CN1059001A - Make clothes be easy to ironing and the better silicone gel of ironing back outward appearance - Google Patents
Make clothes be easy to ironing and the better silicone gel of ironing back outward appearance Download PDFInfo
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Abstract
The present invention relates to Fabrid care composition, it contains a kind of silicone gel, thereby makes fabric be easy to ironing, and the outward appearance after the ironing is improved.
Description
The present invention relates to a kind of method of Fabrid care composition and processing fabric,, particularly be easy to ironing, and ironing back outward appearance is improved to improve the various performances of fabric.
The most of clothes in the world today are all made by textiles, existing some centuries of textile technology.In general the weaving invention should be given the credit to ancient Egypt really.Natural cotton, wool or linen fibre are made yarn, and the textiles made from these yarns is made clothes again, and clothes usually can damage in wearing process, to change during washing a lot of time and efforts with its ironing so that they keep original outward appearance.
In nearly half a century, textile manufacturer is mainly being done two improvement aspect the washing of clothes and the dress: (1) is containing in the cotton cloth and is using crosslinked resin, and (2) are with synthetic and synthetic mixture.Though these two kinds of measures are to reducing the wrinkling existing bigger progress of clothes, the consumer is still dissatisfied to its result, still thinks to be necessary ironing.
Used herein term " be easy to ironing; and ironing back outward appearance is improved " meaning is meant that fabric only need press a little, (the flatiron degree of slip is increased, the easier wrinkle of removing), and through specific cleaning operation then again after the ironing than the wrinkle after common cleaning operation and the flatiron still less.
Therefore, the object of the invention is to provide the better composition of outward appearance after making processed clothes be easy to especially plate/press.Can find out that from following explanation the present invention can reach this and other purpose.
The Fabrid care composition that the present invention relates to contains a kind of silicone gel reagent, and when being used for the fabric cleaning operation, this silicone gel of effective dose is deposited on this fabric, thereby makes it be easy to ironing, and ironing back outward appearance is improved.
The silicone gel composition that the present invention relates to can make fabric be easy to ironing and ironing back outward appearance is improved.On the other hand, the present invention relates to carry out the method for fabric nursing, thereby outward appearance is improved after making it be easy to ironing and ironing with this silicone gel composition.Preferred compositions is liquid, aqueous, and it also contains a kind of fabric softener and/or a kind of surfactant or a kind of starch.Usually said composition is added in the washing agent of using in the laundry operations or flushing water, preferably these compositions are water base, dispersible additives of water, it contains about 0.1%-80%, preferably contains the 0.1%-50% silicone gel approximately, and these additives are diluted in washing agent or the flushing water.
Surprisingly, silicone gel adds that a kind of suitable carriers (this carrier can make the silicone gel of effective dose be deposited on the fabric) can make fabric be easy to ironing, and ironing back outward appearance is improved.Therefore, herein disclosed is several Fabrid care compositions that contain silicone gel.Also disclose with silicone gel nursing fabric so that it is easy to press and press the several method that the back outward appearance is improved.
Silicone gel composition of the present invention uses with a kind of suitable carriers.Term used herein " carrier " meaning is meant and is used for that silicone gel supplied with fabric and is deposited on any suitable carriers (liquid, solid or machinery) on the fabric, silicone gel if can be added in water base softener or the composition of detergent, or a kind of containing in the aqueous emulsion.It can be used in the bottled liquid injection liquid.Embodiment preferred comprises: the liquid wash water component contains silicone gel and adds fabric softener.
In a kind of preferred version, will about 0.1%-10%(weight) silicone gel mix mutually with a kind of suitable liquid fabric softener composition of commercially available washing.The result obtains a kind of Fabrid care composition can make processed fabric be easy to ironing, and ironing back outward appearance is better.
In another program, the silicone gel of equivalent is mixed into a kind of suitable commercially available liquid detergent and/or softener composition, and (the surfactant based washing agent of anionic/nonionic type is as liquid TIDE
, or nonionic surface active agent base washing agent, as BOLD
3Liquid
) in, note using the silicone gel emulsion compatible, in order to avoid this silicone gel de-emulsification with detergent surfactant.This novel liquid detergent/silicone gel product has the beyond thought effect that the back outward appearance is improved that is easy to press and press.In another kind of scheme, silicone gel is sprayed directly on on the fabric that soaks.In washing agent or flushing liquor, the content of silicone gel is about 1-300ppm, is preferably 5-150ppm.When direct injection, silicone gel content should be higher, as 1000ppm to 200000ppm.
In another program, the present invention includes a kind of liquid starchy composition, it contains this silicone gel and adds starch and a kind of suitable carriers.In a kind of preferred version, will about 0.1%-10%(weight) the emulsification silicone gel be mixed in a kind of suitable commercially available pump spray starch composites.The result obtains a kind of injection starch composites, and it can make the fabric after the injection be easier to ironing and press the back outward appearance be improved.The main moisture and a kind of suitable emulsifying agent of suitable commercially available injection starch composites.Attention must be selected the silicone gel emulsifying agent compatible with silicone gel with this starch for use, in order to avoid de-emulsification.Second kind of scheme comprises the laundry flushing liquor, and wherein silicone gel content in this flushing water is about 1-300ppm, preferably is about 5-150ppm.
Be not that hope is bound by theory, think that in a single day these silicone gels are deposited on the fabric, its spreads and form one deck three-dimension film on fabric in washing process, and it will help to iron easily, in the ironing process, smooth away wrinkles, and make this appearance of fabrics better after the ironing.
To notice preferably guaranteeing that composition of the present invention does not contain the uncomfortable thing of heavy wax, abrasive material, glass fibre and other fabric substantially.
Silicone gel
Silicone gel is a kind of cross-linking agent of siloxanes fluids and silicone resin.Siloxanes fluids is defined as the flowable siloxane polymer with variable viscosity, and it can be branch or linear.In general, silicone resin is highly cross-linked silicone solids system, and it has with three functions (T) (as RSiO
1.5) or four functional units (Q) (as, SiO
2) linked introduced of form.Do not increase single function or terminal component (M) owing to only increase by three or four functional units (as, R
3SiO
0.5), this resin becomes more crisp.
The present invention is of paramount importance to be, owing to increased by two functional units (D) (as, R
2SiO), make this resin deliquescing, can regard a kind of silicone gel as fully.Except list, three, four and two functional units to silicone resin and gel influential, changing organic group also can influence its performance.Term Q, tetra-and quat-are synonyms.Usually silicone resin and gel are made organic group with methyl, phenyl, vinyl and composition thereof, but do not have too many qualification.Other possible group comprises amine (monobasic, binary, ternary, quaternary, ring-type, diamines and triamine), and epoxides, ester, ether, halogen function organic matter, carboxyl etc. comprise hydrogen.
For purposes of the invention, the importance of silicone gel is that it is softer than resin, compares its degree of cross linking lower (that is, three-(T) and/or four-(Q) functional unit content are low) with silicone resin.It is higher that silicone gel of the present invention and siloxanes fluids or adhesive silicone rubber gum stock are compared its degree of cross linking.More particularly, preferred silicone gel has about 3%-30%T and/or Q functional unit, about 70%-97%D functional unit, about 0.1%-10%M functional unit; This silicone gel has about 5%-20%T and/or Q functional unit, about 80%-95%D functional unit, about 0.3%-8%M functional unit is better, preferably this silicone gel has about 5%-15%T and/or Q functional unit, about 85%-95%D functional unit, about 0.5%-5%M functional unit, wherein M is curable, available following molecular formula is represented
Preferably separate alkyl or the H of R and R ' or be selected from some other groups (but being not limited thereto) of following groups wherein: amine (monobasic, binary, ternary, quaternary, ring-type, diamines and triamine), epoxides, ester, ether, halogen function organic matter, carboxyl etc. comprise hydrogen.This polymer siloxane gel molecular amount should be greater than about 20000; Greater than about 50000; Even greater than about 100000; It is about 500000 ± 400000 that the molecular weight of this silicone gel can be higher than, even be higher than about 1000000.In theory, their molecular weight can be up to 10
20Preferred polymer siloxane of the present invention is lower than 10
15, even be preferably lower than 10
10Important factor is that this polymer siloxane is gel form.When T and/or Q functional unit content were high, the molecular weight of this gel was then lower.
In addition, this silicone gel must be a kind of like this form, preferably by a kind of aqueous carrier it is added on the fabric of washing; Therefore the emulsification form is very desirable, yet can not be limited to the emulsification of precast gel, and it is the best method of implementing most preferred embodiment of the present invention that silicone gel itself generates emulsion.
Can realize this point by multiple diverse ways.Two kinds of methods are arranged usually: (1) emulsion polymerization (referring to US4600436, Traver/Thimineur/zotto, issued July 15,1986, for Durable Silicone Emulsion Polish has listed this paper list of references in, 6.11 hurdles wherein particularly, 35-47); (2) emulsification of polymer, in emulsion, solidify then (referring to " siloxanes ", people such as Hardman, Encyclopedia of Polymer Science and Engineering, Vol.15, Second Edition, Pages 204-308, John Wiley and Sons, Inc., 1989, also listed this paper list of references in).People such as Harding have pointed out four kinds of curings: (1) concentrates; (2) peroxide; (3) platinum catalysis hydrosilation; (4) ultraviolet ray.These curings are known in the prior art, but must be noted that selection initiation material and reaction condition are to guarantee to obtain desired " gel ".
A kind of ad hoc approach of preparation gel is to make the emulsification of curable branch siloxane polymer earlier, then on being added to fabric before with in the gel of this polymer cure in the emulsion droplet.For example: with pH in the glass container is a kind of emulsification branch solidity amine functional siloxane (test emulsion of 9-10, provide by General Electric, No.124-7701, it is 20% emulsion of commercially available curable amine functions siloxanes GE, and vending articles are called SF1706) can generate the silicone gel of emulsification in 5-10 days 50 ℃ of heating.
This silicone gel is made by the branch solidity amine functional siloxane with following array structure:
Wherein X equals Z+2; Y is at least 3; Z is at least 1; R ', R " are C
1-20Alkyl or be selected from the amine groups that cyclammonium, polymeric amine and alkyl chain contain the alkylamine of 2-7 the carbon atom of having an appointment, wherein R ' or R " are amine groups at least; Curable amine functions siloxanes solidifies with the emulsification form by heating and/or adding alkali, to generate a kind of silicone gel of emulsification.
Preferred siloxanes is to work as: R is hydrogen or a kind of C
1-3Alkyl; R
1Be C
1-3Alkyl; R " is the alkyl amine group that contains 2-7 the carbon atom of having an appointment in the alkyl chain; Wherein curable amine functions siloxanes solidifies with the emulsification form by heating and/or adding alkali, to generate a kind of silicone gel of emulsification.
Preferred siloxanes is to work as: R is a methyl; R ' is a methyl; R " is (CH
2)
3NH(CH
2)
2NH
2; X is about 4; Y be about 27 and Z be about 2; Wherein this siloxane molecule amount is about 1000-2800, and the viscosity in the time of 25 ℃ is about the 5-40 centistoke; The solidity amine functional siloxane solidifies to generate a kind of silicone gel of emulsification with the emulsification form by heating and/or adding alkali.
The physical property of this system and starting polymer are different greatly.Help reducing wrinkle with the solidity amine functional siloxane, open in this former United States Patent (USP), as US4800026, coffindaffer/wong, 1989.1.24 approval; US4911852, coffindaffer/Trinh 1990.3.27 approval; US4923623, coffindaffer, the 1990.5.8 approval, all these patents have all been listed in this paper list of references, wherein a kind of polymer is added on the fabric, then by with other siloxane reactions it being solidified, what exceed greatly that we expect is, if make polymer cure, in emulsion, form gel, transmit this gel by a kind of liquid-carrier then, can reach the effect that outward appearance is improved after being easy to press and press, this is that the consumer is obvious to all.
The pH that increases emulsion can shorten the reaction time of the above-mentioned disclosed gel of preparation.For example, pH is 13 o'clock, can generate the SF1706 gel of emulsification at 6-30 hour, this depend on be added in the product before desired state of cure.Temperature is brought up to about 75 ℃ ± 15 ℃ from room temperature, also can improve curing reaction speed, and reduce the pH value curing reaction speed that will slow down, for example, pH is about at 2.5 o'clock, solidifies hardly after one month 23 ℃ of placements.Attention should keep temperature enough low so that this emulsion consistency.
In this reaction, amine in this system and alkali work the catalyst action that concentrates curing reaction, and alkali metal hydroxide is made the effectiveness of catalyst by Li
+＜Na
+＜K
+＜Rb
+＜Cs
+Order and increasing.It is known that many methods that do not need with amine or alkali siloxane polymer to be solidified are arranged in the prior art, some has been disclosed in Encyclopedia of Polymer Science and Engineering in these methods, Vol.15, Second Edition, Pages 204-308, John Wiley and Sons, Inc., 1989, these have all been listed in this paper list of references.
A kind of method of expression silicone gel characteristic is
29Si; NMR.Even be emulsification form (having lax auxiliary agent such as Cr(acac)
3), in above-mentioned particular range, also discern M.D.T and Q easily.
Fabrid care composition of the present invention contains a kind of suitable silicone gel, preferably also contain another kind of fabric nursing material, as be selected from organic solvent, water, surfactant, fabric softener, dirt remover, builder, brightening agent, spices, dyestuff and composition thereof.
A kind of embodiment of the present invention is a kind of liquid fabric softening composition, it contains the silicone gel of effective dose and a kind ofly is selected from multiple softener (as US4661269, people such as Trinh, 1987.4.28 approval has been listed in described in this paper list of references) fabric softener.People such as US3904533(Neiditch, this paper list of references has been listed in 1975,9.9 approvals in) many other fabric-conditioning prescriptions of the present invention that are applicable to have been described.
Liquid detergent
Another embodiment of the present invention is a kind of liquid detergent composition, it contains silicone gel and a kind of surfactant of effective dose, as be selected from people such as US4318818(Letton, March 9 nineteen eighty-two approval) and US4911852(coffindaffer/Trinh, approval on March 27 nineteen ninety) a kind of described in (the two all lists this paper list of references in).Suitable surfactant can be selected from anionic, nonionic, both sexes, both sexes (negative and positive) ion and cationic surface active agent and composition thereof.In preferred version, adding accounts for the liquid detergent composition total amount and is about 0.1%-33%, about 0.5%-20% is better, the best silicone gel of about 1.0%-10%, a kind of product that the result obtains, when fabric is placed on when wherein washing with common mode, it can make fabric obviously be easy to ironing, and ironing back outward appearance is improved.
Certain preferred embodiments
Preferred compositions of the present invention is a kind of aqueous dispersion, and it contains: a kind of silicone gel, and wherein the weight ratio of this silicone gel and fabric softener is about 17: 1-1: 350, preferably be about 10: 1-1: 100.Some of silicone gel and fabric softener more preferably weight ratio are 1: 1-1: 10 and 1: 5-1: 10.These compositions are added in the flushing water, can make fabric be easy to ironing and press the back outward appearance to be improved, and help fabric sofetening.
Suitable fabric softener is selected from following material:
ⅰ. quaternary ammonium compound;
ⅱ. the aliphatic amine fabric softening compound;
ⅲ. aliphatic amide compound;
ⅳ. aliphatic acid;
ⅴ. aliphatic alcohol; With
ⅵ. its mixture
In the present composition that adds some flushing liquor, the amount of fabric softener is about 2%-35%, preferably is about 4%-27%, (in total composition).This amount lower limit must be to make fabric effectively softening when it is added to the household laundry flushed channel in a usual manner.Its upper limit is applicable to only needs the seldom product that more thicks liquid of consumption.
The preferred content of silicone gel in the said composition (by concentrate weight) is about 0.05%-40%; About 0.1%-20%; About 0.5%-10%.
Suitable fabric soft compound comprises quaternary ammonium salt and non-quaternary ammonium salt and amine salt.
In the laundry flushing process, use the composition (being quaternary ammonium salt and the substituted imidazoline salt form that two acyclic aliphatic hydrocarbon groups of long-chain are arranged) of cation nitrogen-containing compound (for example to help fabric-softening, referring to US3644203, people such as Lamberti, 1972.2.22 approval; US 4426299, Verbruggen, 1984.1.17 approval; Also have " Cationic surface Active Agents as Fabric softeners " R.R.Egan, Journal of the American Oil chemists ' society, January 1978, P118-121; And " How to choose cationics for Fabric softeners, " J.A.Ackerman, Journal of the American oil chemists ' society, June 1983, P 1166-1169).
Fabric softening compound right and wrong season acid amides and non-quaternary amines that other is suitable.Usually the material of quoting is the product of higher fatty acids and hydroxy alkyl Alkylenediamine.The product that an example of these materials is higher fatty acids and hydroxyethylethylene diamine (referring to " enriched product of beta-hydroxyethyl ethylenediamine and aliphatic acid or its Arrcostab; and they do the application of fabric softener in the washing agent ", H.W.Eckert, Fette-seifen-Anstrichmittel, September 1972, P 527-533).These materials usually with other cation quaternary ammonium salt and imidazoline salt as the soft active component in the fabric sofetening composition.(referring to US 4460485, people such as Rapisarda, 1984,7.17 approvals; US4421792, people such as Rudy, 1983,12.20 approvals; US4327133, people such as Rudy, 1982.4.27 approval).
Particularly preferred fabric softener is the aqueous dispersion form, and it contains 3%-35%(by weight approximately) following mixture:
(a) product of the higher fatty acids of about 10%-92% and a kind of polyamine, this polyamine are selected from hydroxyalkyl Alkylenediamine and two alkylene triamine and composition thereof
(b) about 8%-90% has only a long-chain not have cycloaliphatic C
15-C
22The CATION of alkyl contains nitrogen salt and selectivity contains
(c) 0%-about 80% has two or more a plurality of long-chain not have cycloaliphatic C
15-C
22The CATION that contains the aralkyl of 15-22 carbon atom in alkyl or this group and the alkyl chain approximately contains nitrogen salt.
The detailed description of some preferred fabric softener can be referring to the US4661269(Trinh/Wahl/Swartley/Hemingway that has transferred the possession of usually that lists this paper list of references in full in, the 1987.4.28 approval).
Except as otherwise noted, term herein for example, soften compound is meant one pack system and compounding ingredients.
Starch
A preferred embodiment of the present invention is a kind of liquid starchy composition, and it contains the silicone gel of effective dose and up to about 99% liquid starchy composition, this liquid starchy composition is selected from common aqueous starch composition.Said composition contains 0.1%-35% approximately, preferably contains 0.5%-20% starch approximately, low quantity of surfactant, and accessory constituent, all the other are water.Use starch to help ironing and shaping, and can be used as the carrier of this silicone gel component.Therefore, used any water base starch composites all can be used for the present invention in the fabric nursing technology.For example, US4780499, people such as Villarreal, approval on October 25th, 1988; US3644241, Falivene, in February, 1972 approval; US3833393, Kandathil, in September, 1974 approval; US4495226, Smith, approval on January 22nd, 1985; (all in full list in this paper list of references), these patent disclosures suitable starch and starch derivative composition.
Preferred carrier is a liquid, and it is selected from water and water and short chain C
1-C
4The mixture of monohydric alcohol.Used water can be distilled water, deionized water or running water.Also available water and about at the most 10%, the short chain alcohol most preferably less than about 5% (as, ethanol, propyl alcohol, isopropyl alcohol or butanols and composition thereof) mixture make liquid-carrier.
Some short chain alcohol is present in the commercially available quaternary ammonium compound product.These products can be used to prepare the preferred Aquo-composition of the present invention, and the content of short chain alcohol is generally about 1%-10% of Aquo-composition weight in these products.
Other carrier can be suitable solid, polyalcohol wax and waxy substance, and they are generally used for washing agent and add in the softener and spray containers of drier.
Some optional ingredient and preferred embodiment
As everyone knows, also can in the present composition, add compatible assistant, this class assistant includes, but is not limited to viscosity modifier, spices, emulsifying agent, preservative agent, antioxidant, bactericide, kill (very) microbial inoculum, colouring agent, dyestuff, fluorescent dye, brightening agent, opalizer, freeze molten conditioning agent and contraction conditioning agent and other reagent that can be easy to press (as starch etc.).If use these assistants, usually each addition is about 5% of preferred liquid composition weight at the most.
Viscosity modifier can be the organic or inorganic thing.The example of organic viscosity modifier is aliphatic acid and ester, fatty alcohol, reaches solvent such as short chain alcohol that water can mix.The example of inorganic viscosity modifier is water-soluble ionizable salt.Can use multiple ionizable salt, the example of suitable salt is an I in the periodic table of elements
AAnd II
AThe halide of family's metal is as calcium chloride, magnesium chloride, sodium chloride, potassium bromide and lithium chloride.Calcium chloride preferably.Each component is mixed and made into fluid composition of the present invention, and when making said composition reach desired viscosity, this ionizable salt is useful especially.The consumption of ionizable salt depends on the consumption of active component in the said composition, can require to regulate according to prescription.The salinity that is used to control said composition viscosity is generally 1,000,000/(ppm) 20-6000 parts of composition weight, preferably is about 20-4000ppm.
The compatible concentration of sterilant that is used for the present composition generally is about the 1-1500ppm of said composition weight.
Can be added to examples of antioxidants in the present composition and be propyl gallate (can be from Eastman Chemical Products, Inc. has bought, trade mark is called Tenox
PG and Tenox S-1) and butylated hydroxy-methylbenzene (bought from UOP Process Division, trade mark is called Sustane
BHT).
Said composition can contain non-curing silicone fluid, thereby makes it have additional advantage as improving the feel of fabric.Preferred auxiliary siloxanes is a dimethyl silicone polymer, and its viscosity is about 100 centistokes (cs)-100000cs, preferably is about 200-60000cs.The pre-emulsification form that these auxiliary siloxanes can directly obtain from the supplier is used or can easily it be added to the softener composition.The example of these pre-emulsification siloxanes is 60% emulsion of dimethyl silicone polymer (350cs), and it is sold by Dow corning corporation, and trade mark is called Dow CORNING
50% emulsion of 1157 Fluid and dimethyl silicone polymer (10000cs), it is sold by General Electric Company, and trade mark is called General Electric
SM 2140 Silicones.The consumption of optional silicone components is about the 0.1%-6% of composition weight.
Preferred compositions contains the bactericide of (in composition total weight): 1-1000ppm and the spices of about 0.2%-2%, the dimethyl silicone polymer of 0%-about 3%, the calcium chloride of 0%-about 0.4%, the dyestuff of about 10-100ppm, the short chain alcohol of 0%-about 10% approximately.
Usually the pH with preferred composition of the present invention is transferred to about 2-11, preferably is about 2-8.Usually in prescription, add small-amount free acid or free alkali to regulate pH.Available any acidic materials; The personnel that know the softener technology can be selected according to situations such as cost, availability, securities.Available any suitable acid for adjusting pH.Preferably hydrochloric acid, sulfuric acid, phosphoric acid and formic acid.Equally, also available any suitable alkali such as NaOH are regulated pH.For realizing the object of the invention, in whole concentration soft compound, measure pH with glass electrode, and compare with the standard calomel reference electrode.
The present composition can prepare with several different methods.Some easy and gratifying method is disclosed in the following non-limiting examples.
The embodiment I
Method A
The liquid fabric softener composition that contains silicone gel by following method preparation.In the premixed container, add 4.33 parts of chlorinations two (hydrogenated tallow) dimethylammoniums (DTDMAC) of having weighed, 1.00 parts of methyl isophthalic acid-tallow-acid amides ethyl-2-tallow imidazoline methylsulfuric acid esters and 0.025 part of dyestuff.
Be heated to 75 ℃ and mix after, pre-composition is joined in the mixer (44 ℃) that 88.14 parts of distilled water and 0.025 part of antioxidant solution are housed while stirring.In this " master " mixture, add 0.45 part of spices then.Should be chilled to 21 ℃ by main mixture again, while stirring to the silicone gel that wherein adds 5.0 parts of emulsifications (20% siloxanes).
Method B
Basic identical with method A, just before being cooled to 21 ℃, mixture just the emulsification silicone gel is added in the main mixture.
The ratio of polymer siloxane gel and fabric softener total amount is about 1: 5.The molecular weight of this polymer siloxane gel is at least about 100000, and the molecular weight of some gel particle is estimated to be higher than 1000000.The functional unit of this silicone gel is about 10%T and Q; 88%D and 2%M, each value estimates at ± 15% relative error.
Table 1
A and B
Composition weight %
DTDMAC
14.33
Methyl isophthalic acid-tallow acid amides
Ethyl-2-tallow imidazoline methylsulfuric acid ester 1.00
Alcohol (from active component) 0.80
Spices 0.45
Dye solution 0.02
The silicone gel of emulsification
25.00
Antioxidant
30.025
Distilled water 88.37
1. chlorination two (hydrogenated tallow) Dimethyl Ammonium
2. specific contains aqueous emulsion 124-7701(as mentioned above) make by General Electric Company, it contains 20% SF 1706(as mentioned above) and about 5% octylphenoxy polyethoxy ethanol and the alkylbenzene mixture that gathers (oxyethylene group) glycol emulsifying agent.In glass container, the siloxanes of emulsification is made gel at 120 (50 ℃) heating emulsion 7 days.
3.Tenox S-1 is provided by Eastman Kodak.
The embodiment II
Prepare silicone gel and fabric softener composition with method A.Its component is: 6,0.80 parts of MTTMAC of 2.00 parts of Mazamide, and 4.03 parts of DTDMAC, 1.00 parts of imidazoline salts, 0.42 part of spices, 1.28 parts of alcohol (from active constituent), the silicone gel of 10.00 part of 20% emulsification, all the other are distilled water.This component and preparation method are referring to the explanation of table 2 and embodiment I.Silicone gel is about 1: 7 with the ratio of the total amount of fabric softener.
The embodiment III
Prepare silicone gel and fabric softener composition with method A.Its component is: 6,6.50 parts of DTDMAC of 17.50 parts of Mazamide, and 1.32 parts of spices, 2.07 parts of alcohol (from active constituent), the silicone gel of 12.00 part of 20% emulsification, all the other are distilled water.This component and preparation method are referring to the explanation of table 2 and embodiment I.Gel is about 1: 10 with the total amount ratio of softener.
Table 2
Embodiment II embodiment III
Composition weight % weight %
Mazamide 6
12.00 17.50
MTTMAC
20.80 -
DTDMAC
34.03 6.53
Spices 0.42 1.32
The bright blue dyestuff 0.025 0.072 of polarity
Alcohol (from active constituent) 1.28 2.07
Emulsification silicone gel (20%) 10.00 12.00
The distilled water surplus surplus
1.2 the product of mole hydrogenated tallow fatty acid and 1 mole of N-2-hydroxyl vinyl diamines
2. single (hydrogenated tallow) trimethyl ammonium of chlorination
3. chlorination two (hydrogenated tallow) Dimethyl Ammonium.
The comparative example IV
Product B M
Prepare amine functions silicone gel (AFSG) and fabric softener composition with method A.Its component is: 3.75 parts of DTDMAC, and 3.40 parts of imidazolines, 0.57 part of MTTMAC, 0.40 part of spices, 0.025 part of dyestuff, 0.77 part of alcohol (from active constituent), 0.4-0.9 part HCl, 5.00 parts of AFSG, all the other are distilled water.
The contrast product D
Method by product B M prepares fabric softener composition, and different is not add AFSG.
Produce BM﹠amp; The component of D is referring to the explanation of table 3 and embodiment IV.
Use product B M﹠amp; D makes to add the fabric softener of flushing liquor to handle the COTTON FABRIC of polymerization cotton (65%/35%) and 100%.With 5 lasting wash/rinse/dried routine processes fabrics.Used washing agent is TIDE
With liquid TIDE
Only 48 cover fabric sample TIDE only 25 apply mechanically liquid TIDE.The fabric that makes liquid TIDE and TIDE washing separately allows many groups personnel press then, and each a kind of fabric of ironing of handling is selected the fabric of the easiest ironing.Hang over fabric on the suspension hook after the ironing and estimate its outward appearance (wrinkle is minimum).To " not have preferential " and select taker in two, and evenly divide to go in the handled thing.The result is summarized as follows:
Be easy to ironing
% selects BM % to select D
Cotton 58 42
Cotton 64 S 36 of polymerization
Outward appearance after the ironing
% selects BM % to select D
Cotton 61 S 39
Cotton 65 S 35 of polymerization
S=has the assurance more than 90% or 90% to have obviously difference.
The embodiment V
At room temperature while stirring about 25 silicone gels (25 parts) (20% silicone gel) that restrain emulsifications are added to 75 parts of 2-3% starch composites (SPRAY ' N STARCH
By Texize, a division of Dow, Inc. makes) in.This mixture that contains 5% silicone gel is approximately sprayed thing as pre-ironing, so that fabric is easy to ironing and ironing back outward appearance is improved.
Embodiment VI and VII
Method by the embodiment V prepares other two kinds of starch/silicone gel compositions.Respectively 20% silicone gel emulsion of about 5 parts and 50 parts is mixed silicone gel composition to obtain stable 1% and 10% respectively with liquid SPRAY ' N STARCH composition.
This starch composites is stable.
Table 3
The embodiment IV
Product B M product D
Component weight % weight %
MTTMAC
10.57 0.57
DTDMAC
23.75 3.75
Imidazoline
33.40 3.40
Spices 0.40 0.40
The bright blue dyestuff 0.025 0.025 of polarity
Alcohol (from active constituent) 0.77 0.77
The silicone gel (20%) 5.00 of emulsification-
HCl（31.5%）??0.4-0.9??0.4-0.9
The distilled water surplus surplus
1. single (hydrogenated tallow) trimethyl ammonium of chlorination
2. chlorination two (hydrogenated tallow) Dimethyl Ammonium
3.1-hydrogenated tallow acid amides ethyl-2-hydrogenated tallow imidazoline.
Fabric after the silicone gel of adding emulsification can make washing in the fabric softener composition of embodiment is easy to press and outward appearance is improved (as product B M and product D).Fabrid care composition of the present invention all has good effect to polyester, cotton and the cotton/polyester mixture through washing.
Claims (34)
1, a kind of liquid Fabrid care composition is characterized in that it contains:
(1) a kind of emulsion polymerization silicone gel;
Wherein said polymer siloxane is curable, and has
T (three functional units)=R " SiO
3/2
Q (four functional units)=SiO
4/2
D (two functional units)=R '
ZSiO
2/2With
M (functional unit)=(RO) R '
2SiO
1/2
Wherein R ', R " are C
1-20Alkyl or be selected from an amine groups of the alkylamine that contains about 2-7 carbon atom in cyclammonium, polyamine and its alkyl chain;
Wherein R is hydrogen or C
1-3Alkyl;
Wherein said polymer siloxane contains above-mentioned T and/or the Q functional unit of 3%-30% approximately; The above-mentioned D functional unit of about 70-97%; About 0.1%-10%M functional unit;
(2) be selected from the another kind of Fabrid care composition of the effective dose of starch, surfactant and fabric softener and composition thereof; With
(3) a kind of suitable carriers can make the described silicone gel of effective dose be deposited on this fabric;
Wherein said fabric softener is selected from following material:
I. quaternary ammonium compound;
Ii. aliphatic amine fabric softening compound;
Iii. aliphatic amide compound;
Iv. aliphatic acid;
V. aliphatic alcohol; With
Vi. its mixture.
2, the Fabrid care composition of claim 1 is characterized by said polymer siloxane gel and makes by emulsion polymerization; The molecular weight of this polymer siloxane is about 20000-10
15
3, the Fabrid care composition of claim 1 is characterized by by the said curable silicone polymer of emulsification, and makes curable silicone crosslinked polymer in the emulsion and solidify to make this silicone gel.
4, the Fabrid care composition of claim 3 is characterized by the curing of quickening this siloxane polymer with a kind of curing catalysts.
5, the Fabrid care composition of claim 3 is characterized by the curing of quickening silicone gel by heating.
6, the Fabrid care composition of claim 5, the solidity amine functional siloxane polymer that to it is characterized by said curable silicone polymer be a kind of branch can quicken to solidify with a kind of curing catalysts.
7, the Fabrid care composition of claim 6, it is characterized by said curing catalysts is a kind of alkali, said heating is to rise to about 75 ℃ ± 15 ℃ from room temperature.
8, the Fabrid care composition of claim 1, it is characterized by said composition is a kind of concentrate, it contains the 0.05%-40%(weight of having an appointment) silicone gel, can dilute this concentrate during use.
9, the Fabrid care composition of claim 8, it is a kind of liquid, aqueous it is characterized by this concentrate, and it contains the silicone gel of the 0.1%-20% that has an appointment, and described carrier mainly is a water.
10, the Fabrid care composition of claim 8 is characterized by the silicone gel that said concentrate contains about 0.5%-10%.
11, the Fabrid care composition of claim 1, the content that it is characterized by this fabric softener is about the 3%-35% of composition total weight; The weight ratio of silicone gel and fabric softener is about 17: 1-1: 350.
12, the Fabrid care composition of claim 11, the weight ratio that it is characterized by silicone gel and fabric softener is about 10: 1 to 1: 100.
13, the Fabrid care composition of claim 11, the weight ratio that it is characterized by silicone gel and fabric softener is about 1: 1 to 1: 10.
14, the Fabrid care composition of claim 11, the weight ratio that it is characterized by silicone gel and fabric softener is about 1: 5 to 1: 10.
15, the Fabrid care composition of claim 2, the molecular weight that it is characterized by said polymer siloxane gel is approximately greater than 500000 ± 400000.
16, the Fabrid care composition of claim 2 is characterized by said polymer siloxane gel and has about 5%-20%T and/or Q functional unit, about 80%-95%D functional unit, the about 8%M functional unit of 0%-; Its molecular weight is greater than about 100000 ± 50000.
17, the Fabrid care composition of claim 16, it is characterized by said polymer siloxane and have about 5%-15% said three and/or four functional units, said two functional units of about 85%-95%, the said functional unit of about 2%-5%, its molecular weight is about 100000-1000000.
18, the Fabrid care composition of claim 1, it is characterized by said silicone gel is to be made by the solidity amine functional siloxane of the branch with following array structure:
Wherein X equals Z+2; With
Y is at least 3; With
Z is at least 1;
Wherein R ' or R " are amine groups at least;
Wherein curable amine functions siloxanes is solidified into a kind of emulsification silicone gel with the emulsification form.
19, the Fabrid care composition of claim 18, it is characterized by R ' is C
1-3Alkyl;
R " is the alkyl amine group that contains 2-7 carbon atom in the alkyl chain approximately; Wherein curable amine functions siloxanes is by heating and/or add alkali and solidify with the emulsification form, thereby forms the silicone gel of emulsification.
20, the Fabrid care composition of claim 19, it is characterized by said R is methyl; R ' is a methyl, R " is (CH
2)
3NH(CH
2)
2NH
2; X is about 3.5; Y is about 27, Z is about 2; The molecular weight of this siloxanes is about 1000-2800, and the viscosity in the time of 25 ℃ is about the 5-40 centistoke; Wherein the solidity amine functional siloxane is by heating and/or add alkali and be solidified into the emulsification silicone gel with the emulsification form.
21, the Fabrid care composition of claim 1 is characterized by said fabric softener and comprises amines.
22, the Fabrid care composition of claim 1 is characterized by said fabric softener and comprises quaternary ammonium compound.
23, the Fabrid care composition of claim 1 is characterized by said fabric softener and is selected from acid amides, amine and quaternary ammonium compound and composition thereof.
24, the Fabrid care composition of claim 1, it is characterized by said another kind of fabric nursing compound is starch; Said contents of starch is about the 0.5%-20% of composition weight.
25, the composition of claim 1, it is characterized by said fabric is contacted with said composition with the water of effective dose, and press this fabric so that the amine functions siloxanes solidifies on this fabric, thus make fabric be easy to ironing with said composition, and the outward appearance of ironing back fabric is improved.
26, the composition of claim 25, it is characterized by said carrier is a kind of aqueous cleaning solution; Said silicone gel content in this solution is about 1ppm-300ppm.
27, the composition of claim 25, it is characterized by said carrier is a kind of aqueous cleaning solution; Wherein said silicone gel concentration in this solution is about 5-150ppm.
28, the composition of claim 26, it is characterized by said aqueous cleaning solution is a kind of detergent solution.
29, the composition of claim 26, it is characterized by aqueous cleaning solution is a kind of flushing liquor.
30, the liquid Fabrid care composition of claim 1, it is characterized by described another kind of fabric nursing compound is a kind of surfactant; This surfactant is selected from: anionic, nonionic, both sexes, both sexes (negative and positive) ion with cationic surface active agent and composition thereof.
31, the liquid Fabrid care composition of claim 30, it is characterized by said silicone gel is a kind of concentrate, it contains the silicone gel of 0.1%-33% approximately, can dilute this concentrate during use.
32, the liquid Fabrid care composition of claim 31, it is a kind of liquid, aqueous it is characterized by this concentrate, and it contains the silicone gel of the 0.5%-20% that has an appointment, and said carrier mainly is a water.
33, the liquid Fabrid care composition of claim 30 is characterized by the silicone gel that this concentrate contains 1%-10% approximately.
34, a kind of method that fabric is easy to press and outward appearance is improved that makes through washing, it is characterized in that this method comprises: (1) washs this fabric in the solution of the composition that contains effective water gaging and claim 30; Thereby said silicone gel is deposited on this fabric; (2) flushing and dry this fabric; (3) press this fabric.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US534,110 | 1990-06-06 | ||
| US07/534,109 US5064543A (en) | 1990-06-06 | 1990-06-06 | Silicone gel for ease of ironing and better looking garments after ironing |
| US534,109 | 1990-06-06 | ||
| US695,357 | 1991-05-08 | ||
| US07/695,357 US5336419A (en) | 1990-06-06 | 1991-05-08 | Silicone gel for ease of ironing and better looking garments after ironing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1059001A true CN1059001A (en) | 1992-02-26 |
Family
ID=27064356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91104548 Pending CN1059001A (en) | 1990-06-06 | 1991-06-06 | Make clothes be easy to ironing and the better silicone gel of ironing back outward appearance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1059001A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117386B (en) * | 2006-07-31 | 2011-09-28 | 赢创高施米特有限公司 | New polysiloxanes with quaternary ammonium groups, method for their manufacture and their use as textile softeners |
| CN104854227A (en) * | 2012-12-21 | 2015-08-19 | 高露洁-棕榄公司 | Biofuels production from bio-derived carboxylic-acid esters |
| CN113047037A (en) * | 2021-03-26 | 2021-06-29 | 广州市爱家有方日用品有限公司 | Fabric ironing water and preparation method thereof |
-
1991
- 1991-06-06 CN CN 91104548 patent/CN1059001A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117386B (en) * | 2006-07-31 | 2011-09-28 | 赢创高施米特有限公司 | New polysiloxanes with quaternary ammonium groups, method for their manufacture and their use as textile softeners |
| CN104854227A (en) * | 2012-12-21 | 2015-08-19 | 高露洁-棕榄公司 | Biofuels production from bio-derived carboxylic-acid esters |
| CN104854227B (en) * | 2012-12-21 | 2019-03-01 | 高露洁-棕榄公司 | Fabric conditioner containing amine function silicone |
| CN113047037A (en) * | 2021-03-26 | 2021-06-29 | 广州市爱家有方日用品有限公司 | Fabric ironing water and preparation method thereof |
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