CN1319510C - Liquid cosmetic - Google Patents
Liquid cosmetic Download PDFInfo
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- CN1319510C CN1319510C CNB031193595A CN03119359A CN1319510C CN 1319510 C CN1319510 C CN 1319510C CN B031193595 A CNB031193595 A CN B031193595A CN 03119359 A CN03119359 A CN 03119359A CN 1319510 C CN1319510 C CN 1319510C
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- polyoxyethylene
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/676—Ascorbic acid, i.e. vitamin C
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/63—Steroids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
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Abstract
To provide a liquid cosmetic excellent in use feeling and stability with time even in the presence of a water-soluble L-ascorbic acid derivative. This liquid cosmetic contains the following (a) to (c) components as essential ingredients, (a): a polyoxyethylene adduct sterol derivative having 2-30 mol added number of moles of ethylene oxide, (b): an emollient agent and (c): a water-soluble L-ascorbic acid derivative, and the blending mass ratio of the components (a) to (b) is (20:1)-(1:20).
Description
Technical field
The present invention relates to the liquid make-up that the stable dispersion lubricant obtains in the presence of the water solublity ascorbic acid derivates, in more detail, relate to the sensation that has good moistening effect, is not clamminess when using, the liquid make-up that usability is good and outward appearance can remain unchanged for a long time.
Background technology
Water solublity ascorbic acid derivates in the past has good whitening effect because of it, and is widely used in preparing cosmetics.But, if these cosmetics contain a large amount of water miscible vitamin C derivatives, will produce unique sensation that is clamminess and form the sensation of mucosa, feel very bad after therefore using.In order to obtain good result of use, prior art adopted respectively high molecular such as sneaking into water-soluble high-molecular compound or wax material method and sneak into the sensation that the method for wet goods lubricant suppresses to be clamminess.But, when these methods are used for liquid make-up, technical very difficult enforcement.
In addition, if in the solution of the water solublity ascorbic acid derivates of liquid make-up, sneak into the lubricant of needed q.s, then be difficult to keep the liquid condition of liquid make-up, and be difficult to guarantee the stability of cosmetics.The spy opens communiques such as 2000-229812 number, special fair 6-1876 number, special fair 6-99271 number and special fair 8-16047 number and discloses the technology of sneaking into lubricant in liquid make-up.But, when these technology are used for the aqueous solution of water solublity ascorbic acid derivates, can not obtain effect of sufficient.
Summary of the invention
In view of the foregoing, the present invention relates to have the liquid make-up that contains the water solublity ascorbic acid derivates of good usability and long-time stability.
The present inventor is for solving above-mentioned problem, further investigate, it found that, the liquid make-up that contains water solublity L-ascorbic acid derivates, if contain specific polyoxyethylene sterol derivative and lubricant, just can have good usability and long-time stability, finish the present invention thus.
That is, the present invention relates to a kind of liquid make-up, these cosmetics contain the following composition (a)～(c) as neccessary composition:
(a) the average addition molal quantity of oxygen ethylene is 2～30 polyoxyethylene sterol derivative,
(b) lubricant,
(c) water solublity L-ascorbic acid derivates;
And the mass ratio of composition (a) and composition (b) is 20: 1 to 1: 20.And, the present invention relates to also contain the liquid make-up of composition (d) anion surfactant, and the dispersant liquid drop mean diameter that relates to composition (b) lubricant is 0.5 μ m or the following liquid make-up of 0.5 μ m.
Below composition of the present invention is described.
Composition used in the present invention (a) polyoxyethylene sterol derivative is the surfactant that is used for stable dispersion composition (b) lubricant.The hydrophilic group of polyoxyethylene sterol derivative has polyoxyethylene chain, and hydrophobic group has the sterol structure.The object lesson of sterol structure comprises cholesterol, plant sterol, Dihydrocholesterol and dihydrocholesterol etc., the material that can use the material that extracts from animals and plants or chemosynthesis to obtain.When with respect to 1 mole of sterol structure, when the average addition molal quantity of forming the oxygen ethylene of hydrophilic group-polyoxyethylene chain was 2～30 moles, it is stable that liquid make-up keeps.Consider that from the viewpoint of the stability that improves liquid make-up the average addition molal quantity of preferred oxygen ethylene is 5～20 moles.Concrete example as, polyoxyethylene (5～30) cholesterol ether, polyoxyethylene (5～30) plant sterol ether, polyoxyethylene (5～30) dihydrocholesterol ether, polyoxyethylene (5～30) cholestane alcohol ether etc.As commercially available goods, for example, as cholesterin derivative such as BELBOL C-10 (Ji Chuan system oil), EMALEX CS-5,10,15,20,24 and 30 (above) for helping wooden chemistry, Japanese latex system; As Dihydrocholesterol derivant such as BELBOL DCH-30 (Ji Chuan system oil), NIKKOLDHC-20, DHC-30 (above is daylight chemicals system); As plant sterol derivant such as NIKKOL BPS-10 systems such as () daylight chemicals, cadinol 122E5,122E10,122E16,122E25 (assistant assistant lignify length of schooling) etc.Also can select one or more described polyoxyethylene sterol derivatives to be used in combination as required.
With respect to the gross mass of liquid make-up, the content of the composition that uses among the present invention (a) is preferably 0.001～10 quality %, and (following simplification is represented with " % ", " the quality % " in this description and " weight % " same meaning.), more preferably 0.01～3%.In this scope, can obtain having the good usability and the liquid make-up of long-time stability.
The composition that uses among the present invention (b) lubricant is that the softness of giving the cosmetics moisturizing effect that is used for skin and hair keeps composition, and used in the present invention is the oiliness composition.The material that it can use the material that extracts from animals and plants or chemosynthesis to obtain.They can be solid-state, paste, liquid state etc. at normal temperatures.More preferably using is the material of paste～liquid state at normal temperatures, because of it can further improve usability.
The object lesson of described oiliness composition comprises, for example hydrocarbon-type oils such as Liquid Paraffin, hydrogenation polyisobutylene, isomerization alkanes, paraffin, ceresin(e), vaseline, microwax.Isononyl isononanoate, different n-nonanoic acid isotridecyl ester, isopropyl myristate, sad cetyl ester, tetradecanoic acid octyl group dodecyl ester, the hexadecanoic acid isopropyl ester, butyl stearate, the own ester of dodecylic acid, tetradecanoic acid myristyl fat, tetradecanoic acid-2-hexyl decyl ester, hexadecanoic acid-2-hexyl decyl ester, hexadecanoic acid-2-ethyl hexyl ester, the oleic acid decyl ester, Cetiol, hexadecanoic acid-2-heptyl ester, sad hexyl decyl ester, isopropyl stearate, stearic acid isocetyl ester, isostearic acid isocetyl ester, the different stearyl ester of isostearic acid, two (2 ethyl hexanoic acid) glycol ester, two (2 ethyl hexanoic acid) season pentadiol ester, NPDC, malic acid two different stearyl esters, three (2 ethyl hexanoic acid) glyceride, three (sufferings, the last of the ten Heavenly stems) acid glyceride, three (tetradecanoic acid) glyceride, three (2-heptyl hendecanoic acid) glyceride, three (2-Methylpentadecane acid) glyceride, three (2 ethyl hexanoic acid) trihydroxy methyl propyl ester, three isostearic acid trihydroxy methyl propyl ester, four (2 ethyl hexanoic acid) five erithritol esters, the Castor Oil Fatty Acid methyl ester, diisobutyl adipate, N-dodecyl-L-glutamic acid-2-octyl group dodecyl ester, adipic acid two (2-heptyl undecyl) ester, decanedioic acid (two-2-ethyl is own) ester, adipic acid two (2-hexyl decyl) ester, succinic acid two (the 2-ethyl is own) ester, two (2 ethyl hexanoic acid) propylene glycol ester, the didecyl acid propylene glycol ester, dialkyl carbonate (the alkyl carbon number is 14,15), the lactic acid cetyl ester, lactic acid myristyl ester, acetic acid agnolin ester, 12-hydroxy stearic acid cholesterol ester, the isostearic acid cholesterol ester, 12-hydroxy stearic acid plant sterol ester, esters oil or triglycerin esters oil that isostearic acid plant sterol ester etc. obtain by chemosynthesis;
Semen Tritici aestivi germ oil, rice embryo oil, spiraea oil, oil of rosemary, olive oil, Oleum Ricini, Jojoba oil, macadimia nut oil, Flos Carthami wet goods vegetable oil; The animal oil and the fish oil of agnolin, mink oil, three decanes, squalene, octadecane, Orange Roughy wet goods;
Methyl polysiloxane, methyl phenyl silicone, methyl cyclopolysiloxane, alkyl-modified silicone oil, polyether-modified silicone oil such as silicone oil;
Senior alcohols such as dodecanol, hexadecanol, stearyl alcohol, tadenan, tetradecanol, oleyl alcohol, hexadeca-octadecyl alcohol, 2-decyl tetradecanol, agnolin, hexyl dodecanol, isooctadecanol, octyldodecanol; Dodecylic acid, tetradecanoic acid, hexadecanoic acid, stearic acid, behenic acid, oleic acid, 9-undecylenic acid, the acid of appropriate that, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), clupanodonic acid senior fatty acids such as (DHA);
The fat soluble vitamin class of vitamin E and derivant thereof, vitamin A and derivant thereof, fat soluble vitamin C etc.; Oil-solubles such as oil-soluble Radix Glycyrrhizae extract, oil-soluble chamomile extract, oil-soluble Herba Rosmarini Officinalis extract, triterpene class improve looks to become to grade; The oiliness composition of sterols such as single stearic glycerin ether (batilol), ceramide and derivant thereof, cholesterol, plant sterol.
Wherein, preferred lubricant is to be dissolved in 95 degree ethanol (15 ℃ the time, about 92.9～93.6 quality %) composition, concrete example as, isononyl isononanoate, different n-nonanoic acid isotridecyl ester, three (2 ethyl hexanoic acid) glyceride, 2 ethyl hexanoic acid cetyl ester, three (suffering, the last of the ten Heavenly stems) acid glyceride, four (2 ethyl hexanoic acid) five erithritol esters, three isostearic acid trihydroxy methyl propyl ester, NPDC, didecyl acid propylene glycol ester, methyl phenyl silicone etc.Can select one or more lubricant to be used in combination as required.
With respect to the gross mass of liquid make-up, the content of described composition (b) is preferably 0.01～5%.In this scope, can obtain the good and usability better fluid cosmetics of moisturizing effect.
If the mass ratio (a) of described composition (a) and composition (b): (b) be 1: 20 to 20: 1, just can reduce the sensation that is clamminess, if the mass ratio (a) of described composition (a) and composition (b): in the time of (b) more preferably in 1: 10 to 10: 1 scope, can improve effect of the present invention more significantly.(" mass ratio " in this description and " weight ratio " same meaning.)
The composition that uses among the present invention (c) water solublity L-ascorbic acid derivates (L-Ascorbate) Pear Power effect is as long as it is that just there is no particular limitation for water-soluble substances.Specifically can enumerate L-sodium ascorbate, L-potassium ascorbate, L-Magnesium ascorbate, L-sodium ascorbyl phosphate, L-magnesium ascorbyl phosphate, L-sodium ascorbyl phosphate potassium, L-ascorbic acid sodium sulfate, L-ascorbic acid magnesium sulfate, L-ascorbic acid potassium sulfate etc.Wherein, preferred L-magnesium ascorbyl phosphate, L-sodium ascorbyl phosphate, L-ascorbic acid sodium sulfate.As required, can select one or more water solublity L-Ascorbate to be used in combination.
With respect to the gross mass of liquid make-up, the content of described composition (c) is preferably 0.01～5%, and more preferably 0.1～3%.In this scope, can obtain whitening effect good, sense, stable liquid make-up are not clamminess.
And, if the mass ratio (b) of described composition (b) and composition (c): (c) be 1: 300 to 300: 1, just can further reduce the sensation that is clamminess.If the mass ratio of described composition (b) and composition (c) in preferred 1: 30 to 30: 1 scope the time, can improve effect of the present invention more significantly.
Adding ingredient in liquid make-up of the present invention (d) anion surfactant can improve the long-time stability of liquid make-up.Described examples of anionic surfactants comprises, alkyl sulfate salt such as sodium lauryl sulphate, lauryl sulphate acid potassium; POE alkyl sulfate salt such as polyoxyethylene (following abbreviation " POE ") dodecyltriethanolamine sulfate, POE sodium lauryl sulphate; N-acyl sarcosinates such as lauroyl sodium sarcosinate; Senior fatty acid amide sulfonate such as N-stearyl-N methyl taurine sodium, N-hexadecanoyl-N methyl taurine sodium, N-tetradecanoyl-N methyl taurine sodium, coco-nut oil fatty acid N-methyltaurine sodium, dodecyl methyl sodium taurocholate; POE alkyl ether phosphate salts such as POE lauryl ether sodium phosphate, POE myristyl ether sodium phosphate, POE cetyl ether sodium phosphate, POE oleyl ether sodium phosphate, POE stearyl ether sodium phosphate; Sulfosuccinates such as two (2-ethylhexyl) sodium sulfosuccinate, single lauroyl single ethanol amide POE sodium sulfosuccinate, dodecyl polypropylene glycol sodium sulfosuccinate; Alkylbenzenesulfonates such as Potassium dodecylbenzenesulfonate, DBSA triethanolamine; N-lauroyl list sodium glutamate, N-stearyl disodium glutamate, N-tetradecanoyl-N-acyl glutamates such as L-sodium glutamate; Senior fatty acid ester sulfuric acids such as sclerosis coco-nut oil fatty acid glycerol sodium sulfate; POE alkyl ether carboxylic acid, POE alkyl allyl ether carboxylic acid, alpha-alkene sulfonate, higher fatty acids sulfonated ester, secondary alcohol sulfuric acid, higher fatty acids alkylolamides sulfuric acid, lauroyl single ethanol amide sodium succinate, the two triethanolamine of N-hexadecanoyl aspartic acid, casein sidium etc.
Wherein, POE alkyl ether phosphate salts such as N-stearyl-N methyl taurine sodium, N-hexadecanoyl-N methyl taurine sodium, N-tetradecanoyl-N methyl taurine sodium, coco-nut oil fatty acid N-methyltaurine sodium, dodecyl methyl sodium taurocholate, POE lauryl ether sodium phosphate, POE myristyl ether sodium phosphate, POE cetyl ether sodium phosphate, POE oleyl ether sodium phosphate, POE stearyl ether sodium phosphate etc. can improve the long-time stability of liquid make-up.Described material can select one or more to be used in combination as required.
With respect to the gross mass of liquid make-up, the content of described composition (d) is preferably 0.001～5%, and more preferably 0.01～3%.In this scope, can improve the stability of liquid make-up.
Liquid make-up of the present invention is owing to contain composition (a)～(c), and has stability.When the dispersant liquid drop mean diameter of composition (b) lubricant is 0.5 μ m or below the 0.5 μ m, more preferably during 0.05～0.3 μ m, can advance～go on foot the long-time stability that improve liquid make-up of the present invention.Described small dispersant liquid drop can obtain with following condensing method, but handles by high-pressure homogenizer, can obtain uniform more small dispersant liquid drop.The mean diameter of dispersant liquid drop is measured with COULTER NS-4 type (Coulter-counter society system).
The liquid condition of liquid make-up of the present invention is meant when using to have mobile state under general state, its viscosity number at 20 ℃ is 5～40,000mPa.s.Preferred 10～20,000mPa.s, preferred 10～5, in the time of in the 000mPa.s scope, can obtain desired liquid make-up with good usability.
There is no particular limitation to the compound method of liquid make-up of the present invention, can suitably select according to the formula property of cosmetics.Have for instance, surfactant and lubricant etc. is dissolved in the ethanol, and then be dispersed in the condensing method of preparing in the water; And the method etc. of utilizing the mechanical force preparation of high-pressure homogenizer etc.
Liquid make-up of the present invention can also be as medical exterior-applied article and topical drug etc. except can be used as cosmetics.The example of described cosmetics comprises, various liquid preparations such as astringent, beautifying liquid, fragrant composition.And described liquid make-up also can be made preparations such as spray, mousse by known method, and it is immersed on non-woven fabrics etc., makes the film like preparation.
In the scope that does not influence effect of the present invention, liquid make-up of the present invention can contain the composition that generally uses in the fields such as cosmetics, medical exterior-applied article and topical drug.For example, in addition non-ionic surface active agent of composition (a), wetting agent, polymer substance, UV absorbent, sequestering agent, nertralizer, pH regulator agent, antioxidant, antibacterial, antiseptic, pigment, powder body, pigment, spice, drug effect agent etc. can suitably be used as required.
The specific embodiment
[embodiment]
The following examples illustrate the present invention in further detail, but the present invention is not limited to these embodiment.
Embodiment 1～15 and comparative example 1～7; Astringent
Prepare the astringent of shown in table 1, table 2 (embodiment) and table 3 (comparative example), forming, and the mean diameter of long-time stability, usability and emulsion droplet is estimated.
Table 1
| Composition | Embodiment (%) | |||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | ||
| 1 | Polyoxyethylene (5) cholesterol ether | 1 | 1 | 1 | 1 | 1 | 0.5 | 0.1 | 0.05 | 0.05 |
| 2 | Single oleic acid polyoxyethylene (20) sorbitol ester | - | - | - | - | - | - | - | - | - |
| 3 | Sesquialter oleic acid sorbitol ester | - | - | - | - | - | - | - | - | - |
| 4 | Polyoxyethylene (20) hardened castor oil | - | - | - | - | - | - | - | - | - |
| 5 | Three (2 ethyl hexanoic acid) glyceride | 0.05 | 0.1 | 0.5 | 1 | 5 | 0.1 | 0.1 | 0.1 | 1 |
| 6 | Ethanol | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 |
| 7 | Glycerol | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
| 8 | Polyoxyethylene (8) alkyl (C12-18) ether phosphoric acid sodium | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 |
| 9 | The L-magnesium ascorbyl phosphate | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| 10 | Sodium citrate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 11 | Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
| Composition (a)/composition (b) ratio | 20/1 | 10/1 | 2/1 | 1/1 | 1/5 | 5/1 | 1/1 | 1/2 | 1/20 | |
| Composition (b)/composition (c) ratio | 1/12 | 1/6 | 5/6 | 10/6 | 50/6 | 1/6 | 1/6 | 1/6 | 10/6 | |
| Estimate | Mean diameter | ◎ | ◎ | ◎ | ○ | ○ | ◎ | ○ | ◎ | ○ |
| Usability | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | |
| Long-time stability | ◎ | ◎ | ◎ | ○ | ○ | ◎ | ◎ | ○ | ◎ | |
Table 2
| Composition | Embodiment (%) | ||||||
| 10 | 11 | 12 | 13 | 14 | 15 | ||
| 1 | Polyoxyethylene (5) cholesterol ether | 1 | 1 | 1 | 1 | 1 | 1 |
| 2 | Single oleic acid polyoxyethylene (20) sorbitol ester | - | - | - | - | - | - |
| 3 | Sesquialter oleic acid sorbitol ester | - | - | - | - | - | - |
| 4 | Polyoxyethylene (20) hardened castor oil | - | - | - | - | - | - |
| 5 | Three (2 ethyl hexanoic acid) glyceride | 0.1 | 0.1 | 0.5 | 0.5 | 0.1 | 0.5 |
| 6 | Ethanol | 10 | 10 | 10 | 10 | 10 | 10 |
| 7 | Glycerol | 5 | 5 | 5 | 5 | 5 | 5 |
| 8 | Polyoxyethylene (8) alkyl (C12-18) ether phosphoric acid sodium | 0.02 | 0.02 | 0.02 | 0.02 | - | - |
| 9 | The L-magnesium ascorbyl phosphate | 1 | 3 | 1 | 3 | 0.5 | 0.5 |
| 10 | Sodium citrate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 11 | Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
| Composition (a)/composition (b) ratio | 10/1 | 10/1 | 2/1 | 2/1 | 10/1 | 2/1 | |
| Composition (b)/composition (c) ratio | 1/11 | 1/31 | 5/11 | 5/31 | 1/11 | 5/11 | |
| Estimate | Mean diameter | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ |
| Usability | ○ | ○ | ○ | ○ | ◎ | ◎ | |
| Long-time stability | ◎ | ◎ | ◎ | ◎ | ○ | ○ | |
Table 3
| Composition | Comparative example (%) | |||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | ||
| 1 | Polyoxyethylene (5) cholesterol ether | - | - | - | - | 0.002 | 3 | 1 |
| 2 | Single oleic acid polyoxyethylene (20) sorbitol ester | - | 1 | 0.5 | - | - | - | - |
| 3 | Sesquialter oleic acid sorbitol ester | - | - | 0.5 | 0.5 | 1 | - | - |
| 4 | Polyoxyethylene (20) hardened castor oil | - | - | - | 0.5 | - | - | - |
| 5 | Three (2 ethyl hexanoic acid) glyceride | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | - |
| 6 | Ethanol | 10 | 10 | 10 | 10 | 10 | 10 | 10 |
| 7 | Glycerol | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
| 8 | Polyoxyethylene (8) alkyl (C12-18) ether phosphoric acid sodium | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 |
| 9 | The L-magnesium ascorbyl phosphate | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| 10 | Sodium citrate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 11 | Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
| Composition (a)/composition (b) ratio | - | - | - | - | 1/50 | 30/1 | - | |
| Composition (a)/composition (b) ratio | 1/6 | 1/6 | 1/6 | 1/6 | 1/6 | 1/6 | - | |
| Estimate | Mean diameter | × | ◎ | ◎ | × | △ | ○ | ◎ |
| Usability | ○ | △ | ○ | △ | ○ | × | × | |
| Long-time stability | × | × | × | × | △ | ◎ | ◎ | |
Preparation method
A: with composition 1～8 at 40 ℃ of mixed dissolutions.
B: composition 9～11 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining astringent.
Evaluation methodology 1: long-time stability
The astringent that obtains was placed for two weeks in 50 ℃ temperature chamber, and bore hole is observed cosmetic variation such as having or not separation.
[evaluation]
◎: do not have cosmetic variation fully.
Zero: almost do not have cosmetic variation.
△: cosmetic variation such as separation occur.
*: cosmetic variation such as separation are remarkable.
Evaluation methodology 2: usability
Usability (clearly feeling, have or not the sensation that is clamminess) when being coated in astringent on the skin by 10 professional judges' evaluations, following commentary price card is accurate to divide 5 ranks, and judges according to its average mark.
5 minutes: very good
4 minutes: good
3 minutes: general
2 minutes: bad
1 minute: very bad
[judgement]
◎: average mark is more than 4.5 minutes
Zero: average mark 3.5 minutes～4.5 minutes
△: average mark 2.5 minutes～3.5 minutes
*: average mark is below 2.5 minutes
Evaluation methodology 3: mean diameter
To the astringent of firm preparation, with COULTER NS-4 type (Coulter-counter society system), measure the mean diameter of emulsion droplet, estimate with following evaluation criterion.
[evaluation]
◎: 0.3 μ m or below the 0.3 μ m
○：0.3μm～0.5μm
△：0.5μm～5.0μm
*: more than the 5.0 μ m
The result who obtains by above evaluation methodology is shown in table 1～table 3.
Shown in the result of table 1 and table 2, the astringent of the embodiment of the invention 1～15 has used water solublity L-magnesium ascorbyl phosphate even mix, and also can obtain good surface appearance and have long-time stability and good usability.In contrast, the comparative example of table 3 can not be met the astringent of all assessment items.
Embodiment 16: astringent
(composition) (%)
1, polyoxyethylene (5) cholesterol ether 0.03
2, polyoxyethylene (10) cholesterol ether 0.03
3, polyoxyethylene (6) alkyl (C12-18) ether phosphoric acid sodium 0.02
4, four (2 ethyl hexanoic acid) five erithritol esters 0.05
5, three (2 ethyl hexanoic acid) glyceride 0.05
6, four (2-hexyldecanoic acid) acid ascorbyl ester 0.01
7, vitamin e acetate 0.01
8, ethanol 5.0
9,1,3 butylene glycol 10.0
10, the L-magnesium ascorbyl phosphate 3.0
11, sodium citrate 0.5
12, sodium ethylene diamine tetracetate (EDT) 0.03
13, Radix Scutellariae extract 0.01
14, the Radix Ginseng extractive solution 0.01
15, sweet amino castor oil acid disodium 0.01
16, phenyl phenol 0.01
17, Garden lavender water 10.0
18, the L-serine 0.1
19, antiseptic is an amount of
20, pure water surplus
Preparation method
A: with composition 1～8 at 40 ℃ of mixed dissolutions.
B: composition 9～20 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining astringent.
The astringent of embodiment 16 is that the mean diameter of the dispersant liquid drop of lubricant is 0.3 μ m or the 0.3 μ m astringent that is clamminess and feels few, have long-time stability following, that produced by water solublity L-magnesium ascorbyl phosphate.
Embodiment 17: astringent
(composition) (%)
1, polyoxyethylene (10) plant sterol ether 0.1
2, polyoxyethylene (20) hardened castor oil 0.05
3, polyoxyethylene (6) alkyl (C12-18) ether phosphoric acid sodium 0.1
4, Jojoba oil 0.2
5, NPDC 0.2
6, the oil-soluble Herba Rosmarini Officinalis extract 0.01
7, vitamin E Nicotinate 0.01
8, ethanol 10.0
9, glycerol 10.0
10, polyoxyethylene (10) methyl glucoside 3.0
11, sodium citrate 0.5
12, sodium ethylene diamine tetracetate (EDT) 0.03
13, Semen Coicis extract 0.01
14,2-hydroxyl-4-methoxy benzophenone-5-sodium sulfonate 0.01
15, the L-magnesium ascorbyl phosphate 1.0
16, methyl parahydroxybenzoate 0.01
17, sodium pyroglutamate 0.2
18, sodium lactate 0.1
19, hyaluronate sodium 2.0
20, pure water surplus
Preparation method
A: with composition 1～8 at 40 ℃ of mixed dissolutions.
B: composition 9～20 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining astringent.
The astringent of embodiment 17 is that the dispersant liquid drop mean diameter of lubricant is below 0.3 μ m or the 0.3 μ m, few by the sensation that is clamminess of water solublity L-magnesium ascorbyl phosphate generation, as to have abundant moisture feeling and long-time stability astringent.
Embodiment 18: beautifying liquid
(composition) (%)
1, polyoxyethylene (5) cholestane alcohol ether 1.0
2, polyoxyethylene (30) cholestane alcohol ether 0.03
3, the hydrogenation soybean phospholipid 0.5
4, ceramide III 0.01
5, three (2 ethyl hexanoic acid) glyceride 0.05
6, the oil-soluble Radix Glycyrrhizae extract 0.01
7, vitamin A palmitate 0.01
8, dipropylene glycol 5.0
9, pure water 20.0
10, L-ascorbic acid sodium sulfate 0.3
11, sodium citrate 0.05
12, citric acid 0.01
13,1% carboxyl ethylene polymer aqueous solution 15.0
14, polyoxyethylene glycol 400 1.0
15, diglycerol 5.0
16,1% (folder) oxa-grace robber cement solution 3.0
17, aminomethyl propanol 0.3
18, spherical nylon powder 1.0
19, antiseptic is an amount of
20, pure water surplus
Preparation method
A: with composition 1～8 at 85 ℃ of mixed dissolutions.
B: 85 ℃ of heating, and the limit is fully stirred to wherein adding A in the limit with composition 9.
C: cooling B, carry out corpusculed by high-pressure homogenizer.
D: with composition 10～20 mixed dissolutions.
E: in D, add C, mix obtaining beautifying liquid.
The beautifying liquid of embodiment 18 is that the dispersant liquid drop mean diameter of lubricant is 0.3 μ m or the 0.3 μ m beautifying liquid that is clamminess and feels few, have abundant moisture feeling, long-time stability and proper viscosity following, that produced by water solublity L-magnesium ascorbyl phosphate.
Embodiment 19: beautifying liquid
(composition) (%)
1, polyoxyethylene (10) cholesterol ether 0.05
2, the different hard ester ether 0.05 of polyoxyethylene (10)
3, polyoxyethylene (6) alkyl (C12-18) ether phosphoric acid sodium 0.1
4, four (2 ethyl hexanoic acid) five erithritol esters 0.05
5, methyl phenyl silicone 0.5
6, decamethylcyclopentasiloxane 0.1
7, natural Vitamin E 0.01
8, ethanol 5.0
9, glycerol 10.0
10, the L-magnesium ascorbyl phosphate 0.5
11, sodium lactate 0.5
12, lactic acid 0.03
13, chamomile extract 0.01
14, the oolong tea extracting solution 0.01
15,1% methylated cellulose aqueous solution 10.0
16,, Fructus cydoniae oblongae seed extracting solution 20.0
17, polyacrylamide 0.02
18, Macrogol 2000 0 0.5
19, antiseptic is an amount of
20, pure water surplus
Preparation method
A: with composition 1～8 at 40 ℃ of mixed dissolutions.
B: composition 9～20 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining beautifying liquid.
The beautifying liquid of embodiment 19 be the dispersant liquid drop mean diameter of lubricant be 0.5 μ m or 0.5 μ m following, feel few by being clamminess of producing of water solublity L-magnesium ascorbyl phosphate, have the beautifying liquid of abundant moisture feeling and long-time stability.
Embodiment 20: the cleaning astringent
(composition) (%)
1, polyoxyethylene (5) cholesterol ether 0.03
2, polyoxyethylene (20) hardened castor oil 0.03
3, polyoxyethylene (8) alkyl (C12-18) ether phosphoric acid sodium 0.02
4, four (2 ethyl hexanoic acid) five erithritol esters 0.1
5, the p-methoxycinnamic acid monooctyl ester 0.05
6, polyoxyethylene (5) dodecyl diglycollic amide 0.02
7, sweet amino castor oil acid stearyl ester 0.01
8, dehydrated alcohol 15.0
9, propylene glycol 2.0
10, the L-magnesium ascorbyl phosphate 2.0
11, sodium citrate 0.5
12, sodium ethylene diamine tetracetate (EDT) 0.03
13, sodium hydrogen phosphate 0.01
14, the Radix Hamamelidis Mollis extracting solution 0.01
15, the crystalline cellulose powder 0.05
16, Kaolin 0.01
17, blue Hibisci Mutabilis water 10.0
18, acetylglutamate sodium 0.1
19, antiseptic is an amount of
20, pure water surplus
Preparation method
A: with composition 1～8 at 40 ℃ of mixed dissolutions.
B: composition 9～20 is dissolved in mixed at room temperature.
C: in B, add A, mix obtaining astringent.
The astringent of present embodiment is that mean diameter is 0.3 μ m or the 0.3 μ m astringent that is clamminess and feels few, have long-time stability following, that produced by water solublity L-magnesium ascorbyl phosphate.
As mentioned above, liquid make-up of the present invention not only has the whitening function of water solublity L-ascorbic acid derivates, and also has long-time stability and good usability under the situation that water solublity L-ascorbic acid derivates exists.
Claims (4)
1, liquid make-up is characterized in that, this liquid make-up contains the following ingredients (a)～(c) as neccessary composition:
(a) the average addition molal quantity of oxygen ethylene is 2～30 polyoxyethylene sterol derivative, and described polyoxyethylene sterol derivative is selected from polyoxyethylene cholesterol ether, polyoxyethylene plant sterol ether, polyoxyethylene dihydrocholesterol ether and polyoxyethylene cholestane alcohol ether;
(b) lubricant is selected from least a in the group of being made up of NPDC, three (2 ethyl hexanoic acid) glyceride, four (2 ethyl hexanoic acid) five erithritol esters, oil-soluble Herba Rosmarini Officinalis extract, Jojoba oil, methyl phenyl silicone, decamethylcyclopentasiloxane, fat soluble vitamin, oil-soluble Radix Glycyrrhizae extract, ceramide;
(c) water solublity L-Ascorbate;
And the mass ratio of composition (a) and composition (b) is 20: 1 to 1: 20, and the mass ratio of composition (b) and composition (c) is 1: 300 to 300: 1.
2, liquid make-up as claimed in claim 1, it is characterized in that the water solublity L-Ascorbate of described composition (c) is selected from least a in the group of being made up of L-sodium ascorbate, L-potassium ascorbate, L-Magnesium ascorbate, L-sodium ascorbyl phosphate, L-magnesium ascorbyl phosphate, L-sodium ascorbyl phosphate potassium, L-ascorbic acid sodium sulfate, L-ascorbic acid magnesium sulfate, L-ascorbic acid potassium sulfate.
3, liquid make-up as claimed in claim 1 is characterized in that, this liquid make-up also contains the anion surfactant as composition (d).
4, liquid make-up as claimed in claim 1, the dispersant liquid drop mean diameter that it is characterized in that described composition (b) lubricant are 0.5 μ m or below the 0.5 μ m.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002071117A JP2003267830A (en) | 2002-03-15 | 2002-03-15 | Liquid cosmetic |
| JP071117/2002 | 2002-03-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1444924A CN1444924A (en) | 2003-10-01 |
| CN1319510C true CN1319510C (en) | 2007-06-06 |
Family
ID=28035091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031193595A Expired - Lifetime CN1319510C (en) | 2002-03-15 | 2003-03-14 | Liquid cosmetic |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP2003267830A (en) |
| KR (1) | KR100985368B1 (en) |
| CN (1) | CN1319510C (en) |
| HK (1) | HK1058002A1 (en) |
| TW (1) | TW200303761A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5263940B2 (en) * | 2008-05-29 | 2013-08-14 | 株式会社 資生堂 | Topical skin preparation |
| JP5610746B2 (en) * | 2009-11-19 | 2014-10-22 | 花王株式会社 | Nonwoven impregnated cosmetics |
| JP5610745B2 (en) * | 2009-11-19 | 2014-10-22 | 花王株式会社 | Nonwoven impregnated cosmetics |
| JP2011178736A (en) * | 2010-03-03 | 2011-09-15 | Fancl Corp | Oil-in-water type emulsified composition |
| JP5074637B2 (en) * | 2010-10-29 | 2012-11-14 | 株式会社コーセー | Vesicle composition, external preparation for skin containing the same, and cosmetics |
| CN104940096B (en) * | 2015-07-27 | 2017-10-13 | 广西信业生物技术有限公司 | A kind of medical bio face cleaning dressing and preparation method thereof |
| JP6982697B2 (en) * | 2018-09-28 | 2021-12-17 | 株式会社マンダム | Composition for skin cosmetics |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1300215A (en) * | 1998-05-15 | 2001-06-20 | 昭和电工株式会社 | Preventives/remedies for skin diseases |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH035426A (en) * | 1989-06-02 | 1991-01-11 | Nippon Saafuakutanto Kogyo Kk | Stable electrolyte-containing lecithin dispersion |
| JPH082801B2 (en) * | 1989-11-09 | 1996-01-17 | 株式会社資生堂 | Transdermal absorption enhancer and skin external preparation |
| US5529769A (en) * | 1994-12-20 | 1996-06-25 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Cosmetic compositions containing betulinic acid |
| JP4406498B2 (en) * | 2000-07-10 | 2010-01-27 | ライオン株式会社 | Skin cosmetics |
-
2002
- 2002-03-15 JP JP2002071117A patent/JP2003267830A/en active Pending
-
2003
- 2003-03-04 TW TW092104512A patent/TW200303761A/en not_active IP Right Cessation
- 2003-03-13 KR KR1020030015582A patent/KR100985368B1/en active IP Right Grant
- 2003-03-14 CN CNB031193595A patent/CN1319510C/en not_active Expired - Lifetime
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- 2004-02-09 HK HK04100861A patent/HK1058002A1/en not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1300215A (en) * | 1998-05-15 | 2001-06-20 | 昭和电工株式会社 | Preventives/remedies for skin diseases |
Non-Patent Citations (1)
| Title |
|---|
| 一些新型非离子表面活性剂的制备和应用 梁梦兰，日用化学品科学，第23卷第增刊1期 2000 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1444924A (en) | 2003-10-01 |
| KR100985368B1 (en) | 2010-10-04 |
| TWI359031B (en) | 2012-03-01 |
| TW200303761A (en) | 2003-09-16 |
| JP2003267830A (en) | 2003-09-25 |
| KR20030074401A (en) | 2003-09-19 |
| HK1058002A1 (en) | 2004-04-30 |
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