of magnetic refrigerator |
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| Country | Link |
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| CN (1) | CN1242228C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100368742C (en) * | 2004-10-28 | 2008-02-13 | 四川大学 | Natural convection heat transfer type room-temperature magnetic Refrigerator |
| CN101512250B (en) * | 2006-07-10 | 2011-01-12 | 大宇电子株式会社 | Shuttle type magnetic refrigerator |
| CN101517337B (en) * | 2006-11-09 | 2011-11-16 | 利勃海尔-家用电器奥克森豪森有限责任公司 | Refrigerator and/or freezer |
| CN101765892B (en) * | 2007-02-12 | 2013-10-02 | 真空熔焠有限两合公司 | Article for magnetic heat exchange and method of manufacturing same |
| CN103822412A (en) * | 2014-02-28 | 2014-05-28 | 华南理工大学 | Active heat regenerator for room temperature magnetic refrigerator |
| CN104662380A (en) * | 2012-08-01 | 2015-05-27 | 制冷技术应用股份有限公司 | One-piece part including a magnetocaloric material not including an alloy including iron and silicon and a lanthanide, and heat generator including said part |
| CN105823263A (en) * | 2015-01-06 | 2016-08-03 | 青岛海尔智能技术研发有限公司 | Magnetic refrigeration equipment |
| CN110887268A (en) * | 2019-10-14 | 2020-03-17 | 珠海格力电器股份有限公司 | Magnetic refrigeration regenerator and magnetic refrigeration system |
| WO2021083129A1 (en) * | 2019-10-30 | 2021-05-06 | 中国长江三峡集团有限公司 | Magnetic refrigeration heat exchanger and refrigeration heating system and method |
-
2002
- 2002-03-01 CN CNB021134073A patent/CN1242228C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100368742C (en) * | 2004-10-28 | 2008-02-13 | 四川大学 | Natural convection heat transfer type room-temperature magnetic Refrigerator |
| CN101512250B (en) * | 2006-07-10 | 2011-01-12 | 大宇电子株式会社 | Shuttle type magnetic refrigerator |
| CN101517337B (en) * | 2006-11-09 | 2011-11-16 | 利勃海尔-家用电器奥克森豪森有限责任公司 | Refrigerator and/or freezer |
| CN101765892B (en) * | 2007-02-12 | 2013-10-02 | 真空熔焠有限两合公司 | Article for magnetic heat exchange and method of manufacturing same |
| CN104662380A (en) * | 2012-08-01 | 2015-05-27 | 制冷技术应用股份有限公司 | One-piece part including a magnetocaloric material not including an alloy including iron and silicon and a lanthanide, and heat generator including said part |
| US10101062B2 (en) | 2012-08-01 | 2018-10-16 | Cooltech Applications | One-piece part including a magnetocaloric material not including an alloy including iron and silicon and a lanthanide, and heat generator including said part |
| CN112797664A (en) * | 2012-08-01 | 2021-05-14 | 法国布雷维茨公司 | Monolithic component comprising magnetocaloric material without alloy comprising iron and silicon and a lanthanide and heat generator comprising such a component |
| CN103822412A (en) * | 2014-02-28 | 2014-05-28 | 华南理工大学 | Active heat regenerator for room temperature magnetic refrigerator |
| CN105823263A (en) * | 2015-01-06 | 2016-08-03 | 青岛海尔智能技术研发有限公司 | Magnetic refrigeration equipment |
| CN105823263B (en) * | 2015-01-06 | 2022-10-28 | 青岛海尔智能技术研发有限公司 | Magnetic refrigeration equipment |
| CN110887268A (en) * | 2019-10-14 | 2020-03-17 | 珠海格力电器股份有限公司 | Magnetic refrigeration regenerator and magnetic refrigeration system |
| WO2021083129A1 (en) * | 2019-10-30 | 2021-05-06 | 中国长江三峡集团有限公司 | Magnetic refrigeration heat exchanger and refrigeration heating system and method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1242228C (en) | 2006-02-15 |
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Granted publication date: 20060215 |