CN1679500A - Liquid cosmetics - Google Patents
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Abstract
To easily prepare a cloudy liquid cosmetic excellent in long-term stability and vibration or shaking stability and yielding refreshing touch feeling in use and skin-ameliorating effect. This liquid cosmetic is obtained by compounding together (a) 0.01-2 mass% of an isostearic acid-containing oily component, (b) 0.04-1.0 mass% of a hydrophilic activator selected from polyoxyethylene (30) phytosterol, polyoxyethylene octyl dodecyl ether, polyoxyethylene polyoxypropylene decyl tetradecyl ether and polyoxyethylene hydrogenated castor oil and (c) 0.01-0.75 mass% of a lipophilic activator selected from sorbitan sesquisostearate and polyoxyethylene methylpolysiloxane copolymer.
Description
Technical field
The present invention relates to liquid cosmetic preparation, be in more detail, relate to the watery liquid cosmetic preparation of the light cosmetic of nebulousurine shape.
Technical background
In recent years, with oiliness composition corpusculed be the cosmetics of nebulousurine shape in appearance, give sensation with the skin gentleness, and, because of the usability that conforms with hobby being arranged and having realized that the effect of improving skin widely liked by people, not only, also be widely used for the whole body nursing product with being skin care item.
But, for example, by oiliness composition or oil-soluble medicament ultramicronization being expected higher percutaneous permeability and improve in the cosmetics of skin effects almost do not have excellent ageing stability, the nebulousurine shape cosmetics that can make easily.Particularly, if want to use the high-pressure emulsification machine that oiliness composition corpusculed is made nebulousurine shape cosmetics, then must not only need long manufacturing time, and manufacture be also restricted through high-pressure emulsification machine processing many times.In addition, the method of using specific surfactant to make nebulousurine shape cosmetics is easily also arranged, (for example patent documentation 1,2), though good long term stability is arranged under static condition, but the phenomenon that translucence changes takes place in the vibration or the vibration of user between the operating period that produce owing to the transportation till taking in the hands up to user, often causes losing the shortcoming of commodity value.In addition, though know the nebulousurine shape astringent that oiliness stable components ground cooperates, can obtain salubrious usability, but in order in astringent, stably to cooperate the oiliness composition, the use level that needs the adjustment form surface-active agent, though, cause producing because of this surfactant and be clamminess along with the amount of surfactant increases the oiliness composition increase that may cooperate.
Therefore, be difficult to modulation with prior art and not only suppressed the use level of surfactant but also can stably cooperate the oiliness composition, salubrious usability is arranged, L-value is about 40 nebulousurine shape astringent.
[patent documentation 1] spy opens clear 63-132813 communique
[patent documentation 2] spy opens clear 64-047710 communique
Summary of the invention
The present invention is the invention of making in order to solve aforesaid existing situation, its purpose is to provide long-time stability and excellent vibration or oscillatory stability, have salubrious usability and the effect of improving skin, and, the nebulousurine liquid cosmetic preparation that can make easily.
Liquid cosmetic preparation of the present invention is characterized in that containing following (a)～(c) composition,
(a) the oiliness composition of 0.01～2 quality %, wherein, containing with respect to whole oiliness composition quality percentage ratios in this oiliness composition is 34% or isostearic acid more than it;
(b) the hydrophilic active agent of 0.04～1.0 quality %, wherein, this hydrophilic active agent is selected from polyoxyethylene (30) plant sterol, polyoxyethylene octyl group lauryl ether, polyoxyethylene polyoxypropylene decyl myristyl ether and polyoxyethylene hardened castor oil;
(c) the lipophile activating agent of 0.001～0.75 quality %, wherein, this lipophile activating agent is selected from sesquialter isostearic acid sorbitan esters, polyoxyethylene methyl polysiloxane copolymer.
According to the present invention, can provide by the specific surfactant that cooperates specified quantitative, be difficult to so far syntheticly not only suppress the amount of surfactant but also stably cooperated many oiliness compositions, L-value 40 or its following nebulousurine shape cosmetics.Among the present invention, further preferably contain (d) isooctadecanol.
Liquid cosmetic preparation of the present invention is a nebulousurine shape liquid cosmetic preparation, and its emulsified particle is 100～500nm directly, is preferably 100～300nm.
According to the present invention, long-time stability and excellent vibration or oscillatory stability can be provided, have salubrious usability and the effect of improving skin, and, the nebulousurine liquid cosmetic preparation that can make easily.
Specific embodiments
Below, optimum implementation of the present invention is described.
(a) oiliness composition
In the present invention, isostearic acid is as using by composition.With respect to whole oiliness compositions, the use level of isostearic acid is 34 quality % or more than it, also can only use isostearic acid as the oiliness composition.The use level of isostearic acid is separated during with respect to oiliness composition less than 34 quality %.
Other oiliness composition that is used for liquid cosmetic preparation of the present invention so long as getting final product of can cooperating in cosmetics has no particular limits, can be from crude, also can be synthetic material, can be that liquid also can be solid.
For example, can enumerate American Avocado Tree oil, Camellia oil, Oleum Testudinis, macadimia nut oil, Semen Maydis oil, ermine oil, olive oil, Oleum Brassicae campestris, egg oil, Oleum sesami, almond oil, Semen Tritici aestivi germ oil, Flos Camelliae Japonicae caul-fat, Oleum Ricini, Semen Lini oil, safflower oil, Oleum Gossypii semen, perilla oil, soybean oil, Oleum Arachidis hypogaeae semen, Oleum Camelliae, Chinese torreya oil, Testa oryzae oil, Paulownia oil, Japanese tung oil, Jojoba oil, germ oil, three isooctyl acid glyceride, three different tripalmitins, different octyl palmitate, the isostearic acid isopropyl ester, isostearyl isostearate ester, the different cetyl of isostearic acid, the own ester of isostearic acid, the isostearic acid myristin, sad different cetyl, isooctyl acid cetyl, sad isooctadecanol ester, different isodecyl pelargonate, the misery basic lauryl of dimethyl-octa, myristic acid grease, erucic acid isooctadecanol ester, Standamul 7061, octyl stearate, Palmic acid isooctadecanol ester, the different cetyl of Palmic acid, octyl palmitate, myristic acid isooctadecanol ester, the different cetyl of myristic acid, myristic acid octyl group lauryl, myristic acid ester in the last of the ten Heavenly stems, isopropyl palmitate, isopropyl myristate, three isostearic acid trimethylolpropanes, two capric acid DOPCP, di-n-octyl sebacate, 12-stearoyl-oxy stearic acid octyl group lauryl, stearyl glutamic acid dioctyl lauryl, dioctyl adipate, malic acid two isooctadecanol esters, octyl methoxycinnamate, lactic acid octyl group lauryl, lactic acid isooctadecanol ester, the ESCAROL 507 monooctyl ester, liquid paraffin, squalane, isoparaffin, alpha-olefin low polymers, polybutene, volatile cyclic silicones, the volatility dimethyl polysiloxane, methyl phenyl siloxane, oleyl alcohol, the liquid fat of 2-octyldodecanol etc.; Cocoa butter, cocos nucifera oil, horse fat, sclerosis cocos nucifera oil, Petiolus Trachycarpi oil, Adeps Bovis seu Bubali, Adeps caprae seu ovis, sclerosis Adeps Bovis seu Bubali, palm kernel oil, Adeps Sus domestica, Os Bovis seu Bubali fat, haze tallow kernel oil, fixed oil, cattle foot fat, haze tallow, hardened castor oil, Cera Flava, candelilla wax, cotton wax, Brazil wax, Fructus Lauri nobilis wax, insect wax, spermaceti, montan wax, bran wax, lanoline, kapok wax, the acetic acid lanoline, liquid lanolin, Caulis Sacchari sinensis fat, lanolin fatty acid isopropyl ester, lauric acid hexyl ester, reduction lanoline, Jojoba wax, hard lanoline, shellac wax, cholesterol, plant sterol, microwax, tadenan, stearyl alcohol, spermol, behenic acid, stearic acid, the solid grease of myristic acid etc. and wax.These materials can be used alone, or with two kinds or be used in combination more than it.
In these oiliness compositions, particularly be used alone or as a mixture liquid paraffin, squalane, alpha-olefin low polymers, isoparaffin, the hydrocarbon ils of polybutene etc., or octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, the volatile cyclic silicones oil of tetradecamethylcycloheptasiloxane etc., decamethyl tetrasiloxane, ten dimethyl, five siloxanes, tetradecamethylhexasiloxane, the volatility dimethyl polysiloxane of ten hexamethyl, seven siloxanes etc., or by with other oiliness composition combination, can be had good stability the liquid cosmetic preparation of usability excellence.
In the oiliness composition of liquid cosmetic preparation of the present invention, can further cooperate oil-soluble medicament and/or spice, medicament immerses the effect that skin can improve cosmetics, and spice can be paid the armaticity psychological effects.
As the oil-soluble medicament, for example can enumerate retinol, retinyl acetate, retinol cetylate, Riboflavine Tertrabutyrate, pyridoxol dicaprylate, pyridoxol two Palmic acids, pyridoxol dilaurate, Vitamin C dipalmitate, vitamin D
2, vitamin D
3, tocopherols, tocopherol acetate, vitamin K, pyridine-.beta.-carboxylic acid benzyl ester, trichlorine diphenylurea, trichlorine hydroxy diphenyl ether, enoxolone acid stearyl ester, γ-Mi paddy phenol, dibutyl paracresol etc.
In the liquid cosmetic preparation of the present invention, cooperate 0.01～2 quality %, the oiliness composition that contains isostearic acid of preferred 0.1～1 quality %.During less than 0.01 quality %, the nebulousurine degree reduces (L-value increase), when surpassing 2 quality %, is difficult to obtain stable nebulousurine shape astringent.
(b) hydrophilic active agent
The hydrophilic active agent of using in the present invention is selected from polyoxyethylene (30) plant sterol, polyoxyethylene octyl group lauryl ether, polyoxyethylene polyoxypropylene decyl myristyl ether and polyoxyethylene hardened castor oil.When using the hydrophilic active agent beyond the mentioned component, can not stably cooperate the oiliness composition, the condition of high temperature issue estranged from.
As polyoxyethylene (30) plant sterol, the enumerated NIKKOL that sells on market BPS-30 (daylight ケ ミ カ Le ズ Co., Ltd. system trade name).
As polyoxyethylene octyl group lauryl ether, the enumerated Emalex that sells on market OD-30 (Japanese エ マ Le ジ ヨ Application Co., Ltd. system trade name), セ オ De one Le E-2020 (Japanese エ マ Le ジ ヨ Application Co., Ltd. system trade name).
As polyoxyethylene polyoxypropylene decyl myristyl ether, the enumerated エ that sells on market ス セ one Off 1324 (D) (NOF Corp's system trade name).
As polyoxyethylene hardened castor oil, the enumerated NIKKOL HCO-60 that sells on the market (daylight ケ ミ カ Le ズ Co., Ltd. system trade name).
In the liquid cosmetic preparation of the present invention, the use level of hydrophilic active agent is 0.04～1.0 quality %, preferred 0.08～0.20 quality %.During less than 0.04 quality %, take place to separate to obtain stable nebulousurine shape cosmetics, when surpassing 1.0 quality %, usability is clamminess.
(c) lipophile activating agent
The lipophile activating agent of Shi Yonging is selected from sesquialter isostearic acid sorbitan esters in the present invention, polyoxyethylene methyl polysiloxane copolymer.When using the lipophile activating agent beyond the mentioned component, can not obtain stable nebulousurine shape cosmetics.
As sesquialter isostearic acid sorbitan esters, can enumerate エ ス テ モ one Le 182V (day clear オ イ リ オ Co., Ltd. system trade name).As polyoxyethylene methyl polysiloxane copolymer, the enumerated シ that sells on market リ コ one Application KF6019 (KCC of SHIN-ETSU HANTOTAI system trade name).
In the liquid cosmetic preparation of the present invention, the use level of lipophile activating agent is 0.001～0.75 quality %, preferred 0.02～0.10 quality %.During less than 0.001 quality %, the oiliness composition can not be stably cooperated, when surpassing 0.75 quality %, stable nebulousurine shape cosmetics can not be obtained.
In the liquid cosmetic preparation of the present invention, above-mentioned (a) oiliness composition and (b) hydrophilic active agent composition and (c) the lipophile bioactive agent composition the total amount cooperate ratio (mass ratio) preferred (a): (b)+(c)=15: 1～1: 15, more preferably (a): (b)+(c)=5: 1～2: 1.
In the present invention,, the dissolubility of isostearic acid is increased, particularly when low temperature, can suppress separating out of isostearic acid etc. effectively, can improve long-time stability by further containing (d) isooctadecanol.(d) the suitable use level of isooctadecanol is 0.01～0.1 quality %.
Except that mentioned component, the composition that is used for general cosmetics can suit to cooperate in the scope of not damaging effect of the present invention in the liquid cosmetic preparation of the present invention.Such composition can be enumerated propylene glycol, dipropylene glycol, and 1,3 butylene glycol, 1,4-butanediol, diethylene glycol, 2,2'-ethylenedioxybis(ethanol)., molecular weight are higher than the glycols of Polyethylene Glycol of these compositions etc.; Glycerol, diglycerol, molecular weight are higher than the polyglycereol class of these compositions; Sorbitol, mannitol, maltose alcohol, xylitol, the sugar alcohols of erythritol etc.; Fructose, glucose, galactose, maltose, lactose, the saccharide of trehalose etc.; Talcum, Kaolin, Muscovitum, silicon dioxide, the inorganic powder of zeolite etc.; Polyamide powder (nylon powder), polyethylene powders, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, organic dusts such as cellulose powder; Titanium dioxide, the inorganic Chinese white of zinc oxide etc.; The inorganic red class pigment of ferrum oxide (iron oxide red) etc.; Yellow iron oxide, the inorganic yellow class pigment of loess etc.; Black iron oxide, the black class pigment of white carbon black etc.; Chromium oxide, chromic oxide gel, the inorganic green class pigment of cobalt titanate etc.; Ultramarine, the inorganic blue class pigment of dark purple indigo plant etc.; The be covered Muscovitum of titanium oxide, the Muscovitum of the painted titanium oxide that has been covered, bismuth oxychloride, the pearl pigment of guanin etc.; Aluminium powder, the metallic powdery pigment of copper powders may etc.; Red No. 201, red No. 202, red No. 204, red No. 205, red No. 220, red No. 226, red No. 228, red No. 405, orange No. 203, orange No. 204, yellow No. 205, yellow No. 401, and the organic pigment of blue No. 404 grades; Red No. 3, red No. 104, red No. 106, red No. 227, red No. 230, red No. 401, red No. 505, orange No. 205, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, the zirconium of green No. 3 and blue No. 1 etc., barium, the organic pigment in aluminum color lake etc.; Chlorophyll, the natural pigment of beta-carotene etc.; Arabic gum, Tragacanth, galactan, guar gum, tragon, karaya, the plant family macromolecule of gellan gum, carrageenin etc.; HANSHENGJIAO, glucosan, succinum polysaccharide, the microbiology class macromolecule of the mould polysaccharide of short stalk etc.; Virgin rubber, casein, albumin, the animal family macromolecule of gelatin etc.; Carboxymethyl starch, the starch based macromolecule of methyl hydroxypropyl starch etc.; Methylcellulose, ethyl cellulose, methylhydroxypropylcellulose, hydroxyethyl-cellulose, cellulose sodium sulfate, hydroxypropyl cellulose, carboxy methyl cellulose sodium, the cellulose macromolecule of crystalline cellulose etc.; Sodium alginate, the alginic acid family macromolecule of alginic acid propylene glycol ester etc.; Polyvinyl alcohol, polyvinyl acetate, polyvinyl methyl ethermaleic anhydride, polyvinylpyrrolidone, vinylpyrrolidone and vinyl acetate copolymerized compound, the vinyl macromolecule of CVP Carbopol ETD2050 etc.; Sodium polyacrylate, polyvinylacrylate, polyacrylic acid alkanolamine, alkyl methacrylate and dimethyl amino ethyl methacrylate copolymer, poly-2-acrylamido-2-methyl propane sulfonic acid, the acrylic polymer of polymethyl acyl-oxygen trimethyl ammonium etc.; Magnesium ascorbyl phosphate, ascorbic acid glucoside, pyridoxine hydrochloride, the vitamins of panthenol ether etc.; UV absorbent, chelating agen, antibacterial, antiinflammatory, antiseptic, plant extract, aminoacid, the medicament of freshener etc.; Ethanol, the lower alcohol of isopropyl alcohol etc., arbutin, tranamic acid, the amide body of tranamic acid or its salt, salicylic acid, alkoxyl salicylic acid or its salt, the water miscible medicament of 3-O-ethyl ascorbic acid or its salt etc., the wetting agent of polyoxyethylene polyoxypropylene dimethyl ether random copolymer etc.
Aqueous phase after stirring and dissolving adds surfactant and oiliness composition after the heating for dissolving while stirring, can make liquid cosmetic preparation of the present invention.
Liquid cosmetic preparation of the present invention is that L-value is 1～60 nebulousurine shape cosmetics.At this, L-value is to use SM color computer (SM-4: ス ガ testing machine Co., Ltd. system) for the yardstick of expression turbidity, in aquarium, pack into the purifying waste water of 5ml, transparency during with light transmission is 100, and light is blocked fully, and not having the transparency that sees through the light time is 0 numerical value of measuring.
It is the astringent of purpose that liquid cosmetic preparation of the present invention is used for the skin protection, beautifying liquid, and emulsion in addition, also can be used for the base of sunscreen, the base of tanned goods, the base of Cleaning preparations.Wherein be particularly preferred for the watery goods of making up.
Embodiment
Embodiments of the invention below are described.
Before embodiment, evaluation methodology and the standard thereof that adopts in the present embodiment is described earlier.
(1) averaged particles footpath
Use ALV-5000/EPP Multiple Tau Digital Correlator (Marubun Corporation's system) to measure the averaged particles footpath of the emulsion droplet of the astringent after newly modulating, estimate by following evaluation criterion.
◎: averaged particles footpath 300nm or below it.
Zero: averaged particles directly surpasses 300nm, 500nm or below it.
△: averaged particles directly surpasses 500nm, 3000nm or below it.
*: averaged particles directly surpasses 3000nm.
(2) footpath of the averaged particles after the vibration
Contain in well on the vibrator of flourish hall Co., Ltd. the glass container that half amount has been filled the 100mL of sample is installed, the speed vibration with 300 times/minute in the distance of 4cm was measured after 20 minutes, estimate transportation and use in vibration or the averaged particles footpath after the vibration.
◎: averaged particles footpath 300nm or below it.
Zero: averaged particles directly surpasses 300nm, 500nm or below it.
△: averaged particles directly surpasses 500nm, 3000nm or below it.
*: averaged particles directly surpasses 3000nm.
(3) long-time stability
Test specimen was preserved 3 months under 50 ℃ the temperature respectively at 0 ℃, by following standard evaluation long-time stability.
◎: can't see separation fully, the variation in averaged particles footpath etc. unusual.
Zero: see little by little and separating, the separating out of the variation in averaged particles footpath or isostearic acid wait unusually.
△: see little by little and separating, the separating out of the variation in averaged particles footpath or isostearic acid wait unusually.
*: see the variation in averaged particles footpath, the separating out of isostearic acid wait unusually.
(4) usability
Estimate the usability of nebulousurine shape cosmetics of the present invention by 20 women triers, service test is estimated by following standard.
◎: estimate very salubrious trier and be 16 or more than it.
Zero: estimating very salubrious trier is 10～15.
△: estimating very salubrious trier is 6～9.
*: estimate very salubrious trier and be 5 or below it.
Embodiment 1～16, comparative example 1～5
By the prescription of following table 1～4, make liquid cosmetic preparation with following method, its characteristic is estimated as stated above.Its result charges in table 1～4 in the lump.
In the table, dimethyl polysiloxane uses シ リ コ one Application KF-96L-1.5CS (chemistry society of SHIN-ETSU HANTOTAI system), POE (30) plant sterol uses ニ Star コ one Le BPS-30 (daylight ケ ミ カ Le ズ society system), POE octyl group lauryl ether uses エ マ レ Star Network ス OD-30 (Japanese エ マ Le ジ ヨ Application Co., Ltd. system), or セ オ De one Le E-2020 (Japanese エ マ Le ジ ヨ Application Co., Ltd. system), POEPOP decyl myristyl ether uses エ ス セ one Off 1324 (D) (Japanese oils and fats society system), sesquialter isostearic acid sorbitan esters is used エ ス テ モ one Le 182V (day clear オ イ リ オ Co., Ltd. system), POE methyl polysiloxane copolymer uses シ リ コ one Application KF6019 (KCC of SHIN-ETSU HANTOTAI system), POE docosyl ether uses ニ Star コ one Le BB-20 (daylight ケ ミ カ Le ズ society system), and isostearic acid POE glycerin ether uses エ マ レ Star Network ス GWIS (Japanese エ マ Le ジ ヨ Application society system).
(manufacture method)
Aqueous phase after stirring and dissolving, the surfactant～oiliness component layer that adds while stirring after the heating for dissolving obtains nebulousurine shape astringent.
Table 1
| The material name | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Water | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | |
| Octanoic acid, hexadecyl ester three-2 ethyl hexanoic acid glyceride four-2 ethyl hexanoic acid pentaerythritol ester saualane two neopentanoic acid trimerization propylene glycol ester dimethyl polysiloxane isostearic acids | - - - 0.25 - - 0.25 | - - - 0.25 - - 0.25 | 0.25 - - - - - 0.25 | - 0.25 - - - - 0.25 | - - 0.25 - - ? 0.25 | - - - - 0.25 - 0.25 | |
| POE (30) plant sterol POE octyl group lauryl ether POEPOP decyl myristyl ether polyoxyethylene hardened castor oil | 0.1 ? - - - | - ? 0.067 - - | - ? 0.1 - - | - ? 0.1 - - | - ? 0.1 - - | - ? 0.067 - - | |
| Sesquialter isostearic acid sorbitan esters POE methyl polysiloxane copolymer | 0.033 ? - | - ? 0.067 | 0.033 ? - | 0.033 ? - | 0.033 ? - | 0.033 ? 0.033 | |
| The 1,3 butylene glycol dipropylene glycol | 0.6 - | 0.6 - | 0.6 - | 0.6 - | 0.6 - | 0.6 - | |
| The citric acid sodium citrate | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | |
| Sodium versenate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
| Estimate | Particle footpath [nm] L-value stability of vibration long-time stability, (0 ℃) long-time stability, (50 ℃) usability | 170 50 ◎ ? ○ ◎ ◎ | 250 45 ◎ ? ○ ◎ ◎ | 150 40 ◎ ? ○ ◎ ◎ | 120 40 ◎ ? ○ ◎ ◎ | 150 35 ◎ ? ○ ◎ ◎ | 200 40 ◎ ? ○ ◎ ◎ |
Table 2
| The material name | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Embodiment 13 | |
| Water | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | |
| Octanoic acid, hexadecyl ester three-2 ethyl hexanoic acid glyceride four-2 ethyl hexanoic acid pentaerythritol ester saualane two neopentanoic acid trimerization propylene glycol ester dimethyl polysiloxane isostearic acids | - ? - ? - - ? 0.25 ? 0.25 | - ? - ? - - ? - 0.25 0.25 | 0.25 ? - ? - - ? - - 0.25 | - ? - ? - 0.3 ? - - 0.2 | - ? - ? - 0.33 ? - - 0.17 | - ? - ? - 0.4 ? - - 0.4 | - ? - ? ? 0.5 ? - - 0.5 | |
| POE (30) phytosterol POE octyl group lauryl ether POEPOP decyl myristyl ether polyoxyethylene hardened castor oil | ? 0.033 ? - ? ? - ? - ? | ? - ? 0.067 ? ? - ? - ? | ? - ? - ? ? 0.1 ? - ? | ? 0.09 ? - ? ? - ? - ? | ? 0.12 ? - ? ? - ? - ? | ? 0.1 ? - ? ? - ? - ? | ? 0.1 ? - ? ? - ? - ? | |
| Sesquialter isostearic acid sorbitan esters POE methyl polysiloxane copolymer | ? 0.067 ? 0.033 | ? 0.067 ? - | ? 0.033 ? - | ? 0.03 ? - | ? 0.04 ? - | ? 0.033 ? - | ? 0.033 ? - | |
| The 1,3 butylene glycol dipropylene glycol | 0.6 - | 0.6 - | 0.6 - | 0.54 - | 0.6 - | 0.6 - | 0.6 - | |
| The citric acid sodium citrate | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | |
| Sodium versenate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
| Estimate | Particle footpath [nm] L value stability of vibration long-time stability (0 ℃) long-time stability (50 ℃) usability | 200 40 ◎ ? ○ ? ◎ ? ◎ | 100 60 ◎ ? ○ ? ◎ ? ◎ | 150 40 ◎ ? ○ ? ◎ ? ◎ | 150 35 ◎ ? ◎ ? ◎ ? ◎ | 150 20 ◎ ? ◎ ? ○ ? ◎ | 180 15 ◎ ? ○ ? ○ ? ◎ | 200 7 ◎ ? ○ ? ○ ? ◎ |
Table 3
| The material name | Embodiment 14 | Embodiment 15 | Embodiment 16 | |
| Water | Remaining | Remaining | Remaining | |
| Octanoic acid, hexadecyl ester three-2 ethyl hexanoic acid glyceride four-2 ethyl hexanoic acid pentaerythritol ester saualane isooctadecanol two neopentanoic acid trimerization propylene glycol ester dimethyl polysiloxane isostearic acids | - 0.25 - - ? - - 0.25 | - - - 0.25 0.07 - - 0.18 | - - - 0.25 0.03 - - 0.22 | |
| POE (30) plant sterol POE octyl group lauryl ether POEPOP decyl myristyl ether polyoxyethylene hardened castor oil | - - - 0.12 | 0.09 - - - | 0.09 - - - | |
| Sesquialter isostearic acid sorbitan esters POE methyl polysiloxane copolymer | 0.04 - | 0.33 - | 0.33 - | |
| The 1,3 butylene glycol dipropylene glycol | 0.6 - | 0.54 - | 0.54 - | |
| The citric acid sodium citrate | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | |
| Sodium versenate | 0.1 | 0.1 | 0.1 | |
| Estimate | Particle footpath [nm] L-value stability of vibration long-time stability, (0 ℃) long-time stability, (50 ℃) usability | 180 42 ◎ ? ○ ○ ◎ | 130 42 ◎ ? ◎ ○ ◎ | 130 30 ◎ ? ◎ ◎ ◎ |
Table 4
| The material name | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | Comparative example 5 | |
| Water | Remaining | Remaining | Remaining | Remaining | Remaining | |
| Octanoic acid, hexadecyl ester three-2 ethyl hexanoic acid glyceride four-2 ethyl hexanoic acid pentaerythritol ester saualane two neopentanoic acid trimerization propylene glycol ester dimethyl polysiloxane isostearic acids | - - - 0.25 - - - | - - - 0.417 - - 0.083 | 0.25 - - - - - 0.25 | - 0.25 - - - - 0.25 | - - - 1 - - - | |
| POE (30) phytosterol POE octyl group lauryl ether POEPOP decyl myristyl ether polyoxyethylene hardened castor oil POE docosyl ether isostearic acid POE glyceride | 0.1 ? - ? - ? - - ? - | 0.1 ? - ? - ? - - ? - | - ? - ? - ? - 0.1 ? - | - ? - ? - ? - - ? 0.1 | 0.09 ? - ? - ? - - ? - | |
| Sesquialter isostearic acid sorbitan esters POE methyl polysiloxane copolymer | 0.033 - | - 0.067 | 0.033 - | 0.033 - | 0.033 - | |
| The 1,3 butylene glycol dipropylene glycol | 0.6 - | 0.6 - | 0.6 - | 0.6 - | 0.6 - | |
| The citric acid sodium citrate | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | 0.01 0.09 | |
| Sodium versenate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
| Estimate | Particle footpath [nm] L-value stability of vibration long-time stability, (0 ℃) long-time stability, (50 ℃) usability | 600 10 × ? △ × △ | 550 10 × ? △ △ △ | Separate-* * * * | Separate-* * * * | 600 5 × ? × × × |
Embodiment 17 nebulousurine astringent
(prescription)
Ethanol 5.0 (quality %)
Glycerol 1.0
1,3 butylene glycol 5.0
Polyoxyethylene (30) plant sterol 0.1
Sesquialter isostearic acid sorbitan esters 0.033
Squalane 0.25
Isostearic acid 0.25
Sodium hexameta phosphate 0.03
Trimethyl glycine 1.0
Poly (sodium aspartate) 0.1
Alpha-tocopherol-2-L-sodium ascorbyl phosphate diester potassium 0.1
Thiolaurine 0.1
Green tea extract 0.1
The West Folium Menthae extract 0.1
Orrisroot extract 0.1
HEDTA3 sodium 0.1
Citric acid 0.2
Sodium citrate 0.8
Phenyl phenol is an amount of
The Purified Water residual volume
Spice is an amount of
Embodiment 18 whitens and uses the nebulousurine astringent
(prescription)
Ethanol 10.0 (quality %)
Dipropylene glycol 1.0
1,3 butylene glycol 0.6
Cetomacrogol 1000 1.0
Glucam E-10 1.0
Isostearic acid 0.2
Three-2 ethyl hexanoic acid glyceride 0.3
Polyoxyethylene (30) plant sterol 0.09
Sesquialter isostearic acid sorbitan esters 0.03
Citric acid 0.05
Sodium citrate 0.2
Potassium hydroxide 0.4
Glycyrrhizic acid dipotassium 0.1
Arginine hydrochloride 0.1
L-ascorbic acid 2-glucoside 2.0
Radix Scutellariae extract 0.1
Herba Saxifragae extract 0.1
Herba lamii barbati extract 0.1
Tranamic acid 1.0
Sodium versenate 0.05
P-methoxycinnamic acid 2-ethyl hexyl ester 0.01
Dibutyl paracresol is an amount of
P-Hydroxybenzoate is an amount of
Deep seawater 3.0
The Purified Water residual volume
Spice is an amount of
Embodiment 19 nebulousurine astringent
(prescription)
Ethanol 5.0 (quality %)
Glycerol 1.0
1,3 butylene glycol 3.0
Polyoxyethylene octyl group lauryl ether 0.12
Sesquialter isostearic acid sorbitan esters 0.03
Octanoic acid, hexadecyl ester 0.2
Isostearic acid 0.4
Sodium hexameta phosphate 0.03
Trimethyl glycine 1.0
Poly (sodium aspartate) 0.1
Tocopheryl acetate 0.05
Thiolaurine 0.1
Green tea extract 0.1
The West Folium Menthae extract 0.1
Orrisroot extract 0.1
HEDTA3 sodium 0.1
Lactic acid 0.004
Sodium lactate 0.4
Phenyl phenol is an amount of
The Purified Water residual volume
Spice is an amount of
Embodiment 20 nebulousurine astringent
(prescription)
Ethanol 5.0 (quality %)
Glycerol 0.5
Dipropylene glycol 2.0
1,3 butylene glycol 6.0
Polyoxyethylene (30) plant sterol 0.06
Sesquialter isostearic acid sorbitan esters 0.02
Squalane 0.2
Isostearic acid 0.2
Oil of rosemary 0.01
Sage oil 0.01
Succinic acid 0.14
Disodium succinate 0.36
Sodium hexameta phosphate 0.03
Hydroxypropyl-beta-schardinger dextrin-0.1
Fructus Sapindi Mukouossi extract 0.1
Fructus rosae multiflorae extract 0.1
Bulbus Lilii extract 0.1
Cortex Phellodendri extract 0.1
Fructus Rosae Normalis extract 0.1
Rasp berry extract 0.1
Essential lavender oil 0.1
Semen Persicae extract 0.1
Sodium alginate 0.001
The Purified Water residual volume
Embodiment 21 nebulousurine astringent
(prescription)
Ethanol 5.0 (quality %)
Glycerol 1.0
1,3 butylene glycol 5.0
Polyoxyethylene (30) plant sterol 0.12
Sesquialter isostearic acid sorbitan esters 0.4
Squalane 0.4
Isostearic acid 0.4
Sodium hexameta phosphate 0.03
Trimethyl glycine 1.0
Poly (sodium aspartate) 0.1
Thiolaurine 0.1
Green tea extract 0.1
The West Folium Menthae extract 0.1
Orrisroot extract 0.1
HEDTA trisodium 0.1
Phenyl phenol is an amount of
Phosphoric acid 0.3
The Purified Water residual volume
Spice is an amount of
Claims (5)
1. a liquid cosmetic preparation is characterized in that, contains following (a)～(c) composition,
(a) the oiliness composition of 0.01～2 quality %, wherein, containing with respect to whole oiliness composition quality percentage ratios in this oiliness composition is 34% or isostearic acid more than it;
(b) the hydrophilic active agent of 0.04～1.0 quality %, wherein, this hydrophilic active agent is selected from polyoxyethylene (30) plant sterol, polyoxyethylene octyl group lauryl ether, polyoxyethylene polyoxypropylene decyl myristyl ether and polyoxyethylene hardened castor oil;
(c) the lipophile activating agent of 0.001～0.75 quality %, wherein, this lipophile activating agent is selected from sesquialter isostearic acid sorbitan esters, polyoxyethylene methyl polysiloxane copolymer.
2. liquid cosmetic preparation as claimed in claim 1 is characterized in that, above-mentioned (a) composition and (b) composition and (c) ratio (mass ratio) that cooperates of the total amount of composition be (a): (b)+(c)=15: 1～1: 15.
3. liquid cosmetic preparation as claimed in claim 1 is characterized in that, further contains (d) isooctadecanol.
4. liquid cosmetic preparation as claimed in claim 1 is characterized in that, the averaged particles of the dispersant liquid drop of oiliness composition directly is 100～500nm.
5. aqueous cosmetic product as claimed in claim 1 is characterized in that, is that L-value is 1～60 nebulousurine shape cosmetics.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004034479 | 2004-02-12 | ||
| JP034479/2004 | 2004-02-12 | ||
| JP360402/2004 | 2004-12-13 | ||
| JP2004360402A JP2005255667A (en) | 2004-02-12 | 2004-12-13 | Liquid cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1679500A true CN1679500A (en) | 2005-10-12 |
| CN100469347C CN100469347C (en) | 2009-03-18 |
Family
ID=35066532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100075846A Expired - Fee Related CN100469347C (en) | 2004-02-12 | 2005-02-08 | Liquid cosmetics |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2005255667A (en) |
| CN (1) | CN100469347C (en) |
| HK (1) | HK1084031A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288629B (en) * | 2007-04-20 | 2012-10-10 | 莱雅公司 | External Preparation |
| CN103781462A (en) * | 2011-09-14 | 2014-05-07 | 株式会社资生堂 | Liquid cosmetic material |
| CN113347959A (en) * | 2019-01-29 | 2021-09-03 | 株式会社资生堂 | Whitish and turbid cosmetic |
| CN114867451A (en) * | 2019-12-27 | 2022-08-05 | 株式会社资生堂 | Oily composition |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5072245B2 (en) * | 2006-03-24 | 2012-11-14 | 株式会社 資生堂 | Oil-in-water emulsified cloudy skin cosmetic |
| JP2009242326A (en) * | 2008-03-31 | 2009-10-22 | Shiseido Co Ltd | Skin-lightening liquid cosmetic |
| JP2010173999A (en) * | 2009-02-02 | 2010-08-12 | Shiseido Co Ltd | Liquid cosmetic |
| WO2018149491A1 (en) | 2017-02-15 | 2018-08-23 | Lvmh Recherche | Cosmetic lotion |
| JP7550451B2 (en) | 2021-04-13 | 2024-09-13 | 株式会社みらい中央研究所 | Translucent cosmetic material with radiance |
-
2004
- 2004-12-13 JP JP2004360402A patent/JP2005255667A/en active Pending
-
2005
- 2005-02-08 CN CNB2005100075846A patent/CN100469347C/en not_active Expired - Fee Related
-
2006
- 2006-04-11 HK HK06104390.2A patent/HK1084031A1/en not_active IP Right Cessation
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288629B (en) * | 2007-04-20 | 2012-10-10 | 莱雅公司 | External Preparation |
| CN103781462A (en) * | 2011-09-14 | 2014-05-07 | 株式会社资生堂 | Liquid cosmetic material |
| CN103781462B (en) * | 2011-09-14 | 2016-02-24 | 株式会社资生堂 | Liquid cosmetic |
| CN113347959A (en) * | 2019-01-29 | 2021-09-03 | 株式会社资生堂 | Whitish and turbid cosmetic |
| CN113347959B (en) * | 2019-01-29 | 2023-10-27 | 株式会社资生堂 | Cosmetic with white turbidity |
| CN114867451A (en) * | 2019-12-27 | 2022-08-05 | 株式会社资生堂 | Oily composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005255667A (en) | 2005-09-22 |
| CN100469347C (en) | 2009-03-18 |
| HK1084031A1 (en) | 2006-07-21 |
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