CN1319647A - High sulfur heavy fuel desulfurating agent and use thereof - Google Patents

High sulfur heavy fuel desulfurating agent and use thereof Download PDF

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Publication number
CN1319647A
CN1319647A CN 01109827 CN01109827A CN1319647A CN 1319647 A CN1319647 A CN 1319647A CN 01109827 CN01109827 CN 01109827 CN 01109827 A CN01109827 A CN 01109827A CN 1319647 A CN1319647 A CN 1319647A
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heavy fuel
sweetening agent
sulfur
oil
high sulfur
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CN 01109827
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CN1166752C (en
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吴国志
翟有成
曹志德
何平
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ZHONGYOU FUEL CO Ltd
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ZHONGYOU FUEL CO Ltd
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Priority to CNB011098279A priority Critical patent/CN1166752C/en
Publication of CN1319647A publication Critical patent/CN1319647A/en
Priority to PCT/CN2002/000162 priority patent/WO2002074885A1/en
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Publication of CN1166752C publication Critical patent/CN1166752C/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1225—Inorganic compounds halogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2443—Organic compounds containing sulfur, selenium and/or tellurium heterocyclic compounds
    • C10L1/245—Organic compounds containing sulfur, selenium and/or tellurium heterocyclic compounds only sulfur as hetero atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The desulfurizing agent made up by using potassium permanganate, methyl alcohol, glycol, pentaerythritol, sulfolane, cyclohexane, alkylphenol ethoxylates, cholamine, zinc naphthenate and barium sulfonate as raw material can be added in high-sulfur heavy fuel, specially added in high-sulfur oli emulsified oil, and can be substituted for low-surfur heavy fuel to make combustion. Test shows that the Oli emulsified oil in which said invented desulfurizing agent is added can obtain obvious desulfurizing effect.

Description

A kind of high sulfur heavy fuel desulfurating agent and application thereof
The present invention relates to the desulfurization technology of heavy fuel oil (HFO), or rather, is to add a kind of sweetening agent in high sulfur heavy fuel oil, with the sulphur dioxide emission in the gas after the reduction fuel combustion.
As everyone knows, requiring for the important quality of heavy fuel oil (HFO) such as boiler oil is exactly that sulphur content is low, requires to be lower than 3% as the sulphur content of homemade No. 200 heavy oil, because in the flue gas of discharging behind the high sulfur heavy fuel oil firing, amount of sulfur dioxide is higher, can bring severe contamination to environment.In order to reduce the content of sulfur dioxide in the gas, the employing tail gas dry process or the wet desulphurization that have, the sweetener that the needs that have increase is huge.These method commonly used investments are big, and complicated operation need conditions such as great amount of manpower, electric power, and sweetening effectiveness is not obvious, is difficult to apply.
The objective of the invention is to overcome the shortcoming of prior art, propose a kind of particularly sweetening agent of high-sulfur oil in water emulsion of high sulfur heavy fuel oil that is used for.
Another object of the present invention is that sweetening agent is applied to high sulfur heavy fuel oil and particularly is applied to contain high-sulfur emulsified orinoco crude oil (a kind of heavy fuel oil (HFO)), is used for combustion equipment to substitute the low-sulfur low-volatility fuel.
Sweetening agent of the present invention is a kind of composition, concrete component and content (is 100 in the composition weight sum):
Potassium permanganate 4～6%, methyl alcohol 9～11%, ethylene glycol 9～11%, tetramethylolmethane 4～6%, tetramethylene sulfone 9～11%, hexanaphthene 4～6%, alkylphenol polyoxyethylene 4～6%, thanomin 9～11%, zinc naphthenate 19～21%, barium iodate 19～21%.
Above-mentioned raw materials all is commercially available Chemicals.
The preparation method of sweetening agent of the present invention: potassium permanganate is joined under whipped state in the methyl alcohol lentamente, stir and add other component again after 10 minutes, continue to stir after 5 minutes and get final product.
Sweetening agent of the present invention is applicable to that high sulfur heavy fuel oil is specially adapted to the high-sulfur emulsified orinoco crude oil.The concrete application: in low-volatility fuel, add sweetening agent, mix and get final product, its add-on is that the weight ratio of heavy fuel oil (HFO) and sweetening agent is 90～93: 10～7, described emulsified orinoco crude oil is the oil-in-water emulsion that is made of the water of about 70% the promptly super mink cell focus of heavy rock asphalt and 30% and 0.3～0.5% emulsifying agent, the used emulsified orinoco crude oil of the present invention is to be No. 400, emulsified orinoco crude oil from the subordinate's of Venezuelan Petroleum Company research and development company with the trade mark of British Petroleum Company p.l.c.'s cooperative development, and its performance sees Table 1.
Advantage of the present invention:
The present invention finds out through a large amount of tests to concentrate bituminous matter that compounds such as sulphur are arranged and colloid to dissolve each other in a kind of and the low-volatility fuel and have high oil-soluble composite desulfurizing agent, it is added in the high sulfur heavy fuel, its physicochemical property are stable, burning-point, flash-point, viscosity, calorific value and low-sulfur low-volatility fuel are approaching, can substitute the low sulphur heavy oil burning, so just can save low sulphur heavy oil, particularly at present domestic and international low sulphur heavy oil seems even more important very after a little while.
The raw material of sweetening agent of the present invention is easy to get, and can adopt three grades of products of industry, and the process of producing is simple, causes low production cost; Sweetening agent of the present invention is applied to the high-sulfur emulsified orinoco crude oil, and method is simple, but and continuous automatic production; Sweetening agent of the present invention is added in the emulsified orinoco crude oil, carries out commerical test on the oil-firing boiler of 4 ton per days, and its sweetening effectiveness reaches national environmental standard fully.In sum, sweetening agent of the present invention is applied to high sulfur heavy fuel oil particularly can substitute low-sulfur low-volatility fuel oil firing behind the high-sulfur emulsified orinoco crude oil, therefore has important social benefit and economic benefit.
Further specify characteristics of the present invention below by concrete example.
Example 1
This example is a preparation sweetening agent of the present invention.
Under agitation be added to 25kg potassium permanganate in the 50kg methyl alcohol lentamente, stir after 10 minutes again with 50kg ethylene glycol, 25kg season amylalcohol, 50kg tetramethylene sulfone, 25kg hexanaphthene, 25kg alkylphenol polyoxyethylene, 50kg thanomin, 100kg zinc naphthenate, 100kg barium sulfonate, continue to stir after 5 minutes and get final product.The performance of sweetening agent sees Table 2.
Example 2
This example is the application example of example 1 sweetening agent.
No. 400, the high-sulfur emulsified orinoco crude oil of Venezuela's import is mixed by 93: 7 weight ratios with sweetening agent, obtain mixing oil.
Mixing oil is sent into boiler combustion.Test condition: the boiler model is WNS4-1.0-Y4 ton horizontal internal combustion three backhaul oil-fired steam boilers, and Boiler Steam is pressed 0.5Mpa * oil pressure 0.25～0.3Mpa, and air quantity is 1560～3120m 3/ h, amount of fuel 178kg/h, funnel temperature 200-250 ℃, monitoring time is 72 hours.Test result sees Table 3, and the data in the table 3 are by GWPB3-1999 regulation measured result by China Environmental Monitoring General Station.
The conclusion that is drawn by table 3 data: adopt sweetening agent of the present invention, sweetening effectiveness is obvious, desulfurization degree be 80～83% (?), reaching the limit value standard that GWPB3-1999 stipulates, flue dust, lingemann blackness also reach standard.
Table 1
Project Performance
Moisture, % ????30
Density (20 ℃), g/cm 3???? ????0.99
Calorific value, MJ/kg ????30.1
Ash content, % ????≤0.1
Sulphur content, % ????3.1
Table 2
Project Performance Test method
Density, g/cm 3 ????1.029 ????GB611-88
Colourity Combine red Visual
Mechanical impurity, % ????≤0.0001 ????GB511-88
Moisture content Do not have ????GB606-88
Water-soluble acid and alkali Do not have ????GB604-88
Table 3
Project The emulsified orinoco crude oil that does not add sweetening agent The emulsified orinoco crude oil that adds sweetening agent
SO 2Emission concentration, mg/Nm 3 ????5109～5205 ????860～1066
Smoke dust discharge concentration, mg/Nm 3 ????0.69 ????0.72
Lingemann blackness ????＜1 ????＜1

Claims (3)

1. heavy fuel desulfurating agent is characterized in that each component and content thereof (is 100 in the composition weight sum):
Potassium permanganate 4～6%, methyl alcohol 9～11%, ethylene glycol 9～11%, tetramethylolmethane 4～6%, tetramethylene sulfone 9～11%, hexanaphthene 4～6%, alkylphenol polyoxyethylene 4～6%, thanomin 9～11%, zinc naphthenate 19～21%, barium iodate 19～21%.
2. the preparation method of the described sweetening agent of claim 1 is: potassium permanganate is joined under whipped state in the methyl alcohol lentamente, stir and add other component again after 10 minutes, continue to stir after 5 minutes and get final product.
3. the concrete application of the described sweetening agent of claim 1: with high sulfur heavy fuel and sweetening agent with 90～93: 10～7 weight ratios mix and get final product.
CNB011098279A 2001-03-20 2001-03-20 High sulfur heavy fuel desulfurating agent and use thereof Expired - Fee Related CN1166752C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CNB011098279A CN1166752C (en) 2001-03-20 2001-03-20 High sulfur heavy fuel desulfurating agent and use thereof
PCT/CN2002/000162 WO2002074885A1 (en) 2001-03-20 2002-03-15 Desulfurizing agent for heavy fuel oil and the method for preparing the same and the usage thereof

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Application Number Priority Date Filing Date Title
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102264875A (en) * 2008-10-24 2011-11-30 卢布里佐尔公司 Nitrogen free deposit control fuel additives
CN101434880B (en) * 2007-11-15 2012-12-26 中国石油化工股份有限公司 Oxidative desulfurization method for liquefied petroleum gas
CN104711043A (en) * 2015-01-30 2015-06-17 安徽海德石油化工有限公司 Novel burner plant oil and preparation method thereof
CN105623752A (en) * 2016-02-27 2016-06-01 安徽海德石油化工有限公司 Soybean and plant mixed fuel oil and preparing method thereof
CN105713681A (en) * 2016-02-27 2016-06-29 安徽海德石油化工有限公司 Low-temperature EVA hot melt adhesive-corn oil mixed fuel oil for paper and preparation method of mixed fuel oil
CN105713680A (en) * 2016-02-27 2016-06-29 安徽海德石油化工有限公司 Mixed plant fuel oil and preparation method thereof
CN105733696A (en) * 2016-02-27 2016-07-06 安徽海德石油化工有限公司 Non-toxic epoxy resin-soybean protein plant fuel oil and preparation method thereof
CN105733697A (en) * 2016-02-27 2016-07-06 安徽海德石油化工有限公司 Environment-friendly graft chloroprene rubber and corn oil hybrid fuel oil and preparation method thereof
CN107243244A (en) * 2017-06-16 2017-10-13 中国石油大学(华东) Carbide slag and biological pyrolysis oil prepare biological desulphurization denitrfying agent and its application method

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1163925A (en) * 1996-11-15 1997-11-05 覃戊文 Combustion enhancing sweetening agent

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434880B (en) * 2007-11-15 2012-12-26 中国石油化工股份有限公司 Oxidative desulfurization method for liquefied petroleum gas
CN102264875A (en) * 2008-10-24 2011-11-30 卢布里佐尔公司 Nitrogen free deposit control fuel additives
CN102264875B (en) * 2008-10-24 2014-01-22 卢布里佐尔公司 Nitrogen free deposit control fuel additives
CN104711043A (en) * 2015-01-30 2015-06-17 安徽海德石油化工有限公司 Novel burner plant oil and preparation method thereof
CN105623752A (en) * 2016-02-27 2016-06-01 安徽海德石油化工有限公司 Soybean and plant mixed fuel oil and preparing method thereof
CN105713681A (en) * 2016-02-27 2016-06-29 安徽海德石油化工有限公司 Low-temperature EVA hot melt adhesive-corn oil mixed fuel oil for paper and preparation method of mixed fuel oil
CN105713680A (en) * 2016-02-27 2016-06-29 安徽海德石油化工有限公司 Mixed plant fuel oil and preparation method thereof
CN105733696A (en) * 2016-02-27 2016-07-06 安徽海德石油化工有限公司 Non-toxic epoxy resin-soybean protein plant fuel oil and preparation method thereof
CN105733697A (en) * 2016-02-27 2016-07-06 安徽海德石油化工有限公司 Environment-friendly graft chloroprene rubber and corn oil hybrid fuel oil and preparation method thereof
CN107243244A (en) * 2017-06-16 2017-10-13 中国石油大学(华东) Carbide slag and biological pyrolysis oil prepare biological desulphurization denitrfying agent and its application method

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