CN1337224A - Cosmetic cleaning composition - Google Patents

Cosmetic cleaning composition Download PDF

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Publication number
CN1337224A
CN1337224A CN01124836A CN01124836A CN1337224A CN 1337224 A CN1337224 A CN 1337224A CN 01124836 A CN01124836 A CN 01124836A CN 01124836 A CN01124836 A CN 01124836A CN 1337224 A CN1337224 A CN 1337224A
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L·塞比洛特－阿诺
V·吉尤
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LOreal SA
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LOreal SA
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212—Face masks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Medicinal Preparation (AREA)

Abstract

The invention provides a foaming cleansing product. This cleansing composition is obtained by including at least one foaming surfactant, at least one hydrophobic silica and at least one oxyalkylene compound in a physiologically acceptable aqueous medium. The hydrophobic silica and oxyalkylenated compounds, especially in the case of soap-containing foam products, is capable of being rinsed, thickened but keeping properties required for foaming products such as good miscibility with water, quick mobility into foam, good rinsing properties and good acceptability.

Description

Cosmetic cleaning composites
Technical field
The present invention relates to a kind of flushable frothing cleaning composition, it comprises at least a hydrophobic silica and at least a oxyalkylene chemical compound, with relate to the especially purposes in cosmetics of described compositions, as the cleaning product of skin, eyes, scalp and/or hair or the product of the make up product of removal and conduct processing oily skin and/or sterilization skin and/or scalp.
Background technology
In order to nurse face, cleaning skin is very important.This must be effective as far as possible, because butyrous residue such as too much sebum, remaining cosmetics used in everyday and some cosmetics can gather and can block the pore of skin in wrinkle of skin, the result causes speckle.
Thoroughly a kind of method of cleaning skin is to use frothing cleaning product.Present commercially available frothing cleaning product is bar, gel or the cream form of foaming, and they can contain or not contain soap (soap).The foamed products that contains soap has the cream-colored foamy advantage of generation; Yet some consumer finds that these products have and causes the defective of tightening that this is because their undue washing forces.For product is stood better, therefore seek to reduce the content of soap.Yet such product viscosity is not enough.
In addition, the foamed products that does not contain soap can be stood usually well.Yet they are the form or the relative gel of liquid of fluid product normally.For thickening does not contain the foamed products of soap, known in the practice to wherein adding thickening agent such as alkyl-or acyl group-oxygen ethylidene chemical compound, polysaccharide such as cellulose derivative, melon ear wood glue and its derivant, and acrylate copolymer.Yet,, need to add these a large amount of thickening agents for the viscosity that increases the foamed products that does not contain soap with in order to obtain a kind of condensed structure.Now; when alkyl-or the percentage composition of for example conventional PEG-120 methyl glucoside dioleate that uses of acyl group-oxygen ethylidene chemical compound such as oxygen ethylidene alkyl glucose ester or ceteareth-60 myristyl ethylene glycol when increasing; the chemical compound that obtains is on being administered to skin the time; can not uniform spreading; because it is sprawled with particulate, this makes consumer can not accept these compositionss.In addition, produce also difficulty of foam.In addition, can not ad infinitum increase the percentage composition of these thickening agents, because they no longer are dissolved in the medium like that.
In addition, when the percentage composition of cellulose gum, melon ear wood glue or acrylate copolymer increased, the foam that the product that obtains causes was medium, and it is difficult to rinse out usually, because film forming deposit makes skin that the sensation of cleaning difference be arranged.
Therefore, also need flushable and condensed frothing cleaning product, but only will keep the required character of foamed products, promptly with water fine mixing of energy, be quickly converted to foam, good washability and good tolerance, particularly to the situation of the foamed products that contains soap.
Summary of the invention
The applicant finds surprisingly, hydrophobic silica and oxyalkylene (oxygen ethylideneization and/or oxygen propylideneization) combination of compounds, can obtain foamed products in they own wt current downflow, they have suitable denseness comparatively speaking simultaneously, and its viscosity is similar to milk or condensed foamable gel in other words.These products are butyrous and cosmetics.
Admittedly, known in practice the cleaning or composition of detergent in use silicon dioxide.Therefore, for example, the US-A-5880076 document discloses a kind of liquid detergent composition, and it can contain silicon dioxide.EP-A-550281 and US-A-5389279 document have been mentioned a kind of silicon dioxide of powder type, and it can be impregnated in the Cleasing compositions.Yet, in the foamed products that does not contain soap, using separately silicon dioxide, it can not and obtain required rheology by thickening fully, and does not have document openly to be used for the thickening foamed products with hydrophobic silica and oxyalkylene combination of compounds.
Therefore, a theme of the present invention is a kind of Cleasing compositions, it comprises, in physiologically acceptable water-bearing media, the gross weight of relative compositions, this medium comprises the water of at least 35% weight, (1) at least a foaming surfactant, (2) at least a hydrophobic silica and (3) at least a oxyalkylene chemical compound.
It is the medium compatible with skin, mucosa, scalp, eyes and/or hair that term " physiologically acceptable medium " here looks like.In addition, it is aqueous medium, i.e. relative composition total weight comprises the medium of the water yield at least 35% weight, and the preferred water weight range is a 35%-95% weight, is more preferably 40%-90% weight.
The present composition is foaming and flushable Cleasing compositions.They are gels, under himself weight, can flow, rather than fluid, in other words, range of viscosities can be at, 70-200 pool (7-20Pa.s) for example, a kind of gel of preferred 90-150 pool (9-15Pa.s), this viscosity is under 25 ℃, uses the Rheomat180 measuring device with 180-200s -1Measure, this machine is equipped with different rotating shafts, and this depends on viscosity, and for example No. 2 rotating shafts are used for range of viscosities and are lower than 7 pools, and No. 3 rotating shafts are used for range of viscosities 2-40 pool, and No. 4 rotating shafts are used for range of viscosities greater than 20 pools.
Hydrophobic silica
In this application, term " hydrophobic silica " meaning is pure hydrophobic silica and the granule that is coated with hydrophobic silica.
The content of hydrophobic silica in the present composition, no matter be pure silicon dioxide or the granule that is coated with hydrophobic silica, with respect to the gross weight of compositions, by the weight of active material, preferably at least 1%, its content range, with respect to the gross weight of compositions,, for example can be 1%-15% weight by the weight of active material, be more preferably 2%-10% weight, even be more preferably 2%-6% weight.
The product that can be used for the preferably amorphous and dry distilling source of hydrophobic silica in the present composition.They are powdery preferably.
The amorphous hydrophobic silica in dry distilling source is to be obtained by hydrophilic silicon dioxide.These hydrophilic silicon dioxides are by in the presence of hydrogen and oxygen, at 1000 ℃ of following continuous burning pyrolysis Silicon chloride. (SiCl 4) obtain.They are processed into hydrophobicity with halogenated silanes, alkoxy silane or silazane then.Hydrophobic silica is different from hydrophilic raw material silicon dioxide, more low-density silanol is especially arranged and water vapour is had less adsorptivity.
According to a kind of embodiment preferred of the present invention, hydrophobic silica is selected from that to have specific surface be 50-500m 2/ g, number average particle size is that 3-50nm and density are 40-200, is more preferably the silicon dioxide of 50-150g/l.More specifically, they are hydrophobic silica and its mixture that are described in the following table (1).
Table (1)
Trade name Aerosil R202 (from DegussaHuls) Aerosil R805 (from DegussaHuls) Aerosil R812 (from DegussaHuls) Aerosil R972 (from DegussaHuls) Aerosil R974 (from DegussaHuls)
BET surface (m 2/g) 90±20 150±25 260±30 110±20 170±20
Particle mean size (nm) 14 12 7 16 12
Density (g/l) About 50 About 50 About 50 About 50 About 50
PH in 4% water 4-6 3.5-5.5 5.5-7.5 3.6-.3 3.4-4.2
The hydrophobic silica that uses in the present composition also can be by granulometric composition, this granule is used silica-coating wholly or in part, particularly use the mineral grain of silica-coating wholly or in part, for example be coated with the pigment and the metal-oxide of hydrophobic silica.These granules also can have optical property in product He on the skin, for example their effects that can have a kind of extinction effect or brighten slightly.
By DegussaHuls company with title Aerosil R972 The hydrophobic silica of selling preferably is used as hydrophobic silica of the present invention.
The oxyalkylene chemical compound
The oxyalkylene chemical compound that can be used in the present composition can comprise ethylene oxide group (oxygen ethylidene chemical compound), propylene oxide group (oxygen propylidene chemical compound) or the two (oxygen ethylideneization/oxygen propylidene chemical compound).
Can use one or more oxyalkylene chemical compounds, the content of oxyalkylene chemical compound in the present composition, by the weight of active material, with respect to the gross weight of compositions, for example its scope is a 1%-20% weight, is more preferably 2%-10% weight.
The oxyalkylene chemical compound can be selected from; particularly Polyethylene Glycol, macrogol ester and/or polypropylene glycol ester; polyglycol ether and/or polypropylene glycol ether; the alkoxylate acyl derivative; ethoxylation acyl group polyol derivative particularly; the oxyalkylene of glycerol and fatty acid and particularly oxygen ethylideneization three esters are with ethyoxyl ethylidene urethane derivatives and its mixture of alkyl chain modification.
1. can be used for Polyethylene Glycol in the present composition and be ethylene oxide unit (EO) number greater than 10 oxirane condensation polymer.The scope of ethylene oxide number for example can be 10-50000, preferred 14-10000.The example of the Polyethylene Glycol that can mention comprises Polyethylene Glycol (the CTFA title: PEG-7M) that comprises 7000EO, for example by Amerchol company with title Polyox WSR N-750  product sold, Polyethylene Glycol (the CTFA title: PEG-75) that comprises 75EO, Polyethylene Glycol (the CTFA title: PEG-20M) that comprises 20000EO, for example by Amerchol company with title PolyoxWSR1105  product sold with comprise Polyethylene Glycol (the CTFA title: PEG-150) of 150EO.
2. macrogol ester and/or polypropylene glycol ester are the condensation substances of Polyethylene Glycol and/or polypropylene glycol and one or more fatty acids.They are chemical compounds of following formula:
RCOO-(EO) m-(PO) n-R ＇ is 0≤m≤300 wherein, with 0≤n≤300, and m+n 〉=6, R and R ' represent hydrogen independently of one another or contain 1-30 carbon atom, the hydroxylating of the saturated or unsaturated straight or branched of preferred 12-22 carbon atom or the alkyl chain of non-hydroxylated, or the aryl chain, condition is that R and R ' are not hydrogen simultaneously.
The Polyethylene Glycol acid esters that can mention and/or the example of polypropylene glycol acid esters comprise polyglycol distearate (150EO), for example by Uniqema company with title Atlas G-1821  product sold, PEG-150 two behenates, for example by Ethox company with title Ethox PEG6000 two behenate  product solds, Polyethylene Glycol Palmic acid stearate (120EO), for example by Gattefosse company with title Stearate6000WL1644  product sold, the copolymer of Polyethylene Glycol (30EO) and 12-hydroxy stearic acid, for example by Uniqema company with title Arlacel P135  product sold, and polyglycol distearate (40EO), for example by Uniqema company with title MYRJ52  product sold.
In the situation of R=R '=H, can mention, for example the copolymer (17EO/6PO) on the polyoxyethylene/polyoxypropylene statistics of selling with title UCON75-H-450  by AMERCHOL company.Outside molecule with more EO and/or more PO is not precluded within.
3. polyglycol ether and/or polypropylene glycol ether are the condensation substances of Polyethylene Glycol and/or polypropylene glycol and one or more aliphatic alcohol.They are chemical compounds of following formula:
R-(EO) m-(PO) n-R ＇ is 0≤m≤300 wherein, with 0≤n≤300, and m+n 〉=6, R and R ' represent hydrogen independently of one another or contain 1-30 carbon atom, the hydroxylating of the saturated or unsaturated straight or branched of preferred 12-22 carbon atom or the alkyl chain of non-hydroxylated, or the aryl chain, condition is that R and R ' are not hydrogen simultaneously.
The example of the polyglycol ether that can mention is oxygen ethylideneization (30EO) spermol particularly, for example by Nikkol company with title Nikkol BC-30TXt  product sold, oxygen ethylideneization (15EO) oleyl alcohol, for example by Nikkol company with title Nikkol BO-15TX  product sold, oxygen ethylideneization (50EO) oleyl alcohol, for example by Nikkol company with title Nikkol BO-50  product sold, oxygen ethylideneization (10EO) behenyl alcohol, for example by Nikkol company with title Mergital B10  product sold, oxygen ethylideneization (30EO) behenyl alcohol, for example by Nikkol company with title NikkolBB30  product sold, oxygen ethylideneization (12EO) lauryl alcohol, for example by Goldschmidt company with title Rewopal 12  product solds, oxygen ethylideneization (23EO) lauryl alcohol, for example by SEPPIC company with title Simulsol P23  product sold, oxygen ethylideneization (20EO) 2-octyl dodecanol, for example by Stearinerie Dubois company with title octyl dodecanol ether-20  product sold, the different spermol of oxygen ethylideneization (20EO), for example by Uniqema company with title Arlasolve200 US  product sold, oxygen ethylideneization (10EO) oleyl alcohol, for example by Uniqema company with title Brji97  product sold, oxygen ethylideneization (20EO) oleyl alcohol, for example by Uniqema company with title Brij98  product sold, oxygen ethylideneization (100EO) stearyl alcohol, for example by Uniqema company with title Brij700  product sold, with oxygen ethylideneization (21EO) stearyl alcohol, for example by Uniqema company with title Brij721  product sold.
The example of the polyethylene/polypropylene glycol ether that can mention is oxygen ethylideneization (5EO) oxygen propylideneization (5PO) lauryl alcohol particularly, for example by Cognis company with title Aethoxal B  product sold, oxygen propylideneization (3PO) myristyl alcohol, for example by Croda company with title Promyristyl PM-3  product sold, oxygen ethylideneization (20EO) oxygen propylideneization (5PO) spermol, for example by Croda company with title Procetyl AWS  product sold, oxygen ethylideneization (26EO) oxygen propylideneization (26PO) butanols, for example by Goldschmidt company with title PPG-26-Buteth-26  product sold, oxygen ethylideneization (26EO) oxygen propylideneization (26PO) butanols, for example by Goldschmidt company with title Varonic Apeb  product sold, oxygen ethylideneization (30EO) oxygen propylideneization (6PO) decyl tetradecanol, for example by Nikkol company with title Nikkol PEN-4630  product sold, with oxygen ethylideneization (25EO) oxygen propylideneization (25PO) lauryl alcohol, for example by Vevy company with title ADF-Oleile  product sold.
4. the ethoxylated alkyl of polyhydric alcohol or acyl derivative can be the polyhydric alcohol oxygen ethylidene derivant of the fatty acid ester of glycerol, Sorbitol, glucose or tetramethylolmethane or the polyhydric alcohol oxygen ethylidene derivants of the fatty alcohol ether of glycerol, Sorbitol, glucose or tetramethylolmethane for example for example for example.
This analog derivative that can mention, it for example is oxygen ethylideneization (78EO) glyceryl cocoate, for example by SEPPIC company with title Simulsol CG product sold, oxygen ethylideneization (120EO) methyl glucoside dioleate, for example by Amerchol company with title Glucamate DOE-120Vegetal  product sold, oxygen ethylideneization (40EO) seven oleic acid sorbitan esters, for example by Uniqema company with title Arlatone T  product sold, oxygen ethylideneization (10EO) polyoxyethylene lauryl acid glycerol (2 mole of glycerin) ester, for example by Clariant company with title HOES 3495  product solds, oxygen ethylideneization (60EO) glyceryl isostearate, for example by SACI-CFPA company with title Emalex GWIS-160  product sold, oxygen ethylideneization (20EO) glyceryl monostearate, for example by Cognis company with title Cutina E24  product sold, oxygen ethylideneization (200EO) tristerin, for example by SEPPIC company with title Simulsol 220TM  product sold, with oxygen ethylideneization (150EO) pentaerythritol tetrastearate, for example by Croda company with title Crothix  product sold.
5. the oxyalkylene triglyceride of the fatty acid that can mention for example is oxygen ethylideneization (6EO) caprylic/capric glyceride, for example by Condea company with title Softigen 767  product solds and oxygen ethylideneization (50EO) olive oil.For example by Croda company with title Crovol O-70  product sold.
6. the ethyoxyl ethylidene urethane derivatives with the alkyl chain modification that can mention for example is those of following formula: Residue R wherein 1, R 2And R 5Expression C 1-18Alkyl; R 3And R 6Expression is based on straight chain, ring-type or aromatics C 4-36The residue of hydrocarbon; R 4Expression hydrogen atom or C 1-6Alkyl, preferred hydrogen atom; A is the integer of 90-600 scope, and b is the integer of 1-4 scope.
For example, they are water-soluble polymers, are by vulcabond (HMDI: hexamethylene diisocyanate) with the additive reaction of glycol (polyethers, polyester), and use the hydrophobic group end-blocking that is obtained by ethoxylation or ethoxylated/propoxylated fatty alcohol to obtain.For example, the SERAD FX1100 that is sold by Adrise company is exactly this situation, and it is oxygen ethylideneization (100EO) stearyl alcohol/Polyethylene Glycol (136EO)/hexamethylene diisocyanate copolymer.
This base polymer that can mention, for example, comprise with title Acrysol 44 (or Aculyn44) and Acrysol 46 (or Aculyn 46) product sold (CTFA title: PEG-150/ decanol/SMDI copolymer), it is the poly-urethane that is obtained by hexamethylene diisocyanate and Polyethylene Glycol condensation, is loaded with methyl and octadecyl respectively in their end.These poly-urethanes also contain the starch matrix of 3%-5% enzymatically modify.They are by Rohm﹠amp; Haas company sells.They also are by the product sold Rheolate  of Elementis company 205,210,212,216,244,278,255,266,288,300 and 350 or by the product sold Borchigel LW.44 of Borchers company, L.75.N; L76; VP9628-LL36; VP97 105-NT40; VP9620.
Surfactant
Composition, foam of the present invention contains at least a surfactant that foam properties is provided to compositions.This surfactant can be selected from any nonionic, anion, both sexes or amphion foaming surfactant and its mixture.
The content range of surfactant for example, by the weight of active substance, with respect to the gross weight of compositions, is 2%-50% weight, is more preferably 3%-30% weight.
1. non-ionic surface active agent;
Spendable non-ionic surface active agent for example comprises alkyl polyglucoside (APGs), Fructus Hordei Germinatus sugar ester, bound to polyglycerol aliphatic alcohol, glycosamine derivant for example 2-ethyl hexyl oxy carbonyl-N-methyl-glycosamine and its mixture.
The preferred alkyl polyglucoside that uses is to contain to have 6-30 carbon atom, the alkyl of preferred 8-16 carbon atom with contain those of the hydrophobic group (glucoside) that preferably comprises 1.2-3 sugar unit.The alkyl polyglucoside that can mention for example comprises decyl glucoside (alkyl C9/C11-poly glucoside (1.4)), for example by Kao Chemicals company with title Mydol 10  product solds, by Henkel company with title Plantaren 2000UP  product sold and by SEPPIC company with title Oramix NS10  product sold; Decyl/octyl glucoside, for example by SEPPIC company with title Oramix CG110  product sold; The lauryl glucoside, for example by Henkel company with title Plantaren1200N  and Plantacare 1200  product solds; With the cocos nucifera oil glucoside, for example by Henkel company with title Plantacare 818/UP  product sold.
The maltose derivant for example is to be disclosed among the EP-A-566438 those, for example is disclosed in neighbour-caprylyl-6 '-D-maltose or neighbour-dodecanoyl-6 '-D-maltose among the FR-2739556.
In the bound to polyglycerol aliphatic alcohol, can should be mentioned that bound to polyglycerol dodecanediol (3.5 mole of glycerin), this product is sold with title Chimexane NF  by Chimex company.
2. anion surfactant can be selected from; carboxylate particularly; amino acid derivativges; alkyl sulfate; alkyl ether sulfate, sulfonate, isethionate, taurate, sulfosuccinate, alkyl sulfoacetate, phosphate ester salt and alkyl phosphate salt, polypeptide, anion alkyl polyglucoside derivant and fatty acid soaps and its mixture.
The carboxylate that can mention for example comprises N-acyl amino acid alkali metal salt; Acylamino-ether carboxylate (AECs), for example the lauryl acylamino-ether carboxylic acid sodium (3EO) of selling with title Akypo Foam30  by Kao Chemicals company; Polyoxyethylene carboxylate, for example oxygen ethylideneization (6EO) the Laurel ether carboxylic acid sodium (C12-14-16 65/25/10) of selling with title Akypo Soft45NV  by Kao Chemicals company; The polyoxyethylene fatty acid of olive oil and carboxymethyl, this product is sold with title Olivem 400  by Biologia ETechnologia company; By oxygen ethylideneization (6EO) the tridecyl ether carboxylic acid sodium of Nikkol company with title Nikkol ECTD-6NEX  sale.
Amino acid derivativges can be selected from for example sarcosinate, acyl sarcosinates particularly, for example sodium N-lauroyl sarcosinate of selling with title Sarkosyl NL97  by Ciba company or the sodium N-lauroyl sarcosinate of selling with title OramixL30  by SEPPIC company, myristoyl sodium sarcosinate of selling with title Nikkol sarcosinate MN  by Nikkol company or the palmitoyl sarcosine sodium of selling with title Nikkol sarcosinate PN  by Nikkol company; Alanine salt, N-lauroyl-N-methyl acylamino-sodium propionate that for example sell with title Sodium Nikkol Alaninate LN30  or that sell with title Alanone ALE  by Kawaken company and N-lauroyl-N-methylalanine triethanolamine of selling with title Alanone Alta  by Kawaken company by Nikkol company; N-acyl glutamate, for example a cocoyl glutamic acid triethanolamine of selling with title acyl glutamate CT-12  by Ajinomoto company and the lauroyl glutamic acid triethanolamine of selling with title acyl glutamate LT-12  by Ajinomoto company; Aspartate, for example the N-lauroyl aspartic acid triethanolamine of selling with title Asparack  by Mitsubishi company and the mixture of N-myristoyl aspartic acid triethanolamine; Citrate and its mixture.
The alkyl ether sulfate that can mention, for example comprise that the Laurel ether sodium sulfate (C12-1470/30) sold with title SiponAOS225  or Texapon N702PATE  by Henkel company (2.2EO), the Zetesol AP of being sold with title Sipon Lea370  by Henkel company (C12-14 70/30) (3EO) and (C12-C14) alkyl ether (9EO) ammonium sulfate of being sold with title RhodapexAB/20  by Rhodia Chimie company.
The sulfonate that can mention, for example comprise the a-alkenyl sulphonate, a-sodium olefin sulfonate (C14-16) that for example sell with title Bio-Terge AS-40 , that sell with title Witconate AOSProtege  and Sulframine AOS PHl2  by Witco company or that sell with title Bio-Terge AS-40 CG  by Stepan company by Stepan company, the secondary alkene sulfonic acid sodium of selling with title Hostapur SAS30  by Clariant company; Straight chained alkyl arylsulphonate, for example sodium xylene sulfonate of selling with title Manrosol SXS30 , Manrosol SXS40  and ManrosolSXS93  by Manro company.
The isethionate that can mention comprises acyl isethinate, cocoyl hydroxyethyl sulfonate for example, for example by Jordan company with title Jordapon CIP  product sold.
The taurate that can mention comprises the palm-kernel oil N-methyltaurine sodium of being sold with title Hostapon CTPate  by Clariant company; N-acyl group N methyl taurine salt; N-cocoyl N methyl taurine sodium that for example sell with title Hostapon LT-SF  or that sell with title NikkolCMT-30-T  by Nikkol company and the palmityl N-methyltaurine sodium of selling with title Nikkol PMT  by Nikkol company by Clariant company.
The sulfosuccinate that can mention for example comprises by Witco company with title Setacin103Special ; oxygen ethylideneization (3EO) lauryl one sulfosuccinate (C12/C14 70/30) that Rewopol SB-FA 30K4  sells; by the C12-C14 alkyl half disodium sulfosuccinate salt of Zschimmer Schwarz with title Setacin FSpecial Paste  sale; by oxygen ethylideneization (2EO) the oleoyl disodium sulfosuccinate of Henkel company with title Standapol HS 135  sale; by oxygen ethylideneization (5EO) lauryl amide one sulfosuccinate of Sanyo company with title LebonA-5000  sale; Oleum Ricini single ethanol amide one sulfosuccinate that oxygen ethylideneization (10EO) lauryl citrate one disodium sulfosuccinate salt of being sold with title Rewopol SB CS 50  by Witco company and Witco company sell with title Rewoderm S1333 .
The phosphate ester salt that can mention and alkyl phosphate salt for example comprise alkylphosphonate and dialkyl phosphate salt, for example by the lauryl Monophosphate salt of Kao Chemicals company with title MAP 20  sale, by the 1-isobutyl-3,5-dimethylhexylphosphoric acid potassium salt of Cognis company with title Crafol AP-31  sale, it is the mixture (mainly being diester) of monoesters and diester, the phosphoric acid octyl group monoesters of selling with title Crafol AP-20  by Cognis company and the mixture of diester, ethoxylation (the 7 moles of EO) phosphate monoester of the 2-butyl capryl alcohol of selling with title Isofol12 7EO-phosphate ester by Condea company and the mixture of diester, the potassium salt of monoalkyl (C12-13) phosphate ester of selling with specified Arlatone MAP 230K-40  and Arlatone MAP 230T-60  by Uniqema company or triethanolamine salt and the Tryfac 5573 potassium of selling with title Dermalcare MAP XC-99/09  by Rhodia Chimie company.
For example, by with aliphatic chain with by corn, particularly the aminoacid coupling that is obtained by Semen Tritici aestivi and Herba bromi japonici obtains polypeptide.The polypeptide that can mention; for example comprise the potassium salt with the hydrolysis lauroyl wheat protein of title AminofoamW OR  sale by Croda company; by the triethanolamine salt of Maybrook company with the hydrolysis cocoyl soybean protein of title May-Tein SY  sale; by the sodium salt of SEPPIC company with the Herba bromi japonici lauroyl amino acid of title Proteol Oat  sale; by the soybean protein with hydrogenation coconut oil acidylate that be grafted to collagen hydrolysate fatty acid distribution of coconut oil on and by SEPPIC company with title Proteol VS22  sell of DeutscheGelatine company with title Geliderm 3000  sale.
The anionic derivative of alkyl polyglucoside especially can be glycerin ether, carbonate, sulfosuccinate, tartrate and the citrate that is obtained by alkyl polyglucoside.Can mention, it for example is the cocoyl polyglucoside of selling with title Eucarol AGE-ET  by Cesalpinia company (1,4) sodium salt of tartrate, by the cocoyl polyglucoside (1 of SEPPIC company with title Essai 512 MP  sale, 4) disodium salt of sulfosuccinate, sodium salt with cocoyl polyglucoside (1, the 4) citrate of selling with title Eucarol AGE-EC  by Cesalpinia company.
Spendable fatty acid soaps as anion surfactant is the fatty acid with the salifiable natural or synthetic source of mineral alkali or organic base.Aliphatic chain can comprise 6-22 carbon atom, preferred 8-18 carbon atom.Mineral alkali or organic base can be selected from alkali metal or alkaline-earth metal, aminoacid and amino alcohol.Spendable salt for example comprises lysine and arginic sodium, potassium, magnesium, triethanolamine and N-methylglucosamine salt.The soap that can mention for example comprises lauric acid, myristic acid, Palmic acid or stearic potassium or sodium salt (potassium laurate or sodium, potassium myristate or sodium, potassium palmitate or sodium and potassium stearate or sodium) and its mixture.
3. both sexes and zwitterionic surfactant can be selected from, for example betanin, N-alkyl amido betanin and its derivant, glycine derivative, sulfobetaines, alkyl polyaminocarboxylate and alkyl both sexes acetate and its mixture.
The betanin that can mention, for example comprise coco betaine, for example by Henkel company with title Dehyton AB-30  product sold, lauryl betaine, for example by Clariant company with title Genagen KB  product sold, oxygen ethylideneization (10EO) lauryl betaine, for example by Shin Nihon Rica company with title Laurel ether (10EO) betanin  product sold, with oxygen ethylideneization (10EO) stearyl betaine, for example by Shin Nihon Rica company with title stearyl ether (10EO) betanin  product sold.
In N-alkyl amido betanin and its derivant, can mention for example be sell with title Lebon 2000 HG  by Sanyo company or by Albright﹠amp; Wilson company is with the cocoamidopropyl of title Empigen BB  sale and the lauramido propyl betaine of being sold with title Rewoteric AMBl2P  by Witco company.
The glycine derivative that can mention comprises the N-cocoyl Glycine sodium of being sold with title Amilite GCS-12  by Ajinomoto company.
The sulfobetaines that can mention comprises the cocos nucifera oil acylamino-propyl hydroxy sulfobetaines of being sold with title Crosultaine C-50 by Croda company.
The alkyl polyaminocarboxylate (APACs) that can mention comprises the cocoyl polyaminocarboxylic acid sodium of being sold with title Ampholak 7CX/C  and Ampholak 7 CX  by Akzo Nobel company, gathers propylamine sodium with the stearyl polyamidoamines carboxylic acid sodium of title Ampholak 7 TX/C sale with by Akzo Nobel company with the carboxymethyl oil base that title Ampholak XO7/C  sells by Akzo Nobel company.
The alkyl both sexes acetate that can mention, for example comprise N-cocoyl-N-carboxymethoxyl ethyl-N-carboxymethyl ethylenediamine N-disodium (the CTFA title: cocos nucifera oil both sexes oxalic acid disodium), for example by RhodiaChimie company with title Miranol C2M Concentre NP  product sold and N-cocoyl-N-ethoxy-N-carboxymethyl ethylenediamine N-sodium (CTFA title: cocos nucifera oil both sexes sodium acetate).
A kind of specific embodiment according to the present invention, in above-mentioned surfactant, the anion surfactant of more special use is acyl sarcosinates, oxygen ethylidene alkyl ether sulfate, N-acyl group N methyl taurine salt, N-acyl glutamate, acyl isethinate, sulfosuccinate, phosphate ester salt and alkyl phosphate salt, polypeptide and soap; The both sexes of more special use and zwitterionic surfactant are betanin and alkyl both sexes acetate; The non-ionic surface active agent of more special use is alkyl polyglucoside, O-caprylyl-6 '-D-maltose, O-lauroyl-6 '-D-maltose, bound to polyglycerol dodecanediol (3.5 mole of glycerin) and 2-ethylhexyl oxygen carbonyl N-methylglucosamine and these surfactant mixtures.
According to the water-bearing media of compositions of the present invention, except water, also can contain one or more solvents, it is selected from the lower alcohol that contains 1-6 carbon atom, for example ethanol; And polyhydric alcohol.The polyhydric alcohol that can mention comprises glycerol, ethylene glycol, for example butanediol, isoprenediol, propylene glycol and Polyethylene Glycol PEG-8 for example; Sorbitol; Sugar is glucose, fructose, maltose, lactose or sucrose for example; With its mixture.The content of solvent in the present composition, for example, the gross weight of compositions is 0.5%-30% weight relatively, preferred 2%-20% weight.
The present composition can contain the additive that is generally used in the cosmetics, especially in the cleaning products those.The additive that can mention, for example, comprise spice, antiseptic, chelating agen (EDTA), pigment, Concha Margaritifera, mineral or organic filler, delustering agent, bleaching or remover, the coloring agent of solubility, sunscreen, cosmetics or dermatosis activating agent be water solublity or liposoluble vitamin for example, antiseptic, antiseborrheic, antibacterial is benzoyl peroxide for example, salicylic acid, trichloro hydroxyl diphenyl ether and Azelaic Acid, also has fluorescent whitening agent, non-ionic polymers is polyvinyl pyrrolidone (PVP) for example, anion and amphiphilic polymers, with with the immiscible fatty material of water-bearing media, for example oil or wax.The consumption of these various additives be consider the conventional amount used in field, for example be the 0.01%-20% of composition total weight.These additives and their concentration must make them not change the required character of the present composition.
As filler, can mention, for example for example Talcum or magnesium silicate (size: 5 microns) of the mineral filler of selling with title LUZENAC 15M00  by LUZENAC company; Kaolin or aluminium silicate are for example sold with title KAOLIN SUPREME by IMERYS company; Or organic filler, starch for example, such as by ROQUETTE company with title AMIDON DE MAIS B product sold, nylon framboid, for example those that sell with title Orgasol 2002UD NATCOS by Atochem company; The expansible framboid that contains iso-butane, for example those that sell with title Expancel551 DE by EXPANCEL company based on vinylidene chloride/acrylonitrile/methacrylonitrile copolymers.Also may in the present composition, add fiber, nylon fiber (polyamide 0.9Dtex 0.3mm for example, sell by Etablissements Paul Bonte), the RAYONFLOCK RCISE NOOO3 MO4  that cellulose or staple fibre (by CLAREMONT FLOCK CORPORATTON) company sells).
The present composition especially can be configured for skin (human body, face and eyes), scalp and/cleaning or the cosmetics of hair remove product.
Constituting another theme of the present invention is the cosmetic use of compositions conduct as defined above from the product of skin, eyes, scalp and/or hair cleaning and/or removal cosmetics.
The present composition also can be configured for handling oily skin and/or the compositions of be used to sterilize skin and/or scalp, especially when they contain antibacterial.Especially, the particular active agent that is used to handle oily skin can be included in wherein, for example salicylic acid, Azelaic Acid, trichloro hydroxyl diphenyl ether, piroctoneolamine or nicotiamide (vitamin PP).
The compositions that another theme of the present invention is above definition is used to prepare expection processing oily skin and/or the purposes of the compositions of be used to sterilize skin and/or scalp.
The cosmetic method that to constitute another theme of the present invention be cleaning skin, eyes, scalp and/or hair, be characterised in that in the presence of water, be applied to the present composition on skin, eyes, scalp and/or the hair and the foam and the dirty residue of formation are removed in water flushing.
In the situation of cleaning face, the present composition can form facial film, is rinsed after keeping 1-3 minute.
Preferred forms
Following embodiment is used to illustrate the present invention, rather than as restriction.Unless otherwise indicated, shown content is percetage by weight.
Embodiment 1 and comparative example 1 and 2: the compositions that does not contain soap
Compositions The comparative example 1 The comparative example 2 According to embodiments of the invention 1
Coco betaine [Dehyton AB-30 , 30% active matter (A.M.)] 9.75% (pressing A.M.) 9.75% (pressing A.M.) 9.75% (pressing A.M.)
Laurel ether sodium sulfate (2.2EO) [Texapon N702 Pate , 70% active matter (A.M.)] 2.6% (pressing A.M.) 2.6% (pressing A.M.) 2.6% (pressing A.M.)
PEG-120 methyl glucose dioleate (Glucamate DOE-120 Vegetal ) 4％ 0 4％
Hydrophobic silica (Aerosil R-972 ) 0 5％ 5％
Sorbitol 3.5％ 3.5％ 3.5％
Glycerol 3.5％ 3.5％ 3.5％
Antiseptic In right amount In right amount In right amount
Water An amount of 100g An amount of 100g An amount of 100g
Outward appearance The crystallization gel that liquidity preference is arranged Fluid product Condensed translucent gels
pH 7 6.7 6.6
At about 25 ℃, use the viscosity under 180, No. 4 rotating shafts of Rheomat 59 pools (=5.9Pa.s) 1-100 centipoise (1-100mPa.s) 97 pools (=9.7Pa.s)
The present composition has and is condensed gelatinous advantage, and it uses easily than the gel that liquidity preference is arranged, and has good cosmetic property.
Embodiment 2: do not contain (Mydol10) 6.5% (pressing A.M.) potassium hydroxide 1.7%PEG-120 methyl glucose dioleate (Glucamate 2%DOE-120Vegetal ) hydrophobic silica (Aerosil R-972 ), 5% anticorrisive agent suitable quantity of water an amount of 100% of composition, foam lauryl Monophosphate (containing 75% monoesters) (MAP20 ) 6.5% (the pressing A.M.) alkyl of soap-C9/C11-polyglucoside (1.4)
Said composition is the condensed gel form that liquidity preference is arranged, and its pH is 7.1, under 25 ℃, measures with the Rheomat180 viscosity apparatus that No. 4 rotating shafts are housed, and viscosity is 142 pools (14.2Pa.s).
Sensory property characteristic: according to the foam property of following proposal evaluation generation.
Before using this product, wash hands with animal soap, then suitably flushing and dry.Then by following scheme:
1-is put into moistening hands under the circulating water with hands, shake hands three times, and with the water of draining,
2-is put into the palm of the hand of a hands with the 1g product,
3-10 seconds of operated products between two palms of the hand,
4-adds 2ml water and 10 seconds of operated products again,
5-washes hands under water,
6-dry they.In each step of following scheme, estimate its standard, and press the 0-10 mark they classifications.-step 3: estimate covering power: it is few more to see through the appreciable skin of sprawling of product, and the grade of ownership is corresponding high more.-step 4: assess foam characteristic.-foam volume: volume is big more, and the grade that provides is corresponding high more.-form foamy bubble size: steep greatly more, the grade that provides is corresponding high more.-density: foamy density and state: density is high more, and the grade that provides is corresponding high more.-foam flexibility: foam is soft more, and the grade that provides is corresponding high more.-step 5: evaluation-flushing in flushing process: the smooth film of being deposited that is difficult to remove is serious more, and the grade that provides is corresponding low more.In following table, provided the sensory property that obtains for every kind of standard:
The comparative example 1 The comparative example 2 According to embodiments of the invention 1 According to embodiments of the invention 2
The speed that initial foam occurs ?10 ?9.5 ?9.8 ?10
Covering power ?6.3 ?4.6 ?6.4 ?6.4
Foam volume ?6.4 ?6.8 ?6.4 ?6.1
The size of bubble ?4.5 ?5 ?3.9 ?3.8
Density ?6.9 ?6.8 ?7.4 ?7.1
The foam flexibility ?6.4 ?6.1 ?6.9 ?5.8
Flushing ?6.9 ?7.3 ?7.3 ?8.4
In order to reach significance, the difference between two kinds of different numerical value should be more than or equal to 1.
As above shown in the table, add hydrophobic silica and oxygen ethylidene chemical compound, more condensed Cleasing compositions and better rheological property have been obtained simultaneously, and do not change resulting foaming properties attribute, and some standard has improvement, Pao size (with foamy fineness thus) for example, with in the situation of embodiment 1, use Laurel ether sodium sulfate (2.2EO) and coco betaine as surfactant system, notice that the foam flexibility has improvement.

Claims (17)

1. Cleasing compositions, in physiologically acceptable water-bearing media, the gross weight of relative compositions, this medium comprises the water of at least 35% weight, said composition comprises, (1) at least a foaming surfactant, (2) at least a hydrophobic silica and (3) at least a oxyalkylene chemical compound.
2. according to the compositions of claim 1, be characterised in that the gross weight of relative compositions, it comprises 35%-95% weight water.
3. the compositions that requires according to arbitrary aforesaid right is characterised in that its viscosity is 7-20Pa.s.
4. the compositions that requires according to arbitrary aforesaid right is characterised in that the weight of hydrophobic silica by active matter, and composition total weight is at least 1% relatively.
5. the compositions that requires according to arbitrary aforesaid right is characterised in that the weight of hydrophobic silica by active matter, and composition total weight is 1%-15% relatively.
6. the compositions that requires according to arbitrary aforesaid right is characterised in that hydrophobic silica is selected from the amorphous silica in dry distilling source.
7. the compositions that requires according to arbitrary aforesaid right is characterised in that hydrophobic silica is selected from that to have specific surface be 50-500m 2/ g, number average particle size is that 3-50nm and density are the silicon dioxide of 40-200g/l.
8. the compositions that requires according to arbitrary aforesaid right is characterised in that the weight of oxyalkylene chemical compound by active matter, the gross weight of relative compositions, and its content is 1%-20%.
9. the compositions that requires according to arbitrary aforesaid right, be characterised in that the oxyalkylene chemical compound is selected from Polyethylene Glycol, macrogol ester and/or polypropylene glycol ester, polyglycol ether and/or polypropylene glycol ether, the alkoxylated alkyl derivant of polyhydric alcohol, oxyalkylene three esters of glycerol and fatty acid are with ethyoxyl ethylidene urethane derivatives and its mixture of alkyl chain modification.
10. the compositions that requires according to arbitrary aforesaid right is characterised in that foaming surfactant is selected from non-ionic surface active agent, anion surfactant, amphoteric surfactant and zwitterionic surfactant and its mixture.
11. the compositions according to arbitrary aforesaid right requires is characterised in that the weight of foaming surfactant by active matter, the gross weight of relative compositions, and its content is 2%-50%.
12. compositions according to arbitrary aforesaid right requirement; be characterised in that foaming surfactant is selected from alkyl polyglucoside; the Fructus Hordei Germinatus sugar ester; the bound to polyglycerol aliphatic alcohol; the glycosamine derivant; carboxylate; amino acid derivativges; alkyl sulfate, alkyl ether sulfate; sulfonate; isethionate; taurate; sulfosuccinate; alkyl sulfoacetate; phosphate ester salt and alkyl phosphate salt; polypeptide; anion alkyl polyglucoside derivant; fatty acid soaps; betanin; N-alkyl amido betanin and its derivant; glycine derivative; sulfobetaines; alkyl polyaminocarboxylate and alkyl both sexes acetate and its mixture.
13. the compositions according to arbitrary aforesaid right requires is characterised in that it also comprises at least a solvent, it is selected from pure and mild polyhydric alcohol and its mixture that comprises 1-6 carbon atom.
14. clean and/or remove the cosmetic use of the product of cosmetics from skin, eyes, scalp and/or hair according to the compositions conduct of arbitrary aforesaid right requirement.
15. the compositions according to arbitrary claim 1-13 is used to prepare the purposes that the compositions of oily skin and/or sterilization skin and/or scalp is handled in expection.
16. the cosmetic method of cleaning skin, eyes, scalp and/or hair, be characterised in that in the presence of water, to be administered on skin, eyes, scalp and/or the hair according to the compositions of arbitrary claim 1-12, and the foam of formation and dirty residue are removed in the water flushing.
17., be characterised in that it constitutes a kind of facial film according to the compositions of arbitrary claim 1-13.
CN01124836A 2000-07-13 2001-07-12 Cosmetic cleaning composition Pending CN1337224A (en)

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US20020039976A1 (en) 2002-04-04
ES2184725T3 (en) 2003-04-16

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