CN1260827A - Foaming component - Google Patents

Abstract

The invention provides a substantially anhydrous foaming component, capable of providing foaming or sudsing without agitation, comprising intimately mixed, an effervescence component capable of producing a gas upon contact with water, and a substantially anhydrous surface active component, capable of reducing the surface tension. The compositions are in particular useful in solid cleaning compositions, solid pharmaceutical compositions and solid food and beverage products.

Description

Foaming component

Technical field

The present invention relates to a kind of foaming composition, it needing to be used for any application examples of foamy such as cleaning combination, pharmaceutical composition, food and drink.

Background of invention

Since different, in various application, all need to form foam or foaming.In washing composition, known specific tensio-active agent can provide foaming in washing water.

It is desirable that foaming easily or foaming and this foaming or foaming have the needed time length.For example, it is desirable to: when contacting, bubble, become bubble or foaming immediately, and be stable or lasting during use with water.

In addition, in order to make the foaming when contacting in use of these technology, to become bubble or latherability maximum, making or should avoid contacting between the shelf lives with water or moisture with water.

One reacts that to produce blistered component be known detergent component when contacting with water.For example, WO92/18596 disclose contain blended citric acid and sodium carbonate salt as auxiliary agent to improve the washing composition of detergent dissolution.The foaming system also is widely known in medicine or agricultural application, as described in the GB-A-2184946.

The inventor has now found that: can use to provide the foaming of gas component to produce foaming or foaming, when its with can reduce capillary surface active composition the time with specific being used in combination, cause obtain controllable, fast, improved foaming and/or foaming.When contacting with water, the described component that contains specific foaming component and particular surface active ingredient can chemical reaction forms the microvesicle that preferably has 200 microns or littler mean diameter.The inventor has been found that forming these microvesicles can improve one-tenth bubble or foaming or blistered control, and causes improved foaming or foaming stability, for example, and that can be formed fast and stable or long-time foam or the bubble that continues.In addition, find: component of the present invention makes this component or the product that contains this component have improved foaming and dispersiveness and solvability.

In addition, find that also these components are very stable when storing.

Summary of the invention

The invention provides anhydrous basically need not to stir just can provide foam or blistered foaming component, it contains tight blended and can produce the foaming component of gas and anhydrous basically can reduce the capillary surface active composition of air-water when contacting with water.

Can be used for into bubble, foaming or foaming method according to the mixture of component of the present invention or different foaming components is useful any application.Especially, this component can be used for: preferred solid cleaning combination, medicament production, makeup and solid food or drink product, can be used for need not stirring with this component or may or the application of the limited stirring of needs, for example hand-wash detergent composition and soak in the composition.

Detailed Description Of The Invention

Foaming component of the present invention need not to stir just can provide foaming or foaming.Should understand: for purpose of the present invention, when using " foaming " speech herein, it refers to the formation that forms any type of bubble, comprises into bubble and foaming.Will also be appreciated that for the object of the invention stirring can be an ideal.

Foaming component of the present invention and surface active composition and preferred foaming component are anhydrous basically.

When being used for herein, " anhydrous basically " refers to the free water content that has no more than 5% weight, and preferred no more than 4%, more preferably no more than 3%, most preferably no more than 2% or even 1% weight.Free water content used herein can be put in the Petri dish and this Petri dish is placed in 50 ℃ the convection oven 2 hours by the component that 5g is anhydrous basically, measures then because the weightlessness that moisture evaporation causes is determined.

This foaming component and surface active composition are tight blended.When being used for herein, " closely mixing/blended " or " intimate mixture " refer to: for the object of the invention, each component of foaming component is in this foaming component basically equably.

The intimate mixture of each component of foaming component of the present invention can obtain by any method, and these methods comprise mixes each component, and it can be a part of making sheet method, pressing method and agglomeration method.Preferably, this particle is to prepare by such method: the melts of surface active composition is mixed in the foaming component, thereby afterwards this mixture solidified is formed foaming component, preferably by this melt is solidified, preferably by reducing technological temperature.When the foaming component contains more than a kind of component, preferred each component of pre-mixing.In the time will being incorporated into additional component in this component, preferably with the melt-mixing of surface active composition in additional component and foaming component, its preferably before mixing this melt by pre-mixing, thereby before adding melt, obtain the intimate mixture of each component.

Foaming component of the present invention preferably contains foaming component and surface active composition, causing and chemically produce mean diameter when contacting with water is 400 microns or littler, preferred 200 microns or littler, more preferably 150 microns or littler, most preferably 100 microns or littler or and even 50 microns or littler gas microbubbles, this can realize by closely mixing each component.

As described herein, foaming component or the composition that contains this component also can contain additional component.The definite character of these annexing ingredients and its add-on depend on the purposes of this component or composition and the physical form of this component and composition.

This component preferably contains surface active composition, and its amount is to count 1-95% by composition weight, preferred 10-70%, more preferably 20 60%, and even 50%.Said composition preferably contains the foaming component, and its amount is counted 5-99% by composition weight, preferred 10-90%, more preferably 1 5-60%.

Surface active composition and foaming component maybe when existing with the weight ratio of wherein acid source preferably 20: 1-1: 10, more preferably 9: 1-1: 9, more preferably 5: 1-1: 8, most preferably 4: 1-1: 4.

This component is when being particle form or preferably such when being contained in the particle, and it makes the particle of 80% weight have the particle diameter (particle on No. 200 sieves of Taylor is more than 80% weight) greater than 75 microns and has particle diameter greater than 2cm less than the particle of 10% weight; The particle of preferred 80% weight has particle diameter greater than 150 microns (particle on No. 100 sieves of Taylor is more than 80% weight) and has particle diameter greater than 1cm less than the particle of 10% weight; Or more preferably the particle of 80% weight has particle diameter greater than 300 microns (particle on No. 48 sieves of Taylor is more than 80% weight) and has particle diameter greater than 0.5cm less than the particle of 10% weight; More preferably this particle have 500 median size of (on No. 32 sieves of Taylor)-3000 microns, more preferably 710 (on No. 24 sieves of Taylor)-1180 microns (by No. 14 sieves of Taylor).

The density of this component is 500-1200g/l preferably, more preferably 650-900g/l.

This component of the present invention is at non-aqueous liquid compositions or solids composition, and is particularly useful in preferred cleaning products or the Foods or drinks product.This component can be used as independent particle existence or it can be used as a part of component existence of solid or non-aqueous liquid compositions.This solid cleaning combination is solid laundry or dishwashing compositions preferably, the form of thin slice or lozenge preferably, and more preferably the form of particle or extrudate or sheet preferably has the density of 500g/l at least, more preferably 700g/l at least.

The foaming component

Any foaming system that can form gas when contacting with water well known in the prior art can be as the foaming component in the foaming component of the present invention.Can be when water exists and the acid source of alkali source reaction generation gas thereby preferred foaming component comprises.

When having acid source, preferably the bubble component of component of alkali source or its part.

This acid source can be any organic, mineral or mineral acid, or derivatives thereof, or its mixture.This acid source preferably contains organic acid.

This acid source preferably is anhydrous or non-moisture absorption basically and is should acid preferably water miscible.Preferably this acid source is a super-dry.

Suitable acid source component comprises: citric acid, oxysuccinic acid, toxilic acid, fumaric acid, aspartic acid, pentanedioic acid, tartrate, succsinic acid or hexanodioic acid, mono phosphoric acid ester sodium, boric acid, or derivatives thereof.Citric acid, toxilic acid or oxysuccinic acid are particularly preferred.

Most preferably, this acid source provides has about 75-1180 micron, more preferably the acidic cpd of the about 710 microns median sizes of 150-(calculating by this acid source sample of screening on a series of Tyler meshs).

This foaming component preferably contains alkali source.Any alkali source that has with the ability of acid source generated reactive gas can be present in this particle, comprises the alkali source that can produce nitrogen, oxygen or carbon dioxide.Preferably can be perhydrate SYNTHETIC OPTICAL WHITNER and silicate material.This alkali source preferably is anhydrous or non-moisture absorption basically.Preferably this alkali source is a super-dry.

The gas that is produced is carbonic acid gas preferably, so this alkali source carbonate source preferably; In preferred embodiments, this alkali source is a carbonate.The example of preferred carbonate is alkaline-earth metal and alkaline carbonate, the any mixture that comprises yellow soda ash or potassium, sodium bicarbonate or potassium and concentrated crystal soda or potassium and itself and calcium carbonate superfine powder is for example disclosed on November 15th, 1973 disclosed German patent application numbers 2321001.Alkali metal percarbonate also is suitable carbonate source, and it can exist in combination with one or more other carbonate source.

This carbonate and supercarbonate preferably have unformed structure.This carbonate and/or supercarbonate can apply with coating material.The particle of this carbonate and supercarbonate can have 75 microns or bigger, preferred 150 μ m or bigger, more preferably 250 μ m or bigger, preferred 500 μ m or bigger mean diameter.Preferably this carbonate is such, and it makes the particle that is less than 20% weight have the particle diameter that is lower than 500 μ m, and it is to calculate by the sample that sieves this carbonate or supercarbonate on a series of Tyler meshs.In addition or except above-mentioned carbonate, preferably be lower than 60% or even 25% particle have the particle diameter that is lower than 150 μ m, be lower than 5% particle simultaneously and have particle diameter greater than 1.18mm, particle more preferably less than 20% has the particle diameter greater than 212 μ m, and it is to calculate by the sample that sieves this carbonate or supercarbonate on a series of Tyler meshs.

The mol ratio that is present in acid source in the granular core and alkali source preferably 60: 1-1: 60, more preferably 20: 1-1: 20, more preferably 10: 1-1: 10, more preferably 5: 1-1: 3, most preferably 3: 1-1: 2, most preferably 2: 1-1: 2.

Surface active composition

Foaming component of the present invention can contain any surface active composition known in the art, and it reduces water-gas meter surface tension.Those surface active compositions preferably are incorporated into purposes and its physical form that depends on component of the present invention in the present composition.

This surface active composition can contain one or more compounds.It is the water miscible compound of part at least that this component preferably contains.This component is preferably anhydrous.

This surface active composition preferably has more than 30 ℃, more preferably more than 45 ℃, the fusing point more than 50 ℃ most preferably, preferably this surface active composition has the fusing point more than 80 ℃, guarantee that in particular this surface active composition is a solid under common condition of storage, the purposes of thing combined according to the invention easily forms melt on preferred fusing point simultaneously.

Preferably, this surface active composition contains one or more nonionic components or one or more anionic groups or its mixture.

Especially, when component of the present invention is used for cleaning combination, this surface active composition preferably contains one or more components, it is selected from: as described alkyl sulfate surfactant and alkyl sulfonate surfactants in this article, particularly oxyalkylated alcohol comprises polyoxyethylene glycol and/or polypropylene glycol, oxyalkylated fatty acid amide and oxyalkylated alcohol amide comprise that glycollic amide and specific ionic surfactant pack draw together (poly-hydroxy) fatty acid amide, oxyalkylated pure tensio-active agent, effective for treatment of premature ejaculation and specific alkyl polysaccharide surfactant or the mixture of these non-ionic compounds and anionic compound.

Therefore, be included in one or more components detergent active preferably in this foaming component, it helps this particle or contains the cleaning performance of this particulate cleaning combination.The anhydrous basically surface active composition very preferably that is suitable for foaming component of the present invention is one or more nonionogenic tensides, it is selected from: as the oxyalkylated tensio-active agent of described nonionic hereinafter, comprise oxyalkylated pure tensio-active agent, polyhydroxy fatty acid amide surfactant, (oxyalkylated) fatty acid amide surfactant and alkyl polysaccharide surfactant, or its mixture.

The present invention very preferably aspect, this surface active composition contains polyhydroxy fatty acid amide and/or polyoxyethylene glycol, and/or the mixture of the condensation product of oxyalkylated fatty acid amide and/or Fatty Alcohol(C12-C14 and C12-C18) and 1-11 mole alkylene oxide, as below in greater detail.When it exists, the ratio of polyhydroxy fatty acid amide and the condensation product of Fatty Alcohol(C12-C14 and C12-C18) preferably 20: 1-1: 20, more preferably 10: 1-1: 10, more preferably 8: 1-1: 8, more preferably 6: 1-1: 6, most preferably 2: 1-1: 3.When it exists, the ratio of polyhydroxy fatty acid amide and polyoxyethylene glycol preferably 20: 1-1: 8, more preferably 15: 1-1: 3, more preferably 12: 1-1: 1, most preferably 10: 1-1: 1.When it exists, the ratio of polyhydroxy fatty acid amide and oxyalkylated fatty acid amide preferably 20: 1-1: 20, more preferably 15: 1-1: 10, most preferably 10: 1-1: 10.

The oxyalkylated tensio-active agent of nonionic

Basically any oxyalkylated nonionogenic tenside also can be included in the surface active composition of foaming component of the present invention.The nonionogenic tenside in ethoxylation and propoxy-generation is preferred.The tensio-active agent of preferred alkoxylated can be selected from: the nonionic condenses of alkylphenol, the alcohol of nonionic ethoxylation, nonionic ethoxylation/propenoxylated Fatty Alcohol(C12-C14 and C12-C18), non-ionic ethoxylate/propoxylated glycerine and the condenses of propylene glycol and the condensation product of nonionic ethoxylate and propylene oxide/quadrol affixture.

It is most preferred that the oxyalkylated pure tensio-active agent of nonionic, Fatty Alcohol(C12-C14 and C12-C18) and 1-75 mole, high to 50 moles, the condensation product of preferred 1-15 mole alkylene oxide, particularly oxyethane and/or propylene oxide is included in the particularly preferred nonionogenic tenside in the particle anhydrous components of the present invention.The alkyl chain of this Fatty Alcohol(C12-C14 and C12-C18) can be straight or branched, uncle or secondary, and contain 6-22 carbon atom usually.Particularly preferably be alcohol and every mol of alcohol 2-9 mole, the particularly condenses of 3 or 5 moles of ethylene oxide with the alkyl that contains 8-20 carbon atom.

The nonionic polyhydroxy fatty acid amide surfactant

Polyhydroxy fatty acid amide is the nonionogenic tenside that very preferably is included in the surface active composition of foaming component of the present invention, particularly has formula R ²CONR ¹Those of Z: R wherein ¹Be H, C _1-18Alkyl, preferred C ₁-C ₄Alkyl, 2-hydroxyethyl, 2-hydroxypropyl, oxyethyl group, propoxy-, or its mixture, preferred C ₁-C ₄Alkyl, more preferably C ₁Or C ₂Alkyl, most preferably C ₁Alkyl (being methyl); R ²Be C _5-31Alkyl, preferred straight chain C ₅-C ₁₉Or C _7-19Alkyl or alkenyl, more preferably straight chain C ₉-C ₁₇Alkyl or alkenyl, most preferably straight chain C ₁₁-C ₁₇Alkyl or alkenyl, or its mixture; Z be have the straight-chain alkyl chain, at least 3 hydroxyls are directly connected to the polyhydroxy alkyl on this chain, or its oxyalkylated (preferred ethoxylation or propenoxylated) derivative.Z preferably in reductive amination process from the reducing sugar deutero-; More preferably Z is sugar alcohol base (glycityl).

The nonionic polyhydroxy fatty acid amide surfactant very preferably that is used for herein is C ₁₂-C ₁₄, C ₁₅-C ₁₇And/or C ₁₆-C ₁₈Alkyl N-methyl glucose amide.

Particularly preferably be this surface active composition and contain C ₁₂-C ₁₈Alkyl N-methyl glucose amide and have alcohol and every a mol of alcohol 2-9 mole, the particularly mixture of the condenses of 3 or 5 moles of ethylene oxide that contains 8-20 carbon atom alkyl.

Can pass through the prepared by any suitable process polyhydroxy fatty acid amide.A particularly preferred method is described in detail among the WO 9206984.Can prepare undesirable impurity for example fatty acid ester and the cyclic amide and that contains have an appointment 95% weight polyhydroxy fatty acid amide and low levels by this method generally at about fused product more than 80 ℃.

The nonionic fatty acid amide surfactant

Fatty acid amide surfactant or oxyalkylated fatty acid amide also can be included in the particulate anhydrous material of the present invention.They comprise having formula R ⁶CON (R ⁷) (R ⁸) those materials, R wherein ⁶Be to contain 7-21, preferred 9-17, so that the alkyl of 12-14 carbon atom, each R ⁷And R ⁸Be selected from hydrogen, C independently of one another ₁-C ₄Alkyl, C ₁-C ₄Hydroxyalkyl and-(C ₂H ₄O) _xH, wherein x is in the scope of 1-11, preferred 1-7, more preferably 1-5, wherein R preferably ⁷With R ⁸Be different, one has less alkoxylate number than another.

Nonionic fatty acid alkyl ester surfactant

Effective for treatment of premature ejaculation also can be included in the particulate anhydrous material of the present invention.They comprise having formula R ⁹COO (R ¹⁰) those, R wherein ⁹Be to contain 7-21, preferred 9-17, the more preferably alkyl of 10-13 carbon atom, R ¹⁰Be C ₁-C ₄Alkyl, C ₁-C ₄Hydroxyalkyl, or-(C ₂H ₄O) _xH, wherein x is in the scope of 1-11, preferred 1-7, more preferably 1-5, wherein R preferably ¹⁰Be methyl or ethyl.

The nonionic alkyl polysaccharide surfactant

Alkyl polysaccharide also can be included in the surface active composition of foaming component of the present invention, for example be disclosed among the US4565647 of the Llenado that issued on January 21st, 1986, it has the hydrophobic group that contains 6-30 carbon atom and contains 1.3-10 the unitary polysaccharide of saccharides (for example many glycosides) hydrophilic radical.

Preferred alkyl polyglycoside has following formula:

R ²O (C _nH _2nO) _t(glycosyl) _x

R wherein ²Be selected from: alkyl, alkyl phenyl, hydroxyalkyl, hydroxyalkyl phenyl and its mixture, wherein alkyl contains 10-18 carbon atom; N is 2 or 3; T is 0-10; X is 1.3-8.This glycosyl is preferably from the glucose deutero-.

Polyethylene/polypropylene glycol

One component of surface active composition can be that polyoxyethylene glycol and/or polypropylene glycol, particularly molecular weight are 1000-10000, more preferably 2000-8000 and most preferably from about 4000 those.

Anion surfactant

The surface active composition of the present composition can contain one or more anion surfactants.Any anion surfactant that is used to wash purpose all is suitable.Example comprise anion sulfate, sulfonate, carboxylate salt and sarcosinate (comprise, for example, sodium, potassium, ammonium and replacement ammonium be for example single, two and triethanolamine salt).The anion sulfate acid salt surfactant is preferred.

Other anion surfactant comprises isethionate for example fatty acid amide, alkyl succinate and sulfosuccinate, monoesters (the especially saturated or unsaturated C of sulfosuccinate of acyl isethinate, N-acyl taurine salt, methyl taurate ₁₂-C ₁₈Monoesters), the diester of sulfosuccinate (especially saturated or undersaturated C ₆-C ₁₄Diester), N-acyl sarcosinate.Resinous acid and hydrogenant resinous acid also are suitable, for example rosin, staybelite and be present in or be derived from the resinous acid and the hydrogenated resin acid of tallow oil.

By the weight of foaming component, this anion surfactant preferably can exist with the content of 1-90%, preferred 5-60%, more preferably 8-50%.

The anion sulfate acid salt surfactant

Be applicable to that anion sulfate tensio-active agent herein comprises: the primary and secondary alkyl-sulphate of straight chain and side chain, alkyl ethoxy sulfate, fatty oil acylglycerol vitriol, alkyl phenol epoxy ethane ether salt, C ₅-C ₁₇Acyl group-N-(C ₁-C ₄Alkyl) and-N-(C ₁-C ₂Hydroxyalkyl) vitriol of glucosamine sulfate and the alkyl polysaccharide vitriol of alkyl polyglucoside (compound of described herein nonionic non-sulfuric acidization) for example.

Alkyl sulfate surfactant is preferably selected from the uncle C of straight chain and side chain ₉-C ₂₂Alkyl-sulphate, more preferably side chain C ₁₁-C ₁₅Alkyl-sulphate and straight chain C ₁₂-C ₁₄Alkyl-sulphate.

Alkyl ethoxy sulfate surfactant is preferably selected from the C of every mole of molecule with the ethoxylation of 0.5-50 moles of ethylene oxide ₁₀-C ₁₈Alkyl-sulphate.More preferably, this alkyl ethoxy sulfate surfactant is every mole of molecule 0.5-7 mole, the C of preferred 1-5 moles of ethylene oxide ethoxylation ₁₁-C ₁₈, C most preferably ₁₁-C ₁₅Alkyl-sulphate.

The anion sulfoacid salt surfactant

Be applicable to that anionic sulphonate tensio-active agent herein comprises: C ₅-C ₂₀Straight or branched alkylbenzene sulfonate, alkyl ester sulfonate, particularly methyl ester sulfonate, C ₆-C ₂₂Uncle or secondary paraffin sulfonate, C ₆-C ₂₄Alkene sulfonate, sulfonated poly carboxylic acid, alkyl glycerol sulfonate, fatty acyl group glycerol sulfonate, fatty oil acylglycerol sulfonate and its any mixture.

The anionic carboxylic acid salt surfactant

Suitable anionic carboxylate tensio-active agent comprises: alkyl ethoxy carboxylate, alkyl polyethoxye multi-carboxylate's tensio-active agent and soap (" alkyl carboxyl "), particularly some secondary soap as described herein.

Suitable alkyl ethoxy carboxylate comprises formula RO (CH ₂CH ₂O) _xCH ₂COO ^-M ⁺Those, wherein R is C ₆-C ₁₈Alkyl, x be in the scope of 0-10, this oxyethyl group be causing of distributing like this it is measured less than 20% when x is 0 by weight, M is a positively charged ion.Suitable alkyl polyethoxye multi-carboxylate tensio-active agent comprises formula RO-(CHR ₁CHR ₂-O) _x-R ₃Those, wherein R is C ₆-C ₁₈Alkyl, x are 1-25, R ₁And R ₂Be selected from hydrogen, methyl acid group, succsinic acid group, hydroxy succinic acid group and its mixture, R ₃Be selected from alkyl and its mixture of hydrogen, replacement or the unsubstituted 1-8 of a having carbon atom.

Suitable soap surfactant comprises and contains the unitary secondary soap surfactant of the carboxyl that is connected on the secondary carbon(atom).The preferred secondary soap surfactant that is used for herein is water miscible, and it is selected from 2-methyl isophthalic acid-undecanoic acid, 2-ethyl-1-capric acid, 2-propyl group-1-n-nonanoic acid, 2-butyl-1-is sad and the water-soluble salt of 2-amyl group-1-enanthic acid.Can comprise that also some soap is as suds suppressor.

The basic metal sarcosinate surfactant

Other suitable anion surfactant is formula R-CON (R ¹) CH ₂The basic metal sarcosinate of COOM, wherein R is C ₅-C ₁₇Straight or branched alkyl or alkenyl, R ¹Be C ₁-C ₄Alkyl, M are alkalimetal ions.Preferred example is the myristyl and the oleoyl methyl sarcosinate of its sodium-salt form.

Cats product

Cats product can be included in the surface active composition of the present composition, and by this composition weight, preferably its amount is 0.5-80%, more preferably 1-60%, most preferably 3-50%.

Cats product is preferably selected from amine tensio-active agent and its mixture of cationic ester tensio-active agent, the oxyalkylated amine tensio-active agent of cation mono, positively charged ion bis-alkoxyization.

Cation mono alkoxylated amines tensio-active agent

The optional cation mono alkoxylated amines tensio-active agent that is used for herein has following general formula:

R wherein ¹Be to contain about 6-18, preferably about 6-16 is individual, most preferably from about the alkyl of 6-11 carbon atom or alkenyl part; R ²And R ³Be the alkyl that contains about 1-3 carbon atom independently of one another, preferable methyl; R ⁴Be selected from hydrogen (preferably), methyl and ethyl, X ^-Be negatively charged ion for example muriate, bromide, methylsulfate, sulfate radical or analogue so that electric neutrality is provided; A is selected from C ₁-C ₄Alkoxyl group, especially oxyethyl group (promptly-CH ₂CH ₂O-), propoxy-, butoxy and its mixture; P is that 1-is about 30, and preferred 1-is about 15, and most preferably 1-about 8.

The cation mono alkoxylated amines tensio-active agent very preferably that is used for herein has following general formula:

R wherein ¹Be C ₆-C ₁₈Alkyl and its mixture, preferred C ₆-C ₁₄, C particularly ₆-C ₁₁Alkyl, preferred C ₈And C ₁₀Alkyl, X provide any negatively charged ion easily of charge balance, preferred muriate or bromide.

As noted, the compound of the above-mentioned type comprises wherein oxyethyl group (CH ₂CH ₂O) unit (EO) is by butoxy, isopropoxy [CH (CH ₃) CH ₂O] and [CH ₂CH (CH ₃O)] unit (i-Pr) or positive propoxy unit (Pr), or EO and/or Pr and/or displaced those compounds of the unitary mixture of i-Pr.

Positively charged ion bis-alkoxy amine tensio-active agent

The optional positively charged ion bis-alkoxy amine tensio-active agent that is used for herein has following general formula: R wherein ¹Be to contain about 6-18, preferably about 6-16, more preferably from about 6-11 is individual, most preferably from about the alkyl of 8-10 carbon atom or alkenyl part; R ²Be the alkyl that contains 1-3 carbon atom, preferable methyl; R ³And R ⁴Change independently of one another and be selected from hydrogen (preferably), methyl and ethyl, X ^-Be negatively charged ion for example muriate, bromide, methylsulfate, sulfate radical or analogue so that electric neutrality is provided; A and A ' can change and be selected from C independently of one another ₁-C ₄Alkoxyl group, especially oxyethyl group (promptly-CH ₂CH ₂O-), propoxy-, butoxy and its mixture; P is that 1-is about 30, and preferred 1-is about 4, and q is that 1-is about 30, and preferred 1-is about 4, and most preferably p and q are 1.

The positively charged ion bis-alkoxy amine tensio-active agent very preferably that is used for herein has following general formula: R wherein ¹Be C ₆-C ₁₈Alkyl and its mixture, preferred C ₆, C ₈, C ₁₀, C ₁₂, C ₁₄Alkyl and its mixture.X provides any negatively charged ion easily of charge balance, preferred muriate.With reference to the formula of above-mentioned positively charged ion bis-alkoxy amine, in preferred compound, R ¹Be from (coconut) C ₁₂-C ₁₄Alkyl fraction fatty acid derived, R ²Be methyl and ApR ³And A ' qR ⁴It is monosubstituted ethoxy separately.

Other useful herein bis-alkoxy amine tensio-active agent comprises the compound of following formula:

R wherein ¹Be C ₆-C ₁₈Alkyl, preferred C ₆-C ₁₄Alkyl, independently of one another, p is that 1-about 3 and q are that 1-is about 3, R ²Be C ₁-C ₃Alkyl, preferable methyl, X is a negatively charged ion, particularly muriate or bromide.

Other compounds of the above-mentioned type comprise wherein oxyethyl group (CH ₂CH ₂O) unit (EO) is by butoxy (Bu), isopropoxy [CH (CH ₃) CH ₂O] and [CH ₂CH (CH ₃O)] unit (i-Pr) or positive propoxy unit (Pr), or EO and/or Pr and/or displaced those compounds of the unitary mixture of i-Pr.

Amphoterics

The suitable amphoterics that is used for herein comprises amine oxide surfactant and alkyl both sexes carboxylic acid.

Suitable amine oxide comprises having formula R ³(OR ⁴) _xN ⁰(R ⁵) ₂Those compounds, R wherein ³Be selected from the alkyl, hydroxyalkyl, acyl group amido propyl group and the alkyl phenyl that contain 8-26 carbon atom, or its mixture; R ⁴Be alkylidene group or the hydroxy alkylidene that contains 2-3 carbon atom, or its mixture; X is 0-5, preferred 0-3; Each R ⁵It is the polyethylene oxide group that contains the alkyl or the hydroxyalkyl of 1-3 carbon atom or contain 1-3 ethylene oxide group.C preferably ₁₀-C ₁₈Alkyl dimethyl amine oxide and C ₁₀-C ₁₈Acyl group amidoalkyl dimethyl oxidation amine.

The suitable example of alkyl both sexes (apho) dicarboxylic acid is by Miranol, Inc., Dayton, Miranol (TM) the C2M Conc that NJ produces.

Zwitterionics

Zwitterionics also can be included in the present composition or contain in the surface active composition in the grains of composition of the present invention.These tensio-active agents can briefly be described as the derivative of the second month in a season or tertiary amine, the derivative of the heterocycle second month in a season or tertiary amine, or the derivative of quaternary ammonium, quaternary phosphine or uncle's sulfonium compound.Trimethyl-glycine and sultaine tensio-active agent are the examples that is used for zwitterionics herein.

The trimethyl-glycine that is fit to is to have formula R (R ¹) ₂N ⁺R ²COO ^-Those compounds, wherein R is C ₆-C ₁₈Alkyl, each R ¹Generally be C ₁-C ₃Alkyl, R ²Be C ₁-C ₅Alkyl.Preferred trimethyl-glycine is C _12-18Dimethylamino hexanoate and C _10-18Acyl group amido propane (or ethane) dimethyl (or diethyl) trimethyl-glycine.The compound beet alkali surface activator also is applicable to herein.

Cleaning combination

Foaming component of the present invention can be incorporated into cleaning combination, preferred solids composition, preferred granular composition is preferably in laundry or the dishwashing compositions.Composition of the present invention is particulate form or be included in the particle preferably.

So, the component of the present invention that is used for cleaning combination, and/or this cleaning combination preferably contains one or more additional detergent components, and it is selected from: additional surfactant, SYNTHETIC OPTICAL WHITNER, washing assistant, sequestrant, (additional) alkali source, organic polymer, enzyme, suds suppressor, lime soap dispersing agent, whitening agent, dirt suspension and anti redeposition agent and corrosion inhibitor.

Additional detergent active thing very preferably or component are aforesaid positively charged ion and anion surfactant, press down foam system, whitening agent and bleaching compounds, comprise the perhydrate SYNTHETIC OPTICAL WHITNER, but preferred bleach-activating agent, as described hereinafter.

Press down foam system

Foaming component of the present invention provides and has formed highly stable foam very fast.

, some in washing process for example in order to improve bubble or the foamy discharging that washing process or washing machine produce, preferably limits or the reduction foaminess constantly.In addition, further preferably, during with foaminess is limited to water contacts beginning (for example beginning of washing process) bubble or improve component or contain the dispersiveness or the solvability of the product of this component so that provide.Therefore, preferably, by composition or this composition weight, containing amount is 0.01-15%, preferred 0.05-10%, and most preferably the foam that presses down of 0.1-5% is.

The foam that presses down that is fit to that is used for herein is to contain any basically known defoamer compound, for example, comprises siloxanes defoaming compounds, 2-alkyl chain triacontanol defoaming compounds.

About defoaming compounds, referred to herein such as the one-tenth bubble or any compound of foaming effect or the mixture of compound that suppress to produce by detergent composition solution.

The particularly preferred defoaming compounds that is used for herein is the siloxanes defoaming compounds, is defined as any defoaming compounds that comprises the siloxanes component herein.Such siloxanes defoaming compounds generally also contains silica component.As employed usually in this paper and the whole industry, term " siloxanes " comprises the various relative high molecular weight polymers that contains siloxane unit and all kinds alkyl.Preferred siloxanes defoaming compounds is a siloxanes, particularly has the unitary polydimethylsiloxane of trimethyl silyl end-blocking.

Other suitable defoaming compounds comprises mono carboxylic lipid acid and its soluble salt.These materials have description in the US2954347 of the Wayne St.John of promulgation on September 27 nineteen sixty.This mono carboxylic lipid acid and its salt as suds suppressor generally have 10-24 carbon atom, the hydrocarbyl chain of preferred 12-18 carbon atom.Suitable salt comprises basic metal for example sodium, potassium and lithium salts and ammonium and alkanol ammonium salts.

Other suitable defoaming compounds comprises: for example, and high molecular fatty ester (for example triglyceride), the fatty acid ester of monovalent alcohol, aliphatics C ₁₈-C ₄₀The alkylating aminotriazine of ketone (for example stearone) N-for example three-to six-alkyl melamine or as cyanuryl chloride and 2 or 3 moles contain that the product of the uncle of 1-24 carbon atom or secondary amine forms two-to four-alkyl diamine chloro triazine, propylene oxide, two stearic amide and single stearyl two basic metal (for example sodium, potassium, lithium) phosphoric acid salt and phosphoric acid ester.

The preferred foam system that presses down comprises:

(a) defoaming compounds, preferred siloxanes defoaming compounds most preferably is the siloxanes defoaming compounds that comprises following mixture:

(i) in the weight of this siloxanes defoaming compounds, content is 50-99%, the polydimethylsiloxane of preferred 75-95%; With

(ii) in the weight of this siloxanes/silicon-dioxide defoaming compounds, content is 1-50%, the silicon-dioxide of preferred 5-25%;

Wherein with 5-50% (weight), the amount of preferred 10-40% (weight) adds described silica/silicon oxygen alkane defoaming compounds;

(b) compound dispersing agent, most preferably comprise silicone glycols rake formula multipolymer, its polyoxyalkylene content is 72-78% (weight) and oxyethane and the ratio of propylene oxide is 1: 0.9-1: 1.1 (weight), and its amount is 0.5-10% (weight), preferred 1-10% (weight); Particularly preferred this class silicone glycols rake formula multipolymer is DCO544, can obtain with trade(brand)name DCO544 from DOWCorning;

(c) inert support fluid compound comprises that most preferably ethoxylation degree is 5-50, the C of preferred 8-15 ₁₆-C ₁₈Ethoxylated alcohol, its amount is 5-80% (weight), preferred 10-70% (weight);

Granular suds suppressing system very preferably is described among the EP-A-0210731 and comprises the siloxanes defoaming compounds and fusing point is 50-85 ℃ a organic carrier, and wherein this organic carrier comprises glycerine and the monoesters with lipid acid of the carbochain that contains 12-20 carbon atom.EP-A-0210721 discloses other preferred granular suds suppressing system, and wherein this organic carrier is lipid acid or the alcohol with the carbochain that contains 12-20 carbon atom, or its mixture, and its fusing point is 45-80 ℃.

The water soluble detergency promoter compound

Foaming component of the present invention or cleaning combination preferably contain the water soluble detergency promoter compound, and by composition or composition weight, its amount is generally 1-80%, preferred 10-70%, most preferably 20-60%.

Suitable water soluble detergency promoter compound comprises poly carboxylic acid or its salt of water miscible monomer multi-carboxylate or its sour form, homopolymerization and copolymerization, wherein this poly carboxylic acid contains at least 2 by no more than 2 carboxyls that carbon atom is separated from each other, the any mixture of borate, phosphoric acid salt and above-mentioned substance.

Can be monomer or oligomeric on carboxylate salt or the multi-carboxy acid salt washing agent's type, but owing to the reason monomer multi-carboxylate of cost and performance is normally preferred.

The suitable carboxylate salt that contains 1 carboxyl comprises: the water-soluble salt of lactic acid, oxyacetic acid and its ether derivant.The multi-carboxylate of containing 2 carboxyls comprises: the water-soluble salt of succsinic acid, propanedioic acid, (ethylenedioxy) oxalic acid, toxilic acid, diethyl alkyd, tartrate, tartronic acid and fumaric acid, and ether multi-carboxylate and sulfinyl carboxylate salt.The multi-carboxylate of containing 3 carboxyls comprises: particularly, water-soluble citrate, aconitate and citraconate and succinate derivative, for example, the carboxyl methoxy succinate described in the British Patent No. 1379241, the newborn oxidation succinate described in the British Patent No. 1389732 and at the aminosuccinic acid salt described in the Holland application 7205873 and oxidation multi-carboxylate material for example at the 2-oxa--1 described in the British Patent No. 1387447,1,3-tricarballylic acid salt.

The multi-carboxylate of containing 4 carboxyls comprises: disclosed oxygen di-succinate, 1,1,2 in British Patent No. 1261829,2-ethane tetracarboxylic acid hydrochlorate, 1,1,3,3-propane tetracarboxylic acid salt and 1,1,2,3-propane tetracarboxylic acid salt.Containing the substituent multi-carboxylate of sulfo group comprises: British Patent No. 1398421 and 1398422 and US3936448 in disclosed sulfo-succinic acid salt derivative and at the sulfonated pyrolytic Citrate trianion described in the British Patent No. 1439000.Preferred multi-carboxylate is every mole and contains the hydroxycarboxylate who is up to 3 carboxyls, more specifically is Citrate trianion.

Borate washing assistant and containing form borate material (it washing composition store or wash conditions under can form borate) washing assistant be useful herein water soluble detergency promoter.

The suitable example of water-soluble phosphate washing assistant is an alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate salt, the pyrophosphate salt of sodium and potassium and ammonium, the orthophosphoric acid salt of sodium and potassium, wherein the polymerization degree about 6-21 scope poly-partially/sodium phosphate, and phytate.

Partly soluble or insoluble washing-aid compound

Component of the present invention or the composition that contains this component of the present invention can contain and be partly dissolved or insoluble washing-aid compound, and by composition or composition weight, its amount is generally 1-80%, preferred 10-70%, most preferably 20-60%.

Basically the example of water-fast washing assistant is a sodium silicoaluminate.

Suitable aluminosilicate zeolite has structure cell formula: Na _z[(AlO ₂) _z(SiO ₂) _y] xH ₂O, wherein z and y are at least 6, and the mol ratio of z and y is that 1.0-0.5 and x are 5 at least, preferred 7.5-276, more preferably 10-264.This alumino-silicate materials be hydrated form and crystalline preferably, contain 10-28%, more preferably the water of 18-22% combining form.

This aluminosilicate zeolite can be naturally occurring material, but preferably synthetic obtaining.Synthetic crystal aluminosilicate ion-exchange material can title zeolite A, zeolite B, zeolite P, X zeolite, zeolite HS and its mixture obtain.Zeolite A has following formula:

Na ₁₂[(AlO ₂) ₁₂(SiO ₂) ₁₂]xH ₂O

Wherein x is 20-30, particularly 27.X zeolite has formula Na ₈₆[(AlO ₂) ₈₆(SiO ₂) ₁₀₆] .276H ₂O.

The preferred crystalline layered silicate that is used for herein has following general formula:

NaMSi _xO _2x+1yH ₂O

Wherein M is sodium or hydrogen, and x is that 1.9-4 and y are 0-20.This class crystalline layered sodium silicate is disclosed among the EP-A-0164514, and its preparation method is disclosed among DE-A-3417649 and the DE-A-3742043.Herein, the x in the general formula is preferably 2,3 or 4 and be preferably 2 in the above.Most preferred material is the β-Na that obtains with NaSKS-6 from Hoechst AG ₂Si ₂O ₅

The perhydrate SYNTHETIC OPTICAL WHITNER

A preferred annexing ingredient of foaming component of the present invention or cleaning combination is the perhydrate SYNTHETIC OPTICAL WHITNER, for example metal perborate, metal percarbonate, particularly sodium salt.Perborate can be one or four hydrations.SPC-D has corresponding to 2Na ₂CO ₃.3H ₂O ₂Formula, and can be used as crystalline solid and buy.

Peroxide Potassium peroxysulfate and sodium are the optional inorganic perhydrate salt that another kind is used for detergent composition or foaming component.

The organic peroxide acid bleach system

Component of the present invention or the preferred feature that contains the cleaning combination of foaming component of the present invention are the organic peroxide acid bleach systems.In a preferred embodiment, this bleach system contains hydrogen peroxide cource and organic peroxy acid blanching precursor compound.Form organic peroxide acid by this precursor and hydrogen peroxide cource reaction in.Preferred hydrogen peroxide cource comprises for example claimed perborate bleach of the present invention of inorganic perhydrate SYNTHETIC OPTICAL WHITNER.In another preferred embodiment, the ready-formed organic peroxide acid directly is incorporated in the composition.The composition that contains the mixture that hydrogen peroxide cource and organic peroxy acid precursor and ready-formed organic peroxide acid be combined together also is considered.

Peroxyacid bleach precursor

Peroxyacid bleach precursor is the compound that forms peroxy acid in crossing hydrolysis reaction with hydroperoxidation.Usually peroxyacid bleach precursor can be expressed as

Wherein L is a leavings group, and X is any functional group basically, causes the structure of the peroxy acid that produces when crossing hydrolysis to be

By composition or composition weight, the peroxyacid bleach precursor compound is preferably with 0.5-6%, more preferably 1-40%, and most preferably the amount of 1.5-25% adds.

Suitable peroxyacid bleach precursor generally contains one or more N-or O-acyl group, and this precursor can be selected from all kinds.Suitable type comprises: the acyl derivative of acid anhydrides, ester, imide, lactan and imidazoles and oxime.The example of useful materials is disclosed among the GB-A-158789 in these classes.Suitable ester is disclosed among English Patent 836988,864798,1147871,2143231 and the EP-A-0170386.

Leavings group

Leavings group, L group hereinafter must have enough reactivities in the time period of the best (for example cycles of washing) hydrolysis reaction taking place., if the L reactivity is too strong, this activator is used for bleaching composition and will be difficult to stablize so.Preferred L group is selected from following these groups and its mixture:

R wherein ¹Be alkyl, aryl or the alkaryl that contains 1-14 carbon atom, R ³Be the alkyl chain that contains 1-8 carbon atom, R ⁴Be H or R ³, Y is H or solubilizing group, any R ¹, R ³And R ⁴Basically can be replaced by any functional group, these functional groups comprise: for example alkyl, hydroxyl, alkoxyl group, halogen, amine, nitrosyl radical, acid amides and ammonium or alkyl ammonium group.

Preferred solubilizing group is-SO ₃ ^-M ⁺,-CO ₂ ^-M ⁺,-SO ₄ ^-M ⁺,-N ⁺(R ³) ₄X ^-And O＜--N (R ³) ₃, most preferably-SO ₃ ^-M ⁺With-CO ₂ ^-M ⁺, R wherein ³Be the alkyl chain that contains 1-4 carbon atom, M provides deliquescent positively charged ion to this bleach-activating agent, and X provides deliquescent negatively charged ion to this bleach-activating agent.Preferably, M is basic metal, ammonium or replacement ammonium cation, and sodium and potassium are most preferred, and X is halogen root, hydroxide radical, methylsulfate or acetate anion.

Alkyl percarboxylic acids bleach precursor

Alkyl percarboxylic acids bleach precursor forms percarboxylic acids when crossing hydrolysis.Preferred this class precursor provides peracetic acid when crossing hydrolysis.

The alkyl peroxycarboxylic acid precursors compound of preferred imide type comprises N, N, N ¹N ¹The Alkylenediamine of tetra-acetylatedization, wherein this alkylidene group contains 1-6 carbon atom, and especially wherein this alkylidene group contains those compounds of 1,2 and 6 carbon atom.Tetra acetyl ethylene diamine (TAED) is particularly preferred.This TAED preferably is not present in the agglomerant particle of the present invention, contains in this particulate detergent composition but preferably be present in.

Other preferred alkyl peroxycarboxylic acid precursors comprises: 3,5,5-trimethyl acetyl oxygen base benzene sulfonic acid sodium salt (different-NOBS), acyloxy benzene sulfonic acid sodium salt in the ninth of the ten Heavenly Stems (NOBS), acetoxyl group benzene sulfonic acid sodium salt (ABS) and penta-acetyl glucose.

The alkyl peroxy acids precursor that acid amides replaces

The alkyl peroxy acids precursor that acid amides replaces is suitable for herein, comprises those compounds with following general formula:

R wherein ¹Be alkyl with 1-14 carbon atom, R ²Be the alkylidene group that contains 1-14 carbon atom, R ⁵Be H or the alkyl that contains 1-10 carbon atom, L can be any leavings group basically.The bleach activating immunomodulator compounds that this class acid amides replaces is described among the EP-A-0170386.

Peroxybenzoic acid precursors

The peroxybenzoic acid precursors compound provides peroxybenzoic acid when hydrolysis.The peroxybenzoic acid precursors compound of suitable O-acylations comprises and replacing and unsubstituted benzoyloxy benzene sulfonate; with product with the formylated sorbyl alcohol of benzoyl reagent benzene, glucose and all saccharidess; these compounds of acid imide comprise the urea that N-benzoyl succinimide, four benzoyl quadrols and N-benzoyl replace.Suitable imidazoles peroxybenzoic acid precursors comprises N-benzoyl imidazoles and N-benzoyl benzo imidazoles.The peroxybenzoic acid precursors that contains the N-acyl group that other is useful comprises N-benzoyl pyrrolidone, dibenzoyl taurine and benzoyl Pyrrolidonecarboxylic acid.

The positively charged ion peroxyacid precursor

The positively charged ion peroxyacid precursor produces the positively charged ion peroxy acid when crossing hydrolysis.

Usually, the positively charged ion peroxyacid precursor is by with positively charged functional group for example ammonium or alkylammonium, and preferred ethyl or ammonium methyl replace that the peroxy acid of suitable peroxyacid precursor compound partly forms.The positively charged ion peroxyacid precursor general as with suitable negatively charged ion for example the salt of halide ions be present in the solid detergent composition.

The peroxyacid precursor compound that such positively charged ion replaces can be the derivative of peroxybenzoic acid or its replacement, precursor compound as previously described.In addition, this peroxyacid precursor compound can be the alkyl peroxy acids precursor that alkyl peroxycarboxylic acid precursors compound or acid amides replace, and is as mentioned below.

The positively charged ion peroxyacid precursor is described in United States Patent (USP) 4904406,4751015,4988451,4397757,5269962,5127852,5093022,5106528; English Patent 1382594; European patent 475512,458396 and 284292; And among the Japanese Patent 87-318332.

The example of preferred cation peroxyacid precursor is described in UK Patent Application 9407944.9 and U.S. Patent application 08/29803,08/298650,08/298904 and 08/298906.

Suitable positively charged ion peroxyacid precursor comprises the hexanolactam and the tetra-acetylated glucose benzoyl peroxide of single benzoyl of alkyl that any ammonium or alkylammonium replace or benzoyloxy benzene sulfonate, N-acylations.The hexanolactam cationoid peroxyacid precursor of preferred N-acylations comprises trialkyl ammonium methylene radical benzoyl caprolactam and trialkyl ammonium methylene radical alkyl hexanolactam.

Benzoxazine organic peroxy acid precursor

Also suitable is the peroxide acids precursor compound of benzo oxazinyl, as disclosed in EP-A-332294 and EP-A-482807, particularly has those compounds of following formula: R wherein ₁Be H, alkyl, alkaryl, aryl or arylalkyl.

The ready-formed organic peroxide acid

Except the organic peroxide acid bleach precursor, perhaps as the quid pro quo of organic peroxide acid bleach precursor, this organic peroxide acid bleach system can contain the ready-formed organic peroxide acid, and with composition weight meter, its amount is generally 1-15%, more preferably 1-10%.

The compound that the acid amides that a preferred class organic peroxy acid compound is following general formula replaces:

R wherein ¹Be alkyl, aryl or alkaryl with 1-14 carbon atom, R ²Be alkylidene group, arylidene and the alkyl arylene that contains 1-14 carbon atom, R ⁵Be H or alkyl, aryl or the alkaryl that contains 1-10 carbon atom.The organic peroxy acid compound that this class acid amides replaces is described among the EP-A-0170386.

Other organic peroxide acid comprises diacyl and four acyl peroxides, especially diperoxy dodecanedioic acid, diperoxy tetradecane diacid and diperoxy Thapsic acid.List and two is crossed nonane diacid, undecane dicarboxylic acid crossed by list and two and the amino oxy hexanoic acid of crossing of N-phthaloyl also is suitable for herein.

Heavy metal ion chelating agent

Component of the present invention or the cleaning combination that contains component of the present invention preferably contain heavy metal ion chelating agent as optional components.Referred to the component of sequester (chelating) heavy metal ion effect herein about " heavy metal ion chelating agent ".These components also can have calcium and magnesium sequestering power, but preferably their para-linkage heavy metal ion for example iron, manganese and copper show selectivity.

By composition or composition weight, the amount that heavy metal ion chelating agent exists is generally 0.005-20%, preferred 0.1-10%, more preferably 0.25-7.5%, most preferably 0.5-5%.

The suitable heavy metal ion chelating agent that is used for herein comprises: organic phosphonate is poly-(alkylene phosphonic acids salt), basic metal ethane 1-hydroxyl diphosphonate of amino alkylidenyl, nitrilo trimethylene phosphonic salt for example.

Preferably diethylenetriamine five (methylene phosphonic acid salt), quadrol three (methylene phosphonic acid salt), hexamethylene-diamine four (methylene phosphonic acid salt) and hydroxy ethylene 1,1 diphosphonate in the above-mentioned substance.

Other the suitable heavy metal ion chelating agent that is used for herein comprises: nitrilotriacetic acid(NTA) and polyaminocarboxylic acid be the amino tetraacethyl of ethylene, ethylidene pentaacetic acid, ethylenediamine disuccinic acid, quadrol two pentanedioic acids, 2-hydroxy propylidene diamines disuccinic acid or its salt for example.Particularly preferably be quadrol-N, N '-disuccinic acid (EDDS) or its basic metal, alkaline-earth metal, ammonium or substituted ammonium salt, or its mixture.

The iminodiacetic acid derivatives that is used for herein other suitable heavy metal ion chelating agent and is being described in EP-A-317542 and EP-A-399133 is 2-hydroxyethyl oxalic acid or glyceryl iminodiethanoic acid for example.Iminodiethanoic acid-N-2-hydroxypropyl the sulfonic acid and the aspartic acid N-carboxymethyl N-2-hydroxypropyl-3-sulfonic acid sequestrant that are described among the EP-A-516102 also are suitable for herein.Be described in the Beta-alanine-N among the EP-A-509382, N '-oxalic acid, aspartic acid-N, single acetate of N '-oxalic acid, aspartic acid-N-and imino-diacetic succsinic acid sequestrant also are suitable.

EP-A-476257 has described the suitable sequestrant based on amino.EP-A-510331 has described from collagen protein, Keratin sulfate or casein derived suitable sequestrant.EP-A-528859 has described suitable alkyl imino oxalic acid sequestrant.Dinicotinic acid and 2-phosphine butane-1,2, the 4-tricarboxylic acid also is suitable.G-NH2-N, N '-disuccinic acid (GADS), quadrol-N, N '-two pentanedioic acid (EDDG) and 2-hydroxyl propylene diamine-N, N '-disuccinic acid (HPDDS) also is suitable.

Enzyme

In component of the present invention or to contain another useful in the cleaning combination of component of the present invention preferred ingredient be one or more additional enzymes.

Preferred additional enzyme material comprises commercially available lipase, at, amylase, neutrality and Sumizyme MP, esterase, cellulase, polygalacturonase, Sumylact L and the peroxidase that is routinely added in the detergent composition.Suitable enzyme has been discussed in US3519570 and US3533139.

Preferred commercially available proteolytic enzyme comprises those that sold with trade name Alcalase, Savinase, Primase, Durazym and Esperase by Novo Industries A/S (Denmark), those that sell with trade name Maxatase, Maxacal and Maxapem by Gist-Brocades, those that sell by Genencor International and sell with trade name Opticlean and Optimase by SolvayEnzymes those.Proteolytic enzyme can be joined in the composition of the present invention, by composition or composition weight, its content is the 0.0001-20% organized enzyme.

Preferred amylase comprises: for example, from the α-Dian Fenmei that the specific bacterial strain of Bacillus licheniformis obtains, it is described in greater detail among the GB-1269839 (Novo).Preferred commercially available amylase comprises: for example, and those that those that sold with trade name Rapidase by Gist-Brocades and Novo Industries A/S sell with trade name Termamyl and BAN.Amylase can be incorporated in the composition of the present invention, press composition weight meter, its amount is the 0.0001-2% organized enzyme.

By composition weight of the present invention, lipolytic enzyme can be with 0.0001-12%, and the amount of the active lipolytic enzyme of preferred 0.001-10% exists, and by the weight of composition, most preferably the amount with the active lipolytic enzyme of 0.001-0.3% exists.

Lipase can be obtained by mould or bacterial origin, for example it is the bacterial strain that belongs to the generation lipase of (Thermomyces sp.) or Rhodopseudomonas (Pseudomonas sp.) from Humicola (Humicola sp.), tea toadstool, comprises what pseudomonas pseudoalcaligenes (Pseudomonas pseudoalcaligenes) or Pseudomonas fluorescens (Pseudomonasfluorecens) obtained.Coming from the chemistry of these bacterial strains or the lipase of genetically altered mutant also is useful in this article.Preferred lipase is that it is described among the European patent EP-B-0218272 that has authorized from pseudomonas pseudoalcaligenes (Pseudomonas pseudoalcaligenes) deutero-.

Another preferred lipase is to come from the gene of Humicolalanuginosa and express this gene in as host's aspergillus oryzae (Aspergillus oryza) by the clone to obtain herein, as described in European patent application EP-A-0258068, it can be from Novo Industri A/S, Bagsvaerd, Denmark buys with trade name Lipolase.Among the US4810414 of the Huge-Jensen that this lipase was issued on March 7th, 1989 etc. description is arranged also.

Organic polymer

Organic polymer is the preferred annexing ingredient of foaming component of the present invention or the cleaning combination that contains this component of the present invention, and preferably as the component existence of any grain fraction, they can play a part for example grain fraction to be bonded together.Refer to herein about " organic polymer " and in detergent composition, to be used as dispersion agent usually, with any basically polymeric organic compound of anti redeposition agent and soil-suspending agent, comprise any high molecular organic polymer that is described as the clay flocculating agent herein.

By composition or composition weight, organic polymer is generally with 0.1-60%, preferred 0.5-25%, and most preferably the amount of 1-15% joins in the detergent composition of the present invention.

The example of organic polymer comprises poly carboxylic acid or its salt of water miscible organic homopolymerization or copolymerization, and wherein this poly carboxylic acid comprises at least 2 by no more than 2 carboxyls that carbon atom is separated from each other.The polymkeric substance of back one type is disclosed among the GB-A-1596756.The example of such salt is the multipolymer of the polyacrylate of MW 2000-5000 and itself and maleic anhydride, and such multipolymer has 20000-100000, particularly the molecular weight of 40000-80000.

Polyamino compounds is useful in this article, comprises from aspartate-derived those those disclosed among EP-A-305282, EP-A-305283 and EP-A-351629 for example.

Contain the terpolymer that is selected from toxilic acid, vinylformic acid, poly aspartic acid and vinyl alcohol monomeric unit, those that particularly have a 5000-10000 molecular-weight average also are suitable for herein.

Other organic polymer that is suitable for joining in the detergent composition herein comprises derivatived cellulose for example methylcellulose gum, carboxymethyl cellulose, Vltra tears and Natvosol.

Another is applicable to that organic compound (it is preferred clay suspending agent/anti redeposition agent) herein can be the positively charged ion monoamine and the diamines of the ethoxylation of following formula:

Wherein X is a non-ionic group, and it is selected from H, C ₁-C ₄Alkyl or hydroxyalkyl acrylate or ether group and its mixture, a is 0-20, preferred 0-4 (for example ethylidene, propylidene, hexa-methylene), b is 1 or 0; For positively charged ion monoamine (b=0), n is 16 at least, general scope at 20-35; For cationic diamine (b=1), n is about 12 at least, generally in the scope of about 12-42.

Other the dispersion agent/anti redeposition agent that is used for herein is described in EP-B-011965 and US4659802 and US4664848.

The soft system of clay

Foaming component of the present invention or cleaning combination can contain the soft system of clay, and it contains clay mineral compound and optional clay flocculating agent.

The clay mineral compound is the terre verte compound preferably.Terre verte is disclosed in Procter ﹠amp; Among the US3862058 of Gamble Company, US3948790, US3954632 and US4062647 and EP-A-299575 and the EP-A-313146, it has described suitable organic polymer clay flocculating agent.

The polymeric dye transfer inhibitor

Foaming component herein or cleaning combination also can contain 0.01-10% weight, the polymeric dye transfer inhibitor of preferred 0.05-0.5% weight.

This polymeric dye transfer inhibitor is preferably selected from multipolymer, the polyvinylpyrrolidonepolymers polymers of polyamine N-oxide pllymers, N-vinyl pyrrolidone and N-vinyl imidazole, or its mixture.

A) polyamine N-oxide pllymers

Be applicable to that herein polyamine N-oxide pllymers contains the unit of following structural formula I:

Wherein P is that polymerizable unit and A are :-NCO-,-COO-,-CO-,-O-,-S-,-N-; X is 0 or 1; R is aliphatic series, aromatic series, heterocycle or alicyclic group or its any mixture of aliphatic series, ethoxylation, and the nitrogen-atoms of N-O group can be connected thereto or the nitrogen of N-O group is the part of these groups.

The N-O group can be represented by following general formula:

R wherein ₁, R ₂, R ₃Be aliphatic series, aromatic series, heterocycle or alicyclic group or its mixture, x or/and y or/and z is 0 or 1, and wherein the nitrogen-atoms of N-O group can be connected or form the part of these above-mentioned groups.This N-O group can be that the part of this polymerizable unit (P) maybe can be connected on this polymeric skeleton, or both combinations.

Wherein the N-O group suitable polyamine N-oxide that forms a polymerizable unit part comprises that R wherein is selected from the polyamine N-oxide of aliphatic series, aromatic series, alicyclic ring or heterocyclic group.The described polyamine N-oxide of one class comprises the wherein polyamine N-oxide of the nitrogen-atoms formation R group part of N-O group.Preferred polyamine N-oxide compound is that wherein R is for example those of pyridine, pyrroles, imidazoles, tetramethyleneimine, piperidines, quinoline, acridine and its derivative of heterocyclic group.

Other suitable polyamine N-oxide is the polyamine oxide compound, and wherein the N-O group is connected on the polymerizable unit.A preferred class of these polyamine N-oxide comprises the have general formula polyamine N-oxide of (I), and wherein R is aromatic series, heterocycle or alicyclic group, and wherein the nitrogen-atoms of N-O functional group is the part of described R group.This class examples of substances is that wherein R is for example polyamine oxide compound of pyridine, pyrroles, imidazoles and its derivative of heterogeneous ring compound.

Can obtain polyamine N-amine oxide with almost any polymerization degree.The polymerization degree is not crucial, as long as this material has needed water-soluble and dye suspension ability.Usually, molecular-weight average is in the scope of 500-1000000.

B) multipolymer of N-vinyl pyrrolidone and N-vinyl imidazole

Be suitable for herein be N-vinyl imidazole and N-vinylpyrrolidone copolymers with 5000-50000 molecular-weight average.Preferred multipolymer has 1: 0.2 N-vinyl imidazole: N-vinyl pyrrolidone mol ratio.

C) Polyvinylpyrolidone (PVP)

Component of the present invention or composition also can use the Polyvinylpyrolidone (PVP) (" PVP ") of molecular-weight average as 2500-400000.Suitable Polyvinylpyrolidone (PVP) is from ISPCorporarion, New York, NY and Montreal, Canada buys with ProductName PVP K-15 (viscosity molecular weight is 10000), PVP K-30 (molecular-weight average is 40000), PVP K-60 (molecular-weight average is 160000) and PVP K-90 (molecular-weight average is 360000).Also can obtain PVP K-15 from ISP Corporation.Can comprise SokalanHP 165 and Sokalan HP 12 from other suitable Polyvinylpyrolidone (PVP) that BASF Cooperation buys.

D) Ju Yi Xi oxazolidinone

Composition of the present invention also can use Ju Yi Xi oxazolidinone as the polymeric dye transfer inhibitor.The molecular-weight average of described Ju Yi Xi oxazolidinone is 2500-400000.

E) polyvinyl imidazol

Composition of the present invention also can use polyvinyl imidazol as the polymeric dye transfer inhibitor.The molecular-weight average of described polyvinyl imidazol is preferably 2500-400000.

White dyes

Foaming component herein or cleaning combination also can randomly contain the hydrophilic white dyes of some type of the 0.005-5% weight of having an appointment.

Useful herein hydrophilic white dyes comprises those with following structural formula:

R wherein ₁Be selected from anilino, N-2-two-hydroxyethyl and NH-2-hydroxyethyl; R ₂Be selected from N-2-pair-hydroxyethyl, N-2-hydroxyethyl-N-methylamino, morpholino, chlorine and amino; With M be for example sodium or potassium of the salifiable positively charged ion of shape.

As the R in following formula ₁Be anilino, R ₂Be N-2-two-hydroxyethyl and M are positively charged ions for example during sodium, this whitening agent is 4,4 ' ,-two [(4-anilino-6-(N-2-two-hydroxyethyl)-s-triazine-2-yl) amino]-2,2 '-stilbene disulfonic acid and disodium salt.This specific whitening agent is sold by Ciba-Geigy Corporation with trade(brand)name Tinopal-UNPA-GX.Tinopal-UNPA-GX is a preferred hydrophilic white dyes useful in this paper detergent composition.

As the R in following formula ₁Be anilino, R ₂Be that N-2-hydroxyethyl-N-2-methylamino and M are positively charged ions for example during sodium, this whitening agent is 4,4 '-two [(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazine-2-yl) amino]-2,2 '-stilbene disulfonic acid disodium salt.This specific whitening agent is sold by Ciba-Geigy Corporation with trade(brand)name Tinopal 5BM-GX.

As the R in following formula ₁Be anilino, R ₂Be that morpholino and M are positively charged ions for example during sodium, this whitening agent is 4,4 '-two [(4-anilino-6-morpholino-s-triazine-2-yl) amino] 2,2 '-stilbene disulfonic acid, sodium salt.This specific whitening agent is sold by Ciba-Geigy Corporation with trade(brand)name Tinopal AMS-GX.

Cationic fabric softener

Also cationic fabric softener can be incorporated into component of the present invention or contain in the composition of component of the present invention.Suitable cationic fabric softener comprises water-insoluble tertiary amine or two long-chain acid amides materials, as disclosed in GB-A-1514276 and EP-B-0011340.

The general total amount that adds of cationic fabric softener is a 0.5-15% weight, usually 1-5% weight.

The component that other is optional

Be suitable for being included in other optional components in component of the present invention or this paper cleaning combination and comprise very preferably spices, bleaching catalyst, tinting material and filling salt, sodium sulfate is preferred filling salt.

The pH of composition

Foaming component of the present invention or cleaning combination can have acidity, neutrality or alkaline pH, and this depends on its purposes or is included in annexing ingredient in this component or the composition.This component herein or composition are preferably 3-13.5 by the pH of 1% measured in solution in distilled water, preferably 4.0-12.5, most preferably 5-12.0 at least.

The form of cleaning combination

The cleaning combination that contains component of the present invention can pass through prepared in various methods, comprises that various dry component in the detergent composition are mixed with being included in, extruding, compacting and agglomeration.Foaming component of the present invention can be used as independent composition component and is present in the cleaning combination, perhaps can be the part of other component of composition or compound or joins in other component or compound of composition.

Cleaning combination of the present invention can adopt various physical form, comprises granular, extrudate, sheet or bar form.Especially, this cleaning combination is so-called spissated granular detergent composition, and it is adapted to pass through the distribution drawer or joins in the washing machine by distribution device, and described distribution device is placed in the washing machine rotating cylinder with dirty fabric.

The median size of basic composition that contains the granular cleaning combination of foaming composition of the present invention can be 0.1-5.0mm, but should be preferably such, it makes no more than 5% particulate diameter greater than 2.5mm, or even 1.7mm, no more than 5% particulate diameter is less than 0.15mm.

Defined herein term " median size " calculates by composition sample is divided into a lot of parts (generally being 5 parts) at a series of Tyler sieve top sieves.The parts by weight that obtain thus are to the aperture mapping of sieve.Median size is that sample passes through the aperture of 50% (weight).

The bulk density that contains the granular cleaning of particulate composition of the present invention or detergent composition generally is 300g/l at least, and more preferably 500g/l, and even 650-1200g/l more preferably arrives 850g/l.Bulk density is by being measured by simple funnel and measuring cup device, and it is installed in by rigidity that coniform funnel on the base is formed and a plate valve is housed so that allow object in the funnel be emptied to be placed in the axially aligned coniform measuring cup below the funnel in its lower end.This funnel 130mm height, the upper and lower ends internal diameter is respectively 130mm and 40mm.It is to install like this, makes 140mm place on base upper surface, lower end.The height overall of measuring cup is 90mm, and interior height is 87mm, and internal diameter is 84mm, and it demarcates volume is 500ml.

In order to measure, topple over hand this funnel is filled up powder, open plate valve and allow the powder measuring cup that overfills.From base, take out this measuring cup that fills up and with a straight flange instrument for example cutter remove excessive powder by its upper limb.This measuring cup that fills up of weighing then multiply by 2 values that obtain by powder weight bulk density (g/l) is provided.If desired, repeat to measure.

Said composition be preferably dissolved in cold or cold water in, promptly the easy dissolution of said composition is at about 0-32.2 ℃, in the water of preferably about 1.6-10 ℃ of temperature.

The laundry washing methods

Machine washing clothes washing method herein generally comprises in washing machine with dissolving therein or having disperseed the present invention of significant quantity to machine-wash the laundry component or the aqueous cleaning solution that comprises the composition of foaming component of the present invention is handled the dirt clothes.About the detergent composition of significant quantity, it refers to the product dissolving of 40-300g or is dispersed in the washing soln of 5-65 liter, and this is normally used common product dosage and a washing soln volume in the machine washing clothes washing method of routine.

That uses in an embodiment writes a Chinese character in simplified form

In illustrative foaming component and cleansing composition, write a Chinese character in simplified form the component symbol and have following meaning: LAS: straight chain C ₁₂Sodium alkyl benzene sulfonate TAS: tallow alkyl sodium sulfate C45AS: C ₁₄-C ₁₅Straight-chain alkyl sulfate MES: C ₁₈The alpha-sulfo methyl ester C of lipid acid _XyE _zS: with the C of z moles of ethylene oxide condensation _1x-C _1yBranched-chain alkyl sulphur

Acid sodium MBAS _{X, y}: the alkylsurfuric acid with mid-chain branched of an average x carbon atom

Sodium wherein comprises average y carbon atom C in a chain unit ₄₈SAS: C ₁₄-C ₁₈Secondary alcohol sodium sulfate SADE _xS: with formula 2-(R) .C of z moles of ethylene oxide condensation ₄H ₇-

1,4-(SO ₄-) ₂C ₁₄-C ₂₂Alkyl two sodium sulfate, wherein

R=C ₁₀OC ₁₈C _XyE _z: with the C of average z moles of ethylene oxide condensation _1x-C _1yBranching

Primary alconol QAS I: R ₂.N ⁺(CH ₃) ₂(C ₂H ₄OH), R ₂=50%-60%C ₉40

-50%C ₁₁QAS II: R ₁.N ⁺(CH ₃) (C ₂H ₄OH) ₂, R ₁=C ₁₂-C ₁₄Soap: the straight chain alkane that obtains from 80/20 tallow and coconut oil blend

Yl carboxylic acid sodium TFAA I: C ₁₂-C ₁₄Alkyl N-methyl glucose amide TFAA II: C ₁₆-C ₁₈Alkyl N-methyl glucose amide TPKFA: the full fraction lipid acid STPP of C12-C14 topping: unformed tripolyphosphate natrolite A I: formula Na ₁₂(AlO ₂SiO ₂) ₁₂.27H ₂The primary particle diameter of O is 0.1

-10 microns hydrated sodium aluminosilicate zeolite A II: the zeolite A INaSKS-6 of super-dry: formula δ-Na ₂Si ₂O ₅Crystalline layered silicate citric acid I: no water citric acid citric acid II: citric acid monohydrate compound malic acid: anhydrous malic acid maleic acid: anhydrous maleic acid aspartic acid: anhydrous aspartic acid carbonate I: average particle diameter is at the no aqueous sodium carbonate carbonate II between the 200-900 μ m: average particle diameter is at the no aqueous sodium carbonate bicarbonate between the 100-200 μ m: particle diameter is distributed in the no aqueous carbonate hydrogen between the 400-1200 μ m

Sodium silicate: amorphous silicic sodium (SiO ₂: Na ₂O is than=2.0) sodium sulfate: the anhydrous slufuric acid na citrate: activity is 86.4%, size distribution 425-850 μ m it

Between citrate trisodium dihydrate MA/AA: toxilic acid/acrylic copolymer of 1: 4, molecular-weight average are approximately

70000CMC: Xylo-Mucine proteolytic enzyme: by NOVO Industries A/S with trade(brand)name Savinase

The activity of selling is the proteolytic ferment Acalase of 4KNPU/g: the activity of being sold by NOVO Industries A/S is 3AU/g

The proteolytic ferment cellulase: by NOVO Industries A/S with trade(brand)name Carezyme

The activity of selling is the cellulase amylase of 1000CEVU/g: by NOVO Industries A/S with trade(brand)name Termamyl

The activity that 60 T sell is the amylolytic enzymes lipase of 60KNU/g: by NOVO Industries A/S with trade(brand)name Lipolase

The activity of selling is the lipolytic enzyme endoenzyme of 100kLU/g: the activity of being sold by NOVO Industries A/S is

The endo-dextranase of 3000CEVU/g (endoglunase) PB4: nominal formula NaBO ₂.3H ₂O.H ₂O ₂Sodium perborate tetrahydrate PB1: nominal formula NaBO ₂.H ₂O ₂Anhydrous sodium perborate SYNTHETIC OPTICAL WHITNER percarbonate: the nominal formula is 2Na ₂CO ₃.3H ₂O ₂SODIUM PERCARBONATE NAC-OBS: (nonanoyl amino caproyl) oxygen base benzene sulfonic acid sodium salt NOBS: the nonanoly acyloxy benzene sulfonate DPDA of sodium-salt form: diperoxy dodecane diacid PAP: the amino peroxy caproic acid NAPAA of N-O-phthalic acyl group acyl: the amino peroxide adipic acid of nonanoyl base acyl NACA: 6-nonyl amino-6-oxo-caproic acid TAED: tetra-acetylated ethylenediamine DTPMP: sold with trade name Dequest 2060 by Monsanto

The SYNTHETIC OPTICAL WHITNER of diethylenetriamine five (methylene phosphonic acid salt) photoactivation: sulfonated zinc of sealing or aluminium phthalocyanine white dyes 1: 4,4 '-two (2-sulfo group styryl) biphenyl disodium white dyes 2: 4,4 '-two [(4-anilinos-6-morpholino-1,3, the 5-triazine-

The 2-yl) amino] stilbene-2,2 '-disulfonic acid disodium HEDP: 1,1-hydroxyl ethane di 2 ethylhexyl phosphonic acid PNVO: polyvinylpyridine N-oxide compound PVPVI: the multipolymer QEA of polyvinylpyrrolidone and vinyl imidazole: two ((C ₂H ₅O) (C ₂H ₄O) _n) (CH ₃)-N ⁺-C ₆H ₁₂-N ⁺-(CH ₃)

Two ((C ₂H ₅O)-(C ₂H ₄O) _n), n=20-30SRP1 wherein: sulfo group with oxidation inferior ethoxyl and terephthaloyl skeleton

The end capped ester SRP2 of benzoyl: poly-(1,2 propylidene terephthalate) of diethoxyization is short

Block polymer silicone antifoam agent: have the siloxanes oxyalkylene copolymers as poly-two of dispersion agent

The methylsiloxane Foam Control, described Foam Control

With the ratio of described dispersion agent be 10: 1-100: 1

As noted, below among the embodiment, all content are all represented in the umber of every composition weight or by the % of composition weight meter:

Granule foaming component embodiment

Following embodiment illustrates granule foaming component of the present invention, its each, or its mixture may be used in the cleaning combination.

As mentioned above, be used to form the particulate currently known methods by any this area and can make grain fraction of the present invention.By forming the melt of anhydrous basically stablizer, and this melt is joined in the premixture of other component and form melt, this component of thorough mixing solidify to form following grain fraction with this melt afterwards.Particle _A-J

	???A	???B	???C	????D	????E	????F	????G	????H	????I	????J
											TFAAI/TFAAII	??32.0	??31.0	??12.0	??32.0	??15.0	??15.0	???37	???25.0	????-	??10.0
C24E3/C24E5	???-	????-	??28.0	????-	??25.0	??25.0	???-	???5.0	??15.0	??15.0
											PEG?4000	???5.0	???5.3	???-	???5.0	????-	???-	??7.0	???5.0	????-	???5.0
Citric acid I	??13.5	??14.0	??20.0	??15.5	??16.0	??20.0	??15.0	??10.0	????-	??10.0
											Toxilic acid	???-	???-	???-	????-	????-	????-	????-	????-	??10.5	??10.0
Yellow soda ash I	??13.5	???-	??20.0	????-	???-		????-	????-	??15.0	??10.0
											Yellow soda ash II	????-	??14.0	???-	???6.0	??14.0	??20.0	??10.0	??10.0	???5.0	????-
Sodium bicarbonate	????-	???-	???-	???6.0	???0	????-	??10.0	????-	???5.5	???5.0
											Zeolite A II	??18.0	??35.7	??20.0	??18.0	???-	???9.0	??10.0	???5.0	??14.0	??17.0
LAS	??9.0	???-	???-	???-	??12.0	????-	????-	??10.0	???-	??13.0
											QAS?I/QAS?II	??9.0	???-	???-	???-	???-	????-	???6.0	???3.0	???-	????-
TAED/NOBS/ NACA-OBS	???-	???-	???-	??19.0	??10.0	????-	????-	???7.0	??35.0	????-
											The perborate percarbonate	???-	???-	???-	???-	???-	??19.0	????-	??20.0	???-	????-
Silicone antifoam agent	???-	???-	???-	???-	??8.0	????-	????-	????-	???-	???5.0

Following embodiment has illustrated below the cleaning combination that contains foaming component of the present invention: the embodiment 1 to be according to high-density of the present invention and to contain the detergent formulation of SYNTHETIC OPTICAL WHITNER:

	?????a	????b	????c
				The powder of blowing
Zeolite A	????5.0	????5.0	????15.0
				Sodium sulfate	????0.0	????5.0	????0.0
??????????????????LAS	?????-	????5.0	????3.0
				????????????????C45AS	????3.0	????2.0	????4.0
??????????????????QAS	?????-	?????-	????1.5
				????????????????DTPMP	????0.4	????0.4	????0.4
??????????????????CMC	????0.4	????0.4	????0.4
				????????????????MA/AA	????4.0	????2.0	????2.0
Particle A	????20.0
				Particle B	?????-	????15.0	?????-
Particle E	?????-	?????-	????10.0
				In the spraying (on particle)
The spices of sealing	????0.3	????0.3	????0.3
				?????????????????C25E3	?????-	?????-	????2.0
The additive of doing

?????????????????????????????QEA	?????-	?????-	????0.5
				Citrate trianion	????5.0	?????-	????2.0
Supercarbonate	?????-	????3.0	?????-
				Carbonate	????8.0	????10.0	????5.0
???????????????????????NAC?OBS	????6.0	?????-	?????-
				Mn catalyst	?????-	?????-	????0.3
????????????????????????????NOBS	?????-	????2.0	?????-
				?????????????????????????????PB1	????14.0	????7.0	?????-
Polyethylene oxide MW 5,000,000	?????-	?????-	????0.2
				Wilkinite	?????-	?????-	????10.0
Citric acid	?????-	?????-	????0.5
				Proteolytic enzyme	????1.0	????1.0	????1.0
Lipase	????0.4	????0.4	????0.4
				Amylase	????0.6	????0.6	????0.6
Cellulase	????0.6	????0.6	????0.6
				Silicone antifoam agent	????5.0	????5.0	????5.0

The additive of doing
				Sodium sulfate	?????0.0	?????3.0	?????0.0
Surplus material (moisture and other component)	????100.0	????100.0	????100.0
				Density (g/l)	?????850	?????850	?????850

Be according to high density detergent agent prescription of the present invention below the embodiment 2:

	????d	????e
			Particle A	????15.0
Particle H		????30.0
			In the spraying
?????????C25E3	?????-	????1.0
			Spices	????0.5	????0.5
The additive of doing
			??????????HEDP	????0.5	????0.3
??????????SKS6	????13.0	????10.0
			Citrate trianion	?????-	????1.0
??????NAC?OBS	????4.1	?????-
			?????????TAED	????0.8	?????-
Percarbonate	????20.0	????5.0
			??????????SRP1	????0.3	????0.3
Proteolytic enzyme	????1.4	????1.4
			Lipase	????0.4	????0.4
Cellulase	????0.6	????0.6
			Amylase	????0.6	????0.6

??????????????QEA	????1.0	?????-
			Silicone antifoam agent	????5.0	????5.0
Whitening agent 1	????0.2	????0.2
			Whitening agent 2	????0.2	?????-
Density (g/l)	????850	????850

Claims (16)

1, a kind of anhydrous basically need not to stir just can provide foam or blistered foaming component, its contain tight blended anhydrous basically can reduce capillary surface active composition of air-water and the foaming component that when contacting, can produce gas with water.

2, according to the foaming component of claim 1, producing the average bubble particle diameter when it contacts with water is 400 microns or littler, preferred 200 microns or littler, and more preferably 100 microns or littler bubble.

3, according to the component of claim 1 or 2, it is to obtain by the method that comprises following step:

A) melt of formation surface active composition;

B) thus the melt of step a) is joined the intimate mixture that obtains this foaming component and this surface active composition in the foaming component and forms this foaming component.

4, according to the component of above-mentioned arbitrary claim, wherein should the foaming component contain organic acid source and carbonate source, preferably be anhydrous basically.

5, according to claim 1,2 or 4 component, wherein this surface active composition contains one or more anion surfactants, preferred alkyl sulfonate or alkyl-sulphate or its mixture.

6, according to the component of above-mentioned arbitrary claim, wherein this surface active composition has the fusing point more than 45 ℃, preferably contain the non-ionic surface active compound, it is selected from: the oxyalkylated acid amides of nonionic, effective for treatment of premature ejaculation or oxyalkylated alcohol, preferred one or more non-ionic surface active compounds, it is selected from the condensation product of polyhydroxy fatty acid amide and Fatty Alcohol(C12-C14 and C12-C18) and 1-15 mole alkylene oxide.

7, according to the component of above-mentioned arbitrary claim, it contains the surface active composition of 10-70% weight and the foaming component of 10-90% weight.

8, according to the component of above-mentioned arbitrary claim, it also contains one or more detergent active, and it is selected from washing assistant, perhydrate SYNTHETIC OPTICAL WHITNER, bleach-activating agent, enzyme, sequestrant, presses down foam system, whitening agent.

9, in cleaning combination, be used to provide the purposes of foaming according to the component of above-mentioned arbitrary claim.

10, be used for the purposes that the Foods or drinks product provides foaming according to each composition of claim 1-8.

11, bubble or the method for foaming by contacting with water to provide according to each component of claim 1-8 with need not to stir.

12, will contact the method that improved foaming and dispersing or dissolving property are provided with water according to each component of claim 1-8.

13, each the method for component of preparation claim 1-7 comprises following step:

A) melt of formation surface active composition;

B) thus the melt of step a) is joined the intimate mixture that obtains this foaming component and this surface active composition in the foaming component and forms this foaming component.

14, according to the method for claim 13, it is the part of agglomeration or extrusion method.

15, component preferred that contains arbitrary claim 1-8 is particle or sheet form, the on-aqueous liquid of preferred particulates form or solid cleaning combination.

16, a kind of method of laundering of textile fabrics, wherein with the composition of component or the claim 15 of fabric and arbitrary claim 1-8, or its solution contacts.