CN1366565A - Non-permanent softening finishing of textile piece goods in jet-dyeing machines, and compositions suitable for this purpose - Google Patents

Non-permanent softening finishing of textile piece goods in jet-dyeing machines, and compositions suitable for this purpose Download PDF

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Publication number
CN1366565A
CN1366565A CN 01800785 CN01800785A CN1366565A CN 1366565 A CN1366565 A CN 1366565A CN 01800785 CN01800785 CN 01800785 CN 01800785 A CN01800785 A CN 01800785A CN 1366565 A CN1366565 A CN 1366565A
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scope
acid
parts
weight
dispersion
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伯纳德·丹纳
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Clariant Finance BVI Ltd
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Clariant Finance BVI Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/405—Acylated polyalkylene polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/419—Amides having nitrogen atoms of amide groups substituted by hydroxyalkyl or by etherified or esterified hydroxyalkyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0036—Dyeing and sizing in one process
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D06P1/6496—Condensation products from carboxylic acids and hydroxyalkyl amine (Kritchewski bases)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D06P1/6497—Amides of di- or polyamines; Acylated polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/06—After-treatment with organic compounds containing nitrogen
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Aqueous dispersions (W) which comprise the following components: (A) at least one condensation product of at least one C12-24-fatty acid or at least one low-molecular-weight alkyl ester thereof with 2-[( beta -hydroxyethyl)-amino]-ethylamine, (B) at least one (C12-24-fatty acid)-[ gamma -(N,N-dimethylamino)-propyl]amide, and (C) at least one low-molecular-weight carboxylic acid, and optionally (D) at least one oligoethylene glycol, liquid at ambient temperature, and/or (E) at least one formulation additive, and are substantially free from dispersion-modifying other additives (Z), in particular concentrated dispersions (W'), are eminently suitable as softener compositions for the non-permanent, softening finishing of dyed and/or optically brightened textile piece goods in rope form or tubular form by exhaust methods from aqueous liquors in jet dyeing machines.

Description

The softening composition of handling and being suitable for this purposes of the impermanency of fabric in the jet-dyeing
The fabric-softening that carries out in the jet-dyeing is handled, particularly impermanency is softening handles, have serious problems: the treatment fluid in these machines is subjected to the pressure of very strong continuous variation, wherein shearing force becomes and to cause corresponding reagent treatment to become unstable greatly, makes treatment fluid like this and/or the material performance minimizing handled and/or be damaged.To dyeing or in the softening processing of glazing fabric, particularly in identical jet-dyeing, to dye or the glazing fabric be further processed dyeing separately or go up photoreduction process and can not destroy by processed reagent, and the feel of fabric significantly improves, and this is very important.The quality of the waste water of discharging in the process is also very important, and therefore, people also expect to allow softening agent as far as possible progressively be formed on the substrate.
Have been found that, by using the composition (W) that defines below, can solve basically or overcome above-mentioned problem of mentioning and difficulty with wonderful plain mode, and satisfy the above-mentioned requirement of mentioning basically, obtain the softening treatment product of high-quality impermanency.
The purposes of the composition (W) that the present invention relates to define, be used for jet-dyeing to dye and/or the fabric of glazing carry out that impermanency is softening to be handled, relate to the concentrated dispersion build of composition (W) and relate to their preparation.
First main purpose of the present invention is the purposes of (W) aqueous dispersion as softener composition, it be used for jet-dyeing use the method (exhaustmethod) from the aqueous solution, contaminated to dyeed and/or the rope form of glazing or tubing carry out that impermanency is softening to be handled, wherein dispersion comprises following component:
(A) at least a by at least a C 12-24Aliphatic acid or at least a C 12-24The micromolecular Arrcostab of aliphatic acid and 2-[(beta-hydroxyethyl)-amino]-product of ethamine condensation,
(B) at least a (C 12-24Aliphatic acid)-[γ-(N, N-dimethylamino)-propyl group]-acid amides and
(C) at least a low molecular weight carboxylic acid,
With optional
(D) at least a at room temperature is the low polyethylene glycol of liquid, and/or
(E) at least a formulation additives,
And do not contain other additives (Z) of improvement diffusion substantially.
Condensation product (A) is known or can particularly uses the 2-[(beta-hydroxyethyl with known method preparation in principle)-amino]-ethamine and C 12-24Aliphatic acid dehydration carrying out acylation reaction or and C 12-24Corresponding small molecular alcohol is sloughed in the micromolecule Arrcostab reaction of aliphatic acid.Select aliphatic acid or its Arrcostab and 2-[(beta-hydroxyethyl to help forming the mode that contains the diacyl condensation compound)-amino]-mol ratio of ethamine; Mol ratio is preferably＞1.1/1 and＜2.5/1, preferred 1.2/1 to 2.2/1 scope is preferably 1.4/1 to 2/1 especially.
Suitable fatty acids can be desirable arbitrarily, preferred 12 to 24 carbon atoms, the linear fatty acid of 14 to 22 particularly traditional carbon atoms, preferred saturated fatty acid is laurate, myristic acid, palmitic acid, stearic acid, arachidic acid and docosanoic acid for example.Can use independent acid and the acid of technical grade (acid blend), for example hydroxylation tallow fatty acid, hydroxylation technical grade oleic acid or hydroxylation technical grade behenic acid.In described acid, preferably have the acid of 14 to 18 carbon atoms and the mixture of these sour technical grades.The micromolecule Arrcostab that carries out condensation is mainly C for for example by the alkyl (for example methyl, ethyl, isopropyl or normal-butyl) of 1 to 4 carbon atom 1-2Alkyl, particularly methyl, the ester of formation.About fatty acid alkyl esters and aliphatic acid, preferred fatty acid.
Condensation reaction is suitable for carrying out in anhydrous medium, and the simplest is the situation that does not have solvent, for example under 140 to 200 ℃ of temperature conditions, preferred 170 to 190 ℃, is suitable for carrying out and/or being suitable for reduced pressure under inert gas (for example under the blanket of nitrogen) condition.
Acylation reaction occur in primary amine, secondary amine and or oh group on, along with the variation of mol ratio, can form single acidylate, two acidylates and/or three acidylate products, acylation reaction is mainly amidation process, and basically forms acyclic product.Acylate is the open chain product substantially.Especially, N-[(beta-hydroxyethyl)-amino]-(A) that ethylenediamine and described aliphatic acid form can be the monoamide of monoamide, diamides, band ester and the diamides of band ester, main compound is a following formula:
R-CO-NH-CH 2-CH 2-NH-CH 2-CH 2-OH (I)
R-CO-NH-CH 2-CH 2-N(CO-R)-CH 2-CH 2-OH (II)
R-CO-NH-CH 2-CH 2-NH-CH 2-CH 2-O-CO-R (III)
And/or R-CO-NH-CH 2-CH 2-N (CO-R)-CH 2-CH 2-O-CO-R (IV)
Wherein R-CO-is C 12-24Fatty acid group.
Condensation product (A) comprises one or more suc as formula (I), (II), (III) and product (IV) substantially, (A) the preferred mixture of these compounds, its Chinese style (I), (II) and (III) more preferably.
Be in particular following formula
(H 3C) 2N-CH 2-CH 2-CH 2-NH-CO-R (V)
(C 12-24-aliphatic acid)-[γ-(N; the N-dimethylamino) propyl group] acid amides is preferably component (B), and it is known and/or can be similar to the method for above-mentioned (A) with known method preparation; mainly be to use γ-(N, N-dimethylamino) propylamine and aliphatic acid or its micromolecule Arrcostab to carry out acylation reaction.Acylation reaction begins to suit to carry out under gentle relatively temperature, particularly is lower than the boiling point of γ-(N, N-dimethylamino) propylamine, and suitable scope is 100 to 130 ℃, and temperature can raise then, and preferred 130 to 190 ℃, preferred 150 to 190 ℃ of end temperature.Amidation process can be chosen wantonly under inert atmosphere and/or under the reduced pressure and carry out, and does not preferably have solvent.
In this way Zhi Bei product (A) and (B) can mix mutually promptly mixes when fusion, and then cooling mixture for example forms the drying type of wandering grain, for example particle, bead or fritter simultaneously.
In accordance with a specific feature of the present invention,, two acylation reactions, promptly about the 2-[(beta-hydroxyethyl)-amino]-ethamine and γ-(N, N-dimethylamino) propylamine, can carry out in a step, for example two kinds of amine are mixed mutually, to improve constantly the mode of temperature, use the total amount of desired fats acid separately or effective for treatment of premature ejaculation to carry out acylation reaction then, begin to be mild temperature, particularly＜130 ℃, elevated temperature is finished reaction then; Perhaps originally introduce aliphatic acid or fatty acid alkyl esters separately, then under＜130 ℃ of conditions, at first add γ-(N, the N-dimethylamino) propylamine, then under higher temperature, under preferred 130-150 ℃, add the 2-[(beta-hydroxyethyl)-amino]-ethamine, further improve under preferred 150 to 190 ℃ of the temperature and finish reaction.With the mixture cooling, form the drying type of wandering grain simultaneously, for example particle, bead or fritter as mentioned above.
(B)/(A) weight ratio scope is preferably from 6/100 to 60/100, and preferred 10/100 to 40/100, preferred especially 13/100 to 30/100.
Can prepare composition (W) by simple mode, particularly mix with (A) and mixture (B) and water with (C), and randomly mixed composition (D) and (E) at least a component.
(C) that be fit to is in particular the aliphatic monocarboxylic acid, and saturated is more excellent, is mainly to contain 1 to 3 carbon atom preferable formic acid, acetate, propionic acid and lactic acid, wherein preferred especially acetate.
Component (B) also is similar to formula (V), contain one can be protonated uncle's amino.Along with the degree of acidylate, component (A) contains amino alkalescence, can be protonated of different amounts, mainly is similar to formula (I) and (III).Can by the quantity of determining amine estimate can protonated amino content.(A) quantity of amine is equivalent to every gram condensation product 30 to 100 in, and is preferred 50 to 80, preferred especially 55 to 70 milligrams of KOH.
(C) content is preferably in (A)+(B) whenever amino 0.5 equivalent (C) that uses of the total alkalescence of amount at least.Mixture (A)+(B) is preferably protonated fully, promptly uses 〉=1 equivalent (C) whenever measuring alkalescence amino in preferred (A)+(B).Preferably every molar equivalent alkalescence amino uses 0.5 to 6 molar equivalent (C) in (A)+(B), and the amino use 1 to 5 of every molar equivalent alkalescence in preferred (A)+(B) especially especially is 1.5 to 4 molar equivalents (C).
Its aqueous solution of use is suitable in acid (C), for example provides all required water of product (W) or only a part of as the solution of determining amount (C), for latter event, regulates required accurate concentration by adding water again.About the mixing of condensation product (A), acid amides (B), water and acid (C), suitable to elevated temperature, for example 30 to 85 ℃ of scopes, under preferred 50 to 75 ℃ of conditions, dumpable mixture (A)+(B) is joined in the aqueous solution of acid (C) and finish.
Suitable (D) is generally in room temperature (=20 ℃) and is the low polyethylene glycol of liquid, particularly those mean molecule quantities M WBetween 150 to 400, preferred 200 to 400 (for example Macrogol 200,300 or 400), and do not comprise list or diethylene glycol in fact.Component (D) is decided with the need.(D)/(A) weight ratio can for, for example in from 0 to 300/100 the scope.Exist in (W) according to the present invention a certain proportion of (D); (D)/(A) weight ratio preferably between 20/100 to 260/100, preferred especially 35/100 to 140/100 scope.
According to the present invention, the aqueous dispersion of use (W) is not improved the additive (Z) of diffusion substantially.By adding improvement diffusion additive (Z), the kenel of product and/or the amount of other products have been determined, significant variation (particularly damage or weakened performance, for example viscosity, flowability, storage stability etc.) has taken place in the stability of their surface, physical aspect and/or composition or their performance.
(Z) be mainly big molecule and/or water-insoluble compound and/or have the compound of three or more hydroxyls, it may be present in the fabric treatment composition in addition, but in composition of the present invention, it has opposite effect for preparation, stability and/or performance.Add (Z) and mean the polymerization of unsaturated monomers thing of sneaking into wax, fat or oil and/or their derivative, epoxides, alkyl or hydroxy alkyl ester, saccharide and saccharide derivative, polysiloxane or ethene.And the weight concentration based on (W) is＞1%, and the weight concentration that is preferably based on (W) especially is for only＞0.5%.
(W) also can choose wantonly and contain one or more and plant formulation additives (E), it is used to keep the physical aspect of dispersion (W) substantially.
This formulation additives is mainly
(E 1) at least a reagent that is used for the prophylaxis of microbial infringement, and/or
(E 2) at least a defoamer.
Suitable (E 1) be generally common commercial product, can commercial buy obtain be used to suppress harmful microorganism (fungi or bacterium) growth agents or biocides (for example fungicide or bactericide), usually recommend to use low concentration, for example based on dispersion (W)＜concentration of 0.5 weight %, preferred＜0.1 concentration of weight %, the concentration of special＜0.02 weight %.
About (E 2), generally may be with some needed defoamers, it is generally the known aqueous solution or can commercial buys, for example polysiloxanes, oil, hydrophobic silicic acid or ethylenediamine and have aliphatic acid than high saturation (C for example 16-30C particularly 18-24) diamides that forms, be mainly distearyl acid acetamide.When transportation or carrying or use when not having the dispersion (W) of defoamer, can temporarily form foam, add (E 2) can quicken or help disappearing of the temporary transient foam that forms substantially.Correspondingly, (E 2) use amount very little, for example the weight concentration based on (W) is＜1%, preferred＜0.5%, especially＜0.2%.If (E 2) during for the mixture of the compound of compound or the above-mentioned type of mentioning (Z), the concentration of product is also very little, to such an extent as to it can not produce the physical aspect that adverse effect changes dispersion (W), i.e. (E on the meaning of (Z) 2) not other " improvement diffusion " additive.
(E)/(A) weight ratio is for example in 0 to 6/100 scope, to be suitable for to be lower than 4/100 preferred 0.01/100 to 2/100 scope, preferred especially 0.05/100 to 1/100.
(E 1The weight ratio of)/(A) is for example in 0 to 1/100 scope, to be suitable for to be lower than 0.5/100 preferred 0.001/100 to 0.2/100 scope, preferred especially 0.002/100 to 0.1/100.
(E 2The weight ratio of)/(A) is for example in 0 to 5/100 scope, to be suitable for to be lower than 3/100 preferred 0.01/100 to 1.8/100 scope, preferred especially 0.045/100 to 0.9/100.
When component (A), (B), (C) and at least a portion water have mixed mutually, can add other additive (D) and/or (E).Component (E) is suitable for aqueous solution form (can commercially buy in principle and obtain) and adds.If necessary, can further add entry at last and accurately regulate concentration.
Dispersion (W) mainly comprises (A), (B), (C) and water, and optional add (D) and/or (E).
About dispersion (W), be suitable for the dispersion that preparation concentrates (W '), particularly dry matter weight content scope is 8 to 60% in the dispersion, preferred 9 to 40%, preferred especially 10 to 30%, wherein to be suitable for be 4 to 50% to (A) content range, preferred 6 to 30%, preferred especially 7 to 20%; Component (B), (D) and (E) with respect to the weight ratio of component (A), and component (C) is suitable in the scope of foregoing detailed description with respect to the mol ratio of whole (A)+(B).
Composition (W) particularly (W ') is preferably acidity or alkalescent.The pH value scope of concentrate composition (W ') is preferably 3 to 8, preferred 3.5 to 7, preferred especially 4 to 6.
Composition (W) and (W ') are generally liquid, particularly fluid, and they are preferably≤1000cP in the viscosity of room temperature, and be preferred≤500cP, and particularly at first the range of viscosities of (W ') is 30 to 500cP, and special preferable range is 40 to 200cP.
The present invention is specific themes as these dispersions that do not contain (Z) that concentrate (W '), wherein the weight content of (A) is 4 to 50%, the weight content of dry matter is 8 to 60%, viscosity≤1000cP under its room temperature, component (B), (D) and (E) with respect to the weight ratio of component (A), and component (C) with respect to the mol ratio of whole (A)+(B) in the scope of foregoing detailed description.Particularly in (W ')
Weight ratio (B)/(A) is in 6/100 to 60/100 scope
Weight ratio (D)/(A) is in 0 to 300/100 scope
And weight ratio (E)/(A) is in 0 to 6/100 scope
(C) content is (C) whenever the amino use of amount alkalescence at least 0.5 equivalent in whole (A)+(B).
In (W ') preferred and particularly preferred (B)/(A), (D)/(A) and (E)/(A) content of value and preferred and particularly preferred (A) content, (C) content and pH value, dry matter and viscosity all as above (W) described.
The present invention is specific themes as concentrated dispersion (W '), and with described concentration and quantity ratio, it mainly comprises (A), (B), (C) and water, and optionally contains (D) and/or (E).
The dispersion that can concentrate with the preparation of aforesaid method (W ').Particularly, prepare being characterized as of these condensed water dissolubility softener compositions (W '), with being respectively (A) of essential quantity ratio and (B) mixture and water, (C) mix, and at least randomly add be respectively must the quantity ratio (D) and one of (E).
Dispersion (W) particularly (W ') is highly stable under general storage and temperature conditions, and also very stable for the effect of high shear force, is highly suitable for and handles fabric in the jet-dyeing.They are the liquid with high fluidity, so can weight feed.They can be used as softening agent, and the softening processing of impermanency has been dyeed or the fabric of glazing in jet-dyeing.Fabric can be for any form, particularly rope form that are adapted at handling in the jet-dyeing or tubulose.It is mainly woven or braided fiber, and can comprise any fibrous material as common fabric fibre, fibrous material particularly natural, the selectivity sex change or semi-synthetic and/or full composite fibre materials.About natural, the selectivity sex change or semisynthetic fibre material, should mention especially, the cellulose fibre of selectivity sex change (for example cotton of cotton, hemp, flax, mercerising processing), regenerated cellulose (viscose or lyocel), cellulose ethanoate and polyamide natural, the selectivity sex change (for example wool and Hercoset wool).About synthetic fiber, need mention for example polyester, polyamide, polyurethane and acrylate copolymer.The blending thing of that the substrate that mainly is suitable for technology of the present invention comes from natural fabric and/or comes from sex change or semisynthetic fibre and they and synthetic fiber (for example fiber blend thing or woven or weave blend fibre for example cotton/polyester, cotton/polyester/elastomer or wool/polyamide).
Substrate is colored or glazing.Being used for the dyestuff of this purpose or glazing agent can be any dyestuff or the glazing agent that is suitable for substrate usually in principle, for example direct dyeing agent, REACTIVE DYES, acid stain, basic stain, SULPHUR DYES, reducing dye and be used in particular for the DISPERSE DYES of synthetic fiber.About the optics glazing agent, according to circumstances the substrate with glazing uses, particularly anion or CATION glazing agent or dispersion glazing agent.
Technology by any conventional can be with substrate staining or glazing, in preferred operation, with substrate staining or glazing, and then handles with (W) in same jet-dyeing.Because preferably substrate natural or the selectivity sex change is dyeed or glazing, so preferred anionic coloring agent (being mainly direct dyeing agent, REACTIVE DYES, acid stain) or anion glazing agent at jet-dyeing.
Can after dyeing or glazing, directly soften processing according to the present invention with (W), according to the dyeing situation, be suitable in washing or if necessary use the washing of soap (for use the REACTIVE DYES situation) and clear water or optional one (for example glazing or use direct or acid stain), carry out after also can be with clear water and if necessary choose wantonly after fixation and carry out.
According to the present invention, the operation of using (W) to handle in the conventional jets dyeing machine of wanting of can in officely what is the need for and with the conventional material and the liquid fraction of any needs, for example substrate/liquid fraction scope is 1: 5 to 1: 20, preferred 1: 6 to 1: 12.According to the substrate difference of dyeing or glazing, the pH value of liquid should be in acidity to weakly alkaline scope, and for example pH value scope is 4 to 8.5, is suitable for 4.5 to 8, and preferred 5 to 8.Handling operation can carry out under mild temperature, for example from room temperature to 70 ℃ scope, is suitable for from 25 to 60 ℃, preferably from 30 to 50 ℃.The concentration of aqueous solution of the composition (W) that uses is advisable to satisfy corresponding softening processing requirements.Even relatively low (A)+(B)+(C) concentration also can satisfy effectively softening the processing, for example calculate not protonated yet component (A)+(B), based on dry matter, the weight concentration scope from 0.02 to 4% of whole (A)+(B), preferred 0.05 to 2%, preferred especially 0.1% to 1%.
In fact in softening process, interfering friction or fold can not take place, and can ideally finish technical process.From machine, remove the material of handling then, optional more centrifugal and dry.
Softener composition has suitable affinity to substrate, can on substrate, progressively form up hill and dale during on the one hand for processing in jet-dyeing, to such an extent as to behind the substrate staining of handling, they can represent its softening function fully, on the other hand in order to be attached on the substrate in unsettled mode, they can carry out the impermanency processing like this, suitable or need in, be suitable for when the material piece of handling becomes material (for example becoming the commodity of cloth or other application), can wash away from substrate.
The softening method of handling of this usefulness (W) has volatile characteristics, and the softening material of handling is soft, comfortable and not sliding according to the present invention, is suitable as very much the material of exquisite goods.
In the following embodiments, part refers to weight portion, and percentage refers to percentage by weight; The temperature that provides is a Celsius temperature.In Application Example, application can commercial obtain, activity substance content is 25% dyestuff, and described concentration is based on this dyestuff.C.I. representative color index, dH is German intensity.
Defoamer and biocide among the embodiment are as follows:
" Silikon Antischaumemulsion SE 2 " (obtaining) from German Wacker Chemie, it is the silicone aqueous emulsion of 23% non-electrolysis, its pH value is 3.5-5.0.
It is chlorination 2-methyl-4-isothiazoline-3-ketone aqueous hydrochloric acid solution of 1.5% for " Saniprot9480 " (obtaining from Switzerland Sanitized).
Embodiment 1
1.1 condensation product (A 1) preparation
Under blanket of nitrogen, 435 parts of technical grade stearic acid (acid number 207.5) (stearic acid and palmitic acid mixture) are heated to 180 ℃, in 3 hours, 98 parts of N-(2-ethoxy)-ethylenediamine is quantitatively added then, collect the water of reaction generation and distillate (about 29 parts) with separator during this time, after adding amine, continuation was reacted 60 minutes down at 180 ℃, and was evacuated down to 100 millibars.After 1 hour, product is cooled to 80 ℃ and discharge.
1.2 acid amides (B 1) preparation
Under blanket of nitrogen, 324 parts of technical grade stearic acid (acid number 207.5) (stearic acid and palmitic acid mixture) are heated to 100 ℃, temperature between 100 to 110 ℃, add 134.6 parts of 3-dimethylamino-1-propylamine, behind the adding amine reactant mixture was heated to 130 ℃ in 60 minutes, kept 3 hours down at 130 ℃, in 6 hours, be heated to 180 ℃ then, kept 5 hours down at 180 ℃, be evacuated down to 60 millibars, product is cooled to 100 ℃ and discharge.In the whole condensation reaction, distillate 12.2 parts of amine and 21.6 parts of water.
1.3 dispersion (W 1) preparation
With 108.3 parts of condensation product (A 1) and 21.7 parts of acid amides (B 1) mix mutually, be heated to fusing point, stir and be processed into graininess, cooling joins 130 parts of this spherical mixtures in 19.5 parts of glacial acetic acid solutions that are dissolved in 773.5 parts of water while stirring again.After being heated to 60 ℃, under this temperature, continue again to stir 60 minutes, then cool to room temperature.Obtain meticulous dispersion with high fluidity, at first sneak into 75 parts of Macrogol 200s, then add 1 part of Silikon Antischaumemulsion SE2 (obtaining) and 1 part of Saniprot 9408 (obtaining) from Switzerland Sanitized from German WackerChemie.Discharge composition, obtain 1000 parts of dispersion (W 1).
Embodiment 2
2.1 condensation product (A 2) preparation
Operation as embodiment 1.1 descriptions, difference is, replace 435 parts of technical grade stearic acid with 435 parts of pure stearic acid (gas chromatographic detection 90-95%) (acid number 196.8), use 93.6 parts of N-(2-ethoxy)-ethylenediamine to replace 98 parts, and 27.5 parts of water that reaction generates are distillated.
2.2 acid amides (B 2) preparation
Operation as embodiment 1.2 descriptions, difference is, replace 324 parts of technical grade stearic acid with 324 parts of pure stearic acid (gas chromatographic detection 90-95%) (acid number 196.8), use 127.8 parts of 3-dimethylaminos-1-propylamine to replace 134.6 parts, 11.6 parts of amine and 20.5 parts of water are distillated.
2.3 dispersion (W 2) preparation
As the operation that embodiment 1.3 describes, difference is, with 108.3 parts of condensation product (A 2) and 21.7 parts of acid amides (B 2) 108.3 parts of condensation product (A of replacement 1) and 21.7 parts of acid amides (B 1).
Embodiment 3
3.1 condensation product (A 3) preparation
As the operation that embodiment 1.1 describes, difference is, uses 111.7 parts of N-(2-ethoxy)-ethylenediamine to replace 98 parts.
3.2 dispersion (W 3) preparation
As the operation that embodiment 1.3 describes, difference is, with 108.3 parts of condensation product (A 3) and 21.7 parts of acid amides (B 2) 108.3 parts of condensation product (A of replacement 1) and 21.7 parts of acid amides (B 1), and replace Macrogol 200 with PEG400.
Embodiment 4
4.1 condensation product (A 4) preparation
As the operation that embodiment 1.1 describes, difference is, uses 88.2 parts of N-(2-ethoxy)-ethylenediamine to replace 98 parts.
4.2 dispersion (W 4) preparation
As the operation that embodiment 1.3 describes, difference is, with 108.3 parts of condensation product (A 4) and 41.7 parts of acid amides (B 1) 108.3 parts of condensation product (A of replacement 1) and 21.7 parts of acid amides (B 1) spherical mixture, replace being dissolved in 19.5 parts of glacial acetic acid solutions in 773.5 parts of water with being dissolved in 19.5 parts of glacial acetic acid solutions in 753.5 parts of water.
Embodiment 5
5.1 condensation product (A 5) and acid amides (B 5) preparation of mixture
Under blanket of nitrogen, 512 parts of technical grade stearic acid (acid number 207.5) (stearic acid and palmitic acid mixture) are heated to 100 ℃, the temperature between 100 to 110 ℃ adds 32 parts of 3-dimethylamino-1-propylamine.After adding dimethylaminopropylamine, in 60 minutes, reactant mixture is heated to 130 ℃, kept 3 hours, in 6 hours, be heated to 180 ℃ then at 130 ℃.In 3 hours, 98 parts of N-(2-ethoxy)-ethylenediamine is quantitatively added then, continue to react 60 minutes down, and be evacuated down to 100 millibars at 180 ℃.Keep 180 ℃ 100 millibars after 1 hour, mixture is cooled to 80 ℃, inflated with nitrogen is removed vacuum state, and discharges mixture.In whole condensation reaction, condistillation goes out 37 parts of products, comprising 34.1 parts of water and 2.9 parts of dimethylaminopropylamines.
5.2 dispersion (W 5) preparation
With condensation product (A 5) and acid amides (B 5) mixture is heated to fusing point for 130 parts, stirs and be processed into graininess, cooling joins 130 parts of this spherical mixtures in 19.5 parts of glacial acetic acid solutions that are dissolved in 374.5 parts of water while stirring again.After being heated to 60 ℃, under this temperature, continuing again to stir 60 minutes, and dropwise add 399.5 parts of water and 75 parts of Macrogol 200s in succession.Then with the mixture cool to room temperature.Obtain meticulous dispersion, sneak into 1 part of Silikon Antischaumemulsion SE2 (obtaining) and 1 part of Saniprot 9408 (obtaining) from Switzerland Sanitized from German Wacker Chemie with high fluidity.Discharge composition, obtain 1000 parts of dispersion (W 5).
Application Example A
Under 40 ℃, in Mathis (Switzerland) laboratory nozzle, be 1: 8 ratio with material and flowing fluid ratio, 1 kilogram of (dry weight) substrate (cotton jersey that desire is handled, with active blue 52 dyeing of 3.1% color index, washing and rinsing then) restrain dispersion (W with 40 1) handle, and carry out liquid circulation with 60 liters/minute, handled 30 minutes.Wherein the dH of water is 10 ° (according to DIN53905), and the pH of liquid is 5 (regulating with glacial acetic acid).The material crossed of centrifugal treating then, and under the situation that is not having tension force under 140 ℃ dry 90 seconds detects the feel of material.In processing procedure, do not have deposit, on fabric, do not have stain.After discharging liquid, on machine, do not observe residual yet.Obtain the material that soft degree is significantly improved.
Application Example B
In Mathis (Switzerland) the laboratory nozzle that 10 premium on currency (dH is 10 °) are arranged, put into 1 kilogram of (dry weight) substrate (cotton textured fiber) that desire is handled, the 12 gram color indexs that will be dissolved in 1 premium on currency then join in the dye bath for direct purple 66 solution, and with 60 liters of/minute hydronic to 95 ℃, when reaching this temperature, metabisulfite solution with 100 grams 15% in 20 minutes adds, further under this temperature, dyeed 30 minutes, be cooled to 70 ℃ then, take out the material after the dyeing, with its rinsing repeatedly (3 times) in hot and cold water.Emit behind the last washings 8 liters of cold water (dH is 10 °) are injected, and to be adjusted to pH with acetate be 6, add 40 gram dispersion (W then 1), promptly 60 liters/minute of the usefulness and the same circulation rates that dyes are heated to 40 ℃ with dye bath, under this temperature, handled 30 minutes, emptying does not have the dye bath of using up fully of dyestuff then, the material crossed of centrifugal treating then, and under the situation that is not having tension force under 140 ℃ dry 90 seconds.On fabric, do not have stain, in the nozzle of Mathis laboratory, do not observe deposit.Obtain the material that soft degree is significantly improved.
In embodiment A and B, use dispersion (W with being similar to 1) method use dispersion (W 2), (W 3), (W 4) and (W 5).All (W 1) to (W 5) dispersion all stable to shearing force, and the soft degree of material is significantly improved.

Claims (9)

1. aqueous dispersion (W) is as the purposes of softener composition, it be used for jet-dyeing use the method from the aqueous solution, contaminated to dyeed and/or the rope form of glazing or tubing carry out that impermanency is softening to be handled, dispersion comprises following component:
(A) at least a by at least a C 12-24Aliphatic acid or at least a C 12-24The micromolecular Arrcostab of aliphatic acid and 2-[(beta-hydroxyethyl)-amino]-product of ethamine condensation,
(B) protonated (C of at least a selectivity 12-24Aliphatic acid)-[γ-(N, N-dimethylamino)-propyl group]-acid amides and
(C) at least a low molecular weight carboxylic acid,
With optional
(D) at least a at room temperature is the low polyethylene glycol of liquid, and/or
(E) at least a formulation additives,
And do not contain other additives (Z) of improvement diffusion substantially.
2. purposes as claimed in claim 1, it is characterized in that, improvement diffusion additive (Z) is the polymerization of unsaturated monomers thing of wax, fat or oil and their derivative, epoxides, alkyl or hydroxy alkyl ester, saccharide and saccharide derivative, polysiloxane or ethene
(E) be
(E 1) at least a reagent that is used for the infringement of prophylaxis of microbial, and/or
(E 2) at least a defoamer.
3. purposes as claimed in claim 1 or 2 is characterized in that, in (W)
Weight ratio (B)/(A) in 6/100 to 60/100 scope,
Weight ratio (D)/(A) in 0 to 300/100 scope,
Weight ratio (E)/(A) in 0 to 6/100 scope,
(A) weight content in 4% to 50% scope,
(C) content is, has (C) of 0.5 equivalent in (A)+(B) in the whole alkaline amino of amount at least,
The weight content of dry matter in 8% to 60% scope,
And viscosity≤1000cP.
4. as each described purposes in the claim 1～3, it is characterized in that (A) is the open chain condensation product, it mainly comprises following formula: compound:
R-CO-NH-CH 2-CH 2-NH-CH 2-CH 2-OH (I)
R-CO-NH-CH 2-CH 2-N(CO-R)-CH 2-CH 2-OH (II)
R-CO-NH-CH 2-CH 2-NH-CH 2-CH 2-O-CO-R (III)
And/or R-CO-NH-CH 2-CH 2-N (CO-R)-CH 2-CH 2-O-CO-R (IV)
Wherein R-CO-is C 12-24Fatty acid group.
As in the claim 1～4 each described to dye and/or the glazing fabric carried out the softening purposes of handling of impermanency, fabric is wherein made for the semisynthetic fibre material that is mixed with full composite fibre materials by fibrous material natural, the selectivity sex change and/or selectivity.
6. as each described purposes in the claim 1～5, wherein (W) is aqueous dispersion, comprises (A), (B), (C) and water substantially, and contains at least a (D) and/or (E) arbitrarily.
Such as claim 3～6 definition, do not contain the water-soluble composition (W) of (Z), it is aqueous dispersion (W '), comprises (A), (B), (C) and water substantially, and contains at least a additive (D) and/or (E) arbitrarily,
Wherein the weight content of (A) is in 4% to 50% scope, and the weight content of dry matter is viscosity≤1000cP in 8% to 60% scope and at room temperature,
And wherein wt than (B)/(A) in 6/100 to 60/100 scope,
Weight ratio (D)/(A) in 0 to 300/100 scope,
Weight ratio (E)/(A) in 0 to 6/100 scope,
(C) content is to have (C) of 0.5 equivalent in (A)+(B) in measuring whole alkaline amino at least.
Aqueous dispersion 8. as claimed in claim 7 (W '), the pH scope is 3 to 8.
9. as the preparation method of claim 7 or 8 described aqueous dispersions (W '), it is characterized in that mixing at least a component (D) and (E) mixing optional again and that institute must the quantity ratio respectively with (A)+(B) mixture of the essential quantity ratio of institute respectively and water and (C).
CN 01800785 2000-04-12 2001-04-10 Non-permanent softening finishing of textile piece goods in jet-dyeing machines, and compositions suitable for this purpose Pending CN1366565A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP00810320.2 2000-04-12
EP00810320 2000-04-12

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DE2841076C2 (en) * 1978-09-21 1980-02-14 Basf Ag, 6700 Ludwigshafen Process for the liquefaction of aqueous fabric softeners
DE3334575A1 (en) * 1982-10-04 1984-04-05 Sandoz-Patent-GmbH, 7850 Lörrach Aqueous wax dispersions, their preparation and use
DE3501521A1 (en) * 1985-01-18 1986-07-24 Henkel KGaA, 4000 Düsseldorf AQUEOUS CONCENTRATED TEXTILE SOFTENER
DE3810108A1 (en) * 1987-04-04 1988-10-13 Sandoz Ag Liquid finish
DE4111648A1 (en) * 1991-04-10 1992-10-15 Henkel Kgaa TEXTILE TREATMENT AGENT WITH IMPROVED WATER DISPERSIBILITY

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