CN1278294A

CN1278294A - Bleaching compositions

Info

Publication number: CN1278294A
Application number: CN 98810832
Authority: CN
Inventors: S·J·马森; L·P·M·格里派; N·E·格迪拉; D·R·布朗; M·F·梅莱
Original assignee: Procter and Gamble Co
Current assignee: Procter and Gamble Co
Priority date: 1997-09-11
Filing date: 1998-06-12
Publication date: 2000-12-27
Anticipated expiration: 2018-06-12
Also published as: JP2001515952A; CA2303769A1; CN1155687C; EP1015539A1; AU8071198A; EP1015539A4; BR9812446A; WO1999013037A1

Abstract

Granular detergent compositions and in particular low density, phosphate containing detergent compositions comprise a specific bleaching system containing hydrophobic peracid bleach and hydrophilic peracid bleach and a peroxide source. These detergent compositions have specific low levels of available oxygen from hydrophobic aid hydrophilic peroxyacid bleach, specific ratios of available oxygen from the hydrophobic peracid bleach to the hydrophilic peracid bleach and specific ratios of available oxygen of the peroxide source to the available oxygen of the peracids. These specific mixed bleach systems are useful for sanitization or reduction of bacterial activity.

Description

Bleaching composition

Invention field

The present invention relates to be applicable to the composition that contains SYNTHETIC OPTICAL WHITNER in the clothes washing method.

Background of invention

In the past few decades, research work is can get on except that the bleach system based on organic peroxide acid of spot and/or dirt from fabric effectively under low wash temperature at exploitation.Organic peroxide acid is normally crossed hydrolysis on the spot by organic peroxide acid bleach precursor compound (bleach-activating agent) and is obtained.

Normally used precursor compound is tetraacetyl ethylene diamine (TAED), and it has effective hydrophilic cleaning force, particularly to the beverage spot.In order to make washing composition realize effective bleaching power, hydrophobic and hydrophilic spot all needs to be bleached by bleach system.Therefore also having developed the organic peroxy acid precursor in addition handles hydrophobic spot and dirt.There are various documents to disclose in washing composition the mixture that uses hydrophobic and hydrophilic SYNTHETIC OPTICAL WHITNER, JP7-238298 for example, DE196,16,782, WO94/28103.

Yet, the inventor finds that the bleaching composition of most prior art is when using under adverse environmental factor, for example cold washing, at washing under the limited stirring, the detergent active of using low amount, highly polluted fabric, have high-load metal ion or after storing under humidity or the high temperature, work not always satisfactoryly.These problems particularly occur in the low density detergent, and particularly when the total amount of the bleach system in the detergent composition was hanged down, these problems also occurred in the washing composition that contains a large amount phosphate builders, and this washing composition can be introduced metal ion in washing.

In addition, in order to obtain effective bleach system, this bleach system should can provide excellent bleaching power under low levels, reduces the possibility of damage fabric thus.

Therefore, need provide the detergent composition that comprises the low levels bleach system, it all has very effective bleachability to hydrophobic and hydrophilic dirt under adverse environmental factor.

The inventor now finds to contain the bleaching power that the low bleaching composition of measuring bleach-activating agent and peroxide source can obtain the improvement under adverse environmental factor by use amazedly, be that described bleaching composition has the available oxygen (AvO) that obtains from hydrophobic and hydrophilic bleach-activating agent and is lower than 5000ppm and has hydrophobic activation agent AvO and the specified proportion of hydrophilic activator AvO, promptly 3: 1-1: 50, and the specified proportion with total AvO and activator AvO is promptly greater than 2: 1.Found that this bleach system is specially adapted to also be applicable in the washing methods that uses the lower concentration washing composition in low density detergent, hand washing washing composition, the phosphatic composition.

Generally, known SYNTHETIC OPTICAL WHITNER, particularly hypochlorite bleaching can killing bacterias.Usually need high-load SYNTHETIC OPTICAL WHITNER to reduce bacterium or elimination bacterium fully.Therefore, comprise most of washing composition of bleach system well known in the prior art, the SYNTHETIC OPTICAL WHITNER that it only comprises low amount can not be effective as the disinfectant biocides.

The inventor finds to comprise hydrophobic, the hydrophilic bleaching additive of certain content and ratio and the mixed bleach system of peroxide source is very useful as biocides.

They find in washing soln or washing composition or clean-out system even use the specific bleaching composition of low amount effective sterilization is provided also can for the fabric or the surface of washing, maybe when using the bleaching component by above-mentioned specified proportion, can reduce bacterium effectively.

The relevant portion of all documents of quoting is in this manual quoted for referencial use at this paper.

Summary of the invention

The present invention relates to the detergent composition that density is 330 grams per liters-700 grams per liter, it comprises and contains bleach system hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or peracid bleach precursor and peroxide source, the total amount that it is characterized in that the available oxygen (AvO-a) that obtains from hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or bleach precursor is lower than 5000ppm, the available oxygen of hydrophobic peracids or precursor (AvO-hb) is 3 with the ratio of the available oxygen (AvO-hp) of hydrophilic peracid or precursor: 1-1: 50, and the available oxygen of peroxide source (AvO-o) was at least 2: 1 with the ratio of AvO-a.

Detailed Description Of The Invention

In detergent composition of the present invention, the total amount of the available oxygen (AvO-a) that obtains from hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or bleach precursor is lower than 5000ppm, or even be lower than 4000ppm, or even be lower than 3000ppm, or even be lower than 2500ppm.

The ratio of the available oxygen (AvO-hp) of the available oxygen of hydrophobic peracids or precursor (AvO-hb) and hydrophilic peracid or precursor is 3: 1-1: 50, more preferably 2.5: 1-1: 30, or even 2: 1-1: 20.

The ratio of the available oxygen of peroxide source (AvO-o) and AvO-a was at least 2: 1, and preferably at least 3: 1, or even 4: 1.

Said composition preferably has density 370-700 grams per liter, or even to 650 grams per liters, or even to 600 grams per liters.

Preferred said composition is the low-density particles composition, particularly phosphatic composition, particularly highly foaming composition, immersion or pretreatment compositions, hand washing composition.

Therefore, the invention still further relates to and wash by hand the method for washing clothes or pre-treatment or immersion clothes, wherein use according to detergent composition of the present invention.

The invention still further relates to and use bleaching composition to reduce the activity of bacterium, this bleaching composition comprises hydrophobic and hydrophilic peracid SYNTHETIC OPTICAL WHITNER or its precursor and peroxide source, wherein the ratio of AvO-hb and AvO-hp is 3: 1-1: 50, preferred 2.5: 1-1: 10, even 2: 1-1: 20, wherein the ratio of AvO-o and AvO-a is at least 2: 1, preferably at least 3: 1, or even 4: 1.

" reduce bacterium activity " when when this paper uses, and comprises killing bacteria or part bacterium and suppresses further growth or the growth of bacterium.

Preferred this bleaching composition is to be used to sterilize fabric or surface with this bleaching composition cleaning.Then preferred, this sterilization method comprises fabric or the surface of containing bacterium with the said composition contact, and described bacterium particularly is present in the bacterium in fabric or the lip-deep spot.Therefore, the present invention also comprises the method for the fabric of sterilizing, wherein the solution of fabric with composition or composition is contacted, described composition comprises hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or its precursor and peroxide source, the available oxygen (AvO-hb) that is characterised in that hydrophobic peracids or precursor is 3 with the ratio of the available oxygen (AvO-hp) of hydrophilic peracid or precursor: 1-1: 50, and the available oxygen of peroxide source (AvO-o) was at least 2: 1 with the ratio of the total amount of the available oxygen (AvO-a) that obtains from hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER.

This bleaching composition preferably is present in the cleaning combination that is used for cleaning fabric or surface, preferably in laundry or dishwashing detergent or the hard surface cleaner.The laundry detergent composition that preferably comprises component described herein.

Preferably contain bleaching composition and be used for reducing the cleaning combination of bacterial activity or the amount of the AvO-a of detergent composition or its solution preferably is up to 10000ppm, more preferably be up to 5000ppm, or even 4000ppm, or even 3000ppm or 2500ppm.

Hereinafter describe preferred hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or its precursor and preferred peroxide source.Hydrophobic and hydrophilic peracid or peracid precursors

The essential feature of detergent composition of the present invention is hydrophobic peracids or its precursor.

This bleach system preferably comprises hydrophobic percarboxylic acids and/or its precursor of following formula:

R ¹-CO ₃M is R wherein ¹Have at least 6 carbon atoms, M is a counter ion; Or following formula:

R ¹-CO-L wherein L is and the R with Sauerstoffatom ¹The leavings group that-CO-group links to each other, R ¹Have at least 6 carbon atoms.Preferred leavings group is phenylformic acid and its derivative, particularly benzene sulfonate.

The percarboxylic acids bleach precursor is the compound that generates percarboxylic acids in crossing hydrolysis reaction with hydroperoxidation.

The counter ion M of percarboxylic acids is sodium, potassium or hydrogen preferably.

The parent carboxylic of preferred this hydrophobic peracids or its precursor has that micelle-forming concentration is lower than 0.5 mol and wherein said micelle-forming concentration is to measure in 20 ℃-50 ℃ the aqueous solution.

Percarboxylic acids, preferably the percarboxylic acids that is formed by precursor preferably contains at least 7 carbon atoms, or at least 8 or even 9 carbon atoms, preferably it contains 7-12 carbon atom, more preferably 8-11 carbon atom, most preferably 9 or 10 carbon atoms.Aspect preferred, percarboxylic acids that is formed by precursor or peroxy acid have and contain at least 7 carbon atoms, more preferably at least 8 carbon atoms, the most preferably alkyl chain of 9 carbon atoms.

Peroxycarboxylic acid precursors can be the described any ester that is used for detergent for washing clothes as bleach-activating agent; alkyl peroxycarboxylic acid precursors for example described herein, sugar ester be penta-acetyl glucose, imido-ester for example triacetyl cyanurate and tri-benzoyl cyanurate of benzo imido acid ethyl ester, three acyl group cyanurates for example for example, and this ester can produce the active oxidation products of apparent surface and for example be described in C among GB-A-864798, the GB-A-1147871 _8-18Alkanoic acid or aralkyl acid, this ester is described among EP-A-98129 and the EP-A-106634.

Preferably can be C _14-22Two diester of the phenyl ester of alkanoic acid or alkenoic acid, the ester of oxyamine, rudimentary alkanoic acid and two glycol, for example be described among the EP-A-0125781 those, particularly 1,1,5-nitrilotriacetic base penta-4-alkene and 1,1,5,5-tetrem acidic group pentane and corresponding butylene and butane compound, ethylidene benzoic ether acetic ester and two (ethylidene acetate) adipic acid ester and the enol ester for example in EP-A-0140648 and EP-A-0092932, described.

Other highly preferred hydrophobic alkyl peroxycarboxylic acid precursors comprises caprinoyl aminobenzoic acid or its salt, dodecane acyl-oxygen base benzene sulfonic acid sodium salt or sylvite, last of the ten Heavenly stems acyloxy benzene sulfonic acid sodium salt or sylvite (DOBS), benzoyloxy benzene sulfonic acid sodium salt or sylvite (BOBS), more preferably 3,5,5-trimethyl acetyl oxygen base benzene sulfonic acid sodium salt or potassium (different-NOBS) and even the more preferably ninth of the ten Heavenly Stems acyloxy benzene sulfonic acid sodium salt or potassium (NOBS).

The bleach activating immunomodulator compounds that acid amides replaces also can be used for the present invention, for example is described among the EP-A-0170386 those.The suitable example of this class reagent comprises precursor or acid, for example (6-hexyl amino)-6-oxo-caproic acid, (6-octyl group amino)-6-oxo-caproic acid, (6-nonyl amino)-6-oxo-caproic acid, (6-decyl amino)-6-oxo-caproic acid, monoperphthalic acid magnesium hexahydrate, a chloro peroxybenzoic acid salt, 4-amino in the ninth of the ten Heavenly Stems-4-oxo Perbutyric Acid and diperoxy dodecanedioic acid, or its precursor, particularly have the precursor of benzene sulfonate leavings group.This SYNTHETIC OPTICAL WHITNER is disclosed in U.S. Pat 4483781, US4634551, and EP0133354 is among US4412934 and the EP0170386.

Other organic peroxide acid that is fit to comprises the diperoxy docosandioic acid that has more than 7 carbon atoms, for example diperoxy dodecanedioic acid (DPDA), diperoxy tetradecane diacid and diperoxy Thapsic acid.List and two is crossed nonane diacid, brazilic acid crossed by list and two and N-O-phthalic amido peroxide caproic acid (PAP), nonanoyl amido peroxide hexanodioic acid (NAPAA) and hexane sulfinyl Perpropionic Acid also are suitable for the present invention.

Said composition also comprises hydrophilic peracid or its precursor, preferably has formula:

R ¹-CO ₃M is R wherein ¹Be less than 6 carbon atoms, M is a counter ion; Or following formula:

R ¹-CO-L wherein L is and the R with Sauerstoffatom ¹The leavings group that-CO-group links to each other, R ¹Have and be less than 6 carbon atoms.

Preferred hydrophilic precursor is TAED.Peroxide source

Inorganic perhydrate salt is the preferred source of superoxide.The content of preferred these salt is 0.01%-30% weight, more preferably 0.5%-10%.

The example of inorganic perhydrate salt comprises: perborate, percarbonate, superphosphate, persulphate and persilicate.Inorganic perhydrate salt is an alkali metal salt normally.Inorganic perhydrate salt is not mixed by the crystalline solid forms of supplementary protection can.But for some perhydrate salt, the preferred version of particulate composition is the coated form that adopts this material, thereby good storage stability is provided for perhydrate salt in particulate product.The suitable coating material comprises inorganic salt such as alkalimetal silicate, carbonate or borate, or its mixture, perhaps organic substance such as wax, oil or fatty soap.

Sodium peroxoborate is preferred perhydrate salt, and it can be nominal formula NaBO ₂H ₂O ₂Monohydrate or tetrahydrate NaBO ₂H ₂O ₂-3H ₂The O form.

Alkali metal percarbonate, particularly SPC-D are the preferred perhydrate of the present invention.SPC-D is to have corresponding to 2Na ₂CO ₃-3H ₂O ₂The addition compound of formula, it can crystalline solid be purchased.

The peroxide Potassium peroxysulfate is the inorganic perhydrate salt that another kind is used for detergent composition of the present invention.Other detergent component

Detergent composition of the present invention also can contain other detergent component.The physical form that the definite character of these annexing ingredients and incorporation thereof will depend on composition or component with and the definite character of the washing operation that is used for.

Composition of the present invention preferably comprises one or more other detergent components, is selected from other tensio-active agent, other SYNTHETIC OPTICAL WHITNER, bleaching catalyst, alkaline system, washing assistant, phosphatic washing assistant, organic polymer, enzyme, suds suppressor, lime soap dispersing agent, soil-suspending agent and anti redeposition agent, dirt release agent, spices, whitening agent, optical white and other corrosion inhibitor.Bleaching catalyst

Bleach system can contain a kind of bleaching catalyst that contains transition metal.

A kind of bleaching catalyst of suitable type is to comprise the active transition-metal cation of the bleach catalyst with definition such as copper, iron or manganese positively charged ion, have very little or do not have the active assistant metal positively charged ion of bleach catalyst such as zinc or aluminium cations, with the catalyst system of the sequestrant with catalysis and the defined stability constant of assistant metal positively charged ion, described sequestrant is ethylenediamine tetraacetic acid (EDTA), ethylenediamine tetraacetic (methylene phosphonic acid) and its water-soluble salt particularly.This catalyzer is disclosed in US4, and 430,243.

The bleaching catalyst of other type comprises and is disclosed in US 5,246, the manganese basigamy compound in 621 and US5,244,594.The preferred embodiment of these catalyzer comprises: Mn ^IV ₂(u-O) ₃(1,4,7-trimethylammonium-1,4,7-7-triazacyclononane) ₂(PF ₆) ₂, Mn ^III ₂(u-O) ₁(u-OAc) ₂(1,4,7-trimethylammonium-1,4,7-7-triazacyclononane) ₂(ClO ₄) ₂, Mn ^IV ₄(u-O) ₆(1,4, the 7-7-triazacyclononane) ₄(ClO ₄) ₂, Mn ^IIIMn ^IV ₄(u-O) ₁(u-OAc) ₂(1,4,7-trimethylammonium-1,4,7-7-triazacyclononane) ₂(ClO ₄) ₃And their mixture.Other are described in the European patent application publication No. 549272.Other is applicable to that ligand of the present invention comprises 1,5,9-trimethylammonium-1,5,9-triazododecane, 2-methyl isophthalic acid, 4,7-7-triazacyclononane, 2-methyl isophthalic acid, 4,7-7-triazacyclononane, 1,2,4,7-tetramethyl--1,4,7-7-triazacyclononane and its mixture.

The example of the bleaching catalyst that is fit to is referring to US 4,246, and 612 and 5,227,084.Also referring to US 5,194,416, it has lectured for example Mn (1,4,7-trimethylammonium-1,4,7-7-triazacyclononane)-(OCH of monokaryon manganese (IV) title complex ₃) ₃(PF ₆).

As the another kind of bleaching catalyst that is disclosed among the US 5114606 is the water-soluble complexes of the polyol ligand of manganese (III) and/or the non-carboxylate salt that (IV) and at least has three continuous C-OH groups.Preferred ligand comprises Sorbitol Powder, iditol, galactitol, mannitol, Xylitol, arabitol, adonit, meso-tetrahydroxybutane, meso-inositol, lactose and its mixture.

U.S. Pat 5114611 has been lectured bleaching catalyst, comprises the title complex of transition metal and non-(greatly) ring ligand, and described transition metal comprises Mn, Co, Fe or Cu.Described ligand has formula: R wherein ¹, R ², R ³And R ⁴Each can be selected from the alkyl and the aryl of H, replacement, makes each R ¹-N=C-R ²And R ³-C=N-R ⁴Formation five or six-ring.Described ring also can be substituted.B is an abutment, is selected from O, S, CR ⁵R ⁶, NR ⁷And C=O, wherein R ⁵, R ⁶And R ⁷Each can be H, alkyl or aryl, comprises replacing or unsubstituted group.Preferred ligand comprises pyridine, pyridazine, pyrimidine, pyrazine, imidazoles, pyrazoles and triazole ring.Randomly, described ring can be substituted base for example alkyl, aryl, alkoxyl group, halogen and nitro replacement.Particularly preferably be ligand 2,2 '-two pyridine amine.Preferred bleaching catalyst comprises Co, Cu, the two pyridine methane of Mn, Fe-and two pyridine amine complex.Highly preferred catalyzer comprises Co (2,2 '-two pyridine amine) Cl ₂, two (isothiocyanatos) two pyridine amine cobalts (II), three pairs of pyridine amine cobalts (II) perchlorate, Co (2,2 '-two pyridine amine) ₂O ₂ClO ₄, two (2,2 '-two pyridine amine) copper (II) perchlorate, three (two-2-pyridine amine) iron (II) perchlorate and its mixture.Highly preferred can be the cyclams of manganese bridge joint, for example Mn dichloro cyclam or Mn1,4,8,11-tetraazacyclododecane tetradecane.

Other example comprises the double-core Mn title complex that cooperates with four-N-dentate and two-N-dentate ligand, comprises N ₄Mn ^III(u-O) ₂Mn ^IVN ₄ ⁺) and [(2,2 '-dipyridyl) ₂Mn ^III(u-O) ₂Mn ^IV(2,2 '-dipyridyl) ₂]-(ClO ₄) ₃

Other bleaching catalyst is disclosed in the following document, for example European patent application publication No. 408,131 (cobalt complex catalyzer), European patent application publication No. 384,503 and 306,089 (metal-porphyrin catalyst), US 4,728,455 (manganese/polygamy position polymerization of olefin using catalyst body catalyst), US 4,711, and 748 and European patent application publication No. 224,952 (being adsorbed in the Mn catalyst on the silico-aluminate), US 4,601,845 (being carried on manganese and zinc or magnesium salts on the silico-aluminate), US 4,626,373 (manganese/ligand catalyzer), US 4,119,557 (iron complex catalyzer), DE 2,054,019 (cobalt chelates catalyzer), CA 866,191 (salt that contain transition metal), US 4,430,243 (sequestrant with manganese positively charged ion and on-catalytic metallic cation) and US 4,728,455 (gluconic acid Mn catalysts).Highly preferred can be dichloride five amine cobalt (III) acetates.

Bleaching catalyst generally is to be used for the present composition and method with catalytically effective amount." catalytically effective amount " meaning be this amount no matter under which type of simultaneous test condition of use, all be enough to strengthen the spot on bleaching and the removal target substrates or some spots of being concerned about.This test conditions will change according to washing plant type of using and user's custom.Some users select to use very hot water; Other user uses temperature or even cold water in washing operation.Certainly, the catalytic performance of bleaching catalyst will be subjected to the influence of these Considerations, can suitably be adjusted in the amount of the bleaching catalyst that uses in the washing composition of complete formula and the bleaching composition.In fact, do not limited to, the present composition and method can be conditioned so that provide in wash water solution at least about per active bleaching catalyst of 1/10000000th, preferably provide about 0.2ppm to about 200ppm catalyzer in washing soln, the catalyzer of preferred 0.4-100ppm.In order to further specify this point, using under perborate and bleach precursor 40 ℃, the European condition of pH 10, about 3 micromole's Mn catalysts are effective.Under U.S.'s condition,, may need concentration to increase 3-5 doubly in order to obtain equifinality.Tensio-active agent

Detergent composition of the present invention preferably contains one or more tensio-active agents, and these tensio-active agents are selected from anion surfactant, nonionogenic tenside, cats product, amphoterics (ampholytic), amphoterics (amphoteric), zwitterionics and its mixture.

Be issued to the US3 of Laughlin and Heuring on December 30th, 1975, provided the general catalogue of negatively charged ion, nonionic, both sexes and zwitterionics class and the kind of these tensio-active agents in 929,678.Other example is given in following document: " tensio-active agent and washing composition " (I volume and II volume, Schwartz, Perry and Berch).The catalogue of suitable cats product was issued among the US 4,259,217 of Murphy on March 31st, 1981.

Amphoterics (ampholytic), amphoterics (amphoteric) and zwitterionics generally are to be used in combination with one or more negatively charged ion and/or nonionogenic tenside when existing.Anion surfactant

Preferably comprise additional anion surfactant according to detergent composition of the present invention.Any basically anion surfactant that is used for the decontamination purpose all can be included in this detergent composition.These can comprise anion sulfate, sulfonate, carboxylate salt and sarcosinate surfactant (for example, comprise sodium, potassium, ammonium and substituted ammonium salt, as one, two and triethanolamine salt).Preferred anionic vitriol and sulfosalt surfactant.

Highly preferred surfactant system comprises sulfonate as described herein and sulfate surfactant, preferred straight or branched alkylbenzene sulfonate and alkyl ethoxy sulfate, the described cats product of preferred combination such as text.

Other anion surfactant comprises isethionate, as fatty acid amide, alkyl succinate and the alkyl sulfo succinate of acyl isethinate, N-ethanoyl taurate, methyl taurate, monoesters (the particularly saturated and unsaturated C of sulfosuccinate ₁₂-C ₁₈Monoesters), the diester of sulfosuccinate (particularly saturated and unsaturated C ₆-C ₁₄Diester), N-acyl sarcosinate.Resinous acid and hydrogenated resin acid also suit, as rosin, staybelite, and the resinous acid and the hydrogenated resin acid that are present in butter or obtain by butter.The anion sulfate acid salt surfactant

Be applicable to that anion sulfate tensio-active agent of the present invention comprises straight chain and side chain primary and secondary alkyl-sulphate, alkyl ethoxy sulfate, fatty oil acylglycerol vitriol, alkyl phenol epoxy ethane ether salt, C ₅-C ₁₇Acyl group-N-(C ₁-C ₄Alkyl) and-N-(C ₁-C ₂Hydroxyalkyl) vitriol of glucosamine sulfate and alkyl polysaccharide is as the vitriol (compound of nonionic non-sulfuric acid salinization is described hereinafter) of alkyl polyglucoside.

Alkyl sulfate surfactant is preferably selected from straight chain and side chain uncle C ₁₀-C ₁₈Alkyl-sulphate, more preferably C ₁₁-C ₁₅Branched-chain alkyl vitriol and C ₁₂-C ₁₄Straight-chain alkyl sulfate.

Alkyl ethoxy sulfate surfactant is preferably selected from every mole by the C of 0.5-20 moles of ethylene oxide ethoxylation ₁₀-C ₁₈Alkyl-sulphate.More preferably, alkyl ethoxy sulfate surfactant be every mole by 0.5-7, the C of the oxyethane ethoxylation of preferred 1-5 mole ₁₁-C ₁₈, C most preferably ₁₁-C ₁₅Alkyl-sulphate.

The particularly preferred aspect of the present invention is to adopt the mixture of preferred alkyl-sulphate and/or sulfonate and alkyl ethoxy sulfate surfactant.This mixture is stated in following document: PCT number of patent application WO93/18124.The anion sulfoacid salt surfactant

Be applicable to that anionic sulphonate tensio-active agent of the present invention comprises C ₅-C ₂₀Linear alkylbenzene sulfonate, alkyl ester sulfonate, C ₆-C ₂₂Uncle or secondary paraffin sulfonate, C ₆-C ₂₄Alkene sulfonate, sulfonation poly carboxylic acid, alkyl glycerol sulfonate, fatty acyl group glycerol sulfonate, fatty oil acylglycerol sulfonate and its any mixture.The anionic carboxylic acid salt surfactant

Suitable anionic carboxylate tensio-active agent comprises alkyl ethoxy carboxylate, alkyl polyethoxye multi-carboxylate's tensio-active agent and soap (" alkyl carboxyl " soap), the secondary soap class of particularly as described herein some.

Suitable alkyl ethoxy carboxylate comprises having formula RO (CH ₂CH ₂O) _xCH ₂COO ^-M ⁺Those, wherein, R is C ₆-C ₁₈Alkyl, x are 0-10, and ethoxylate distributes and should make, by weight, x be 0 amount of substance less than 20%, M is a positively charged ion.Suitable alkyl polyethoxye multi-carboxylate tensio-active agent comprises having formula RO-(CHR ₁-CHR ₂-O)-R ₃Those, wherein R is C ₆-C ₁₈Alkyl, x is 1-25, R ₁And R ₂Be selected from hydrogen, methyl acid group, succsinic acid group, hydroxy succinic acid group and its mixture, R ₃Be selected from hydrogen, have replacement or unsubstituted hydrocarbon and its mixture of 1-8 carbon atom.

Suitable soap class tensio-active agent comprises secondary soap surfactant, and it comprises the carboxyl unit that links to each other with secondary carbon(atom).Being preferred for secondary soap surfactant of the present invention is to be selected from following water-soluble substances: the water-soluble salt that the water-soluble salt of the water-soluble salt of 2-methyl isophthalic acid-undecanoic acid, 2-ethyl-1-capric acid, the water-soluble salt of 2-propyl group-1-n-nonanoic acid, 2-butyl-1-are sad and the water-soluble salt of 2-amyl group-1-enanthic acid.

Some soap class also can be used as suds suppressor and adds.The basic metal sarcosinate surfactant

Other suitable anion surfactant is formula R-CON (R ¹) CH ₂The basic metal sarcosinate of COOM, wherein R is C ₅-C ₁₇Straight or branched alkyl or alkenyl, R ¹Be C ₁-C ₄Alkyl, M are alkalimetal ion.Preferred examples is the myristyl and the oleoyl methyl sarcosinate of sodium-salt form.Alkoxy-based non-ionic surface active agent

Basically any alkoxy-based non-ionic surface active agent all is applicable to the present invention.Preferred ethoxylation and propoxylation nonionogenic tenside.

The preferred alkoxylated tensio-active agent can be selected from the alkylphenol condensation of non-ionic type, the ethoxylated alcohol of non-ionic type, the ethoxylated/propoxylated fatty alcohol of non-ionic type, ethoxylated/propoxylated condenses non-ionic type and propylene glycol, and ethoxylation condensation product non-ionic type and propylene oxide/ethylenediamine adduct.Nonionic alcohol alcoxylates tensio-active agent

The condensation product of Fatty Alcohol(C12-C14 and C12-C18) and 1-25 mole alkylene oxide, particularly oxyethane and/or propylene oxide is applicable to the present invention.The alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) can be straight or branched, and uncle or secondary comprises 6-22 carbon atom usually.Particularly preferably be the alcohol of alkyl and the condensation product of every mol of alcohol 2-10 moles of ethylene oxide with 8-20 carbon atom.The nonionic polyhydroxy fatty acid amide surfactant

Be applicable to that polyhydroxy fatty acid amide of the present invention is to have those of following structural formula: R ²CONR ¹Z, wherein R ¹Be H, C ₁-C ₄Alkyl, 2-hydroxyethyl, 2-hydroxypropyl, oxyethyl group, propoxy-or its mixture, preferred C ₁-C ₄Alkyl, more preferably C ₁Or C ₂Alkyl, most preferably C ₁Alkyl (being methyl); R ²Be C ₅-C ₃₁Alkyl, preferred straight chain C ₅-C ₁₉Alkyl or alkenyl, more preferably straight chain C ₉-C ₁₇Alkyl or alkenyl, most preferably straight chain C ₁₁-C ₁₇Alkyl or alkenyl, or its mixture; Z is the polyhydroxy alkyl with the straight-chain alkyl chain that is connected directly to few 3 hydroxyls, or its alkoxy derivative (preferred ethoxylation or propoxylation).Z is preferably obtained in reductive amination process by reducing sugar; More preferably Z is a glycosyl.The nonionic fatty acid amide surfactant

Suitable fatty acid amide surfactant comprises those with following formula: R ⁶CON (R ⁷) ₂, R wherein ⁶For comprising 7-21, the alkyl of preferred 9-17 carbon atom, each R ⁷Be selected from hydrogen, C ₁-C ₄Alkyl, C ₁-C ₄Hydroxyalkyl and-(C ₂H ₄O) _xH, wherein x is 1-3.The nonionic alkyl polysaccharide surfactant

Be applicable to that alkyl polysaccharide of the present invention is described among the US 4565647 of the Llenado that authorized on January 21st, 1986, they have the hydrophobic grouping that contains 6-30 carbon atom, and the hydrophilic polysaccharide group that comprises 1.3-10 sugar unit, for example many glycosides.

Preferred APG has following formula:

R ²O (C _nH _2nO) _t(glycosyl) _xR wherein ²Be selected from alkyl, alkyl phenyl, hydroxyalkyl, hydroxyalkyl phenyl and its mixture, wherein alkyl contains 10-18 carbon atom; N is 2 or 3; T is 0-10; X is 1.3-8.This glycosyl is preferably obtained by glucose.Amphoterics

Be used for the amphoterics that the present invention is fit to and comprise amine oxide surfactant and alkyl both sexes carboxylic acid.

Suitable amine oxide comprises formula R ³(OR ⁴) _xN ⁰(R ⁵) ₂Those compounds, R wherein ³Be selected from the alkyl, hydroxyalkyl, acyl group amido propyl group and the alkyl phenyl that contain 8-26 carbon atom, or its mixture; R ⁴Be alkylidene group or the hydroxy alkylidene that contains 2-3 carbon atom, or its mixture; X is 0-5, preferred 0-3; Each R ⁵Be alkyl or the hydroxyalkyl that contains 1-3 carbon atom, perhaps contain the polyethylene oxide group of 1-3 ethylene oxide group.Preferred C ₁₀-C ₁₈Alkyl dimethyl amine oxide and C ₁₀-C ₁₈Acyl group amidoalkyl dimethyl oxidation amine.

The example of suitable alkyl both sexes dicarboxylic acid is Miranol (TM) C2M Conc., by Miranol, and Inc., Dayton, NJ produces.Zwitterionics

Zwitterionics also can add in the detergent composition of the present invention.These tensio-active agents can be described as the derivative of derivative, heterocyclic secondary and the tertiary amine of secondary amine and tertiary amine widely, or the derivative of quaternary ammonium, quaternary phosphine or uncle's sulfonium compound.Trimethyl-glycine and sultaine tensio-active agent are the examples that is used for zwitterionics of the present invention.

Suitable trimethyl-glycine is those compounds with following formula: R (R ') ₂N ⁺R ²COO ^-, wherein R is C ₆-C ₁₈Alkyl, each R ¹Be generally C ₁-C ₃Alkyl, R ²Be C ₁-C ₅Alkyl.Preferred trimethyl-glycine is C ₁₂-C ₁₈Dimethyl Ammonium hexanoate and C ₁₀-C ₁₈Acyl group amido propane (or ethane) dimethyl (or diethyl) trimethyl-glycine.Complicated beet alkali surface activator also is applicable to the present invention.Cats product

The cats product that is fit to that is used for washing composition of the present invention comprises quaternary ammonium surfactant.The preferably single C of quaternary ammonium surfactant ₆-C ₁₆, preferred C ₆-C ₁₀N-alkyl or alkenyl ammonium surfactant, wherein all the other positions of N are replaced by methyl, hydroxyethyl or hydroxypropyl.Preferred monoalkoxyization and bis-alkoxy amine tensio-active agent in addition.

The suitable cats product of another group that can be used for detergent composition of the present invention or its component is the cationic ester tensio-active agent.This cationic ester tensio-active agent is water dispersible preferably, is to comprise at least one ester bond (promptly-COO-) and the compound with surfactant properties of at least one positively charged ion charged groups.

Suitable cationic ester tensio-active agent comprises the cholinesterase tensio-active agent, for example is disclosed in US 4228042,4239660 and 4260529.

In a kind of preferred situation, ester bond and positively charged ion charged groups are spaced apart base and are separated from each other in surfactant molecule, described spacer is made up of a kind of chain, this chain comprises at least three atoms (i.e. three atom chain lengths), preferred 3-8 atom, more preferably 3-5 atom, most preferably 3 atoms.The atom that forms the spacer chain is selected from carbon, nitrogen and Sauerstoffatom and its any mixture, and condition is that any nitrogen-atoms in described chain or Sauerstoffatom only link to each other with carbon atom in the chain.Therefore, got rid of for example have-O-O-(being superoxide) ,-N-N-and-spacer of N-O-key, and comprise for example having-CH ₂-O-CH ₂-and-CH ₂-NH-CH ₂The spacer of-key.In preferred situation, the spacer chain only comprises carbon atom, and most preferably described chain is a hydrocarbyl chain.Cation mono alkoxylated amines tensio-active agent

This paper it is highly preferred that the cation mono alkoxylated amines tensio-active agent with general formula I: R wherein ¹Be to contain 6-18 the carbon atom of having an appointment, preferred about 16 carbon atoms of 6-, the most preferably from about alkyl of 6-14 carbon atom or alkenyl part; R ²And R ³Each is the alkyl that contains about 3 carbon atoms of 1-independently, preferable methyl, most preferably R ²And R ³It all is methyl; R ⁴Be selected from hydrogen (preferably), methyl and ethyl, X ^-Provide electroneutral negatively charged ion, for example chlorine, bromine, methylsulfate, sulfate radical etc.A is an alkoxyl group, particularly oxyethyl group, propoxy-or butoxy; P is that 0-is about 30, and preferred 2-is about 15, and most preferably 2-about 8.

Preferred ApR ⁴Be hydroxyalkyl with no more than 6 carbon atoms, thus-the OH group separated with quaternary nitrogen atoms by no more than 3 carbon atoms.Particularly preferred ApR ⁴Group is-CH ₂CH ₂OH ,-CH ₂CH ₂CH ₂OH ,-CH ₂CH (CH ₃) OH and-CH (CH ₃) CH ₂OH ,-CH ₂CH ₂OH is particularly preferred.Preferred R ¹Group is a straight chained alkyl.Straight chain R with 8-14 carbon atom ¹Group is preferred.

Be used for the highly preferred cation mono alkoxylated amines of another kind of the present invention tensio-active agent and have following formula:

R wherein ¹Be C ₁₀-C ₁₈Alkyl and their mixture, particularly C ₁₀-C ₁₄Alkyl, preferred C ₁₀And C ₁₂Alkyl, X provide any suitable negatively charged ion of charge balance, preferred chlorine or bromine.

As described, the compound of the above-mentioned type comprises wherein oxyethyl group (CH ₂CH ₂O) unit (EO) is by butoxy, isopropoxy [CH (CH ₃) CH ₂O] and [CH ₂CH (CH ₃O] unit (i-Pr) or positive propoxy unit (Pr) or EO and/or Pr and/or the unitary mixture of i-Pr displaced those.

Be used for the content of the cation mono alkoxylated amines tensio-active agent of detergent composition of the present invention, the weight by composition is preferably 0.1%-20%, more preferably 0.2%-7%, most preferably 0.3%-3.0%.Positively charged ion dialkoxy amine tensio-active agent

Positively charged ion dialkoxy amine tensio-active agent preferably has general formula I I:

R wherein ¹Be to contain about 18 carbon atoms of the 8-that has an appointment, preferred about 16 carbon atoms of 10-, the most preferably from about alkyl of about 14 carbon atoms of 10-or alkenyl part; R ²Be the alkyl that contains 1-3 carbon atom, preferable methyl; R ³And R ⁴Can change independently, they are selected from hydrogen (preferably), methyl and ethyl; X ^-Be to be enough to provide electroneutral negatively charged ion, for example chlorine, bromine, methylsulfate, sulfate radical etc.A and A ' can change independently, respectively are selected from C ₁-C ₄Alkoxyl group, particularly oxyethyl group (promptly-CH ₂CH ₂O), propoxy-, butoxy and their mixture; P is that 1-is about 30, and preferred 1-is about 4, and q is that 1-is about 30, and preferred 1-is about 4, and most preferably p and q are 1.

Be used for the highly preferred positively charged ion dialkoxy of the present invention amine tensio-active agent and have following formula:

R wherein ¹Be C ₁₀-C ₁₈Alkyl and its mixture, preferred C ₁₀, C ₁₂, C ₁₄Alkyl and its mixture, X provides any suitable negatively charged ion of charge balance, preferred chlorine.About above-mentioned positively charged ion dialkoxy amine formula, in preferred compound, R ¹Be by (cocounut oil) C ₁₂-C ₁₄Moieties lipid acid obtains, R ²Be methyl, ApR ³And A ' qR ⁴All are monosubstituted ethoxies.

Be applicable to that other positively charged ion dialkoxy amine tensio-active agent of the present invention comprises the compound of following formula: R wherein ¹Be C ₁₀-C ₁₈Alkyl, preferred C ₁₀-C ₁₄Alkyl, p are that 1-is about 3 independently, and q is that 1-is about 3, R ²Be C ₁-C ₃Alkyl, preferable methyl, X is a negatively charged ion, particularly chlorine or bromine.

Other compound of the above-mentioned type comprises wherein oxyethyl group (CH ₂CH ₂O) unit (EO) is by butoxy (Bu), isopropoxy [CH (CH ₃) CH ₂O] and [CH ₂CH (CH ₃O] unit (i-Pr) or positive propoxy unit (Pr) or EO and/or Pr and/or the unitary mixture of i-Pr displaced those.The water soluble detergency promoter compound

Detergent composition preferred package of the present invention contains water-soluble washing-aid compound, and by the weight of composition, generally its content is 1-80%, preferred 10-60%, more preferably 15-40%.

Detergent composition of the present invention preferably comprises phosphatic washing assistant material.By the weight of composition, preferably its content is 0.5%-60%, more preferably 5%-50%, more preferably 8%-40%.

Phosphatic washing assistant material preferably includes tetrasodium pyrophosphate or even more preferably anhydrous sodium tripolyphosphate.

Suitable water soluble detergency promoter compound comprises water-soluble monomer multi-carboxylate or its sour form, homopolymerization or copolymerization poly carboxylic acid or its salt, wherein poly carboxylic acid comprises and is no more than at least two carboxyls that two carbon atoms separate are opened each other, and described washing-aid compound also comprises the mixture of borate and aforementioned any compound.

Carboxylate salt or multi-carboxy acid salt washing agent can be monomer type or oligomer types, but because Cost And Performance, the multi-carboxylate of preferred monomers type usually.

The suitable carboxylate salt that contains a carboxyl comprises the water-soluble salt and the ether derivant thereof of lactic acid, oxyacetic acid.The multi-carboxylate of containing two carboxyls comprises the water-soluble salt of succsinic acid, propanedioic acid, (ethylidene dioxy base) oxalic acid, toxilic acid, Glyoxylic acid hydrate, tartrate, tartronic acid and fumaric acid and ether carboxylate and sulfinyl carboxylate salt.The multi-carboxylate or its acid that contain three carboxyls comprise particularly water-soluble citrate, aconitate and citraconate, and the succinate derivative, as English Patent 1,379,241 described carboxy methoxy-succinic acid salt, the newborn acyloxy succinate described in the English Patent 1389732, HOII P 7205873 described aminosuccinic acid salt, and English Patent 1,387,447 described oxygen multi-carboxylate material, for example 2-oxa-s-1,1,3-tricarballylic acid salt.The most preferred poly carboxylic acid that contains three carboxyls is a citric acid, and by the weight of composition, preferably its content is 0.1%-15%, more preferably 0.5%-8%.

The multi-carboxylate of containing four carboxyls comprises English Patent 1,261,829 described oxygen di-succinates, and 1,1,2,2-ethane tetracarboxylic acid hydrochlorate, 1,1,3,3-propane tetracarboxylic acid salt and 1,1,2,3-propane tetracarboxylic acid salt.Comprise the substituent multi-carboxylate of sulfo group and comprise English Patent 1,398,421 and 1,398,422 and U.S. Pat 3,936,448 described sulfo-succinic acid salt derivatives, and English Patent 1,439,000 described sulfonation pyrolytic Citrate trianion.Preferred multi-carboxylate is contained the hydroxycarboxylate of 3 carboxyls of as many as, Citrate trianion more specifically for per molecule.

The parent acid of monomer or oligomeric multi-carboxylate's sequestrant or can replenish as useful builder component with the mixture of its salt, for example, citric acid or Citrate trianion/citric acid mixture.

The borate washing assistant and can washing composition store or wash conditions under to produce the boratory washing assistant that forms borate substance that contains be the useful water soluble detergency promoter of the present invention.

The suitable example of water-soluble phosphate washing assistant is an alkali metal tripolyphosphates, trisodium phosphate, potassium and ammonium, and trisodium phosphate, potassium and ammonium, sodium orthophosphate and potassium, partially poly-/sodium phosphate, wherein the polymerization degree is about 6-21, and phytate.Part solubility or insoluble washing-aid compound

Detergent composition of the present invention can comprise part solubility or insoluble washing-aid compound, presses composition weight meter, and generally its content is 0.5-60%, preferred 5-50%, most preferably 8-40%.

The example of basic water-insoluble washing assistant comprises sodium silicoaluminate.

The aluminosilicate zeolite that is suitable for has unit structure cell formula Na _z[(AlO ₂) _z(SiO ₂) _y]-xH ₂O, wherein z and y are at least 6, and the mol ratio of z and y is 1.0-0.5, and x is at least 5, preferred 7.5-276, more preferably 10-264.Alumino-silicate materials is a hydrated form, and preferably crystal contains 10-28%, more preferably the 18-22% combination water.

Aluminosilicate zeolite can be natural product, but preferably synthetic obtaining.Synthetic crystallization type silico-aluminate ion exchange material is zeolite A, zeolite B, zeolite P, X zeolite by name, and zeolite HS and composition thereof buys.Zeolite A has following formula:

Na ₁₂[(AlO ₂) ₁₂(SiO ₂) ₁₂]-xH ₂O wherein x is 20-30, particularly 27.X zeolite has formula: Na ₈₆[(AlO ₂) ₈₆(SiO ₂) ₁₀₆]-276H ₂O.

Zeolite MAP builder is in addition preferred aluminosilicate zeolite.

With composition weight meter, the content of zeolite MAP is 1-80%, more preferably 15-40%.

Zeolite MAP is stated in EP 384070A (Unilever).It is defined as the ratio with silicon and aluminium and is not more than 1.33, is preferably 0.9-1.33, more preferably the zeolite P type alkali metal aluminosilicate of 0.9-1.2.

Making us interested especially is silicon and the ratio of aluminium is not more than 1.15, is not more than 1.07 zeolite MAP more specifically.

In preferred situation, the particle diameter of zeolite MAP detergent builders is with d ₅₀Value representation is 1.0-10.0 μ m, more preferably 2.0-7.0 μ m, most preferably 2.5-5.0 μ m.

d ₅₀Value is meant that 50 weight % particulate diameters are worth less than this.Particle diameter specifically can be by the routine analysis technical measurement, measures or with laser particle size instrumentation amount as the microscope that adopts scanning electron microscope to carry out.Other determines d ₅₀The method of value is stated in EP 384070A.Heavy metal ion chelating agent

The present composition preferably comprises the heavy metal ion chelating agent as optional ingredient.So-called heavy metal ion chelating agent has been meant the component of chelating heavy metal ion effect at this paper.These components also can have calcium and magnesium chelating capacity, but preferably they demonstrate the selectivity in conjunction with heavy metal ion such as iron, manganese and copper.

The content of heavy metal ion chelating agent is generally the 0.005-10% of the present composition or composition weight, preferred 0.1%-5%, more preferably 0.25-7.5%, most preferably 0.3-2%.

Be suitable for heavy metal ion chelating agent of the present invention and include organic phosphonates, as amino alkylidenyl poly-(alkylene phosphonic acids salt), basic metal ethane 1-hydroxyl diphosphonate and nitrilo trimethylene phosphonic salt.

Preferred diethylenetriamine five (methylene phosphonic acid salt), quadrol three (methylene phosphonic acid salt), hexamethylene-diamine four (methylene phosphonic acid salt) and hydroxyl-ethylidene 1 in the above-mentioned substance, 1-diphosphonate, 1,1-hydroxyl ethane di 2 ethylhexyl phosphonic acid and 1,1-hydroxyl ethane dimethylene phosphonic acids.

Other is applicable to that heavy metal ion chelating agent of the present invention comprises nitrilotriacetic acid(NTA) and polyamino carboxylic acid, as ethylenediamine tetraacetic acid (EDTA), ethylenediamine disuccinic acid, quadrol two pentanedioic acids, 2-hydroxy propylidene diamines disuccinic acid or its any salt.

Other is applicable to that heavy metal ion chelating agent of the present invention is an iminodiacetic acid derivatives, as 2-hydroxyethyl oxalic acid or glyceryl iminodiethanoic acid, and as EP-A-317,542 and EP-A-399, described in 133.The present invention also can adopt as EP-A-516,102 described iminodiethanoic acid-N-2-hydroxypropyl sulfonic acid and aspartic acid N-carboxymethyl N-2-hydroxypropyl-3-sulfonic acid sequestrant.The present invention also can adopt EP-A-509,382 described Beta-alanine-N, N '-oxalic acid, aspartic acid-N, single acetate of N '-oxalic acid, aspartic acid-N-and imino-diacetic succsinic acid sequestrant.

EP-A-476,257 disclose the suitable sequestrant based on amino.EP-A-510,331 disclose the suitable sequestrant that is obtained by collagen, Keratin sulfate or casein.EP-A-528,859 disclose a kind of suitable alkyl imino oxalic acid sequestrant.Pyridine dicarboxylic acid and 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid also is fit to.Glycine acid amides-N, N '-disuccinic acid (GADS), quadrol-N, N '-two pentanedioic acid (EDDG) and 2-hydroxyl propylene diamine-N, N '-disuccinic acid (HPDDS) also is fit to.

Particularly preferably be diethylene triaminepentaacetic acid(DTPA), quadrol-N, N '-disuccinic acid (EDDS), 1,1-hydroxyl ethane di 2 ethylhexyl phosphonic acid and 1, the ammonium salt of 1-hydroxyl ethane dimethylene phosphonic acids or its basic metal, alkaline-earth metal, ammonium or replacement, or its mixture.Enzyme

Another preferred ingredient that is used for detergent composition of the present invention is one or more additional enzymes.

Preferred additional enzymes material comprises the commercial lipase of purchasing, at, amylase, neutrality and Sumizyme MP, cellulase, restriction endonuclease (endolase), esterase, polygalacturonase, Sumylact L and the peroxidase that is routinely added in the detergent composition.Suitable enzyme is discussed in US3519570 and 3533139 to some extent.

Those proteolytic enzyme that the preferred commercial proteolytic enzyme of purchasing comprises those proteolytic enzyme of being sold with trade(brand)name Alcalase, Savinase, Primase, Durazym and Esperase by Novo Industries A/S (Denmark), sold with trade(brand)name Maxatase, Maxacal and Maxapem by Gist-Brocades, those proteolytic enzyme of selling by Genencor International and those proteolytic enzyme of selling with trade(brand)name Opticlean and Optimase by Solvay Enzymes.Proteolytic enzyme can add in the present composition by the content of composition weight meter with the 0.0001%-4% organized enzyme.

Preferably amylase comprises, for example the α-Dian Fenmei that the special bacterial strain by Bacillus licheniformis of detailed description obtains among the GB-1269839 (Novo).The preferred commercial amylase of purchasing comprises those amylase of for example being sold those amylase and sold with trade(brand)name Termamyl, Duramyl and BAN by Novo IndustriesA/S with trade(brand)name Rapidase by Gist-Brocades.Highly preferred amylase is to be described among PCT/US 9703635 and WO95/26397 and the WO96/23873 those.

By the weight of composition, amylase adds in the present composition with the content of 0.0001%-2% organized enzyme.

By the weight of composition, lipolytic enzyme can 0.0001%-2%, preferably 0.001%-1%, the most preferably active lipolytic enzyme content existence of 0.001%-0.5%.

Lipase can be obtained by fungi or bacterial origin, for example by the detritus enzyme belong to, the bacterial strain of the generation lipase of Thermomicrobium (Thermomyces sp.) or Rhodopseudomonas obtains, described bacterial strain comprises pseudomonas pseudoalcaligenes or Pseudomonas fluorescens.Lipase chemical or that genetically altered mutation obtains by these bacterial strains also can be used among the present invention.Preferred lipase is obtained by pseudomonas pseudoalcaligenes, and it is stated in the European patent EP-B-0218272 that authorizes.

Another preferred lipase of the present invention is as described in European patent application EP-A-0258068, be by cloning the gene that obtains by fetal hair detritus bacterium and in as host's aspergillus oryzae, expressing the lipase that this gene obtains, it is from Novo Industri A/S Bagsvaerd, Denmark, Lipolase is purchased with trade(brand)name.This lipase also is described among the US4810414 of the Huge-Jensen of on March 7th, 1989 promulgation etc.Organic polymer

Organic polymer is the preferred annexing ingredient of detergent composition of the present invention, and it preferably exists as the component of any grain fraction, and they play the effect that for example grain fraction is bonded together.So-called organic polymer looks like here and is meant any basically organic polymer that is used as dispersion agent, anti redeposition agent and soil-suspending agent in detergent composition usually, be included in any high molecular organic polymer that is stated as the clay flocculating agent herein, comprise that ethoxylation (gathering) amine of quaternary ammonium salinization of the present invention removes great soil group dirt agent/anti redeposition agent.

Press composition weight meter, the incorporation of organic polymer in detergent composition of the present invention is generally 0.01-30%, preferred 0.1-15%, more preferably 0.5-10%.

The example of organic polymer comprises water-soluble organic homopolymerization or copolymerization poly carboxylic acid or its salt, and wherein poly carboxylic acid comprises at least two and is no more than the carboxyl that two carbon atoms separate are opened each other.The polymkeric substance of latter's type is disclosed in GB-A-1, in 596,756.The example of this salt be molecular weight 1000-5000 polyacrylate and with the multipolymer of maleic anhydride, this multipolymer has molecular weight 2000-100,000, particularly 40,000-80,000.

Polyamino compounds can be used for the present invention, comprises those materials that obtained by aspartate-derived, for example EP-A-305282, EP-A-305283 and EP-A-351629 described those.

The terpolymer that comprises the monomeric unit that is selected from toxilic acid, vinylformic acid, poly aspartic acid and vinyl alcohol, particularly molecular-weight average are 5, and 000-10, those of 000 also are applicable to the present invention.

Other organic polymer that is fit to add in the detergent composition of the present invention comprises derivatived cellulose, as methylcellulose gum, carboxymethyl cellulose, Vltra tears and Natvosol.

Other useful organic polymer is that polyoxyethylene glycol, particularly molecular weight are 1000-10000, more preferably 2000-8000, most preferably from about those polyoxyethylene glycol of 4000.

The highly preferred polymeric component of the present invention is the U.S. Pat 5415807 according to the U.S. Pat 4968451 of Scheibel etc. and Gosselink etc., particularly according to the cotton goods and the non-cotton goods dirt release agent polymkeric substance of U.S. Patent application 60/051517.

Be used for another kind of organic compound of the present invention, it is a kind of preferred clay suspending agent/anti redeposition agent, and it can be cationic ethoxy monoamine and the diamines with following formula:

Wherein X is a non-ionic group, is selected from H, C ₁-C ₄Alkyl or hydroxyalkyl acrylate or ether group and its mixture, a are 0-20, preferred 0-4 (as ethylidene, propylidene, hexa-methylene), and b is 1 or 0; For positively charged ion monoamine (b=0), n is at least 16, and general range is 20-35; For cationic diamine (b=1), n is at least about 12, and general range is about 12-about 42.

Be used for other dispersion agent/anti redeposition agent of the present invention and be described in EP-B-011965, US4659802 and US 4664848.Press down foam system

When detergent composition of the present invention is mixed with when being used to machine-wash composition, can comprise a kind of foam system that presses down, by the weight of composition, its content is 0.01-15%, preferred 0.02-10%, more preferably 0.05-3%.

Being used for the suitable foam that presses down of the present invention is to comprise any basically known defoamer compound, comprises for example polysiloxane defoamers compound and 2-alkyl alkanol defoamer compound.

Defoamer compound is meant detergent composition solution, the foaming that produces when particularly stirring this solution or for example inhibiting any compound of puff or its mixture.

Being used for the particularly preferred defoamer compound of the present invention is the polysiloxane defoamers compound, and it is defined as any defoamer compound that comprises the polysiloxane component at this paper.This polysiloxane defoamers compound generally also contains silica component.Used herein and also be that the term " polysiloxane " of industrial common employing comprises the various relative high molecular weight polymers that contain siloxane unit and all kinds alkyl.Preferred polysiloxane defoamers compound is a siloxanes, particularly has the unitary polydimethylsiloxane of trimethyl silyl end-blocking.

Other suitable defoamer compound comprises monobasic aliphatic carboxylic acid and its soluble salt.These substance descriptions are in the US 2954347 of the Wayne St.John of mandate on September 27 nineteen sixty.Monobasic aliphatic carboxylic acid and salt thereof as suds suppressor generally have the 10-24 of containing carbon atom, the hydrocarbyl chain of preferred 12-18 carbon atom.The salt that is fit to comprises an alkali metal salt, sodium salt for example, sylvite, and lithium salts and ammonium salt and alkanol ammonium salts.

Other suitable defoamer compound comprises for example high-molecular weight fatty ester (as fatty acid triglyceride), monohydroxy-alcohol fatty acid ester, aliphatic C ₁₈-C ₄₀Ketone (as stearone), N-alkylation aminotriazine, as three to six alkyl melamines or two to the tetraalkyl diammonium chloride for triazine, it is to contain the uncle of 1-24 carbon atom or the product of secondary amine forms, propylene oxide, distearyl acid acid amides and single stearyl di(2-ethylhexyl)phosphate basic metal (as sodium, potassium, lithium) salt and phosphoric acid ester as cyanuric chloride and 2 or 3 moles.

The preferred foam system that presses down comprises: (a) defoamer compound, preferred polysiloxane defoamers compound, the polysiloxane defoamers compound that most preferably comprises following combination: (i) polydimethylsiloxane, its content accounts for the 50-99% of polysiloxane defoamers compound, preferred 75-95%; (ii) silicon-dioxide, its content accounts for the 1-50% of polysiloxane/silicon-dioxide defoamer compound, preferred 5-25%; The incorporation of wherein said silicon-dioxide/polysiloxane defoamers compound is 5%-50%, preferred 10%-40% weight; (b) a kind of compound dispersing agent, most preferably comprise silicone glycol comb copolymer (rakecopolymer), its polyoxyalkylene content is 72-78%, and the ratio of oxyethane and propylene oxide is 1: 0.9-1: 1.1, its content is 0.5-10%, preferred 1-10% weight; Particularly preferred the type silicone glycol comb copolymer is DCO544, is purchased with trade(brand)name DCO544 from DOW Corning company; (c) a kind of inert support fluid compound, most preferably it comprises C ₁₆-C ₁₈Ethoxylated alcohol, its ethoxylation degree are 5-50, preferred 8-15, and its content is 5-80%, preferred 10-70% weight.

Highly preferred granular suds suppressing system is disclosed among the EP-A-0210731, should pressing down foam system, to comprise a kind of polysiloxane defoaming compounds and a kind of fusing point be 50-85 ℃ organic carrier material, wherein the organic carrier material comprises the monoesters of glycerine and a kind of lipid acid, and described lipid acid has the carbochain that contains 12-20 carbon atom.EP-A-0210721 discloses other preferred granular suds suppressing system, and wherein the organic carrier material is lipid acid or the alcohol with the carbochain that contains 12-20 carbon atom, or its mixture, and its fusing point is 45-80 ℃.

Other highly preferred foam system that presses down comprises polydimethylsiloxane or polysiloxane mixture for example polydimethylsiloxane, silico-aluminate and multi-carboxy acid copolymer, for example lactic acid (laic) and acrylic acid multipolymer.The polymeric dye transfer inhibitor

Detergent composition of the present invention also can comprise 0.01-10%, the polymeric dye transfer inhibitor of preferred 0.05-0.5% weight.

The polymeric dye transfer inhibitor is preferably selected from multipolymer, polyvinylpyrrolidonepolymers polymers or its mixture of polyamine N-oxide pllymers, N-vinyl pyrrolidone and N-vinyl imidazole, so these polymkeric substance can be cross-linked polymers.White dyes

Detergent composition of the present invention also can randomly contain the hydrophilic white dyes of some type of have an appointment 0.005% to 5% (weight).

Can be used for hydrophilic white dyes of the present invention and have the following formula structure:

R wherein ₁Be selected from anilino, N-2-pair-hydroxyethyl and NH-2-hydroxyethyl; R ₂Be selected from N-2-pair-hydroxyethyl, N-2-hydroxyethyl-N-methylamino-, morpholino, chlorine and amino; With M be salt-forming cation such as sodium or potassium.

In following formula, R ₁Be anilino, R ₂Be N-2-two-when hydroxyethyl and M were positively charged ion such as sodium, whitening agent was 4,4 '-two [(4-anilino-6-(N-2-two-hydroxyethyl)-guanamine-yl) amino]-2,2 '-stilbene disulfonic acid and disodium salt.Such special whitening agent can be bought from Ciba-Geigy company according to trade(brand)name Tinopal-UNPA-GX commercial.Tinopal-CBS-X and Tinopa]-UNPA-GX is the preferred hydrophilic white dyes that can be used in the detergent composition of the present invention.

In following formula, R ₁Be anilino, R ₂Be N-2-hydroxyethyl-N-2-methylamino-and M when being positively charged ion such as sodium, whitening agent is 4,4 '-two [(4-anilino-6-(N-2-hydroxyethyl-N-methylamino-)-guanamine-yl) amino]-2,2 '-stilbene disulfonic acid disodium salt.Such special whitening agent can be bought from Ciba-Geigy company according to trade(brand)name Tinopal 5BM-GX commercial.

In following formula, R ₁Be anilino, R ₂Be morpholino and M when being positively charged ion such as sodium, whitening agent is 4,4 '-two [(4-anilino-6-morpholino-guanamine-yl) amino]-2,2 '-stilbene disulfonic acid sodium salt.Such special whitening agent can be bought from Ciba-Geigy company is commercial according to trade(brand)name Tinopal-DMS-X and Tinopal AMS-GX.The polymerization dirt release agent

Can randomly use known polymerization dirt release agent in the detergent composition of the present invention, hereinafter referred is " SRA ".If you are using, SRA ' s generally accounts for 0.01% to 10.0% of composition weight, is typically 0.1% to 5%, and preferred 0.2% to 3.0%.

The hydrophobic part that preferred SRA ' s generally has the hydrophilic segment that makes hydrophobic fiber such as polyester and nylon surface hydrophilic and is deposited on the hydrophobic fiber and keeps being attached thereto in whole washing and rinse cycle, so it is as the fixture of hydrophilic segment.This can be so that handle spot easier being cleaned in washing process afterwards that the back produces with SRA.

Preferred SRA ' s comprises the terephthalate of oligomerisation, and it generally by comprising the method preparation of at least a transesterify/oligomerisation reaction, carries out under metal catalyst such as titanium alkoxide (IV) usually.This ester can use can by one, two, three, four or more position add other monomers preparations of ester structure, certainly, do not form fine and close crosslinked overall structure.

SRA ' the s that is fit to comprises the sulfonated products of the ester oligomer that is straight chain basically; it contains oligomer ester skeleton and the oxyalkylene oxygen repeating unit and the allyl group deutero-sulfonation terminal portions covalently bound with skeleton of terephthaloyl, for example described in the U.S. Pat 4968451 of J.J.Scheibel that authorizes in November 6 nineteen ninety and E.P.Gosselink.This ester oligomer can prepare through the following steps: (a) ethoxylation allyl alcohol; (b) product and terephthalic acid dimethyl ester (" DMT ") and 1 that will (a) in two step transesterify/oligomerizations, 2-propylene glycol (" PG ") reacts; (c) in water with the product of (b) and sodium metabisulfite reaction.Other SRA ' s comprises the nonionic end capped 1 in the people's such as Gosselink that authorized on December 8th, 1987 the U.S. Pat 4711730,2-propylidene/polyoxyethylene terephthalate polyester, for example by poly-(ethylene glycol) methyl ether, DMT, the product of transesterify/oligomerisation preparation of PG and poly-(ethylene glycol) (" PEG ").Other SRA ' s example comprises part and the whole end capped oligomer esters of negatively charged ion in the U.S. Pat 4721580 of the Gosselink that authorized on January 26th, 1988, as derive from ethylene glycol (" EG "), PG, DMT and 3, the oligopolymer of 6-two oxa-s-8-hydroxyl perfluorooctane sulfonate; Nonionic end-blocking block polyester oligomerisation compound in the U.S. Pat 4702857 of the Gosselink that on October 27th, 1987 authorized, for example by DMT, methyl (Me)-end capped PEG and EG and/or PG preparation, perhaps by DMT, EG and/or PG, the product of the mixture preparation of end capped PEG of Me-and 5-sulfoisophthalic acid dimethyl esters sodium; With the Maidonado that authorized on October 31st, 1989; negatively charged ion in people's such as Gosselink the U.S. Pat 4877896; especially the end capped terephthalate of sulfo group aroyl; the latter is typical useful SRA ' s in laundry and fabric-conditioning product; one example be by-sulfosalicylic acid list sodium salt, the ester composition of PG and DMT preparation, but randomly preferably also contain the PEG of adding; for example, PEG3400.

SRA ' s also comprises: the simple copolymerization block thing of ethylene terephthalate or terephthalic acid propylene glycol ester and polyethylene oxide or poly(propylene oxide) terephthalate, referring to the U.S. Pat 3959230 of the Hays on May 25th, 1976 and the U.S. Pat 3893929 of the Basadur on July 8th, 1975; Derivatived cellulose such as the hydroxy ethers cellulose polymer compound bought from Dow by METHOCEL; C ₁-C ₄Alkylcellulose and C ₄Hydroxy alkyl cellulose is referring to the people's such as Nicol on December 28th, 1976 U.S. Pat 4000093; And methyl cellulose ether, it is about 1.6-2.3 that its each anhydroglucose unit has average substitution degree (methyl), the aqueous solution by 2% is about 80-120 centipoise at 20 ℃ of soltion viscosities of measuring down.This material can be buied by METOLOSE SM100 and METOLOSE SM200, and they are the trade(brand)names by the methyl cellulose ether of Shin-etsu Kagaku Kogyo KK production.

Another kind of SRA ' s comprises: (I) use vulcabond coupler and polyester construction banded nonionic terephthalate, referring to people's such as people's such as Violland U.S. Pat 4201824 and Lagasse U.S. Pat 4240918; (II) have the SRA ' s of carboxylicesters end group, it transforms terminal hydroxy group and becomes the trimellitate preparation by trimellitic acid 1,2-anhydride is added among known SRA ' s.By suitable selecting catalyst, trimellitic acid 1,2-anhydride forms the end group banded key with polymkeric substance, and this is to carry out by the isolated carboxylicesters of trimellitic acid 1,2-anhydride rather than by opening the acid anhydride key.Nonionic or negatively charged ion SRA ' s can be used as starting raw material, as long as have can esterified hydroxyl end groups for they, referring to people's such as Tung U.S. Pat 4525524.Other type comprises: (III) link the SRA ' s based on the negatively charged ion terephthalate of urethanes, referring to people's such as Violland U.S. Pat 4201824.Other optional ingredient

Other optional ingredient that is fit to be included in the present composition comprises spices, pigment and filling salt, and sodium sulfate is preferred filling salt.

Highly preferably add the look grain.Following look grain is preferred look grain: by the sodium carbonate particle that agglomeration and screening powdered sodium carbonate make, wherein 75% particle has particle diameter 600-850 micron, and 25% particle has particle diameter 425-600 micron.The particle that obtains is thus sprayed the blue BV slurry of Monastral solution, and is dry then, obtains comprising the look grain of about 1000ppm dyestuff.

Highly preferred composition contains the 2%-10% weight organic acid of having an appointment, optimization citric acid.Also preferred combination carbonate, a small amount of (for example being lower than about 20% weight) neutralizing agent, buffer reagent, phase modifier, hydrotropic agent, enzyme stabilizers, polyprotonic acid, foaming regulator, opalizer, antioxidant, sterilant and dyestuff, for example those (they quote for referencial use at this paper) of describing in the U.S. Pat 4285841 of the Barrat that authorizes on August 25th, 1981 etc.The form of composition

Detergent composition of the present invention can pass through prepared in various methods, comprises all cpds dry blend agglomeration and/or the spraying drying that will comprise in the detergent component.

Various physical form be can take according to composition of the present invention, liquid and solid form for example sheet, cake, lozenge and bar comprised, the preferred particulates form.

The present composition also can be used for or is used in combination with compositions of additives that the bleaching compositions of additives for example comprises chlorine bleach.SYNTHETIC OPTICAL WHITNER based on chlorine

Detergent composition of the present invention can comprise the SYNTHETIC OPTICAL WHITNER based on chlorine as annexing ingredient.Yet because the preferred detergent composition of the present invention is a solid, great majority are not suitable in these detergent composition based on the liquid bleach of chlorine, and only particle or the powdery SYNTHETIC OPTICAL WHITNER based on chlorine is fit to.

In addition, detergent composition of the present invention can be mixed with make they be compatible based on the SYNTHETIC OPTICAL WHITNER of chlorine, guarantee that thus the user can add the SYNTHETIC OPTICAL WHITNER based on chlorine in the detergent composition in the beginning of washing stage or process.

Should can make based on the SYNTHETIC OPTICAL WHITNER of chlorine and in the aqueous solution, form the hypochlorite material.Hypochlorite ion is chemically being represented by formula OCT.

Those SYNTHETIC OPTICAL WHITNER that produce the hypochlorite material in the aqueous solution comprise basic metal and alkaline-earth metal hypochlorite, hypochlorite affixture, chloramines, chlorimide, chloro-acid amide and chlorine imide.The specific examples of this compounds comprises clorox, potassium hypochlorite, generation Losantin, two generation magnesium chlorates, Efficacious Disinfeitant dodecahydrate, DCCK, dichloroisocyanuric acid sodium, dichloroisocyanuric acid sodium dihydrate, trichlorocyanuric acid, 1,3-two chloro-5,5-T10, N-chloro sulphonamide, chloramine-T, dichloramine-T, chloramine B and dichloramine B.The preferred SYNTHETIC OPTICAL WHITNER that is used for the present composition is clorox, potassium hypochlorite or its mixture.Preferably the SYNTHETIC OPTICAL WHITNER based on chlorine can be Triclosan (trade(brand)name).

The SYNTHETIC OPTICAL WHITNER of most of above-mentioned generation hypochlorites can solid or spissated form be purchased, in preparation present composition process, be dissolvable in water water.Some above-mentioned materialss can be buied by the aqueous solution.

The mean particle size that the component of particulate composition of the present invention has should make preferably that diameter is no more than 25% greater than the particle of 1.8mm; Diameter is no more than 25% less than the particle of 0.25mm.Preferred average particle size is to make the 10%-50% particle have diameter 0.2mm-0.7mm.

Herein Ding Yi term mean particle size be by with composition sample at one group of sieve, preferred Tyler sieve top sieve is divided into that mass part (common 5 parts) calculates.With each wt part aperture mapping of sieve relatively that obtains thus, mean particle size is the aperture size that the sample of 50% weight passes through.Clothes washing method

Machine clothes washing method of the present invention generally comprises and is used in containing dissolving or disperseing the machine-wash wash water solution of detergent composition of the present invention of significant quantity to handle soiled clothes in the washing machine.The detergent composition of significant quantity is meant at 5-65 and rises in the washing soln of volume dissolving or disperse the 10g-300g product that this is typical products consumption and the washing soln volume that is generally used in the conventional machine washing method.

Aspect preferred use, detergent composition is formulated into and makes it be applicable to hand washing.

Another preferred aspect, detergent composition is to be used for pre-treatment or to soak dirty and pollute the pre-treatment of fabric or soak composition.

That uses among the embodiment writes a Chinese character in simplified form

In detergent composition, the component symbol of writing a Chinese character in simplified form has following implication: LAS: straight chain C ₁₁- ₁₃Sodium alkyl benzene sulfonate TAS: tallow alkyl sodium sulfate CxyAS: C _1x-C _1ySodium alkyl sulfate C46SAS: C ₁₄-C ₁₆Secondary (2,3) sodium alkyl sulfate CxyEzS: with the C of z moles of ethylene oxide condensation _1x-C _1ySodium alkyl sulfate CxyEz: with the condensation of average z moles of ethylene oxide mainly be straight chain

C _1x-C _1yPrimary alconol QAS: R ₂N ⁺(CH ₃) ₂(C ₂H ₄OH), R ₂=C ₁₂-C ₁₄QAS1: R ₂N ⁺(CH ₃) ₂(C ₂H ₄OH), R ₂=C ₈-C ₁₁SADS: formula 2-(R) C ₄H ₇-1,4-(SO ₄-) ₂C ₁₄-C ₂₂Alkyl two sulphur

Acid sodium, wherein R=C ₁₀-C ₁₈SADE2S: formula 2-(R) C ₄H ₇-1,4-(SO ₄-) ₂C ₁₄-C ₂₂Alkyl two sulphur

Acid sodium, wherein R=C ₁₀-C ₁₈, condensation z moles of ethylene oxide MES: C ₁₈The x-sulfo group methyl ester APA of lipid acid: C ₈-C ₁₀Amido propyl-dimethyl amine soap: straight-chain alkyl carboxylic acid's sodium, by 80/20 of butter and coconut fatty acid

Mixture obtains STS: toluenesulfonic acid sodium salt CFAA: C ₁₂-C ₁₄(cocounut oil) alkyl N-methyl glucose amide TFAA: C ₁₆-C ₁₈Alkyl N-methyl glucose amide TPKFA: C ₁₆-C ₁₈Top full cut lipid acid STPP: anhydrous sodium tripolyphosphate TSPP: tetrasodium pyrophosphate zeolite A: formula Na ₁₂(AlO ₂SiO ₂) ₁₂27H ₂The hydrated sodium aluminosilicate of O, just

The level granularity is 0.1-10 micron (weight of representing by moisture-free basis) NaSKS-6: formula δ-Na ₂Si ₂O ₅The crystalline layered silicate citric acid: Citric Acid, usp, Anhydrous Powder borate: Sodium Tetraborate carbonate: granularity is the anhydrous sodium carbonate supercarbonate of 200-900 micron: size-grade distribution is at the anhydrous sodium bicarbonate silicate of 400-1200 micron: amorphous sodium silicate (SiO ₂: Na ₂O ratio=2.0: 1) vitriol: anhydrous sodium sulphate sal epsom: anhydrous magnesium sulfate Citrate trianion: citrate trisodium dihydrate, activity 86.4%, size-grade distribution

At 425-850 micron MA/AA: 1: 4 toxilic acid/acrylic copolymer, the about 70000MA/AA of molecular-weight average (1): 4: 6 toxilic acid/acrylic copolymer, the about 10000AA of molecular-weight average: the polyacrylic acid sodium polymer CMC of molecular-weight average 4500: the plain ether of sodium carboxyme-thylcellulose fibre: the polymerization degree is 650 methyl cellulose ether, by Shin Etsu

Chemicals buys proteolytic enzyme: by Novo Industries A/S with trade(brand)name Savinase

The proteolytic ferment of selling, have 3.3% weight organized enzyme proteolytic enzyme I: the proteolytic ferment of describing in WO95/10591 has 4

% weight organized enzyme, sell Alcalase by Genencor Int.Inc.: by the proteolytic ferment of Novo Industries A/S sale,

Have 5.3% weight organized enzyme cellulase: by Novo Industries A/S with trade(brand)name Carezyme

The cellulase of selling has 0.23% weight organized enzyme amylase: by Novo Industries A/S with trade(brand)name Termamyl

The amylase that 120T sells has 1.6% weight organized enzyme amylase II: disclosed amylase lipase in PCT/US9703635: by Novo Industries A/S with trade(brand)name Lipolase

The lipolytic enzyme of selling has 2.0% weight organized enzyme lipase (1): by Novo Industries A/S with trade(brand)name Lipolase

The lipolytic enzyme that Ultra sells has 2.0% weight organized enzyme Endolase: endoglucanase, sell by Novo Industries A/S,

Has 1.5% weight organized enzyme PB4: nominal formula NaBO ₂3H ₂OH ₂O ₂Sodium perborate tetrahydrate PB1: nominal formula NaBO ₂H ₂O ₂Anhydrous sodium perborate SYNTHETIC OPTICAL WHITNER percarbonate: nominal formula 2Na ₂CO ₃3H ₂O ₂SPC-D DOBS: the last of the ten Heavenly stems acyloxy benzene sulfonate; sodium-salt form DPDA: diperoxy dodecanedioic acid NOBS: nonanoly acyloxy benzene sulfonate; sodium-salt form NACA-OBS: (6-nonanoyl amino caproyl) oxygen benzene sulfonate LOBS: 12 carbon alkanoyloxy benzene sulfonate DOBS of sodium-salt form: the acyloxy benzene sulfonate DOBA in the last of the ten Heavenly stems of sodium-salt form: caprinoyl aminobenzoic acid TAED: tetraacetyl ethylene diamine DTPA: diethylene triaminepentaacetic acid(DTPA) DTPMP: diethylenetriamine five (methylene phosphonic acid), by Meng Shan all with the merchant

Name of an article Dequest 2060 sells EDDS: quadrol-N, N '-disuccinic acid, (S, S) isomer, sodium salt

Floating of form photoactivation: the floating of sulfonated phthalocyanine zinc white agent (1) photoactivation of sealing with the dextrin soluble polymer: the white agent of aluminum phthalocyanine (2) whitening agent of sealing with the dextrin soluble polymer 1: 4,4 '-two (2-sulfo group styryl) biphenyl disodium whitening agent 2: 4,4 '-two (4-phenylaminos-6-morpholino-1,3,5-triazine-2-

Base) stilbene-2: 2 '-disulfonic acid disodium HEDP amino): hydroxyl ethane 1,1-di 2 ethylhexyl phosphonic acid HEDMP: hydroxyl ethane 1,1-dimethylene phosphonic acids PEG _x: polyoxyethylene glycol, molecular weight is x (general 4000) PEO: polyethylene oxide, molecular-weight average 50000TEPAE: ethoxylation tetren PVI: polyvinyl imidazol, molecular-weight average 20000PVP: polyvinylpyrrolidonepolymers polymers, molecular-weight average 60000PVNO: polyvinylpyridine N-oxide polymer, molecular-weight average

50000PVPVI: the multipolymer of Polyvinylpyrolidone (PVP) and vinyl imidazole is flat

Average molecular weight 20000QEA: two ((C ₂H ₅O)-(C ₂H ₄O) _n) (CH ₃)-N ⁺-C ₆H ₁₂-N ⁺-(CH ₃)

Two ((C ₂H ₅O)-(C ₂H ₄O)) _n, n=20-30SRP1 wherein: the end capped polyester SRP2 of negatively charged ion: the short block of diethoxyization poly-(terephthalic acid 1,2 inferior propyl ester)

Polymer P EI: polymine, molecular-weight average 1800, average ethoxylation

Degree disappears for 7 vinyloxy group residues of each nitrogen-atoms polysiloxane: polydimethylsiloxane foam control agent and as the poly-silica infusion alkane-oxyalkylene copolymers of dispersion agent, the weight of described foam control agent and described dispersion agent

Amount is than being 10: 1-100: 1 opalizer: water base single styrene latex mixture, and by BASF

Aktiengesellschaft sells waxes with trade(brand)name Lytron 621: paraffin look grain: at the look grain described in the 40th page in this paper

In following embodiment, all content are represented by the % of composition weight meter: embodiment 1

Following detergent formulation is according to prescription of the present invention:

	????A	????B	????C	????D
	????A	????B	????C	????D	The powder of blowing
????MES	????2.0	????0.5	????1.0	?????-	The powder of blowing
????MES	????2.0	????0.5	????1.0	?????-	????SADS	?????-	?????-	?????-	????2.0
????LAS	????6.0	????5.0	????11.0	????6.0	????SADS	?????-	?????-	?????-	????2.0
????LAS	????6.0	????5.0	????11.0	????6.0	????TAS	????2.0	?????-	?????-	????2.0
Zeolite A	????24.0	?????-	?????-	????20.0	????TAS	????2.0	?????-	?????-	????2.0
Zeolite A	????24.0	?????-	?????-	????20.0	????STPP	?????-	????27.0	????24.0	??????-
Vitriol	????4.0	????6.0	????13.0	??????-	????STPP	?????-	????27.0	????24.0	??????-
Vitriol	????4.0	????6.0	????13.0	??????-	????MA/AA	????1.0	????4.0	????6.0	????2.0

Silicate	????1.0	????7.0	????3.0	????3.0
Silicate	????1.0	????7.0	????3.0	????3.0	????CMC	????1.0	????1.0	????0.5	????0.6
Whitening agent 1	????0.2	????0.2	????0.2	????0.2	????CMC	????1.0	????1.0	????0.5	????0.6
Whitening agent 1	????0.2	????0.2	????0.2	????0.2	Polysiloxane defoamers	????1.0	????1.0	????1.0	????0.3
????DTPMP	????0.4	????0.4	????0.2	????0.4	Polysiloxane defoamers	????1.0	????1.0	????1.0	????0.3
????DTPMP	????0.4	????0.4	????0.2	????0.4	Spray
Whitening agent	????0.02	????-	????-	????0.02	Spray
Whitening agent	????0.02	????-	????-	????0.02	????C45E7	?????-	????-	????-	????5.0
????C45E2	????2.5	????2.5	????2.0	????-	????C45E7	?????-	????-	????-	????5.0
????C45E2	????2.5	????2.5	????2.0	????-	????C45E3	????2.6	????2.5	????2.0	????-
Spices	????0.5	????0.3	????0.5	????0.2	????C45E3	????2.6	????2.5	????2.0	????-
Spices	????0.5	????0.3	????0.5	????0.2	Polysiloxane defoamers	????0.3	????0.3	????0.3	????-
Dried additive					Polysiloxane defoamers	????0.3	????0.3	????0.3	????-
Dried additive					????QEA	?????-	????-	????-	????1.0
????EDDS	????0.3	????-	????-	????-	????QEA	?????-	????-	????-	????1.0
????EDDS	????0.3	????-	????-	????-	Vitriol	????2.0	????3.0	????5.0	????10.0
Carbonate	????6.0	????13.0	????15.0	????14.0	Vitriol	????2.0	????3.0	????5.0	????10.0
Carbonate	????6.0	????13.0	????15.0	????14.0	Citric acid	????2.5	????-	????-	????2.0
????QASII	????0.5	????-	????-	????0.5	Citric acid	????2.5	????-	????-	????2.0
????QASII	????0.5	????-	????-	????0.5	????SKS-6	????10.0	????-	????-	????-
Percarbonate	????4.0	????3.0	????-	????1.9	????SKS-6	????10.0	????-	????-	????-
Percarbonate	????4.0	????3.0	????-	????1.9	????PB4	?????-	????-	????5.0
????NOBS	????0.5	????-	????-	????0.3	????PB4	?????-	????-	????5.0
????NOBS	????0.5	????-	????-	????0.3	????TAED	????0.75	????0.5	????0.2	????0.5
????DOBS	????-	????0.5	????0.6	????-	????TAED	????0.75	????0.5	????0.2	????0.5
????DOBS	????-	????0.5	????0.6	????-	Proteolytic enzyme	????1.0	????1.0	????1.0	????1.0
Lipase	????-	????0.4	????-	????0.2	Proteolytic enzyme	????1.0	????1.0	????1.0	????1.0
Lipase	????-	????0.4	????-	????0.2	Lipase (1)	????0.4	????-	????0.4	????-
Amylase	????0.2	????0.2	????0.2	????0.4	Lipase (1)	????0.4	????-	????0.4	????-
Amylase	????0.2	????0.2	????0.2	????0.4	Whitening agent 1	????0.05	????-	????-	????0.05
Trace/a small amount of component to 100%					Whitening agent 1	????0.05	????-	????-	????0.05

Embodiment 2

Following granulated detergent prescription is according to prescription of the present invention:

	????E	????F	????G	??H	????I	????J
	????E	????F	????G	??H	????I	????J	The powder of blowing
????LAS	??23.0	????8.0	????7.0	??9.0	????7.0	???7.0	The powder of blowing
????LAS	??23.0	????8.0	????7.0	??9.0	????7.0	???7.0	????QAS	???-	?????-	?????-	???-	????1.0	?????-
????C45AS	???6.0	????6.0	????5.0	???8.0	?????-	?????-	????QAS	???-	?????-	?????-	???-	????1.0	?????-
????C45AS	???6.0	????6.0	????5.0	???8.0	?????-	?????-	????C45AE11S	???-	????1.0	????1.0	???1.0	?????-	?????-
????MES	???2.0	?????-	?????-	????-	????2.0	????4.0	????C45AE11S	???-	????1.0	????1.0	???1.0	?????-	?????-
????MES	???2.0	?????-	?????-	????-	????2.0	????4.0	Zeolite A	??10.0	??18.0	????14.0	??12.0	????10.0	????10.0
????MA/AA	???-	???0.5	?????-	????-	?????-	????2.0	Zeolite A	??10.0	??18.0	????14.0	??12.0	????10.0	????10.0
????MA/AA	???-	???0.5	?????-	????-	?????-	????2.0	????MA/AA(1)	???7.0	????-	?????-	????-	?????-	?????-
????AA	???-	????3.0	????3.0	????2.0	????3.0	????3.0	????MA/AA(1)	???7.0	????-	?????-	????-	?????-	?????-
????AA	???-	????3.0	????3.0	????2.0	????3.0	????3.0	Vitriol	???5.0	????6.3	????11.1	???11.0	????11.0	????18.1
Silicate	??10.0	????1.0	????1.0	????1.0	????1.0	????1.0	Vitriol	???5.0	????6.3	????11.1	???11.0	????11.0	????18.1
Silicate	??10.0	????1.0	????1.0	????1.0	????1.0	????1.0	Carbonate	??15.0	????20.0	????10.0	???20.7	????8.0	????6.0
????PEG4000	???0.4	?????1.5	????1.5	????1.0	????1.0	????1.0	Carbonate	??15.0	????20.0	????10.0	???20.7	????8.0	????6.0
????PEG4000	???0.4	?????1.5	????1.5	????1.0	????1.0	????1.0	????DTPA	???-	?????0.9	????0.5	????-	?????-	????0.5
Whitening agent 2	???0.3	?????0.2	????0.3	????-	????0.1	????0.3	????DTPA	???-	?????0.9	????0.5	????-	?????-	????0.5
Whitening agent 2	???0.3	?????0.2	????0.3	????-	????0.1	????0.3	Spray
????C45E7	???-	????2.0	?????-	????-	??2.0	??2.0	Spray
????C45E7	???-	????2.0	?????-	????-	??2.0	??2.0	????C25E9	???3.0	????-	?????-	????-	???-	?????-
????C23E9	???-	????-	????1.5	????2.0	???-	????2.0	????C25E9	???3.0	????-	?????-	????-	???-	?????-
????C23E9	???-	????-	????1.5	????2.0	???-	????2.0	Spices	??0.3	???0.3	????0.3	????2.0	????0.3	????0.3
Agglomerate							Spices	??0.3	???0.3	????0.3	????2.0	????0.3	????0.3
Agglomerate							????C45AS	??-	???5.0	????5.0	????2.0	????-	????5.0

????LAS	????-	????2.0	????2.0	????-	????-	????2.0
????LAS	????-	????2.0	????2.0	????-	????-	????2.0	Zeolite A	????-	????7.5	????7.5	????8.0	????-	????7.5
Carbonate	????-	????4.0	????4.0	????5.0	????-	????4.0	Zeolite A	????-	????7.5	????7.5	????8.0	????-	????7.5
Carbonate	????-	????4.0	????4.0	????5.0	????-	????4.0	????PEG4000	????-	????0.5	????0.5	????-	????-	????0.5
Minor component (water etc.)	????-	????2.0	????2.0	????2.0	????-	????2.0	????PEG4000	????-	????0.5	????0.5	????-	????-	????0.5
Minor component (water etc.)	????-	????2.0	????2.0	????2.0	????-	????2.0	Dried additive
????QAS?(I)	????-	????-	?????-	?????-	????1.0	????-	Dried additive
????QAS?(I)	????-	????-	?????-	?????-	????1.0	????-	Citric acid	????-	????-	?????-	?????-	????2.0	????-
????PB4	????-	????3.0	?????-	?????-	????5	????-	Citric acid	????-	????-	?????-	?????-	????2.0	????-
????PB4	????-	????3.0	?????-	?????-	????5	????-	????PB1	????-	????-	????4	????1.0	????-	????-
Percarbonate	????2.0	????-	?????-	????1.0	????-	????2.0	????PB1	????-	????-	????4	????1.0	????-	????-
Percarbonate	????2.0	????-	?????-	????1.0	????-	????2.0	Carbonate	????-	????5.3	????1.8	?????-	????4.0	????4.0
????NOBS	????0.5	????-	????0.4	????0.3	????-	????0.6	Carbonate	????-	????5.3	????1.8	?????-	????4.0	????4.0
????NOBS	????0.5	????-	????0.4	????0.3	????-	????0.6	????DOBS	????-	????0.9	?????-	?????-	????0.3	?????-
????TAED	????0.6	????0.4	????0.6	????0.3	????0.9	????0.5	????DOBS	????-	????0.9	?????-	?????-	????0.3	?????-
????TAED	????0.6	????0.4	????0.6	????0.3	????0.9	????0.5	Methylcellulose gum	????0.2	????-	?????-	?????-	????-	????0.5
????DTPA	????0.7	????0.5	????1.0	????0.5	????0.5	????1.2	Methylcellulose gum	????0.2	????-	?????-	?????-	????-	????0.5
????DTPA	????0.7	????0.5	????1.0	????0.5	????0.5	????1.2
????SKS-6	????8.0	????-	?????-	?????-	????-	????-
????SKS-6	????8.0	????-	?????-	?????-	????-	????-	????STS	????-	????-	????2.0	?????-	????1.0	????-
Cumene sulfonic acid	????-	????1.0	?????-	?????-	????-	????2.0	????STS	????-	????-	????2.0	?????-	????1.0	????-
Cumene sulfonic acid	????-	????1.0	?????-	?????-	????-	????2.0	Lipase	????0.2	????-	????0.2	?????-	????0.2	????0.4
Cellulase	????0.2	????0.2	????0.2	????0.3	????0.2	????0.2	Lipase	????0.2	????-	????0.2	?????-	????0.2	????0.4
Cellulase	????0.2	????0.2	????0.2	????0.3	????0.2	????0.2	Amylase II	????0.2	????-	????0.1	?????-	????0.2	????-
Proteolytic enzyme	????0.5	????0.5	????0.5	????0.3	????0.5	????0.5	Amylase II	????0.2	????-	????0.1	?????-	????0.2	????-
Proteolytic enzyme	????0.5	????0.5	????0.5	????0.3	????0.5	????0.5	????PVPVI	????-	????-	?????-	?????-	????0.5	????0.1
????PVP	????-	????-	?????-	?????-	????0.5	????-	????PVPVI	????-	????-	?????-	?????-	????0.5	????0.1
????PVP	????-	????-	?????-	?????-	????0.5	????-	????PVNO	????-	????-	????0.5	????0.3	????-	????-
????QEA	????-	????-	?????-	?????-	????1.0	????-	????PVNO	????-	????-	????0.5	????0.3	????-	????-

????SRP1	????0.2	????0.5	????0.3	?????-	????0.2	????-
????SRP1	????0.2	????0.5	????0.3	?????-	????0.2	????-	Polysiloxane defoamers	????0.2	????0.4	????0.2	????0.4	????0.1	????-
Sal epsom	???-	?????-	????0.2	?????-	????0.2	????-	Polysiloxane defoamers	????0.2	????0.4	????0.2	????0.4	????0.1	????-
Sal epsom	???-	?????-	????0.2	?????-	????0.2	????-	Spot jewelry	???-	????2.0	????1.0	????0.5	????2.0	????6.0
Trace/a small amount of component to 100%							Spot jewelry	???-	????2.0	????1.0	????0.5	????2.0	????6.0

Embodiment 3

	????K	????L	????M	????N
	????K	????L	????M	????N	The base-material particle
????STPP	????-	????22.0	?????-	????15.0	The base-material particle
????STPP	????-	????22.0	?????-	????15.0	Zeolite A	????30.0	?????-	????24.0	????5.0
Vitriol	????5.5	????5.0	????7.0	????7.0	Zeolite A	????30.0	?????-	????24.0	????5.0
Vitriol	????5.5	????5.0	????7.0	????7.0	????MA/AA	????3.0	?????-	?????-	????-
????AA	?????-	????1.6	????2.0	????-	????MA/AA	????3.0	?????-	?????-	????-
????AA	?????-	????1.6	????2.0	????-	????MA/AA(1)	?????-	????12.0	?????-	????6.0
????LAS	????14.0	????10.0	????9.0	???20.0	????MA/AA(1)	?????-	????12.0	?????-	????6.0
????LAS	????14.0	????10.0	????9.0	???20.0	????C45AS	????8.0	????7.0	????9.0	????7.0
????C45AE11S	????-	????1.0	?????-	????1.0	????C45AS	????8.0	????7.0	????9.0	????7.0
????C45AE11S	????-	????1.0	?????-	????1.0	????MES	????0.5	????4.0	????6.0	?????-
????SADS	????2.5	?????-	?????-	????1.0	????MES	????0.5	????4.0	????6.0	?????-
????SADS	????2.5	?????-	?????-	????1.0	Silicate	?????-	????1.0	????0.5	????10.0
Soap	?????-	????2.0	?????-	?????-	Silicate	?????-	????1.0	????0.5	????10.0
Soap	?????-	????2.0	?????-	?????-	Whitening agent 1	????0.2	????0.2	????0.2	????0.2
Carbonate	????6.0	????9.0	????8.0	????10.0	Whitening agent 1	????0.2	????0.2	????0.2	????0.2
Carbonate	????6.0	????9.0	????8.0	????10.0	????PEG4000	?????-	????1.0	????1.5	?????-
????DTPA	?????-	????0.4	?????-	?????-	????PEG4000	?????-	????1.0	????1.5	?????-

Spray
Spray					????C25E9	????-	?????-	?????-	????5.0
????C45E7	????1.0	????1.0	?????-	?????-	????C25E9	????-	?????-	?????-	????5.0
????C45E7	????1.0	????1.0	?????-	?????-	????C23E9	????-	????1.0	????2.5	?????-
Spices	????0.2	????0.3	????0.3	?????-	????C23E9	????-	????1.0	????2.5	?????-
Spices	????0.2	????0.3	????0.3	?????-	Dried additive
Carbonate	????5.0	????10.0	????13.0	????8.0	Dried additive
Carbonate	????5.0	????10.0	????13.0	????8.0	????PVPVI/PVNO	????0.5	?????-	????0.3	?????-
Proteolytic enzyme	????1.0	????1.0	????1.0	????0.5	????PVPVI/PVNO	????0.5	?????-	????0.3	?????-
Proteolytic enzyme	????1.0	????1.0	????1.0	????0.5	Lipase	????0.4	?????-	????-	????0.4
Amylase	????0.1	?????-	????1	????0.1	Lipase	????0.4	?????-	????-	????0.4
Amylase	????0.1	?????-	????1	????0.1	Cellulase	????0.1	?????0.2	????0.2	????0.1
????DTPA/HEDP	????0.5	?????0.3	????0.5	????1.0	Cellulase	????0.1	?????0.2	????0.2	????0.1
????DTPA/HEDP	????0.5	?????0.3	????0.5	????1.0	????LOBS	?????-	?????0.8	?????-	????0.3
????PB1	????5	?????3.0	????10	????4.0	????LOBS	?????-	?????0.8	?????-	????0.3
????PB1	????5	?????3.0	????10	????4.0	????DOBA	????1.0	??????-	????0.4	????-
????TAED	????0.5	?????0.3	????0.5	????0.6	????DOBA	????1.0	??????-	????0.4	????-
????TAED	????0.5	?????0.3	????0.5	????0.6	Vitriol	????4.0	?????5.0	????-	????5.0
????SRPI	?????-	?????0.4	????-	?????-	Vitriol	????4.0	?????5.0	????-	????5.0
????SRPI	?????-	?????0.4	????-	?????-	Suds suppressor	?????-	?????0.5	????-	?????-
Spot jewelry	????1.0	?????0.5	????-	????5.0	Suds suppressor	?????-	?????0.5	????-	?????-
Spot jewelry	????1.0	?????0.5	????-	????5.0	Trace/a small amount of component to 100%

Embodiment 4

Following composition is according to pretreatment compositions of the present invention:

	????O	????P	????Q	????R	????S	????T	????U
	????O	????P	????Q	????R	????S	????T	????U	?MES	????1.0	????2.0	????0.8	????4.0	???-	??-	??-


								C45E7	????6.5	????7.5	?????-	????-	?????-	?????-	?????-
C23E3	?????-	????2.0	????5.0	????5.0	????7.0	????9.0	????3.0	C45E7	????6.5	????7.5	?????-	????-	?????-	?????-	?????-
C23E3	?????-	????2.0	????5.0	????5.0	????7.0	????9.0	????3.0	C25E2.5S	???10.0	???14.0	???17.0	????8.0	????5.0	????15.0	????20.0
SADS	?????-	????-	????3.0	?????-	????1.0	????1.0	????2.0	C25E2.5S	???10.0	???14.0	???17.0	????8.0	????5.0	????15.0	????20.0
SADS	?????-	????-	????3.0	?????-	????1.0	????1.0	????2.0	Acetyl triethyl citrate	????3.5	????4.0	????2.5	?????-	?????-	????3.0	????3.5
Percarbonate	?????-	?????-	????3.0	????2.0	????3.0	?????-	????-	Acetyl triethyl citrate	????3.5	????4.0	????2.5	?????-	?????-	????3.0	????3.5
Percarbonate	?????-	?????-	????3.0	????2.0	????3.0	?????-	????-	Perborate	????2.0	????3.0	?????-	?????-	?????-	????1.0	????5.0
NACA-OBS	?????-	????0.3	?????-	?????-	?????-	????0.6	????0.4	Perborate	????2.0	????3.0	?????-	?????-	?????-	????1.0	????5.0
NACA-OBS	?????-	????0.3	?????-	?????-	?????-	????0.6	????0.4	NOBS/LOBS/ DOBS	????1.0	????-	????1.0	????0.2	????0.4	?????-	?????-
TAED	????0.5	????0.6	????0.3	????0.8	????0.9	????0.4	????0.7	NOBS/LOBS/ DOBS	????1.0	????-	????1.0	????0.2	????0.4	?????-	?????-
TAED	????0.5	????0.6	????0.3	????0.8	????0.9	????0.4	????0.7	Sequestrant	????0.3	????0.5	????-	?????-	????0.2	????-	????0.8
Water and a small amount of component H ₂SO ₄As many as pH4								Sequestrant	????0.3	????0.5	????-	?????-	????0.2	????-	????0.8

Embodiment 5

????????????????????????????????????????V????????W???????X????????Y???????Z						?AA	?BB
						?AA	?BB	??C ₁₁-C ₁₃Sodium alkyl benzene sulfonate	?12.0	?16.0	?23.0	??19	??18.0	??20.0	??16.0
??C ₁₄-C ₁₅Alcohol sodium sulfate		??4.5	???-		???-	????-	??4.0	??C ₁₁-C ₁₃Sodium alkyl benzene sulfonate	?12.0	?16.0	?23.0	??19	??18.0	??20.0	??16.0
??C ₁₄-C ₁₅Alcohol sodium sulfate		??4.5	???-		???-	????-	??4.0	??C ₁₄-C ₁₅Alcohol ethoxylate (0.5) vitriol			???-	??-	???-	????-	???-
??C ₁₄-C ₁₅Alcohol ethoxylate (3) vitriol	???-	???-	??2.0	??-	??1.0	??1.0	??1.0	??C ₁₄-C ₁₅Alcohol ethoxylate (0.5) vitriol			???-	??-	???-	????-	???-
??C ₁₄-C ₁₅Alcohol ethoxylate (3) vitriol	???-	???-	??2.0	??-	??1.0	??1.0	??1.0	??C ₁₄-C ₁₅Alcohol ethoxylate (3.0) sodium	??2.0	??2.0	???-	??1.3	???-	????-	??0.6
??C ₉-C ₁₄The alkyl dimethyl ethoxyl quaternary ammonium salt			????-	??-	??1.0	??0.5	??2.0	??C ₁₄-C ₁₅Alcohol ethoxylate (3.0) sodium	??2.0	??2.0	???-	??1.3	???-	????-	??0.6
			????-	??-	??1.0	??0.5	??2.0	Tallow fatty acid			???-	??-	???-	????-	??1.0
Tallow alcohol ethoxylate (50)	???-	???-	???-	??-	???-	????-	????-	Tallow fatty acid			???-	??-	???-	????-	??1.0
Tallow alcohol ethoxylate (50)	???-	???-	???-	??-	???-	????-	????-	Tripoly phosphate sodium STPP	??23.0	??25.0	??24.0	??22，0	??20.0	??15.0	??20.0
Yellow soda ash	??15.0	??12.0	??15.0	??10.0	??13.0	??11.0	??10.0	Tripoly phosphate sodium STPP	??23.0	??25.0	??24.0	??22，0	??20.0	??15.0	??20.0
Yellow soda ash	??15.0	??12.0	??15.0	??10.0	??13.0	??11.0	??10.0	Sodium polyacrylate (45%)	??0.5	??0.5	??0.5	??0.5	???-	????-	????-
Sodium polyacrylate/sodium maleate polymkeric substance	???-	???-	??1.0	??1.0	??1.0	??2.0	??0.5	Sodium polyacrylate (45%)	??0.5	??0.5	??0.5	??0.5	???-	????-	????-
Sodium polyacrylate/sodium maleate polymkeric substance	???-	???-	??1.0	??1.0	??1.0	??2.0	??0.5	Water glass (NaO/SiO ₂Than being 1: 6) (46%)	??3.0	??6.0	??9.0	??8.0	??9.0	??6.0	??8.0
Sodium sulfate	?25.0	?18.0	?20.0	?18.0	?20.0	?22.0	?13.0	Water glass (NaO/SiO ₂Than being 1: 6) (46%)	??3.0	??6.0	??9.0	??8.0	??9.0	??6.0	??8.0
Sodium sulfate	?25.0	?18.0	?20.0	?18.0	?20.0	?22.0	?13.0	Sodium peroxoborate	??5.0	?5.0	?10.0	??8.0	??3.0	?1.0	??2.0
Poly-(ethylene glycol), MW～4000 (50%)	??1.5	??1.5	??1.0	??1.0	???-	??-	??0.5	Sodium peroxoborate	??5.0	?5.0	?10.0	??8.0	??3.0	?1.0	??2.0
Poly-(ethylene glycol), MW～4000 (50%)	??1.5	??1.5	??1.0	??1.0	???-	??-	??0.5	Xylo-Mucine	??1.0	??1.0	??1.0	??-	??0.5	??0.5	??0.5

Citric acid	???-	??-	???-	???-	???-	???-	???-
Citric acid	???-	??-	???-	???-	???-	???-	???-	NOBS/DOBS	??0.5	??1.0	??0.5	??0.5	??1.0	??0.7	??0.3
TAED	??1.5	??1.0	??2.5	??3.0	??0.3	??0.2	??0.5	NOBS/DOBS	??0.5	??1.0	??0.5	??0.5	??1.0	??0.7	??0.3
TAED	??1.5	??1.0	??2.5	??3.0	??0.3	??0.2	??0.5	The dirt release agent polymkeric substance ¹	??1.5	??1.5	??1.0	??1.0	???-	??1.0	???-
The dirt release agent polymkeric substance ²	???-	????-	???-	???-	??1.0	???-	??1.0	The dirt release agent polymkeric substance ¹	??1.5	??1.5	??1.0	??1.0	???-	??1.0	???-
The dirt release agent polymkeric substance ²	???-	????-	???-	???-	??1.0	???-	??1.0	Moisture	??7.5	??7.5	??6.0	??7.0	??5.0	??3.0	??5.0
Sal epsom	???-	????-	???-	???-	??1.0	??0.5	??1.5	Moisture	??7.5	??7.5	??6.0	??7.0	??5.0	??3.0	??5.0
Sal epsom	???-	????-	???-	???-	??1.0	??0.5	??1.5	Spot jewelry	??0.5	??3.0	???-	??5.0	??2.0	???-	??0.2
Sequestrant	???-	????-	???-	???-	??0.8	??0.6	??1.0	Spot jewelry	??0.5	??3.0	???-	??5.0	??2.0	???-	??0.2
Sequestrant	???-	????-	???-	???-	??0.8	??0.6	??1.0	Enzyme comprises amylase, amylase II, cellulase, proteolytic enzyme and lipase	???-	????-	???-	???-	??2.0	??1.5	??2.0
A small amount of component, for example spices, whitening agent, optical white, dyestuff	??1.0	??1.0	??1.0	??1.0	??0.5	??1.5	??1.0		???-	????-	???-	???-	??2.0	??1.5	??2.0

1. according to the Gosselink that authorizes May 16 nineteen ninety-five, Pan, the non-cotton goods dirt release agent polymkeric substance of the U.S. Pat 5415807 of Kellett and Hall.2. according to the non-cotton goods dirt release agent polymkeric substance of Application No. 60/051517.Embodiment 6

CC???????DD??????EE???????FF

C ₁₁-C ₁₃Sodium alkyl benzene sulfonate	?13.3	?13.7	?10.4	?8.0
C ₁₁-C ₁₃Sodium alkyl benzene sulfonate	?13.3	?13.7	?10.4	?8.0	C ₁₄-C ₁₅Alcohol sodium sulfate	??3.9	??4.0	??4.5	??-
C ₁₄-C ₁₅Alcohol ethoxylate (0.5) vitriol	??2.0	??2.0	???-	??-	C ₁₄-C ₁₅Alcohol sodium sulfate	??3.9	??4.0	??4.5	??-
C ₁₄-C ₁₅Alcohol ethoxylate (0.5) vitriol	??2.0	??2.0	???-	??-	C ₁₄-C ₁₅Alcohol ethoxylate (3) vitriol	???-	??-	???-	??-
C ₁₄-C ₁₅Alcohol ethoxylate (6.5) sodium	??0.5	??0.5	?0.5	?5.0	C ₁₄-C ₁₅Alcohol ethoxylate (3) vitriol	???-	??-	???-	??-

C ₉-C ₁₄The alkyl dimethyl ethoxyl quaternary ammonium salt	??1.0	???-	???-	?0.5
C ₉-C ₁₄The alkyl dimethyl ethoxyl quaternary ammonium salt	??1.0	???-	???-	?0.5	Tallow fatty acid	??0.5	???-	???-	??-
Tallow alcohol ethoxylate (50)	???-	???-	??1.0	??0.3	Tallow fatty acid	??0.5	???-	???-	??-
Tallow alcohol ethoxylate (50)	???-	???-	??1.0	??0.3	Tripoly phosphate sodium STPP	???-	?41.0	???-	?20.0
Zeolite A, hydrate (0.1-10 micron)	??26.3	???-	?21.3	??1.0	Tripoly phosphate sodium STPP	???-	?41.0	???-	?20.0
Zeolite A, hydrate (0.1-10 micron)	??26.3	???-	?21.3	??1.0	Yellow soda ash	??23.9	?12.4	?25.2	?17.0
Sodium polyacrylate (45%)	??3.4	??0.0	??2.7	???-	Yellow soda ash	??23.9	?12.4	?25.2	?17.0
Sodium polyacrylate (45%)	??3.4	??0.0	??2.7	???-	Sodium polyacrylate/sodium maleate polymkeric substance	???-	???-	??1.0	??1.5
Water glass (NaO/SiO ₂Than being 1: 6) (46%)	??2.4	??6.4	??2.1	???6.0	Sodium polyacrylate/sodium maleate polymkeric substance	???-	???-	??1.0	??1.5
Water glass (NaO/SiO ₂Than being 1: 6) (46%)	??2.4	??6.4	??2.1	???6.0	Sodium sulfate	??10.5	??10.9	??8.2	??15.0
Sodium peroxoborate	??1.0	???1.0	??1.0	??2.0	Sodium sulfate	??10.5	??10.9	??8.2	??15.0
Sodium peroxoborate	??1.0	???1.0	??1.0	??2.0	Poly-(ethylene glycol), MW～4000 (50%)	??1.7	???0.4	??1.0	???-
Xylo-Mucine	??1.0	????-	???-	??0.3	Poly-(ethylene glycol), MW～4000 (50%)	??1.7	???0.4	??1.0	???-
Xylo-Mucine	??1.0	????-	???-	??0.3	Citric acid	???-	????-	??3.0	???-
????NOBS/DOBS	??0.2	???0.5	??0.5	??0.1	Citric acid	???-	????-	??3.0	???-
????NOBS/DOBS	??0.2	???0.5	??0.5	??0.1	????TAED	??0.6	???0.5	??0.4	??0.3
Dirt release agent polymkeric substance 1	??1.5	????-	???-	???-	????TAED	??0.6	???0.5	??0.4	??0.3
Dirt release agent polymkeric substance 1	??1.5	????-	???-	???-	Dirt release agent polymkeric substance 2	???-	???1.5	??1.0	??1.0
Moisture	??7.5	???3.1	??6.1	??7.3	Dirt release agent polymkeric substance 2	???-	???1.5	??1.0	??1.0
Moisture	??7.5	???3.1	??6.1	??7.3	Sal epsom	???-	????-	???-	??1.0
Sequestrant	???-	????-	???-	??0.5	Sal epsom	???-	????-	???-	??1.0

Enzyme comprises amylase, amylase II, cellulase, proteolytic enzyme and lipase	???-	??1.0	???-	??1.5
	???-	??1.0	???-	??1.5	A small amount of component, for example spices, whitening agent, optical white, dyestuff	??1.0	??1.0	??1.0	??1.0

1. according to the non-cotton goods dirt release agent polymkeric substance of the U.S. Pat 4968451 of the Scheibel that authorizes November 6 nineteen ninety etc.2. according to the non-cotton goods dirt release agent polymkeric substance of Application No. 60/051517.

Claims

1. detergent composition, its density is 330 grams per liters-700 grams per liters, comprise and contain bleach system hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or its precursor and peroxide source, be characterised in that weight by composition, the total amount of the available oxygen (AvO-a) that obtains from hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER is lower than 5000ppm, the available oxygen of hydrophobic peracids or precursor (AvO-hb) is 3 with the ratio of the available oxygen (AvO-hp) of hydrophilic peracid or precursor: 1-1: 50, and the available oxygen of peroxide source (AvO-o) was at least 2: 1 with the ratio of AvO-a.

2. according to the detergent composition of claim 1, wherein hydrophilic bleach precursor comprises TAED.

3. according to the detergent composition of claim 2, wherein hydrophobic peracids or precursor comprise the hydrophobic group that is obtained by the lipid acid that contains at least 8 carbon atoms, preferably have the peracid precursors of hydroxy benzene sulfonate leavings group.

4. according to the detergent composition of any aforesaid right requirement, wherein the ratio of AvO-o and AvO-a was at least 3: 1, more preferably was at least 4: 1.

5. according to the detergent composition of claim 1 or 2, it comprises phosphate builders.

6. according to the detergent composition of any aforesaid right requirement, wherein the peroxide source SYNTHETIC OPTICAL WHITNER comprises one or more inorganic perhydrate salt, preferred perborate or percarbonate.

7. according to the detergent composition of any aforesaid right requirement, it comprises one or more enzymes, preferred at least a amylase.

8. one kind is used the method according to the detergent composition hand washing clothes of aforesaid right requirement arbitrarily.

9. one kind with detergent composition pre-treatment that requires according to any aforesaid right or the method for soaking clothes.

10. use bleaching composition to reduce the purposes of bacterial activity, wherein said composition comprises hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or its precursor and peroxide source, the available oxygen (AvO-hb) that is characterised in that hydrophobic peracids or precursor is 3 with the ratio of the available oxygen (AvO-hp) of hydrophilic peracid or precursor: 1-1: 50, the available oxygen of peroxide source (AvO-o) was at least 2: 1 with the ratio of the total amount of the available oxygen (AvO-a) that obtains from hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER, SYNTHETIC OPTICAL WHITNER preferably with AvO-a be lower than 10000ppm or even the amount of 5000ppm be present in the detergent composition.

11. method with fabric and a kind of composition or composition solution contact sterilizing fabric, described composition comprises hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER or its precursor and peroxide source, the available oxygen (AvO-hb) that is characterised in that hydrophobic peracids or precursor is 3 with the ratio of the available oxygen (AvO-hp) of hydrophilic peracid or precursor: 1-1: 50, and the available oxygen of peroxide source (AvO-o) was at least 2: 1 with the ratio of the total amount of the available oxygen (AvO-a) that obtains from hydrophilic and hydrophobic peracids SYNTHETIC OPTICAL WHITNER.