CN1370221A - Detergent compsns. components - Google Patents

Abstract

The present invention relates to detergent compositions or components comprising certain hydrophibically modified cellulosic materials, which provides protection of fabrics, whereof at least 80% by weight or even at least 90% by weight has a particle size of below 1000 microns or even below 850 or even 710 microns. Selection of material of this particle size results in improved dispercancy of the cellulosic material and imparts improved appearance and integrity benefits to fabrics and textiles laundered in washing solutions formed from such compositions.

Description

Detergent composition or component

Technical field

The present invention relates to detergent composition or component, it contains some hydrophobic nature modified fibre quality that has the specified particle size and preferably have the specified particle size distribution, and this material can provide protection to fabric.

Background of invention

As everyone knows, because the mechanical effect in washing and the use, fabric and textiles just tend to wearing and tearing through after a while, for example, staple fibre can come off from fabric also may form visible fiber bits, fine hair or " bobbles " on the surface of fabric, make fabric lose brand-new outward appearance.Common pending application PCT/US98/19139 has described the application of hydrophobic nature modified-cellulose polymkeric substance, has found that they can provide good whole structure for fabric.Though do not wish to be entangled in any theory, believe that these materials can combine the fiber of himself and fabric and textiles in washing process, and therefore the proneness of the fabric/textile degraded appearance of being washed is reduced or drop to minimum.

These materials are difficult for dissolving in water, so it depends on the dispersion of this material in bath water especially to washings and to the transmission on the fabric.The inventor finds that these hydrophobic nature modified-cellulose polymkeric substance can not disperse satisfactorily under certain conditions, so that use properties reduces, even stays the residue of this material on fabric.And the inventor finds that also other detergent ingredients can be entrained in this cellulosic materials under certain conditions, thereby further causes the residue problem, perhaps even also can reduce the use properties of these other compositions.

The contriver finds now, when use has the hydrophobic nature modified fibre quality of specified particle size, can reduce even avoid these problems.They find, when the size of particles of selected material is preferably below 1000 microns, or even be below 710 microns or even be below 500 microns the time, the breaking up of the branch of these materials improves, and can improve with dispersing or dissolving also of other detergent ingredients that polymkeric substance closely contacts.They also find, can improve the efficient of hydrophobic nature modified fibre quality thus, and improve the integrity of fabric thus.They find that also therefore preferably this material has narrow particle size distribution.

Common pending application US 60/113306 has described these hydrophobic nature modified materials and can be introduced in the detergent composition then with forming condensation product as washing assistants such as zeolites.The contriver has now found that, select the hydrophobic nature modified-cellulose polymkeric substance of size of particles to introduce these ready-formed particles when having, in the time of in the powder that blows out as condensation product and spraying drying, also can improve the dispersiveness or the solvability of these prefabricated particles and this composition and wherein important cellulosic materials.

Summary of the invention

The present invention relates to a kind of detergent composition or component, it contains hydrophobic nature modified fibre quality, wherein at least 80% or even at least 90% or even 100% size of particles be below 1000 microns, be preferably below 850 microns or even be below 710 microns.

Hydrophobic nature modified fibre quality can be introduced in said composition or the component with the form that dry method adds, and/or this hydrophobic nature modified fibre quality can be present in ready-formed particle such as aggregate with other detergent ingredients, in spraying drying or powder that blows out or the extrudate.

Said composition can be cloth-washing detergent or additive, fabric softener or fabric treating product.Preferred said composition or component are solid, are preferably particulate state or sheet, but also can are liquid, on-aqueous liquid and colloidal compositions here.

The present invention also relates to the washing or the processing of fabric and textiles in aqueous cleaning of making by the described detergent composition or the component of significant quantity or treatment soln.Detailed Description Of The Invention hydrophobic nature modified fibre quality and polymkeric substance

Hydrophobic nature modified fibre quality is also referred to as cellulosic materials here, is such some materials, wherein at least 80wt% or even 90wt%, but the size of particles of preferred 100wt% is lower than 1000 microns.But, can be preferably at least 80wt% or even 90wt% or even the size of particles of 100wt% be lower than 850 microns or even be lower than 710 microns or even be lower than 500 microns.

For reaching effect of the present invention, hydrophobic nature modified fibre quality pelletizing size and particle size distribution or span really can change in specific scope, this depends on this material is incorporated into mode in composition or the component, and depends on the definite character of composition and component.

When cellulosic materials adds fashionable with the form that dry method adds, as described here, the size of particles of preferred this material is the 1-1000 micron, more preferably its size of particles of 80% is the 10-900 micron, and more preferably its size of particles of 80% is 50 microns or even is 150 microns or even is 250-850 micron or even to 800 microns or even to 710 microns.The average particle size of this cellulosic materials is preferably the 100-850 micron so, more preferably 250-800 micron or even be the 350-800 micron.

When cellulosic materials is introduced into the prefabricated grain period of the day from 11 p.m. to 1 a.m, as described here, the size of particles of preferred this material is the 0.1-710 micron, more preferably its size of particles of 80% is the 1-550 micron, and more preferably its size of particles of 80% is 2 microns or even is 10 microns or even is 25-500 micron or even to 450 microns or even to 350 microns.The average particle size of this cellulosic materials is preferably the 5-500 micron so, more preferably 25-450 micron or even be the 50-400 micron.

In some applications, particle size distribution is narrow to be favourable, and for example span is 3 or lower, preferred 2 or lower, even more preferably 1.7 or even 1.5 or lower.

Term used herein " average particle size " means the geometry quality mid-diameter of one group of discrete particle, and it is preferably the dry screening technology and measures by the size of particles measuring technology based on quality of arbitrary standard." span " of particle size distribution used herein means geometric standard deviation, the best plan data of its available for example above-mentioned size of particles are closed the geometric widths of lognormality function and are calculated, and above-mentioned particle size data can be passed through the diameter (D of the diameter at 84.13% place in the cumulative distribution divided by 50% place _84.13/ D ₅₀) obtain, see people's such as Gotoh PowderTechnology Handbook, 6-11 page or leaf, Marcel Dekker, 1997.

Cellulosic materials with specified particle size can be by being that any means that material is screened on the basis obtains with size of particles.Preferable methods is for reducing its particle diameter by grinding or grinding the larger particles of this material, afterwards sieving and select required screening part than small-particle gained.Other method is known for those skilled in the art.A preferred part is used for composition described here or component with the form that dry method adds, and another part is incorporated in the ready-formed particle as described below.

Generally speaking, hydrophobic nature modified fibre quality contains that to account for this material 40wt% polymer-modified to the hydrophobic nature as described below of 100wt%, more preferably 50wt% is to 99wt%, or even 60wt% or even 70wt% polymer-modified to the hydrophobic nature as described below of 90wt%.Remaining wt% generally contains the impurity of introducing in manufacturing processed, as water, salt and a spot of organic compound, it can comprise alcohols, organic acid or its salt and/or processing aid.

The consumption of cellulosic materials in composition or component can thing combined according to the invention or the application of component and changing.Generally speaking, cellulosic materials is about 0.01-90wt% of detergent composition or component, 0.05-20wt% more preferably, or even be 0.05-15wt%.In detergent composition of the present invention, just as, amount that can optimum fiber quality is the 0.05-10wt% of detergent composition, preferred 0.05-5wt% or even 0.05-3wt% or even 0.1-2wt%.In detergent additives or component, or in the described hereinafter prefabricated particle, the preferred amount of this material can be the 0.05-40wt% of component, or even 0.05-20wt% or even 0.1-15wt% or even 1-10wt%.

It is 1-10 that cellulosic materials of the present invention preferred amount in composition or component makes the concentration of hydrophobic nature modified-cellulose polymkeric substance in washing lotion, 000ppm, preferred 10-7,000ppm or even 20-about 1,000ppm.

Hydrophobic nature modified-cellulose polymkeric substance comprises polymkeric substance, oligopolymer, multipolymer in the material of the present invention, also has crosslinked polymkeric substance, oligopolymer and multipolymer.Just as is known to the person skilled in the art, oligopolymer is the molecule of only being made up of several monomeric units, and polymkeric substance contains a large amount of monomeric units.To the present invention, oligopolymer is defined as molecular-weight average and is lower than about 1,000 molecule, is higher than about 1,000 molecule and polymkeric substance is a molecular-weight average.The molecular-weight average of a kind of suitable cellulose polymer compound of the present invention is about 5,000 to about 2,000,000, preferred about 50,000 to about 1,000,000.

Cellulose polymer compound used herein preferably have as shown in the formula:

Wherein each R is selected from R ₂, R _cAnd

Wherein:

-each R ₂Be independently selected from H and C ₁-C ₄Alkyl;

-each R _cFor :-(CH ₂) y-CO-OZ,

Wherein each Z is independently selected from M, R ₂, R _cAnd R _H

-each R _HBe independently selected from C ₅-C ₂₀Alkyl, C ₅-C ₇Cycloalkyl, C ₇-C ₂₀Alkaryl, C ₇-C ₂₀Aralkyl, substituted alkyl, hydroxyalkyl, C ₁-C ₂₀Alkoxyl group-2-hydroxyalkyl, C ₇-C ₂₀Alkyl-aryloxy-2-hydroxyalkyl, (R ₄) ₂The N-alkyl, (R ₄) ₂The N-2-hydroxyalkyl, (R ₄) ₃The N-alkyl, (R ₄) ₃The N-2-hydroxyalkyl, C ₆-C ₁₂Aryloxy-2-hydroxyalkyl.

-each R ₄Be independently selected from H, C ₁-C ₂₀Alkyl, C ₅-C ₇Cycloalkyl, C ₇-C ₂₀Alkaryl, C ₇-C ₂₀Aralkyl, aminoalkyl, alkyl aminoalkyl, dialkyl amino alkyl, piperidines substituted alkyl, morpholino alkyl, cycloalkyl aminoalkyl and hydroxyalkyl.

-each R ₅Be independently selected from H, C ₁-C ₂₀Alkyl, C ₅-C ₇Cycloalkyl, C ₇-C ₂₀Alkaryl, C ₇-C ₂₀Aralkyl, substituted alkyl, hydroxyalkyl, (R ₄) ₂N-alkyl and (R ₄) ₃The N-alkyl;

Wherein:

M is the positively charged ion that is fit to, and is preferably selected from Na, K, 1/2Ca and 1/2Mg;

Each x is 0 to about 5;

Each y is about 1 to about 5; And

Condition is:

-R _HSubstitution value be about 0.001 to 0.1, more preferably about 0.005 to 0.05, most preferably be about 0.01 to 0.05.

R when-Z is H or M _cSubstitution value be about 0.2 to 2.0, more preferably about 0.3 to 1.0, most preferably be about 0.4 to 0.7.

If-any one R _HHave a positive charge, it is by a suitable negatively charged ion institute balance; And

Two R4 the on-same nitrogen-atoms can together form a ring texture, and it is selected from piperidines or morpholine.

R _H" substitution value ", this paper is abbreviated as " DS sometimes _RH", mean substituted R in each dehydrated glucose unit _HThe mole number of component group, one of them dehydrated glucose unit are six-rings, shown in the repeating unit of general structure as indicated above.

R _C" substitution value ", this paper is abbreviated as " DS sometimes _RC", when meaning Z and being H or M, substituted R in each dehydrated glucose unit _CThe mole number of component group, one of them dehydrated glucose unit are six-rings, the repeating unit of general structure as indicated above.Requiring Z is that H or M exist the carboxymethyl of sufficient amount so that resulting polymers is solvable in order to guarantee.Be appreciated that the Z that removes requested number is the R of H or M _COutside the component, can also have and most preferably have other Z is not the R of H or M _CComponent.

This base polymer can by, the method described in for example common pending application PCT/US98/19139 and the PCT/US98/19142 makes.

The highly preferred modified-cellulose polymkeric substance of the present invention has the following specific parameter all different to each polymkeric substance, and below can be used for the general parameter of each highly preferred polymkeric substance.

The polymers for general use parameter

Molecular parameter is described
	The main polymer chain carboxymethyl cellulose
Carboxymethylation degree DS RC=0.3-2.0; Preferred DS RC=0.5-0.70
	Carboxymethyl distribution carboxymethyl is along the average and random distribution of main chain
Molecular weight Mw:5000-2000000.Preferably: moderate (approximately 250000g/mol)
	Modification type ether modification (except that carboxymethylation).The blended ether of cellulose
Modification degree DS RH=about 0.001-about 0.1

The particular polymers parameter

ID polymer modification type * * * preferred manufacturing procedure
	* A hexyl CMC hexyl ether chlorohexane joins the preparation method among the CMC
* B decyl CMC decyl ethers chlorodecane joins the preparation method among the CMC
	* C C12-C13 alkoxyl group-2-C12-C13 alkoxy C 12-C13 alkyl glycidyl ether adds hydroxypropyl CMC-2-hydroxypropyl ether and goes into preparation method in the CMC
* D hexadecyl CMC cetyl ether chlorine n-Hexadecane joins the preparation method among the CMC
	* 3-three methylamino-3-three methylamino-s-2-2 of E CMC, 3-epoxypropyl trimethylammonium chloride-2-hydroxypropyl ether hydrochloride hydroxypropyl ether hydrochloride ammonium joins the preparation method among the CMC
* 1 of [(C (O)-hexadecyl ketene dimer adds CH (C16H33) C (O) CH2 (the preparation method 6H33 of C1 in the CMC))] ester of F CMC or CMC, 3-dioxy-2-cetostearyl ester

The CMC=carboxymethyl cellulose

* make by Metsa Specialty Chemicals company

* is made by Akzo company

* * is DS concerning these materials _RHBe about 0.001-0.1 detergent composition and component

Hydrophobic nature modified fibre quality can be contained in the detergent composition or component described here with the form of independent particle with specified particle diameter described herein, and promptly so-called dry method adds, and it mainly is made up of polymer materials.

Hydrophobic nature modified fibre quality can also be with the pre-blend that forms with other detergent active ingredients, and/or exists with the prefabricated particulate forms that contains this material and other detergent active ingredients.

Premixture can be any cellulosic materials and one or more to be planted the premixture that other detergent component mixes formation herein.

The prefabricated particle that is fit among the present invention can obtain by following process: cellulosic materials is mixed with other component, with the mixture spraying drying, condense marumerizer then, extrude or compress, it is known that all these methods in conjunction with detergent component are those skilled in the art.Particularly preferred prefabricated particle is from the drying process of spraying, and condenses and extrudes the powder that obtains.For example, EP-A-763594 or EP-A-437888 have described the spray drying process that is fit to that forms such prefabricated particle.For example, common pending application US60/113306 and WO93/25378, EP-A-367339, EP-A-420317 or EP-A-506184 have described the method that is fit to that forms prefabricated particle by cohesion, and for example WO91/02047 has described the method that is fit to that forms prefabricated particle by extruding.

Prefabricated particle or premixture preferably comprise solid support material and/or matrix material, and preferably comprise a kind of tensio-active agent.

Matrix material can be can be with each composition combination or any composition that bonds together.Highly preferred matrix material is a tensio-active agent, particularly negatively charged ion and nonionogenic tenside.Most preferably there is a kind of anion surfactant at least.The tensio-active agent that is fit to sees below described.Other matrix material comprises polyoxyethylene glycol, PVAA, polyacrylic ester and/or maleic acid ester, Polyvinylpyrolidone (PVP) and derivative thereof, or their mixture.

Solid support material can be a particulate state composition arbitrarily.Useful particulate material comprises inorganic or organic acid or salt and washing assistant material such as silicate.Useful especially solid support material comprises Sulfates, phosphoric acid salt, carbonate, bicarbonate salts, inorganic peroxy salt, organic carboxyl acid class and salt thereof, amorphous silicic acid salt, crystalline (stratiform) silicates, Aluminosilicates and composition thereof.Preferably there is a kind of silico-aluminate at least.Other detergent ingredients

Composition of the present invention or component also contain other detergent component.The definite character of these other components and be incorporated into composition or component in amount will depend on the definite character of the physical form and the washing operation that is applied to thereof of composition or component.

They preferably contain at least a tensio-active agent and a kind of washing assistant, preferably also contain one or more other detergent ingredients, and it is selected from other tensio-active agent and washing assistant, SYNTHETIC OPTICAL WHITNER, bleaching catalyst, alkaline system, organic polymer, enzyme, suds suppressor, calcium soap, dispersion agent, dirt suspends and anti-redeposition agent, stain remover, spices, brightener, optical white, fabric softening agent such as clay and positively charged ion softener, other fabric care agent and other inhibiter.

Preferred other composition is a cyclic amine based polymer, as described in common pending application PCT/US98/19143 and the PCT/US98/19141, it can provide extra fabric integrity effect, particularly embodiment, especially those compounds described in the embodiment 1 and 2.The consumption of these polymkeric substance can be the 0.01-10wt% of composition or component, more preferably the 0.05-5wt% of composition or even 0.1-2wt%, or be the 0.05-30wt% of component, the more preferably 0.1-20wt% of component or even 0.3-10wt%.

When having the polymer-modified material of hydrophobic nature in the prefabricated particle, preferably in identical prefabricated particle, there are cyclic amine based polymer or its part.Tensio-active agent

Component of the present invention or composition preferably contain one or more tensio-active agents, and it is selected from negatively charged ion, nonionic, positively charged ion, both sexes, both sexes and zwitterionics and composition thereof.Anion surfactant

Component of the present invention or composition preferably contain at least a anion surfactant.Any in fact anion surfactant that washs purpose that can be used as all can be included in detergent component or the composition.

These tensio-active agents comprise negatively charged ion be sulfate radical, sulfonate radical, carboxylate radical salt (comprise sodium for example, potassium, ammonium and the ammonium salt class that replaces such as list, two and the trolamine salt), also comprise alkyl ethoxy carboxylate class and soap class, and sarcosinate surfactant.Preferred anionic is vitriol and sulfosalt surfactant.

Also preferably contain the dianionic surfactant of preferred two sulfate radicals or two sulfonate radicals or a sulfate radical and a sulfonate radical.

Highly preferred surfactant system contains a kind of sulfonate and a kind of sulfate surfactant, preferably straight or branched alkylbenzene sulfonate and alkyl-sulphate and/or alkyl ethoxy sulfate as described herein.

The soap class tensio-active agent that is fit to comprises secondary soap class tensio-active agent, and it contains a carboxyl unit that is connected on the secondary carbon(atom).Preferred as used herein secondary soap class tensio-active agent is water miscible material, and it is selected from 2-methyl isophthalic acid-undecanoic acid, 2-ethyl-1-capric acid, 2-propyl group-1-n-nonanoic acid, the water-soluble salt of the sad and 2-amyl group-1-enanthic acid of 2-butyl-1-.In some soap class also can be included in, as suds suppressor.

Other anion surfactant comprises N-acyl sarcosinate class; isethionic acid salt such as acyl isethinate class; N-acyl taurine salt class; the methylamino esilate; the fatty amide of alkyl succinic acid salt and sulfosuccinate, sulfosuccinic acid monoesters class (especially saturated and undersaturated C ₁₂-C ₁₈The monoesters class), sulfosuccinic acid diesters class (especially saturated and undersaturated C ₆-C ₁₄The diester class).Resin Acid and hydrogenated resin acids also are fit to, as rosin, and staybelite, and be present in or be derived from the Resin Acid and the hydrogenated resin acids of tallow oil.The anion sulfate acid salt surfactant

Suitable anion sulfate tensio-active agent as used herein comprises the primary and secondary alkylsurfuric acid salt of straight chain and side chain, alkyl ethoxy sulfate class, fatty oil acylglycerol Sulfates, alkyl phenol epoxy ethane ether salt class, C ₅-C ₁₇Acyl group-N-(C ₁-C ₄Alkyl) and N-(C ₁-C ₂The Sulfates of the Sulfates of glucosamine sulfate class hydroxyalkyl), and alkyl polysaccharide such as alkyl glucosan (nonionic non-sulfuric acid compound described here).

Alkyl sulfate surfactant is preferably selected from the uncle C of straight chain and side chain ₁₀-C ₁₈Alkylsurfuric acid salt, more preferably C ₁₁-C ₁₅Branched-chain alkyl Sulfates and C ₁₂-C ₁₄The straight-chain alkyl sulfate class.

Alkyl ethoxy sulfate surfactant is preferably selected from every mole of C with the oxyethane ethoxylation of 0.5-20 mole ₁₀-C ₁₈The alkylsurfuric acid salt.More preferably, alkyl ethoxy sulfate surfactant is every mole and uses 0.5-7, the C of preferred 1-5 moles of ethylene oxide ethoxylation ₁₁-C ₁₈, C most preferably ₁₁-C ₁₅Alkyl-sulphate.

The present invention especially preferably use the mixture of preferred alkyl-sulphate and/or sulfonate and alkyl ethoxy sulfate surfactant.This mixture has been disclosed among the PCT patent application WO 93/18124.The anion sulfoacid salt surfactant

Being fit to as used herein, the anionic sulphonate tensio-active agent comprises C ₅-C ₂₀The linear alkylbenzene sulfonate class, alkyl ester sulfonate class, C ₆-C ₂₂Uncle or secondary paraffin sulfonate class, C ₆-C ₂₄The alkene sulfonic acid salt, the sulfonation multi-carboxylic acid, the alkyl glycerol sulfonate class, fatty acyl group glycerol sulfonate class, fatty oil acylglycerol Sulfonates, and composition thereof.Alkoxy-based non-ionic surface active agent

Alkoxy-based non-ionic surface active agent all is suitable in this use in fact arbitrarily.Preferred ethoxylation and propenoxylated nonionogenic tenside.

The preferred alkoxylated tensio-active agent can be selected from the nonionic condenses of induced by alkyl hydroxybenzene, the nonionic ethoxylated alcohol class, nonionic ethoxylated/propoxylated fatty alcohol class, with the nonionic ethoxylate/propoxylated glycerine condenses of propylene glycol condensation with the nonionic ethoxylate condensation product of propylene oxide/ethylenediamine adduct condensation.Nonionic alcohol alcoxylates tensio-active agent

The condensation product of the oxirane of aliphatic alcohols and 1-25 mole, particularly oxyethane and/or propylene oxide is adapted at this use.The alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) can be a straight or branched, the uncle or the second month in a season, and generally comprise 6-22 carbon atom.Particularly preferred is to comprise the alcohol of 8-20 carbon atom and the condensation product that the condensation of 2-10 moles of ethylene oxide obtains in every mole of alkyl.The nonionic polyhydroxy fatty acid amide surfactant

Suitable polyhydroxy fatty acid amide class as used herein is for having R ²CONR ¹Those of Z structural formula, wherein R ¹Be hydrogen, C ₁-C ₄Alkyl, 2-hydroxyethyl, 2-hydroxypropyl, oxyethyl group, propoxy-or its mixture, preferred C ₁-C ₄Alkyl, more preferably C ₁Or C ₂Alkyl, most preferably C ₁Alkyl (being methyl); R ²Be C ₅-C ₃₁Alkyl, preferred straight chain C ₅-C ₁₉Alkyl or alkenyl, more preferably straight chain C ₉-C ₁₇Alkyl or alkenyl, most preferably straight chain C ₁₁-C ₁₇Alkyl or alkenyl, or its mixture; Z is the polyhydroxy alkyl that contains the straight-chain alkyl chain, and wherein at least 3 hydroxyls are directly connected on the chain, or its alkoxy derivative (preferred ethoxylation or propoxylated derivative), and Z preferably is derived from the reducing sugar in the reductive amination process; More preferably Z is a glycidyl.The nonionic fatty acid amide surfactant

The fatty acid amide surfactant that is fit to comprises having R ⁶CON (R ⁷) ₂Those tensio-active agents of molecular formula, wherein R ⁶For comprising 7-21, be preferably the alkyl of 9-17 carbon atom, each R ⁷Be selected from hydrogen, C ₁-C ₄Alkyl, C ₁-C ₄Hydroxyalkyl and-(C ₂H ₄O) _xH, wherein x is 1-3.The nonionic alkyl polysaccharide surfactant

Suitable alkyl polysaccharide as used herein was open already in the US patent 4 565 647 of the Llenado of 21 mandates January in 1986, it contains one and comprises 6-30 carbon atom and a polysaccharide, as hydrophobic group and hydrophilic radical that comprises 1.3-10 sugar unit of many glycosides.

Preferred alkyl polysaccharide has following structure:

R ²O (C _nH _2nO) _t(glycosyl) _x

R wherein ²Be selected from alkyl, alkyl phenyl, hydroxyalkyl, the hydroxyalkyl phenyl, and composition thereof, wherein alkyl comprises 10-18 carbon atom; N is 2 or 3; T is 0-10, and x is 1.3-8, and glycosyl preferably is derived from glucose.Cats product

Here, preferably in composition or component, contain cats product.Quaternary ammonium surfactant preferably.

The consumption of quaternary ammonium surfactant in detergent composition of the present invention is preferably the 0.1-20wt% of detergent composition, and more preferably 0.4-7wt% most preferably is the about 5.0wt% of 0.5-.The consumption of quaternary ammonium surfactant in component of the present invention or additive is preferably the 0.1-90wt% of detergent component or additive, and more preferably 0.5-50wt% most preferably is the about 30wt% of 2-.

Preferably, cats product is selected from cation mono alkoxylated amines tensio-active agent, positively charged ion bis-alkoxy amine tensio-active agent and composition thereof.Preferred cationic C ₁₂-C ₁₄The tensio-active agent of alkyl dimethyl alcohol salt class.The softener compound

Preferably, composition of the present invention or component contain one or more submissive compounds, preferably clay class such as POLARGEL NF.

The submissive compound of quaternary ammonium also is useful, and it contains one or two C ₁₂-C ₂₄The alkyl or alkenyl chain, randomly use one or more as-OH ,-O-, CONH, the functional group of-COO-replaces and uses two or three C ₁-C ₁₁, preferred C ₁-C ₆Or even C ₁-C ₄Alkyl or alkenyl replaces, described C ₁-C ₁₁, preferred C ₁-C ₆Or even C ₁-C ₄Alkyl or alkenyl is randomly used again as-OH ,-O-, and CONH, the functional group of-COO-or its mixture replaces.Preferably they are as disclosed pair of long-chain acid amides among the EP-B-0 242 919.Preferably, when containing two C ₁₂-C ₂₄During group, they contain two C ₁-C ₄Group is preferably methyl or ethyl.When softener contains three C ₁-C ₁₁During alkyl or alkenyl, they preferably contain a C ₁₈-C ₂₄Alkyl or alkenyl.Negatively charged ion is preferably chlorion or bromide anion.Other preferred cation softener is described in as among the US 5 540 850.The perhydrate SYNTHETIC OPTICAL WHITNER

A preferred other component is the perhydrate SYNTHETIC OPTICAL WHITNER in described component or the composition, as metal peroxyboric acid salt, and metal percarbonic acid salt, especially sodium salt class.Perborate can be the salt of single or four hydrations.The corresponding molecular formula of SPC-D is 2Na ₂CO ₃.3H ₂O ₂, its commercial goods is the crystalloid solid.

Peroxide Potassium peroxysulfate and sodium are the another kind of optional inorganic perhydrate salts that is used for detergent component of the present invention or composition.The organic peroxide acid bleach system

A preferred feature of described component or composition is to contain a kind of organic peroxide acid bleach system.In a preferred embodiment, bleach system comprises a kind of hydrogen peroxide cource and a kind of organic peroxide acid bleach precursor compound or a kind of ready-formed peroxy acid or its mixture.When having the ready-formed peroxy acid, preferred use only reduces the hydrogen peroxide cource of content or even omits any hydrogen peroxide cource.Organic peroxide acid is by preparing precursor and hydrogen peroxide cource situ reaction.Preferred hydrogen peroxide cource comprises inorganic hydrogen peroxide compound SYNTHETIC OPTICAL WHITNER, as the perborate bleach of claimed invention.In a selectivity preferred embodiment, the ready-formed organic peroxide acid is introduced directly in component or the composition.Also can consider to comprise the hydrogen peroxide cource that is used in combination with prefabricated organic peroxide acid and the component or the composition of organic peroxide acid precursor mixture.

Peroxyacid bleach precursor be those in peroxidation hydrogenation reaction can with hydroperoxidation to generate the compound of peroxy acid.General peroxyacid bleach precursor can be expressed as:

Wherein L is a leavings group, and X can be functional group arbitrarily in fact, it can so that the structure of the peroxy acid that in peroxidation hydrogenation, produces be:

The peroxyacid bleach precursor compound is preferably with the 0.5-20wt% of detergent composition, more preferably with the 1-15wt% of detergent composition, most preferably introduces with the amount of the 1.5-10wt% of detergent composition.

The peroxyacid bleach precursor compound that is fit to comprises one or more N-or O-acyl group usually, and this precursor can be selected in many types.The kind that is fit to comprises anhydrides, ester class, imines class, the acyl derivative of lactone and imidazoles and oximes.Useful examples of substances is disclosed among the GB-A-1586789 in these kinds, and the ester class that is fit to is disclosed in GB-A-836988,864798,1147871,2143231 and EP-A-0170386 in.

Preferred imines type alkyl peroxycarboxylic acid precursors compound comprises N, N, and N ', N '-four acylations Alkylenediamine, wherein alkylidene group comprises 1-6 carbon atom, and especially wherein alkylidene group comprises those compound of 1,2 and 6 carbon atom.Preferred especially tetra acetyl ethylene diamine (TAED).

Other preferred alkyl peroxycarboxylic acid precursors comprises 3,5,5-trimethyl acetyl base phenolsulfonic acid sodium (different-NOBS), nonanoyl phenolsulfonic acid sodium (NOBS), acetoxyl group benzene sulfonic acid sodium salt (ABS) and penta-acetyl glucose.

The alkyl peroxy acids precursor compound that acid amides replaces also is suitable for the present invention, comprises that those have the compound of following general formula:

R wherein ¹For containing the alkyl of 1-14 carbon atom, R ²For containing the alkylidene group of 1-14 carbon atom, R ⁵For hydrogen or contain the alkyl of 1-10 carbon atom, L can be in fact a leavings group arbitrarily.The bleach activating immunomodulator compounds that such acid amides replaces is seen and is set forth among the EP-A-0170386.

Detergent composition can be in addition or is alternatively comprised organic peroxyacid bleach precursor compound, the ready-formed organic peroxide acid, and generally its consumption is the 1-15wt% of composition, more preferably 1-10wt%.

The preferred kind of organic peroxy acid compound is the acid amides substitution compound with following general formula: R wherein ¹Be alkyl, aryl or the alkaryl that contains 1-14 carbon atom, R ²Be alkylidene group, arylidene and the alkyl arylene that contains 1-14 carbon atom, R ⁵For hydrogen or contain alkyl, aryl or the alkaryl of 1-10 carbon atom.The organic peroxy acid compound that such acid amides replaces is seen and is set forth among the EP-A-0170386.

Other organic peroxide acid comprises diacyl or four acyl peroxides, especially diperoxy dodecanedioic acid, diperoxy tetradecane diacid and diperoxy Thapsic acid.List and two is crossed nonane diacid, undecane dicarboxylic acid crossed by list and two and N-O-phthalic amido peroxidation caproic acid also is suitable for the present invention.The water soluble detergency promoter compound

Component of the present invention or composition preferred package contain water-soluble washing-aid compound, and generally its consumption in detergent composition 1-80wt% that is composition is preferably 10-60wt%, most preferably is 15-40wt%.

Detergent component of the present invention or composition preferably contain phosphatic builder material, and its preferred consumption is 0.5-60%, more preferably 5-50%, more preferably 8-40%.

Phosphatic builder material preferably contains tetrasodium pyrophosphate or even more preferably anhydrous sodium tripolyphosphate.

The water soluble detergency promoter compound that is fit to comprises water-soluble monomer polycarboxylate class or its sour form; All or copolymerization multi-carboxylic acid or its salt, wherein poly carboxylic acid contains the separate hydroxy-acid group that at least two spacings are no more than two carbon atoms; Borate family; And the mixture of above-mentioned any compound.Carboxylate salt or multi-carboxy acid salt washing agent can be haplotype or oligomeric-type, although since cost and use properties, general preferred monomers type polycarboxylate class.

The metal carboxylate that comprises a carboxyl that is fit to comprises the water soluble salt and the ether derivant thereof of lactic acid, oxyacetic acid.The poly carboxylic acid salt that comprises two carboxyls comprises water soluble salt and the ether carboxylate class and the sulfinyl metal carboxylate of Succinic Acid, propanedioic acid, (ethylidene dioxy) oxalic acid, toxilic acid, diglycollic acid, tartrate, tartronic acid and fumaric acid.The poly carboxylic acid salt or its acids that comprise three carboxyls comprise, especially water-soluble citrate class, with the equisetic acid salt, the carboxymethoxyl Succinic Acid salt of describing in citraconic acid salt and succinate derivative such as the English Patent 1379241, the newborn oxygen base succinate of describing in the English Patent 1389732, the amino-succinic acid salt of describing in Holland's application 7205873, and oxo multi-carboxylate's material such as the 2-oxa--1 described in the English Patent 1387447,1,3-tricarballylic acid salt.

The most preferred poly carboxylic acid that comprises three carboxyls is a citric acid.Preferred its consumption is the 0.1-15wt% of composition, more preferably 0.5-8wt%.

The poly carboxylic acid salt that comprises four carboxyls comprises disclosed oxygen two Succinic Acid salts in the English Patent 1261829,1,1,2,2-ethane tetracarboxylic acid salt, 1,1,3,3-propane tetracarboxylic acid salt and 1,1,2,3-propane tetracarboxylic acid salt.Comprise the substituent poly carboxylic acid salt of sulfo group comprise English Patent 1398421 and 1398422 and US patent 3 936 448 in the sulfonation pyrolysis citric acid salt described in the sulfosuccinate derivant described and the English Patent 1439000.Preferred poly carboxylic acid salt is that per molecule comprises nearly the hydroxycarboxylic acid salt of three carboxyls, more especially citric acid salt.

The example of the water-soluble phosphate washing assistant that is fit to is the tripolyphosphate alkaline metal salt, trisodium phosphate, potassium and ammonium, and sodium orthophosphate and potassium, partially poly-/sodium phosphate, its polymerization degree is about 6-21, and the salt of phytinic acid.Be partly dissolved or insoluble washing-aid compound

Component of the present invention and composition can comprise a kind of being partly dissolved or insoluble washing-aid compound, and generally speaking, its consumption in detergent composition is the 0.5-60wt% of composition, is preferably 5-50wt%, most preferably is 8-40wt%.

The example of water-fast substantially washing assistant comprises sodium silicoaluminate.

The structure cell that the Si-Al zeolite that is fit to has is Na _z[(AlO ₂) _z(SiO ₂) _y] .xH ₂O, wherein z and y are at least 6; The mol ratio of z and y is 1.0-0.5, and x is at least 5, is preferably 7.5-276, more preferably 10-264.The silico-aluminate material is hydrated form, is preferably crystalloid, comprises 10-28% at least under combining form, more preferably the water of 18-22%.

Si-Al zeolite can be natural product, but preferred synthetic material.Synthetic is crystalline silico-aluminate ion exchange material is with trade(brand)name zeolite A, zeolite B, and zeolite P, X zeolite, zeolite HS and composition thereof sells.Zeolite A has following formula:

Na ₁₂[(AlO ₂) ₁₂(SiO ₂) ₁₂].xH ₂O

Wherein x is 20-30, especially 27.The molecular formula of X zeolite is: Na ₈₆[(AlO ₂) ₈₆(SiO ₂) ₁₀₆] .276H ₂O.

Another kind of preferred Si-Al zeolite is a zeolite MAP builder.The consumption of zeolite MAP can be the 1-80wt% of composition, more preferably 15-40wt%.

Among the EP 384070A (Unilever) zeolite MAP is described.It is defined as the silicoaluminate an alkali metal salt of zeolite P type, and its silica alumina ratio is not more than 1.33, preferably in the 0.9-1.33 scope, more preferably in the 0.9-1.2 scope.

The silica alumina ratio that can cause the zeolite MAP of people's interest especially is not more than 1.15, more especially is not more than 1.07.

The size of particles of preferred zeolite MAP detergent builder compound is with d ₅₀Expression, its value is the 1.0-10.0 micron, more preferably the 2.0-7.0 micron most preferably is the 2.5-5.0 micron.

d ₅₀The diameter of the particle of value representation 50wt% is worth less than this.Size of particles can, especially can be by analytical technology commonly used as using scanning electronic microscope and carry out microscopic measurement or measuring by laser particle analyzer.Mensuration d is disclosed in EP 384070A ₅₀Other method of value.

Other preferred builder material comprises the crystalline layered silicate class, as sodium SKS-6, is sold by Clariant company.Heavy metal ion chelating agent

Component of the present invention or composition preferably comprise a kind of heavy metal ion chelating agent as optional components.In the present invention, heavy metal ion chelating agent has meant the component of chelating heavy metal ion effect.These components also can have the ability of chelating calcium and magnesium, but they show the selectivity in conjunction with heavy metal ion such as iron, manganese and cupric ion according to qualifications.

The consumption of heavy metal ion chelating agent is generally the 0.005-10wt% of composition or component, is preferably 0.1-5wt%, and more preferably 0.25-7.5wt% most preferably is 0.3-2wt%.

Be suitable for heavy metal ion chelating agent of the present invention and include the machine phosphonic acid salt, as amino alkylidenyl poly-(alkylene phosphonic acids salt), ethane-1-hydroxyl bisphosphate alkaline metal salt and nitrilo trimethylene phosphonic salt class.

Preferred diethylenetriamine five (methylene phosphonic acid salt) in the above all cpds, ethylene diamine three (methylene radical phosphoric acid salt), hexamethylene-diamine four (methylene phosphonic acid salt) and hydroxyl ethylidene-1, the 1-diphosphonate, 1,1 hydroxyethanediphosphonic acid and 1,1-hydroxyl ethane dimethylene phosphonic acids.

Other is applicable to that heavy metal ion chelating agent of the present invention comprises nitrilotriacetic acid(NTA) and polyamino carboxylic-acid, as the amino tetraacethyl of ethylene, ethylene diamine two Succinic Acid, ethylene diamine two pentanedioic acids, 2-hydroxyl propylene diamine two Succinic Acid or its be salt arbitrarily.

Other is applicable to that heavy metal ion chelating agent of the present invention is an iminodiacetic acid derivatives, 2-hydroxyethyl oxalic acid described in EP-A-317542 and EP-A-399133 or glyceryl iminodiethanoic acid.Iminodiethanoic acid described in EP-A-516102-N-hydroxypropyl sulfonic acid and aspartic acid-N-carboxymethyl-N-2-hydroxypropyl-3-sulfonic acid sequestrant also is applicable to the present invention.β-Beta Alanine described in EP-A-509382-N, N '-oxalic acid, aspartic acid-N, N '-oxalic acid, single acetate of aspartic acid-N-and imino-diacetic Succinic Acid sequestrant also are fit to.

EP-A-476257 has described the amino based sequestrant that is fit to.EP-A-510331 described be fit to be derived from collagen, Keratin sulfate or caseic sequestrant.EP-A-528859 has described a kind of suitable alkyl imino oxalic acid sequestrant.Dipicolinic acid and 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid also is fit to.G-NH2-N, N '-two Succinic Acid (GADS), quadrol-N, N '-two pentanedioic acid (EDDG) and 2-hydroxyl propylene diamine-N, N '-two Succinic Acid (HPDDS) also is fit to.

Preferred especially diethylenetriamine pentaacetic acid, quadrol-N, N '-two Succinic Acid (EDDS) and 1, the ammonium salt of 1-hydroxyl ethane di 2 ethylhexyl phosphonic acid or its basic metal, alkaline-earth metal, ammonium or replacement, or its mixture.Enzyme

Another preferred component useful in component of the present invention or composition is one or more additional enzymes.

Preferred additional enzyme material comprises the commercially available lipase that is introduced into usually in detergent component or the composition, at, and amylase, neutrality or Sumizyme MP, cellulase, enolase, esterase, polygalacturonase, lactose decomposes ferment enzyme and peroxidase.The enzyme that is fit to is given to discuss in US patent 3 519 570 and 3 533 139.

Preferred commercially available proteolytic enzyme comprise those by the Novo Industries A/S company of Denmark with trade(brand)name Alcalase, Savinase, Primase, the product that Durazym and Esperase sell, by Gist-Brocades company with trade(brand)name Maxatase, the product that Maxacal and Maxapem sell, by the product of Genencor International company sale, and by the product of Solvay Enzymes company with trade(brand)name Opticlean and Optimase sale.Proteolytic enzyme can be that the amount of the 0.0001-4wt% of composition is incorporated in the composition of the present invention with its organized enzyme.

Preferably amylase comprises, as comes from a kind of α-Dian Fenmei of special bacterial classification B lichens shape starch, and it is described in detail in GB-1269839 (Novo).Preferred commercially available amylase comprises the product of selling with trade(brand)name Rapidase as Gist-Brocade company, and Novo Industries A/S company is with trade(brand)name Termamyl, the product that Duramyl and BAN sell.Highly preferred amylase may be those that describe in PCT/US9703635 and WO95/26397 and WO96/23873.

Amylase can be that the amount of the 0.0001-2wt% of composition is incorporated in the composition of the present invention with its organized enzyme.

Lipolytic enzyme can be preferably 0.001-1wt% with its active lipolytic enzyme 0.0001-2wt% that is composition, and the amount that most preferably is 0.001-0.5wt% is incorporated in the composition of the present invention.

Lipase can be the original form of fungi or bacterium, as come from the Humicola sp. bacterial classification of producing lipase, Thermomyces sp. bacterial classification or comprise PseudomonasPseudoalcaligenes or the Pseudomonas sp. bacterial classification of Pseudomas fluorescens.These bacterial classifications also are useful through the lipase of chemical or genetically altered mutant in the present invention.Preferred lipase is the lipase that comes from Pseudomonas pseudoalcaligenes, and it is described in the European patent EP-B-0218272 that is authorized to.

The another kind of preferred lipase of the present invention obtains from the gene of Humicola lanuginosa by the clone and is Aspergillus oryza with this gene representation, as main body, described in European patent application EP-A-0258068, it can be the product of the Novo Industri A/S company of Denmark Bagsvaerd with trade(brand)name Lipolase sale.This lipase also is described in the US patent 4810414 that was authorized on March 7th, 1989 people such as Huge-Jensen.Other organic polymer

Preferably there is other organic polymer in the present invention except hydrophobic nature modified fibre quality, it preferably exists as the component of particle component arbitrarily, and wherein their effect is that this particle component is bonded together.In the present invention, organic polymer is meant in essence appoints any polymeric organic compound that is used as dispersion agent, anti-redeposition agent and soil-suspending agent usually in detergent component or composition, comprises quaternised ethoxylation (many) amine clay-soil removal/anti redeposition agent among the present invention.

Organic polymer with the 0.01-30wt% of composition, is preferably 0.1-15wt% usually, and the amount that most preferably is 0.5-10wt% is incorporated in the detergent composition of the present invention.

The example of organic polymer comprises water-soluble all organic or copolymerization multi-carboxylic acid or its esters, and wherein poly carboxylic acid contains at least two by being no more than two carbon atoms with the carboxyl that is separated from each other.The polymkeric substance that the back is one type discloses in GB-A-1596756.The example of described salt be MWt be 1000-5000 polyacrylate with and with the multipolymer of maleic anhydride, the molecular weight of this multipolymer is 2000-100000, especially 40000-80000.

Useful in the present invention polyamino compound comprises those compounds that are derived from aspartic acid, as at EP-A-305282, and those disclosed compound among EP-A-305283 and the EP-A-351629.

Contain and be selected from toxilic acid, vinylformic acid, the trimer of the monomeric unit of poly aspartic acid and vinyl alcohol, especially molecular-weight average are that those trimers of 5000-10000 also are applicable to the present invention.

Other other organic polymer that preferably is suitable for being incorporated in detergent component of the present invention or the composition comprises other non-hydrophobic nature modified-cellulose derivative, as methylcellulose gum, and carboxymethyl cellulose, Vltra tears and Natvosol.

More useful organic polymer is that polyoxyethylene glycol, especially molecular weight are 1000-10000, more preferably 2000-8000, most preferably from about 4000 polyoxyethylene glycol.

The highly preferred polymeric constituent of the present invention is people's such as people's such as Scheibel US patent 4968451 and Gosselink a US patent 5415807, particularly cotton and the non-cotton soil release polymers described in the US application 60/051517.Press down foam system

When being used to machine-wash composition by allotment, detergent composition of the present invention can contain a kind of foam system that presses down, and consumption is the 0.01-15wt% of composition, is preferably 0.02-10wt%, most preferably is 0.05-3wt%.

Being used for the suitable foam that presses down of the present invention is to contain known arbitrarily defoaming compounds in fact, comprises as siloxanes defoaming compounds and 2-alkyl alcohol defoaming compounds.The polymeric dye transfer inhibitor

Composition of the present invention also can preferably contain 0.01-10wt%, be preferably the polymeric dye transfer inhibitor of 0.05-0.5wt%, be preferably selected from polyamines N-oxide polymer, the multipolymer of N-vinyl pyrrolidone and N-vinyl imidazole, polyvinylpyrrolidonepolymers polymers or its combination, wherein these polymkeric substance can be crosslinked polymkeric substance.Optical brightener

The also optional wetting ability optical brightener that comprises some type of about 0.005-5wt% of composition of the present invention.Other optional member

Other optional member that is suitable for being included in component of the present invention or the composition comprises spices, and pigment and filler salt, sodium sulfate salt are preferred filling salts.

Highly preferred composition comprises the organic acid of about 2-10wt%, is preferably citric acid.Also preferably there is a spot of (as being lower than about 20wt%) neutralizing agent with carbonate, buffer reagent, phase modifier helps water solvent, enzyme stabilizers, the polyacid class, foaming regulator, opalizer, antioxidant, those (being hereby incorporated by) described in sterilant and the dyestuff, the US patent 4285841 that is authorized on August 25th, 1981 as people such as Barrat.The shape of component or composition

Component of the present invention or composition can present and comprise liquid and solid-state various physical forms, and laminar as sheet, bulk and strip are preferably particulate state.Described component or composition can be by the whole bag of tricks manufacturings, and this depends on the shape of product of the whole bag of tricks.Solids composition or component can be undertaken as dry mixed by all cpds or the mixture in these methods that will be included in the detergent component, and cohesion compresses or spray-dired method is made.

The tap density of detergent composition of the present invention and component be preferably 300g/L or even 350g/L or 450g/L to being preferably 1500g/L or 1000g/L or even 850g/L.Fabric cleaning process

The present invention also provides a kind of washing methods.This method be with these fabrics with by the above-mentioned detergent component of significant quantity or composition is made or the water-based washing soln made by the independent component of these components or composition contacts.Be used for the moisture non-stirring soak solution that fabric cleans and handles although component of the present invention or composition also can be used to form, generally speaking, fabric is to carry out under stirring condition with contacting of washing soln.As discussed above, it is about 11.0 that the pH value of preferred washing soln is lower than, and preferably its pH value is lower than 10.5, and most preferably its pH value is lower than 9.5.

The significant quantity of the high density liquid of aqueous cleaning solution or detergent granules component or composition is preferably about 500-10000ppm or even 7000ppm, more preferably from about 1000-3000ppm in the washing machine.

Detergent component of the present invention or composition also can be used for handling and conditioning fabric and textiles.Therefore, for example in order to obtain aforementioned desirable appearance of fabrics and integrity effect, the fabric-conditioning component or the composition that contain hydrophobic nature modified fibre quality of the present invention can add in the rinse cycle process of common household laundry operation.Then, preferably at least about 1wt%, preferred about 10wt%, 20-80wt% more preferably from about, more preferably composition or the component to about 60wt% is one or more fabric softening active substances, as cationic charged hydro carbons, the quaternary ammonium salt and/or the clay class that replace of C12-C22 dialkyl group for example optionally comprises a kind of flocculating polymer.

Alternatively, composition of the present invention or component may reside in the submissive and cleaning combination, or exist with submissive and form cleaning combination, described in EP-B1-313146 and WO93/01267, it preferably contains other submissive composition, as clay and optional a kind of flocculating polymer.

With the abbreviation among the dry detergent composition embodiment

LAS: straight chain C 11-13 sodium alkyl benzene sulfonate

TAS: tallow alkyl sodium sulfate

CxyAS: C1x-C1y sodium alkyl sulfate

CxyEzS: the contracting of C1x-C1y sodium alkyl sulfate and z moles of ethylene oxide

Close product

The primary alconol that is mainly straight chain of CxyEz: C1x-C1y and average z mole

The condensation product of oxyethane

QAS: R2N+ (CH3) 2 (C2H4OH), wherein R2=C12-C14

Alkyl

QASA: R2R3N+ (CH3) 2, wherein R2 and R3 are independently

The alkyl of C12-C14

Soap: be derived from 80/20 butter and coconut oil fat acid mixture

Straight-chain alkyl carboxylic acid's sodium

STS: toluenesulfonic acid sodium salt

CFAA: C12-C14 (cocounut oil) alkyl N-methyl glucose amide

TFAA: C16-C18 alkyl N-methyl glucose amide

TPKFA: the fatty acid of the full cut of topping

STPP: anhydrous sodium tripolyphosphate

TSPP: tetrasodium pyrophosphate zeolite A: hydrated sodium aluminosilicate, molecular formula is

Na12 (AlO2SiO2) 1227H2O, main size of particles is

0.1-10 micron (is the weight of basic representation with the anhydride) NaSKS-6: crystalline layered silicate, molecular formula is the d-Na2Si2O5 oxysuccinic acid: anhydrous oxysuccinic acid toxilic acid: Maleic Acid, Anhydrous tartrate: anhydrous tartrate carbonate: anhydrous sodium carbonate supercarbonate: anhydrous sodium bicarbonate silicate: amorphous silicic sodium (SiO2: Na2O=2.0: 1) vitriol: anhydrous sodium sulphate sal epsom: anhydrous magnesium sulfate Citrate trianion: citrate trisodium dihydrate, activity is 86.4%, and particle is big

For a short time be distributed as 425 μ m-850 μ m.MA/AA: 1: 4 toxilic acid/acrylic copolymer, molecular-weight average is for about

70000MA/AA (1): 4: 6 toxilic acid/acrylic copolymer, molecular-weight average is for about

10000AA: polyacrylic acid sodium polymer, molecular-weight average are the enforcement of 4500CABP: PCT/US98/19143 and PCT/US98/19141

Cyclic amine based polymer HMC I described in example 1 and 2 tables: the hydrophobic nature that contains one or more polymkeric substance numberings A-F changes

The property cellulosic materials is described in the 6-7 page table, wherein

The size of particles of 80wt% is 10-450 micron HMC II: the hydrophobic nature that comprises one or more polymkeric substance numberings A-F changes

The property cellulosic materials is described in the 6-7 page table, wherein

The size of particles of 80wt% is 350-850 micron AC: the hydrophobic nature modification with the amide group that contains 2-12 carbon atom

The plain CMC of nylon: the plain ether of sodium carboxyme-thylcellulose fibre: methyl cellulose ether, its polymerization degree are 650, by Shin Etsu

Chemicals company sells PB4: comprise the Sodium peroxoborate that the nominal molecular formula is NaBO23H2O

The particle PB1 of tetrahydrate: comprising the nominal molecular formula is the anhydrous boron of crossing of NaBO2H2O2

The particle percarbonate of acid sodium SYNTHETIC OPTICAL WHITNER: comprise the percarbonic acid that the nominal molecular formula is 2Na2CO33H2O2

The particle NOBS of sodium: contain the particle of the sodium-salt form of nonanoyl phenolsulfonic acid, particle

Weight average size of particles be 750 microns-900 microns NAC-OBS: the grain that contains (6-nonanoyl amido caproyl) hydroxy benzene sulfonate

Son, the weight average size of particles of particle be 825 microns-875 little

Rice TAED: acetylethylenediamine DTPA: diethylenetriamine pentaacetic acid DTPMP: Diethylenetriamine five (methene phosphonate ester), by Monsanto

Company sells with trade(brand)name Dequest 2060.Brightener: 4,4 '-two (2-sulfo group styryl) phenylbenzene disodiums or

4,4 '-two [(4-anilinos-6-morpholino-1,3,5-triazines

-2-yl) amino]-stilbene base-2,2 '-disulfonic acid

Disodium EDDS: quadrol-N, N '-two Succinic Acid exists with its sodium-salt form

(S, S) isomer HEDP: 1,1-hydroxyl ethane di 2 ethylhexyl phosphonic acid PEGx: polyoxyethylene glycol, molecular weight is x (typically being 4000) PEO: polyethylene oxide, molecular-weight average is 50000PVI: polyvinyl imidazol, molecular-weight average is 20000PVP: polyvinylpyrrolidonepolymers polymers, molecular-weight average is

60000PVNO: polyvinylpyridine N-oxide polymer, molecular-weight average

Be 50000PVPVI: the multipolymer of polyvinylpyrrolidone and vinyl imidazole is flat

Average molecular weight is 20000QEA: two ((C2H5O) be n (C2H4O)) (CH3)-N+-C6H12-N+-

(CH3) two ((C2H5O) be n (C2H4O)), wherein n=20-30SRP: negatively charged ion end capped polyesters class PEI: polyethylene imine based, molecular-weight average is 1800, average second

Oxygen base degree is 7 oxyethyl group silicone antifoam agents of each nitrogen-atoms: polydimethylsiloxane Foam Control and as dispersion agent

Siloxanes-oxyalkylene copolymers, described Foam Control and institute

The ratio of stating dispersion agent is 10: 1-100: 1

All consumptions are the weight percentage of composition in the following examples.

Contain the embodiment of the prefabricated particle G-J of HMC I arbitrarily

Particle: HMC I CABP zeolite water LAS or AS AE3, AE5 or AE7 PVNO or PVP AA or MA/AA brightener sodium carbonate CMC/PEG amount to

????G ??14.0 ??6.0 ??- ??10.0 ??40.0 ??- ??- ??27.0 ??- ??- ??3.0 ??100.0

?????H ????3.0 ????- ????33.0 ????- ????20.0 ????- ????- ????20.0 ????- ????24.0 ????- ????100.0

?????I ????5.0 ????- ????25 ????6.0 ????- ????- ????34 ????- ????25.0 ????5.0 ????100.0

????J ??10.0 ??- ??30.0 ??10.0 ??20.0 ??- ??- ??- ??5.0 ??15.0 ??- ??100.0

Composition below the Table III is corresponding to composition of the present invention.

	N	O	P	Q	R	S	?T	?U	?V
										Spray dried particle
LAS	10.0	10.0	15.0	5.0	5.0	10.0	?-	?-	?-
										MBAS	-	-		5.0	5.0		?-	?-	?-
C 45AS	-	-	1.0		2.0	2.0	?-	?-	?-
										C 45AE 3S	-	-		1.0			?-	?-	?-
QAS	1.0	1.5	1.0	1.0	0.5	0.8	?-	?-	?-
										HMC?I	0.3	0.8	1.5	1.0	0.9	1.3	?-	?-	?-
MgSO4	0.5	0.5	0.1	-			?-	?-	?-
										Trisodium Citrate	-	-	-	3.0	5.0		?-	?-	?-
Yellow soda ash	10.0	7.0	15.0			10.0	?-	?-	?-
										Sodium sulfate	5.0	5.0	-	-	5.0	3.0	?-	?-	?-
Water glass, 1.6R	-	-	-	-	2.0		?-	?-	?-
										Zeolite A	16.0	18.0	20.0	20.0	-	-	?-	?-	?-
SKS-6	?-	-	-	3.0	5.0	-	?-	?-	?-
										MA/AA or AA	?1.0	2.0	11.0	-	-	2.0	?-	?-	?-

PEG?4000	-	2.0	-	1.0	-	1.0	-	-	-
										QEA	1.0	-	-	-	1.0	-	-	-	-
Brightener	0.05	0.05	0.05	-	0.05	-	-	-	-
										Silicone oil	0.01	0.01	0.01	-	-	0.01	-	-	-
Condensation product
										LAS	-	-	-	-	-	-	2.0	2.0	-
MBAS	-	-	-	-	-	-	-	-	1.0
										C 45AS	-	-	-	-	-	-	2.0	-	-
AE 3	-	-	-	-	-	-	-	1.0	0.5
										Carbonate	-	-	-	-	-	-	1.0	1.0	-
Trisodium Citrate	-	-	-	-	-	-	-	-	5.0
										CFAA	-	-	-	-	-	-	-	-	-
Citric acid	-	-	-	-	-	-	-	1.0	1.0
										QEA	-	-	-	-	-	-	2.0	-	-
SRP	-	-	-	-	-	-	1.0	0.2	-
										Zeolite A	-	-	-	-	-	-	26.0	15.0	16.0
Water glass			-	-	-	-	-	-	-
										PEG	-	-	-	-	-	-	4.0	-	-
HMC?I	-	-	-	-	-	-	5.0	-	-
										The washing assistant condensation product
SKS-6	-	-	-	-	-	3.0	-	7.0	10.0
										LAS	-	-	-	-	-	3.0	-	10.0	12.0
										The particle component that dry method is added
Particle G-J arbitrarily	-	-	?-	-	10.0	5.0	-	2.0	4.0
										NACAOBS	3.0	-	-	?4.5	-	-	-	2.5	-
NOBS	1.0	3.0	3.0	-	-	-	-	-	5.0
										TAED	2.5	-	-	1.5	2.5	6.5	-	1.5	-
Citrate trianion/citric acid	-	-	-	4.0	-	5.0	-	-	5.0

Percarbonate	15.0	3.0	6.0	10.0	-	-	24.0	18.0	5.0
										Perborate	-	-	-	-	6.0	18.0	-	-	-
Optical white	0.02	0.02	0.02	0.1	0.05	-	0.3	-	0.03
										Enzyme (cellulase, amylase, proteolytic enzyme, lipase)	1.3	0.3	0.5	0.5	0.8	2.0	0.5	0.16	0.2
Carbonate	0.0	10.0	-	-	-	5.0	8.0	10.0	5.0
										Spices (sealing)	-	0.5	0.5	-	0.3	-	0.2	-	-
Suds suppressor	1.0	0.6	0.3	-	0.10	0.5	1.0	0.3	1.2
										Soap	0.5	0.2	0.3	3.0	0.5	-	-	0.3	-
HMC?II	1.0	0.5	-	-	-	-	-	-	-
										Painted carbonate (blueness, green)	0.5	0.5	1.0	2.0	-	0.5	0.5	0.5	1.0
Spray method
										Brightener	0.2	0.2	0.3	0.1	0.2	0.1	-	0.6	0.3
Dyestuff	-	-	-	0.3	0.05	0.1	-	-	-
										AE7	-	-	-	-	-	0.5	-	0.7	-
Spices	1.0	?0.5	1.1	0.8	0.3	0.5	0.3	0.5	-
										Filler adds up to 100%

Composition below the Table IV is corresponding to composition of the present invention

	W	X	Y	Z	AA	BB	CC	DD	EE
										Spray dried particle
LAS	10.0	10.0	?16.0	5.0	5.0	10.0	-	?-	-
										TAS	-	1.0	-				-	?-	-
MBAS	-	-	-	5.0	5.0		-	?-	-
										C 45AS	-	-	1.0		2.0	2.0	-	?-	-
C 45AE 3S	-	-	-	1.0			-	?-	-

QAS	1.0	0.8	1.0	1.0	?2.0	?4.0	-	-	-
										DTPA, HEDP and/or EDDS	0.3	0.3	0.3	0.3	-	-	-	-	-
MgSO4	0.5	0.4	0.1	-			?-	-	-
										Trisodium Citrate	10.0	12.0	-	3.0	-		-	-	-
Yellow soda ash	15.0	8.0	15.0			10.0	-	-	-
										Sodium sulfate	5.0	5.0	-	-	5.0	3.0	-	-	-
Water glass, 1.6R	-	-	-	-	2.0		-	-	-
										Zeolite A	-	-	-	2.0	-	-	-	-	-
SKS-6	-	-	-	3.0	5.0	-	-	-	-
										MA/AA or AA	1.0	2.0	10.0	-	-	2.0	-	-	-
PEG?4000	-	2.0	-	1.0	-	1.0	-	-	-
										QEA	1.0	-	-	-	1.0	-	-	-	-
Brightener	0.05	0.05	0.05	-	0.05	-	-	-	-
										Silicone oil	0.01	0.01	0.01	-	-	0.01	-	-	-
HMC?I	0.5	1.2	2.0	-	-	-	-	-	-
										Condensation product
LAS	-	-	-	-	-	-	2.0	2.0	-
										MBAS	-	-	-	-	-	-	-	-	1.0
C 45AS	-	-	-	-	-	-	2.0	-	-
										CABP	-	-	-	-	-	1.0	0.2	-	0.5
Carbonate	-	-	-	-	-	1.0	1.0	1.0	-
										Trisodium Citrate	-	-	-	-	-	-	-	-	5.0
CFAA	-	-	-	-	-	-	-	-	-
										Citric acid	-	-	-	-	-	4.0	-	1.0	1.0
QEA	-	-	-	-	-	2.0	2.0	1.0	-
										SRP	-	-	-	-	-	1.0	1.0	0.2	-
Zeolite A	-	-	-	-	-	15.0	26.0	15.0	16.0
										Water glass	-	-	-	-	-	-	-	-	-
PEG	-	-	-	-	-	-	4.0	-	-

HMC?I							3.0
										The particle component that dry method is added
Particle G-J arbitrarily	-	-	4.0	-	6.0	5.0	-	-	-
										NACAOBS	3.0	-	-	1.5	-	-	-	5.5	-
NOBS/LOBS/DOBS	-	3.0	3.0	-	-	-	-	-	5.0
										TAED	2.5	-	-	1.5	2.5	6.5	-	1.5	-
HMC?II	-	-	-	0.7	-	-	1.0	3.5	0.5
										QEA	-	-	-	0.2	0.5	-	-	-	-
Percarbonate	15.0	3.0	6.0	10.0	-	-	12.0	18.0	5.0
										Perborate	-	-	-	-	6.0	18.0	-	-	-
Optical white	0.02	0.02	0.02	0.1	0.05	-	0.3	-	0.03
										Enzyme (cellulase, amylase, proteolytic enzyme, lipase)	1.5	0.3	0.5	0.5	0.8	2.0	0.5	0.16	0.2
Carbonate	-	-	-	-	-	5.0	8.0	10.0	5.0
										Spices (sealing)	0.6	0.5	0.5	-	0.3	0.5	0.2	0.1	0.6
Suds suppressor	1.0	0.6	0.3	-	0.10	0.5	1.0	0.3	1.2
										Soap	0.5	0.2	0.3	3.0	0.5	-	-	0.3	-
Citric acid	-	-	-	-	-	-	-	5.0	5.0
										Painted carbonate (blueness, green)	0.5	0.5	？	2.0	-	0.5	0.5	0.5	1.0
Spray method
										Brightener	0.2	0.2	0.3	0.1	0.2	0.1	-	0.6	-
Dyestuff	-	-	-	0.3	0.05	0.1	-	-	-
										AE7	-	-	-	-	-	0.5	-	0.7	-
Spices	-	-	-	0.8	-	0.5	?0.8	0.5	?1.0
										Filler adds up to 100%

Below the Table V high-density of the present invention and the detergent formulation that contains SYNTHETIC OPTICAL WHITNER

	????FF	????GG	????HH
				Condensation product
STPP/ zeolite A	????10.0	????25.0	????15.0
				??????????????????QAS	????-	????2.5	????-
??????????????????LAS	????3.0	????-	????3.0
				????????????????C45AS	????3.0	????2.0	????4.0
??????????????????QAS	????-	????-	????1.5
				????????????????DTPMP	????0.4	????0.4	????0.4
??????????????????CMC	????0.4	????0.4	????0.4
				????????????????MA/AA	????4.0	????2.0	????2.0
??????????????????HMC	????2.0	????-	????1.5
				?????????????????CABP	????0.8	????1.0	????0.5
Condensation product
				NaSKS-6 (I) or (II)	????15.0	????-	????-
??????????????????LAS	????8.0	????-	????-
				???????????????????AS	????5.0	????-	????-
Spray method
				Spices	????0.3	????0.3	????0.3
????????????????C25E3	????2.0	????-	????2.0
				Brightener	????0.1	????0.4
Optical white	????0.03	????0.05	????-
				The dry method additive
??????????????????QEA	????1.0	????2.0	????-
				Citric acid	????5.0	????-	????2.0
Particle G-J arbitrarily	????-	????7.0
				Carbonate	????8.0	????15.0	????10.0

??????????????????????????NACOBS	?????6.0	????-	????5.0
				??????????????????????????HMC?II	?????-	????-	????2.0
????????????????????????????TAED	?????	????3.0	????-
				????????????????????????????NOBS	?????-	????2.0	????-
Percarbonate	?????-	????7.0	????10.0
				Polyethylene oxide, molecular weight are 5000000	?????-	????-	????0.2
POLARGEL NF	?????-	????-	????10.0
				Proteolytic enzyme	?????1.0	????1.0	????1.0
Lipase	?????0.4	????0.4	????0.4
				Amylase	?????0.6	????0.6	????0.6
Cellulase	?????0.6	????0.6	????0.6
				Silicone antifoam agent	?????5.0	????5.0	????5.0
?????????????????????????????CMC	?????1.0	????0.5	????1.0
				Surplus (moisture and other)	?????100.0	????100.0	????100.0
Density (g/L)	?????850	????850	????850

Be corresponding to liquid composition of the present invention below the Table VI

Component I I JJ KK LL
	C 12-15Alkyl oxide (2.5) vitriol 38 38 38 38
C 12Glucamide 6.86 6.86 6.86 6.86
	Citric acid 4.75 4.75 4.75 4.75
C 12-14Lipid acid 2.00 2.00 2.00 2.00
	Enzyme 1.02 1.02 1.02 1.02
MEA?????????????????????????1.0???1.0???1.0???1.0

Propylene glycol 0.36 0.36 0.36 0.36
	Borax 6.58 6.58 6.58 6.58
Dispersion agent 1.48 1.48 1.48 1.48
	Toluenesulfonic acid sodium salt 6.25 6.25 6.25 6.25
??QAS?????????????????????1.0??????1.0??????-????????1.0
	??QEA?????????????????????2.0??????2.0??????2.0??????-
??CABP????????????????????-????????-????????1.0??????0.5
	HMC I or II 5.0-0.5 5.0-0.5 5.0-0.5 5.0-0.5
CMC or AC 1.0 1.0 2.0-
	Equal amount equal amount equal amount equal amount dyestuff, spices, brightener, sanitas, suds suppressor, other accessory constituent, water
??????????????????????????100％????100％????100％????100％

Liquid detergent formula below Table VII is produced according to the present invention

	???MM	????NN	????OO	????PP	?????QQ
						?LAS	???11.5	????9.0	????-	????4.0	?????-
?C25E2.5S	???-	????3.0	????18.0	????-	?????16.0
						?C45E2.25S	???11.5	????3.0	????-	????16.0	?????-
?C23E9	???-	????3.0	????2.0	????2.0	?????1.0
						?C23E7	???3.2	????-	????-	????-	?????-
?CFAA	???-	????-	????5.0	????-	?????3.0
						?TPKFA	???2.0	????-	????2.0	????0.5	?????2.0
Citric acid (50%)	???6.5	????1.0	????2.5	????4.0	?????2.5
						Calcium formiate	???0.1	????0.06	????0.1	????-	?????-
Sodium formiate	???0.5	????0.06	????0.1	????0.05	?????0.05
						?STS	???4.0	????1.0	????3.0	????1.2	?????-
Borate	???0.6	????-	????3.0	????2.0	?????3.0
						Sodium hydroxide	???6.0	????2.0	????3.5	????4.0	?????3.0
Ethanol	???2.0	????1.0	????4.0	????4.0	?????3.0
						1, the 2-propylene glycol	???3.0	????2.0	????8.0	????8.0	?????5.0
Monoethanolamine	???3.0	????1.5	????1.0	????2.5	?????1.0
						HMC I or II	???5.0-0.5	????5.0-0.5	????5.0-0.5	????5.0-0.5	?????5.0-0.5
?CABP	???0.5	????0.5	????-	????-	?????-
						Proteolytic enzyme	???0.03	????0.01	????0.03	????0.02	?????0.02
Lipase	???-	????-	????0.002	????-	?????-
						Amylase	???-	????-	????-	????0.002	?????-
Cellulase	???-	????-	????0.0002	????0.0005	?????0.0001
						?CMC	???0.2	????-	????0.5	????-	?????1.0
?DTPA	???-	????-	????0.3	????-	?????-
						?PVNO	???-	????-	????0.3	????-	?????0.2
Silicone antifoam agent	???0.04	????0.02	????0.1	????0.1	?????0.1

Claims (9)

1. detergent composition or component, it contains the hydrophobic modified cellulosic materials of a kind of granulous, 80wt% at least wherein, the preferred size of particles of 90wt% at least is lower than 1000 microns.

2. the detergent composition of claim 1 or component, wherein at least 80wt% or even the size of particles of the hydrophobic modified cellulosic materials of 100wt% be lower than 850 microns or even be lower than 710 microns.

3. claim 1 or 2 detergent composition or component, wherein hydrophobic nature modified fibre quality contains the polymkeric substance as shown in the formula expression:

Wherein R is selected from R ₂, R _cWith Wherein:

-each R ₂Be independently selected from H and C ₁-C ₄Alkyl;

-each R _cFor :-(CH ₂) y-CO-OZ,

Wherein each Z is independently selected from M, R ₂, R _cAnd R _H

-each R _HBe independently selected from C ₅-C ₂₀Alkyl, C ₅-C ₇Cycloalkyl, C ₇-C ₂₀Alkaryl, C ₇-C ₂₀Aralkyl, substituted alkyl, hydroxyalkyl, C ₁-C ₂₀Alkoxyl group-2-hydroxyalkyl, C ₇-C ₂₀Alkyl-aryloxy-2-hydroxyalkyl, (R ₄) ₂The N-alkyl, (R ₄) ₂The N-2-hydroxyalkyl, (R ₄) ₃The N-alkyl, (R ₄) ₃The N-2-hydroxyalkyl, C ₆-C ₁₂Aryloxy-2-hydroxyalkyl,

-each R ₄Be independently selected from H, C ₁-C ₂₀Alkyl, C ₅-C ₇Cycloalkyl, C ₇-C ₂₀Alkaryl, C ₇-C ₂₀Aralkyl, aminoalkyl, alkyl aminoalkyl, dialkyl amino alkyl, piperidines substituted alkyl, morpholino alkyl, cycloalkyl aminoalkyl and hydroxyalkyl.

-each R ₅Be independently selected from H, C ₁-C ₂₀Alkyl, C ₅-C ₇Cycloalkyl, C ₇-C ₂₀Alkaryl, C ₇-C ₂₀Aralkyl, substituted alkyl, hydroxyalkyl, (R ₄) ₂N-alkyl and (R ₄) ₃The N-alkyl;

Wherein:

M is the positively charged ion that is fit to, preferably from Na, and K, 1/2Ca and 1/2Mg;

Each x is 0-about 5;

Each y is about 1-5; And

Condition is:

-R _HSubstitution value be about 0.001-0.1, more preferably about 0.005-0.05 most preferably is about 0.01-0.05.

R when-Z is H or M _cSubstitution value be about 0.2-2.0, more preferably about 0.3-1.0 most preferably is about 0.4-0.7.

If-any one R _HHave positive charge, it comes balance by a suitable negatively charged ion; And

Two R the on-same nitrogen-atoms ₄Can together form a ring texture, this ring texture can be piperidines or morpholine.

4. the composition of claim 3 or component, wherein each R _HBe independently selected from C ₅-C ₂₀Alkyl, C ₅-C ₇Cycloalkyl, C ₇-C ₂₀Alkaryl, C ₇-C ₂₀Aralkyl, substituted alkyl, hydroxyalkyl, C ₁-C ₂₀Alkoxyl group-2-hydroxyalkyl, C ₇-C ₂₀Alkyl-aryloxy-2-hydroxyalkyl, (R ₄) ₂The N-alkyl, (R ₄) ₂The N-2-hydroxyalkyl, (R ₄) ₃The N-alkyl, (R ₄) ₃N-2-hydroxyalkyl and C ₆-C ₁₂Aryloxy-2-hydroxyalkyl.

5. the composition of claim 3 or component, wherein each R _HBe independently selected from:

6. the detergent component of aforementioned arbitrary claim or composition, wherein hydrophobic nature modified fibre quality exists with the form of the prefabricated particle that contains a kind of solid support material and/or a kind of tensio-active agent, and the size of particles of preferred at least 80% material is lower than 500 microns thus.

7. the detergent component of claim 6 or composition, wherein prefabricated particle is a kind of condensation product, it contains one or more and is selected from inorganic salt, the solid support material of silicate or silico-aluminate and a kind of negatively charged ion and/or nonionogenic tenside.

8. the detergent component of claim 6 or composition, wherein prefabricated particle is the powder particle that spraying drying blows out, it contains one or more and is selected from inorganic salt, the solid support material of silicate or silico-aluminate and a kind of negatively charged ion and/or nonionogenic tenside.

9. each detergent component or composition of claim 1-5, wherein hydrophobic nature modified fibre quality is dry form of adding particle.