CN103945821B - Cosmetic composition - Google Patents

Cosmetic composition Download PDF

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Publication number
CN103945821B
CN103945821B CN201280054003.2A CN201280054003A CN103945821B CN 103945821 B CN103945821 B CN 103945821B CN 201280054003 A CN201280054003 A CN 201280054003A CN 103945821 B CN103945821 B CN 103945821B
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China
Prior art keywords
compositionss
siloxanes
content
vitamin
aminofunctional
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CN201280054003.2A
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CN103945821A (en
Inventor
E·克霍斯德
Q·张
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Unilever IP Holdings BV
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Unilever NV
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Priority to CN201280054003.2A priority Critical patent/CN103945821B/en
Priority claimed from PCT/EP2012/070485 external-priority patent/WO2013064365A1/en
Publication of CN103945821A publication Critical patent/CN103945821A/en
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Abstract

The invention relates to a cosmetic composition comprising an emulsion comprising hydrophobically modified particles, amino functionalized silicone and water; the cosmetic composition further comprising a moisturizing agent and at least one component selected from the group consisting of vitamin, anti-dandruff agent and surfactant, wherein the composition comprises at least a vitamin or anti-dandruff agent. The invention further relates to a method of treating a skin condition comprising the step of topically applying to the skin the cosmetic composition of the invention.

Description

Cosmetic composition
Invention field
The present invention relates to cosmetic composition, it is particularly suitable for improving the cosmetic composition of skin health.
Background of invention
Many consumers pay close attention to their skin characteristic.Some consumers can feel that they have xerosis cutiss, obscure Skin appearance or other defect such as wrinkle and microgroove.
In order to meet the needs of consumer, have been developed for the product solving skin health and improving skin properties. This kind of skin care compositions and methods typically at least comprise wetting agent such as glycerol.In addition to wetting agent, using other compositions for example Solve vitamin and the dandruff removing agent of (address) particular skin characteristic.
Consumer prefers (being for example easy to be applied to skin) easy to use and/or delivers after local application to skin The product of excellent organoleptic benefits' (such as non-sticky or soft and smooth sensation).
After application to skin, wetting agent can leave adhesion sense.
Accordingly, it would be desirable to have for example inviscid cosmetic composition of good organoleptic properties.
Inventor developed not having the cosmetic composition of aforesaid drawbacks.
Invention summary
Therefore, the present invention relates to cosmetic composition, it contains and comprises following emulsions:
A. the granule of hydrophobically modified, selected from silicon dioxide, metal-oxide and its mixture;
B. the siloxanes of aminofunctional;With
C. water;
Described cosmetic composition further includes:
D. wetting agent;With
E. at least one component selected from vitamin, dandruff removing agent and surfactant;
Wherein said compositionss comprise at least vitamin or dandruff removing agent.
The invention further relates to the method processing skin disorder, it includes the cosmetic composition of the local application present invention Step.
Detailed Description Of The Invention
Unless otherwise stated, percetage by weight (wt%) is the gross weight meter based on compositionss.The cosmetics group of the present invention Compound is emulsion, and it can be water-in-oil type or emulsion oil-in-water.Preferably emulsion is emulsion oil-in-water.Preferably Ground, the content of water is 10 to 90wt%, more preferably 20 to 85wt%, even more preferably 30 to 80wt%, and still even more Preferably 40 to 70wt%.
The granule of hydrophobically modified
The compositionss of the present invention include the granule of the hydrophobically modified of silicon dioxide, metal-oxide and its mixture.Preferably Ground, the granule of described hydrophobically modified includes silicon dioxide or titanium oxide, the more preferably silicon dioxide (silicon dioxide of hydrophobically modified (silicone dioxide)).
It is particularly preferred that the silicon dioxide of hydrophobically modified includes the hydrophobic group of following formula:
Wherein r is c4To c18Alkyl.
It is particularly preferred to be the silicon dioxide of hydrophobically modified, comprising:
Preferably silicon dioxide is described in us7282236, and be from supplier such as evonik degussa gmbh with Title aerosil r812, r202 and r805 are commercially available obtainable.There is the silicon dioxide of c4 to the c15 alkyl connecting to silane It is preferred.Particularly preferably comprise the octyl group silane (selling with title aerosil r805) of the group that above formula represents.
The initial particle size (being counted with its dry state) that the silicon dioxide of hydrophobically modified preferably has for 1nm to 100nm, more Preferably 5nm to 70nm.
The compositionss of the present invention preferably comprise the silicon dioxide accounting for total composition 0.05 to the hydrophobically modified of 15wt%, more excellent Select 0.1 to 10wt%, most preferably 0.2 to 5wt%.
The siloxanes (silicone) of aminofunctional
Include the siloxanes of amino-functional according to the compositionss of the present invention.
" siloxanes of aminofunctional " refers to comprise the siloxanes of at least one primary amine, secondary amine or tertiary amine groups or quaternary ammonium group.
Primary amine, secondary amine, tertiary amine and/or quaternary amine base can form a part for main polymer chain, or more preferably gathered The side chain radical (side group) that conjunction main chain carries or side base (pendant group) are entrained.
The siloxane polymer of the suitable aminofunctional using for the present invention is described in us4185087.
The scope being applied to mole % amine degree of functionality that the siloxanes of the aminofunctional of the present invention generally has is about 0.1 To about 8.0 moles of %, preferably from about 0.1 to about 5.0 mole of %, most preferably from about 0.1 to about 2.0 mole of %.Generally, amine concentration should It is not greater than about 8.0 moles of %.
In a preferred embodiment, the polymer of described functionalization is the ammonia end poly dimethyl with following formulas Siloxanes (amodimethicone):
Wherein each r independently is h or c1-4Alkyl, preferably h;
Each r1It independently is or or c1-4Alkyl;With
Each x independently 1 to 4 integer, each y is more than 0 and independently is integer, produce have molecular weight 500 to 1000000, preferably 750 to 25,000, most preferably 1,000 to 15,000 polymer.It is particularly preferred to be and comprise aminodiol altogether The siloxanes of polymers (amino glycol copolymer).It is particularly preferred to be double (c13-c15 alkoxyl) pg ammonia ends poly- two Methylsiloxane, is such as derived from the dc8500 of dow corning.For the polymer of functionalization, trimethyl silyl ammonia end Polydimethylsiloxane is also included within the scope of the invention.Preferably, the content structure of the siloxane polymer of aminofunctional Become 0.05 to the 25wt%, more preferably 0.05 to 15wt%, even more preferably 0.1 to 10% of total composition, still even more excellent Select 0.2 to 5wt%.
Preferably, the granule of hydrophobically modified and the weight of the siloxanes of aminofunctional are than for 3: 1 to 1: 50, more preferably 1: 1 to 1: 10.
Wetting agent
The compositionss of the present invention include wetting agent.Preferably, described wetting agent is selected from polyhydric alcohol, the urea replacing and its mixing Thing.
Typical polyhydric alcohol includes glycerol (that is, glycerol), propylene glycol, dipropylene glycol, polypropylene glycol, Polyethylene Glycol, mountain Pears alcohol, hydroxypropyl sorbitol, hexanediol, 1,3 butylene glycol, isoprene, 1,2,6- hexane triols, the glycerol of ethoxylation, third The glycerol of epoxide and its mixture.
The typical urea replacing is methylolurea, ethoxy urea, hydroxypropyl urea;Two (methylol) urea;Two (ethoxy) urea; Two (hydroxypropyl) urea;N, n '-bishydroxymethyl urea;N, n '-dihydroxy ethyl urea;N, n '-dihydroxypropyl urea;N, n, n '-three Hydroxyethyl urea;Four (methylol) urea;Four (ethoxy) urea;Four (hydroxypropyl) urea;N- methyl, n '-ethoxy urea;N- ethyl- N '-ethoxy urea;N- hydroxypropyl-n '-ethoxy urea and n, n '-dimethyl-n- ethoxy urea or its mixture.When term occurs During hydroxypropyl, implication is 3- hydroxyl-n-propyl, 2- hydroxyl-n-propyl, 3- hydroxyl-i-propyl or 2- hydroxyl-i-propyl It is referred to as.Most preferably ethoxy urea.The latter can be by the national starch&chemical division of ici with business Mark hydrovance obtains as 50% waterborne liquid.
Preferably, wetting agent comprises at least polyhydric alcohol.Preferably, described polyhydric alcohol is glycerol.
Preferably, the content of wetting agent is 0.01 to 25wt%, preferably 0.2 to 20wt%, more preferably 1 to 15wt%, and And even more preferably 2 to 10wt%.
Vitamin, dandruff removing agent, surfactant
The compositionss of the present invention comprise at least one selected from following components: vitamin, dandruff removing agent and surfactant, The compositionss of the wherein present invention include at least vitamin or dandruff removing agent.
Exemplary vitamin is vitamin a (retinol), vitamin b2, vitamin b6, vitamin c, vitamin e, Folic Acid And biotin.The derivant of vitamin can also be used.For example, Ascorbic Acid Derivatives include Ascorbyl Tetraisopalmitate, Magnesium ascorbyl phosphate and ascorbic acid glucoside.The derivant of vitamin e includes tocopherol acetate, tocopheryl palmitate And Vitamin E linoleate.Dl- pantothenylol and derivant can also be used.
Preferably, vitamin is selected from a, b, c, d, e, its derivant and combinations thereof.
Preferably, the content of vitamin is 0.001 to 10wt%, preferably 0.01 to 8wt%, more preferably 0.1 to 6wt%, And even more preferably 1 to 3wt%.Dandruff removing agent is the compound active for dandruff, and usually antimicrobial is excellent Selection of land is antifungal.Antifungal generally shows for chlosma (malassezia spp) about 50mg/ml or less Minimum inhibitory concentration.
Suitable dandruff removing agent includes selected from following compounds: Ketoconazole, climbazole (climbazole), pyridone Ethanolamine (octopirox), metal pyrithione (pyrithione) salt and its mixture.
Preferably azole-based antifungal agent is Ketoconazole and climbazole.Preferably metal pyrithione salt is pyrithione Zinc, copper, silver and zirconium.Most preferably Zinc Pyrithione.Preferably, the amount of anti-dandruff activating agent be compositionss 0.01 to 5wt.%, more preferably 0.1 to the 2.5wt.% of compositionss.
Surfactant can also be present in the cosmetic composition of the present invention.The total concentration of surfactant is combination 0 to the 40wt% of thing, preferably 0.01 to 20wt%, optimal 0.01 to 5wt%.Surfactant is selected from: anion, non-from Son, cation and amphoteric surfactant.Particularly preferred nonionic surfactant be have c10-c20 fatty alcohol or with often rub The oxirane of your 2 to 100 moles of hydrophobe or the acid hydrophobe of expoxy propane condensation;With 2 to 20 moles of alkylene oxide contracting The c2-c10 alkyl phenol closing;The mono fatty acid ester of ethylene glycol and di fatty acid ester;Glycerine monofatty ester;Anhydro sorbitol, list- With two-c8-c20 fatty acids;Block copolymer (ethylene oxide/propylene oxide);Polyethenoxy sorbitan with and combinations thereof Those.Alkyl polyglucoside and sugared fatty acid amide (for example, methyl glucose amide (methyl gluconamide)) are also to close Suitable nonionic surfactant.
Preferably anion surfactant include soap, alkyl ether sulfate and sulfonate, alkyl sulfate and sulfonate, Alkylbenzenesulfonate, alkyl sulfo succinate and dialkyl sulfosuccinates, c8-c20 acyl isethinate (acyl Isothionate), acyl glutamate, c8-c20 alkyl ether phosphate and combinations thereof.
Viscosity modifier
The compositionss of the present invention preferably also include viscosity modifier, selected from the siloxanes of non-amino functionalization, fatty acid, The ester of fatty acid, hydrocarbon, fatty alcohol and its mixture.
The siloxanes of suitable non-amino functionalization includes and preferably polydiorganosiloxanewith, particularly has ctfa The polydimethylsiloxane of specified title dimethicone (dimethicone).The compositionss applying also for the present invention are tools There is the polydimethylsiloxane of hydroxyl end groups, it has ctfa and specifies designation Dimethicone alcohol (dimethiconol). The siloxane glue with the little degree of cross linking is also applied for the compositionss of the present invention, as described in such as wo96/31188.Suitably The siloxanes of non-amino functionalization is volatile silicone oil, and for example D5 (is for example derived from dow corning's dc245fluid);Non-volatile dimethicones polymer, has viscosity 0.65cst extremely such as from dow corning The oils of the dc200 series of 600,000cst;Silicone elastomer blend, the such as dc9041 (diformazan from dow corning Base silicone oil and dimethicone cross polymer), dc9045 the and dc9040 (D5 and two from dow corning Methyl-silicone oil cross linked polymer), dc9546 (D5 and dimethicone cross polymer, and dimethicone/ethylene Base dimethicone cross polymer and dimethiconol, from dow corning), dc9506 (dimethicone/ Vinyl-dimethyl base silicone oil cross linked polymer, from dow corning);Silicone elastomers liquid suspension, such as dc9509 (diformazan Base silicone oil/vinyl-dimethyl base silicone oil cross linked polymer, and c12-14pareth-12, from dow corning).
Suitable fatty acid is the fatty acid of 10 to 30 carbon atoms.The illustrative examples of this kind of fatty acid include n-nonanoic acid, Lauric acid, myristic acid, Palmic acid, stearic acid, isostearic acid, Oleic acid, linoleic acid, arachidic acid, behenic acid or erucic acid and its mixed Compound.
The ester of fatty acid include and preferably have 10-24 carbon atom satisfied fatty acid Arrcostab;Ether-ester is such as The fatty acid ester of the fatty alcohol of ethoxylation saturation;The single- and di- fatty acid ester of polyol ester, ethylene glycol, diethylene glycol are single- and di- Fatty acid ester etc.;Wax ester, such as Cera Flava, spermaceti and three Rhizoma Atractylodis Macrocephalae waxes (tribehenin wax);The sugar ester of fatty acid, such as sugarcane The many behenates of sugar and sucrose polycottonseedate oleate (sucrose polycottonseedate);Based on single-, two-, triglycerin The Natural ester emollients of ester.
Hydro carbons include and preferably vaseline, mineral oil, c11-c13 isoparaffin, polytubene, 2-Methylpentadecane (with Permethyl101a is commercially available from presperse inc.).
Fatty alcohol is the aliphatic alcohol being made up of the chain of at least 8 carbon atoms.Preferably, to have 10 to 30 carbon former for fatty alcohol The chain of son.Preferably, viscosity modifier includes the siloxanes of at least non-amino functionalization, it is highly preferred that viscosity modifier is selected from Polydimethylsiloxane, five siloxanes (pentasiloxane), dimethicone, mineral oil and its mixture.
Preferably viscosity modifier is from dow corning, has viscosity 0.65cst to 6000cst The oils of dimethicone dc200 series, mineral oil 70sus.
Preferably, the content of viscosity modifier is 0.05 to 60wt%, preferably 1 to 40wt%, more preferably 5 to 30wt%.
Preferably, viscosity modifier and the weight of the siloxanes of aminofunctional are than for 10: 1 to 1: 50, preferably 3: 1 to 1: 20.
Other compositions
In addition to water, organic solvent can be optionally added into serve as carrier or the auxiliary load within the present composition Body.Be applied to the type of organic solvent of the present invention exemplary and non-limiting examples include alkanol such as ethanol and isopropanol, its Mixture etc..
Thickening agent is also used as a part for the cosmetic composition of the present invention.Typical thickening agent includes the third of crosslinking Olefin(e) acid ester (such as carbopol982), the acrylate (such as carbopol1382) of hydrophobically modified, cellulose derivative and sky So natural gum.Useful cellulose derivative has sodium carboxymethyl cellulose, hydroxypropyl methyl cellulose, hydroxypropyl cellulose, hydroxyl second Base cellulose, ethyl cellulose and hydroxymethyl cellulose.The natural gum being applied to the present invention includes guar gum, xanthan gum, bacterium Core glue (sclerotium), the combination of carrageenin, pectin and these natural gum.The amount of thickening agent can be 0.0 to 5wt%, lead to It is often 0.001 to 1wt%, most preferably for 0.01 to 0.5wt%.
Aromatic can be used in the cosmetic composition of the present invention.The exemplary non-limit of the aromatic type that can use Property example processed includes those comprising terpenes and terpene derivatives, such as in bauer, k., et al., common fragrance Those described in and flavor materials, vch publishers (1990).
Exemplary other non-limiting examples of the fragrance type that can use in the present invention include myrcene, dihydro Myrcenol (dihydromyrenol), citral, tagetone, cis geranic acid, citronellic acid or cis geranic acid nitrile, its Mixture etc..
Preferably, used in the cosmetic composition of the present invention, the amount of spice is 0 to 10wt%, more preferably 0.00001 To 5wt%, most preferably 0.0001 to 2wt%.
Sunscreen includes those materials being generally used for shielding of ultraviolet light.Exemplary compound is the derivative of paba Thing, cinnamate and salicylate.Such as avobenzophenone (parsol1789 can be used), methoxy cinnamic acid Monooctyl ester and ESCALOL 567 (also referred to as oxybenzone).Octyl methoxycinnamate and 2- hydroxyl -4- methoxyl group Benzophenone is commercially available obtainable with trade mark parsol mcx and benzophenone-e respectively.Sun-proof used in compositionss The precise volume of agent can change according to the expectation degree of protection that sun uv is radiated.Many cosmetic compositions, particularly wrap Aqueous those are it should prevent the growth of potentially harmful microorganism.Therefore, Antimicrobe compound such as triclosan and anti-corrosion Agent is generally necessary.Suitable preservative include the Arrcostab of p-hydroxy Benzoic Acid, hydantoin derivatives, propionate and Multiple quaternary ammonium compounds.The particularly preferred preservative of the present invention is methyl hydroxybenzoate, propylparaben, phenyl phenol and benzene Methanol.The usual amount ranges of preservative are 0.1 to the 2wt% of compositionss.
Cosmetic composition
Cosmetic composition refers to the skin for topical application to the mammal particularly mankind as used herein The compositionss of skin.The compositionss of the present invention are typically " leave (leave-on) " compositionss, and mean including conditioner Or tonic agent, and in some manner and refer at least to and solve the general topical composition of skin health conditions.Skin health shape Condition can include skin moisture-keeping, reduce the impact to skin for the sebum and reduce wrinkle of skin.
The cosmetic composition of the present invention can be liquid, skin care liquid, the form of frost, essence (serum) or gel.When When skin refers to face, cervical region, chest, back, arm, hand, the skin of leg and preferred scalp, the combination of the present invention Thing is the compositionss at least solving skin health conditions.
Final cosmetic composition is preferably 10 in 25 degrees Celsius of viscosity3Pa.s to 105Pa.s, more preferably 5*104pa.s To 5*105pa.s.
Generally, the fusing point that the cosmetic composition of the present invention has is about 30 to 45 degrees Celsius.In particularly preferred enforcement In scheme, the cosmetic composition of the present invention is 4.5 to about 8 in 25 degrees Celsius of ph having.More preferably 5 to 7.
The method processing skin disorder
The invention still further relates to the method processing skin disorder, it includes the cosmetic of the present invention described in topical application The step of product compositionss.
Preferably, the compositionss of the present invention are used as " leave " compositionss.
Preferably, methods described is related to the cosmetic non-medical process of skin disorder, and preferably methods described solves skin It is dried.
The cosmetic composition of the present invention is particularly well-suited to deliver wetting agent, without to the cosmetic applying the present invention thereon The skin of product compositionss leaves " cohesiveness sensation ".Even if when being applied to scalp, the compositionss of the present invention also will not hinder head The sensory feel of hair (if present) on skin.Therefore, methods described preferably solves the problems, such as scalp health.
Now, the present invention will be illustrated with reference to following non-limiting examples.
Embodiment
Initial particle size
Initial particle size can be according to s.gu et al in journal of colloid and interface Method described in science289 (2005) 419-426, is obtained by transmission electron microscopy.
Viscosity measurement
Viscosity is fluid measuring to the resistance applying stress.Using mcr501 flow graph (from anton paar Instrument ltd) measurement viscosity.This flow graph is connected to compressed air source, to keep the pressure of 5 bars, continuous to guarantee Rotating speed.Parallel-plate using the geometry of a diameter of 25mm.In 25 degrees Celsius of temperature, with shear rate 0.001 to 100s-1, measure described power using automatically controlling rate mode.
Compound method
Embodiment is prepared by mixing silicon dioxide microparticle in silicone oil.By stirring, remaining composition is added to In oil phase.Prepare comparative example a by mixing each composition.Prepare all of sample at ambient temperature.
The composition using
Aerosil r805, from evonik degussa gmbh;Dc8500, dc245, dc200 fluid 5cst, all From dow corning.
Embodiment 1
Table 1, the compositionss (in terms of wt%) of embodiment 1
Comparative example a
Table 2, the compositionss (in terms of wt%) of comparative example a
Characteristic
Can spreadability by what compositionss were applied to that scalp skin (32 people) evaluates embodiment 1 and comparative example a (spreadibility), cohesiveness and be easy to absorbability.Everyone is directed to these three characteristics and their preference is scored (scored their preference).
Table 3, the characteristic of embodiment 1 and comparative example a
Characteristic Embodiment 1 Comparative example a
Can spreadability 24 8
Less cohesiveness 23 9
It is easy to absorbability 22 10
Compared with comparative example a (not being according to the present invention), embodiment 1 (according to the present invention) all has in all characteristics Better performance.
Embodiment 2 and 3
Prepare leave anti-dandruff essence (serum) (embodiment 2) according to the present invention and leave anti-dandruff is nursed one's health Agent (embodiment 3).
Table 4, the compositionss (in terms of wt%) of embodiment 2 and 3

Claims (27)

1. cosmetic composition, it contains the emulsion comprising following component:
A. the granule of hydrophobically modified, it is selected from: silicon dioxide;
B. the siloxanes of aminofunctional;With
C. water;
Described cosmetic composition comprises further:
D. wetting agent;With
E. at least one component selected from vitamin, dandruff removing agent and surfactant;
Wherein said compositionss comprise at least vitamin or dandruff removing agent, and wherein said silicon dioxide comprises:
Wherein r is c4 to c18 alkyl,
The siloxanes of described aminofunctional includes aminodiol copolymer.
2. compositionss according to claim 1, wherein r is c8h17 alkyl.
3. the compositionss according to claim 1 or 2, the initial particle size that the granule of wherein said hydrophobically modified has is 1nm To 100nm.
4. compositionss according to claim 3, the initial particle size that the granule of wherein said hydrophobically modified has be 5nm extremely 70nm.
5. the compositionss according to claim 1 or 2, the content of the siloxanes of wherein said aminofunctional is total composition 0.05 to 25wt%.
6. compositionss according to claim 5, the content of the siloxanes of wherein said aminofunctional is the 0.05 of total composition To 15wt%.
7. compositionss according to claim 6, the content of the siloxanes of wherein said aminofunctional be total composition 0.1 to 10wt%.
8. compositionss according to claim 7, the content of the siloxanes of wherein said aminofunctional be total composition 0.2 to 5wt%.
9. the weight of the compositionss according to claim 1 or 2, the granule of wherein said hydrophobically modified and the siloxanes of aminofunctional Amount ratio is for 3: 1 to 1: 50.
10. the weight of compositionss according to claim 9, the granule of wherein said hydrophobically modified and the siloxanes of aminofunctional Than for 1: 1 to 1: 10.
11. according to the compositionss of claim 1 or 2, and wherein said wetting agent is selected from polyhydric alcohol, the urea replacing and its mixture.
12. comprise at least polyhydric alcohol according to the compositionss of claim 1 or 2, wherein said wetting agent.
13. compositionss according to claim 12, wherein said polyhydric alcohol is glycerol.
14. according to the compositionss of claim 1 or 2, and the content of wherein said wetting agent is 0.01 to 25wt%.
15. compositionss according to claim 14, the content of wherein said wetting agent is 0.2 to 20wt%.
16. compositionss according to claim 15, the content of wherein said wetting agent is 1 to 15wt%.
17. compositionss according to claim 16, the content of wherein said wetting agent is 2 to 10wt%.
18. according to the compositionss of claim 1 or 2, its further include siloxanes selected from non-amino functionalization, fatty acid, The viscosity modifier of the ester of fatty acid, hydrocarbon, fatty alcohol and its mixture, and the silicon of wherein viscosity modifier and aminofunctional The weight of oxygen alkane is than for 10: 1 to 1: 50.
The weight of 19. compositionss according to claim 18, wherein viscosity modifier and the siloxanes of aminofunctional is than for 3: 1 To 1: 20.
20. are selected from vitamin a, b, c, d, e and combinations thereof according to the compositionss of claim 1 or 2, wherein said vitamin.
21. according to the compositionss of claim 1 or 2, and the content of wherein said vitamin is 0.001 to 10wt%.
22. compositionss according to claim 21, the content of wherein said vitamin is 0.01 to 8wt%.
23. compositionss according to claim 22, the content of wherein said vitamin is 0.1 to 6wt%.
24. compositionss according to claim 23, the content of wherein said vitamin is 1 to 3wt%.
25. is 10 according to the compositionss of claim 1 or 2, wherein said compositionss in 25 degrees Celsius of viscosity3Pa.s is extremely 105pa.s.
26. is 5*10 according to the compositionss of claim 1 or 2, wherein said compositionss in 25 degrees Celsius of viscosity4Pa.s to 5* 105pa.s.
The cosmetic composition of any one of 27. claim 1 to 26 is used for the use in the product processing skin disorder in preparation On the way.
CN201280054003.2A 2011-11-04 2012-10-16 Cosmetic composition Expired - Fee Related CN103945821B (en)

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CN109952087B (en) * 2017-06-05 2022-09-27 宝洁公司 Hair care compositions comprising sebum modifying material
EP3801447A1 (en) * 2018-06-05 2021-04-14 The Procter & Gamble Company Rinse-off cleansing compositions comprising materials that modify sebum

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Publication number Priority date Publication date Assignee Title
CN1337224A (en) * 2000-07-13 2002-02-27 莱雅公司 Cosmetic cleaning composition
CN101087579A (en) * 2004-12-24 2007-12-12 德古萨有限责任公司 Storage of pulverulent substances having a high water content

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1337224A (en) * 2000-07-13 2002-02-27 莱雅公司 Cosmetic cleaning composition
CN101087579A (en) * 2004-12-24 2007-12-12 德古萨有限责任公司 Storage of pulverulent substances having a high water content

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