CN1320029A - 洁齿乳膏 - Google Patents

洁齿乳膏 Download PDF

Info

Publication number
CN1320029A
CN1320029A CN99811561A CN99811561A CN1320029A CN 1320029 A CN1320029 A CN 1320029A CN 99811561 A CN99811561 A CN 99811561A CN 99811561 A CN99811561 A CN 99811561A CN 1320029 A CN1320029 A CN 1320029A
Authority
CN
China
Prior art keywords
weight
tooth cleaning
cleaning agents
liquid tooth
contain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN99811561A
Other languages
English (en)
Inventor
汉斯－西奥·莱内恩
多萝西娅·格雷戈里
玛丽亚·罗莎·卡尔博
米拉科·普霍尔·加利亚诺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of CN1320029A publication Critical patent/CN1320029A/zh
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/03—Liquid compositions with two or more distinct layers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
  • Dental Preparations (AREA)
  • Pens And Brushes (AREA)
  • Cleaning In General (AREA)

Abstract

本发明涉及一种透明的洁齿乳膏。它含有10－15重量%硅酸抛光剂、55－70重量%保湿剂、15－30重量%水和2－10重量%其它牙膏成分。所述洁齿乳膏的粘度在10000－100000 mPas(20℃)范围内。如果由山梨醇(a)、甘油(b)和聚乙二醇(c)按重量比(a)∶(b)∶(c)=10∶(7－8)∶(0.5－1.5)组成的混合物作为保湿剂,它可以容易地从给料软管中流出。优选水和保湿剂的重量比为1∶(2－3)。

Description

洁齿乳膏
本发明涉及一种含有一定量的抛光剂、保湿剂和水的洁齿乳膏。它呈充分透明至清澈状并具有良好的流变性能，能应用塑料软管给出准确的剂量。
现有技术已知多种洁齿乳膏，如专利WO94/01080 A1公开的洁齿乳膏，它能在很轻的按压下，容易地从塑料软管中流出。这些产品的外观为白色至暗灰色。为了使这些产品变成透明或清澈，要求水、保湿剂和必要时具有一定溶解度的与抛光剂具有相似的折射率的液体载体。专利WO95/22958公开了一种透明的洁齿乳膏，它含有大于50重量％的山梨醇。但是这种洁齿乳膏不能在低温下保持满意的透明度。专利WO94/01081 A1也公开了一种透明洁齿剂，它含有约21重量％山梨醇、30％重量％甘油和5重量％乙醇。这些洁齿乳膏粘性均很低，其粘度明显地小于10000mPas(25℃)。
本发明的目的是提供一种洁齿乳膏，它既使在低温下也能保持透明，并具有一定粘性，在挤压到牙刷上时，乳膏不会从软管中流出太快，乳膏也不会太深地下沉到鬃毛的间隙中。
因此本发明的解决方案是应用一种特效的混合保湿剂。本发明的对象是一种含有10-15重量％硅酸抛光剂、55-70重量％保湿剂(a+b+c)、15-30重量％水和2-10重量％其它牙膏成分的透明洁齿乳膏，其特征在于，含有由山梨醇(a)、甘油(b)和聚乙二醇(c)按重量比(a)∶(b)∶(c)=10∶(7-8)∶(0.5-1.5)组成的混合物作为保湿剂。
本发明的洁齿乳膏具有液体性质，它的粘度在10000-100000mPas范围内(20℃时采用型号为RVF的Brookfield的旋转粘度计，在4RPM时，转轴3/4，相应地剪切率D=4/秒)。本发明的洁齿乳膏既能容易地从塑料给料软管中流出，又缓慢地下沉到牙刷的鬃毛间隙中。
本发明的洁齿乳膏的透明性至少必须达到下述程度，透过约1cm厚的洁齿乳膏层(如放在边长1×1×4cm的透明玻璃板上)还能很好地看清约4mm高、3mm宽的字母体。
所有已知可作为抛光剂的凝胶硅酸、水凝硅酸和沉淀硅酸均适合作为硅酸-抛光组分。通过用无机强酸转化硅酸钠生成水溶胶，经过陈化生成水凝胶，再经清洗和干燥生成凝胶硅酸。如专利US 4 153 680所公开的，在保护性条件下干燥将水含量降到15至35重量％，得到所谓的水凝硅酸。又如专利US 3 538 230所公开的，通过干燥将水分降到15重量％以下，使原先的水凝胶的疏松结构经过不可逆的收缩变成所谓的干凝胶的致密结构。
第二优选的适宜的硅酸-抛光剂是沉淀硅酸。在不出现溶胶和凝胶的条件下，通过加入强酸，使硅酸从碱金属硅酸稀溶液中沉淀析出。如专利DE-OS 25 22 486和DE-OS 31 14 493所公开的生产沉淀硅酸的适宜方法。优选根据专利DE-OS 31 14 493所公开的生产方法生产的沉淀硅酸是适宜的，其比表面(BET)为15-110m2/g，粒度为0.5-20μm，其中至少必须有80重量％初生颗粒的粒度小于5μm。10-20重量％牙用凝胶在含30％甘油-水(1∶1)-乳化剂中，其粘度为30-60 Pa·s(20℃)。此外优选具有园棱角类型的适宜沉淀硅酸，其商品名称为Sident12DS(DEGUSSA)。
这种类型的另一些沉淀硅酸是Sident8(DEGUSSA)和Sorbosil AC39(Crosfield Chemicals)。这种硅酸比表面在40-75m2/g(根据BET)的情况下，其特点是具有较小的增稠作用和较高的平均粒度，其范围为8-14μm。它特别适用于根据本发明的洁齿乳膏。
其它的抛光剂，特别是指具有某种折射率的抛光剂，它每多含0.1偏差就有1.45μm，优选不含这种抛光剂或至多含有小于2重量％的抛光剂。
对根据本发明的洁齿乳膏的流变性能和透明性具有决定作用的是水载体液相和保湿剂的成分。总量为55-70重量％的保湿剂是由山梨醇(a)、甘油(b)和聚乙二醇(c)按范围相对较窄的量比(a)∶(b)∶(c)=10∶(7-8)∶(0.5-1.5)组成。因此在优选的山梨醇含量为30-35重量％时，甘油含量为21-28重量％和聚乙二醇含量为1.5-5.25重量％。
优选含有水(d)和保湿剂(a+b+c)的重量比是(d)∶(a+b+c)=1∶(2-3)。在优选保湿剂含量为55-65重量％时，水含量为20-25重量％。其中水含量是通过如含70％山梨醇或含86％甘油等的原料中带入的水和单独加入水的总和。所给出的山梨醇和甘油的数量是针对无水的活性物质而言。
根据本发明的洁齿乳膏，除了含有上述必需加入的组分外，还可以含有其它的牙膏成分，这些物质的种类和含量对透明性不应有负面影响。这些成分，如粘合剂、表面活性剂、调味剂、治牙病和牙龈病的活性物质例如氟化物、抗牙石活性物质、抗菌物质(如双胍、二十三烷)、维生素、泛酰醇和其它活性物质。
最后根据本发明的透明洁齿乳膏非常突出的是，通过加入溶解的染色剂和/或色素于产品中得到所要求的外观颜色。特别适宜作为色素颗粒的有商品Sorbosil BFG51、BFG52和BFG55或Sorbosil SD2352。有时也可应用不同色素颗粒的混合物。根据本发明的洁齿乳膏可含有构成深橙色、红色或兰色的含量为0.1-1.0重量％的有色凝胶硅酸颗粒。
作为粘合剂可使用天然的和/或合成的聚合物，如藻酸酯、角叉菜胶、黄蓍胶、淀粉、淀粉醚，纤维素醚如羧甲基纤维素(Na盐)、羟基乙基纤维素、甲基羧基丙基纤维素，瓜耳树胶、阿拉伯树胶、琼脂、黄原胶、琥珀聚糖胶、稻子豆粉、果胶、水溶的羧基乙烯基聚合物(如Carbopol-类型)、聚乙烯醇、聚乙烯吡咯烷酮、聚乙二醇，特别是分子量为1500-1000000的聚合物。
特别适宜的粘合剂是黄原胶、羧甲基纤维素、聚乙烯吡咯烷酮和这些聚合物的混合物，其含量为小于0.5重量％。
合适的表面活性剂是如在烷基中有12-18个碳原子的直链烷基硫酸钠，这些物质对牙垢的细菌物料交换，还附加地具有抑制酶的作用。其它合适的表面活性剂是碱金属盐，优选在直链烷基中有12-16个碳原子和在分子中有2-6乙二醇醚基的烷基聚乙二醇硫酸钠酯、直链烷烃(C12-C18)-磺酸钠酯、磺基琥珀酸烷基(C12-C18)钠酯、硫酸处理过的脂肪酸-丙三醇钠酯、硫酸处理过的脂肪酸链烷醇酰胺钠盐、磺基乙酸烷基(C12-C16)钠酯、酰基肌氨酸、酰基牛磺酸和在酰基中有8-18个碳原子的酰基羟乙基磺酸盐。此外两性离子的、两性电解质的和非离子的表面活性剂均是合适的，如脂肪酸单乙氧基酯和脂肪酸脱水山梨醇酯的乙氧基甘油二酯和烷基(低分子量)葡糖苷。
优选月桂基硫酸钠盐和月桂基硫酸钠盐与椰子氨基丙基甜菜碱的混合物作为表面活性剂。
作为调味剂应用的有常用的香料和甜味剂。合适的香料有如薄荷油、变种卷叶薄荷油、按叶油、大茴香油、小茴香油、枯茗油、乙酸甲酯、肉桂醛、大茴香脑、香草醛、麝香草酚和其它天然的或与天然相同的醚类油，也可应用合成的调味料。
合适的甜味剂有糖精、环己基氨基磺酸钠酯、蔗糖、乳糖、麦芽糖和果糖。
其它的常用牙膏成分是：
-防腐剂和抗菌物质：如对羟基苯甲酸甲酯、对羟基苯甲酸乙酯、对羟基苯甲酸丙酯、山梨酸钠酯、苯甲酸钠酯、溴氯代苯酚、二十三(碳)烷、合克替啶、水杨酸苯基酯、双胍如洗必太和过氧化物；
-氟化物：如氟化钠、氟化锌、一氟磷酸钠、氟化铵；
-缓冲物质：如碱金属的磷酸盐、磷酸一氢盐、磷酸二氢盐、柠檬酸-柠檬酸钠；
-创口愈合物质和消炎物：如脲、尿囊素、泛酰醇、碱性绕丹宁、甘菊生物活性物质(甘菊环)和乙酰水杨酸衍生物；
-维生素：如维生素A、维生素E或维生素C；
-矿物盐：如锰盐、锌盐或镁盐。
在根据本发明的洁齿乳膏中所有这些可随意选择的牙膏成分的总量为2-10重量％。
下述的实施例将进一步说明本发明：
实施例
按下述成份生产洁齿乳膏
 1     2  3   4  5 6
    Sident12SPLS  12     12  12  12  12 12
    Sipemat320DS  -     -  -  -  0.5  -
    SorbosilBFG51  0.1     0.1  0.1  0.1  0.1  0.1
    山梨醇  33.6     33.6  33.6  33.6  33.6  33.6
    甘油  24.3     24.3  23.9  24.3  23.9  23.9
    聚乙二醇400  3.8     3.8  3.8  3.8  3.8  3.8
    KeltrolF  -     0.15  -  -  -  0.2
 Blanose9-M-31-XF  -     -  -  -  0.2  -
 Blanose12-M-31-P  -     -  0.25  0.25  -  -
    LuviskolK30  -     0.01  -  -  0.02  -
    TexaponK12  0.5     0.5  0.5  0.5  0.5  0.5
 Tego BetainF50  0.72     0.72  0.72  0.72  0.72  0.72
CremophorRH60 -  -  -  - -  -
    TagatS -  -  -  - -  -
    香料 0.8  0.8  0.8  0.8 0.8  0.8
    糖精 0.25  0.25  0.25  0.25 0.25  0.25
    泛酰醇 -  -  -  - -  -
维生素A醇-棕榈酸酯 -  -  -  - -  -
    Na2PO3F 1.1  1.1 1.1  1.1 1.1  1.1
      水 加至100 加至100 加至100  加至100 加至100  加至100
粘度(20℃)Pas  27.5 19.5  20.0   22.5 10.0  32.5
7   8   9   10   11   12   13
    Sident12SPLS 12   12   12   12   12   12   12
    Sipernat320 DS -   0.5   1.0   0.5   0.5   0.5   -
    Sorbosil BFG51 0.1   0.1   0.1   0.1   0.1   0.1   0.1
    山梨醇 33.6   33.6   33.6   33.6   33.6   33.6   33.6
    甘油 24.3   23.9   23.9   23.9   23.9   23.9   23.9
    聚乙二醇400 3.5   3.5   3.5   3.5   3.5   3.5   3.5
    KeltrolF 0.18   -   -   -   -   -   -
 Blanose9-M-31-XF -   0.2   0.2   0.25   -   0.13   0.2
 Blanose12-M-31-P -   -   -   -   -   -   -
   Luviskol K30 -   -   -   -   -   -   -
   TexaponK12 0.5   0.5   0.5   0.5   0.5   0.5   0.5
  Tego BetainF50 0.72   0.72   0.72   0.72   0.72   0.72   0.72
  CremophorRH60 -   -   -   -   -   -   0.2
    TagatS -   -   0.5   -   -   -   -
    香料 0.8   0.8   1.0   0.8   0.8   0.8   0.8
    糖精 0.25   0.25   0.25   0.25   0.25   0.25   0.25
    泛酰醇 -   0.13   0.13   -   -   -   -
维生素A醇-棕榈酸酯 -   0.018   0.018   -   -   -   -
    Na2PO3F 1.1   1.1   1.1   1.1   1.1   1.1   1.1
      水 加至100   加至100   加至100   加至100   加至100   加至100   加至100
  粘度(20℃)Pas 26.0   21.25    22.5   20.0   37.0   37.0   18.75
所有的实施例均显示为透明的乳膏，在25℃保持4周后仍保持透明。
本发明中应用了下述商品：
Sident12SPLS     ：沉淀硅酸
                     比表面(BET)：80m2/g
                     生产厂：DEGUSSA AG
Sipernat320 DS   ：沉淀硅酸
                     比表面(BET)：170m2/g
                     生产厂：DEGUSSA AG
SorbosilBFG51    ：着色凝集沉淀硅酸
                     平均凝集物颗粒粒度：310μm
                     (最小90％106-710μm)
KeltrolF         ：黄原胶
                     生产厂：KELCO工厂(布鲁塞尔)
Blanose9-M-31-XF ：Na-羧甲基纤维素
                     置换度(Subst-Grad)：0.8-0.95
                     粘度：100-300mPas(1％)
                     生产厂：HERCULES
Blanose12-M-31-XP：Na-羧甲基纤维素
                     置换度：1.2
                     粘度：100-300mPas(1％)
                     生产厂：HERCULES
LuviskolK30      ：聚乙烯吡咯烷酮MG：约40000
                     生产厂：BASF AG
TexaponK12       ：月桂基硫酸钠盐
                     (汉高两合股份公司)
Tego BetainF50   ：N,N-二甲基-N-椰子酰氨基丙基铵-乙酰基
                     甜菜碱(约36％AS)
                     生产厂：TEGO-CosmeticsCremophorRH60       ：PEG60氢化蓖麻油
                     (BASF AG)TagatS              ：聚氧化乙烯-(20)-甘油单硬脂酸酯
                      生产厂：TEGO-Cosmetics

Claims (6)

1．一种透明洁齿乳膏，含有：
10-15重量％硅酸抛光剂、
55-70重量％保湿剂、
15-30重量％水和
2-10重量％其它牙膏成分，
其特征在于，含有由山梨醇(a)、甘油(b)和聚乙二醇(c)按重量比(a)∶(b)∶(c)=10∶(7-8)∶(0.5-1.5)组成的混合物作为保湿剂。
2．根据权利要求1所述的洁齿乳膏，其特征在于，含有水(d)和保湿剂(a+b+c)，其重量比为(d)∶(a+b+c)=1∶(2-3)。
3．根据权利要求1或2所述的洁齿乳膏，其特征在于，为了达到要求的外观含有着色的硅酸颗粒，其含量为0.1-1.0重量％。
4．根据权利要求1-3中任一项所述的洁齿乳膏，其特征在于，含有作为其它牙膏成分的粘合剂、表面活性剂、调味剂和治牙病和牙龈病的活性物质。
5．根据权利要求1-4中任一项所述的洁齿乳膏，其特征在于，含有作为粘合剂的由黄原胶、羧甲基纤维素、聚乙烯吡咯烷酮或水溶性的聚合物组成的混合物，其含量小于0.5重量％。
6．根据权利要求4或5所述的洁齿乳膏，其特征在于，含有作为活性物质的氟化物、抗微生物剂、维生素和矿物盐。
CN99811561A 1998-10-01 1999-09-22 洁齿乳膏 Pending CN1320029A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19845247A DE19845247A1 (de) 1998-10-01 1998-10-01 Flüssiges Zahnreinigungsgel
DE19845247.0 1998-10-01

Publications (1)

Publication Number Publication Date
CN1320029A true CN1320029A (zh) 2001-10-31

Family

ID=7883071

Family Applications (1)

Application Number Title Priority Date Filing Date
CN99811561A Pending CN1320029A (zh) 1998-10-01 1999-09-22 洁齿乳膏

Country Status (16)

Country Link
US (1) US6506366B1 (zh)
EP (1) EP1119341B1 (zh)
JP (1) JP2002526393A (zh)
KR (1) KR20010075492A (zh)
CN (1) CN1320029A (zh)
AT (1) ATE283682T1 (zh)
AU (1) AU764465B2 (zh)
BR (1) BR9914187A (zh)
CA (1) CA2346002A1 (zh)
CZ (1) CZ20011184A3 (zh)
DE (2) DE19845247A1 (zh)
ES (1) ES2233080T3 (zh)
HU (1) HUP0104163A2 (zh)
NO (1) NO20011628D0 (zh)
SK (1) SK4352001A3 (zh)
WO (1) WO2000019970A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106537120A (zh) * 2014-07-24 2017-03-22 高露洁-棕榄公司 聚合物筛选方法

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19845247A1 (de) * 1998-10-01 2000-04-06 Henkel Kgaa Flüssiges Zahnreinigungsgel
US7041277B2 (en) * 2000-03-10 2006-05-09 Cadbury Adams Usa Llc Chewing gum and confectionery compositions with encapsulated stain removing agent compositions, and methods of making and using the same
DE10017998A1 (de) * 2000-04-11 2001-10-18 Henkel Kgaa Belaghemmendes flüssiges Zahnreinigungsgel
DE10017997A1 (de) 2000-04-11 2001-10-18 Henkel Kgaa Belaghemmendes flüssiges Zahnreinigungsgel
AU2002323135A1 (en) * 2001-08-14 2003-03-03 Variant Holdings, Llc. System for marketing goods and services utilizing computerized central and remote facilities
US20040131558A1 (en) * 2002-06-21 2004-07-08 Hauck Douglas J. Oral disease prevention and treatment
US7445769B2 (en) * 2002-10-31 2008-11-04 Cadbury Adams Usa Llc Compositions for removing stains from dental surfaces and methods of making and using the same
US20040131559A1 (en) * 2002-11-04 2004-07-08 Hauck Douglas J. Oral disease prevention and treatment
US6746681B1 (en) * 2002-12-20 2004-06-08 Preventive Dental Specialties, Inc. Pet tooth care preparation
US7041311B2 (en) * 2003-02-28 2006-05-09 International Flavors & Fragrances Inc. Preparation for saliva flow
EP1641536A1 (en) * 2003-05-19 2006-04-05 Unilever N.V. Multiphase toothpaste composition
US7390518B2 (en) * 2003-07-11 2008-06-24 Cadbury Adams Usa, Llc Stain removing chewing gum composition
US20080317681A1 (en) * 2003-07-11 2008-12-25 Petros Gebreselassie Compositions containing a stain removing complex, and methods of making and using the same
US7195658B2 (en) * 2003-10-17 2007-03-27 Saint-Gobain Abrasives, Inc. Antiloading compositions and methods of selecting same
US8591972B2 (en) * 2005-05-23 2013-11-26 Kraft Foods Global Brands Llc Delivery system for coated active components as part of an edible composition
US8389031B2 (en) * 2005-05-23 2013-03-05 Kraft Foods Global Brands Llc Coated delivery system for active components as part of an edible composition
US8591974B2 (en) 2003-11-21 2013-11-26 Kraft Foods Global Brands Llc Delivery system for two or more active components as part of an edible composition
US8597703B2 (en) * 2005-05-23 2013-12-03 Kraft Foods Global Brands Llc Delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component
US8591973B2 (en) * 2005-05-23 2013-11-26 Kraft Foods Global Brands Llc Delivery system for active components and a material having preselected hydrophobicity as part of an edible composition
US8591968B2 (en) * 2005-05-23 2013-11-26 Kraft Foods Global Brands Llc Edible composition including a delivery system for active components
US9271904B2 (en) * 2003-11-21 2016-03-01 Intercontinental Great Brands Llc Controlled release oral delivery systems
US20050112236A1 (en) * 2003-11-21 2005-05-26 Navroz Boghani Delivery system for active components as part of an edible composition having preselected tensile strength
US20060263474A1 (en) * 2005-05-23 2006-11-23 Cadbury Adams Usa Llc. Enhanced flavor-release comestible compositions and methods for same
US8389032B2 (en) * 2005-05-23 2013-03-05 Kraft Foods Global Brands Llc Delivery system for active components as part of an edible composition having selected particle size
US20060263473A1 (en) * 2005-05-23 2006-11-23 Cadbury Adams Usa Llc Compressed delivery system for active components as part of an edible composition
US20050281758A1 (en) * 2004-06-18 2005-12-22 Dodd Kenneth T Oral care compositions
US7641892B2 (en) * 2004-07-29 2010-01-05 Cadburry Adams USA, LLC Tooth whitening compositions and delivery systems therefor
US20060263476A1 (en) * 2004-08-25 2006-11-23 Cadbury Adams Usa, Llc. Center-filled chewing gum with barrier layer
US7955630B2 (en) * 2004-09-30 2011-06-07 Kraft Foods Global Brands Llc Thermally stable, high tensile strength encapsulated actives
US20060068058A1 (en) * 2004-09-30 2006-03-30 Cadbury Adams Usa Llc Thermally stable, high tensile strength encapsulation compositions for actives
US7727565B2 (en) 2004-08-25 2010-06-01 Cadbury Adams Usa Llc Liquid-filled chewing gum composition
US20060068059A1 (en) * 2004-09-30 2006-03-30 Cadbury Adams Usa Llc Encapsulated compositions and methods of preparation
US9198448B2 (en) 2005-02-07 2015-12-01 Intercontinental Great Brands Llc Stable tooth whitening gum with reactive ingredients
US7851006B2 (en) * 2005-05-23 2010-12-14 Cadbury Adams Usa Llc Taste potentiator compositions and beverages containing same
MX349340B (es) * 2005-05-23 2017-07-24 Intercontinental Great Brands Llc Composiciones potenciadoras del sabor y bebidas que contienen las mismas.
US7851005B2 (en) * 2005-05-23 2010-12-14 Cadbury Adams Usa Llc Taste potentiator compositions and beverages containing same
US20070053972A1 (en) * 2005-09-08 2007-03-08 Cadbury Adams Usa Llc. Gelatin capsules containing actives
KR100795434B1 (ko) * 2005-10-20 2008-01-17 주식회사 매스틱코리아 매스틱을 함유한 치약조성물
US20070178188A1 (en) * 2006-01-27 2007-08-02 Cadbury Adams Usa Llc Chewing gum compositions including free neotame sweetener compositions
US20070178187A1 (en) * 2006-01-27 2007-08-02 Cadbury Adams Usa Llc Chewing gum compositions including free neotame sweetener compositions
JP4926490B2 (ja) * 2006-02-16 2012-05-09 花王株式会社 歯磨剤
JP2007254396A (ja) * 2006-03-23 2007-10-04 Takasago Internatl Corp 香気成分揮散方法
US20090004360A1 (en) * 2007-05-14 2009-01-01 Cadbury Adams Usa Llc Taste Potentiator Compositions in Oral Delivery Systems
US8551457B2 (en) 2008-11-25 2013-10-08 The Procter & Gamble Company Oral care compositions comprising spherical fused silica
JP5697600B2 (ja) * 2008-11-25 2015-04-08 ザ プロクター アンド ギャンブルカンパニー 溶融シリカを有する口腔抗菌ケア組成物
CA2834512A1 (en) 2011-04-29 2012-11-01 Intercontinental Great Brands Llc Encapsulated acid, method for the preparation thereof, and chewing gum comprising same
JP5924010B2 (ja) * 2012-02-09 2016-05-25 ライオン株式会社 歯磨剤組成物
RU2608129C2 (ru) 2012-11-05 2017-01-13 Дзе Проктер Энд Гэмбл Компани Термически обработанная осажденная двуокись кремния
JP6236773B2 (ja) * 2012-11-28 2017-11-29 ライオン株式会社 不透明歯磨剤組成物
CN108904325B (zh) 2013-06-18 2022-04-12 株式会社Lg生活健康 按压式牙膏产品
WO2019163460A1 (ja) 2018-02-26 2019-08-29 ライオン株式会社 歯磨剤組成物
CN113164339B (zh) * 2018-11-23 2024-05-28 Blbr股份有限公司 牙齿护理和牙齿清洁组合物、系统及牙齿清洁方法
JP7138029B2 (ja) * 2018-11-30 2022-09-15 ライオン株式会社 舌擦掃用透明ジェル組成物及びそれを使用した舌の清掃方法
EP3949942A4 (en) 2019-03-28 2023-04-05 LG Household & Health Care Ltd. TOOTHPASTE COMPOSITION

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3538230A (en) 1966-12-05 1970-11-03 Lever Brothers Ltd Oral compositions containing silica xerogels as cleaning and polishing agents
US3803301A (en) * 1971-06-03 1974-04-09 Colgate Palmolive Co Clear toothpastes containing visible agglomerates
US3767791A (en) * 1971-06-03 1973-10-23 Colgate Palmolive Co Dental cream containing abrasive agglomerates
GB1397248A (en) * 1971-10-20 1975-06-11 Beecham Inc Dental compositions
US4108978A (en) 1971-10-20 1978-08-22 Beecham Inc. Dental compositions
US3935306A (en) * 1972-04-11 1976-01-27 Colgate-Palmolive Company Toothpaste formulations
IT957698B (it) * 1972-05-03 1973-10-20 Squibb Spa Pasta dentifricia trasparente e procedimento per la sua produ zione
ZA737495B (en) * 1972-10-30 1975-05-28 Colgate Palmolive Co Toothpastes
US4089943A (en) * 1974-02-08 1978-05-16 Colgate-Palmolive Company Toothpaste formulations
AU497891B2 (en) 1974-05-22 1979-01-18 J.M. Huber Corp. Siliceous pigments & their production
AU514418B2 (en) 1976-02-05 1981-02-12 W.R. Grace & Co. Dentifrice
US4294894A (en) * 1979-01-15 1981-10-13 E. R. Squibb & Sons, Inc. Transparent toothpaste having a medicinal action and process for its production
DE3114493A1 (de) 1981-04-10 1982-10-28 Degussa Ag, 6000 Frankfurt "faellungskieselsaeuren und verfahren zu ihrer herstellung"
US4456585A (en) * 1983-05-16 1984-06-26 Colgate-Palmolive Company Visually clear pigment-colored dentifrice composition
AU578392B2 (en) 1984-07-31 1988-10-20 Lion Corporation Toothpaste composition containing silica
FR2605012B1 (fr) * 1986-10-10 1988-11-25 Rhone Poulenc Chimie Pigments colores a base d'un oxyde mineral du type silice, alumine ou oxyde de titane ou de zirconium et leurs procedes de preparation.
GB2240473B (en) * 1990-01-31 1994-06-29 Lion Corp Liquid dentifrice compositions
US5252313A (en) * 1991-12-20 1993-10-12 Colgate-Palmolive Company Visually clear gel dentifrice
DE4222739A1 (de) 1992-07-10 1994-01-13 Henkel Kgaa Flüssige Zahnreinigungsmittel
DE69512647T2 (de) * 1994-02-24 2000-04-27 Smithkline Beecham Consumer Durchsichtiges flüssiges zahnputzmittel
US5582816A (en) * 1995-06-01 1996-12-10 Colgate Palmolive Company Preparation of a visually clear gel dentifrice
DE19522750A1 (de) * 1995-06-22 1997-01-02 Henkel Kgaa Flüssige Zahnreinigungsmittel
US5695746A (en) * 1995-07-28 1997-12-09 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Liquid dentifrice with mouthwash fresh taste
DE19831547A1 (de) * 1998-07-14 2000-01-20 Henkel Kgaa Flüssige Zahnreinigungsmittel
US6074629A (en) * 1998-07-27 2000-06-13 J. M. Huber Corporation Dentifrice with a dye absorbing silica for imparting a speckled appearance thereto
DE19845247A1 (de) * 1998-10-01 2000-04-06 Henkel Kgaa Flüssiges Zahnreinigungsgel
US6143280A (en) * 1999-05-18 2000-11-07 J. M. Huber Corporation Color containing silica resistant to dye migration and method of making the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106537120A (zh) * 2014-07-24 2017-03-22 高露洁-棕榄公司 聚合物筛选方法

Also Published As

Publication number Publication date
JP2002526393A (ja) 2002-08-20
SK4352001A3 (en) 2001-11-06
NO20011628L (no) 2001-03-30
NO20011628D0 (no) 2001-03-30
DE59911203D1 (de) 2005-01-05
ES2233080T3 (es) 2005-06-01
AU6328699A (en) 2000-04-26
CA2346002A1 (en) 2000-04-13
WO2000019970A1 (de) 2000-04-13
HUP0104163A2 (hu) 2002-04-29
EP1119341B1 (de) 2004-12-01
DE19845247A1 (de) 2000-04-06
EP1119341A1 (de) 2001-08-01
KR20010075492A (ko) 2001-08-09
CZ20011184A3 (cs) 2001-08-15
BR9914187A (pt) 2001-11-20
ATE283682T1 (de) 2004-12-15
US6506366B1 (en) 2003-01-14
AU764465B2 (en) 2003-08-21

Similar Documents

Publication Publication Date Title
CN1320029A (zh) 洁齿乳膏
US5605677A (en) Remineralizing dental care preparation
CN1079383A (zh) 目视清澈的凝胶状牙膏
GB2149661A (en) Dentifrices
US6685919B2 (en) Plaque-controlling liquid tooth cleaning gel
AU740042B2 (en) Oral and dental hygiene products for sensitive teeth
JP2003530337A (ja) 歯垢抑制液体歯清浄製剤
CN1137151C (zh) 交联马来酸酐共聚物的制备方法
US4407788A (en) Dentifrice
CN1745743A (zh) 一种含有阴阳离子表面活性剂的牙膏及其制造方法
CN1267081C (zh) 牙膏组合物
CN1314806A (zh) 洁齿乳膏
JPH0244283B2 (zh)
FI58588B (fi) Visuellt klar tandkraem i gelform och foerfarande foer dess framstaellning
CN1771020A (zh) 口腔用组合物的生产方法
CN114209604A (zh) 一种口腔护理无水组合物及其制备方法和应用
CN113382711A (zh) 口腔护理组合物
RO127805B1 (ro) Compoziţie pentru pastă de dinţi
WO2024046751A1 (en) Process for the manufacture of a non-aqueous composition
MXPA01003317A (en) Liquid tooth cleaning gel
CZ2001161A3 (cs) Tekutý prostředek pro čištění zubů

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication