CN1355098A - Corrosion-resistance compound steel plate and its manufacture method - Google Patents
Corrosion-resistance compound steel plate and its manufacture method Download PDFInfo
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- CN1355098A CN1355098A CN01118865A CN01118865A CN1355098A CN 1355098 A CN1355098 A CN 1355098A CN 01118865 A CN01118865 A CN 01118865A CN 01118865 A CN01118865 A CN 01118865A CN 1355098 A CN1355098 A CN 1355098A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K11/00—Resistance welding; Severing by resistance heating
- B23K11/06—Resistance welding; Severing by resistance heating using roller electrodes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K11/00—Resistance welding; Severing by resistance heating
- B23K11/16—Resistance welding; Severing by resistance heating taking account of the properties of the material to be welded
- B23K11/20—Resistance welding; Severing by resistance heating taking account of the properties of the material to be welded of different metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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Abstract
Disclosed are a corrosion-resistant clad steel plate and its manufacturing method. The corrosion-resistant clad steel plate can be manufactured by tack-welding a thin strip of Fe-based amorphous alloy as a binder onto one side or both sides of a carbon steel plate and seam-welding a corrosion-resistant metal plate such as an alloy of nickel or titanium onto the binder to produce a corrosion-resistant clad steel plate; or alternatively, produced by tack-welding a thin strip of Fe-based amorphous alloy as a first binder onto one side or both sides of a carbon steel plate, tack-welding a thin strip of an alloy of nickel or stainless steel and copper as a second binder onto the thin strip and seam-welding a corrosion-resistant metal plate such as an alloy of nickel or titanium onto the binder.
Description
The present invention relates to corrosion-resistance compound steel plate, particularly between different metal, have the corrosion-resistance compound steel plate and the manufacture method thereof of good mechanical engaging force.
Compare with common metal, corrosion resistant metal is not easy welding and costs an arm and a leg therefore often use in industry as titanium (Ti), zirconium (Zr), tantalum (Ta), niobium (Nb) and nickel alloy.Yet, this have corrosion resistance, metal lightweight, that intensity is good can be used for various field, but be only limited in their applied scopes.In the field of the good resistant material of needs (as chemical plant, environmental protection facility etc.), join resistant material on the not expensive carbon steel sheet clad steel plate, because therefore their economic advantages, easy to use and various effectiveness are widely used.Adopt a lot of methods to make the different composite steel plate.For example, the hot rolling method is fit to the roll compacting clad steel plate, and the explosive welding (EW) connection is suitable for the explosive welding clad steel plate.In addition, electric-resistance seam-welding also is used to make clad steel plate.
In the technology of preparing with hot rolling manufactured roll compacting clad steel plate, the corrosion resisting alloy layer that has excellent corrosion resistance is heated simultaneously, then by a roll hot rolling at high temperature.Wherein, this alloy-layer is included on the carbon steel sheet nickel alloy or nickel-copper alloy or the titanium alloy as base material.From the angle of manufacturing cost, it is not a kind of favourable technology.
Compare with form the roll compacting composite plate by hot rolling, form the technology of clad steel plate owing to used the explosion energy of explosive, therefore have the engaging force higher than roll compacting by explosion welding method.Yet the shortcoming of this technology is: have more expensive manufacturing cost; Preparation time that need be longer than roll compacting; And limited the size of clad steel plate; And explosive is that danger has been brought in the workplace.
In order to solve the above-mentioned problem economically and simply, proposed to use electric-resistance seam-welding to make the method for clad steel plate.In the method, according to the principle of James Joule invention, when big electric current passed through metal, the heat that utilizes resistance to produce came weld metal.Proposed to utilize this electric-resistance seam-welding to engage the trial of different metal.For example, copper alloy and stainless band or net are embedded into as conjugant in the steel plate or titanium steel plate of clad steel plate and corrosion-resistant nickel alloy, then by the seam weldering.
Thereby, the purpose of this invention is to provide a kind of composite plate and manufacture method thereof for what address the above problem, resistant material that it had and carbon steel are not only not expensive, and have good engaging force between different metal.
By detailed description, can more be expressly understood above and other objects of the present invention, characteristics and other advantage below in conjunction with accompanying drawing.In the accompanying drawing:
Fig. 1 is the schematic diagram of corrosion-resistant clad plate of the present invention, and this composite plate is had the resistance welding machine welding of two annular electrodes.
Fig. 2 is the section three-dimensional map of composite plate of the present invention.
According to the present invention, above-mentioned purpose can be realized by following steps: the thin band of Fe-based amorphous alloy is welded (tack-welding) to the one or both sides of carbon steel sheet as conjugant tack, and the plate such as the corrosion resistant metal such as nickel or titanium alloy is seam welded on the conjugant, to produce corrosion-resistance compound steel plate.
Alternatively, also can produce corrosion-resistance compound steel plate by following steps: the one or both sides that the thin band of Fe-based amorphous alloy are welded to carbon steel sheet as the first conjugant tack, the thin band of nickel or stainless steel and copper alloy is welded on the thin band as the second conjugant tack, and the plate such as the corrosion resistant metal such as nickel or titanium alloy is seam welded on the conjugant.
The thin band of Fe-based amorphous alloy is used as the conjugant in the intermediate layer between resistant material and the base metal (being generally carbon steel).Therefore, utilize the characteristic of non-crystaline amorphous metal can make clad steel plate simultaneously with different metal bond to together with good adhesiveness.
The reason of Fe-based amorphous alloy as first conjugant is Fe-based amorphous alloy lacks in the sliding system of finding usually in structure crystal, but owing to atomic arrangement has at random kept free volume.It has high strength and high ductibility, and shows high resistance so that produce seam weldering (a kind of electric resistance welding) required high heat, thereby brings good engaging force.
Usually, the iron-based amorphous thin band has high resistance and has better ductility and flowability than common metal, thereby when carrying out electric-resistance seam-welding, it can not rely on the shape on the shape of material or their surfaces and engages.And, because Fe-based amorphous band unstable but crystallization when approximately 300-500 spends under typical temperature, therefore when stitching weldering under about 1000 degree or higher temperature, its welding portion has formed rock-steady structure, thereby has formed the composite plate with high bonding force and mechanical strength.
Alternatively, in order to obtain to have the clad steel plate of better engaging force and mechanical strength, having high-intensity second conjugant (comprising nickel or stainless steel) can be laminated on first conjugant simultaneously, is welded to make clad steel plate by seam then.This clad steel plate comprises having high-intensity different metal.
Referring to Fig. 1, clad steel plate of the present invention is following manufacturing: thin nickel band 3 is approached on the band 2 as the amorphous fe-base that second conjugant is laminated to as first conjugant, this lamination is placed between corrosion resistant metal plate 4 and the base metal 1, utilize annular electrode 5 to stitch weldering then.Method of the present invention is compared with conventional method has higher engaging force.Only the thin band to nickel alloy stitches weldering in conventional method, or before stitching weldering wire netting, copper mesh, stainless (steel) wire or analog is laminated on the thin band of nickel alloy.Therefore, the present invention can be according to the kind and the thickness of resistant material, conjugant and clad steel plate, pressing pressure, electric current and time cycle is carried out suitable control, to realize best seam weldering.
Referring now to Fig. 2,, wherein shows clad steel plate.This steel plate comprises corrosion resistant metal plate 4 or the base metal between corrosion resistant metal plate 41 that joins on the base metal 1.Wherein, the weld seam 6 of seam weldering appears on the surface of clad steel plate.
Except resistant materials such as titanium (Ti), zirconium (Zr), tantalum (Ta), niobium (Nb) and nickel are joined on the carbon steel, these resistant materials can also be engaged with stainless steel, copper, aluminium etc.In addition, other different materials that comprises nickel alloy and carbon steel, copper alloy and carbon steel etc. also can be engaged.
When using the iron-based amorphous thin band, we wish to bring the easy degree of raising welding by using other element outside the deironing (Fe) as the thin bar of boron (B) or silicon (Si), thereby improve bond strength.In addition, for engaging force and the mechanical strength that improves clad steel plate, can adopt a lot of first and second junction partner layer to stitch weldering, and can on conjugant, apply solder flux to improve welding effect.
The present invention may be better understood by following example.These examples only are used for explanation, and are not construed as limiting the invention.Example 1
Junction partner layer places between the thick titanium as resistant material of the thick carbon steel as base metal of 6mm (SS400) and 1.6mm.At 2kg/mm
2Downtime of electric resistance welding time and 5-10 hour of welding current, 5-10 hour of pressing pressure, 15000-40000A under, utilize resistance welding machine that they are bonded together, to obtain clad steel plate.The mechanical strength of the titanium clad steel plate by the inventive method and conventional method manufacturing is shown in following table 1.In table 1, find that product of the present invention has the shear strength higher than conventional products.
Table 1
Titanium clad steel plate mechanical strength relatively | ||||||
Manufacture method | Corrosion resistant metal | Conjugant 1 | Conjugant 2 | Shear strength (Kg/mm 2) | Hot strength (Kg/mm 2) | Yield strength (Kg/mm 2) |
Electric-resistance seam-welding (the present invention) | ?Ti-Gr.2 | The amorphous iron band | The nickel band | ????20.5 | ????47.5 | ????35.6 |
?Ti-Gr.2 | The amorphous iron band | The stainless steel band | ????19 | ????47 | ????35 | |
?Ti-Gr.2 | The amorphous iron band | ???- | ????17.8 | ????46.2 | ????33 | |
Electric-resistance seam-welding (routine) | ?Ti-Gr2 | Copper mesh | The nickel band | ????15.2 | ????45 | ????30 |
?Ti-Gr2 | The iron net | The nickel band | ????15.2 | ????45 | ????30 | |
?Ti-Gr2 | Stainless (steel) wire | The nickel band | ????16 | ????47 | ????32 | |
Roll compacting engages | ?Ti-Gr2 | - | ???- | ????14.8 | ????45 | ????- |
Explosive welding | ?Ti-Gr2 | - | ???- | ????15 | ????45 | ????- |
International standard JIS 0601 | ?Ti-Gr2 ?+SS400 | - | ???- | ????≥13.98 | ????≥39.18 | ????- |
Electric-resistance seam-welding (the present invention) | ?Ti-Gr.1 | The amorphous iron band | The nickel band | ????18.4 | ????40.0 | ????30.5 |
?Ti-Gr.1 | The amorphous iron band | The stainless steel band | ????17.5 | ????41.0 | ????30.8 | |
Electric-resistance seam-welding (routine) | ?Ti-Gr.1 | Copper mesh | The nickel band | ????14 | ????39 | ????27.3 |
?Ti-Gr.1 | The iron net | The nickel band | ????14 | ????39 | ????27 | |
?Ti-Gr.1 | Stainless (steel) wire | The nickel band | ????16 | ????40 | ????28 | |
Roll compacting engages | ?Ti-Gr.1 | - | ???- | ????14.5 | ????40 | ????- |
*Base metal SS400,6mm is thick/titanium, the thick example 2 of 1.6mm
Make clad steel plate by method of the present invention and conventional method, and measure their mechanical strength.Wherein use nickel and nickel alloy as resistant material.From the result of table 2, as can be seen, only use the weld strength height of the conventional steel plate of nickel band by the steel plate ratio of the inventive method manufacturing.
Table 2
The mechanical strength of nickel and nickel alloy clad steel plate relatively | ||||||
Manufacture method | Corrosion resistant metal | Conjugant 1 | Conjugant 2 | Shear strength (Kg/mm 2) | Hot strength (Kg/mm 2) | Yield strength (Kg/mm 2) |
Electric-resistance seam-welding (the present invention) | ??Ni200 | Amorphous nickel band | The nickel band | ????30 | ????54 | ????33 |
??Ni400 | Amorphous nickel band | The stainless steel band | ????30 | ????51 | ????33 | |
??C_276 | Amorphous nickel band | The nickel band | ????36 | ????58 | ????38.7 | |
??Ni200 | Amorphous nickel band | ???- | ????28.5 | ????52.2 | ????30.3 | |
??Ni400 | Amorphous nickel band | ???- | ????28.5 | ????49.7 | ????30.3 | |
??C_276 | Amorphous nickel band | ???- | ????33.7 | ????57.3 | ????36 | |
Electric-resistance seam-welding (routine) | ??Ni200 | ?- | The nickel band | ????25.5 | ????51 | ????28.9 |
??Ni400 | ?- | The stainless steel band | ????26 | ????50 | ????30 | |
??C_276 | ?- | The nickel band | ????30 | ????54 | ????35.7 | |
International standard ASTM A265 | ????≥14.06 | ????≥49.21 | ????≥8.12 |
*Base metal SS400,6mm is thick/corrosion resistant metal, the thick example 3 of 1.6mm
Make clad steel plate and measure their mechanical strength by method of the present invention and conventional method.Wherein use zirconium, tantalum, niobium as resistant material, it the results are shown in table 3.As can be seen from Table 3, the intensity of this clad steel plate is similar to the intensity of titanium clad steel plate.Therefore, method of the present invention can engage these corrosion resistant metals effectively.
Table 3
The mechanical strength of zirconium, tantalum, niobium clad steel plate relatively | ||||||
Manufacture method | Corrosion resistant metal | Conjugant 1 | Conjugant 2 | Shear strength (Kg/mm 2) | Hot strength (Kg/mm 2) | Yield strength (Kg/mm 2) |
Electric-resistance seam-welding (the present invention) | ????Zr702 | The amorphous iron band | The nickel band | ????20.2 | ????47.1 | ????31.2 |
????Ta | The amorphous iron band | The nickel band | ????12.4 | ????40 | ????35 | |
????Nb | The amorphous iron band | The nickel band | ????12.4 | ????40 | ????35 | |
????Zr702 | The amorphous iron band | ???- | ????18.0 | ????45.2 | ????27.8 | |
????Ta | The amorphous iron band | ???- | ????10.6 | ????38.1 | ????31.6 | |
????Nb | The amorphous iron band | ???- | ????10.6 | ????38.1 | ????31.6 | |
Electric-resistance seam-welding (routine) | ????Zr702 | Copper mesh | The nickel band | ????15.2 | ????45 | ????30 |
????Ta | Copper mesh | The nickel band | ????10.5 | ????35 | ????30 | |
????Nb | Copper mesh | The nickel band | ????11 | ????34 | ????30 |
*Base metal SS400,6mm is thick/corrosion resistant metal, 1.0mm is thick
Shown in top example, the clad steel plate with the inventive method manufacturing is better than conventional clad steel plate as can be seen, and has the directly related good shear strength of the power of engaging.
Clad steel plate of the present invention with good engagement characteristics and intensity can be produced in enormous quantities, and the substitute products of the resistant material of the conventional costliness of conduct.In addition, use has high-intensity clad steel plate in the workplace, and the life expectancy that not only can prolong corrosion resistant apparatus can also reduce the material consumption of following in the equipment preparation process.Therefore, clad steel plate of the present invention has the economic advantages bigger than conventional steel plate, and is applicable to different fields.
Adopted the mode of example to disclose the present invention.Should be appreciated that employed term is used for illustrating and being not used in restriction.Can much revise and conversion the present invention according to above-mentioned instruction.Therefore it should be understood that and in the scope of appended claims, to implement the present invention, and be not limited to above specifying.
Claims (11)
1. a method of making corrosion-resistance compound steel plate is characterized in that, the thin band of Fe-based amorphous alloy is welded to the one or both sides of carbon steel sheet as the first conjugant tack, then the corrosion resistant metal plate is seam welded on the conjugant.
2. the method for claim 1 is characterized in that, Ni-based thin band is welded on the thin band as the Fe-based amorphous alloy of first conjugant as the second conjugant tack.
3. method as claimed in claim 2 is characterized in that, second conjugant is the thin band of stainless steel or copper alloy.
4. method as claimed in claim 1 or 2 is characterized in that, the corrosion resistant metal plate is selected from following group: titanium, zirconium, tantalum, niobium, nickel, copper and their alloy.
5. method as claimed in claim 1 or 2 is characterized in that, applies solder flux on first conjugant and second conjugant.
6. method as claimed in claim 2 is characterized in that, a lot of first and second junction partner layer are alternately stacked together.
7. clad steel plate, it comprises the corrosion resistant metal plate that joins the carbon steel sheet one or both sides to, it is characterized in that, as first conjugant between carbon steel sheet and the corrosion resistant metal plate, the thin band of Fe-based amorphous alloy is soldered.
8. clad steel plate as claimed in claim 7 is characterized in that, Ni-based thin band further is welded on the thin band as the Fe-based amorphous alloy of first conjugant as second conjugant.
9. clad steel plate as claimed in claim 8 is characterized in that, second conjugant is the thin band of stainless steel or copper alloy.
10. as claim 7 or 8 described clad steel plates, it is characterized in that the corrosion resistant metal plate is selected from following group: titanium, zirconium, tantalum, niobium, nickel, copper and their alloy.
11. clad steel plate as claimed in claim 8 is characterized in that, a lot of first and second junction partner layer are alternately stacked together.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020000071864A KR100365646B1 (en) | 2000-11-30 | 2000-11-30 | Corrosion resistance clad metal plate and method for manufacturing thereof |
KR71864/2000 | 2000-11-30 |
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CN1355098A true CN1355098A (en) | 2002-06-26 |
CN1209241C CN1209241C (en) | 2005-07-06 |
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CNB011188650A Expired - Fee Related CN1209241C (en) | 2000-11-30 | 2001-06-26 | Corrosion-resistance compound steel plate and its manufacture method |
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JP (1) | JP2002239741A (en) |
KR (1) | KR100365646B1 (en) |
CN (1) | CN1209241C (en) |
TW (1) | TW494039B (en) |
Cited By (9)
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CN102059463A (en) * | 2010-12-06 | 2011-05-18 | 四川飞龙电子材料有限公司 | Layered metal continuous composite seam welding method |
CN102500900A (en) * | 2011-11-22 | 2012-06-20 | 西安优耐特容器制造有限公司 | Preparation method for dissimilar metal plate loose lining |
CN104139234A (en) * | 2014-08-04 | 2014-11-12 | 东莞台一盈拓科技股份有限公司 | Resistance welding method for amorphous alloy |
CN105033662A (en) * | 2015-06-12 | 2015-11-11 | 江苏塞维斯数控科技有限公司 | Stand column of numerical control engraving and milling machine |
CN105033661A (en) * | 2015-06-12 | 2015-11-11 | 江苏塞维斯数控科技有限公司 | CNC (Computer Numerical Control) engraving and milling machine base |
CN105033663A (en) * | 2015-06-12 | 2015-11-11 | 江苏塞维斯数控科技有限公司 | Working table of numerical-control engraving and milling machine |
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CN107538860A (en) * | 2017-09-29 | 2018-01-05 | 江苏天时新材料科技有限公司 | A kind of corrosion resistant metal plate |
CN109693075A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | High-performance double-faced titanium steel composite plate with IF steel as transition layer and preparation method thereof |
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KR100411273B1 (en) * | 1999-09-28 | 2003-12-18 | 주식회사 포스코 | A method for cladding Stainless steel and Titanium |
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-
2000
- 2000-11-30 KR KR1020000071864A patent/KR100365646B1/en active IP Right Grant
-
2001
- 2001-01-30 TW TW090101853A patent/TW494039B/en not_active IP Right Cessation
- 2001-06-26 CN CNB011188650A patent/CN1209241C/en not_active Expired - Fee Related
- 2001-11-29 JP JP2001363702A patent/JP2002239741A/en active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102059463A (en) * | 2010-12-06 | 2011-05-18 | 四川飞龙电子材料有限公司 | Layered metal continuous composite seam welding method |
CN102500900A (en) * | 2011-11-22 | 2012-06-20 | 西安优耐特容器制造有限公司 | Preparation method for dissimilar metal plate loose lining |
CN104139234A (en) * | 2014-08-04 | 2014-11-12 | 东莞台一盈拓科技股份有限公司 | Resistance welding method for amorphous alloy |
CN105033662A (en) * | 2015-06-12 | 2015-11-11 | 江苏塞维斯数控科技有限公司 | Stand column of numerical control engraving and milling machine |
CN105033661A (en) * | 2015-06-12 | 2015-11-11 | 江苏塞维斯数控科技有限公司 | CNC (Computer Numerical Control) engraving and milling machine base |
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CN106694600A (en) * | 2015-11-17 | 2017-05-24 | 鞍钢股份有限公司 | Production method of stainless steel ultra-thick composite board |
CN106694600B (en) * | 2015-11-17 | 2018-06-26 | 鞍钢股份有限公司 | Production method of stainless steel ultra-thick composite board |
CN107538860A (en) * | 2017-09-29 | 2018-01-05 | 江苏天时新材料科技有限公司 | A kind of corrosion resistant metal plate |
CN109693075A (en) * | 2017-10-20 | 2019-04-30 | 鞍钢股份有限公司 | High-performance double-faced titanium steel composite plate with IF steel as transition layer and preparation method thereof |
Also Published As
Publication number | Publication date |
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KR20020042108A (en) | 2002-06-05 |
JP2002239741A (en) | 2002-08-28 |
CN1209241C (en) | 2005-07-06 |
KR100365646B1 (en) | 2002-12-26 |
TW494039B (en) | 2002-07-11 |
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