CN1875915A - A water-resistant oil-in-water emulsion composition for personal care - Google Patents
A water-resistant oil-in-water emulsion composition for personal care Download PDFInfo
- Publication number
- CN1875915A CN1875915A CN 200610039874 CN200610039874A CN1875915A CN 1875915 A CN1875915 A CN 1875915A CN 200610039874 CN200610039874 CN 200610039874 CN 200610039874 A CN200610039874 A CN 200610039874A CN 1875915 A CN1875915 A CN 1875915A
- Authority
- CN
- China
- Prior art keywords
- water
- composition
- grams
- carbon number
- personal care
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses the oil emulsion composition, comprising emulsifying agent, grease or fat, thickening agent and water. The emulsifying agent is composed by A and B, the A is phosphoric acid ester surface active agent, and the B is non-ionic emulsifier: R4-O-(G1)a alkyl glycoside, (R5COO)b-G2 sugar esters, (R6COO)c-(G3)d glycerin fatty acid ester or polyglycerol fatty acid ester. The invention solves the problem of feeling oil, and the product is not easy to wash, so the product can be used to make sun-screening cosmetic product.
Description
Technical field
The present invention relates to a kind of personal care product's of being used for compositions, be specifically related to a kind of oil in water emulsion, be particularly suitable for as sun-proof or foundation cream series products.
Background technology
As everyone knows, water-resistance is for the personal care product, and particularly product such as sun care preparations or vanishing cream is very useful.
In the prior art, using the method for preparing water-in-oil emulsion to satisfy the requirement of product water-resistance such as sun-proof or foundation cream usually, promptly is disperse medium with oil, is decentralized photo with water, forms water-in-oil emulsion.For example, disclose a kind of emulsion powdery cream of water-in-oil type among the Chinese invention patent prospectus CN1471903A, disclose a kind of invert emulsion sunscreen composition among the Chinese invention patent application CN1543331A, etc.But along with the more and more diversified trend of sun-proof component, the stability of control water-in-oil emulsion becomes more and more difficult.Another kind method is to use film forming polymer or special oils and fats to satisfy the requirement of product water proofing properties such as sun-proof or foundation cream.
Above several method brings problem greasy and residual on the use feeling inevitably.Especially sunscreen product uses in summer usually, and this greasy and residual sensation can be brought discomfort to consumer.
Thereby people wish to obtain a kind of compositions that does not have greasy and residual sensation, with as sun-proof or foundation cream product, bring salubrious sensation to user, and are difficult for being rinsed out by water.With water is disperse medium, and oil is decentralized photo, forms oil-in-water emulsion, might obtain above-mentioned effect.For making dispersion stable, need to add emulsifying agent.In the prior art, when the preparation water-in-oil emulsion, usually add non-ionic surface active agent as emulsifying agent, and when the preparation oil-in-water emulsion, usually add ionic surfactant at a low price as emulsifying agent, yet, during personal care products such as, foundation cream sun-proof in preparation, need to add various ingredients, might cause the instability of dispersion.Therefore, when the preparation oil-in-water emulsion, seeking suitable emulsifying agent, so that the Emulsion that obtains both had a water resisting property, can form stable dispersion again, is the technical issues that need to address.
Summary of the invention
The object of the invention provides a kind of use in personal care oil in water emulsion compositions that has a water resisting property, so that when keeping the characteristic that is difficult for being rinsed out by water, bring salubrious sensation to user.
For achieving the above object, the technical solution used in the present invention is: a kind of use in personal care oil in water emulsion compositions that has a water resisting property, and it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent and water, described emulsifying agent is made of composition A and composition B, wherein
(1) composition A is a phosphate ester surfactants, is the mixture that phosphate monoester and di-phosphate ester are formed, and mixed proportion is 7: 3～9.5: 0.5 by weight;
The structural formula of described phosphate monoester is,
In the formula, R
1Alkyl or alkenyl for the straight or branched of carbon number 8-22;
X
1, X
2Be selected from the alkanolamine or the hydrogen atom of the straight or branched of alkali metal atom, alkaline earth metal atom, ammonium, carbon number 2-3 respectively;
M is 0～10 integer;
The structural formula of described di-phosphate ester is,
In the formula, R
2And R
3Be respectively the alkyl or alkenyl of the straight or branched of carbon number 8-22;
X
3Be selected from the alkanolamine or the hydrogen atom of the straight or branched of alkali metal atom, alkaline earth metal atom, ammonium, carbon number 2～3;
N, q are respectively 0～10 integer;
(2) composition B is one or more the mixture in the following nonionic emulsifier:
1. general formula is R
4-O-(G
1)
aThe alkyl polyglucoside class, in the formula, R
4The alkyl of expression carbon number 8～18, G
1The sugar unit of expression carbon number 5～6, a is 1～10 integer;
2. general formula is (R
5COO)
b-G
2Sugar esters, in the formula, R
5The alkyl or alkenyl of the straight or branched of expression carbon number 7～23, G
2The expression sugar unit, b is 1～5 integer, described sugar is selected from glucose, sucrose, methyl glucoside, mannitol, sorbitol or anhydrous sorbitol;
3. general formula is (R
6COO)
c-(G
3)
dFatty acid glyceride or polyglyceryl fatty acid ester class, in the formula, R
6The alkyl or alkenyl of the straight or branched of expression 7～21, G
3Expression glycerol unit, c is 1～10, d is≤integer of c+1.
Optimized technical scheme is, among the composition A, and described R
1, R
2And R
3Represent that respectively identical or different carbon number is that straight chained alkyl m, n, the q of 16-22 is 0～5 integer; M, n, q are 0 o'clock better (promptly not containing additional oxirane); The content of phosphate monoester is more than 75%.
Among the composition B, preferred R
4Be the alkyl of carbon number 12-18, G
1Be glucose unit, a is 2～5; R
5Be the alkyl or alkenyl of the straight or branched of carbon number 12-22, be more preferably the alkyl or alkenyl of the straight or branched of carbon number 16-20, G
2Be anhydrous sorbitol, b is 1～3; R
6Be the alkyl or alkenyl of the straight or branched of carbon number 12-22, be more preferably the alkyl or alkenyl of the straight or branched of carbon number 16-20, G
3Be glycerol residue, c is 2～4.
Composition A of the present invention can select the cetyl phosphate ester of Eleco company with " Romol AFS " name for use, perhaps, cetyl phosphate kalium salt with " Romol AFSK " name has contained the phosphate monoester and the di-phosphate ester that meet required ratio in the technical solution of the present invention in these series of products.
Composition B of the present invention optional kind is as glyceryl monostearate, the dimerization glyceryl stearate, the trimerization glyceryl stearate, the two stearates of two polyglycereol, the two stearates of three polyglycereol, two polyglycerol acrylate, three polyglycerol acrylate, the dimerization glycerin bi-fatty acid ester, the trimerization glycerin bi-fatty acid ester, the methyl glucoside stearate, sorbitan monooleate, the anhydrous sorbitol cetylate, Span60, alkyl polyglucoside, sucrose oleate, sucrose stearate or their mixture etc.
In the technique scheme, the content of described composition A is 0.1～8% of emulsion composition weight, and the content of described composition B is 0.1～8% of emulsion composition weight.
Optimized technical scheme, the content of composition A are 0.5～3% of emulsion composition weight, and the content of composition B is 0.5～3% of emulsion composition weight.
In the technique scheme, the hydrophile-lipophile balance value of described composition A 〉=10; The hydrophile-lipophile balance value of composition B≤8.Hydrophile-lipophile balance value (HLB) is used for representing molecule hydrophilic and the size of lipophilic two opposite groups and the balance of effect, is to be determined by the hydration in chemical constitution, polarity power or the molecule of molecule.The hydrophilic of the high expression of HLB value emulsifying agent is strong, otherwise, represent that then lipophile is strong.
In the technique scheme, described oils and fats or fatty material are selected from oils and fats, wax, higher fatty acids, high fatty alcohol, fatty acid ester, polysiloxanes and their mixture in animal, plant, mineral and synthetic source, and its content is 3～40% of emulsion composition weight.
Optionally kind is as mineral oil, fluorinated oil, natural or accumulated angle zamene, sad capric acid triglyceride, Oleum helianthi, Semen Maydis oil, Jojoba oil, Oleum Ricini, almond oil, American Avocado Tree oil, vaseline, isopropyl palmitate, isopropyl myristate, isononyl isononanoate, 2-octyl group dodecyl alcohol, stearyl alcohol, oleyl alcohol, the two stearates of season the eleventh of the twelve Earthly Branches tetrol, myristic acid, Palmic acid, stearic acid, mountain Yu acid, oleic acid, polydimethylsiloxane, the phenyl polydimethylsiloxane, Cera Flava, lanoline, hydrogenated lanolin, paraffin, ceresine, white beeswax, candelilla wax, Brazil wax, Japan wax, microwax, montan wax, Tissuemat E, and their mixture.
In the technique scheme, described thickening agent is at least a water-soluble polymer, be selected from plant gum class, animal glue class, microbiological gum class, cellulose family, starch based, polyacrylamide, polyvinyl pyrrolidone class, poly acrylic acid-poly methacrylic acid and copolymer thereof and their mixture, its content is 0.1～3% of emulsion composition weight.
Optionally kind is as arabic gum, tragacanth gum, guar gum, pectin, gelatin, HANSHENGJIAO, methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and sodium salt thereof, polyacrylamide, Polyethylene Glycol, polyvinyl pyrrolidone, poly acrylic acid-poly methacrylic acid and copolymer thereof, polymaleic anhydride, polysilicate and their mixture.
Further technical scheme also comprises the composition of at least a the following stated, i.e. pigment, essence, antiseptic, antioxidant, physical sunscreen agent or chemical sunscreen and their mixture.
Can also comprise other helper component, as: inorganic or organic filler, wetting agent and their mixture.
Wherein, inorganic or organic filler, pigment optionally as: Magnesiumaluminumsilicate, sodium lithium magnesium silicate, bentonite, montorillonite clay, titanium dioxide, zinc oxide, silicon dioxide, Pulvis Talci, mica powder, Bismuth Oxychloride, iron oxide black, iron oxide red, iron oxide yellow, ultramarine, manganese violet, chromium oxide, modified starch and their coating and mixture.
Physics or chemical sunscreen optionally comprise: the physical sunscreen agent is as nano titanium oxide, nano zine oxide; The chemistry sunscreen is as salicyclic acid derivatives, cinnamic acid derivative, benzophenone derivative, dibenzoyl methane derivant, para-amino benzoic acid derivant and their mixture.
The optional antiseptic of the present invention, wetting agent, antioxidant, essence etc. can be selected as general knowledge by those skilled in the art.
Because the technique scheme utilization, the present invention compared with prior art has following advantage:
1. owing to the invention provides a kind of oil in water emulsion, during as personal-care supplies, can solve the greasy and residual problem of feeling that available technology adopting water in oil emulsion, film forming polymer or special oils and fats bring, bring salubrious use feeling, be difficult for simultaneously being rinsed out by water.
The present invention preferably water-resistance enable to perspire or be retained on the skin during water flushing at human body, be particularly suitable for making sun care preparations or foundation cream class cosmetics.
The specific embodiment
Below in conjunction with embodiment the present invention is further described, but content of the present invention is not limited in these embodiment.
Embodiment one: a kind of vanishing cream that has a water resisting property, and it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent, other additive and water, described emulsifying agent is made of composition A and composition B, wherein,
Emulsifying agent composition A: cetyl phosphate ester potassium 3 grams
Emulsifying agent composition B: sorbitan monooleate 2.2 grams
Oils and fats and fatty material: white mineral oil 5.1 grams
Palmic acid 8.6 grams
Polydimethylsiloxane (350CS) 3.5 grams
Stearyl alcohol 4.5 grams
Thickening agent: Magnesiumaluminumsilicate 0.5 gram
HANSHENGJIAO 0.2 gram
Other additive: titanium dioxide 8 grams
Iron oxide red 1.15 grams
Iron oxide yellow 2.1 grams
Iron oxide black 0.08 gram
Antiseptic is an amount of
Octyl methoxycinnamate 4 grams
Propylene glycol 10.2 grams
Glycerol 2 grams
Add water to 100 grams.
According to above-mentioned prescription, prepare vanishing cream with conventional method.
The cosmetics of the usefulness that feels secure before vanishing cream is meant and is used to make up, it can make XIANGFEN firm attachment on skin, can hide the facial original colour of skin again, improves the texture of skin, makes the humorous beauty of cosmetic color harmony.The vanishing cream product requirement: similar with other cream, also should have careful appearance, exquisite quality, evenly has good spreadability.In addition, it should possess certain anti-water and anti-antiperspirant ability.
The vanishing cream product of present embodiment gained is applied to the left hand back of the body, and the water flushing is cleaned with the right hand simultaneously, can not remove the coating effect fully.Can obtain to reach one day persistency and good anti-water effect, it is salubrious to apply aftersensation simultaneously.
Embodiment two: a kind of vanishing cream that has a water resisting property, and it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent, other additive and water, described emulsifying agent is made of composition A and composition B, wherein,
Emulsifying agent composition A: myristyl phosphate ester potassium 3.2 grams
Emulsifying agent composition B: dodecyl poly glucoside 1.8 grams
Oils and fats and fatty material: white mineral oil 7.3 grams
Palmic acid 6.2 grams
Polydimethylsiloxane (350CS) 3 grams
Stearyl alcohol 4.5 grams
Thickening agent: Magnesiumaluminumsilicate 0.4 gram
HANSHENGJIAO 0.2 gram
Other additive: titanium dioxide 8 grams
Iron oxide red 1.15 grams
Iron oxide yellow 2.1 grams
Iron oxide black 0.08 gram
Antiseptic is an amount of
Octyl methoxycinnamate 3.5 grams
Propylene glycol 10 grams
Glycerol 2.5 grams
Add water to 100 grams.
According to above-mentioned prescription, prepare vanishing cream with conventional method.
Embodiment three: a kind of vanishing cream that has a water resisting property, and it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent, other additive and water, described emulsifying agent is made of composition A and composition B, wherein,
Emulsifying agent composition A: cetyl phosphate ester potassium 2 grams
Myristyl phosphate ester potassium 1.2 grams
Emulsifying agent composition B: single glyceryl stearate 2.5 grams
Oils and fats and fatty material: white mineral oil 4.2 grams
Palmic acid 10.2 grams
Polydimethylsiloxane (350CS) 3 grams
Stearyl alcohol 4.5 grams
Thickening agent: Magnesiumaluminumsilicate 0.4 gram
HANSHENGJIAO 0.2 gram
Other additive: titanium dioxide 8 grams
Iron oxide red 1.15 grams
Iron oxide yellow 2.1 grams
Iron oxide black 0.08 gram
Antiseptic is an amount of
Octyl methoxycinnamate 4.2 grams
Propylene glycol 10.2 grams
Glycerol 3 grams
Add water to 100 grams.
According to above-mentioned prescription, prepare vanishing cream with conventional method.
Embodiment four: a kind of ultra light sun block lotion, and it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent, other additive and water, described emulsifying agent is made of composition A and composition B, wherein,
Emulsifying agent composition A: cetyl phosphate ester 3 grams
Emulsifying agent composition B: Span60 1.2 grams
Sucrose oleate 0.05 gram
Dimerization glyceryl stearate 1 gram
Sad capric acid triglyceride 1.8 grams
Oils and fats and fatty material: isononyl isononanoate 2.1 grams
Mountain Yu acid 0.2 gram
Ethylhexyl salicylate 3 grams
C12-15 benzoate 5 grams
Phenyl polydimethylsiloxane 1 gram
Vitamin E acetate 0.6 gram
Thickening agent: polyisobutylene 2 grams
Hydroxyethyl-cellulose 0.1 gram
Other additive: triethanolamine 0.56 gram
Nano titanium oxide 2.5 grams
Nanometer titanium dioxide zinc 1.5 grams
Cover holder soil 0.3 gram
Benzophenone-3 1.2 gram
1,3 butanediol, 4 grams
Propylene glycol 2.5 grams
Disodiumedetate 0.01 gram
Essence is an amount of
Add water to 100 grams.
According to above-mentioned prescription, prepare ultra light sun block lotion with conventional method.The gained ultra light sun block lotion is applied to the left hand back of the body, and the water flushing is cleaned with the right hand simultaneously, and flush away and sun-proof result is decreased can obtain to reach one day sun-proof result, and sensation is salubrious easily.
Embodiment five: a kind of ultra light sun block lotion, and it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent, other additive and water, described emulsifying agent is made of composition A and composition B, wherein,
Emulsifying agent composition A: stearyl phosphate ester 2.8 grams
Emulsifying agent composition B: Span60 1.5 grams
Dodecyl poly glucoside 0.5 gram
Sad capric acid triglyceride 1.6 grams
Oils and fats and fatty material: isononyl isononanoate 2.1 grams
Mountain Yu acid 0.2 gram
Ethylhexyl salicylate 3 grams
C12-15 benzoate 5 grams
Phenyl polydimethylsiloxane 1.5 grams
Vitamin E acetate 0.6 gram
Thickening agent: polyisobutylene 2 grams
Hydroxyethyl-cellulose 0.1 gram
Other additive: triethanolamine 0.56 gram
Nano titanium oxide 2.5 grams
Nanometer titanium dioxide zinc 1.5 grams
Cover holder soil 0.3 gram
Benzophenone-3 1.2 gram
1,3 butanediol, 3.2 grams
Propylene glycol 3 grams
Disodiumedetate 0.01 gram
Essence is an amount of
Add water to 100 grams.
According to above-mentioned prescription, prepare ultra light sun block lotion with conventional method.
Embodiment six: a kind of ultra light sun block lotion, and it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent, other additive and water, described emulsifying agent is made of composition A and composition B, wherein,
Emulsifying agent composition A: cetyl phosphate ester 1.8 grams
Stearyl phosphate ester 1.1 grams
Emulsifying agent composition B: Span60 0.8 gram
Dimerization glyceryl stearate 1.5 grams
Sad capric acid triglyceride 1.6 grams
Oils and fats and fatty material: isononyl isononanoate 2.1 grams
Mountain Yu acid 0.2 gram
Ethylhexyl salicylate 3 grams
C12-15 benzoate 5 grams
Phenyl polydimethylsiloxane 1.2 grams
Vitamin E acetate 0.6 gram
Thickening agent: polyisobutylene 2 grams
Hydroxyethyl-cellulose 0.1 gram
Other additive: triethanolamine 0.56 gram
Nano titanium oxide 2.5 grams
Nanometer titanium dioxide zinc 1.5 grams
Cover holder soil 0.3 gram
Benzophenone-3 1.2 gram
1,3 butanediol, 4 grams
Propylene glycol 2.8 grams
Disodiumedetate 0.01 gram
Essence is an amount of
Add water to 100 grams.
According to above-mentioned prescription, prepare ultra light sun block lotion with conventional method.
Claims (6)
1. use in personal care oil in water emulsion compositions that has a water resisting property, it comprises emulsifying agent, at least a oils and fats or fatty material, thickening agent and water, it is characterized in that: described emulsifying agent is made of composition A and composition B, wherein,
(1) composition A is a phosphate ester surfactants, is the mixture that phosphate monoester and di-phosphate ester are formed, and mixed proportion is 7: 3～9.5: 0.5 by weight;
The structural formula of described phosphate monoester is,
In the formula, R
1Alkyl or alkenyl for the straight or branched of carbon number 8-22;
X
1, X
2Be selected from the alkanolamine or the hydrogen atom of the straight or branched of alkali metal atom, alkaline earth metal atom, ammonium, carbon number 2-3 respectively;
M is 0～10 integer;
The structural formula of described di-phosphate ester is,
In the formula, R
2And R
3Be respectively the alkyl or alkenyl of the straight or branched of carbon number 8-22;
X
3Be selected from the alkanolamine or the hydrogen atom of the straight or branched of alkali metal atom, alkaline earth metal atom, ammonium, carbon number 2～3;
N, q are respectively 0～10 integer;
(2) composition B is one or more the mixture in the following nonionic emulsifier:
1. general formula is R
4-O-(G
1)
aThe alkyl polyglucoside class, in the formula, R
4The alkyl of expression carbon number 8～18, G
1The sugar unit of expression carbon number 5～6, a is 1～10 integer;
2. general formula is (R
5COO)
b-G
2Sugar esters, in the formula, R
5The alkyl or alkenyl of the straight or branched of expression carbon number 7～23, G
2The expression sugar unit, b is 1～5 integer, described sugar is selected from glucose, sucrose, methyl glucoside, mannitol, sorbitol or anhydrous sorbitol;
3. general formula is (R
6COO)
c-(G
3)
dFatty acid glyceride or polyglyceryl fatty acid ester class, in the formula, R
6The alkyl or alkenyl of the straight or branched of expression 7～21, G
3Expression glycerol unit, c is 1～10, d is≤integer of c+1.
2. the use in personal care oil in water emulsion compositions that has a water resisting property according to claim 1, it is characterized in that: the content of described composition A is 0.1～8% of emulsion composition weight, the content of described composition B is 0.1～8% of emulsion composition weight.
3. the use in personal care oil in water emulsion compositions that has a water resisting property according to claim 1 is characterized in that: the hydrophile-lipophile balance value of described composition A 〉=10; The hydrophile-lipophile balance value of composition B≤8.
4. the use in personal care oil in water emulsion compositions that has a water resisting property according to claim 1, it is characterized in that: described oils and fats or fatty material are selected from oils and fats, wax, higher fatty acids, high fatty alcohol, fatty acid ester, polysiloxanes and their mixture in animal, plant, mineral and synthetic source, and its content is 3～40% of emulsion composition weight.
5. the use in personal care oil in water emulsion compositions that has a water resisting property according to claim 1, it is characterized in that: described thickening agent is at least a water-soluble polymer, be selected from plant gum class, animal glue class, microbiological gum class, cellulose family, starch based, polyacrylamide, polyvinyl pyrrolidone class, poly acrylic acid-poly methacrylic acid and copolymer thereof and their mixture, its content is 0.1～3% of emulsion composition weight.
6. according to arbitrary described use in personal care oil in water emulsion compositions that has a water resisting property in the claim 1 to 5, it is characterized in that: also comprise the composition of at least a the following stated, i.e. pigment, essence, antiseptic, antioxidant, physical sunscreen agent or chemical sunscreen and their mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100398743A CN100539986C (en) | 2006-04-20 | 2006-04-20 | A kind of use in personal care oil in water emulsion compositions that has a water resisting property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100398743A CN100539986C (en) | 2006-04-20 | 2006-04-20 | A kind of use in personal care oil in water emulsion compositions that has a water resisting property |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1875915A true CN1875915A (en) | 2006-12-13 |
| CN100539986C CN100539986C (en) | 2009-09-16 |
Family
ID=37508591
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100398743A Active CN100539986C (en) | 2006-04-20 | 2006-04-20 | A kind of use in personal care oil in water emulsion compositions that has a water resisting property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100539986C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102058489A (en) * | 2010-11-22 | 2011-05-18 | 苏州元素集化学工业有限公司 | Stiff cleaning composite |
| CN102366384A (en) * | 2011-09-27 | 2012-03-07 | 沈志荣 | Skin-refreshing face-repairing cream composition and preparation method thereof |
| CN104367485A (en) * | 2014-07-26 | 2015-02-25 | 张家港格瑞特化学有限公司 | Composite emulsifier and preparation method thereof |
| US9655821B2 (en) | 2013-04-05 | 2017-05-23 | The Procter & Gamble Company | Personal care composition comprising a pre-emulsified formulation |
| US9993404B2 (en) | 2015-01-15 | 2018-06-12 | The Procter & Gamble Company | Translucent hair conditioning composition |
| CN108635244A (en) * | 2011-06-07 | 2018-10-12 | 拜尔斯道夫股份有限公司 | Use of polyglycerol-10 stearate in sunscreen formulations to increase contact angle and thereby improve water resistance |
| US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
| US10912723B2 (en) | 2016-01-20 | 2021-02-09 | The Procter And Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
-
2006
- 2006-04-20 CN CNB2006100398743A patent/CN100539986C/en active Active
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102058489B (en) * | 2010-11-22 | 2014-09-24 | 苏州元素集化学工业有限公司 | Stiff cleaning composite |
| CN102058489A (en) * | 2010-11-22 | 2011-05-18 | 苏州元素集化学工业有限公司 | Stiff cleaning composite |
| CN108635244A (en) * | 2011-06-07 | 2018-10-12 | 拜尔斯道夫股份有限公司 | Use of polyglycerol-10 stearate in sunscreen formulations to increase contact angle and thereby improve water resistance |
| CN108635244B (en) * | 2011-06-07 | 2023-07-14 | 拜尔斯道夫股份有限公司 | Use of polyglycerol-10 stearate in sunscreen formulations to improve contact angle and thus water resistance |
| CN102366384A (en) * | 2011-09-27 | 2012-03-07 | 沈志荣 | Skin-refreshing face-repairing cream composition and preparation method thereof |
| CN102366384B (en) * | 2011-09-27 | 2013-04-10 | 沈志荣 | Skin-refreshing face-repairing cream composition and preparation method thereof |
| CN103211738A (en) * | 2011-09-27 | 2013-07-24 | 沈志荣 | Beautifying and grooming cream composition containing peony root extractive and pearl powder |
| CN103211728A (en) * | 2011-09-27 | 2013-07-24 | 沈志荣 | Beautifying and grooming cream composition containing Saussurea involucrate extractive and bermuda lily extractive |
| CN103211738B (en) * | 2011-09-27 | 2015-08-26 | 浙江欧诗漫生物股份有限公司 | A kind of shining face containing peony root extractive and Margarita powder repaiies the preparation method holding cream composition |
| CN103211728B (en) * | 2011-09-27 | 2015-09-16 | 浙江欧诗漫生物股份有限公司 | A kind of shining face containing Herba Saussureae Involueratae and bermuda lily flower extract repaiies appearance cream composition |
| US9655821B2 (en) | 2013-04-05 | 2017-05-23 | The Procter & Gamble Company | Personal care composition comprising a pre-emulsified formulation |
| CN104367485A (en) * | 2014-07-26 | 2015-02-25 | 张家港格瑞特化学有限公司 | Composite emulsifier and preparation method thereof |
| US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
| US9993404B2 (en) | 2015-01-15 | 2018-06-12 | The Procter & Gamble Company | Translucent hair conditioning composition |
| US10912723B2 (en) | 2016-01-20 | 2021-02-09 | The Procter And Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100539986C (en) | 2009-09-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1283223C (en) | Water-in-oil emulsion cosmetic composition | |
| CN1104890C (en) | Transparent ultramicro oil water emulsion using fluid non-ion amphiphilic lipid as main component and its applications in cosmetics and skin medicine | |
| CN1875915A (en) | A water-resistant oil-in-water emulsion composition for personal care | |
| CN1170517C (en) | Water-containing powder composition process for producing same and cosmetic preparation containing powder composition | |
| CN1094342C (en) | Cosmetic preparation with peptide addition | |
| CN1237956C (en) | Water in oil emulsion powdery cream | |
| CN1106661A (en) | Preparation for epidermis and process for its preparation | |
| CN1136832C (en) | Wrinkling modifiers | |
| CN100346765C (en) | Emulsion composition | |
| CN1241536C (en) | Humectant and cosmetics and external prepan. contg. same | |
| CN1106660A (en) | Preparation for epidermis and process for its preparation | |
| CN1665478A (en) | Vesicle dispersion and cosmetic containing the same | |
| CN1835732A (en) | Water-in-oil emulsion foundation comprising a polyol | |
| CN1784205A (en) | Lipid composition and skin care formulation containing the same | |
| CN1199608A (en) | Water-in-oil emulsion, composition comprising such emulsion and use in cosmetics pharmacy or hygiene | |
| CN101052369A (en) | Cosmetics refrigerant composition | |
| CN1172641A (en) | Ultraviolet absorbing composition | |
| CN1173321A (en) | Ester in application of powder-stuck composition and compact powdered anhydrous composition | |
| CN1668270A (en) | Powder-containing oil-in-water emulsified composition | |
| CN1753655A (en) | O/w emulsifier and o/w emulsions containing potassium cetyl phosphate and method for the production thereof | |
| CN1946770A (en) | Aqueous dispersions of silicone polyether block copolymers | |
| CN1106659A (en) | Preparation for epidermis and process for its preparation | |
| CN101032451A (en) | Microemulsion skin whitening cosmetics and preparing method thereof | |
| CN1509179A (en) | External skin composition | |
| CN1081876A (en) | Whitening embellisher |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |