CN1365306A - Disintegrative core for high pressure casting, method for manufacturing the same and method for extracting the same - Google Patents
Disintegrative core for high pressure casting, method for manufacturing the same and method for extracting the same Download PDFInfo
- Publication number
- CN1365306A CN1365306A CN00809823A CN00809823A CN1365306A CN 1365306 A CN1365306 A CN 1365306A CN 00809823 A CN00809823 A CN 00809823A CN 00809823 A CN00809823 A CN 00809823A CN 1365306 A CN1365306 A CN 1365306A
- Authority
- CN
- China
- Prior art keywords
- core
- soluble salt
- casting
- water soluble
- fuse
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/10—Cores; Manufacture or installation of cores
- B22C9/105—Salt cores
Abstract
Disclosed is a method for manufacturing a disintegrative core for use in high pressure casting. The disintegrative core can be applied where a light metal such as an aluminum alloy or magnesium alloy is subjected to high pressure casting, such as die casting or squeeze casting and is manufactured from a water-soluble salt which is high in latent heat and ranges, in melting point, from 280 to 520 DEG C and, in heat transfer coefficient ( kappa ), from 9.8x10<-2> to 1.2x10 W/m- DEG C. The water-soluble salt, alone or in combination with a fine hard powder, is melted and solidified in a core mold. Alternatively, the melt is processed into a fine powder which is then molded in a core mold. The method can be applied for the manufacture of complex shapes of cores. Also, disclosed is a method for extracting such a core from a high pressure molded product.
Description
Technical field
The present invention relates to a kind of method that is used to make the defeated and dispersed core that is used for high-pressure casting such as die casting or compression casting.More specifically, the present invention relates to make complicated defeated and dispersed core with water soluble salt.The present invention also relates to such water soluble salt core.In addition, the invention still further relates to a kind of method that extracts this water soluble salt core.
Prior art
Usually, in order to prepare the foundry goods with complex internal structure or indent, the technology of preparing of core is essential.
Under the situation of gravitational casting,, then a kind of motlten metal is imported model and in model, solidify the inside that a kind of defeated and dispersed core of being made by hard sand or ceramic powder or water soluble salt core are placed on model.After this, defeated and dispersed core is passed through machinery and chemical method removal or water or steam with the stripping of salt core.
For internal combustion engine, form an annular oil cooling but during passage at internal piston, salt core technology of preparing is useful.
U.S. Pat 3645491, its content have disclosed a kind of core technology of preparing here with reference to combination, and the water soluble salt of pulverizing in this technology combines with 10% synthetic resin as bonding agent.U.S. Pat 4629708, its content have disclosed a kind of core technology of preparing here with reference to combination, in this technology, and a kind of water soluble salt such as sodium chloride and potassium chloride and pottery as aluminium oxide and mix also sintering as the organic siliconresin of bonding agent.
Yet under actual conditions, in order to prepare a kind of high performance aluminium alloy or composite material piston, piston must be through high-pressure casting such as die casting and compression casting.
In this high-pressure casting, because motlten metal collapses because of high pressure by inside or the core that casting pressure infiltrates core, conventional defeated and dispersed core or the conventional salt core made with sand can not be used for high-pressure casting method.
Recently, several core technologies of preparing that can be used in the high-pressure casting requirement have been developed.For example, U.S. Pat 3963818, its content have disclosed a kind of core technology of preparing here with reference to combination, and a kind of water soluble salt of pulverizing such as sodium chloride and potassium chloride in this technology add about 1% water, at 1.8～4.0 tons/cm
2The high pressure compacted under, then 100～300 ℃ of following sintering 20 minutes.
U.S. Pat 4438804, its content is here with reference to combination, disclosed a kind of core forming method, a kind of in the method water soluble salt powder mixes with hard powder such as zircon sand, and is under high pressure molded and shaped with potash, brium carbonate or alkali silicate as bonding agent.
U.S. Pat 3407864, its content is here with reference to combination, disclosed a kind of core forming method, a kind of in the method water soluble salt powder such as sodium chloride and potassium chloride mix with the borax of 3% weight, the magnesia of 1% weight and the mica of 1% weight, and is under high pressure molded and shaped then.
BP GB2156720, its content is here with reference to combination, disclosed a kind of core technology of preparing with the water soluble salt shaped by fluid pressure pulverized.
Utilize among the preparation method of high pressure or hydraulic pressure at these, gap between particles is reduced to minimum, its adhesion strengthens, as long as this core keeps shape invariance under the casting pressure of 5000～20000psi (pound/square inch), just can prevent that motlten metal from infiltrating the inside of core.
Yet these conventional methods have following shortcoming, and its application is limited by the size and dimension of fuse, and because the strict control of particle size of salt powder, its production cost increases.
In addition, because water dissolving fuse needs a large amount of time so remove fuse fully from the foundry goods of high-pressure casting.
Simultaneously, U.S. Pat 4446906, US4875517 and US5303761, its content is here with reference to combination, disclosed a kind of core preparation method, in the method with a kind of water soluble salt such as sodium chloride and potassium chloride heating, fusing, and selectively combine and carry out die casting with grit such as silica and aluminium oxide.
In fact better a little aspect the forming method of fuse shape and productivity ratio, but these conventional methods since its application of size of fuse be limited.In addition, when water dissolving fuse, conventional method needs a large amount of time to remove fuse fully from the foundry goods of high-pressure casting.
U.S. Pat 4840219, its content is here with reference to combination, disclosed a kind of core preparation method, the fuse salt that contains the mixture of 40% weight sodium chloride and 40% weight sodium carbonate in the method adds 10～50% hard powder to form a kind of slurry, and this slurry is imported in the model.U.S. Pat 3459253, its content have disclosed a kind of core preparation method here with reference to combination, and wire or glass fibre join in the molten mixture salt that contains sulfate and carbonate in the method, to form a kind of slurry that is imported into a model.
These methods have more variation than compacting method or die casting method on the shape and size of fuse.Therebetween, because the fusion temperature of used salt is up to more than 660 ℃, because that solidification shrinkage is easy to generate is cracked, so fuse becomes frangible and is difficult to operation.And, because fuse must dissolve by water, therefore need the fuse of a considerable time removal high-pressure casting foundry goods, thereby resulting core salt can not be reused.
Summary of the invention
With the forgoing problems and concerns in mind, an object of the present invention is to provide a kind of a kind of method that is used for the defeated and dispersed core of high-pressure casting that is used to make, can make the fuse of a complicated shape simply, and by using a kind of aluminium alloy of reusing or a kind of magnesium alloy to obtain a kind of fuse that is used for high-pressure casting.
Another object of the present invention provides a kind of fuse that is used for high-pressure casting.
Another object of the present invention provides a kind of method that extracts this fuse.
In one embodiment, one object of the present invention realizes by the method that manufacturing is used for the fuse of high-pressure casting, and wherein a kind of water soluble salt combines separately or with a kind of fine hard powder, and fusing is also solidified in a core; Perhaps be processed into a kind of fine powder, and moulding in a core under pressure, said water soluble salt has high latent heat, and its fusing point is in 280～520 ℃ of scopes, and heat transfer coefficient (k) is 9.8 * 10
-2To 1.2 * 10W/m ℃, defeated and dispersed thus core is made with this water soluble salt.
In another embodiment, another object of the present invention realizes by the defeated and dispersed core that is used for high-pressure casting with said method manufacturing.
In the another one embodiment, another object of the present invention is to realize by the method that extracts the defeated and dispersed core that is used for high-pressure casting from a high-pressure casting foundry goods, wherein core is heated to a fusion temperature, the high-pressure casting foundry goods does not have thermal deformation under this temperature, the core melt is drawn out of, and the foundry goods water is washed.
Finish preferred forms of the present invention
Following the present invention describes a kind of defeated and dispersed core that is used for high-pressure casting, and the method for making and extract this fuse.
The defeated and dispersed core that is used for high-pressure casting is made with a kind of water soluble salt, and wherein a kind of water soluble salt combines separately or with a kind of fine hard powder, and fusing is also solidified in a core; Perhaps be processed into a kind of fine powder, and moulding in a core under pressure, the fusing point of said water soluble salt is in 280～520 ℃ of scopes, and heat transfer coefficient (k) is 9.8 * 10
-2To 1.2 * 10W/m ℃, have high latent heat, defeated and dispersed thus core can be applied to a kind of light metal such as aluminium alloy or magnesium alloy and carry out high-pressure casting such as die casting or compression casting.
Because it has the fusing point of 280～520 ℃ of scopes, heat transfer coefficient (k) is 9.8 * 10
-2To 1.2 * 10W/m ℃, have high latent heat, water soluble salt is from by potassium nitrate (KNO
3), potassium nitrite (KNO
2), sodium nitrate (NaNO
3), natrium nitrosum (NaNO
2), copper chloride (CuCl
2), sodium chloride (NaCl), potassium chloride (KCl), lithium chloride (LiCl), lead chloride (PbCl
2), magnesium chloride (MgCl
2), barium chloride (BaCl
2), calcium chloride (CaCl
2) and its mixture group of constituting in select.
About fusing point, known potassium nitrate (KNO
3) be 333 ℃, potassium nitrite (KNO
2) be 290 ℃, sodium nitrate (NaNO
3) be 308 ℃, natrium nitrosum (NaNO
2) be 270 ℃.
That measures contains NaCl: CuCl
2Weight ratio is that the fusing point of 82: 17 salt-mixture is 315 ℃, contains KNO
3: the KCl weight ratio is that the fusing point of 92: 8 salt-mixture is 320 ℃, contains KCl: the LiCl weight ratio is that the fusing point of 54: 46 salt-mixture is 320 ℃, contains PbCl
2: the NaCl weight ratio is that the fusing point of 93: 7 salt-mixture is 410 ℃, contains MgCl
2: the NaCl weight ratio is that the fusing point of 54: 44 salt-mixture is 430 ℃, contains CaCl
2: BaCl
2Weight ratio is that the fusing point of 53: 47 salt-mixture is 450 ℃, and contains NaCl: CaCl
2Weight ratio is that the fusing point of 54: 46 salt-mixture is 510 ℃, and the heat transfer coefficient of every kind of salt (k) scope is 9.8 * 10
-2To 1.2 * 10W/m ℃.
This water soluble salt solidifies in model.At this moment, the water soluble salt of fusion imports in the model under than high 30～80 ℃ temperature of its fusing point, thereby has reduced because solidification shrinkage causes cracked generation.
In this, if the temperature of fusion water soluble salt exceeds its fusing point more than 80 ℃, when solidifying, will produce and shrink the cracked and hole that causes.On the other hand, if temperature exceeds 30 ℃ of its fusing point less thaies, water soluble salt just is difficult in the injection model.
In addition, half of the controlled fusing point that is no more than the every kind of salt that imports of model temperature.Its reason is, if model temperature is lower, salt just can not import in the model well.On the other hand, if model temperature is higher, the surface texture that solidifies core becomes coarse, and the deep of core will produce thermal deformation when high-pressure casting like this.
Therefore, the material that is suitable for model is a graphite, and it has splendid heat conductivity.When model was made with graphite, fuse salt imported in the model easily, and it is very fast that setting rate becomes, and the surface texture of solidifying core like this is good.
In fuse salt, can add powder, fiber and the whisker of thin thermally-stabilised grit such as the non-reacting metal of chemistry or pottery.In order to use, they are homodisperse.
As an example, and and unrestricted, be suitable for metallic particle and be having high rigidity and with the silicon of the similar proportion of said salt.Equally, aluminium oxide (Al
2O
3), carborundum (SiC) etc. also can be used as ceramic particle.Can use such fiber or whisker.
Preferably the addition of grit is 5～30% weight ratios.If the addition of grit surpasses 30% weight ratio, the contraction in the time of can suppressing to solidify is uprised by the intensity of the core that peptizaiton produced.But it can produce the part grit and adhere to problem on the high-pressure casting cast(ing) surface.On the other hand, if the amount that adds is lower than 5% weight ratio, just can not obtain the additive effect of grit.
Water soluble salt is processed into a kind of powder, imports in the core and be molded as a fuse.In this, optimum is that the water soluble salt powder has the size of 40～100 μ m, to be used at forming under the pressure.Equally, preferably use a kind of not with the lubricant of this salt chemically reactive so that cast member is easily and model separation.
The scope of the briquetting pressure that is produced by pressurization at this moment, is preferably 60～100MPa.In addition, molded core is preferably in its fusing point and kept 0.5～1 minute, so that the surface texture refinement of fuse.
The resulting fuse of the method according to this invention can be used in the high-pressure casting of a kind of metal alloy such as aluminium alloy or magnesium alloy.
When low heat capacity metal such as aluminium alloy and magnesium alloy high-pressure casting, model is full of fused mass immediately within 0.5～3 second.Because metal alloy such as aluminium alloy or magnesium alloy, though have the fusing point (280～520 ℃) of the common pouring temperature (640～720 ℃) that is lower than common motlten metal, only have the heat transfer coefficient (k) (9.8 * 10 of steel heat transfer coefficient (331～403W/m ℃) 1/1500～1/3000
-2～1.2 * 10W/m ℃), steel is the typical material of high-pressure casting mould.Molten alloy is once importing the violent cooling of model.
Specifically, low because the thermal conductivity ratio steel of fuse is the material of model, so most of heat that fused mass keeps passes to model, and heat passes hardly to fuse.Simultaneously, the high latent heat of fuse only allows on surface to 2～the 3 μ m degree of depth rather than produce thermal deformation in shape whole.In other words, since the high latent heat of fuse, indeformable on its global shape, the not variation of fuse.
As the routine casting of the instantaneous high-pressure casting of finishing in, water soluble salt of the present invention is suitable for doing the fuse of low heat capacity cast metal such as aluminium and magnesium.
A kind of method of removing fuse from the foundry goods of high-pressure casting is provided simultaneously, just, a kind of method that from foundry goods, extracts fuse, undertaken by following step, be about to this fuse and be heated to fusion temperature, foundry goods in this melt temperature high-pressure casting does not have thermal deformation, extracts the fuse fused mass, and water flushing foundry goods.
When the high-pressure casting foundry goods being heated to 320～550 ℃ 3～5 minutes the time, the inside of heat transferred fuse, fuse fusing and taking out like this.The material that obtains like this can be used further to the moulding of fuse, to obtain benefit economically.
Can obtain better understanding of the present invention according to the following examples, these embodiment set forth for example, and are not construed as limiting the invention.
Embodiment 1
With KNO
3(333 ℃ of fusing points), KNO
2(290 ℃ of fusing points), NaNO
3(308 ℃ of fusing points) NaNO
2(270 ℃ of fusing points), NaCl: CuCl
2(82: 17) mixture (315 ℃ of fusing points), KNO
3: KCl (92: 8) mixture (320 ℃ of fusing points), KCl: LiCl (54: 46) mixture (320 ℃ of fusing points), PbCl
2: NaCl (93: 7) mixture (410 ℃ of fusing points), MgCl
2: NaCl (54: 44) mixture (430 ℃ of fusing points), CaCl
2: BaCl
2(53: 47) mixture (450 ℃ of fusing points), NaCl: CaCl
2(54: 46) mixture (510 ℃ of fusing points) is heated to above about 30～80 ℃ temperature of its fusing point respectively separately.Import every kind of fuse salt in the model lentamente and import respectively in the graphite model, these two kinds of models all are preheating to half temperature of this salt fusing point, to make the cylindrical core of a diameter 20mm length 100mm.
The gained core is carried out die casting and compression casting in model, the space distance between the wall of model and the fuse on diameter is arranged to 3mm, 5mm, 7mm, 9mm, 12mm and 15mm, and measures its performance.The result below table 1 and table 2 in provide.
Performance for the analytical test fuse, ADC12 Al alloy is heated to 670 ℃ of high-pressure castings of fused mass being carried out die casting with the feed speed of 1.8m/sec, carry out the high-pressure casting of compression casting with the feed speed of 0.32m/sec, the pressure of die casting and compression casting is 980kg/cm
2After high-pressure casting, the extraction of fuse is by realizing at 320～550 ℃ of following heating high-pressure castings 3～5 minutes, fusing fuse and water flushing foundry goods.
Table 1
The performance of prepared fuse in punching block
| Core | Die casting (the gap mm between core and the model) | Compression casting (the gap mm between core and the model) | ||||||||||
| ???3 | ??5 | ??7 | ??9 | ??12 | ??15 | ??3 | ??5 | ??7 | ??9 | ??12 | ??15 | |
| ????NaNO 2 | ??○ | ??○ | ??× | ??× | ??× | ??× | ??○ | ??× | ??× | ??× | ??× | ??× |
| ????KNO 2 | ??○ | ??○ | ??× | ??× | ??× | ??× | ??○ | ??× | ??× | ??× | ??× | ??× |
| ????NaNO 3 | ??○ | ??○ | ??○ | ??× | ??× | ??× | ??○ | ??× | ??× | ??× | ??× | ??× |
| ??NaCl∶CuCl 2????(82∶17) | ??○ | ??○ | ??○ | ??× | ??× | ??× | ??○ | ??× | ??× | ??× | ??× | ??× |
| ??KNO 3∶KCl ????(92∶8) | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??○ | ??× | ??× | ??× | ??× |
| ??KCl∶LiCl ????(54∶46) | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??○ | ??× | ??× | ??× | ??× |
| ????KNO 3 | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??○ | ??○ | ??○ | ??× | ??× | ??× |
| ??PbCl 2∶NaCl ????(93∶7) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??× |
| ??MgCl 2∶NaCl ??(54∶44) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
| ??CaCl 2∶BaCl 2??(53∶47) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
| ??NaCl∶CaCl 2??(54∶46) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
Annotate) zero: be fit to (surface appearance is good)
*: be not suitable for (surface appearance is poor)
Table 2
The performance of prepared fuse in the graphite model
| Core | Die casting (the gap mm between core and the model) | Compression casting (the gap mm between core and the model) | ||||||||||
| ??3 | ??5 | ??7 | ??9 | ??12 | ??15 | ??3 | ??5 | ??7 | ??9 | ??12 | ??15 | |
| ????NaNO 2 | ??○ | ??○ | ??○ | ??× | ??× | ??× | ??○ | ??× | ??× | ??× | ??× | ??× |
| ????KNO 2 | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??× | ??× | ??× | ??× | ??× |
| ????NaNO 3 | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??○ | ??× | ??× | ??× | ??× |
| ????NaCl∶CuCl ????(82∶17) | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??○ | ??○ | ??○ | ??× | ??× | ??× |
| ????KNO 3∶KCl ????(92∶8) | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??○ | ??○ | ??× | ??× | ??× |
| ????KCl∶LiCl ????(54∶46) | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??○ | ??○ | ??○ | ??× | ??× | ??× |
| ????KNO 3 | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??× |
| ??PbCl 2∶NaCl ????(93∶7) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??× |
| ??MgCl 2∶NaCl ????(54∶44) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
| ??CaCl 2∶BaCl 2????(53∶47) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
| ??NaCl∶CaCl 2????(54∶46) | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
Annotate) zero: be fit to (surface appearance is good)
*: be not suitable for (surface appearance is poor)
Embodiment 2
With KNO3 (333 ℃ of fusing points), KNO
2(290 ℃ of fusing points), NaNO
3(308 ℃ of fusing points) NaNO
2(270 ℃ of fusing points), NaCl: CuCL
2(82: 17) mixture (315 ℃ of fusing points), KNO
3: KCl (92: 8) mixture (320 ℃ of fusing points), KCl: LiCl (54: 46) mixture (320 ℃ of fusing points), PbCl
2: NaCl (93: 7) mixture (410 ℃ of fusing points), MgCl
2: NaCl (54: 44) mixture (430 ℃ of fusing points), CaCl
2: BaCl
2(53: 47) mixture (450 ℃ of fusing points), NaCl: CaCl
2(54: 46) mixture (510 ℃ of fusing points) is heated to above about 30～80 ℃ temperature of its fusing point respectively separately, with the aluminium oxide (Al of the weight ratio 20～30% of diameter 40～100 μ m
2O
3: Japanese Isolite.Co.Ltd. produces) join in the melt of heating and evenly disperse.Then this dispersion is imported lentamente in the graphite model, this model is preheating to half temperature of this dispersion fusing point, to make the cylindrical core of a diameter 20mm length 100mm.
Equally, the silicon carbide whisker (SiC: Japanese TongHae Carbon Co.Ltd. produces) of the weight ratio 5～15% of diameter 0.5～1 μ m, length 100～400 μ m is evenly disperseed, to make a fuse.
The gained core is carried out die casting and compression casting in model, the space distance between the wall of model and the fuse on diameter is arranged to 3mm, 5mm, 7mm, 9mm, 12mm and 15mm, and measures its performance.Provide in result's table 3 below.
Performance for the analytical test fuse, ADC12 Al alloy is heated to 670 ℃ of high-pressure castings of fused mass being carried out die casting with the feed speed of 1.8m/sec, carry out the high-pressure casting of compression casting with the feed speed of 0.32m/sec, the pressure of die casting and compression casting is 980kg/cm
2After high-pressure casting, the extraction of fuse is by realizing at 320～550 ℃ of following heating high-pressure castings 3～5 minutes, fusing fuse and water flushing foundry goods.
Table 3
Performance with mixture prepared fuse in the graphite model of grit
| Core | Die casting (the gap mm between core and the model) | Compression casting (the gap mm between core and the model) | ||||||||||
| ??3 | ??5 | ??7 | ??9 | ??12 | ??15 | ??3 | ??5 | ??7 | ??9 | ??12 | ??15 | |
| ??NaNO 2+Al 2O 3 | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??○ | ??× | ??× | ??× | ??× |
| ??KNO 2+SiC | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??○ | ??× | ??× | ??× | ??× |
| ??NaNO 3+Al 2O 3 | ??○ | ??○ | ??○ | ??○ | ??× | ??× | ??○ | ??○ | ??○ | ??× | ??× | ??× |
| ??NaCl∶CuCl 2??(82∶17)+Al 2O 3 | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??○ | ??○ | ??○ | ??× | ??× | ??× |
| ??KNO 3∶KCl ??(92∶8)+Al 2O 3 | ??○ | ??○ | ??○ | ??○ | ??○ | ??× | ??○ | ??○ | ??○ | ??○ | ??× | ??× |
| ??KCl∶LiCl ??(54∶46)+SiC | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
| ??KNO 3+SiC | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??× |
| ??PbCl 2∶NaCl ??(93∶7)+Al 2O 3 | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ |
| ??MgCl 2∶NaCl ??(54∶44)+SiC | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ |
| ??CaCl 2∶BaCl 2??(53∶47)+SiC | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ |
| ??NaCl∶CaCl 2 | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ | ??○ |
| ??(54∶46)+Al 2O 3 |
Annotate) zero: be fit to (surface appearance is good)
*: be not suitable for (surface appearance is poor)
Embodiment 3
With KNO
3(333 ℃ of fusing points), KNO
2(290 ℃ of fusing points), NaNO
3(308 ℃ of fusing points) NaNO
2(270 ℃ of fusing points), NaCl: CuCl
2(82: 17) mixture (315 ℃ of fusing points), KNO
3: KCl (92: 8) mixture (320 ℃ of fusing points), KCl: LiCl (54: 46) mixture (320 ℃ of fusing points), PbCl
2: NaCl (93: 7) mixture (410 ℃ of fusing points), MgCl
2: NaCl (54: 44) mixture (430 ℃ of fusing points), CaCl
2: BaCl
2(53: 47) mixture (450 ℃ of fusing points), NaCl: CaCl
2(54: 46) mixture (510 ℃ of fusing points) is pulverized the particle into about 40～100 μ m, and the mica that adds weight ratio 1% is as lubricant, and is pressurized to the pressure of 80～100MPa, to be molded as the cylindrical core of a diameter 20mm length 100mm.With molded fuse under the fusing point of its salt, kept 0.5～1 minute, to make a fuse.
Aluminium oxide (Al with the weight ratio 15% of diameter 40～100 μ m
2O
3: Japanese Isolite.Co.Ltd. produces) and the silicon carbide whisker (SiC: Japanese TongHae Carbon.Co.Ltd. produces) of the weight ratio 8% of diameter 0.5～1 μ m, length 100～400 μ m join in the salt powder and evenly mixing, to make a fuse.
The gained core is carried out die casting and compression casting in model, the space distance between the wall of model and the fuse on diameter is arranged to 3mm, 5mm, 7mm, 9mm, 12mm and 15mm, and measures its performance.Provide in result's table 4 below.
Performance for the analytical test fuse, ADC12 Al alloy is heated to 670 ℃ of high-pressure castings of fused mass being carried out die casting with the feed speed of 1.8m/sec, carry out the high-pressure casting of compression casting with the feed speed of 0.32m/sec, the pressure of die casting and compression casting is 980kg/cm
2After high-pressure casting, the extraction of fuse is by realizing at 320～550 ℃ of following heating high-pressure castings 3～5 minutes, fusing fuse and water flushing foundry goods.
Table 4
With the mixture of grit performance at the prepared fuse of forming under the pressure
| Core | Die casting (the gap mm between core and the model) | Compression casting (the gap mm between core and the model) | ||||||||||
| ????3 | ????5 | ????7 | ????9 | ????12 | ????15 | ????3 | ????5 | ????7 | ????9 | ????12 | ????15 | |
| ????NaNO 2+Al 2O 3 | ????○ | ????○ | ????○ | ????○ | ????× | ????× | ????○ | ????○ | ????○ | ????× | ????× | ????× |
| ????KNO 2+SiC | ????○ | ????○ | ????○ | ????○ | ????× | ????× | ????○ | ????○ | ????○ | ????× | ????× | ????× |
| ????NaNO 3+Al 2O 3 | ????○ | ????○ | ????○ | ????○ | ????○ | ????× | ????○ | ????○ | ????○ | ????○ | ????× | ????× |
| ????NaCl∶CuCl ??(82∶17)+Al 2O 3 | ????○ | ????○ | ????○ | ????○ | ????○ | ????× | ????○ | ????○ | ????○ | ????○ | ????× | ????× |
| ????KNO 3∶KCl ??(92∶8)+Al 2O 3 | ????○ | ????○ | ????○ | ????○ | ????× | ????× | ????○ | ????○ | ????○ | ????○ | ????× | ???× |
| ????KCl∶LiCl ??(54∶46)+SiC | ????○ | ????○ | ????○ | ????○ | ????○ | ????× | ????○ | ????○ | ????○ | ????○ | ????○ | ???× |
| ????KNO 3+SiC | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ???× |
| ????PbCl 2∶NaCl ??(93∶7)+Al 2O 3 | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ???○ |
| ????MgCl 2∶NaCl ??(54∶44)+SiC | ????○ | ????○ | ????○ | ????○ | ????○ | ????× | ????○ | ????○ | ????○ | ????○ | ????○ | ???× |
| ????CaCl 2∶BaCl 2??(53∶47)+SiC | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ???○ |
| ????NaCl∶CaCl 2??(54∶46)+Al 2O 3 | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | ???○ |
Annotate) zero: be fit to (surface appearance is good)
*: be not suitable for (surface appearance is poor)
Industrial applicibility
As previously mentioned, can make simply with a kind of water soluble salt the fuse of complicated shape, wherein said water soluble salt, be combined separately or with a kind of fine hard powder, fusing is also solidified in a core, and the fusing point of said water soluble salt is in 280～520 ℃ of scopes, and heat transfer coefficient (k) is 9.8 * 10-2To 1.2 * 10W/m ℃, has high latent heat. In addition, this fuse can be applicable to high-pressure casting such as die casting and the compression casting of light metal such as aluminium alloy or magnesium alloy. At last, heating, fusing and the fuse of extracting out can be reused, thereby produce benefit economically.
Claims (10)
1. a manufacturing is used for the method for the defeated and dispersed core of high-pressure casting, it is characterized in that, a kind of water soluble salt combines separately or with a kind of fine hard powder, and fusing is also solidified in a core; Perhaps be processed into a kind of fine powder, and moulding in a core under pressure, the fusing point of said water soluble salt is in 280～520 ℃ of scopes, and heat transfer coefficient (k) is 9.8 * 10
-2To 1.2 * 10W/m ℃, have high latent heat, this defeated and dispersed core can be applicable to a kind of light metal such as aluminium alloy or magnesium alloy and carries out high-pressure casting such as die casting or compression casting thus, and this defeated and dispersed core is made by this water soluble salt.
2. method according to claim 1 is characterized in that, said water soluble salt is from by KNO
3, KNO
2, NaNO
3, NaNO
2And composition thereof select in the group formed.
3. method according to claim 1 is characterized in that, said water soluble salt is from by selecting the following group that salt mixture constituted, and said salt mixture is: percentage by weight is 82: 17 NaCl: CuCl
2, percentage by weight is 92: 8 KNO
3: KCl, percentage by weight are that 54: 46 KCl: LiCl, percentage by weight are 93: 7 PbCl
2: NaCl, percentage by weight are 54: 44 MgCl
2: NaCl, percentage by weight are 53: 47 CaCl
2: BaCl
2, percentage by weight is 54: 46 NaCl: CaCl
2
4. according to the arbitrary described method of claim 1 to 3, it is characterized in that said water soluble salt is melting under the temperature that is higher than 30～80 ℃ of its fusion temperatures and solidifying in a model.
5. according to the arbitrary described method of claim 1 to 3, it is characterized in that said model is made with graphite, and be heated to half temperature of said salt fusion temperature.
6. according to the arbitrary described method of claim 1 to 3, it is characterized in that said water soluble salt is processed into the powder of a kind of particle size 40～100 μ m, import in the model and at 80～100MPa forming under the pressure.
7. according to the arbitrary described method of claim 1 to 3, it is characterized in that, add the thin grit of reaction non-chemically of weight ratio 5～30% in the water soluble salt of said fusion, said thin grit is selected from the group of being made up of metal or ceramic powders, fiber and whisker and composition thereof.
8. defeated and dispersed core that is used for high-pressure casting is according to the arbitrary method manufacturing of claim 1 to 7.
9. an extraction is used for the method for the defeated and dispersed core of high-pressure casting, it is characterized in that, said core is heated to fusion temperature, does not have thermal deformation at the foundry goods of this temperature high-pressure casting, the fused mass of this fuse is extracted, and water washes said foundry goods.
10. method according to claim 9 is characterized in that, with the foundry goods of high-pressure casting be heated to 320～550 ℃ 3～5 minutes, with the inside of the said fuse of heat transferred, fuse is melted and takes out so thus.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019990027082A KR20000006623A (en) | 1999-07-06 | 1999-07-06 | A method for manufacturing a disintegrative core for a high pressure casting, a core and a method for extracting the core |
| KR1999/027082 | 1999-07-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1365306A true CN1365306A (en) | 2002-08-21 |
| CN1208149C CN1208149C (en) | 2005-06-29 |
Family
ID=19599670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008098239A Expired - Fee Related CN1208149C (en) | 1999-07-06 | 2000-07-04 | Disintegrative core for high pressure casting, method for manufacturing the same and method for extracting the same |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6755238B1 (en) |
| JP (1) | JP3757165B2 (en) |
| KR (2) | KR20000006623A (en) |
| CN (1) | CN1208149C (en) |
| AU (1) | AU5578400A (en) |
| DE (1) | DE10084785T1 (en) |
| WO (1) | WO2001002112A1 (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314498C (en) * | 2005-09-12 | 2007-05-09 | 华南理工大学 | Soluble salt core for extrusion casting and its making process |
| CN1994615B (en) * | 2006-12-11 | 2010-12-01 | 东风汽车有限公司 | Salt core of engine piston |
| CN101391280B (en) * | 2007-09-18 | 2011-02-09 | 山东滨州渤海活塞股份有限公司 | Special-shaped salt core for press casting |
| CN101501177B (en) * | 2006-06-30 | 2012-09-19 | Posco公司 | Molten salts for the refining of MG alloys |
| CN103639366A (en) * | 2013-09-19 | 2014-03-19 | 沈阳工业大学 | Preparation method for U-shaped hole in casting |
| CN103889615A (en) * | 2011-10-19 | 2014-06-25 | 铃木株式会社 | Casting core, method for producing same, and method for casting using said core |
| CN104703725A (en) * | 2012-10-01 | 2015-06-10 | 马勒国际有限公司 | Method for the production of salt cores for producing workpieces by casting |
| CN105171988A (en) * | 2015-06-25 | 2015-12-23 | 贵州航天精工制造有限公司 | Aviation buffer rubber gasket and production method thereof |
| CN104128556B (en) * | 2014-05-24 | 2016-04-13 | 芜湖浙鑫新能源有限公司 | The ceramic core that a kind of inorganic easy depoling is defeated and dispersed |
| CN108213395A (en) * | 2017-12-26 | 2018-06-29 | 吴立兵 | Demould casting method |
| CN108237206A (en) * | 2018-02-28 | 2018-07-03 | 厦门格欧博新材料科技有限公司 | A kind of salt core former |
| CN108237205A (en) * | 2016-12-23 | 2018-07-03 | 现代自动车株式会社 | The salt core and its manufacturing method of die casting are carried out with aluminium |
| CN108838339A (en) * | 2018-08-03 | 2018-11-20 | 襄阳美利信科技有限责任公司 | A kind of method of salt core die casting |
| WO2019085124A1 (en) * | 2017-11-02 | 2019-05-09 | 深圳市爱能森科技有限公司 | Ternary molten salt system-based soluble core, preparation method therefor and application |
| CN110586849A (en) * | 2019-09-26 | 2019-12-20 | 宁波新天阳新材料科技有限公司 | Resin precoated sand easy to collapse |
| CN114833971A (en) * | 2022-04-19 | 2022-08-02 | 西北橡胶塑料研究设计院有限公司 | Method for forming joint of hollow surface composite fabric sealing element |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100400133B1 (en) * | 2000-07-26 | 2003-09-29 | 주식회사 기술연합 | A method for manufacturing a falling off casting sands core for a casting, a core and a method for extracturing the core |
| KR100400132B1 (en) * | 2000-07-26 | 2003-09-29 | 주식회사 기술연합 | A method for manufacturing a dissolution type core for a casting, a core and a method for extracting the core |
| JP4516024B2 (en) * | 2003-09-17 | 2010-08-04 | 盾 八百川 | Casting core |
| DE10359547B3 (en) * | 2003-12-17 | 2005-03-03 | Emil Müller GmbH | Water soluble salt core prepared by compressing a mixture of water soluble salts and a binder under pressure and heating useful in casting operations |
| US7013948B1 (en) | 2004-12-01 | 2006-03-21 | Brunswick Corporation | Disintegrative core for use in die casting of metallic components |
| JP4485343B2 (en) * | 2004-12-24 | 2010-06-23 | トヨタ自動車株式会社 | Method and apparatus for forming water-soluble core |
| US20060243421A1 (en) * | 2005-04-29 | 2006-11-02 | United States Of America, Represented By Secretary Of The U.S. Army | Soluble casting core for metal matrix composite components and method of producing thereof |
| KR100683969B1 (en) * | 2005-07-08 | 2007-02-16 | 김희수 | Methods for manufacturing water soluble core by liquid phase sintering |
| JP4792556B2 (en) * | 2005-11-28 | 2011-10-12 | 富山県 | Casting core manufacturing apparatus and manufacturing method thereof |
| KR101240436B1 (en) | 2006-05-19 | 2013-03-08 | 현대자동차주식회사 | Sand type core manufacturing method for high pressure casting |
| DE102006031532B3 (en) * | 2006-07-07 | 2008-04-17 | Emil Müller GmbH | Water-soluble salt core with functional component |
| US8128478B2 (en) | 2008-11-10 | 2012-03-06 | Igt | Gaming system, gaming device, and method for providing a game having a first evaluation based on drawn symbols and a second evaluation based on an order in which the symbols are drawn |
| US8245757B2 (en) * | 2009-02-02 | 2012-08-21 | Stratasys, Inc. | Inorganic ionic support materials for digital manufacturing systems |
| KR101143614B1 (en) * | 2009-08-18 | 2012-05-09 | 주식회사 스피자 | Producing method for bike's parts |
| DE102010051356B4 (en) * | 2010-11-13 | 2019-02-21 | Volkswagen Ag | Method for producing an insert for the creation of a cavity in a cast component and insert |
| JP5737016B2 (en) * | 2011-07-06 | 2015-06-17 | スズキ株式会社 | Disintegrating core and method for producing the same |
| US8430737B2 (en) | 2011-07-21 | 2013-04-30 | Igt | Gaming system and method providing multi-dimensional symbol wagering game |
| US8357041B1 (en) | 2011-07-21 | 2013-01-22 | Igt | Gaming system and method for providing a multi-dimensional cascading symbols game with player selection of symbols |
| US8485901B2 (en) | 2011-07-21 | 2013-07-16 | Igt | Gaming system and method for providing a multi-dimensional symbol wagering game with rotating symbols |
| EP2586546A1 (en) * | 2011-10-31 | 2013-05-01 | Bühler AG | Method for preparing salt cores |
| JP5798008B2 (en) * | 2011-11-09 | 2015-10-21 | 国立大学法人東北大学 | Manufacturing method of salt core for casting |
| DE102012204480A1 (en) * | 2012-03-21 | 2013-09-26 | Mahle International Gmbh | Process for the preparation of a cooled ring carrier |
| EP2647451A1 (en) | 2012-04-04 | 2013-10-09 | Bühler AG | Method for manufacturing salt cores |
| DE102012022631B3 (en) * | 2012-11-20 | 2014-04-03 | Audi Ag | Method for preparing salt core for formation of cavities with light metal pressure casting, involves closing press tools to carry out pressing operation of salt under destruction of envelope for compressing into cavity |
| EA201690160A1 (en) * | 2013-08-01 | 2016-12-30 | Ими Тами Инститьют Фо Рисерч Энд Дивелопмент Лтд. | WATER-SOLUBLE BASE FOR CONNECTIONS OF PIPES AND METHODS OF ITS MANUFACTURE AND USE |
| US9649687B2 (en) * | 2014-06-20 | 2017-05-16 | United Technologies Corporation | Method including fiber reinforced casting article |
| DE102015209762A1 (en) * | 2015-05-28 | 2016-12-01 | Bayerische Motoren Werke Aktiengesellschaft | Method for producing SMC hollow components |
| CN106670376B (en) * | 2016-12-20 | 2019-11-12 | 华中科技大学 | Low-melting alloy casting high-strength composite salt core material, salt core and preparation method |
| CN107971461A (en) * | 2017-11-02 | 2018-05-01 | 深圳市爱能森科技有限公司 | A kind of soluble core based on monomer fused salt and preparation method and application |
| CN107774883A (en) * | 2017-11-02 | 2018-03-09 | 深圳市爱能森科技有限公司 | A kind of soluble core based on polynary molten salt system and preparation method and application |
| CN107838365A (en) * | 2017-11-02 | 2018-03-27 | 深圳市爱能森科技有限公司 | A kind of soluble core based on Binary Salts System and preparation method and application |
| CN107931533A (en) * | 2017-11-02 | 2018-04-20 | 深圳市爱能森科技有限公司 | A kind of soluble core based on fused salt and preparation method and application |
| KR20190066236A (en) | 2017-12-05 | 2019-06-13 | 현대자동차주식회사 | A salt core |
| CN108907077B (en) * | 2018-09-27 | 2020-04-24 | 安徽工业大学 | Device for preparing salt-coated film sand |
| US11724306B1 (en) | 2020-06-26 | 2023-08-15 | Triad National Security, Llc | Coating composition embodiments for use in investment casting methods |
| KR102576599B1 (en) * | 2022-03-03 | 2023-09-08 | 김준수 | Manufacturing of soluble core for high pressure casting and method using the same |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4904423A (en) * | 1983-03-28 | 1990-02-27 | Park Chemical Company | Pressure molding process using salt cores and composition for making cores |
| US4556096A (en) * | 1985-01-14 | 1985-12-03 | Director-General Of The Agency Of Industrial Science And Technology | Method for the preparation of a spongy metallic body |
| US4840219A (en) * | 1988-03-28 | 1989-06-20 | Foreman Robert W | Mixture and method for preparing casting cores and cores prepared thereby |
| JPH04202608A (en) * | 1990-11-30 | 1992-07-23 | Mitsubishi Materials Corp | Manufacture of noble metal porous body |
| JPH05237596A (en) * | 1992-02-25 | 1993-09-17 | Ube Ind Ltd | Production of sand core |
| JP2929582B2 (en) * | 1992-03-24 | 1999-08-03 | 宇部興産株式会社 | Method for producing collapsible sand core |
-
1999
- 1999-07-06 KR KR1019990027082A patent/KR20000006623A/en active Search and Examination
-
2000
- 2000-07-04 CN CNB008098239A patent/CN1208149C/en not_active Expired - Fee Related
- 2000-07-04 WO PCT/KR2000/000714 patent/WO2001002112A1/en active IP Right Grant
- 2000-07-04 JP JP2001507592A patent/JP3757165B2/en not_active Expired - Fee Related
- 2000-07-04 AU AU55784/00A patent/AU5578400A/en not_active Abandoned
- 2000-07-04 KR KR10-2001-7016476A patent/KR100524642B1/en not_active IP Right Cessation
- 2000-07-04 US US10/019,772 patent/US6755238B1/en not_active Expired - Fee Related
- 2000-07-04 DE DE10084785T patent/DE10084785T1/en not_active Ceased
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314498C (en) * | 2005-09-12 | 2007-05-09 | 华南理工大学 | Soluble salt core for extrusion casting and its making process |
| CN101501177B (en) * | 2006-06-30 | 2012-09-19 | Posco公司 | Molten salts for the refining of MG alloys |
| CN1994615B (en) * | 2006-12-11 | 2010-12-01 | 东风汽车有限公司 | Salt core of engine piston |
| CN101391280B (en) * | 2007-09-18 | 2011-02-09 | 山东滨州渤海活塞股份有限公司 | Special-shaped salt core for press casting |
| CN103889615B (en) * | 2011-10-19 | 2016-06-15 | 铃木株式会社 | Casting core, its manufacture method and use the casting method of these core Footwall drift mo(u)lding goods |
| CN103889615A (en) * | 2011-10-19 | 2014-06-25 | 铃木株式会社 | Casting core, method for producing same, and method for casting using said core |
| CN104703725A (en) * | 2012-10-01 | 2015-06-10 | 马勒国际有限公司 | Method for the production of salt cores for producing workpieces by casting |
| CN104703725B (en) * | 2012-10-01 | 2017-06-09 | 马勒国际有限公司 | By method of the manufacture for manufacturing the salt core of workpiece of casting |
| CN103639366A (en) * | 2013-09-19 | 2014-03-19 | 沈阳工业大学 | Preparation method for U-shaped hole in casting |
| CN104128556B (en) * | 2014-05-24 | 2016-04-13 | 芜湖浙鑫新能源有限公司 | The ceramic core that a kind of inorganic easy depoling is defeated and dispersed |
| CN105171988A (en) * | 2015-06-25 | 2015-12-23 | 贵州航天精工制造有限公司 | Aviation buffer rubber gasket and production method thereof |
| CN108237205A (en) * | 2016-12-23 | 2018-07-03 | 现代自动车株式会社 | The salt core and its manufacturing method of die casting are carried out with aluminium |
| CN108237205B (en) * | 2016-12-23 | 2021-04-09 | 现代自动车株式会社 | Salt core die-cast with aluminum and method for manufacturing same |
| WO2019085124A1 (en) * | 2017-11-02 | 2019-05-09 | 深圳市爱能森科技有限公司 | Ternary molten salt system-based soluble core, preparation method therefor and application |
| CN108213395A (en) * | 2017-12-26 | 2018-06-29 | 吴立兵 | Demould casting method |
| CN108237206A (en) * | 2018-02-28 | 2018-07-03 | 厦门格欧博新材料科技有限公司 | A kind of salt core former |
| CN108838339A (en) * | 2018-08-03 | 2018-11-20 | 襄阳美利信科技有限责任公司 | A kind of method of salt core die casting |
| CN110586849A (en) * | 2019-09-26 | 2019-12-20 | 宁波新天阳新材料科技有限公司 | Resin precoated sand easy to collapse |
| CN114833971A (en) * | 2022-04-19 | 2022-08-02 | 西北橡胶塑料研究设计院有限公司 | Method for forming joint of hollow surface composite fabric sealing element |
Also Published As
| Publication number | Publication date |
|---|---|
| DE10084785T1 (en) | 2002-08-29 |
| WO2001002112A1 (en) | 2001-01-11 |
| KR100524642B1 (en) | 2005-10-28 |
| CN1208149C (en) | 2005-06-29 |
| AU5578400A (en) | 2001-01-22 |
| JP2003503210A (en) | 2003-01-28 |
| KR20020040680A (en) | 2002-05-30 |
| US6755238B1 (en) | 2004-06-29 |
| JP3757165B2 (en) | 2006-03-22 |
| KR20000006623A (en) | 2000-02-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1208149C (en) | Disintegrative core for high pressure casting, method for manufacturing the same and method for extracting the same | |
| CN1921969A (en) | Process for producing cast item | |
| CN101080298A (en) | Highly insulating and fireproof coating material for casting moulds | |
| CN106238699A (en) | The enhancing of shaped in situ is used to make aluminum or magnesium base composite material engine cylinder-body or the method for other parts mutually by extrusion casint or Semi-Solid Metals Forming with after-baking | |
| CN101073819A (en) | Soluble salt element for high-pressure casting | |
| CN104399865B (en) | A kind of water-soluble graphite complex salt core material, graphite complex salt core and preparation method thereof | |
| CN1277319A (en) | Air cylinder body and its metal base composite prefabricate element | |
| CN1305601C (en) | Sleeve, manufacturing method thereof and mixture for the production of said sleeve | |
| CN102416462A (en) | Method for preparing locally-enhanced metal-based composite material | |
| CN100337775C (en) | Method for producing large-sized blank of wrought magnesium alloys | |
| CN1710227A (en) | Method for manufacturing lock shaft parts for container | |
| US4573519A (en) | Method for forming metal base composite | |
| CN101942596B (en) | Method for preparing particle reinforced magnesium alloy composite material by using semisolid vacuum hot pressing | |
| CN1599651A (en) | Method for producing castings, molding sand and its use for carrying out said method | |
| KR100400132B1 (en) | A method for manufacturing a dissolution type core for a casting, a core and a method for extracting the core | |
| CN1603030A (en) | Pseudo semisolid thixotropy forming method for high-melting-point alloy | |
| KR100400133B1 (en) | A method for manufacturing a falling off casting sands core for a casting, a core and a method for extracturing the core | |
| KR100893960B1 (en) | Method for producing a light-alloy bearing bush with a rough external surface | |
| WO2023167342A1 (en) | Soluble core for high-pressure casting and manufacturing method thereof | |
| CN1718324A (en) | Self straggle fast casting method used for battlefield emergency fast shaping of armoured car component part | |
| WO2023136101A1 (en) | Method for manufacturing metal matrix composite material | |
| JP7035549B2 (en) | Complex molding method | |
| WO2024004771A1 (en) | Production method for heat dissipation component using soluble chemical salt for filling pipe, and heat dissipation component produced by same | |
| KR100580027B1 (en) | Method for manufacturing aluminium brake disc | |
| JP2004225145A (en) | Method for manufacturing ceramic-metal matrix composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050629 |