CN1330705A - Lundry detergent compositions with cationically charged dye maintenance polymer - Google Patents

Lundry detergent compositions with cationically charged dye maintenance polymer Download PDF

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Publication number
CN1330705A
CN1330705A CN99814391A CN99814391A CN1330705A CN 1330705 A CN1330705 A CN 1330705A CN 99814391 A CN99814391 A CN 99814391A CN 99814391 A CN99814391 A CN 99814391A CN 1330705 A CN1330705 A CN 1330705A
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Prior art keywords
composition
dye maintenance
fabric
dyestuff
maintenance polymer
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CN99814391A
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CN1227345C (en
Inventor
R·K·帕南迪克
S·L·兰达尔
J·S·利蒂格
E·P·戈塞林克
D·W·比约尔奎斯特
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Procter and Gamble Ltd
Procter and Gamble Co
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Procter and Gamble Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
  • Enzymes And Modification Thereof (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A detergent composition comprising from about 4 % to about 70 % of a surfactant, and from about 0.05 % to about 10 % of a dye maintenance polymer or oligomer having at least three net positive chages per molecule. The dye maintenance polymer should have a Dye Maintenance Parameter, as determined by the Dye Maintenance Parameter Test defined herein, of greater than about 0.23. Further, the dye maintenance polymer is not a polyethyleneimine or alkoxylated derivative thereof.

Description

The laundry detergent composition of the dye maintenance polymer of cation electric charge
Technical field
The present invention relates to the liquid that is used to do washing or the composition of particle form, wherein composition contains the dye maintenance polymer that some have clean positive charge.And provide the stdn test that keeps parameter for arbitrary given polymer determination dyestuff.The composition that contains dye maintenance polymer of the present invention gives the fabric that cleans and textiles with the whole benefit of outward appearance peace the washings that forms from these compositions.
Background of invention
Certainly, this knows, and use and laundering of textile fabrics and textiles (for example threadbare clothes and dress ornament) alternate cycles is with inevitably to the fabric that so uses and wash and the outward appearance and the smooth disadvantageous effect of bringing of textiles.Fabric and textiles are only damaged with use in time.The washing of fabric and textiles must be removed and is deposited on above them in daily use and inner dust and stain., washing operation itself through repeatedly circulation, can make the smooth and outward appearance of these fabrics and textiles worsen.
Fabric is smooth can several modes to be showed with deterioration outward appearance.Mechanical effect staple fibre by washing can come off from the fabric/textile structure of weaving and braiding.These fibers that come off can be formed on observable velveteen on the fabric face, fine hair or " bead ", and influence the new outward appearance of fabric.And the repeated washing of fabric and textiles is particularly with the laundry product that contains SYNTHETIC OPTICAL WHITNER, can remove dyestuff from fabric and textiles, owing to reduce the result of colour intensity, in many cases, owing to change the color of color and deep or light result, produce a kind of threadbare outward appearance of fading.
As previously mentioned, there are a kind of developing needs significantly, promptly recognize and to be added in the laundry product, they are ownly associated mutually with the fabric that washs with this product and the fiber of textiles, thereby the outward appearance degradating trend of the fabric/textile of being washed is alleviated or reduce to minimum material.Certainly, the interpolation material of any cleaning product should be to help the outward appearance of fabric and smooth, and does not have undue disturbance for the ability of desiring to think function that laundry product is finished it.The present invention relates to dye maintenance polymer and in the laundry applications of finishing by the method for this requirement, use and measure the test that the dyestuff of arbitrary given polymkeric substance keeps parameter.
Summary of the present invention
The present invention relates to detergent composition, its composition:
A) from about 4% to about 70% tensio-active agent, it is preferably selected from non-ionic, and is anionic, cationic, amphoteric, property ionic tensio-active agent and composition thereof, even more preferably anion surfactant;
B) from about 0.01% to about 10%, preferably from about 0.1% to about 8%, more preferably from about 0.5% to about 6%, most preferably from about 0.8% to about 5% dye maintenance polymer or oligopolymer, their per molecules have 3 clean positive charges at least, and have the dyestuff that keeps the parameter test to survey by dyestuff and keep parameter greater than about 0.23, be preferably greater than about 0.6, more preferably greater than about 0.8 with most preferably greater than about 0.9.
Dye maintenance polymer is not polymine or its alkoxy derivative
In another aspect of this invention, provide fabric regulating composition, its composition:
A) from about 1% to about 80% fabric-softening actives; With
B) from about 0.01% to about 50%, preferably from about 0.1% to about 40%, more preferably from about 0.5% to about 30%, most preferably from about 0.8% to about 20% dye maintenance polymer or oligopolymer, their per molecules have 3 clean positive charges at least, and have by dyestuff and keep the parameter test determination, and the dyestuff greater than about 0.23 keeps parameter, be preferably greater than about 0.6, more preferably greater than about 0.8 with most preferably greater than about 0.9.
Dye maintenance polymer is not polymine or its alkoxy derivative.
Of the present invention more on the other hand, providing laundry to add composition, its composition:
A) from about 1% water to about 99% (weight meter); With
B) from about 0.01% to about 50%, preferably from about 0.1% to about 40%, more preferably from about 0.5% to about 30%, most preferably from about 0.8% to about 20% dye maintenance polymer and oligopolymer, their per molecules have 3 clean positive charges at least, and have by dyestuff and keep the parameter test determination, and the dyestuff greater than about 0.23 keeps parameter, be preferably greater than about 0.6%, more preferably greater than about 0.8% with most preferably greater than about 0.9.
Dye maintenance polymer is not polymine or its alkoxy derivative.
Except tensio-active agent and dye maintenance polymer of the present invention, laundry detergent composition of the present invention also contains from the organic or inorganic washing assistant of about 0.01% to 80% (weight meter) and other conventional detergent for washing clothes product.
Except fabric softener and dye maintenance polymer of the present invention, the fabric softener composition here also contains the pH regulator agent, other carrier and additive component.
The aqueous solution of dye maintenance polymer of the present invention contains about 0.05% dye maintenance polymer of the present invention to about 50% (by weight), and dissolved fabric treating material and other component in water are as stablizer and pH regulator agent.
Aspect its method, the present invention relates at water lotion, washing or processing fabric and textiles in rinsing liquid or the treatment solution, these washing lotions, rinsing liquid or treatment solution are the detergent composition from any above-mentioned significant quantity, knitting softening compositio, or aqueous solution treatment agent, or make from the individual components of these compositions.In this washing lotion, laundering of textile fabrics and textiles in rinsing liquid and/or the treatment solution, then dry, can give fabric of handling like this and textiles benefit with appearance of fabrics.This benefit can comprise the improvement overall appearance, and bead/fine hair reduces, anti-fading, and improved abrasion resistance, and/or improve kindliness.Determine that astoundingly appearance of fabrics that this peaceful dye maintenance polymer of the present invention gives and smooth benefit are bigger than the benefit that one of two kinds of components of respective amount are reached itself.
Detailed description of the present invention
As what point out, when fabric or textiles are containing the outward appearance and the planarization of the improved fabric in the washing in the solution of dye maintenance polymer of the present invention.Dye maintenance polymer can be by sneaking into detergent composition with them, in the fabric softener and be added in the washing soln, or they is added in the washing soln separately.Dye maintenance polymer this mainly as liquid/or the particle detergent additive introduce, but the present invention is not intended to do this restriction.Below introduce dye maintenance polymer in detail, the detergent composition component is used for the optional composition of this composition and uses these method for compositions.All percentage ratios all by weight except as otherwise noted.
Dye maintenance polymer
Dye maintenance polymer of the present invention can be used in arbitrary the thing washing methods, and uses the benefit of some outward appearances of fabric of these method washings.The outward appearance benefit of this fabric can comprise, for example, improves the overall appearance of the fabric of washing, and reduces the formation of bead and fine hair, prevents to fade, and improves abrasion resistance etc.Dye maintenance polymer that uses in composition of the present invention and method can provide the outward appearance benefit of this fabric, and are having only acceptable few loss or not loss aspect the cleaning function that laundry detergent composition provided of sneaking into these materials.
Be conspicuous for a person skilled in the art, oligopolymer is the molecule that only contains a few monomeric unit, and polymkeric substance contains considerable monomeric unit.For the present invention, oligopolymer is defined as having the molecule that is lower than about 1000 molecular-weight average, and polymkeric substance is the molecule that has greater than about 1000 molecular-weight average.Multipolymer be by 2 kinds or multiple not roughly the same monomer simultaneously or the polymkeric substance or the oligopolymer that are polymerized successively.Multipolymer of the present invention can comprise, for example, and the polymkeric substance or the oligopolymer that obtain from the polymerization of mixtures of multi-functional alkylating agent such as epichlorohydrin and cyclammonium base monomer such as piperazine and another kind of cyclammonium base monomer such as morpholine.
General cationic polymers and their manufacture method are known.For example, the detailed introduction of cationic polymers can be published in Journal of MacromolecularScience.Chemistry, A4 (6), and pp 1327-1417,0ctober finds in the M.Fred Hoover article in 1970.Hoover article complete is presented in this and received for referencial use.Dye maintenance polymer of the present invention, according to the Hoover article, open and embodiment of the present invention can be better understood when reading.
Table A is listed the various dye maintenance polymers of 6 introductions according to this invention, makes the patent application of these polymkeric substance methods and their method of use.Each application complete of listing Table A in is presented in this and all takes in as a reference.
Table A
Exercise question The inventor Date of application Numbering
The fabric of giving this washing provides the laundry detergent composition that contains amino acid based polymkeric substance of outward appearance and smooth benefit People such as Randall 8/8/97 ?PCT/US98 ?/16536
The fabric of giving this washing provides the laundry detergent composition that contains cyclic amine based polymer of outward appearance and smooth benefit People such as Panandiker 9/15/98 ?PCT/US98 ?/19143
The fabric of giving this washing provides the laundry detergent composition that contains amino acid based polymkeric substance of outward appearance and smooth benefit People such as Randall 8/7/98 ?PCT/US98 ?/16495
The laundry detergent composition that contains anion-modified cyclic amine based polymer People such as Panandiker 9/15/98 ?PCT/US98 ?/19141
The detergent for washing clothes and the fabric regulating composition that contain the cyclic amine based polymer of oxidation People such as Panandiker 9/15/98 ?PCT/US98 ?/19144
Table A (continuing)
The laundry detergent composition that contains cyclic amine based polymer and hydrophobically modified carboxy methyl cellulose mixture People such as Panandiker 10/13/98 ?60/103， ?978
Except dye maintenance polymer of the present invention, this detergent for washing clothes and interpolation composition also can comprise common, the washing auxiliary detergent of following more specific definition.Detergent composition of the present invention comprise be selected from non-ionic, anionic, cationic, amphoteric, the tensio-active agent of zwitterionic tensio-active agent and composition thereof.Preferred about at least 4% tensio-active agent (weight meter) is an anion surfactant.
The preferred in the present invention prevailing detergent ingredients that uses comprises: detersive enzyme, preferred cellulose enzyme and preferred a kind of enzyme stabilization system; The inorganic peroxy bleaching compounds, it is preferably selected from the peroxyboric acid an alkali metal salt, percarbonic acid an alkali metal salt and composition thereof, and bleach-activating agent, it preferably the ninth of the ten Heavenly Stems acyloxy benzene sulfonate.Laundry additive composition of the present invention preferably contains pH regulator agent and a kind or various fabrics softening component.
Detergent surfactant
Detergent composition contains from the detergent surfactant of about 4% to 80% (weight meter).Preferred this composition contains from the tensio-active agent of about 5% to 50% (weight meter).Used detergent surfactant can be anionic, non-ionic, zwitterionic, amphoteric or cationic, or the compatible mixture of these types in can quilt.Detergent surfactant has been made introduction: U.S.P.3664961 in following document as used herein, Norris, 1972.5.23 issue, U.S.P.3919678, people such as Laughlin, 1975.12.30 issue, U.S.P.4222905, Cockrell, 1980.9.16 issue and U.S.P.4239659, Murphy, the 1980.12.16 issue, all these patents have all been listed this paper in as a reference.In all surface promoting agent, preferred anionic and non-ionic.
Useful anion surfactant itself can be several dissimilar.For example, the water-soluble salt of higher fatty acid, i.e. " soap " is anion surfactant useful in this composition.This comprises basic metal soap, for example contains big fair 8 to about 24 carbon atoms, and preferably approximately 12 is to the sodium of the higher fatty acid of about 18 carbon atoms, potassium, ammonium and alkylammonium salt.
Other non-soap, the water-soluble salt that comprises organic sulfuric acid reaction product at this anion surfactant that is suitable for, preferred as alkali and ammonium salt have one and contain about 10 alkyl and sulfuric acid or sulfate groups to about 20 carbon atoms in their molecular structure.(" alkyl " speech included be the moieties of acyl group).Valuable especially is the linear straight chain alkylbenzene sulfonate, and wherein the average carbon atom number in alkyl is from about 11 to 13, is abbreviated as C 11-13LAS.
Preferred nonionic is formula R 1(OC 2H 4) nThe tensio-active agent of OH, wherein R 1Be C 10-C 16Alkyl or C 8-C 12Alkyl phenyl and n are from 3 to about 80.Particularly preferably be C 12-C 15Pure and every mol of alcohol is from about 5 condensation products to about 20 moles oxyethane, for example with the C of the about 6.5 moles ethylene oxide condensation of every mol of alcohol 12-C 13Alcohol.
The tensio-active agent that other is suitable comprises polyhydroxy fatty acid amide and amido tensio-active agent, has done introduction in listed the listing in this paper for referencial use 1 or the multinomial common unsettled PCT application of Table A.
Detergent builder
Detergent composition also can contain from the detergent builder of about 0.1% to 80% (weight meter).This composition of preferred liquid form will contain from the builder composition of about 1% to 10% (weight meter).This composition of preferred particulates form will contain from the builder composition of about 1% to 50% (weight meter).Detergent builder is known in the art, can comprise, for example, phosphoric acid salt and various organic and inorganic non-phosphorus builder.
Comprise polyacetic acid at the water-soluble non-phosphorus organic synergistic auxiliary agent of this employing, carboxylic acid, various an alkali metal salts, ammonium salt and the substituted ammonium salt of polycarboxylic and many hydroxyls sulfonic acid.Suitable as used herein many hydroxy acids salt is many acetal carboxylic acids ester, at U.S.P.4144226, (people such as Crutchfield, 1979.3.13 issue) and U.S.P.4144226, (people such as Crutchfield, 1979.3.13 issue) and U.S.P.4246495 (people such as Crutchfield, 1979,3.27. issue) introduction is arranged, it is for referencial use that these two pieces of documents have all been listed this paper in. and particularly preferred multi-carboxylate's builder is oxygen di-succinate and the carboxylate ether builder composition that contains tartrate monobutane diacid ester and the two succinate mixtures of tartrate, in U.S.P.4663071 (people such as Bush, 1987.5.7 issue), introduction is arranged, listed reference at this.
The example of the suitable inorganic builder of non-phosphorus comprises silicate, silico-aluminate, borate and carbonate.Particularly preferably be yellow soda ash and potassium, sodium bicarbonate and potassium, times rice yellow soda ash and potassium, sodium borate decahydrate and potassium and water glass and potassium, its SiO 2With the weight ratio of alkalimetal oxide from about 0.5 to about 4.0, preferably from about 1.0 to about 2.4.Also preferably aluminosilicate salt comprises zeolite.These materials and have in people's such as Corkill U.S.P.4605509 more fully as the purposes of agent builder are introduced, and it is for reference to have listed this paper in.Be suitably in the crystalline layered silicate that uses in the detergent composition of the present invention introduction is also arranged in U.S.P.460559.
Optional detergent component
Except tensio-active agent, outside builder and the dye maintenance polymer, detergent composition of the present invention also can comprise the optional composition of any amount of basic he.They comprise the component of conventional detergent composition, for example enzyme and enzyme stabilizers, profoamer or froth suppressor, anti-dark and gloomy and antiwear agents, SYNTHETIC OPTICAL WHITNER, soil-suspending agent, soil releasing agent, sterilant, pH regulator agent, the alkaline source of non-builder, sequestrant, organic and mineral filler, solvent, hydrotropic agent, white dyes, dyestuff and pigment.
The pH regulator agent the pH of washing soln be higher than about 10.0 some may be essential in using because under than higher pH condition, the smooth benefit of fabric of institute's definitions section compound begins to reduce.Therefore, if after adding dye maintenance polymer of the present invention, the pH of washing soln is greater than about 10.0, and it is about 10.0 to use the pH regulator agent that the pH of washing soln is brought down below so, preferably is lower than approximately 9.5, most preferably is lower than about 7.5.Suitable pH regulator agent it is known to those skilled in the art that.
Any selection component of a kind of preferred adding detergent composition of the present invention is a SYNTHETIC OPTICAL WHITNER, for example peroxygen bleach.This peroxygen bleach can be organic or inorganic in nature.The inorganic peroxy SYNTHETIC OPTICAL WHITNER is usually mixed use with bleach-activating agent.
Useful organic peroxy SYNTHETIC OPTICAL WHITNER comprises percarboxylic acids SYNTHETIC OPTICAL WHITNER and salt thereof.The suitable example of this class reagent comprises six hydration monoperphthalic acid magnesium, partially chlorine peroxybenzoic acid magnesium, 4-nonyl amino-4-oxo perbutyric acid and two peroxide dodecanedioic acid.These SYNTHETIC OPTICAL WHITNER are open in following document: U.S.P.4483781, Hartman, 1984.11.20 issue; European patent application EP-A133354, people such as Banks, 1985.2.20 is open; And U.S.P.4412934, people such as Chung, 1983.11.1 issue.High preferred SYNTHETIC OPTICAL WHITNER comprises that also 6-nonyl amino-6-oxo crosses caproic acid (NAPAA), as introducing in U.S.P.4634551 people such as (, 1987.1.6. issue) Burns.
The inorganic peroxy SYNTHETIC OPTICAL WHITNER also can be used in detergent composition of the present invention, generally with the particulate form.Inorganic SYNTHETIC OPTICAL WHITNER is in fact by preferably.This inorganic peroxy compounds comprises the peroxyboric acid an alkali metal salt and crosses acid alkali metal salt.For example, can use Sodium peroxoborate (for example list or tetrahydrate).Suitable inorganic SYNTHETIC OPTICAL WHITNER also can comprise the peroxyhydrate of yellow soda ash or potassium and " percarbonate " SYNTHETIC OPTICAL WHITNER of equivalence, the peroxyhydrate of trisodium phosphate, the peroxyhydrate of urea, and sodium peroxide.Also can use persulphate SYNTHETIC OPTICAL WHITNER (for example OXONE is made by Du Pont's commercialization).The inorganic peroxy SYNTHETIC OPTICAL WHITNER is usually used silicate, borate, vitriol or water soluble surfactant active's dressing.For example, the percarbonate particles of dressing can be from each commercial source, as FMC, and Solvay Interox, Tokai Denka and Degussa company obtain.
The inorganic peroxy SYNTHETIC OPTICAL WHITNER, perborate for example, percarbonate etc. preferably combine with bleach-activating agent, this can cause (that is to say, using in the process of the present composition for fabric washing/bleaching) in situ generation and the corresponding peroxy acid of bleach-activating agent in the aqueous solution.Various nonrestrictive activator examples have been made introduction: U.S.P4915854 in following document, people such as Mao, 1990.4.10 issue; U.S.P.4412934, people such as Chung, 1983.11.1 issue.Nonanoyl oxygen benzene sulfonate (NOBS) and tetra acetyl ethylene diamine (TAED) activator are typical, preferred.Their mixture also can use.About also the see before U.S.P.4634551. of face reference of other useful here typical SYNTHETIC OPTICAL WHITNER and activator
Other useful acid amides deutero-bleach-activating agent is to have those of following molecular formula:
R ' N (R 5) C (O) R 2C (O) L or R 1C (O) N (R 5) R 2C (O) L is R wherein 1Be to contain about 6 alkyl, R to about 12 carbon atoms 2Be to contain 1 alkylidene group, R to about 6 carbon atoms 5Be hydrogen or alkyl, aryl or contain about 1 to the alkaryl of about 10 carbon atoms and L be any suitable leavings group.Leavings group is the result as the strong hydrolysis negatively charged ion nucleophilic attack on bleach-activating agent of quilt, from the substituted arbitrary group of bleach-activating agent.Preferred leavings group is a sulfophenylate.
The preferred embodiment of the bleach-activating agent of top formula comprises (6-decoyl amido caproyl) oxygen benzene sulfonate; (6-nonanoyl amido caproyl) oxygen benzene sulfonate; (6-caprinoyl amido caproyl) oxygen benzene sulfonate and composition thereof, such as among the U.S.P4634551 of reference in the above introduction.
Another kind of useful bleach-activating agent comprises benzoxazine type activator, and is open by people such as Hodge in the U.S.P.4966723 of 1990.10.30 issue, listed in for reference at this.Also see U.S.P.4548784, Sanderson, 1985.10.8 issue has been listed in for referencely, and it discloses and has been adsorbed the acyl caprolactam that enters Sodium peroxoborate, comprises benzoyl caprolactam.
If use, peroxygen bleach generally will account for about 2% to 30% of cleaning composition weight.More preferably, peroxygen bleach will account for about 2% to 20% of composition weight.Optimum, peroxygen bleach will exist with about amount of 3% to 15% of present composition weight.If use, bleach-activating agent can account for about 2% to 10% of detergent composition weight of the present invention.Usually, activator is use like this, with cause SYNTHETIC OPTICAL WHITNER to the mol ratio of activator from about 1: 1 to 10: 1, more preferably in about 15: 1 to 5: 1 scope.
Other SYNTHETIC OPTICAL WHITNER and bleach-activating agent that is fit to is listed in Table A, has listed in this paper for referencial use one or the multinomial common unsettled PCT application to be disclosed.
Another high preferred component of selection arbitrarily is the detersive enzyme component in detergent composition.For various purposes, comprise and remove protein-basedly from substrate that glycosyl, or triglyceride level base dirt in order to prevent the come off transfer of dyestuff and the recovery of fabric in fabric washing, can comprise enzyme in this detergent composition.Suitable enzyme comprises proteolytic enzyme, amylase, fat (fat) enzyme, cellulase, peroxidase, and the mixture of their any suitable origin thing.For example plant, animal, bacterium, fungi and yeast originates thing.Optimized choice is subjected to the influence of each factor, and for example pH is active and/or stable, best thermostability and to activated detergent, the stability of builder or the like.In this respect, preferred bacterium or fungal enzyme, for example bacterial amylase and proteolytic enzyme, and fungal cellulase.
" detersive enzyme " just as used in this, means have cleaning in laundry detergent composition, removes any enzyme of stain removal or other beneficial effect.For the preferred enzyme of laundry purpose includes, but are not limited to proteolytic enzyme, cellulase, fat (fat) enzyme, amylase and peroxidase.
Enzyme is usually to be enough to the providing level of " cleaning significant quantity " to join in the detergent composition." cleaning significant quantity " speech means and can produce cleaning on substrate such as fabric, decontamination, dust removal soil, brighten, deodorizing or increase arbitrary amount of bright effect, with regard to the practical situation of current commercial preparation, typical amount is about at the most 5 milligrams of every gram detergent composition (weight meter), more typically is 0.01 milligram to 3 milligrams organized enzyme.Explanation is in addition, and the composition here will typically contain from 0.001% to 5%, the commercially available zymin of preferred 0.01%-1% (weight meter).Proteolytic enzyme is usually to be enough to providing every gram composition 0.005 to the active level of 0.1Anson unit (AU) to be present in this commercial preparation.In the detergent formulation of higher concentration, wish higher activity level.
Be included in U.S.P.4435307 at this available cellulase, people such as Barbesgoard, 1984.3.6 and GB-A-2075 028; Those that introduced among GB-A-2095 275 and the DE-OS-2247832.CAREZYME And CELLUZYME (Novo) be useful especially.Also see WO9117243, Novo.
Containing enzyme composition and also can select arbitrarily to contain from about 0.001% to about 10% here, preferably from about 0.005% to about 8%, most preferably from about 0.01% enzyme stabilising system to about 6% (weight meter).The enzyme stabilising system can be any can with the stabilising system of detersive enzyme compatibility.This system can be provided by other prescription activator inherently by the producer of prescription teacher or detersive enzyme, or is added separately.This stabilising system can contain for example calcium ion, boric acid, propylene glycol.The short chain carboxy acid, boronic acid and composition thereof, they are designed to solve the type that depends on detergent composition and the different stable problem of physical form.
The preparation of detergent composition
According to detergent composition of the present invention can be liquid, cream or particle form.These compositions can be by any ordinary method by any suitable order, and concentration is as required mixed basic preparing with optional component.For the front narration of the purposes of defined dye maintenance polymer here is as illustration, and other purposes will be conspicuous for a person skilled in the art, and plan within the scope of the invention.
Particulate composition for example, generally is by mixing basic particulate component, tensio-active agent for example, and builder, water etc. become slurries, and the slurries of spraying drying gained to the level of low residue moisture (5-12%) prepares again.Remaining dry ingredients, the particle of for example basic dye maintenance polymer can mix with spray-dired particle with the particle powder form in the rotation tempering tank.Liquid component, for example basic dye maintenance polymer, enzyme, the solution of builder and spices can be sprayed on the particle of gained to form final detergent composition.According to particulate composition of the present invention also can be " form of compacting ", that is to say that it can have the density more higher relatively than conventional granulates washing composition, promptly from 550 to 950g/l.In this case, will contain " mineral filler salt " than the lower amount of conventional granulates washing composition according to granular detergent composition of the present invention; Typical filling salt is the vitriol and the muriate of alkaline-earth metal, is typically sodium sulfate; " compacting " washing composition does not typically contain and is higher than 10% filling salt.
Liquid detergent composition can mix its basic preparing with optional component by needed concentration according to providing the composition that contains these components desired order.According to liquid composition of the present invention also can be " form of compacting ", in this case, will contain the water of low amount than conventional liq washing composition according to liquid detergent composition of the present invention.Can be by required dye maintenance polymer be sneaked in the solution simply, and dye maintenance polymer is added in liquid washing agent or other aqueous composition of the present invention.
Fabric cleaning process
The present invention also provides a kind of method of laundering of textile fabrics, and the appearance of fabrics that is provided by used here dye maintenance polymer benefit can be provided this method.This method makes these fabrics and forms from the detergent composition of foregoing significant quantity, or the water lotion contact that forms from each component of this composition.Though composition of the present invention also can be used to form cleaning and the processing of not having the immersion aqueous solution that stirs and being used for fabric, but fabric generally is to take place under the condition of stirring with contacting of washing lotion.As discussed above, the pH of preferred washing lotion is less than about 10.0, more preferably about 9.5 and most preferably about 7.5.
For good cleaning, in washing machine, preferably provide stirring.The fabric of preferred washing back dry wet in the drier for clothes of routine.In the rinsing solution of washing machine, the significant quantity of high density liquid or granular detergent composition is preferably from about 500 to about 7000ppm, more preferably from about 1000 to about 3000ppm.
The adjusting of fabric and softening
The dye maintenance polymer as the component of laundry detergent composition of the present invention is introduced in the front, under the situation of detergent surfactant that does not have detergent composition embodiment of the present invention and builder component, also can be used to handle and regulate fabric and textiles.For example, in order to give foregoing desirable appearance of fabrics and smooth benefit, in the rinse cycle that the home laundry of routine is operated, can add fabric regulating composition that contains fabric softener and dye maintenance polymer or the fabric treatment composition that only contains dye maintenance polymer itself, or contain the fabric treatment composition of the aqueous solution of dye maintenance polymer.
Fabric softener composition of the present invention contains about 1% preferably approximately 8% at least, and more preferably from about 20% to about 80% is more preferably about 60%, one or more fabric-softening activator compositions of most preferably about 45% (weight meter).
Preferred fabric-softening activator according to the present invention is the amine with following formula:
Figure A9981439100141
Quaternary ammonium compound with following formula:
Figure A9981439100142
And composition thereof, wherein each R is respectively C 1-C 6Alkyl, C 1-C 6Hydroxyalkyl, benzyl and composition thereof: R 1Be preferably C 11-C 22Linear alkyl, C 11-C 22Branched-alkyl, C 11-C 22The linear chain thiazolinyl, C 11-C 22Alkenyl of branching and composition thereof; Q is independently selected from the carbonyl moiety with unit of following formula:
R wherein 2Be hydrogen, C 1-C 4Alkyl, preferred hydrogen; R 3Be C 1-C 4Alkyl, preferred hydrogen or methyl; Preferred Q has following formula: Or
X -Be the compatibility negatively charged ion of tenderizer, the negatively charged ion of preferred strong acid, for example muriatic, bromide, methyl sulfate base, sulfovinic acid base, sulfate radical, nitrate radical or its mixture, more preferably muriate and methyl sulfate base.Negatively charged ion also can have double charge, but seldom preferred, in this case X (-)Represent group half.The value of exponent m from 1 to 3; The value of index n from 1 to 4, preferred 2 or 3, more preferably 2.
One embodiment of the invention provide a kind of softening activator from the preparation of initial amine methyl (3-aminopropyl) (2-hydroxyethyl) amine for amine and the quaternary amine that per molecule has 2 or a plurality of different index n value.
Preferred softening activator according to the present invention has following formula: Wherein having unit of following formula is the fatty acyl group part.At this
Figure A9981439100155
The suitable fatty acyl group that adopts in the bright softening activator partly derives out from following triglyceride level source: tallow, and vegetables oil and/or partially hydrogenated vegetables oil, particularly including Tower rape oil, Thistle oil; peanut oil, sunflower oil, Semen Maydis oil; soybean oil, tallol, Rice pollard oil.Diester quat (DEQA ' S) more preferably, wherein exponent m equals 2.
The physics and the performance that depend on needed final fabric-softening activator, the prescription teacher can select the source of said fatty acyl group part above any, and perhaps the source that teacher of the prescription can mixed triglyceride forms " mixing of customization ".The technician in fat and oily field generally acknowledges, as under the plant oil condition, the composition of fatty acyl group can be from the crop to the crop, or the kind of originating from the kind in vegetables oil source to vegetables oil and changing.Employing is preferred from the DEQA ' S of the lipid acid preparation of natural source.
The preferred embodiments of the invention provide contain about at least 3%, preferably about at least 5%, more preferably about at least 10%, at least about 15%C most preferably 11-C 22The R of alkenyl 1The unit comprises polyalkenyl (polyunsaturated) unit, and is particularly oleic, linoleic, linolenic softening activator.
For purpose of the present invention; " combination chain fatty acyl group unit " speech is defined as " comprise and have 10-22 the carbon atom that comprises carbonylic carbon atom; under the situation of alkenyl chain; 1-3 two key arranged, and preferably all two keys are in the alkyl of cis-configuration and the unitary mixture of fatty acyl group of alkenyl chain ".For R of the present invention 1The unit, the fatty acyl group of preferred at least 1 sizable per-cent is undersaturated, and is for example about 25%, preferably approximately 50% is to about 70%, preferably approximately 65%.The aggregate level that contains the fabric-softening activator of polyunsaturated fat acyl group can be about 3%, preferably approximately 5%, and more preferably about 10% to about 30%, preferably approximately 25%, more preferably about 18%.As described above, cis/and trans-isomer(ide) all can be used, preferably suitable/reverse proportionality is 1: 1, preferably at least 3: 1, more excellent about 4: 1 to about 5: 1, more preferably about 20: 1, still, minimum was 1: 1.
At tallow; cassava, or contained unsaturated level can be measured by the iodine number (IV) of corresponding lipid acid in other fatty acyl group cellular chain, in this case; the compound iodine number of being distinguished for two classes should have IV and be below or above 25 preferably in the scope of 5-100.
In fact, for compound with following formula from the beef fat fatty acid derived,
Figure A9981439100161
When iodine number is 5-25, during preferred 15-20, have been found that suitable/trans isomer weight ratio greater than about 30/70, be preferably greater than about 50/50 and provide optimum concentrating capacity more preferably greater than about 70/30.
For this compounds that the tallow fatty acids that is higher than 25 from iodine number is made, the ratio that has been found that suitable/trans isomer is not critical, unless need very high concentration.An embodiment that is more preferably of the present invention includes DEQA ' S, wherein R 1Average iodine number be about 45.
The R that uses in isotropic liquid of the present invention suits 1The unit is further characterized in that the iodine number of maternal fatty acid, and said IV is preferably from about 10, more preferably from about 50, most preferably from about 70 to about 140, preferably to about 130, more preferably to about 115.Teacher of the prescription can want to add a certain amount of fatty acyl group unit with top listed scope iodine number in addition according to embodiment of the present invention that they select to go to implement.For example, " hardened material " (IV is less than or equal to about 10) can combine with the source of fatty acid mixt and regulate the characteristic of last softening activator.
The fatty acyl group unit particularly has side chain, and for example " Guerbet side chain ", the fat that methyl, unit such as ethyl replace along the primary alkyl chain is in unitary preferred source, and the unitary synthetic source of fatty acyl group also suits.For example, the prescription teacher can want to add one or more on the position of " non-natural existence ", for example at C 17On the 3rd carbon of chain, a methyl ramose fat fatty acyl group unit is arranged.The implication of " non-natural existence " speech is herein, and " the acyl group unit that exists with tangible amount (greater than about 0.1%) is not as raw material, the common fats in the source of triglyceride level described herein and oil.If " needed side chain fatty acyl group unit can not obtain by calm facile natural matter, and so, synthetic lipid acid just can suitably mix with other synthetic materials or with the triglyceride level in other natural deutero-source, acyl group unit.
It below is the example that preferably softens activator according to the present invention.
N, N-two (tallow base-oxygen ethyl)-N, N-dimethyl oxidation ammonium;
N, N-two (canola oil base-oxygen ethyl)-N, N-dimethyl oxidation ammonium;
N, N-two (tallow base-oxygen ethyl)-N-methyl, N-(2-hydroxyethyl) sulfate methyl ammonium;
N, N-two (canola oil base-oxygen ethyl)-N-methyl, N-(2-hydroxyethyl) methylsulfuric acid ammonium;
N, N-two (tallow base-acyl aminoethyl)-N-methyl, N-(2-hydroxyethyl) methylsulfuric acid ammonium;
N, N-two (2-tallow oxygen base-2-oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (2-canola oil base oxygen-2-oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (2-tallow oxygen base ethyl carbonyl oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-two (2-hangs down Jie's sauerkraut seed oil base oxygen ethyl carbonyl oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-(2-tallow oxygen base-2-ethyl)-N-(2-tallow oxygen base-2-oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N-(2-canola oil base oxygen-2-ethyl)-N-(2-canola oil base oxygen-2-oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride;
N, N, N-three (tallow base-oxygen ethyl)-N-ammonio methacrylate;
N, N, N-three (canola oil base-oxygen ethyl)-N-ammonio methacrylate;
N-(2-tallow oxygen base-2-oxygen ethyl)-N-(tallow base)-N, the N-alkyl dimethyl ammonium chloride;
N-(2-canola oil base oxygen-2-oxygen ethyl)-N-(canola oil base)-N, the N-alkyl dimethyl ammonium chloride;
1,2-two tallow oxygen base-3-N, N, N-trimethylammonium amido propane chloride; With
1,2-two canola oil base oxygen-3-N, N, N-trimethylamine groups propane chloride; And the mixture of above-mentioned activator.
Particularly preferably be N, N-two (tallow base-oxygen ethyl)-N, the N-alkyl dimethyl ammonium chloride, wherein the tallow chain is undersaturated to small part, and N, N-two (canola oil base-oxygen ethyl)-N, the N-alkyl dimethyl ammonium chloride, N, N-two (tallow base-oxygen ethyl)-N-methyl, N-(2-hydroxyethyl) methylsulfuric acid ammonium; N, N-two (canola oil base-oxygen ethyl)-N-methyl, N-(2-hydroxyethyl) methylsulfuric acid ammonium; And composition thereof.
Other has made introduction: U.S.5643865 at this useful fabric softener in following document, people such as Mermelstein, 1997.7.1 issue; U.S.5622925, people such as de Buzzaccarini, 1997.4.22. issue; U.S.5545350, people such as Baker, 1996.8.13. issue; U.S.5474690, people such as Wahl, 1995.12.12 issue; U.S.5417868, people such as Turner, 1994.1.27 issue; U.S.4661269, people such as Trinh, 1987.4.28 issue; U.S.4439335, Burns, 1984.3.27. issue; U.S.4401578, Vetburggen, 1983.8.30. issue; U.S.4308151, Cambre, 1981.12.29 issue; U.S.4237016, Rudkin issue, 1978.10.27 issue; U.S.4233164, Davis, 1980.11.11 issue; U.S.4045361, people such as Watt, 1977.8.30 issue; U.S.3974076, people such as Wiersema, 1976,8.10 issues; U.S.3886075, Bernadino, 1975.5.6 issue; U.S.3861870, people such as Edwards, 1975.1.21 issue; European patent application publication No. 472178, people such as Yamamura, it is for referencial use that all described documents have all been listed this paper in.
Embodiment
Following examples explanation the compositions and methods of the invention, but be not intended to restriction or limit scope of the present invention in addition.
Example I
Dyestuff keeps the parameter test
In order to estimate dye maintenance polymer, the 10ppm solution of preparation dye maintenance polymer in water.This solution of 800ml is added in the 1000ml beaker.In solution, introduce 8gm+/-(C110 is with directly black (Direct Black) 112 painted poplin cloth fabrics for the C110 fabric of 50mg, by Empirical Manufacturing Company of Cincinnati, the OH supply) swatch, so that it is immersed in the liquid fully.Leniently stirred 120 minutes with magnetic stirring bar.From the part dyestuff of fabric slowly in the water leaking-in.After 120 minutes, get the aliquots containig of this liquid, it is put into the cell of 5cm path length, and with HewlettPackard Model 8453 UV-Vis spectrophotometers, the working instructions of this instrument that provides according to manufacturing firm are measured its absorbancy (Abs) at the 600nm wavelength.This absorbancy is called Abspolymer.(Abs polymkeric substance).
The step that employing is listed above repeats this step with the independent distilled water that does not add dye maintenance polymer and obtains Abswater (Abs water).
Dyestuff is protected special parameter (" DMP ") and is defined as (Abswater-Abspolymer).
Example II
The calculating of per molecule mean charge
There is many analysis fields method known to the skilled to go to calculate the electric density of polymer materials.One of method is as follows.Particularly, for the molecule of known chemical structure, electric density provides the ratio of electric charge to quality by the acid base titration or the potentiometric titration of standard.Pass through to measure the molecular-weight average of this material then, and, remove electric density, thereby electric density is converted into the mean charge of per molecule with molecular-weight average in order to determine the average positive changes of per molecule.
For low-molecular-weight material, molecular weight by standard technique for example mass spectroscopy measure.For polymeric material, molecular weight is measured by gel permeation chromatography.These methods are being analyzed for example Willard of textbook, and Merritt has introduction among " instrument analytical method " (Instrumental Methods of Analysis) of Dean and Settle work.
EXAMPLE III
Table III comprises the comparison example according to many examples of the present invention and some known materials in detergent for washing clothes field.Listed chemical structure is an ideal structure in the example below.The side reaction that expectation occurs in condensation course does not illustrate.
Table III
Figure A9981439100201
Figure A9981439100211
28 PAH ????1.08
29 Poly-(vinyl-amine-altogether-vinyl formamide) (ratio 1: 1)
30 Each N-H polyvinylamine of 0-5 moles of ethylene oxide ethoxylation
31 Each N-H is with 0.5 mole of five propenoxylated polyvinylamine of alkane
32 The condensation affixture of guanidine and diethylenetriamine is sold with trade(brand)name Tinofix ECO by company of Ciba special chemical article company (Basel Switzerland)
33 The condensation affixture of guanidine and diethylenetriamine is sold with trade(brand)name Sandofix WE by Clariant (Basel Switzerland) ?????0.97
34 Polyquaternium 2 (CTFA nomenclature) is sold with trade(brand)name Mirapol A15 by Luo Na-Planck (crust claims, France) ?????1.11
35 Polyquaternium 17 (CTFA nomenclature) is sold with trade(brand)name Mirapol AD-1 by Luo Na-Planck (crust claims, France)
36 N-ethylene methacrylic yl pyridines-altogether-vinyl pyridine (ratio 4: 1) multipolymer ?????0.99
37 N-ethylene methacrylic yl pyridines-altogether-vinyl pyridine (ratio 4: 6) multipolymer ?????1.13
38 Poly-(N-ethylene methacrylic yl pyridines-altogether-vinyl pyridine N-oxide compound) (ratio 4: 1) ?????0.96
39 Poly-(N-ethylene methacrylic yl pyridines-altogether-vinyl pyridine N-oxide compound) (ratio 4: 6) ?????0.65
Comparison example
40 Ethoxylation tetren, example are from Vandermeer, and U.S.P. 4,597, and 898
?41 Each N-H is with the polyethylene imine based MW1200 of 1 moles of ethylene oxide ethoxylation, and example is from Watson, U.S.P.5,565,145 ????-0.27
?42 Each N-H is with the polyethylene imine based MW1200 of 7 moles of ethylene oxide ethoxylations, and example is from Watson, U.S.P.5,565,145 ????-0.35
?43 Each N-H is with the polyethylene imine based MW600 of 20 moles of ethylene oxide ethoxylations, and example is from Ghosh, U.S.P.5,854,949 ????-0.07
?44 Each N-H is with the polyethylene imine based MW1200 of 7 moles of ethylene oxide ethoxylations, 9.5% methyl quaternary ammonium example is from Ghosh, U.S.P.5,854,949 ????0.09
?45 Poly-(vinyl pyridine N-oxide compound), example be from Fredj, U.S.P.5,783548 ????0.03
?46 Poly-(vinyl pyrrolidone), commercialization material can be from the world extraordinary Products Co., Ltd (Wayne NJ) obtains
?47 Poly-(vinyl pyrrolidone-altogether-vinyl imidazole), example be from Busch, U.S.P.5,710,119
?48 Poly-(the amino hexanolactam of e--altogether-hexanolactam), sell with trade(brand)name Nylon AQ A90 by Toray (Japan) ????-0.09
EXAMPLE IV
Containing one or more several heavy loading granular detergent compositions that have according to the dye maintenance polymer of DMP of the present invention is produced.These granular detergent compositions all have following basic recipe:
Table IV
Composition weight %
C 12Linear alkyl benzene sulfonate 9.31
C 14-C 15Alkyl oxide (0.35EO) sulfuric ester 12.74
Zeolite builder 27.79
Sodium carbonate 27.31
PEG4000??????????????????????????????????1.60
Dispersion agent 2.26
C 12-13Alcohol ethoxyquin base thing (9EO) 1.5
Sodium peroxoborate 1.03
Soil release polymers 0.41
Enzyme 0.59
Dye maintenance polymer 3.0
Spices, whitening agent, froth suppressor, other is composition in a small amount,
Moisture, sulfate balance
100％
EXAMPLE V
The preparation of liquid washing agent subject composition
Containing a kind or the multiple several heavy loading liquid detergent compositions that have according to the dye maintenance polymer of DMP of the present invention is produced.These liquid detergent compositions all have following basic recipe:
Table V
Composition weight %
C 12-15Alkyl oxide (2.5) vitriol 38
C 12Glucamide 6.86
Citric acid 4.75
C 12-14Lipid acid 2.00
Enzyme 1.02
MEA???????????????????????????????1.0
Propylene glycol 0.36
Borax 6.58
Dispersion agent 1.48
Toluenesulfonic acid sodium salt 6.25
Dye maintenance polymer 1.0
Dyestuff, spices, the whitening agent sanitas, foam formulations,
Other is composition in a small amount, water balance
100％
Example VI
The preparation of granulated detergent subject composition
Containing a kind or the multiple several heavy loading particle cleaning composition that have according to the dye maintenance polymer of DMP of the present invention is produced.These granular detergent compositions all have following basic recipe:
Table VI
% is to weight/power ratio % for component example weight
C 12LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium 9.40 9.40
C 14-C 15Alkyl sodium sulfonate 11.26 11.26
Zeolite builder 27.79 27.79
Yellow soda ash 27.31 27.31
PEG4000???????????????????????1.60?????????????1.60
Dispersion agent, sodium polyacrylate 2.26 2.26
C 12-13Alkylethoxylate (E9) 1.5 1.5
Sodium peroxoborate 1.03 1.03
Dye maintenance polymer 0.8 0
Other supplementary component balance balance
100％????????????100％
Example VII A
Containing a kind or the multiple several fabric softening compositions that have according to the dye maintenance polymer of DMP of the present invention is produced.This fabric softening compositions has any following basic recipe:
Table VII a
Weight %
Composition ????1 ????2 ????3 ????4 ????5 ????6
Softening activator 1 ????24.0 ????- ????- ????- ????- ????25.0
Softening activator 2 ????- ????- ????19.2 ????- ????- ????-
Softening activator 3 ????- ????- ????- ????- ????18.0 ????-
Softening activator 4 ????- ????11.0 ????- ????4.0 ????- ????-
Softening activator 5 ????- ????13.5 ????- ????- ????- ????-
Softening activator 6 ????- ????- ????- ????3.4 ????- ????-
Dye maintenance polymer ????0.5 ????0.5 ????1.0 ????2.0 ????3.0 ????5.0
Ethanol ????4.0 ????5.0 ????- ????1.0 ????- ????4.0
Virahol ????- ????- ????3.0 ????- ????6.0 ????-
Colour protecting agent 10 ????2.5 ????3.0 ????3.0 ????3.0 ????4.0 ????-
Calcium chloride ????2.0 ????0.5 ????0.2 ????0.05 ????0.5 ????0.6
Hydrochloric acid ????0.75 ????- ????0.06 ????0.2 ????0.02 ????0.05
Soil releasing agent 11 ????0.5 ????- ????0.2 ????- ????0.5
Polyamines 12 ????1.0 ????1.0 ????1.5 ????1.5 ????2.0 ????2.0
The froth breaking siloxanes ????0.01 ????- ????0.01 ????0.01 ????- ????0.01
Other ????1.4 ????1.0 ????0.7 ????0.4 ????1.0 ????1.3
Water Balance Balance Balance Balance Balance Balance
1.N, N-(tallow base-oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride (the tallow base has I.V. value 50).
2.N, N-two (tallow base-oxygen ethyl)-N, N-dimethyl ammonium (the tallow base has I.V. value 18).
3.1,2-two tallow oxygen base-3-N, N, N-trimethylamine groups oxidation of propane thing.
4. two tallow dimethyl ammonium chlorides.
5. two (tallow amido-ethyl)-2-hydroxyethyl methylsulfuric acid ammoniums of methyl.
6.1-tallow amido-ethyl-2-imidazolidine.
10.N, N, N ', N '-four (2-hydroxypropyl) quadrol.
11. dimethyl terephthalate (DMT), 1,2-propylene glycol, the PEG polymkeric substance of methyl blocking.
12.N, N '-two (3-aminopropyl)-1,3-propylene diamine.
Table VII b
Weight %
Composition ????7 ????8 ????9 ????10
DEQA 1 ????26.0 ????25.7 ????- ????30.0
MAQ 2 ????- ????- ????26.0 ????-
Dye maintenance polymer ????0.5 ????1.0 ????2.0 ????5.0
Ethanol ????2.2 ????2.4 ????2.2 ????2.6
Hexylene glycol ????2.6 ????2.3 ????2.6 ????2.6
1, the 2-hexylene glycol ????17.0 ????- ????17.0 ????-
TMPD 6 ????- ????11.9 ????- ????12.0
CHDM 7 ????- ????5.0 ????- ????48.1
Water ????52.5 ????53.6 ????52.5 ????48.1
The a small amount of composition 8 Balance Balance Balance Balance
1.N N-two (canola oil base oxygen-ethyl)-N-2-hydroxyethyl-N-methylsulfuric acid ammonium can obtain from Witco company.
2. single Canolyl trimethyl ammonium chloride is as Adogen 417 Can obtain from Witco company.
6.N, N '-(3-aminopropyl) quadrol.
7.N, N '-(3-aminopropyl) butanediamine.
8. tri propylidene tetramine.
9. neopentyl glycol can obtain from Eastman Chemical.
10.1 the 4-cyclohexanedimethanol can obtain from Eastman Chemical.
11. composition can comprise spices, dyestuff, acid, sanitas etc. in a small amount.
Example VII A I
The aqueous treatment preparation of compositions
Containing a kind or the multiple several aqueous treatment compositions that have according to the dye maintenance polymer of DMP of the present invention prepares.This treatment compositions can have any following basic recipe:
Table VIII
Weight %
Composition ????1 ????2 ????3 ????4 ????5
The cationic dyestuff fixing agent 2 ?- ?3.00 ????- ?- ?-
Hydrophobic dispersion agent 3 ?25.00 ?10.00 ?15.00 ?- ?-
Hydrophobic dispersion agent 4 ?- ?- ?- ?10.00 ?-
Hydrophobic dispersion agent 5 ?- ?- ?- ?- ?50.00
Scale inhibitor 6 ?1.00 ?- ?- ?1.00 ?-
Scale inhibitor 7 ?- ?- ?- ?- ?2.00
Enzyme 8 ?- ?0.50 ?- ?- ?-
Polyamines 9 ?10.00 ?20.00 ?5.00 ?- ?-
Dye maintenance polymer ?0.5 ?3.0 ?2.0 ?10.0 ?7.0
Spices ?0.15 ?0.40 ?0.10 ?0.15 ?0.15
The a small amount of composition Balance Balance Balance Balance Balance
1.N, N-(canola oil base-oxygen ethyl)-N-methyl-N-(2-hydroxyethyl) methylsulfuric acid ammonium.
2. be selected from REWIN SRF, REWIN SRF-O and REWIN DWR are from CHT-Beitlich GMBH.
3. the polyalkylene imine that has molecular weight 1800 and the average ethoxylation of each skeleton nitrogen about 4.
4. the polyalkylene imine that has molecular weight 1800 and the average ethoxylation of each skeleton nitrogen about 1.
5. the polyalkylene imine that has molecular weight 1800 and the average ethoxylation of each skeleton nitrogen about 7.
6. hydroxyl ethane bisphosphonates (HEDP).
7.BAYHIBIT AM is from Bayer.
8. suitable enzyme comprises cellulase, fat (fat) enzyme, and proteolytic enzyme, peroxidase, and composition thereof.
9.N, N '-two (propylidene amino)-1,4-piperazine.

Claims (9)

1. detergent composition, it contains:
A) from about 4% to about 70% tensio-active agent,
B) from about 0.01% to about 10%, preferably from about 0.1% to about 8%, more preferably from about 0.5% to about 6%, most preferably from about 0.8% to about 5% dye maintenance polymer or oligopolymer, their per molecules have 3 clean positive charges at least, and have by dyestuff and keep the parameter test determination, greater than about 0.23, be preferably greater than approximately 0.6, more tomahawk's choosing is greater than about 0.8 with most preferably greater than about 0.9 dyestuff maintenance parameter; Wherein dye maintenance polymer is not polymine or its alkoxy derivative.
2. composition is added in a laundry, and it contains:
A) from about 1% water to about 99% (weight meter); With
B) from about 0.01% to about 50%, preferably from about 0.1% to about 40%, more preferably from about 0.5% to about 30%, most preferably from about 0.8% to about 15% dye maintenance polymer or oligopolymer, its per molecule has 3 clean positive charges at least, and has as keep the parameter test determination by dyestuff, greater than about 0.23, be preferably greater than about 0.6, more preferably greater than about 0.8 with most preferably keep parameter greater than about 0.9 dyestuff; Wherein dye maintenance polymer is not polymine or its alkoxy derivative.
3. composition is added in the laundry of claim 2, and wherein composition further contains pH regulator agent and a kind or various fabrics softening component.
4. the detergent composition of claim 1, wherein composition further contains detersive enzyme and preferably contains the enzyme stabilising system.
5. the detergent composition of claim 1, wherein composition also contains the inorganic peroxy bleaching compounds, and it is preferably selected from peroxyboric acid, an alkali metal salt of percarbonic acid and composition thereof, and bleach-activating agent, it is preferably nonanoly acyloxy benzene sulfonate.
6. the detergent composition of claim 1, wherein composition further contains cellulase.
7. the detergent composition of claim 1, wherein tensio-active agent is selected from nonionic, negatively charged ion, positively charged ion, amphoteric, zwitterionic tensio-active agent and composition thereof.
8. the detergent composition of claim 1, the tensio-active agent of wherein about at least 4% (weight meter) is an anion surfactant.
9. fabric regulating composition, it contains:
A) from about 1% to about 80% fabric-softening activator;
B) from about 0.01% to about 50%, preferably from about 0.1% to about 40%, more preferably from about 0.5% to about 30%, most preferably from about 0.8% to about 20% dye maintenance polymer or oligopolymer, their per molecules have 3 clean positive charges at least, and have as keep the parameter test determination by dyestuff, greater than about 0.23, be preferably greater than about 0.6, more preferably greater than about 0.8 with most preferably keep parameter greater than about 0.9 dyestuff; Wherein dye maintenance polymer is not polymine or its alkoxy derivative.
CNB99814391XA 1998-10-13 1999-10-13 Lundry detergent compositions with cationically charged dye maintenance polymer Expired - Fee Related CN1227345C (en)

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